TWI718869B - Electronic device housings with chamfered edges - Google Patents
Electronic device housings with chamfered edges Download PDFInfo
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- TWI718869B TWI718869B TW109103960A TW109103960A TWI718869B TW I718869 B TWI718869 B TW I718869B TW 109103960 A TW109103960 A TW 109103960A TW 109103960 A TW109103960 A TW 109103960A TW I718869 B TWI718869 B TW I718869B
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/026—Anodisation with spark discharge
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/04—Anodisation of aluminium or alloys based thereon
- C25D11/06—Anodisation of aluminium or alloys based thereon characterised by the electrolytes used
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/26—Anodisation of refractory metals or alloys based thereon
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/30—Anodisation of magnesium or alloys based thereon
-
- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D11/00—Electrolytic coating by surface reaction, i.e. forming conversion layers
- C25D11/02—Anodisation
- C25D11/34—Anodisation of metals or alloys not provided for in groups C25D11/04 - C25D11/32
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- C—CHEMISTRY; METALLURGY
- C25—ELECTROLYTIC OR ELECTROPHORETIC PROCESSES; APPARATUS THEREFOR
- C25D—PROCESSES FOR THE ELECTROLYTIC OR ELECTROPHORETIC PRODUCTION OF COATINGS; ELECTROFORMING; APPARATUS THEREFOR
- C25D13/00—Electrophoretic coating characterised by the process
- C25D13/12—Electrophoretic coating characterised by the process characterised by the article coated
- C25D13/14—Tubes; Rings; Hollow bodies
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F1/00—Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
- G06F1/16—Constructional details or arrangements
- G06F1/1613—Constructional details or arrangements for portable computers
- G06F1/1633—Constructional details or arrangements of portable computers not specific to the type of enclosures covered by groups G06F1/1615 - G06F1/1626
- G06F1/1656—Details related to functional adaptations of the enclosure, e.g. to provide protection against EMI, shock, water, or to host detachable peripherals like a mouse or removable expansions units like PCMCIA cards, or to provide access to internal components for maintenance or to removable storage supports like CDs or DVDs, or to mechanically mount accessories
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- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06F—ELECTRIC DIGITAL DATA PROCESSING
- G06F1/00—Details not covered by groups G06F3/00 - G06F13/00 and G06F21/00
- G06F1/16—Constructional details or arrangements
- G06F1/18—Packaging or power distribution
- G06F1/181—Enclosures
- G06F1/182—Enclosures with special features, e.g. for use in industrial environments; grounding or shielding against radio frequency interference [RFI] or electromagnetical interference [EMI]
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
- B05D7/50—Multilayers
- B05D7/52—Two layers
- B05D7/54—No clear coat specified
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- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
- C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
- C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
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- H—ELECTRICITY
- H04—ELECTRIC COMMUNICATION TECHNIQUE
- H04M—TELEPHONIC COMMUNICATION
- H04M1/00—Substation equipment, e.g. for use by subscribers
- H04M1/02—Constructional features of telephone sets
- H04M1/0202—Portable telephone sets, e.g. cordless phones, mobile phones or bar type handsets
- H04M1/0279—Improving the user comfort or ergonomics
- H04M1/0283—Improving the user comfort or ergonomics for providing a decorative aspect, e.g. customization of casings, exchangeable faceplate
Abstract
Description
本發明係有關於具有倒角邊緣之電子裝置殼體。 The present invention relates to an electronic device housing with chamfered edges.
近年來,因為可攜式電子產器朝更輕且更小之方向發展,所以具有輕量及高剛性之金屬殼體很受到歡迎。在該等需求中,結合金屬殼體及塑膠構件或碳纖維構件之複合材料的技術已成為工業中之焦點。複合材料可為由具有不同物理性質之二或二個以上構成材料形成的材料。由該等複合材料製成之殼體可具有高強度及低密度。 In recent years, as portable electronic products have been developed to be lighter and smaller, metal housings with light weight and high rigidity are very popular. In these needs, the technology of combining metal shell and plastic component or carbon fiber component composite material has become the focus in the industry. The composite material may be a material formed of two or more constituent materials with different physical properties. Shells made of these composite materials can have high strength and low density.
在以下詳細說明中且參照圖式說明多個例子,其中: 依據本發明之一實施例,係特地提出一種電子裝置殼體,其包含:一金屬基材,其具有一周緣;一非金屬層,其形成在該金屬基材之一第一側上,該金屬基材之該第一側面向該電子裝置殼體之一內部;一漆塗層,其形成在該非金屬層上;一氧化物層,其形成在該金屬基材之一第二側上,該金屬基材之該第二側面向該電子裝置殼體之一外部;一倒角,其形成在該金屬基材之該周緣上;及一透明保護鈍化層,其形成在該倒角上。 In the following detailed description, a number of examples are described with reference to the drawings, among which: According to an embodiment of the present invention, an electronic device housing is specifically provided, which includes: a metal substrate having a peripheral edge; a non-metal layer formed on a first side of the metal substrate, the The first side of the metal substrate faces the inside of the electronic device casing; a lacquer coating formed on the non-metal layer; an oxide layer formed on a second side of the metal substrate, The second side surface of the metal substrate faces an outside of the electronic device casing; a chamfer formed on the periphery of the metal substrate; and a transparent protective passivation layer formed on the chamfer.
