TWI712080B - Semiconductor structure and the manufacturing method of the same - Google Patents
Semiconductor structure and the manufacturing method of the same Download PDFInfo
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Abstract
Description
本揭露實施例是有關於一種半導體結構的製造方法,且特別是有關於一種利用導電層作為遮罩以進行圖案化製程的半導體結構的製造方法。The embodiment of the disclosure relates to a manufacturing method of a semiconductor structure, and more particularly to a manufacturing method of a semiconductor structure using a conductive layer as a mask for a patterning process.
懸臂(cantilever)結構常用於需要隔絕的裝置中,例如像是質量感測器、熱感測器、聲紋感測器等的感測裝置中。在此類型的裝置中,懸臂結構常作為支撐層或支撐膜(supporting film),使其可作為一懸浮(floating)結構的支撐。The cantilever structure is often used in devices that require isolation, such as sensing devices such as mass sensors, thermal sensors, and voiceprint sensors. In this type of device, the cantilever structure is often used as a supporting layer or a supporting film, so that it can be used as a support for a floating structure.
若支撐層或支撐膜被過度拉伸或壓縮,將使感測裝置無法正常運作。因此,支撐層或支撐膜的厚度、將支撐層或支撐膜圖案化所形成的孔徑的尺寸等,是影響感測裝置之性能的關鍵因素。If the support layer or the support film is excessively stretched or compressed, the sensing device will not operate normally. Therefore, the thickness of the support layer or the support film, the size of the aperture formed by patterning the support layer or the support film, etc., are key factors that affect the performance of the sensing device.
現行用於形成感測裝置的半導體結構雖大致符合需求,但並非在各方面皆令人滿意。Although current semiconductor structures used to form sensing devices generally meet the requirements, they are not satisfactory in every respect.
本揭露實施例是有關於一種利用導電層作為遮罩以進行圖案化製程的半導體結構的製造方法。透過本揭露實施例的製造方法,可精確地調整支撐層的厚度,進一步縮小將支撐層圖案化所形成之孔徑的尺寸。透過本揭露實施例的製造方法,可降低製程複雜程度,進而減少製程的時間與成本。The embodiment of the disclosure relates to a manufacturing method of a semiconductor structure using a conductive layer as a mask to perform a patterning process. Through the manufacturing method of the disclosed embodiment, the thickness of the support layer can be precisely adjusted, and the size of the aperture formed by patterning the support layer can be further reduced. Through the manufacturing method of the disclosed embodiment, the complexity of the manufacturing process can be reduced, thereby reducing the time and cost of the manufacturing process.
本揭露實施例包含一種半導體結構的製造方法。此製造方法包含提供一基板。基板區分為一操作區與一感測區。此製造方法也包含在操作區形成一半導體元件並在感測區形成一感測元件。此製造方法更包含形成一介電層於基板上。此製造方法也包含形成一接點於介電層上。接點電性連接於半導體元件。此製造方法更包含形成一支撐層於接點與介電層上。此製造方法包含形成至少一導電層於支撐層上。導電層包括一第一部分與一第二部分,第一部分電性連接於半導體元件,第二部分具有至少一通孔並設置於感測元件上。此製造方法也包含透過至少一通孔將支撐層、介電層與感測元件圖案化,以形成一蝕刻溝槽。此製造方法更包含將第二部分移除。The disclosed embodiments include a method for manufacturing a semiconductor structure. The manufacturing method includes providing a substrate. The substrate is divided into an operation area and a sensing area. The manufacturing method also includes forming a semiconductor element in the operation area and forming a sensing element in the sensing area. The manufacturing method further includes forming a dielectric layer on the substrate. The manufacturing method also includes forming a contact on the dielectric layer. The contact is electrically connected to the semiconductor element. The manufacturing method further includes forming a support layer on the contact and the dielectric layer. The manufacturing method includes forming at least one conductive layer on the support layer. The conductive layer includes a first part and a second part. The first part is electrically connected to the semiconductor element, and the second part has at least one through hole and is disposed on the sensing element. The manufacturing method also includes patterning the support layer, the dielectric layer and the sensing element through at least one through hole to form an etching trench. This manufacturing method further includes removing the second part.
本揭露實施例包含一種半導體結構。半導體結構包含一基板,基板可具有一操作區與一感測區。半導體結構包含一半導體元件,半導體元件設置於操作區。半導體結構包含一感測元件,感測元件設置於感測區。半導體結構包含一介電層,介電層設置於基板上。半導體結構包含一接點,接點設置於介電層上並電性連接於半導體元件。半導體結構包含一支撐層,支撐層設置於接點與介電層上。半導體結構包含至少一導電層,導電層設置於支撐層上。導電層包含一虛擬部分,虛擬部分位於感測區並設置於感測元件上。The disclosed embodiment includes a semiconductor structure. The semiconductor structure includes a substrate, and the substrate may have an operation area and a sensing area. The semiconductor structure includes a semiconductor element, and the semiconductor element is disposed in the operation area. The semiconductor structure includes a sensing element, and the sensing element is disposed in the sensing area. The semiconductor structure includes a dielectric layer, which is disposed on the substrate. The semiconductor structure includes a contact, which is arranged on the dielectric layer and electrically connected to the semiconductor element. The semiconductor structure includes a support layer disposed on the contact and the dielectric layer. The semiconductor structure includes at least one conductive layer, and the conductive layer is disposed on the support layer. The conductive layer includes a dummy part, which is located in the sensing area and disposed on the sensing element.
