TWI718069B - Compositions having odor eliminating and maintaining fragrance - Google Patents
Compositions having odor eliminating and maintaining fragrance Download PDFInfo
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本發明是有關於一種組合物,尤指一種可大幅提升臭味消除的效果並大幅延長香味保留時間之具除臭留香之組合物。The present invention relates to a composition, in particular to a composition with deodorizing and fragrance retention that can greatly enhance the effect of odor elimination and greatly extend the retention time of fragrance.
日常生活中,人們會使用洗滌劑來去除髒汙,並且隨著生活水準的日漸增高,人們對於異常惡臭較難以忍受,舉例來說,衣物、被單被套等等日常用品的污漬單純使用清水很難除去,所以人們經常會借助洗滌劑去除被洗物沾染的污漬。而相比於無味的洗滌劑,芳香洗滌劑是很多人們的偏好,由於芳香劑會附著於被洗物,使被洗物具有芳香潔淨的嗅覺印象。隨著人們生活水準的提高,對留香洗滌劑的溶解速率和被洗物經洗後的留香要求也越來越高,希望留香洗滌劑可以緩釋長效。 而目前市面上的除臭留香洗滌劑在使用上,保留香味的時效較短(約2~3天),導致需要反覆的進行使用帶有香味的洗滌劑或者額外使用香味洗滌劑,使用上較為不方便之外,還大幅增加使用成本。 以上所述,習知具有下列之缺點: 1.消除臭味效果較差; 2.香味保留的時間較短。 是以,要如何解決上述習用之問題與缺失,即為本案之發明人與從事此行業之相關廠商所亟欲研究改善之方向所在者。 In daily life, people use detergents to remove dirt, and with the increasing standard of living, people are more difficult to tolerate abnormal stench. For example, it is difficult to use clean water for stains on daily necessities such as clothes, sheets and quilts. Remove, so people often use detergent to remove stains contaminated by the laundry. Compared with odorless detergents, aromatic detergents are the preference of many people. Because the fragrances will adhere to the laundry, the laundry has a fragrance and clean olfactory impression. With the improvement of people's living standards, the dissolution rate of fragrance-retaining detergents and the fragrance retention requirements of the laundry after washing have become higher and higher, and it is hoped that fragrance-retaining detergents can have a slow release and long-term effect. However, the deodorizing and fragrance-retaining detergents currently on the market have a shorter retention time (about 2 to 3 days), which leads to repeated use of fragranced detergents or additional fragrance detergents. In addition to being more inconvenient, it also greatly increases the cost of use. As mentioned above, conventional knowledge has the following shortcomings: 1. Poor odor elimination effect; 2. The fragrance retention time is shorter. Therefore, how to solve the above-mentioned conventional problems and deficiencies is the direction that the inventor of this case and the related manufacturers engaged in this industry urgently want to study and improve.
爰此,為有效解決上述之問題,本發明之主要目的在於提供一種可大幅提升臭味消除的效果之具除臭留香之組合物。
本發明之次要目的,在於提供一種可大幅延長香味保留的時間之具除臭留香之組合物。
為達上述目的,本發明係提供一種具除臭留香之組合物,係包含(a)甲基巴豆酸香茅酯(Citronellyl Methylcrotonate)、(b)縮合單寧(condensed tannin)、(c)醛類化合物及(d)PPG-10甲基葡糖醚(PPG-10 Methyl Glucose Ether),其中甲基巴豆酸香茅酯佔該組合物之0.1重量%至2.0重量%,縮合單寧佔該組合物之1.0重量%至7.0重量%,醛類化合物佔該組合物之0.1重量%至2.0重量%,PPG-10甲基葡糖醚佔該組合物之0.1重量%至5.0重量%。
在一實施例中,其中所述甲基巴豆酸香茅酯佔該組合物之最佳重量%為0.2重量%至1.0重量%。
在一實施例中,其中所述縮合單寧佔該組合物之最佳重量%為3.0重量%至5.0重量%。
在一實施例中,其中所述醛類化合物佔該組合物之最佳重量%為0.5重量%至1.0重量%。
在一實施例中,其中所述PPG-10甲基葡糖醚佔該組合物之最佳重量%為1.0重量%至3.0重量%。
在一實施例中,其中所述組合物更包含水及界面活性劑,該界面活性劑係選擇為PEG-40氫化篦麻油(PEG-40 Hydrogenated Castor Oil)或聚山梨醇脂20(Polysorbate 20)。
在一實施例中,其中所述組合物係選擇添加於一待添加物內,該待添加物係選擇為化妝品、保養品、洗滌產品、生活用品、農畜業除臭產品或工業用除臭產品。
在一實施例中,其中所述待添加物選擇為固態或液態或氣態。
在一實施例中,其中所述組合物可延長香味保留時間5至7天。
透過本發明的設計,將前述之組合物根據應用的產業及使用者的需求添加至該待添加物內混合攪拌,而該待添加物可以是女性使用的化妝品(如:體香膏、香水等)或保養品上,或居家生活中常用的清潔用品(如:沐浴乳、洗髮精、廚房/浴室洗淨劑、鞋內除臭劑等)或是寵物的洗滌產品(如:寵物洗毛精)、消臭噴霧,甚至是農畜業使用的除臭產品(如:生物除臭劑、植物除臭劑、圈舍除臭劑、禽畜養殖除臭劑等)或工業用除臭產品(如:汙水除臭劑等),換句話說,該組合物可針對每一位使用者以及各產業各種不同的需求將該組合物加至呈固態、液態或氣態的待添加物內,如此一來,可增強待添加物針對異常惡臭除臭之效果、延緩氣味衰減的速度,並且可拉長待添加物原本的香味保留時間。
Therefore, in order to effectively solve the above-mentioned problems, the main purpose of the present invention is to provide a deodorant and fragrance-retaining composition that can greatly improve the effect of odor elimination.