100:電子裝置殼體 100: electronic device housing
102:金屬基材 102: Metal substrate
104:非金屬層 104: Non-metallic layer
106:漆塗層 106: Lacquer coating
108:氧化物層 108: oxide layer
110:倒角 110: chamfer
112:透明保護鈍化層 112: Transparent protective passivation layer
114:周緣 114: Perimeter
152:電泳沈積層 152: Electrophoretic Deposition Layer
154:底漆塗層 154: Primer coating
156:基底塗層 156: Base coating
158:紫外線頂塗層 158: UV top coat
200,300:流程圖 200,300: flow chart
202,204,206,302,304,306,308,310,402,404,406,408,410,412,414,416,502,504,506, 508,510,512,514,516,602,604,606,608,610,612,614,616,702,704,706,708,710,712,714,716:步驟 202,204,206,302,304,306,308,310,402,404,406,408,410,412,414,416,502,504,506, 508,510,512,514,516,602,604,606,608,610,612,614,616,702,704,706,708,710,712,714,716: steps
400,500,600,700:製程 400,500,600,700: process
圖1A顯示一電子裝置殼體例之橫截面側視圖且顯示在一倒角上之一透明保護鈍化層; 圖1B顯示圖1A之電子裝置殼體例的橫截面側視圖且顯示其他形貌體;圖1C顯示圖1A之電子裝置殼體例的俯視圖且顯示該倒角;圖2顯示製造用於一電子裝置之外罩的一流程圖例;圖3顯示用於製造一電子裝置殼體之另一流程圖例;圖4與5顯示用於在一金屬-塑膠複合框架之一周緣的一倒角表面上形成一透明保護鈍化層及一電泳沈積層的製程例;及圖6與7顯示用於在一金屬-碳纖維複合框架之一周緣的一倒角表面上形成一透明保護鈍化層及一電泳沈積層的製程例。 1A shows a cross-sectional side view of an electronic device housing example and shows a transparent protective passivation layer on a chamfer; 1B shows a cross-sectional side view of the electronic device housing example of FIG. 1A and shows other topography; FIG. 1C shows a top view of the electronic device housing example of FIG. 1A and shows the chamfer; FIG. 2 shows a manufacturing method for an electronic device An example of a flow chart of the outer cover; Figure 3 shows another example of a flow chart for manufacturing an electronic device housing; Figures 4 and 5 show a transparent protection used to form a chamfered surface on a peripheral edge of a metal-plastic composite frame An example of the process of passivation layer and an electrophoretic deposition layer; and FIGS. 6 and 7 show an example of the process of forming a transparent protective passivation layer and an electrophoretic deposition layer on a chamfered surface of a peripheral edge of a metal-carbon fiber composite frame.
用於如行動電話、膝上型電腦、音樂播放器、個人數位助理及全球定位系統裝置等之電子裝置的殼體可由塑膠或金屬形成。金屬殼體具有較佳機械強度,但可導電,這會使通訊信號衰減。塑膠殼體不導電,但機械強度不足。某些殼體可具有如塑膠材料與金屬之一組合的複合材料。例如,一殼體可包括組裝在一起成為一整體之一塑膠層及一金屬層以獲得良好通訊及機械強度。例如,一殼體部份之一外層可由一金屬層形成,且該金屬層被一內塑膠支持。該外金屬層可為該殼體提供一耐磨、堅固及具美感之外觀。 The housings for electronic devices such as mobile phones, laptop computers, music players, personal digital assistants and global positioning system devices can be formed of plastic or metal. The metal shell has better mechanical strength, but can conduct electricity, which will attenuate the communication signal. The plastic shell is not conductive, but the mechanical strength is insufficient. Some shells may have a composite material such as a combination of plastic material and metal. For example, a housing may include a plastic layer and a metal layer assembled into a whole to obtain good communication and mechanical strength. For example, an outer layer of a housing part may be formed by a metal layer, and the metal layer is supported by an inner plastic. The outer metal layer can provide the shell with a wear-resistant, strong and aesthetic appearance.