以下的揭露內容提供許多不同的實施例或範例以實施本案的不同特徵。以下的揭露內容敘述各個構件及其排列方式的特定範例,以簡化說明。當然,這些特定的範例並非用以限定。例如,若是本揭露實施例敘述了一第一特徵部件形成於一第二特徵部件之上或上方,即表示其可能包含上述第一特徵部件與上述第二特徵部件是直接接觸的實施例,亦可能包含了有附加特徵部件形成於上述第一特徵部件與上述第二特徵部件之間,而使上述第一特徵部件與第二特徵部件可能未直接接觸的實施例。The following disclosure provides many different embodiments or examples to implement different features of this case. The following disclosure describes specific examples of each component and its arrangement to simplify the description. Of course, these specific examples are not meant to be limiting. For example, if the embodiment of the present disclosure describes that a first characteristic component is formed on or above a second characteristic component, it means that it may include an embodiment in which the first characteristic component and the second characteristic component are in direct contact. It may include an embodiment in which an additional characteristic part is formed between the first characteristic part and the second characteristic part, and the first characteristic part and the second characteristic part may not be in direct contact.
應理解的是,額外的操作步驟可實施於所述方法之前、之間或之後,且在所述方法的其他實施例中,部分的操作步驟可被取代或省略。It should be understood that additional operation steps may be implemented before, during or after the method, and in other embodiments of the method, part of the operation steps may be replaced or omitted.
此外,其中可能用到與空間相關用詞,例如「在… 下方」、「下方」、「較低的」、「在… 上方」、「上方」、「較高的」及類似的用詞,這些空間相關用詞係為了便於描述圖示中一個(些)元件或特徵部件與另一個(些)元件或特徵部件之間的關係,這些空間相關用詞包括使用中或操作中的裝置之不同方位,以及圖式中所描述的方位。當裝置被轉向不同方位時(旋轉90度或其他方位),則其中所使用的空間相關形容詞也將依轉向後的方位來解釋。In addition, terms related to space may be used, such as "below", "below", "lower", "above", "above", "higher" and similar terms. These space-related terms are used to facilitate the description of the relationship between one element(s) or characteristic part and another (some) elements or characteristic parts in the illustration. These space-related terms include the difference between devices in use or operation. Position, and the position described in the diagram. When the device is turned in different directions (rotated by 90 degrees or other directions), the space-related adjectives used therein will also be interpreted according to the turned position.
在說明書中,「約」、「大約」、「大抵」之用語通常表示在一給定值或範圍的20%之內,或10%之內,或5%之內,或3%之內,或2%之內,或1%之內,或0.5%之內。在此給定的數量為大約的數量,亦即在沒有特定說明「約」、「大約」、「大抵」的情況下,仍可隱含「約」、「大約」、「大抵」之含義。In the manual, the terms "about", "approximately" and "approximately" usually mean within 20%, or within 10%, or within 5%, or within 3% of a given value or range. Or within 2%, or within 1%, or within 0.5%. The quantity given here is an approximate quantity, that is, the meaning of "about", "approximately" and "approximately" can still be implied without specifying "about", "approximately" or "approximately".
除非另外定義,在此使用的全部用語(包括技術及科學用語)具有與此篇揭露所屬之一般技藝者所通常理解的相同涵義。能理解的是,這些用語,例如在通常使用的字典中定義的用語,應被解讀成具有與相關技術及本揭露的背景或上下文一致的意思,而不應以一理想化或過度正式的方式解讀,除非在本揭露實施例有特別定義。Unless otherwise defined, all terms (including technical and scientific terms) used herein have the same meanings commonly understood by the general artisans to whom the disclosure belongs. It is understandable that these terms, such as those defined in commonly used dictionaries, should be interpreted as having meaning consistent with the relevant technology and the background or context of this disclosure, and should not be used in an idealized or overly formal way. Interpretation, unless there is a special definition in the embodiment of the present disclosure.
以下所揭露之不同實施例可能重複使用相同的參考符號及/或標記。這些重複係為了簡化與清晰的目的,並非用以限定所討論的不同實施例及/或結構之間有特定的關係。The different embodiments disclosed below may use the same reference symbols and/or marks repeatedly. These repetitions are for the purpose of simplification and clarity, and are not used to limit the specific relationship between the different embodiments and/or structures discussed.
在本揭露實施例中,由於將導電層與介電層移除所使用的方式不同(例如,使用不同的蝕刻液體進行蝕刻),可產生較高的選擇性(selectivity),使得透過導電層作為遮罩以進行圖案化製程可精確地調整支撐層的厚度,進一步縮小將支撐層圖案化所形成之孔徑的尺寸。此外,透過本揭露實施例的製造方法,可減少圖案化光阻的使用次數,降低製程複雜程度,進而減少製程時間與成本。In the embodiment of the present disclosure, since the method used to remove the conductive layer and the dielectric layer is different (for example, using different etching liquids for etching), a higher selectivity can be generated, so that the conductive layer serves as The mask is used for the patterning process to accurately adjust the thickness of the support layer, and further reduce the size of the aperture formed by patterning the support layer. In addition, through the manufacturing method of the embodiment of the disclosure, the number of uses of the patterned photoresist can be reduced, the complexity of the manufacturing process is reduced, and the manufacturing process time and cost can be reduced.
