JP7060885B2 - Eco-waterproof hot melt adhesive composition, its film material and manufacturing method - Google Patents

Eco-waterproof hot melt adhesive composition, its film material and manufacturing method Download PDF

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JP7060885B2
JP7060885B2 JP2019223322A JP2019223322A JP7060885B2 JP 7060885 B2 JP7060885 B2 JP 7060885B2 JP 2019223322 A JP2019223322 A JP 2019223322A JP 2019223322 A JP2019223322 A JP 2019223322A JP 7060885 B2 JP7060885 B2 JP 7060885B2
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JP2021091796A (en
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王勝義
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誠泰工業科技股▲分▼有限公司
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Description

本発明は、ホットメルト接着剤組成物とそのフィルム材及び製造方法に関し、特に、一種のエコ防水ホットメルト接着剤組成物とそのフィルム材の製造方法に関する。 The present invention relates to a hot melt adhesive composition, a film material thereof, and a method for producing the same, and more particularly to a kind of eco-waterproof hot melt adhesive composition and a method for producing the film material.

建築において、防水工程は相当重要な一環であり、もし施工不良または防水材料の品質不良があった場合、雨漏りや水漏れの現象が起こるになるため、住居と生活の品質に影響する。現在一般的に見られる防水塗装、防水レンガまたは防水フィルムを含む防水材料は、近代建築に広く応用されるものであり、一般住宅だけでなく、高級マンションや公共建築物にも使われている。 In construction, the waterproofing process is a fairly important part, and if there is a poor construction or poor quality of waterproof material, the phenomenon of rain leaks and water leaks will occur, which will affect the quality of housing and life. Waterproof materials, including waterproof paints, waterproof bricks or waterproof films that are commonly found today, are widely applied in modern architecture and are used not only in ordinary homes, but also in luxury condominiums and public buildings.

前記防水材料は一般、優れる防水、断熱、保温などの特性を持つ、且つ低価格と耐食性を有する建造に適した材料であるアスファルト成分を添加するが、それらの利点の代わりに、環境汚染の問題が存在すると共に、製造の工程において作業員の健康と仕事環境に対する損害という問題があった。 The waterproof material adds asphalt components, which are generally, excellent waterproof, heat insulating, heat retaining and other properties, and are low cost and corrosion resistant materials suitable for construction, but at the cost of their advantages, the problem of environmental pollution. In addition to the existence of, there was a problem of damage to the health of workers and the work environment in the manufacturing process.

よって、上記のアスファルト成分を含有する防水材料の欠陥を克服して、環境に優しい防水ホットメルト接着剤組成物とそのフィルム材及び製造方法は、本発明が解決しようとする問題である。 Therefore, an environment-friendly waterproof hot-melt adhesive composition, a film material thereof, and a manufacturing method that overcomes the above-mentioned defects of the waterproof material containing an asphalt component are problems to be solved by the present invention.

既存のアスファルト成分を含有する防水材料が起こる環境汚染の問題に鑑みて、本発明の目的は、一種のエコ防水ホットメルト接着剤組成物と、そのフィルム材の製造方法を提供することにある。その組成物はアスファルト成分を含有しないと共に、防水と耐候性に関しては既存の防水材料に相当し、安全且つ環境に優しいという非常に優れる実用価値がある。 In view of the problem of environmental pollution caused by existing waterproof materials containing asphalt components, an object of the present invention is to provide a kind of eco-waterproof hot melt adhesive composition and a method for producing a film material thereof. The composition does not contain an asphalt component, and is equivalent to an existing waterproof material in terms of waterproofing and weather resistance, and has a very excellent practical value of being safe and environmentally friendly.

前述の技術問題を解決するための本発明が採用する技術手段として、エコ防水ホットメルト接着剤組成物を提供し、その原料は:熱可塑性エラストマー10~40wt%;粘着付与樹脂20~60wt%;プロセスオイル30wt%以下;及びフィラー10wt%以下を含む。 As a technical means adopted by the present invention for solving the above-mentioned technical problems, an eco-waterproof hot melt adhesive composition is provided, and the raw material thereof is: thermoplastic elastomer 10 to 40 wt%; tackifier resin 20 to 60 wt%; Contains 30 wt% or less of process oil; and 10 wt% or less of filler.