金屬層例可為一鎂或鎂合金層。因為輕量及高機械強度,鎂合金適合使用在用於電子裝置之殼體中。但是,該鎂合金層具有不良顏色穩定性、硬度及化學抗性。因此,該等鎂合金會在表面氧化,故難以在該等鎂合金殼體之周緣表面產生金屬光澤感覺。 An example of the metal layer may be a magnesium or magnesium alloy layer. Because of its light weight and high mechanical strength, magnesium alloys are suitable for use in housings for electronic devices. However, the magnesium alloy layer has poor color stability, hardness and chemical resistance. Therefore, the magnesium alloys are oxidized on the surface, and it is difficult to produce a metallic luster feeling on the peripheral surface of the magnesium alloy shells.
在此所述之例子可提供一種電子裝置殼體,其包括如一金屬基材及一非金屬層(例如,一塑膠層或一碳纖維複合層)之一組合的一複合材料。該金屬基材可具有一周緣。此外,該電子裝置殼體可包括形成在該非金屬層上之一 漆塗層及形成在該金屬基材上之一氧化物層。該電子裝置殼體可包括形成在該金屬基材之該周緣上的一倒角。該電子裝置殼體可更包括形成在該倒角上之一透明保護鈍化層。另外,該電子裝置殼體可包括形成在該透明保護鈍化層及該氧化物層上之一電泳沈積層。如此形成在該倒角上之該透明保護鈍化層及該電泳沈積層可通過96小時鹽霧測試。 The example described here can provide an electronic device housing, which includes a composite material such as a combination of a metal substrate and a non-metal layer (for example, a plastic layer or a carbon fiber composite layer). The metal substrate may have a peripheral edge. In addition, the electronic device housing may include one formed on the non-metal layer The lacquer coating and an oxide layer formed on the metal substrate. The electronic device housing may include a chamfer formed on the periphery of the metal substrate. The electronic device housing may further include a transparent protective passivation layer formed on the chamfer. In addition, the electronic device housing may include an electrophoretic deposition layer formed on the transparent protective passivation layer and the oxide layer. The transparent protective passivation layer and the electrophoretic deposition layer thus formed on the chamfer can pass a 96-hour salt spray test.
在此所述之例子可在塑膠-金屬合金殼體及碳纖維複合金屬合金殼體之周緣提供金屬光澤倒角具美感表面。在此所述之例子可透過與鎂合金層組合來增加該塑膠或碳纖維複合外殼之機械強度(即,剛性)。在此所述之例子可提供一較輕及較強金屬-塑膠複合結構或金屬碳纖維複合結構。 The example described here can provide a metallic luster chamfering and aesthetic surface on the periphery of a plastic-metal alloy shell and a carbon fiber composite metal alloy shell. The examples described here can increase the mechanical strength (ie, rigidity) of the plastic or carbon fiber composite shell by combining with the magnesium alloy layer. The examples described here can provide a lighter and stronger metal-plastic composite structure or metal-carbon fiber composite structure.
在以下說明中,為了方便說明,提出許多特定細節以便徹底了解本技術。但是,所屬技術領域中具有通常知識者可了解的是本設備、裝置及系統可在沒有這些特定細節之情形下實施。在說明書中所稱之「一例子」或類似語言表示一所述特定形貌體、結構或特性至少包含在該一例子中,但不一定在其他例子中。 In the following description, for the convenience of description, many specific details are presented to thoroughly understand the technology. However, those with ordinary knowledge in the technical field can understand that this equipment, device, and system can be implemented without these specific details. The term "an example" or similar language in the specification means that a specific morphology, structure, or characteristic is included in at least this example, but not necessarily in other examples.
