TWI706014B - An environmental friendly and waterproof hot melt adhesive film material and production method thereof - Google Patents
An environmental friendly and waterproof hot melt adhesive film material and production method thereof Download PDFInfo
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本發明涉及一種熱熔膠的膜片材及生產製程,尤其涉及一種環保防水的熱熔膠的膜片材生產製程。 The invention relates to a hot melt adhesive film sheet and a production process, in particular to an environment-friendly and waterproof hot melt adhesive film sheet production process.
防水工程對於建築相當重要,如果施工不得當或是防水材料品質不佳,建築就可能會因為下雨而產生漏水、滲水的現象,影響居住生活品質。目前常見的包含防水塗料、防水磚或是防水膜都是現代高新建築廣泛使用的防水材料,不僅僅用在一般住宅建築,更是常見在高檔別墅或是公共工程中。 Waterproofing works are very important to buildings. If the construction is improper or the quality of waterproof materials is poor, the building may leak or seep due to rain, which will affect the quality of living. At present, common waterproof coatings, waterproof bricks or waterproof membranes are widely used waterproof materials in modern high-tech buildings, not only in general residential buildings, but also in high-end villas or public projects.
所述的防水材料往往會添加有瀝青成分,因為瀝青具有優異的防水、隔熱與保溫等性質,且價格低廉又耐腐蝕,是許多建築工程的首選材料之一,但是這些好處的背後,卻藏著潛在環境污染問題,以及瀝青在生產製造過程中會帶給廠家與工人的環境與健康傷害。 Said waterproof materials are often added with bituminous components, because bitumen has excellent water-proof, heat-insulating and heat-preserving properties, and is low in price and corrosion resistant. It is one of the preferred materials for many construction projects. However, behind these benefits, There are potential environmental pollution problems, as well as the environmental and health damage that asphalt will bring to manufacturers and workers during the manufacturing process.
因此,為克服上述現有含瀝青成分的防水材料的不足而設計出一款環保的防水熱熔膠配方與其膜片材及生產製程,正是本發明所要解決的問題。 Therefore, in order to overcome the above-mentioned shortcomings of the existing asphalt-containing waterproof materials, designing an environmentally friendly waterproof hot-melt adhesive formula and its membrane and production process is the problem to be solved by the present invention.
針對現有含瀝青成分的防水材料可能會導致環境污染的問題,本發明的目的是提供一種環保防水的熱熔膠配方與其膜片材生產製程,配方中不 僅不含有瀝青成分,且防水耐候性能與既有的防水材料相當,安全環保,有非常好的實用與利用價值。 Aiming at the problem that existing waterproof materials containing bituminous ingredients may cause environmental pollution, the purpose of the present invention is to provide an environmentally-friendly and waterproof hot-melt adhesive formulation and its film production process. It only contains no asphalt, and its waterproof and weather resistance performance is equivalent to that of existing waterproof materials. It is safe and environmentally friendly, and has very good practical and use value.
本發明解決所述的技術問題所採用的首要技術方案包含:一種環保防水熱熔膠配方,原料包含:熱塑性彈性體10~40wt%;增黏樹脂20~60wt%;軟化油30wt%以下;以及填料10wt%以下。 The primary technical solution adopted by the present invention to solve the technical problems includes: an environmentally friendly waterproof hot-melt adhesive formula, the raw materials include: thermoplastic elastomer 10-40wt%; tackifying resin 20-60wt%; softening oil below 30wt%; and The filler is less than 10wt%.
進一步,該熱塑性彈性體包含合成橡膠、聚烯烴類膠體;以及增黏樹脂包含石油樹脂、松香樹脂或前述二者的衍生物。 Further, the thermoplastic elastomer includes synthetic rubber, polyolefin-based colloid; and the tackifying resin includes petroleum resin, rosin resin, or derivatives of the foregoing two.
進一步,該軟化油包含白蠟油、礦物油或丁基油;以及該填料包含無機填料,該無機填料包含碳酸鈣、染色劑、碳粉、輪胎粉或阻燃粉。 Further, the softening oil includes white wax oil, mineral oil or butyl oil; and the filler includes an inorganic filler, and the inorganic filler includes calcium carbonate, coloring agent, carbon powder, tire powder or flame retardant powder.