第1圖至第8圖是根據本揭露的一些實施例,說明形成第8圖所示之半導體結構100在各個不同製程階段的部分示意圖。應注意的是,為了便於顯示本揭露實施例的特徵,第1圖至第8圖是以剖面的方式繪示半導體結構100,但其不代表半導體結構100之特定位置之剖面。此外,第1圖至第8圖中也可能省略部分元件。FIG. 1 to FIG. 8 are partial schematic diagrams illustrating the formation of the
參照第1圖,提供一基板10。在一些實施例中,基板10可包括元素半導體,例如:矽或鍺;化合物半導體,例如,碳化矽、氮化鎵、砷化鎵、磷化鎵、磷化銦、砷化銦、銻化銦等;合金半導體,例如:矽鍺(silicon germanium)、砷磷化鎵(gallium arsenide phosphide)、磷化鋁銦(aluminum indium phosphide)、砷化鋁鎵(aluminum gallium arsenide)、砷化鎵銦(gallium indium arsenide)、磷化鎵銦(gallium indium phosphide)、砷磷化鎵銦(gallium indium arsenide phosphide)等或前述之組合,但本揭露實施例並非以此為限。在一些實施例中,基板10可為絕緣層上半導體(semiconductor-on-insulator (SOI))基板。前述絕緣層上半導體基板可包括底板、設置於前述底板上的埋藏氧化層以及設置於前述埋藏氧化層上的半導體層。在一些實施例中,基板10可為一半導體晶圓(例如,矽晶圓或其他適當之半導體晶圓)。Referring to Figure 1, a
在一些實施例中,基板10可包括各種以如離子佈植及/或擴散製程所形成之p型摻雜區及/或n型摻雜區。舉例而言,前述摻雜區可被配置來形成電晶體、光電二極體及/或發光二極體,但本揭露實施例並非以此為限。In some embodiments, the
在一些實施例中,基板10可包括各種隔離特徵,以分隔基板10中不同之裝置區域。舉例而言,隔離特徵可包括淺溝槽隔離(shallow trench isolation, STI)特徵,但本揭露實施例並非以此為限。在一些實施例中,形成淺溝槽隔離之步驟可包括於基板10中蝕刻出一溝槽,並於上述溝槽中填入絕緣材料(例如,氧化矽、氮化矽、或氮氧化矽)。所填充的溝槽可具有多層結構(例如,一熱氧化襯層以及填充於溝槽之氮化矽)。可進行化學機械研磨(chemical mechanical polishing, CMP)製程以研磨多餘的絕緣材料並平坦化隔離特徵之上表面。In some embodiments, the
在一些實施例中,基板10可包括各種導電特徵(例如,導線(conductive line)或導孔(via))。舉例而言,前述導電特徵可由鋁(Al)、銅(Cu)、鎢(W)、其各自之合金、其他適當之導電材料或上述之組合所形成。In some embodiments, the
舉例來說,基板10可例如為一P型(P-type)基板,且如第1圖所示,基板10被區分為一操作區10C與一感測區10S,但本揭露實施例並非以此為限。接著,在操作區10C形成一半導體元件20,並在感測區10S形成一感測元件30。For example, the
如第1圖所示,在一些實施例中,半導體元件20例如為一金氧半場效電晶體(Metal-Oxide-Semiconductor Field-Effect Transistor, MOSFET),其可包括一井區21,例如為P型井區,其可包括如硼、鋁、鎵、銦、鉈之摻雜質,但本揭露實施例並非以此為限。在一些實施例中,可例如透過離子佈植形成佈植區,並對佈植區進行熱製程(例如,退火製程)以形成前述井區21,但本揭露實施例並非以此為限。As shown in Figure 1, in some embodiments, the
在一些實施例中,半導體元件20也包括重摻雜區23及重摻雜區25,重摻雜區23及重摻雜區25例如為N型摻雜區,其可包括氮、磷、砷、銻、鉍之摻雜質,但本揭露實施例並非以此為限。類似地,在一些實施例中,可例如透過離子佈植形成佈植區,並對佈植區進行熱製程(例如,退火製程)以形成前述重摻雜區23及重摻雜區25,但本揭露實施例並非以此為限。在一些實施例中,重摻雜區23及重摻雜區25的平均摻雜濃度,皆大於井區21的平均摻雜濃度。在一些實施例中,重摻雜區23及重摻雜區25可例如為半導體元件20的源極/汲極區。In some embodiments, the
在一些實施例中,半導體元件20更包括一閘極結構27,閘極結構27可設置於重摻雜區23與重摻雜區25之間,並位於井區21之上,但本揭露實施例並非以此為限。在一些實施例中,閘極結構27可包括閘極介電層以及設置於閘極介電層上的閘極電極。在一些實施例中,可先依序毯覆性(blanket)沉積一介電材料層及位於其上之導電材料層於基板10上,再將此介電材料層及導電材料層經微影與蝕刻製程圖案化,以分別形成閘極介電層以及閘極電極。In some embodiments, the
舉例而言,前述介電材料層可包括氧化矽、氮化矽、氮氧化矽、高介電常數(high-κ)介電材料、其他任何適合之介電材料或上述之組合,但本揭露實施例並非以此為限。在一些實施例中,前述高介電常數介電材料可包括LaO、AlO、ZrO、TiO、Ta 2O 5、Y 2O 3、SrTiO 3(STO)、BaTiO 3(BTO)、BaZrO、HfO 2、HfO 3、HfZrO、HfLaO、HfSiO、HfSiON、LaSiO、AlSiO、HfTaO、HfTiO、HfTaTiO、HfAlON、(Ba,Sr)TiO 3(BST)、Al 2O 3、其他合適之高介電常數介電材料或其組合。 For example, the aforementioned dielectric material layer may include silicon oxide, silicon nitride, silicon oxynitride, high-k dielectric material, any other suitable dielectric material, or a combination of the above, but the present disclosure The embodiment is not limited to this. In some embodiments, the aforementioned high-k dielectric material may include LaO, AlO, ZrO, TiO, Ta 2 O 5 , Y 2 O 3 , SrTiO 3 (STO), BaTiO 3 (BTO), BaZrO, HfO 2 , HfO 3 , HfZrO, HfLaO, HfSiO, HfSiON, LaSiO, AlSiO, HfTaO, HfTiO, HfTaTiO, HfAlON, (Ba,Sr)TiO 3 (BST), Al 2 O 3 , other suitable high-k dielectric materials Or a combination.