以下請參閱圖式,圖1A顯示一電子裝置殼體例之一橫截面側視圖且顯示在一倒角110上之一透明保護鈍化層112。電子裝置殼體100例可包括一智慧型手機殼體、平板或筆記型個人電腦殼體或數位相機殼體等。
Please refer to the drawings below. FIG. 1A shows a cross-sectional side view of an example of an electronic device housing and shows a transparent
電子裝置殼體100例可包括具有一周緣114之一金屬基材102。金屬基材102例可包括:鋁、鎂、鋁合金、鎂合金或其任何組合。電子裝置殼體100可包括形成在金屬基材102之一第一側上的一非金屬層104。該金屬基材102之第一側可面向電子裝置殼體100之一內部。非金屬層例可包括:塑膠、碳纖維複合材或其組合。
An example of the
此外,電子裝置殼體100可包括形成在該非金屬層104上之一漆塗層106。漆塗層106例係參照圖1B說明。另外,電子裝置殼體100可包括形成在金
屬基材102之一第二側上的一氧化物層108。該金屬基材102之第二側可面向電子裝置殼體100之一外部。例如,氧化物層108可為一微弧氧化層或一鈍化層。
In addition, the
此外,電子裝置殼體100可包括形成在金屬基材102之周緣114上的倒角110。在一例子中,倒角110可形成在金屬基材102之側壁上。另外,倒角110可具有任何適當形狀(例如,倒角、圓形或雙彎形等),因此賦予金屬基材102之周緣114(例如,一外周邊)任何適當橫截面形狀。倒角110可為電子裝置殼體100之美感地及觸覺地令人愉悅的形貌體。
In addition, the
此外,電子裝置殼體100可包括形成在倒角110上之透明保護鈍化層112。透明保護鈍化層112例可包括一金屬離子及一螯合劑之一錯合物。螯合劑例可包括:伸乙二胺四乙酸(EDTA)、伸乙二胺、氮三乙酸(NTA)、二伸乙三胺五(亞甲基膦酸)(DTPPH)、氮參(亞甲基膦酸)(NTMP)、1-羥乙烷-1,1-二膦酸(HEDP)、硫酸、磷酸或其任何組合。金屬離子例可為:鋁離子、鎳離子、錫離子、銦離子、鉻離子、鋅離子或其任何組合。在一例子中,透明保護鈍化層112可具有在30nm至3μm之範圍內的一厚度。
In addition, the
圖1B顯示圖1A之電子裝置殼體100例的橫截面側視圖且顯示其他形貌體。圖1C顯示圖1A之電子裝置殼體100例的俯視圖且顯示倒角110(即,一倒角邊緣)。例如,圖1B與1C之類似命名元件的結構及/或功能類似參照圖1A之命名元件。倒角100可在金屬基材102之一邊界部份形成一向外彎曲形狀或一向內彎曲基材。如圖1B所示,電子裝置殼體100可包括形成在透明保護鈍化層112及氧化物層108上之一電泳沈積層152。電泳沈積層152例可包括與有機及/或金屬顆粒結合之聚合物,例如聚丙烯酸酯聚合物或環氧聚合物。在一例子中,電泳沈積層152可具有在5至40μm之範圍內的一厚度。
FIG. 1B shows a cross-sectional side view of the
在圖1B所示之例子中,漆塗層106可包括形成在非金屬層104之一表面上的一底漆塗層154。底漆塗層154例可包括聚胺甲酸酯。在一例子中,底
漆塗層154可具有在5至20μm之範圍內的一厚度。此外,漆塗層106可包括形成在底漆塗層154上之一基底塗層156。基底塗層156例可包括與至少一顏料組合的聚胺甲酸酯,該至少一顏料係選自於由:碳黑、二氧化鈦、黏土、雲母、滑石、硫酸鋇、碳酸鈣、合成顏料、金屬粉末、氧化鋁、一有機粉末、一無機粉末、塑膠珠、有色顏料及染料構成之群組。在一例子中,基底塗層156可具有在10至20μm之範圍內的一厚度。
In the example shown in FIG. 1B, the
此外,漆塗層106可包括形成在基底塗層156上之一紫外線頂塗層158。紫外線頂塗層158例可包括:聚丙烯酸酯、聚胺甲酸酯、胺甲酸酯丙烯酸酯、丙烯酸丙烯酸酯、環氧丙烯酸酯或其任何組合。在一例子中,紫外線頂塗層158可具有在10至25μm之範圍內的一厚度。例如,紫外線頂塗層158可為一透明聚胺甲酸酯頂塗層且可藉由在60至80℃熱硬化來形成。
In addition, the
在圖1B所示之例子中,氧化物層108可形成在金屬基材102之第二側上,透明保護鈍化層112可沿著周緣114形成在倒角110上,且電泳沈積層152可形成在透明保護鈍化層112及氧化物層108上。如此形成在倒角110上之透明保護鈍化層112及電泳沈積層152可通過96小時鹽霧測試。此外,倒角110上之透明保護鈍化層112及電泳沈積層152可為周緣114提供一閃亮、平坦及平滑之金屬外觀。因此,包括倒角110之周緣114可為電子裝置殼體100提供一美感地吸引之外觀。
In the example shown in FIG. 1B, the
圖2顯示製造用於電子裝置之外罩的一流程圖200例。外罩例可為收容一顯示器之一顯示器殼體、收容一鍵盤之一鍵盤殼體或其組合的一部份。在步驟202,可在一複合金屬基材上施加一漆塗層。複合金屬基材例可為一金屬-塑膠複合基材或一金屬-碳纖維複合基材。金屬例可包括:鋁、鎂、鋁合金、鎂合金或其任何組合。用於施加該漆塗層之一例係在圖3中說明。
FIG. 2 shows an example of a
在步驟204,可倒角該複合金屬基材之一周緣以形成該複合金屬
基材之一暴露表面部份。在該周緣上形成該倒角後,可暴露該金屬基材於一或多個另外精加工程序,例如透明鈍化處理及電泳沈積。在步驟206,可在該周緣之暴露表面部份上施加一透明鈍化處理以形成一透明保護鈍化層。在一例子中,該透明鈍化處理可藉由施加包含一金屬離子及一螯合劑之一錯合物的一鈍化溶液在該暴露表面部份上來施加。此外,一電泳沈積可施加在包括該透明保護鈍化層之該複合金屬基材上。
In
圖3顯示另一用於製造一電子裝置殼體之流程圖300例。電子裝置殼體例可為一顯示器殼體、一鍵盤殼體或其任何組合。在步驟302,可在一金屬基材之一第一側上形成一非金屬層。該金屬基材之第一側可面向該電子裝置殼體之一內部。在一例子中,該非金屬層可包括塑膠。在這例子中,可使用一插入模製程序在該金屬基材之第一側上形成一塑膠層。塑膠層例可包括選自於由:聚丙烯腈、聚乙烯、聚丙烯、聚苯乙烯、聚乙烯乙酸酯、聚(甲基)丙烯酸酯、聚氯乙烯、氟聚合物、氯化聚醚、聚胺甲酸酯、聚醯胺、聚碳酸酯、聚酯、聚醯亞胺、聚鄰苯二甲醯胺、聚伸苯硫醚及聚碸構成之群組中的至少一材料。在另一例子中,該非金屬層可包括碳纖維複合材。在這例子中,可使用一壓縮模製程序在該金屬基材之該表面上形成一碳纖維複合層。