接著,本發明解決所述的技術問題所採用的首要技術方案包含:一種環保防水熱熔膠膜片材,其包含:依序層疊的一面材、一第一環保防水熱熔膠層、一纖維層以及一第二環保防水熱熔膠層,其中:該第一環保防水熱熔膠層與該第二環保防水熱熔膠層部分滲入或含浸在該纖維層的纖維間。 Next, the primary technical solution adopted by the present invention to solve the technical problem includes: an environmentally friendly waterproof hot-melt adhesive film sheet, which includes: a face material, a first environmentally-friendly waterproof hot-melt adhesive layer, and a fiber laminated in sequence Layer and a second environment-friendly waterproof hot-melt adhesive layer, wherein: the first environment-friendly waterproof hot-melt adhesive layer and the second environment-friendly waterproof hot-melt adhesive layer partially penetrate or impregnate between the fibers of the fiber layer.
進一步,該面料包含石質、砂質、塑膠、木質、金屬、發泡材料,或具有隔熱、阻火、抗噪或止滑的單一或複合面料; 進一步,該纖維層包含織布或是無紡布,以塑膠或玻璃或石墨纖維或金屬纖維所製成。 Further, the fabric includes stone, sand, plastic, wood, metal, foam material, or a single or composite fabric with heat insulation, fire resistance, noise resistance or anti-slip; Further, the fiber layer includes woven fabric or non-woven fabric, and is made of plastic or glass or graphite fiber or metal fiber.
最後,本發明解決所述技術問題所採用的最終技術方案包含:一種環保防水熱熔膠膜片材的生產製程,其步驟包含:步驟1:將一環保防水熱熔膠加熱攪拌均勻,使其呈現熔融流體狀態,其中:該環保防水熱熔膠包含熱塑性彈性體10~40wt%、增黏樹脂20~60wt%、軟化油30wt%以下;以及填料10wt%以下;步驟2:將該環保防水熱熔膠過濾後輸送至一含浸槽中; 步驟3:將一纖維層連續輸入該含浸槽中,並浸入熔融的該環保防水熱熔膠;以及步驟4:將含浸環保防水熱熔膠的該纖維層冷卻得到該環保防水熱熔膠膜片材。 Finally, the final technical solution adopted by the present invention to solve the technical problem includes: a production process of an environmentally friendly waterproof hot-melt adhesive film sheet, and the steps include: Step 1: Heating and stirring an environmentally-friendly waterproof hot-melt adhesive to make it Presents a molten fluid state, where: the environmentally friendly waterproof hot melt adhesive contains 10-40wt% of thermoplastic elastomer, 20-60wt% of tackifying resin, less than 30wt% of softening oil; and less than 10wt% of filler; step 2: the environmentally friendly waterproof heat The melted glue is filtered and transported to an impregnation tank; Step 3: Continuously input a fiber layer into the impregnation tank and immerse it in the molten environmental protection waterproof hot melt adhesive; and Step 4: Cool the fiber layer impregnated with environmental protection waterproof hot melt adhesive to obtain the environmental protection waterproof hot melt adhesive film material.
進一步,在步驟4所得到的該環保防水熱熔膠膜片材貼附一面材及/或一離型層,該面材與該離型層為同材質或異材質。 Further, the environmentally friendly waterproof hot melt adhesive film sheet obtained in step 4 is attached with a face material and/or a release layer, and the face material and the release layer are of the same material or different materials.
進一步,將所得到的該環保防水熱熔膠膜片材卷收並包裝入庫。 Further, the obtained environmentally-friendly waterproof hot-melt adhesive film sheet is rolled up and packaged into storage.
本發明上述所提供的技術方案可達到的有益效果如下: The beneficial effects that can be achieved by the technical solutions provided by the present invention are as follows:
1.本發明的環保防水熱熔膠配方原料中不含有瀝青成分,也不包含有機溶劑,具有環保的優點,且廠家在生產製造的過程中不會產生揮發性物質或是刺鼻難聞的氣味,對於廠家工人與環境相當友善。 1. The environment-friendly waterproof hot-melt adhesive formula of the present invention does not contain asphalt components or organic solvents, and has the advantages of environmental protection, and the manufacturer will not produce volatile substances or pungent or unpleasant smells during the manufacturing process. The smell is very friendly to the factory workers and the environment.