さらに、前記熱可塑性エラストマーは合成ゴム、ポリオレフィンコロイドを含み、且つ前記粘着付与樹脂は石油樹脂、ロジン樹脂及び上記両方の誘導体を含む。 Further, the thermoplastic elastomer contains a synthetic rubber and a polyolefin colloid, and the tackifier resin contains a petroleum resin, a rosin resin and both of the above derivatives.

さらに、前記プロセスオイルはパラフィンオイル、鉱物油またはブチル油を含み、且つ前記フィラーは無機フィラーを含み、前記無機フィラーは炭酸カルシウム、着色剤、炭の粉、タイヤパウダーまたは難燃性パウダーを含む。 Further, the process oil contains paraffin oil, mineral oil or butyl oil, and the filler contains an inorganic filler, and the inorganic filler contains calcium carbonate, a colorant, charcoal powder, tire powder or flame-retardant powder.

そして、前述の技術問題を解決するための本発明が採用する技術手段として、エコ防水ホットメルト接着剤フィルム材を提供し、そのフィルム材は、順次積層された表面材、第一エコ防水ホットメルト接着剤層、繊維層、及び第二エコ防水ホットメルト接着剤層を含み、そのうち、前記第一エコ防水ホットメルト接着剤層と前記第二エコ防水ホットメルト接着剤層の一部が、前記繊維層の繊維間に浸潤または含浸する。 Then, as a technical means adopted by the present invention for solving the above-mentioned technical problem, an eco-waterproof hot melt adhesive film material is provided, and the film material is a surface material sequentially laminated and a first eco-waterproof hot melt. An adhesive layer, a fiber layer, and a second eco-waterproof hot-melt adhesive layer are included, of which a part of the first eco-waterproof hot-melt adhesive layer and the second eco-waterproof hot-melt adhesive layer is the fiber. Infiltrate or impregnate between the fibers of the layer.

さらに、前記表面材は石、砂、プラスチック、木、金属、発泡材料、または断熱、耐火、遮音または滑り止めの特性を有する単一または複合の表面材を含む。 Further, the surface material includes stone, sand, plastic, wood, metal, foam material, or a single or composite surface material having heat insulating, fireproof, sound insulating or non-slip properties.

さらに、前記繊維層はプラスチックまたはガラス、グラファイト繊維または金属繊維からなる織物または不織布によって形成する。 Further, the fiber layer is formed of a woven fabric or non-woven fabric made of plastic or glass, graphite fiber or metal fiber.

また、前述の技術問題を解決するための本発明が採用する技術手段として、エコ防水ホットメルト接着剤フィルム材の製造方法を提供し、その方法は以下のステップを含む: Further, as a technical means adopted by the present invention for solving the above-mentioned technical problems, a method for manufacturing an eco-waterproof hot melt adhesive film material is provided, and the method includes the following steps:

ステップ1:熱可塑性エラストマー10~40wt%と、粘着付与樹脂20~60wt%と、粘着付与樹脂20~60wt%と、プロセスオイル30wt%以下と、フィラー10wt%以下と、を含むエコ防水ホットメルト接着剤を加熱して均一に攪拌し、溶融流体の状態にする; Step 1: Eco-waterproof hot melt adhesive containing 10-40 wt% thermoplastic elastomer, 20-60 wt% tackifier resin, 20-60 wt% tackifier resin, 30 wt% or less process oil, and 10 wt% or less filler. Heat the agent and stir it evenly to make it a molten fluid;

ステップ2:前記エコ防水ホットメルト接着剤を濾過した後に、含浸槽中に搬送する; Step 2: After filtering the eco-waterproof hot melt adhesive, it is transported into an impregnation tank;

ステップ3:繊維層を前記含浸槽中に連続搬入し、溶融した前記エコ防水ホットメルト接着剤に浸漬する;及び Step 3: The fiber layer is continuously carried into the impregnation tank and immersed in the melted eco-waterproof hot melt adhesive;

ステップ4:前記エコ防水ホットメルト接着剤を含浸した前記繊維層を冷却して、前記エコ防水ホットメルト接着剤フィルム材を得る。 Step 4: The fiber layer impregnated with the eco-waterproof hot-melt adhesive is cooled to obtain the eco-waterproof hot-melt adhesive film material.