The secondary objective of the present invention is to provide a deodorant and fragrance-retaining composition that can greatly extend the retention time of fragrance.
To achieve the above objective, the present invention provides a deodorant and fragrance-retaining composition, which contains (a) Citronellyl Methylcrotonate, (b) condensed tannin, and (c) Aldehydes and (d) PPG-10 Methyl Glucose Ether (PPG-10 Methyl Glucose Ether), wherein citronellyl methyl crotonate accounts for 0.1% to 2.0% by weight of the composition, and condensed tannin accounts for the composition 1.0% to 7.0% by weight of the composition, the aldehyde compound accounts for 0.1% to 2.0% by weight of the composition, and PPG-10 methyl glucose ether accounts for 0.1% to 5.0% by weight of the composition.
In one embodiment, the optimal weight% of the citronellyl methylcrotonate of the composition is 0.2% to 1.0% by weight.
In one embodiment, the optimal weight% of the condensed tannins of the composition is 3.0% to 5.0% by weight.
In one embodiment, the optimal weight% of the aldehyde compound in the composition is 0.5% to 1.0% by weight.
In one embodiment, the optimal weight% of the PPG-10 methyl glucose ether of the composition is 1.0% to 3.0% by weight.
In one embodiment, the composition further comprises water and a surfactant, and the surfactant is selected as PEG-40 Hydrogenated Castor Oil or
本發明之上述目的及其結構與功能上的特性,將依據所附圖式之較佳實施例予以說明。
除非另有說明,否則所有以重量百分比形式提供之量係以整個組合物計,合先敘明。
請參閱第1圖,係為本發明具除臭留香之組合物之示意圖,如圖所示,一種具除臭留香之組合物2,係包含(a)甲基巴豆酸香茅酯20(Citronellyl Methylcrotonate,3,7-dimethyloct-6-enyl 3-methylbut-2-enoate,分子式為C
15H
26O
2)、(b)縮合單寧21(condensed tannin)、(c)醛類化合物22及(d)PPG-10甲基葡糖醚23(PPG-10 Methyl Glucose Ether),將前述甲基巴豆酸香茅酯20、縮合單寧21、醛類化合物22及PPG-10甲基葡糖醚23混合攪拌均勻後即成為該組合物2,需注意的是,於攪拌過程中,在攝氏約30~40度、環境濕度約40%~60%RH環境下攪拌時間約30~60分鐘,並且需配戴口罩、防滲手套、安全眼鏡、工作鞋及防護衣,而攪拌完成後需徹底洗淨雙手,以防化學物殘留於手上。
在某些實施例中,該組合物2除了前述四種成分外,該組合物2進一步可包含水及界面活性劑(如:PEG-40氫化篦麻油(PEG-40 Hydrogenated Castor Oil,其佔該組合物之3.0重量%至10.0重量%)或聚山梨醇脂20(Polysorbate 20,其佔該組合物之3.0重量%至8.0重量%)),當然,使用者可依照需求調整水及界面活性劑的重量%,並不以前述為限。
(a)甲基巴豆酸香茅酯20為一種消臭成分,其結構式為:
是天然香茅醇的無味衍生物,甲基巴豆酸香茅酯20通過兩步驟來進行化學反應:
一、利用雙鍵的結構來捕捉易產生反應且難聞的分子,例如:胺類、硫醇類、氧化劑及還原劑;
二、由細菌或皮膚上的酶藉由新陳代謝作用釋放香茅醇,而香茅醇即具有遮蓋難聞氣味之功能。
(b)縮合單寧21為一種消臭成分,其結構式為:
由於縮合單寧21擁有較複雜的結構式,其擁有眾多的酚羥基(-OH),能與各種惡臭因子結合並產生反應,具有消臭效果,發揮強大消臭力。
(c)醛類化合物22也是一種消臭成分,其結構式為:
而醛類化合物22之液相對硫分子的反應如下:
R
1CHO + 2RSH → R
1CH(SR)
2+ H
2O
醛類化合物22之氣相對硫分子的反應如下:
RCHO +R
1NH → RCH= NR
1+ H
2O
並且,醛類化合物22具有協同作用而得以中和難聞的氣味;
其中,本發明之醛類化合物22具體可選自香茅素3,7-二甲基-6-辛烯-1-醛(citronellal 3,7-dimethyl-6-octen-1-al)、樟腦醛(campholenic aldehyde)、2,3,5,5-四甲基己醛(2,3,5,5-tetramethyl-hexanal)、(4-甲基-3-戊烯基)-4-環己烯-3-基甲醛((4-methyl-3-pentene-yl)-4-cyclohexene-3-yl carboxaldehyde)、苯乙醛(phenylacetic aldehyde)、烷氧基乙醛(alkoxy-acetaldehyde)、紫蘇醛(perilla aldehyde)、十一碳烯-10-醛(undecene-10-al)、仙客來醛(cyclamen aldehyde)、3-苯基丙醛(3-phenyl-propionic aldehyde)、親水醛(hydratropic aldehyde)、α-己基肉桂醛(α-hexylcinnamic aldehyde)、苯甲醛(benzaldehyde)、茴香醛(anisic aldehyde)、凡醛(veratric aldehyde)所組成之群組中的一種或多種。
(d)PPG-10甲基葡糖醚23則是一種定香成分,其結構式為:
由於PPG-10甲基葡糖醚23係為保濕劑的一種成分,即表示可長時間滯留於接觸面,同時具備官能基PPG-10為一親油端結構,又香味分子屬於油性物質,故PPG-10甲基葡糖醚23可作為香味分子與接觸面的嫁接橋樑,因此可令香味分子更長間停留於目標表面。
以組合物2重量計,甲基巴豆酸香茅酯20(Citronellyl Methylcrotonate)佔該組合物2之0.1重量%至2.0重量%,最佳重量%為0.2重量%至1.0重量%,縮合單寧21(condensed tannin)佔該組合物2之1.0重量%至7.0重量%,最佳重量%為3.0重量%至5.0重量%,醛類化合物22(RCHO)佔該組合物2之0.1重量%至2.0重量%,最佳重量%為0.5重量%至1.0重量%,PPG-10甲基葡糖醚23(PPG-10 Methyl Glucose Ether)佔該組合物2之0.1重量%至5.0重量%,最佳重量%為1.0重量%至3.0重量%。
於混合攪拌的過程中,可以有多種方式對前述四種成分進行混合,舉例來說,可先挑選其中的兩種消臭成分(如:甲基巴豆酸香茅酯20及縮合單寧21,或甲基巴豆酸香茅酯20及醛類化合物22,或縮合單寧21及醛類化合物22)進行混合,混合攪拌一段時間後,接著加入剩餘的一種消臭成分,最後再將定香成分PPG-10甲基葡糖醚23加入混合好的消臭成分中,即形成該組合物2。
在另一實施例中,另一種混合的方式為,將前述三種消臭成分(甲基巴豆酸香茅酯20、縮合單寧21及醛類化合物22)同時進行混合,混合攪拌一段時間後,再將定香成分PPG-10甲基葡糖醚23加入混合好的消臭成分中,也可形成本發明之組合物2。
換句話說,本發明之組合物2其混合的方式並沒有特別限定各成分混合的先後順序,不論成分的添加順序為何,最終產物皆為本發明組合物2,合先敘明。
因此透過本發明的設計,前述之組合物2可應用於各種產業,舉例來說,可應用於化妝保養品產業、洗滌產品產業、生活用品產業、農畜相關產業、工業相關產業、環境工程相關產業等,應用範圍非常廣泛,並且可根據使用者的需求將該組合物2加於一待添加物3內,該待添加物3可以是前述各產業中使用的各種產品,如女性使用的化妝品(如:體香膏(如第2圖所示)、香水等)或保養品,或居家生活中常用的清潔用(如:沐浴乳(如第3圖所示)、洗髮精、廚房/浴室洗淨劑(如第4圖所示)、鞋內除臭劑等),或是寵物的洗滌產品(如:寵物洗毛精(如第5圖所示))、消臭噴霧,甚至是農畜業使用的除臭產品(如:生物除臭劑、植物除臭劑、圈舍除臭劑、禽畜養殖除臭劑等),或工業用除臭產品(如:汙水除臭劑等(如第6圖所示)),換句話說,該組合物2可針對每一位使用者以及各產業各種不同的需求將該組合物2加至呈固態、液態或氣態的待添加物3內,如此一來,透過添加本發明之組合物2可增強添加物針對異常惡臭除臭之效果、延緩氣味衰減的速度,並且可改善傳統待添加物3的香味保留時間僅約2~3天,大幅拉長待添加物3原本的香味保留時間約5~7天。
以上所述,本發明相較於習知具有下列優點:
1.大幅提升臭味消除之效果;
2.大幅延長香味保留之時間。
以上已將本發明做一詳細說明,惟以上所述者,僅為本發明之一較佳實施例而已,當不能限定本發明實施之範圍,即凡依本發明申請範圍所作之均等變化與修飾等,皆應仍屬本發明之專利涵蓋範圍。
The above-mentioned objects and structural and functional characteristics of the present invention will be described based on the preferred embodiments of the accompanying drawings. Unless otherwise specified, all amounts provided in weight percentages are based on the entire composition and are stated first. Please refer to Figure 1, which is a schematic diagram of the composition with deodorizing and leaving fragrance of the present invention. As shown in the figure, a composition with deodorizing and leaving