FIG. 3 shows another example of a
在步驟304,可在該金屬基材之一第二側上形成一氧化物層。該金屬基材之第二側可面向該電子裝置殼體之一外部。金屬基材例可包括:鋁、鎂、鋁合金、鎂合金或其任何組合。在其他例子中,該金屬基材可包括:鋰、鋅、鈦、鋰合金、鋅合金、鈦合金或其組合。在一例子中,藉由施加可為用於在金屬上產生氧化物塗層之電化學表面處理程序的一微弧氧化程序及一鈍化處理中之一者,在該金屬基材之第二側上形成該氧化物層。
In
例如,該微弧氧化程序可為用於在金屬基材上產生氧化物塗層之一程序。在該微弧氧化程序中,可將該金屬基材放在包括電解質之一電解質溶 液中,該電解質係選自於由:矽酸鈉、磷酸鈉、氟化鉀、氫氧化鉀、氫氧化鈉、氟鋯酸鹽、六偏磷酸鈉、氟化鈉、氧化鋁、二氧化矽、草酸鐵銨、磷酸鹽及聚環氧乙烷烷基酚醚構成之一群組。該電解質可依據該電解質溶液總重為基礎按重量用0.05至15%之一濃度存在且在200至600V之範圍內的一電壓可通過該電解質溶液並且該金屬基材(例如,鎂合金基材)放在該電解質溶液中以形成一微弧氧化層(即,該氧化物層)。在一例子中,該電壓可施加大約3至20分鐘且該微弧氧化程序可在室溫與45℃間之一溫度實行。該微弧氧化層之厚度可在3至15μm之範圍內。該微弧氧化性質可包括耐磨性、耐腐蝕性、高硬度及電絕緣性。 For example, the micro-arc oxidation process may be a process used to produce an oxide coating on a metal substrate. In the micro-arc oxidation process, the metal substrate can be placed in an electrolyte solution including an electrolyte. In the liquid, the electrolyte is selected from: sodium silicate, sodium phosphate, potassium fluoride, potassium hydroxide, sodium hydroxide, fluorozirconate, sodium hexametaphosphate, sodium fluoride, alumina, silicon dioxide , Ferric ammonium oxalate, phosphate and polyethylene oxide alkylphenol ether form a group. The electrolyte can exist in a concentration of 0.05 to 15% by weight based on the total weight of the electrolyte solution and a voltage in the range of 200 to 600V can pass through the electrolyte solution and the metal substrate (for example, magnesium alloy substrate ) Is placed in the electrolyte solution to form a micro-arc oxidation layer (ie, the oxide layer). In one example, the voltage can be applied for about 3 to 20 minutes and the micro-arc oxidation process can be performed at a temperature between room temperature and 45°C. The thickness of the micro-arc oxidation layer can be in the range of 3 to 15 μm. The micro-arc oxidation properties may include wear resistance, corrosion resistance, high hardness, and electrical insulation.
類似地,鈍化處理可為處理或塗布該金屬基材以減少該金屬基材之一表面的化學反應性的程序。例如,該鈍化處理可包括產生環繞該金屬基材之一屏蔽材料外層以使該金屬基材「鈍化」,即,比較不會被環境影響或腐蝕。該非金屬層可實質地覆蓋該金屬基材之全部第一側使得實行微弧氧化或鈍化處理後,該第一側可不被該氧化物層覆蓋。 Similarly, the passivation treatment can be a process of treating or coating the metal substrate to reduce the chemical reactivity of a surface of the metal substrate. For example, the passivation treatment may include creating an outer layer of shielding material surrounding the metal substrate to "passivate" the metal substrate, that is, less environmentally affected or corroded. The non-metallic layer can substantially cover the entire first side of the metal substrate so that after the micro-arc oxidation or passivation treatment is performed, the first side may not be covered by the oxide layer.