2.本發明所提供的防水熱熔膠膜片材不僅容易生產,利用廠家既有的含浸設備及可生產,不需要額外增添其他價格昂貴的設備或引進特殊的技術;且經測試本發明的防水熱熔膠膜片材具有優異的防水、耐候與自黏性質,容易加工施作,產品品質優異又價格合理,確實具有好的實用與經濟價值。 2. The waterproof hot-melt adhesive film sheet provided by the present invention is not only easy to produce, but also uses the manufacturer’s existing impregnation equipment and can be produced without the need to add other expensive equipment or introduce special technologies; and the test of the present invention The waterproof hot-melt adhesive film sheet has excellent waterproof, weather-resistant and self-adhesive properties, is easy to process, and has excellent product quality and reasonable price. It does have good practical and economic value.
10:環保防水熱熔膠膜片材 10: Environmental protection waterproof hot melt adhesive film sheet
11:面材 11: Surface material
13:第一環保防水熱熔膠層 13: The first environmental protection waterproof hot melt adhesive layer
15:纖維層 15: Fiber layer
17:第二環保防水熱熔膠層 17: The second environmentally friendly waterproof hot melt adhesive layer
19:離型層 19: Release layer
圖1為本發明環保防水熱熔膠膜片材示意圖。 Figure 1 is a schematic diagram of the environmentally friendly waterproof hot melt adhesive film sheet of the present invention.
圖2為本發明所述的環保防水熱熔膠膜片材之生產製造方法流程圖。 Figure 2 is a flow chart of the manufacturing method of the environmentally friendly waterproof hot-melt adhesive film sheet according to the present invention.
本發明是一種環保防水熱熔膠配方,原料包含如下:熱塑性彈性體10~40wt%; 增黏樹脂20~60wt%;軟化油30wt%以下;以及填料10wt%以下。 The present invention is an environmentally friendly waterproof hot-melt adhesive formula. The raw materials include the following: 10-40wt% of thermoplastic elastomer; Tackifying resin 20~60wt%; softening oil below 30wt%; and filler below 10wt%.
其中,本發明所述的配方原料中,熱塑性彈性體是主要提供防水與自黏著功能的材料,具體熱塑性彈性體可以是合成橡膠(SIS、SBS、SEBS、SEPS)、聚烯烴類膠體(APAO、PO);增黏樹脂則是主要調控膠體整體黏度(Viscosity)的用途,具體材料可以是石油樹脂、松香樹脂或前述二者的衍生物。 Among them, in the formulation materials of the present invention, thermoplastic elastomers are materials that mainly provide waterproof and self-adhesive functions. Specific thermoplastic elastomers can be synthetic rubbers (SIS, SBS, SEBS, SEPS), polyolefin colloids (APAO, PO); Tackifying resin is mainly used to control the overall viscosity of the colloid (Viscosity). The specific material can be petroleum resin, rosin resin or derivatives of the foregoing two.
進一步的,所述的軟化油作用同樣可以用於調控膠體整體黏度,例如白蠟油、礦物油或丁基油;填料除了提供材料剛性強度外,更可節省原料成本,具體可以是無機填料,包含碳酸鈣、染色劑、碳粉、輪胎粉、阻燃劑。 Further, the softening oil effect can also be used to adjust the overall viscosity of the colloid, such as white wax oil, mineral oil or butyl oil; the filler can not only provide the rigidity of the material, but also save the cost of raw materials. Specifically, it can be an inorganic filler, including Calcium carbonate, coloring agent, carbon powder, tire powder, flame retardant.
利用上述環保防水熱熔膠配方可以制得一種環保防水熱熔膠,方法步驟包含:步驟1:先將軟化油及部分增黏樹脂加熱並攪拌到熔融狀態;步驟2:加入熱塑性彈性體後繼續加熱攪拌至熔融;以及步驟3:加入填料與剩餘的增黏樹脂後繼續加熱攪拌至完全熔融與分散均質就得到所述的環保防水熱熔膠。 An environmentally-friendly waterproof hot-melt adhesive can be prepared by using the above-mentioned environmentally-friendly waterproof hot-melt adhesive formula. The method steps include: Step 1: First heat and stir the softening oil and part of the tackifying resin to a molten state; Step 2: Continue after adding the thermoplastic elastomer Heating and stirring to melt; and step 3: adding the filler and the remaining tackifying resin and then continuing to heat and stir to completely melt and disperse homogeneously to obtain the environmentally friendly waterproof hot melt adhesive.