さらに、ステップ4で得られた前記エコ防水ホットメルト接着剤フィルム材に表面材及び/または離型層を貼り付けることを含み、前記表面材と前記離型層は同じ材料または異なる材料からなるものである。 Further, the present invention includes attaching a surface material and / or a release layer to the eco-waterproof hot melt adhesive film material obtained in step 4, and the surface material and the release layer are made of the same material or different materials. Is.

さらに、前記エコ防水ホットメルト接着剤フィルム材をロールで収納且つ梱包貯蔵をする。 Further, the eco-waterproof hot melt adhesive film material is stored in a roll and packed and stored.

本発明が提供した上述の技術手段は、以下のメリットがある: The above-mentioned technical means provided by the present invention have the following advantages:

1.本発明のエコ防水ホットメルト接着剤組成物の原料にはアスファルト成分を含まず、有機溶剤も含まないので、環境に優しい利点があると同時に、業者が製造の工程において揮発性物質や刺激臭を生じることもないので、作業員と仕事環境にも優しい。 1. 1. Since the raw material of the eco-waterproof hot melt adhesive composition of the present invention does not contain an asphalt component and no organic solvent, it has an environmentally friendly advantage, and at the same time, a trader can dissipate volatile substances and pungent odors in the manufacturing process. Since it does not occur, it is friendly to workers and the work environment.

2.本発明が提供した防水ホットメルト接着剤フィルム材は、当業者の既存の含浸設備を使用するだけで容易に製造できるため、他の高価な設備や特殊な技術を導入する必要はない。また、実験によると、本発明の防水ホットメルト接着剤フィルム材は優れた防水、耐候性と自己接着の特性を有し、加工処理が簡単で、優れた品質と価額があって経済的な価値を確実に備えられる。 2. 2. Since the waterproof hot melt adhesive film material provided by the present invention can be easily manufactured only by using the existing impregnation equipment of those skilled in the art, it is not necessary to introduce other expensive equipment or special techniques. Also, according to experiments, the waterproof hot melt adhesive film material of the present invention has excellent waterproof, weather resistance and self-adhesive properties, is easy to process, has excellent quality and value, and has economic value. Is surely prepared.

本発明のエコ防水ホットメルト接着剤フィルム材の概略図である。It is a schematic diagram of the eco-waterproof hot melt adhesive film material of this invention. 本発明のエコ防水ホットメルト接着剤フィルム材の製造方法を示すフローチャートである。It is a flowchart which shows the manufacturing method of the eco-waterproof hot melt adhesive film material of this invention.

本発明はエコ防水ホットメルト接着剤組成物を提供し、その原料は:
熱可塑性エラストマー10~40wt%;
粘着付与樹脂20~60wt%;
プロセスオイル30wt%以下;及び
フィラー10wt%以下を含む。
上記熱可塑性エラストマーは、15~35wt%が好ましく、より好ましくは20~35wt%であり、さらに好ましくは25~35wt%である。
上記粘着付与樹脂は、30~55wt%であることが好ましく、より好ましくは35~50wt%であり、さらに好ましくは40~50wt%である。
上記プロセスオイルは5~28wt%であることが好ましく、より好ましくは10~25wt%であり、さらに好ましくは15~20wt%である。
上記フィラーは、3~10wt%であることが好ましく、より好ましくは4~9wt%であり、さらに好ましくは5~8wt%である。
The present invention provides an eco-waterproof hot melt adhesive composition, the raw material thereof:
Thermoplastic elastomer 10-40 wt%;
Adhesive-imparting resin 20-60 wt%;
Contains 30 wt% or less of process oil; and 10 wt% or less of filler.
The thermoplastic elastomer is preferably 15 to 35 wt%, more preferably 20 to 35 wt%, and even more preferably 25 to 35 wt%.
The pressure-sensitive adhesive resin is preferably 30 to 55 wt%, more preferably 35 to 50 wt%, and even more preferably 40 to 50 wt%.
The process oil is preferably 5 to 28 wt%, more preferably 10 to 25 wt%, still more preferably 15 to 20 wt%.
The filler is preferably 3 to 10 wt%, more preferably 4 to 9 wt%, and even more preferably 5 to 8 wt%.