在步驟306,可在該非金屬層上施加一漆塗層。在一例子中,在該非金屬層上施加該漆塗層可包括:在該非金屬層之一表面上施加一底漆塗層;在該底漆塗層上施加一基底塗層;及在該基底塗層上施加一紫外線頂塗層。
In
例如,在該非金屬層之表面上施加該底漆塗層可包括:在該非金屬層之表面上施加聚胺甲酸酯混合物;及接著在60至80℃之一溫度乾燥該聚胺甲酸酯混合物大約15至40分鐘。該底漆塗層可具有在5至20μm之範圍內的一厚度。 For example, applying the primer coating on the surface of the non-metallic layer may include: applying a polyurethane mixture on the surface of the non-metallic layer; and then drying the polyurethane at a temperature of 60 to 80°C The mixture is about 15 to 40 minutes. The primer coating may have a thickness in the range of 5 to 20 μm.
此外,在該底漆塗層上施加該基底塗層可包括:施加聚胺甲酸酯與至少一顏料組合之一混合物,該至少一顏料係選自於由:碳黑、二氧化鈦、黏土、雲母、滑石、硫酸鋇、碳酸鈣、合成顏料、金屬粉末、氧化鋁、一有機 粉末、一無機粉末、塑膠珠、有色顏料及染料構成之群組;及接著在60至80℃之一溫度乾燥該混合物大約15至40分鐘。該基底塗層可具有在10至20μm之範圍內的一厚度。 In addition, applying the base coating on the primer coating may include: applying a mixture of polyurethane and at least one pigment combination, the at least one pigment is selected from: carbon black, titanium dioxide, clay, mica , Talc, barium sulfate, calcium carbonate, synthetic pigments, metal powder, alumina, an organic The group consisting of powder, an inorganic powder, plastic beads, colored pigments and dyes; and then the mixture is dried at a temperature of 60 to 80°C for about 15 to 40 minutes. The base coating may have a thickness in the range of 10 to 20 μm.
另外,在該基底塗層上施加該紫外線頂塗層可包括:施加一混合物,該混合物係選自於由:聚丙烯酸酯、聚胺甲酸酯、胺甲酸酯丙烯酸酯、丙烯酸丙烯酸酯及環氧丙烯酸酯構成之群組;及接著在50至60℃之一溫度乾燥該混合物大約10至15分鐘,然後在700至1,200mJ/cm2之範圍內進行紫外線曝光10至30秒。該紫外線頂塗層可具有在10至25μm之範圍內的一厚度。 In addition, applying the UV top coat on the base coat may include: applying a mixture selected from the group consisting of: polyacrylate, polyurethane, urethane acrylate, acrylic acrylate and The group consisting of epoxy acrylate; and then the mixture is dried at a temperature of 50 to 60° C. for about 10 to 15 minutes, and then UV exposure is performed in the range of 700 to 1,200 mJ/cm 2 for 10 to 30 seconds. The ultraviolet top coat may have a thickness in the range of 10 to 25 μm.
在步驟308,可倒角該金屬基材之一周緣以形成該金屬基材之一暴露表面部份。在一例子中,可使用一電腦數值控制(CNC)切削或一雷射雕刻程序等倒角該周緣。在步驟310,可在該周緣之暴露表面部份上形成一透明保護鈍化層。在一例子中,該透明保護鈍化層可藉由施加包含一金屬離子及一螯合劑之一錯合物的一鈍化溶液在該暴露表面部份上形成該透明保護鈍化層。金屬離子及螯合劑例係在圖1A中說明。該透明保護鈍化層可防止腐蝕透過該暴露表面部份暴露之金屬基材。
In
此外,可藉由施加電泳沈積在該透明保護鈍化層及該氧化物層上形成一電泳沈積層。電泳沈積可為將該金屬基材放在一流體中且施加一電位差以使該流體中之帶電粒子沈積在該金屬基材上的一程序。電泳沈積可用於使該基材產生某些所需性質,例如硬度及韌性、或某種所需外觀。該漆塗層可實質地覆蓋該非金屬層之一第一表面使得實行透明鈍化處理或電泳沈積後,該第一表面可未被該透明保護鈍化層或該電泳沈積層覆蓋。 In addition, an electrophoretic deposition layer can be formed on the transparent protective passivation layer and the oxide layer by applying electrophoretic deposition. Electrophoretic deposition can be a process in which the metal substrate is placed in a fluid and a potential difference is applied to deposit the charged particles in the fluid on the metal substrate. Electrophoretic deposition can be used to give the substrate certain desired properties, such as hardness and toughness, or a certain desired appearance. The lacquer coating may substantially cover a first surface of the non-metallic layer so that after transparent passivation treatment or electrophoretic deposition is performed, the first surface may not be covered by the transparent protective passivation layer or the electrophoretic deposition layer.