在一些實施例中,介電材料層可藉由化學氣相沉積法(chemical vapor deposition, CVD)、原子層沉積法(atomic layer deposition, ALD)或旋轉塗佈法所形成,但本揭露實施例並非以此為限。舉例而言,前述化學氣相沉積法可為低壓化學氣相沉積法(low pressure chemical vapor deposition, LPCVD)、低溫化學氣相沉積法(low temperature chemical vapor deposition, LTCVD)、快速升溫化學氣相沉積法(rapid thermal chemical vapor deposition, RTCVD)或電漿輔助化學氣相沉積法(plasma enhanced chemical vapor deposition, PECVD)。In some embodiments, the dielectric material layer may be formed by chemical vapor deposition (CVD), atomic layer deposition (ALD), or spin coating, but the disclosed embodiments Not limited to this. For example, the aforementioned chemical vapor deposition method may be low pressure chemical vapor deposition (LPCVD), low temperature chemical vapor deposition (LTCVD), and rapid temperature chemical vapor deposition. Method (rapid thermal chemical vapor deposition, RTCVD) or plasma enhanced chemical vapor deposition (PECVD).
在一些實施例中,前述導電材料層可由多晶矽所形成,但本揭露實施例並非以此為限。在一些實施例中,前述導電材料層可由金屬(例如,鎢、鈦、鋁、銅、鉬、鎳、鉑、類似的金屬材料或前述之組合)、金屬合金、金屬氮化物(例如,氮化鎢、氮化鉬、氮化鈦、氮化鉭、類似的金屬氮化物或前述之組合)、金屬矽化物(例如,矽化鎢、矽化鈦、矽化鈷、矽化鎳、矽化鉑、矽化鉺、類似的金屬矽化物或前述之組合)、金屬氧化物(例如,氧化釕、氧化銦錫、類似的金屬氧化物或前述之組合)、其他適當的導電材料或前述之組合所形成。In some embodiments, the aforementioned conductive material layer may be formed of polysilicon, but the embodiment of the disclosure is not limited thereto. In some embodiments, the aforementioned conductive material layer may be made of metal (for example, tungsten, titanium, aluminum, copper, molybdenum, nickel, platinum, similar metal materials or a combination of the foregoing), metal alloys, metal nitrides (for example, nitride Tungsten, molybdenum nitride, titanium nitride, tantalum nitride, similar metal nitrides or combinations of the foregoing), metal silicides (for example, tungsten silicide, titanium silicide, cobalt silicide, nickel silicide, platinum silicide, erbium silicide, similar Or a combination of the foregoing), a metal oxide (for example, ruthenium oxide, indium tin oxide, similar metal oxides or a combination of the foregoing), other suitable conductive materials, or a combination of the foregoing.
在一些實施例中,導電材料層可藉由化學氣相沉積製程、物理氣相沉積製程(例如:真空蒸鍍製程(vacuum evaporation process)或濺鍍製程(sputtering process))、其他適當的製程或前述之組合所形成,但本揭露實施例並非以此為限。In some embodiments, the conductive material layer may be formed by a chemical vapor deposition process, a physical vapor deposition process (for example, a vacuum evaporation process or a sputtering process), other appropriate processes or The aforementioned combination is formed, but the embodiment of the disclosure is not limited thereto.