本発明の上記組成物の原料において、熱可塑性エラストマーは主に防水と自己接着の特性を提供する材料であり、熱可塑性エラストマーは具体的に合成ゴム(SIS、SBS、SEBS、SEPS)と、ポリオレフィンコロイド(APAO、PO)であることができる。粘着付与樹脂は主にコロイド全体の粘度(Viscosity)を調節するためのものであり、具体的に石油樹脂、ロジン樹脂及び上記両方の誘導体であることができる。 In the raw material of the above composition of the present invention, the thermoplastic elastomer is a material mainly provided with waterproof and self-adhesive properties, and the thermoplastic elastomer is specifically synthetic rubber (SIS, SBS, SEBS, SEPS) and polyolefin. It can be a colloid (APAO, PO). The tackifier resin is mainly for adjusting the viscosity of the entire colloid, and can be specifically a petroleum resin, a rosin resin, or a derivative of both of the above.

さらに、前述したプロセスオイルの作用も同様に、コロイド全体の粘度を調節できるもの、例えばパラフィンオイル、鉱物油またはブチル油である。また、フィラーは材料の強度と剛性を提供する他、原料コストも節約することができ、具体的には無機フィラー、例えば炭酸カルシウム、着色剤、炭の粉、タイヤパウダー、難燃剤などを含む。 Further, the action of the process oil described above is also the one capable of adjusting the viscosity of the entire colloid, for example, paraffin oil, mineral oil or butyl oil. In addition to providing the strength and rigidity of the material, the filler can also save on raw material costs and specifically include inorganic fillers such as calcium carbonate, colorants, charcoal powder, tire powders, flame retardants and the like.

上述のエコ防水ホットメルト接着剤組成物を利用することで、一種のエコ防水ホットメルト接着剤を製造することができる、その方法は以下のステップを含む: By utilizing the eco-waterproof hot-melt adhesive composition described above, a kind of eco-waterproof hot-melt adhesive can be produced, the method of which includes the following steps:

ステップ1:先にプロセスオイル及び一部の粘着付与樹脂を加熱して均一に攪拌して溶融状態にする; Step 1: First, heat the process oil and some tackifier resin and stir them uniformly to make them melted;

ステップ2:熱可塑性エラストマー添加した後も継続的に加熱攪拌して溶融状態にする; Step 2: After adding the thermoplastic elastomer, continuously heat and stir to make it in a molten state;

ステップ3:フィラーと残りの粘着付与樹脂を添加して継続的に加熱攪拌して完全に均一分散の溶融状態にすることで、上述のエコ防水ホットメルト接着剤が得られる。 Step 3: The above-mentioned eco-waterproof hot melt adhesive can be obtained by adding a filler and the remaining tackifier resin and continuously heating and stirring to bring the melted state into a completely uniformly dispersed state.

そして、図1に参照し、本発明が上述のエコ防水ホットメルト接着剤組成物を用いて製造されたエコ防水ホットメルト接着剤フィルム材10は、順次積層された表面材11、第一エコ防水ホットメルト接着剤層13、繊維層15、及び第二エコ防水ホットメルト接着剤層17を含み、そのうち:前記第一エコ防水ホットメルト接着剤層13と前記第二エコ防水ホットメルト接着剤層17の一部が前記繊維層15の繊維間に浸潤または含浸する。 Then, referring to FIG. 1, the eco-waterproof hot-melt adhesive film material 10 produced by the present invention using the above-mentioned eco-waterproof hot-melt adhesive composition includes a surface material 11 and a first eco-waterproof laminated sequentially. It contains a hot melt adhesive layer 13, a fiber layer 15, and a second eco-waterproof hot melt adhesive layer 17, among which: the first eco-waterproof hot-melt adhesive layer 13 and the second eco-waterproof hot-melt adhesive layer 17. Partially infiltrates or impregnates between the fibers of the fiber layer 15.

そのうち、前述した表面材11は建材によく使われる表面材であり、建築の外観または必要の性能によって選択でき、例えば外観テクスチャのパターンまたは色を提供する石、砂、プラスチック、木、金属、発泡材料、または性能を提供する断熱、耐火、遮音または滑り止めの特性を有する単一または複合の表面材であることができる。前述した繊維層15は、プラスチックまたはガラス、グラファイト繊維または金属繊維からなる織物または不織布であることができる。 Of these, the surface material 11 described above is a surface material often used for building materials and can be selected according to the appearance of the building or the required performance, for example stone, sand, plastic, wood, metal, foam, which provides a pattern or color of appearance texture. It can be a material, or a single or composite surface material with thermal insulation, fire resistance, sound insulation or non-slip properties that provide performance. The above-mentioned fiber layer 15 can be a woven fabric or a non-woven fabric made of plastic or glass, graphite fiber or metal fiber.