2:組合物 20:甲基巴豆酸香茅酯 21:縮合單寧 22:醛類化合物 23:PPG-10甲基葡糖醚 3:待添加物2: composition 20: Citronellyl methyl crotonate 21: Condensed tannins 22: Aldehydes 23: PPG-10 Methyl Glucose Ether 3: To be added
第1圖係為本發明具除臭留香之組合物之示意圖; 第2圖係為本發明具除臭留香之組合物第一實施例之實施示意圖; 第3圖係為本發明具除臭留香之組合物第二實施例之實施示意圖; 第4圖係為本發明具除臭留香之組合物第三實施例之實施示意圖; 第5圖係為本發明具除臭留香之組合物第四實施例之實施示意圖; 第6圖係為本發明具除臭留香之組合物第五實施例之實施示意圖。 Figure 1 is a schematic diagram of the deodorant and fragrance-retaining composition of the present invention; Figure 2 is a schematic diagram of the implementation of the first embodiment of the composition with deodorization and fragrance retention of the present invention; Figure 3 is a schematic diagram of the implementation of the second embodiment of the composition with deodorization and fragrance retention of the present invention; Figure 4 is a schematic diagram of the implementation of the third embodiment of the composition with deodorization and fragrance retention of the present invention; Figure 5 is a schematic diagram of the fourth embodiment of the composition with deodorant and fragrance retention of the present invention; Figure 6 is a schematic diagram of the fifth embodiment of the composition with deodorant and fragrance retention of the present invention.
2:組合物 2: composition
20:甲基巴豆酸香茅酯 20: Citronellyl methyl crotonate
21:縮合單寧 21: Condensed tannins
22:醛類化合物 22: Aldehydes
23:PPG-10甲基葡糖醚 23: PPG-10 Methyl Glucose Ether
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WO2012064557A2 (en) * | 2010-11-08 | 2012-05-18 | Lipo Chemicals Inc. | Deodorizing compositions |
WO2016143663A1 (en) * | 2015-03-10 | 2016-09-15 | 日清オイリオグループ株式会社 | Water-based cosmetic |
EP3398585A1 (en) * | 2012-12-27 | 2018-11-07 | Hayashibara Co., Ltd. | External dermal composition for anti-ageing and method for producing the same |
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WO2012064557A2 (en) * | 2010-11-08 | 2012-05-18 | Lipo Chemicals Inc. | Deodorizing compositions |
EP3398585A1 (en) * | 2012-12-27 | 2018-11-07 | Hayashibara Co., Ltd. | External dermal composition for anti-ageing and method for producing the same |
WO2016143663A1 (en) * | 2015-03-10 | 2016-09-15 | 日清オイリオグループ株式会社 | Water-based cosmetic |
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