在一些實施例中,半導體元件20包括一隔絕結構29,隔絕結構29可設置於重摻雜區23與重摻雜區25的外側,但本揭露實施例並非以此為限。在一些實施例中,隔絕結構29的材料可包含介電材料,例如氧化矽(SiO
2)、氮化矽(SiN)、氮氧化矽(SiON)、氧化鋁(Al
2O
3)、氮化鋁(AlN)、氧化鎂(MgO)、氮化鎂(Mg
3N
2)、氧化鋅(ZnO)、氧化鈦(TiO
2)、其他合適的材料或前述之組合,但本揭露實施例並非以此為限。
In some embodiments, the
在一些實施例中,可透過沉積製程、光微影製程、其他適當之製程或前述之組合形成隔絕結構29,但本揭露實施例並非以此為限。舉例來說,光微影製程可包含光阻塗佈(例如,旋轉塗佈(spin-on coating))、軟烘烤(soft baking)、光罩對準(mask aligning)、曝光(exposure)、曝光後烘烤(post-exposure baking, PEB)、顯影(developing)、清洗(rinsing)、乾燥(例如硬烘烤)、其他合適的製程或前述之組合,但本揭露實施例並非以此為限。In some embodiments, the
如第1圖所示,在一些實施例中,感測元件30例如為一熱感測元件。舉例來說,感測元件30可包括一半導體層33、一氧化層31及一熱電堆(Thermopile)35、37。As shown in FIG. 1, in some embodiments, the
在一些實施例中,半導體層33的材料可例如為多晶矽,但本揭露實施例並非以此為限。在一些實施例中,氧化層31的材料可包含氧化矽(SiO
2)、其他合適的材料或其組合,但本揭露實施例並非以此為限。具體而言,如第1圖所示,氧化層31可分為一第一氧化層311及一第二氧化層313。第一氧化層311可圍繞半導體層33,而第二氧化層313可設置於半導體層33的頂表面,但本揭露實施例並非以此為限。
In some embodiments, the material of the
在一些實施例中,熱電堆35、37可設置於氧化層31上。更具體而言,熱電堆35、37可設置於第二氧化層313上。在一些實施例中,熱電堆35、37的材料可分別包含P型重摻雜多晶矽與N型重摻雜多晶矽,P型重摻雜多晶矽可包括如硼、鋁、鎵、銦、鉈之摻雜質,而N型重摻雜多晶矽可包括氮、磷、砷、銻、鉍之摻雜質,但本揭露實施例並非以此為限。In some embodiments, the
如第1圖所示,在本實施例中,熱電堆35可具有通孔35T,熱電堆37可具有通孔37T,通孔35T、37T可裸露氧化層31(第二氧化層313)的部分頂表面。要注意的是,雖然在第1圖所示的實施例中,熱電堆35具有兩個通孔35T,熱電堆37具有兩個通孔37T,但本揭露實施例並非以此為限。As shown in Figure 1, in this embodiment, the
參照第2圖,形成一介電層41於基板10上。具體而言,介電層41可形成於半導體元件20(重摻雜區23、重摻雜區25、閘極結構27、隔絕結構29)與感測元件30(氧化層31、半導體層33、熱電堆35、37)上,並填充於通孔35T、37T中,但本揭露實施例並非以此為限。Referring to FIG. 2, a
在一些實施例中,介電層41的材料可包括四乙氧基矽烷(tetraethylorthosilicate, TEOS)的氧化物、非摻雜的矽玻璃(un-doped silicate glass)(例如硼磷矽玻璃(boron phosphate silicate glass, BPSG))、摻氟的矽玻璃(fluorinated silicate glass, FSG)、磷矽玻璃(phosphosilicate glass, PSG)、硼矽玻璃(borosilicate glass, BSG)等的摻雜的二氧化矽(doped silicon oxide)及/或其他適當的介電材料,但本揭露實施例並非以此為限。In some embodiments, the material of the
在一些實施例中,介電層41可藉由電漿輔助化學氣相沉積法(PECVD)、可流動化學氣相沉積法(flowable chemical vapor deposition, FCVD)或其他適當的方法所形成,但本揭露實施例並非以此為限。In some embodiments, the
接著,形成一接點45於介電層41上。在本實施例中,接點45可電性連接於半導體元件20。舉例來說,如第2圖所示,接點45位於基板10的操作區10C,其可透過導電插塞43電性連接於重摻雜區23與重摻雜區25,但本揭露實施例並非以此為限。Next, a
在一些實施例中,導電插塞43與接點45的材料可包含多晶矽及/或金屬。舉例來說,金屬可包括氮化鈦鋁(TiAlN)、氮化鈦(TiN)、氮化鉭(TaN)、釕(Ru)、鉬(Mo)、鎢(W)、鉑(Pt)、鈦(Ti)、鋁(Al)、鈷(Co) 、碳化鉭(TaC)、氮化碳化鉭(TaCN)、氮化鉭矽(TaSiN)、氮化鈦鋁(TiAlN)、氮化鈦矽(TiSiN)、其他合適的材料或前述之組合,但本揭露實施例並非以此為限。In some embodiments, the material of the
在一些實施例中,導電插塞43與接點45可透過化學氣相沉積、物理氣相沉積、鍍膜法(plating)及/或其他適當的製程所形成,但本揭露實施例並非以此為限。在一些實施例中,接點45可進一步透過光微影製程所形成,但本揭露實施例並非以此為限。光微影製程之例子如前所述,在此不多加贅述。In some embodiments, the
如第2圖所示,在一些實施例中,介電層41可包括孔洞47,孔洞47可裸露部分感測元件30,但不會裸露感測元件30對應於通孔35T、37T的部分。具體而言,孔洞47可裸露部分熱電堆35、37,但本揭露實施例並非以此為限。As shown in FIG. 2, in some embodiments, the
參照第3圖,形成一支撐層48於接點45與介電層41上。支撐層48的材料以及形成方法可與介電層41相同或類似,在此不多加贅述,但本揭露實施例並非以此為限。此外,如第3圖所示,支撐層48可填充介電層41之孔洞47,因此,支撐層48可作為感測元件30於後續製程中形成懸浮結構的支撐。Referring to FIG. 3, a