前記エコ防水ホットメルト接着剤フィルム材10における前記第一エコ防水ホットメルト接着剤層13と前記第二エコ防水ホットメルト接着剤層17は、自己接着の特性を有するので、前記表面材11は直接前記第一エコ防水ホットメルト接着剤層13の表面に貼り付けることができて、前記第二エコ防水ホットメルト接着剤層17が完成した後はさらに離型層19を貼り付けるため、収納、貯蔵や運送の時に互いに粘着することを防ぐことができる。 Since the first eco-waterproof hot-melt adhesive layer 13 and the second eco-waterproof hot-melt adhesive layer 17 in the eco-waterproof hot-melt adhesive film material 10 have self-adhesive properties, the surface material 11 is directly attached. It can be attached to the surface of the first eco-waterproof hot-melt adhesive layer 13, and after the second eco-waterproof hot-melt adhesive layer 17 is completed, the release layer 19 is further attached, so that it is stored and stored. It is possible to prevent them from sticking to each other during transportation.

最後に、図2に参照し、本発明は前述のエコ防水ホットメルト接着剤フィルム材に対して、その製造方法を提供し、その方法は以下のステップを含む:
ステップ1:前記エコ防水ホットメルト接着剤組を加熱して均一に攪拌し、溶融流体の状態にする、加熱温度は110~200℃の間が好ましく、撹拌時間は60~360分で、撹拌速度は10~60rpmである;
ステップ2:前記エコ防水ホットメルト接着剤を濾過した後に、含浸槽中に搬送する;
ステップ3:前記繊維層を前記含浸槽中に連続搬入し、溶融した前記エコ防水ホットメルト接着剤に浸漬する;
ステップ4:前記エコ防水ホットメルト接着剤を含浸した前記繊維層を冷却する;
ステップ5:前記表面材及び/または離型層を貼り付ける;
ステップ6:ロールで収納且つ梱包貯蔵をする。
Finally, with reference to FIG. 2, the present invention provides a method for producing the eco-waterproof hot melt adhesive film material described above, which method comprises the following steps:
Step 1: The eco-waterproof hot-melt adhesive set is heated and uniformly stirred to bring it into a molten fluid state. The heating temperature is preferably between 110 and 200 ° C., the stirring time is 60 to 360 minutes, and the stirring speed is high. Is 10-60 rpm;
Step 2: After filtering the eco-waterproof hot melt adhesive, it is transported into an impregnation tank;
Step 3: The fiber layer is continuously carried into the impregnation tank and immersed in the melted eco-waterproof hot melt adhesive;
Step 4: Cool the fiber layer impregnated with the eco-waterproof hot melt adhesive;
Step 5: Attach the surface material and / or the release layer;
Step 6: Roll and pack and store.

前記ステップ1~6は本発明が実際に製造する時の全プロセスを示すものであるが、ステップ1~4で得られたエコ防水ホットメルト接着剤を含浸した前記繊維層だけでも本発明の範囲であり、ステップ5、6の表面材、離型層を貼り付けるとロールで収納且つ梱包貯蔵をすることは実施上の選択だけで、必ず必要な工程ではない。 Although steps 1 to 6 show the entire process when the present invention is actually manufactured, the scope of the present invention is limited to the fiber layer impregnated with the eco-waterproof hot melt adhesive obtained in steps 1 to 4. Therefore, when the surface material and the release layer of steps 5 and 6 are attached, storing with a roll and packing and storing is only an practical choice, and is not a necessary process.

さらに、本発明の確実な効果を実証するために、以下の具体的な実施例をもって本発明の技術手段を説明する。ここで理解すべきものとしては、これらの実施例は本発明の説明のみに使うものであって本発明の請求の範囲を制限するものではない。また、本発明が提供する技術手段を理解した後、当該領域の技術者は様々な同等の変更や修正を行えるが、それらの形式も同様に本発明が限定する請求の範囲に属する。 Further, in order to demonstrate the reliable effect of the present invention, the technical means of the present invention will be described with the following specific examples. It should be understood here that these examples are used only for the description of the present invention and do not limit the scope of the claims of the present invention. Further, after understanding the technical means provided by the present invention, engineers in the art can make various equivalent changes and modifications, but their forms also belong to the scope of claims limited by the present invention.