接著,請參考圖1,本發明利用所述的環保防水熱熔膠配方所制得的環保防水熱熔膠膜片材10,其包含:依序層疊的一面材11、一第一環保防水熱熔膠層13、一纖維層15以及一第二環保防水熱熔膠層17,其中:該第一環保防水熱熔膠層13與該第二環保防水熱熔膠層17部分滲入或含浸在該纖維層15的纖維間。
Next, please refer to FIG. 1, an environmentally-friendly waterproof hot-melt
其中,前述的該面材11是建築材料常見的面材,可以依據建築的外觀或是額外性能需求來搭配,例如可以是提供外觀質地的花紋或不同顏色的石質、砂質、塑膠、木質、金屬、發泡材料,也可以是提供效能的隔熱、阻火、
抗噪或止滑的單一或複合面料。前述的該纖維層15則可以是織布或是無紡布,利用塑膠、玻璃、石墨或金屬纖維所製成。
Among them, the
該環保防水熱熔膠膜片材10中的該第一環保防水熱熔膠層13與該第二環保防水熱熔膠層17具有自黏的特性,因此該面材11可以直接貼附於該第一環保防水熱熔膠層13的表面,而該第二環保防水熱熔膠層17則在生產完成過後進一步貼附一離型層19,有利於收卷儲藏與運輸過程不會相互沾黏。
The first environmental protection waterproof hot melt
最後,請參考圖2,本發明對照所述的環保防水熱熔膠膜片材提供其生產製造方法,其步驟包含:步驟1:將所述的環保防水熱熔膠加熱攪拌均勻,使其呈現熔融流體狀態,加熱溫度較佳介於110~200℃之間,攪拌時間60~360分鐘,攪拌速度介於10~60rpm;步驟2:將該環保防水熱熔膠過濾後輸送至一含浸槽中;步驟3:將所述的纖維層連續輸入該含浸槽中,並浸入熔融的該環保防水熱熔膠;步驟4:將含浸環保防水熱熔膠的該纖維層冷卻;步驟5:貼附所述的面材及/或離型層;步驟6:卷收並包裝入庫。 Finally, please refer to Figure 2. The present invention provides a manufacturing method for the environmentally-friendly waterproof hot-melt adhesive film sheet. The steps include: Step 1: Heat and stir the environmentally-friendly waterproof hot-melt adhesive to make it appear In the molten fluid state, the heating temperature is preferably between 110~200℃, the stirring time is 60~360 minutes, and the stirring speed is between 10~60rpm; Step 2: Filter the environmentally friendly waterproof hot melt adhesive and transport it to an impregnation tank; Step 3: Continuously input the fiber layer into the impregnation tank and immerse it in the molten environmental protection waterproof hot melt adhesive; Step 4: Cool the fiber layer impregnated with environmental protection waterproof hot melt adhesive; Step 5: Attach the The surface material and/or release layer; Step 6: Roll up and pack into storage.
前述步驟1~6僅是本發明實際生產製造時的全部生產步驟,然而從步驟1~4得到含浸環保防水熱熔膠的該纖維層的步驟即可算是本發明的範圍,步驟5、6所述的貼附面材、離型層與卷收包裝入庫等步驟只是實施上的選擇,並非一定必要之過程。 The foregoing steps 1 to 6 are only all the production steps in the actual production of the present invention. However, the steps of obtaining the fiber layer impregnated with environmentally friendly waterproof hot melt adhesive from steps 1 to 4 can be regarded as the scope of the present invention. Steps 5 and 6 The steps of attaching surface material, release layer, and rewinding and packaging storage are just implementation choices, not necessarily necessary processes.
進一步地,為了證實本發明的確切效能,結合下面具體實施範例,進一步闡述本發明的技術方案,但應當理解的是,這些實施範例只是用於說明本發明而不用於限定本發明的權利要求範圍。此外應理解,在閱讀了本發 明提供的技術方案內容之後,本領域的技術人員可以對本發明做各種等效的改動或修改,這些等價的形式同樣落入本發明權利要求所限定的範圍中。 Further, in order to verify the exact effectiveness of the present invention, the technical solutions of the present invention are further explained in combination with the following specific examples. However, it should be understood that these examples are only used to illustrate the present invention and not to limit the scope of the claims of the present invention. . In addition, it should be understood that after reading this After clarifying the content of the technical solution provided, those skilled in the art can make various equivalent changes or modifications to the present invention, and these equivalent forms also fall within the scope defined by the claims of the present invention.
本發明提供以下表1的三個實施範例,並提供各實施例的相關性能測試數據如以下表2。 The present invention provides three implementation examples in Table 1 below, and provides related performance test data of each embodiment as shown in Table 2 below.