接著,形成一導電層於支撐層48上。如第3圖所示,在本實施例中,導電層可包括一第一部分51C與一第二部分51S,第一部分51C電性連接於半導體元件20,而第二部分51S具有複數通孔51T並設置於感測元件30上。具體而言,導電層的第一部分51C位於基板10的操作區10C,其可透過導電插塞49電性連接於接點45,但本揭露實施例並非以此為限。Then, a conductive layer is formed on the supporting
在一些實施例中,導電層的第二部分51S為一圖案化的導電層,其具有複數通孔51T且每個通孔51T之截面的最大寬度至少小於或等於0.5 μm,但本揭露實施例並非以此為限。具體而言,導電層的第二部分51S位於基板10的感測區10S,其對應設置於感測元件30上。此外,如第3圖所示,通孔51T可對應於熱電堆35的通孔35T與熱電堆37的通孔37T設置。導電層的第二部分51S可作為後續製程中的圖案化遮罩(mask),後方將詳細描述。In some embodiments, the
此外,在一些實施例中,導電層的第一部分51C與第二部分51S的材料以及形成方法可與導電插塞43與接點45相同或類似,在此不多加贅述,但本揭露實施例並非以此為限。In addition, in some embodiments, the materials and forming methods of the
參照第4圖,形成一層間介電層53於導電層(的第一部分51C與第二部分51S)與支撐層48上。層間介電層53的材料以及形成方法可與介電層41相同或類似,在此不多加贅述,但本揭露實施例並非以此為限。接著,形成一導電層57於層間介電層53上。導電層57的材料以及形成方法可與導電插塞43與接點45相同或類似,在此不多加贅述,但本揭露實施例並非以此為限。此外,導電層57可透過導電插塞55電性連接於導電層的第一部分51C,但本揭露實施例並非以此為限。Referring to FIG. 4, an
參照第5圖,形成一層間介電層59於導電層57與層間介電層53上。層間介電層59的材料以及形成方法可與介電層41相同或類似,在此不多加贅述,但本揭露實施例並非以此為限。如第5圖所示,在一些實施例中,層間介電層59可包括孔洞59T,孔洞59T可裸露部分導電層57,但本揭露實施例並非以此為限。Referring to FIG. 5, an
應注意的是,半導體結構100的介電層(含層間介電層)與導電層(含接點)的數量並未限定於第5圖所示。亦即,半導體結構100可包含複數導電層與複數(層間)介電層,(層間)介電層可設置於複數導電層之間。可依實際需求調整介電層與導電層的數量,在此不多加贅述。It should be noted that the number of dielectric layers (including interlayer dielectric layers) and conductive layers (including contacts) of the
參照第6圖,形成一圖案化光阻層61於層間介電層59上。如第6圖所示,圖案化光阻層61可具有孔洞61T,孔洞61T位於感測區10S。更詳細而言,圖案化光阻層61的孔洞61T可對應於導電層的第二部分51S設置。在本實施例中,孔洞61T之截面的最大寬度W1小於導電層的第二部分51S的最大寬度W(標示於第3圖),但本揭露實施例並非以此為限。Referring to FIG. 6, a patterned
在一些實施例中,圖案化光阻層61可例如為正型光阻(positive photoresist)或負型光阻(negative photoresist)。在一些實施例中,圖案化光阻層61可為單層或多層結構,可透過例如沉積製程、光微影製程、其他適當之製程或前述之組合形成圖案化光阻層61,但本揭露實施例並非以此為限。In some embodiments, the patterned
參照第7圖,執行一蝕刻製程並透過圖案化光阻層61的孔洞61T對層間介電層59與層間介電層53進行蝕刻,以裸露出導電層的第二部分51S的頂表面51ST。在一些實施例中,蝕刻製程可包括乾蝕刻、溼蝕刻、反應性離子蝕刻(reactive ion etching, RIE)及/或其他適當的製程。舉例來說,乾蝕刻製程可使用含氟氣體(例如:CF
4、SF
6、CH
2F
2、CHF
3及/或C
2F
6)、其他適當的氣體及/或電漿、及/或上述之組合。舉例來說,溼蝕刻製程可包括在以下的溶液中進行蝕刻:稀釋的氫氟酸(diluted hydrofluoric acid, DHF)、包括氫氟酸(HF)、硝酸(HNO
3)及/或醋酸(CH
3COOH)的溶液或是其他適當的溼式蝕刻劑。然而,本揭露實施例並非以此為限。
Referring to FIG. 7, an etching process is performed and the
接著,執行一蝕刻製程並透過導電層的第二部分51S的通孔51T將支撐層48、介電層41圖案化(例如包含將填充於孔洞35T、37T中的介電層41移除),以形成一蝕刻溝槽63。在本實施例中,蝕刻溝槽63可例如連通至半導體層33。蝕刻製程的例子如前所述,在此不多加贅述,但本揭露實施例並非以此為限。Next, perform an etching process and pattern the
參照第8圖,將導電層的第二部分51S與圖案化光阻層61移除,以形成半導體結構100。在本實施例中,將導電層的第二部分51S移除可裸露部分支撐層48。在一些實施例中,可執行另一蝕刻製程以將導電層的第二部分51S移除。在一些實施例中,此另一蝕刻製程可包括乾蝕刻、溼蝕刻、反應性離子蝕刻及/或其他適當的製程。舉例來說,乾蝕刻製程可使用含氯氣體(例如,Cl
2、CHCl
3, CCl
4及/或BCl
3)、其他適當的氣體及/或電漿、及/或上述之組合。舉例來說,溼蝕刻製程可包括在含氯的溶液中進行蝕刻,但本揭露實施例並非以此為限。
Referring to FIG. 8, the
由於導電層的第二部分51S與支撐層48的材料不同,用於對導電層的第二部分51S進行蝕刻的液體或氣體不易對支撐層48進行蝕刻(即具有高度選擇性),因此,可精確地調整支撐層48的厚度T,降低支撐層48被過度拉伸或壓縮的可能性,使感測元件30可正常運作。在一些實施例中,可進一步對支撐層48進行蝕刻,但本揭露實施例並非以此為限。Since the material of the