本発明は下記表1の3つの実施例を提供し、且つ各実施例の性能に関するテストデータを下記表2に示す。 The present invention provides the three examples shown in Table 1 below, and test data relating to the performance of each example is shown in Table 2 below.

Figure 0007060885000001
Figure 0007060885000001

Figure 0007060885000002
Figure 0007060885000002

注記1:CNS3557K6348(各3セット)、コンクリートの接着強度テストの試験型のサイズは5.0cm*5.0cm*15.0cm、シートの下型面は防水膜(作業台の上に置かれ);所定強度配分のセメントモルタル(セメント/砂の重量比は1/3、水セメント比は0.45)、両層に分かれて型内に注入;注入後すぐにモルタル上に0.2kgf/cmの圧力に加え、そして4時間後に圧力を解除する;その後、相対湿度95%の環境(水に浸漬ではなく)に7日間保存する。そして中間2.5cm*12.0cmの防水膜のある範囲を接着強度のサンプル(6個)として切り取って、そのうち3個のサンプルを49℃の乾燥環境に7日間保存、残り3個のサンプルを23±2℃の水中に7日間保存する。その後に23±2℃の空気中に4時間置かれてから、防水膜を50mm/minの速度、90°の角度で剥離する。 Note 1: CNS3557K6348 (3 sets each), the size of the test mold for the concrete adhesive strength test is 5.0 cm * 5.0 cm * 15.0 cm, and the lower mold surface of the sheet is a waterproof film (placed on the work table). Cement mortar with predetermined strength distribution (cement / sand weight ratio is 1/3, water-cement ratio is 0.45), divided into both layers and injected into the mold; 0.2 kgf / cm on the mortar immediately after injection Add to pressure of 2 and release pressure after 4 hours; then store in an environment of 95% relative humidity (not immersed in water) for 7 days. Then, a certain area of the waterproof film of intermediate 2.5 cm * 12.0 cm was cut out as adhesive strength samples (6 pieces), 3 of them were stored in a dry environment at 49 ° C for 7 days, and the remaining 3 samples were stored. Store in water at 23 ± 2 ° C for 7 days. After that, it is placed in air at 23 ± 2 ° C. for 4 hours, and then the waterproof film is peeled off at a speed of 50 mm / min and an angle of 90 °.

注記2:中空レンガに接着剤を塗った後に、防水膜を貼り付けてローリングする。サンプルを7日間保存した後、防水膜を50mm/minの速度、90°の角度で剥離する。 Note 2: After applying the adhesive to the hollow brick, apply a waterproof film and roll it. After storing the sample for 7 days, the waterproof film is peeled off at a speed of 50 mm / min and an angle of 90 °.

以上、本発明の好適な実施例を開示したが、本発明はこれらの実施例により限定されるものではなく、本発明の趣旨と範囲を逸脱しないすべての変更及び修正は、本発明の請求の範囲に含まれる。 Although preferred embodiments of the present invention have been disclosed above, the present invention is not limited to these examples, and all changes and modifications that do not deviate from the gist and scope of the present invention are claims of the present invention. Included in the range.

10 エコ防水ホットメルト接着剤フィルム材
11 表面材
13 第一エコ防水ホットメルト接着剤層
15 繊維層
17 第二エコ防水ホットメルト接着剤層
19 離型層
10 Eco-waterproof hot-melt adhesive film material 11 Surface material 13 First eco-waterproof hot-melt adhesive layer 15 Fiber layer 17 Second eco-waterproof hot-melt adhesive layer 19 Release layer

Claims (8)