圖4顯示用於在一金屬-塑膠複合框架之一周緣的一倒角表面上形成一透明保護鈍化層及一電泳沈積層的一製程400例。在步驟402,可預成形一金屬合金框架。例如,預成形該金屬合金框架可包括:鍛造、模鑄或CNC切
削該金屬基材成為一所需形狀且接著清潔該鍛造、模鑄或CNC切削之金屬合金框架。該金屬基材之清潔包括一預清潔程序,例如一鹼清潔程序、去油清潔程序、一酸清潔程序或其任何組合。
4 shows a 400 example of a process for forming a transparent protective passivation layer and an electrophoretic deposition layer on a chamfered surface of a peripheral edge of a metal-plastic composite frame. In
在步驟404,可使用一插入模製程序在該金屬基材之一側上形成一塑膠層。插入模製可為塑膠注入收容該預置金屬基材之一模中的一程序。在步驟406,可修整該塑膠層以移除延伸超出該金屬基材之額外塑膠材料以獲得一所需形狀。在步驟408,可在包括一周緣的該金屬基材之另一側上施加一鈍化處理。在步驟410,可在該塑膠層上形成一漆塗層。漆塗層例可在圖3中說明。
In
在步驟412,可倒角該金屬基材之周緣以形成該金屬基材之一暴露表面部份。在步驟414,可在該周緣之暴露表面部份上形成一透明保護鈍化層。在步驟416,可藉由施加電泳沈積在該透明保護鈍化層及該氧化物層上形成一電泳沈積層。該電泳沈積可包括與選自於包含無機及金屬顆粒之群組的顆粒組合的一聚合物。
In
圖5顯示用於在一金屬-塑膠複合框架之一周緣的一倒角表面上形成一透明保護鈍化層及一電泳沈積層的另一製程500例。在步驟502,可預成形一金屬合金框架。
FIG. 5 shows another 500 example of a process for forming a transparent protective passivation layer and an electrophoretic deposition layer on a chamfered surface of a peripheral edge of a metal-plastic composite frame. In
在步驟504,可使用一插入模製程序在該金屬基材之一側上形成一塑膠層。在步驟506,可修整該塑膠層以移除額外塑膠材料以獲得一所需形狀。在步驟508,可在包括一周緣的該金屬基材之另一側上施加一微弧氧化。在步驟510,可在該塑膠層上形成一漆塗層。
In
在步驟512,可倒角該金屬基材之周緣以形成該金屬基材之一暴露表面部份。在步驟514,可在該周緣之暴露表面部份上形成一透明保護鈍化層。在步驟516,可藉由施加電泳沈積在該透明保護鈍化層及該氧化物層上形成一電泳沈積層。
In
圖6顯示用於在一金屬-碳纖維複合框架之一周緣的一倒角表面上形成一透明保護鈍化層及一電泳沈積層的一製程600例。 FIG. 6 shows 600 examples of a process for forming a transparent protective passivation layer and an electrophoretic deposition layer on a chamfered surface of a peripheral edge of a metal-carbon fiber composite frame.
在步驟602,可預成形一金屬合金框架。在步驟604,可使用一壓縮模製程序在該金屬基材之一側上形成一碳纖維複合層。該碳纖維複合層可使用該壓縮模製程序直接地黏著在該金屬基材上。壓縮模製可為碳纖維複合材料可直接放入一加熱金屬模中,被加熱軟化且接著在該模關閉時被迫與該模之形狀一致的一成形程序。
In
在步驟606,可修整該碳纖維複合層以移除額外碳纖維複合材料(即,不必要部份)以獲得一所需形狀。在步驟608,可在包括一周緣的該金屬基材之另一側上施加一鈍化處理。在步驟610,可在該碳纖維複合層上形成一漆塗層。漆塗層例可在圖3中說明。
In
在步驟612,可倒角該金屬基材之周緣以形成該金屬基材之一暴露表面部份。在步驟614,可藉由施加透明鈍化處理在該周緣之暴露表面部份上形成一透明保護鈍化層。在步驟616,可藉由施加電泳沈積在該透明保護鈍化層及該氧化物層上形成一電泳沈積層。
In
圖7顯示用於在一金屬-碳纖維複合框架之一周緣的一倒角表面上形成一透明保護鈍化層及一電泳沈積層的另一製程700例。在步驟702,可預成形一金屬合金框架。
FIG. 7 shows another 700 example of a process for forming a transparent protective passivation layer and an electrophoretic deposition layer on a chamfered surface of a peripheral edge of a metal-carbon fiber composite frame. In
在步驟704,可使用一壓縮模製程序在該金屬基材之一側上形成一碳纖維複合層。在步驟706,可修整該碳纖維複合層以移除額外碳纖維複合材料(即,不必要部份)以獲得一所需形狀。在步驟708,可在包括一周緣的該金屬基材之另一側上施加一微弧氧化。在步驟710,可在該碳纖維複合層上形成一漆塗層。
In
在步驟712,可倒角該金屬基材之周緣以形成該金屬基材之一暴
露表面部份。在步驟714,可在該周緣之暴露表面部份上形成一透明保護鈍化層。在步驟716,可藉由施加電泳沈積在該透明保護鈍化層及該氧化物層上形成一電泳沈積層。
In
依此方式,本申請案揭露一金屬-塑膠複合殼體或金屬-碳纖維複合殼體,其中在該等金屬合金殼體之周緣表面可具有金屬光澤感覺。 In this way, the present application discloses a metal-plastic composite shell or a metal-carbon fiber composite shell, wherein the peripheral surface of the metal alloy shell can have a metallic luster feeling.