如第8圖所示,在一些實施例中,透過圖案化光阻層61的孔洞61T對層間介電層59與層間介電層53進行蝕刻的最大寬度大致等於孔洞61T之截面的最大寬度W1。在此條件下,相較於一般不具有導電層的第二部分51S作為遮罩的半導體結構,由於本揭露實施例可透過圖案化的導電層(即第二部分51S)所形成的蝕刻溝槽63以將半導體層33移除,可使蝕刻溝槽63進一步縮小,舉例來說,蝕刻溝槽63之截面的最大寬度W2可縮小至小於或等於0.5 μm,以進一步提升感測元件30的隔絕效果。As shown in Figure 8, in some embodiments, the maximum width of the
最後,進行又一蝕刻製程,透過蝕刻溝槽63將感測元件30的半導體層33移除,以於原先半導體層33所佔據的區域形成一空腔39。舉例來說,可藉由將氣體通過蝕刻溝槽63以對半導體層33進行電漿蝕刻以形成空腔39,進而使感測元件30形成懸浮結構,但本揭露實施例並非以此為限。Finally, another etching process is performed to remove the
再者,透過本揭露實施例的製造方法,可減少圖案化光阻的使用次數(例如,在本實施例中僅使用一次圖案化光阻61,但本揭露實施例並非以此為限),可降低製程複雜程度,進而減少製程時間與成本。Furthermore, through the manufacturing method of the embodiment of the present disclosure, the number of uses of the patterned photoresist can be reduced (for example, the patterned
須注意的是,雖然前述實施例中是以導電層的第二部分51S與導電層的第一部分51C同時形成為例進行說明,但本揭露並非以此為限。在其他實施例中,導電層的第二部分51S也可與導電層57同時形成,可依據支撐層48的(預定)厚度T進行調整。It should be noted that although in the foregoing embodiments, the
在一些實施例中,由於圖案化光阻61之孔洞61T的截面的最大寬度W1小於導電層的第二部分51S的最大寬度W,在將導電層的第二部分51S移除時可能留下部分虛擬導電層51SD於層間介電層53上,但本揭露實施例並非以此為限。亦即,如第8圖所示,本揭露實施例之半導體結構100可包含一基板10,基板10可具有一操作區10C與一感測區10S。半導體結構100可包含一半導體元件20,半導體元件20設置於操作區10C。半導體結構100可包含一感測元件30,感測元件30設置於感測區10S。半導體結構100可包含一介電層41,介電層41設置於基板10上。半導體結構100可包含一接點45,接點45設置於介電層41上並電性連接於半導體元件20。半導體結構100可包含一支撐層48,支撐層48設置於接點45與介電層41上。半導體結構100可包含至少一導電層,此導電層設置於支撐層48上。此導電層包含一虛擬部分(未繪示),虛擬部分位於感測區10S並設置於感測元件30上。In some embodiments, since the maximum width W1 of the cross section of the
以上概述數個實施例的部件,以便在本揭露所屬技術領域中具有通常知識者可以更理解本揭露實施例的觀點。在本揭露所屬技術領域中具有通常知識者應該理解,他們能以本揭露實施例為基礎,設計或修改其他製程和結構以達到與在此介紹的實施例相同之目的及/或優勢。在本揭露所屬技術領域中具有通常知識者也應該理解到,此類等效的結構並無悖離本揭露的精神與範圍,且他們能在不違背本揭露之精神和範圍之下,做各式各樣的改變、取代和替換。因此,本揭露之保護範圍當視後附之申請專利範圍所界定者為準。另外,雖然本揭露已以數個較佳實施例揭露如上,然其並非用以限定本揭露。The components of the several embodiments are summarized above so that those with ordinary knowledge in the technical field of the present disclosure can better understand the viewpoints of the embodiments of the present disclosure. Those with ordinary knowledge in the technical field of the present disclosure should understand that they can design or modify other processes and structures based on the embodiments of the present disclosure to achieve the same purpose and/or advantages as the embodiments described herein. Those with ordinary knowledge in the technical field to which this disclosure belongs should also understand that such equivalent structures do not depart from the spirit and scope of this disclosure, and they can do everything without departing from the spirit and scope of this disclosure. Various changes, substitutions and replacements. Therefore, the protection scope of this disclosure shall be subject to the scope of the attached patent application. In addition, although the present disclosure has been disclosed in several preferred embodiments as described above, it is not intended to limit the present disclosure.