熱可塑性エラストマー10~40wt%;
粘着付与樹脂35~60wt%;
プロセスオイル10~30wt%;及び
フィラー3~10wt%;
を含むエコ防水ホットメルト接着剤組成物であって、
前記熱可塑性エラストマーは、合成ゴム及びポリオレフィンコロイドであり
前記粘着付与樹脂は石油樹脂及び/又はロジン樹脂である
ことを特徴とする、エコ防水ホットメルト接着剤組成物。
Thermoplastic elastomer 10-40 wt%;
Adhesive-imparting resin 35-60 wt%;
Process oil 10-30 wt %; and filler 3-10 wt %;
Eco-waterproof hot melt adhesive composition containing
The thermoplastic elastomer is a synthetic rubber and a polyolefin colloid .
The tackifier resin is a petroleum resin and / or a rosin resin.
An eco-waterproof hot melt adhesive composition characterized by that.
49℃の乾燥環境に7日間保存した後又は23℃±2℃の水中で7日間保存した後のコンクリート接着強度が最小で1.5kgf/cmである請求項1に記載のエコ防水ホットメルト接着剤組成物。The eco-waterproof hot melt adhesive according to claim 1, wherein the concrete adhesive strength after storage in a dry environment of 49 ° C. for 7 days or in water at 23 ° C. ± 2 ° C. for 7 days has a minimum of 1.5 kgf / cm. Agent composition. 前記プロセスオイルはパラフィンオイル、鉱物油またはブチル油を含み、且つ前記フィラーは無機フィラーを含み、前記無機フィラーは炭酸カルシウム、着色剤、炭の粉、タイヤパウダーまたは難燃性パウダーを含むことを特徴とする、請求項に記載のエコ防水ホットメルト接着剤組成物。 The process oil comprises paraffin oil, mineral oil or butyl oil, and the filler comprises an inorganic filler, wherein the inorganic filler comprises calcium carbonate, a colorant, charcoal powder, tire powder or flame retardant powder. The eco-waterproof hot melt adhesive composition according to claim 1 . 順次積層された表面材、第一エコ防水ホットメルト接着剤層、繊維層、及び第二エコ防水ホットメルト接着剤層を含むエコ防水ホットメルト接着剤フィルム材であって、
前記第一エコ防水ホットメルト接着剤層又は前記第二エコ防水ホットメルト接着剤層のいずれか一方は、請求項1に記載のエコ防水ホットメルト接着剤組成物によって構成され、
前記第一エコ防水ホットメルト接着剤層と前記第二エコ防水ホットメルト接着剤層の一部が前記繊維層の繊維間に浸潤または含浸することを特徴とする、エコ防水ホットメルト接着剤フィルム材。
An eco-waterproof hot-melt adhesive film material comprising a sequentially laminated surface material, a first eco-waterproof hot-melt adhesive layer, a fiber layer, and a second eco-waterproof hot-melt adhesive layer.
Either the first eco-waterproof hot-melt adhesive layer or the second eco-waterproof hot-melt adhesive layer is composed of the eco-waterproof hot-melt adhesive composition according to claim 1.
An eco-waterproof hot-melt adhesive film material, characterized in that a part of the first eco-waterproof hot-melt adhesive layer and the second eco-waterproof hot-melt adhesive layer infiltrates or impregnates between the fibers of the fiber layer. ..
前記表面材は石、砂、プラスチック、木、金属、発泡材料、または断熱、耐火、遮音または滑り止めの特性を有する単一または複合の表面材を含み、且つ
前記繊維層はプラスチックまたはガラス、グラファイト繊維または金属繊維からなる織物または不織布を含むことを特徴とする、請求項に記載のエコ防水ホットメルト接着剤フィルム材。
The surface material comprises a stone, sand, plastic, wood, metal, foam material, or a single or composite surface material having thermal insulation, fire resistance, sound insulation or non-slip properties, and the fiber layer is plastic or glass, graphite. The eco-waterproof hot melt adhesive film material according to claim 4 , which comprises a woven fabric or a non-woven fabric made of a fiber or a metal fiber.
エコ防水ホットメルト接着剤フィルム材の製造方法であって、以下のステップを含む:
ステップ1:請求項1に記載のエコ防水ホットメルト接着剤組成物を加熱して均一に攪拌し、溶融流体の状態にする;
ステップ2:前記エコ防水ホットメルト接着剤を濾過した後に、含浸槽中に搬送する;
ステップ3:繊維層を前記含浸槽中に連続搬入し、溶融した前記エコ防水ホットメルト接着剤に浸漬する;及び
ステップ4:前記エコ防水ホットメルト接着剤を含浸した前記繊維層を冷却して、前記エコ防水ホットメルト接着剤フィルム材を得る;
ことを特徴とする、エコ防水ホットメルト接着剤フィルム材の製造方法。
A method for manufacturing eco-waterproof hot melt adhesive films, including the following steps:
Step 1: The eco-waterproof hot melt adhesive composition according to claim 1 is heated and uniformly agitated to bring it into a molten fluid state;
Step 2: After filtering the eco-waterproof hot melt adhesive, it is transported into an impregnation tank;