以上說明在周緣表面具有金屬光澤感覺之金屬-塑膠複合殼體或金屬-碳纖維複合殼體。雖然參照前述例子顯示及說明了上述申請案,但應了解的是在不偏離這申請案之精神與範疇之情形下作成其他形式、細節及實施例。 The above description has a metal-plastic composite shell or a metal-carbon fiber composite shell with a metallic luster on the peripheral surface. Although the above-mentioned application is shown and explained with reference to the aforementioned examples, it should be understood that other forms, details and embodiments can be made without departing from the spirit and scope of this application.
100:電子裝置殼體 100: electronic device housing
102:金屬基材 102: Metal substrate
104:非金屬層 104: Non-metallic layer
106:漆塗層 106: Lacquer coating
108:氧化物層 108: oxide layer
110:倒角 110: chamfer
112:透明保護鈍化層 112: Transparent protective passivation layer
114:周緣 114: Perimeter
Claims (12)
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WOPCT/US19/29252 | 2019-04-26 | ||
PCT/US2019/029252 WO2020219061A1 (en) | 2019-04-26 | 2019-04-26 | Electronic device housings with chamfered edges |
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TW202041123A TW202041123A (en) | 2020-11-01 |
TWI718869B true TWI718869B (en) | 2021-02-11 |
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WO2022197305A1 (en) * | 2021-03-19 | 2022-09-22 | Hewlett-Packard Development Company, L.P. | Housings for electronic devices |
CN114507892B (en) * | 2022-01-14 | 2023-11-24 | 电子科技大学 | Tantalum alloy self-lubricating wear-resistant antifriction composite coating and preparation method thereof |
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TW201536953A (en) * | 2014-03-17 | 2015-10-01 | Ke Hui Lan | Method for forming protective coating layer of magnesium alloy and protective coating layer of magnesium alloy therefrom |
CN106455391A (en) * | 2016-09-28 | 2017-02-22 | 东莞劲胜精密组件股份有限公司 | 3C electronic product housing and preparation method thereof |
CN107548255A (en) * | 2017-08-07 | 2018-01-05 | 维沃移动通信有限公司 | A kind of terminal shell and preparation method thereof |
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JP2001509549A (en) * | 1997-07-11 | 2001-07-24 | マグネシウム テクノロジー リミティド | Method for sealing metal and / or anodized metal substrate |
KR100848656B1 (en) * | 1999-03-26 | 2008-07-28 | 데이비드 에이. 라포인트 | Abrasion resistant coating and articles coated therewith |
JP2007204835A (en) * | 2006-02-03 | 2007-08-16 | Nippon Paint Co Ltd | Surface conditioning composition and surface conditioning method |
US9114487B2 (en) * | 2012-05-29 | 2015-08-25 | Apple Inc. | Components of an electronic device and methods for their assembly |
WO2016178675A1 (en) * | 2015-05-06 | 2016-11-10 | Hewlett-Packard Development Company, L.P. | Electroplating and electrophoretic deposition over surfaces of metal substrate |
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TW201536953A (en) * | 2014-03-17 | 2015-10-01 | Ke Hui Lan | Method for forming protective coating layer of magnesium alloy and protective coating layer of magnesium alloy therefrom |
CN106455391A (en) * | 2016-09-28 | 2017-02-22 | 东莞劲胜精密组件股份有限公司 | 3C electronic product housing and preparation method thereof |
CN107548255A (en) * | 2017-08-07 | 2018-01-05 | 维沃移动通信有限公司 | A kind of terminal shell and preparation method thereof |
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