註1:CNS 3557K6348(各3組),混凝土膠結強度之試體模尺寸為5.0cm*5.0cm*15.0cm,下模面為防水膜(置於工作桌面上);以設計強度配比之水泥砂漿(水泥/砂之重量比為1/3,水灰比為0.45),分兩層注入模內;注模後立即於漿體上加以0.2kgf/cm2之壓力,並於4小時後解除壓力;而後於相對濕度95%環境(非浸泡於水中)下養護7天。切割中間2.5cm*12.0cm之防水膜範圍為膠結強度之 試體(6個),其中3個試體置於49℃乾燥狀況7天,另3個試體置於23±2℃水中7天;而後置於23±2℃空氣中4小時,之後防水膜以50mm/分鐘之速率,90°角剝揭。 Note 1: CNS 3557K6348 (3 groups each), the size of the test phantom for concrete bonding strength is 5.0cm*5.0cm*15.0cm, and the lower mold surface is a waterproof membrane (placed on the work table); cement with the design strength ratio Mortar (weight ratio of cement/sand is 1/3, water-cement ratio is 0.45), injected into the mold in two layers; immediately after injection molding, pressure of 0.2kgf/cm 2 is applied to the slurry and released after 4 hours Pressure; then curing for 7 days in a 95% relative humidity environment (not immersed in water). Cut the waterproof membrane of 2.5cm*12.0cm in the middle to the test specimens (6) of cementation strength, of which 3 specimens are placed in 49℃ dry condition for 7 days, and the other 3 specimens are placed in 23±2℃ water for 7 days ; Then put it in the air at 23±2℃ for 4 hours, then peel off the waterproof membrane at a rate of 50mm/min and an angle of 90°.
註2:用空心磚先塗接合劑之後,鋪貼防水膜再加滾動。樣品存放7天後,防水膜以50mm/分鐘之速率90°角剝揭。 Note 2: After coating the cement with hollow bricks, pave the waterproof membrane before rolling. After the samples were stored for 7 days, the waterproof membrane was peeled off at a 90° angle at a rate of 50 mm/min.
上述所述僅為本發明的較佳實施例而已,並非用以限定本發明主張的權利範圍,凡其它未脫離本發明所揭示的精神所完成的等效改變或修飾,均應包括在本發明的主張範圍內。 The foregoing descriptions are only preferred embodiments of the present invention, and are not intended to limit the scope of rights claimed by the present invention. All other equivalent changes or modifications completed without departing from the spirit disclosed by the present invention shall be included in the present invention. Within the scope of the claim.
10:環保防水熱熔膠膜片材 10: Environmental protection waterproof hot melt adhesive film sheet
11:面材 11: Surface material
13:第一環保防水熱熔膠層 13: The first environmental protection waterproof hot melt adhesive layer
15:纖維層 15: Fiber layer
17:第二環保防水熱熔膠層 17: The second environmentally friendly waterproof hot melt adhesive layer
19:離型層 19: Release layer
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Citations (3)
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CN101669414A (en) * | 2007-03-16 | 2010-03-10 | 三菱瓦斯化学株式会社 | Light-transmitting electromagnetic-shielding laminate and method for producing the same, light-transmitting radio wave absorber, and adhesive composition |
CN102604552A (en) * | 2011-12-06 | 2012-07-25 | 福建爱贝思日用品有限公司 | Thermoplastic resin film, as well as production technology, production device and adhesive tool product thereof |
CN105295789A (en) * | 2015-11-25 | 2016-02-03 | 广州旭川合成材料有限公司 | Environmental-protection hot melt adhesive for interior and exterior decoration of automobile and preparation method of hot melt adhesive |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN101669414A (en) * | 2007-03-16 | 2010-03-10 | 三菱瓦斯化学株式会社 | Light-transmitting electromagnetic-shielding laminate and method for producing the same, light-transmitting radio wave absorber, and adhesive composition |
CN102604552A (en) * | 2011-12-06 | 2012-07-25 | 福建爱贝思日用品有限公司 | Thermoplastic resin film, as well as production technology, production device and adhesive tool product thereof |
CN105295789A (en) * | 2015-11-25 | 2016-02-03 | 广州旭川合成材料有限公司 | Environmental-protection hot melt adhesive for interior and exterior decoration of automobile and preparation method of hot melt adhesive |
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