Step 3: The fiber layer is continuously carried into the impregnation tank and immersed in the melted eco-waterproof hot melt adhesive; and step 4: the fiber layer impregnated with the eco-waterproof hot melt adhesive is cooled. Obtain the eco-waterproof hot melt adhesive film material;
A method for manufacturing an eco-waterproof hot melt adhesive film material, which is characterized by the fact that.
さらに、ステップ4で得られた前記エコ防水ホットメルト接着剤フィルム材に表面材、離型層の少なくとも1つを貼り付けることを含み、前記表面材と前記離型層は同じ材料または異なる材料からなることを特徴とする、請求項に記載のエコ防水ホットメルト接着剤フィルム材の製造方法。 Further, the present invention includes attaching at least one of the surface material and the release layer to the eco-waterproof hot melt adhesive film material obtained in step 4, and the surface material and the release layer are made of the same material or different materials. The method for producing an eco-waterproof hot melt adhesive film material according to claim 6 , characterized in that. さらに、前記エコ防水ホットメルト接着剤フィルム材をロールで収納且つ梱包貯蔵をすることを特徴とする、請求項に記載のエコ防水ホットメルト接着剤フィルム材の製造方法。
The method for producing an eco-waterproof hot-melt adhesive film material according to claim 6 , further comprising storing the eco-waterproof hot-melt adhesive film material in a roll and packing and storing the eco-waterproof hot-melt adhesive film material.
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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008169281A (en) 2007-01-10 2008-07-24 Nitto Denko Corp Thermoadhesive sheet
CN101864259A (en) 2010-05-05 2010-10-20 广州市豪特粘接材料有限公司 SIS (Styrene-Isoprene-Styrene) hot melt adhesive for car light adhesion and preparation method thereof
JP2012107086A (en) 2010-11-16 2012-06-07 Ricoh Co Ltd Thermosensitive adhesive material and thermosensitive adhesive sheet using the same
JP2014172995A (en) 2013-03-08 2014-09-22 Yokohama Rubber Co Ltd:The Hot melt adhesive composition
JP2014512668A5 (en) 2012-02-08 2015-03-19
CN105694803A (en) 2016-03-08 2016-06-22 滨州职业学院 Hot-melt pressure-sensitive adhesive and preparation technology thereof
JP2016130283A (en) 2015-01-13 2016-07-21 ニチバン株式会社 Adhesive tape
CN110093128A (en) 2019-05-31 2019-08-06 黄敏 Environment-friendly type hot melt pressure sensitive adhesive and preparation method thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP3284205B2 (en) * 1997-02-28 2002-05-20 日立化成ポリマー株式会社 Reinforced adhesive tape
CN102646740B (en) * 2011-02-18 2015-06-10 3M创新有限公司 Adhesive tape, solar assembly manufactured by adhesive tape and product

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2008169281A (en) 2007-01-10 2008-07-24 Nitto Denko Corp Thermoadhesive sheet
CN101864259A (en) 2010-05-05 2010-10-20 广州市豪特粘接材料有限公司 SIS (Styrene-Isoprene-Styrene) hot melt adhesive for car light adhesion and preparation method thereof
JP2012107086A (en) 2010-11-16 2012-06-07 Ricoh Co Ltd Thermosensitive adhesive material and thermosensitive adhesive sheet using the same
JP2014512668A5 (en) 2012-02-08 2015-03-19
JP2014172995A (en) 2013-03-08 2014-09-22 Yokohama Rubber Co Ltd:The Hot melt adhesive composition
JP2016130283A (en) 2015-01-13 2016-07-21 ニチバン株式会社 Adhesive tape
CN105694803A (en) 2016-03-08 2016-06-22 滨州职业学院 Hot-melt pressure-sensitive adhesive and preparation technology thereof
CN110093128A (en) 2019-05-31 2019-08-06 黄敏 Environment-friendly type hot melt pressure sensitive adhesive and preparation method thereof

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