整份本說明書對特徵、優點或類似語言的引用並非意味可以利用本揭露實現的所有特徵和優點應該是或者在本揭露的任何單個實施例中。相對地,涉及特徵和優點的語言被理解為其意味著結合實施例描述的特定特徵、優點或特性包括在本揭露的至少一個實施例中。因而,在整份說明書中對特徵和優點以及類似語言的討論可以但不一定代表相同的實施例。Reference to features, advantages, or similar language throughout this specification does not mean that all the features and advantages that can be achieved with the present disclosure should be or be in any single embodiment of the present disclosure. In contrast, language related to features and advantages is understood as meaning that a particular feature, advantage, or characteristic described in conjunction with the embodiment is included in at least one embodiment of the present disclosure. Thus, the discussion of features and advantages and similar language throughout the specification may but does not necessarily represent the same embodiment.
再者,在一個或多個實施例中,可以任何合適的方式組合本揭露的所描述的特徵、優點和特性。根據本文的描述,相關領域的技術人員將意識到,可在沒有特定實施例的一個或多個特定特徵或優點的情況下實現本揭露。在其他情況下,在某些實施例中可辨識附加的特徵和優點,這些特徵和優點可能不存在於本揭露的所有實施例中。Furthermore, in one or more embodiments, the described features, advantages, and characteristics of the present disclosure may be combined in any suitable manner. Based on the description herein, those skilled in the relevant art will realize that the present disclosure can be implemented without one or more specific features or advantages of a specific embodiment. In other cases, additional features and advantages can be recognized in certain embodiments, and these features and advantages may not exist in all embodiments of the present disclosure.
100:半導體結構100: semiconductor structure
10:基板10: substrate
10C:操作區10C: Operating area
10S:感測區10S: Sensing area
20:半導體元件20: Semiconductor components
21:井區21: Well area
23、25:重摻雜區23, 25: heavily doped area
27:閘極結構27: Gate structure
29:隔絕結構29: isolation structure
30:感測元件30: sensing element
31:氧化層31: Oxide layer
311:第一氧化層311: first oxide layer
313:第二氧化層313: second oxide layer
33:半導體層33: Semiconductor layer
35、37:熱電堆35, 37: thermopile
35T、37T:通孔35T, 37T: through hole
39:空腔39: Cavity
41:介電層41: Dielectric layer
43:導電插塞43: conductive plug
45:接點45: Contact
47:孔洞47: Hole
48:支撐層48: support layer
49:導電插塞49: conductive plug
51C:導電層的第一部分51C: The first part of the conductive layer
51S:導電層的第二部分51S: The second part of the conductive layer
51SD:虛擬導電層51SD: Virtual conductive layer
51ST:頂表面51ST: Top surface
51T:通孔51T: Through hole
53:層間介電層53: Interlayer dielectric layer
55:導電插塞55: conductive plug
57:導電層57: conductive layer
59:層間介電層59: Interlayer dielectric layer
59T:孔洞59T: Hole
61:圖案化光阻層61: Patterned photoresist layer
61T:孔洞61T: Hole
63:蝕刻溝槽63: Etching groove
T:厚度T: thickness
W:寬度W: width
W1:寬度W1: width
W2:寬度W2: width
以下將配合所附圖式詳述本揭露實施例。應注意的是,各種特徵部件並未按照比例繪製且僅用以說明例示。事實上,元件的尺寸可能經放大或縮小,以清楚地表現出本揭露實施例的技術特徵。 第1圖至第8圖是根據本揭露的一些實施例,說明形成第8圖所示之半導體結構在各個不同製程階段的部分示意圖。 The embodiments of the present disclosure will be described in detail below in conjunction with the accompanying drawings. It should be noted that the various characteristic components are not drawn to scale and are only used for illustrative purposes. In fact, the size of the element may be enlarged or reduced to clearly show the technical features of the embodiment of the disclosure. FIG. 1 to FIG. 8 are partial schematic diagrams illustrating the formation of the semiconductor structure shown in FIG. 8 in different process stages according to some embodiments of the present disclosure.
100:半導體結構 100: semiconductor structure
10:基板 10: substrate
10C:操作區 10C: Operating area
10S:感測區 10S: Sensing area
20:半導體元件 20: Semiconductor components
21:井區 21: Well area
23、25:重摻雜區 23, 25: heavily doped area
27:閘極結構 27: Gate structure
29:隔絕結構 29: isolation structure
30:感測元件 30: sensing element
31:氧化層 31: Oxide layer
311:第一氧化層 311: first oxide layer
313:第二氧化層 313: second oxide layer
33:半導體層 33: Semiconductor layer
35、37:熱電堆 35, 37: thermopile
41:介電層 41: Dielectric layer
43、49:導電插塞 43, 49: conductive plug
45:接點 45: Contact
48:支撐層 48: support layer
51C:第一部分 51C: Part One
51S:第二部分 51S: Part Two
51T:通孔 51T: Through hole
W:寬度 W: width
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