TWI704235B - Composition alloy of golf club head - Google Patents

Composition alloy of golf club head Download PDF

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TWI704235B
TWI704235B TW109100751A TW109100751A TWI704235B TW I704235 B TWI704235 B TW I704235B TW 109100751 A TW109100751 A TW 109100751A TW 109100751 A TW109100751 A TW 109100751A TW I704235 B TWI704235 B TW I704235B
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club head
golf club
alloy
strength
present
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TW109100751A
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TW202126828A (en
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周益男
王志文
蕭德福
陳敏宗
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明安國際企業股份有限公司
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Priority to CN202010205725.XA priority patent/CN113215440A/en
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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C14/00Alloys based on titanium
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B53/00Golf clubs
    • A63B53/04Heads
    • AHUMAN NECESSITIES
    • A63SPORTS; GAMES; AMUSEMENTS
    • A63BAPPARATUS FOR PHYSICAL TRAINING, GYMNASTICS, SWIMMING, CLIMBING, OR FENCING; BALL GAMES; TRAINING EQUIPMENT
    • A63B2102/00Application of clubs, bats, rackets or the like to the sporting activity ; particular sports involving the use of balls and clubs, bats, rackets, or the like
    • A63B2102/32Golf

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Organic Chemistry (AREA)
  • Health & Medical Sciences (AREA)
  • General Health & Medical Sciences (AREA)
  • Physical Education & Sports Medicine (AREA)
  • Golf Clubs (AREA)

Abstract

一種高爾夫球桿頭之組成合金,包含7.0wt%~8.0wt%的鋁、0.15~0.3wt%的矽、1.8wt%~2.2wt%的鉻、0.8wt%~1.2wt%的釩、2.3wt%~2.7wt%的鉬、0.3wt%~0.7wt%的鐵,其餘為不可避免的雜質及用以平衡且含量不為0的鈦。本發明具有高韌性及強度,能承受高爾夫球桿頭擊球瞬間的局部高速撞擊而不破裂、不變形,且本發明同時具有低密度之特色,能減輕桿頭重量,使配重分佈能有更大的彈性,以能針對不同的彈道需求、使用者特性來進行重心的調整,達到最適化的桿頭設計。A composition alloy of a golf club head, containing 7.0wt%~8.0wt% aluminum, 0.15~0.3wt% silicon, 1.8wt%~2.2wt% chromium, 0.8wt%~1.2wt% vanadium, 2.3wt% %~2.7wt% of molybdenum, 0.3wt%~0.7wt% of iron, the rest are unavoidable impurities and titanium that is used to balance and whose content is not zero. The invention has high toughness and strength, can withstand the local high-speed impact of the golf club head at the moment of hitting the ball without breaking or deforming, and the invention also has the characteristics of low density, can reduce the weight of the club head, and enable the weight distribution to be With greater flexibility, the center of gravity can be adjusted according to different ballistic requirements and user characteristics to achieve the most suitable club head design.

Description

高爾夫球桿頭之組成合金Composition alloy of golf club head

本發明是有關於一種組成合金,特別是指一種可用於作為高爾夫球桿頭之材料的組成合金。The present invention relates to a component alloy, especially a component alloy that can be used as a material for golf club heads.

由於質量輕及強度高等特點,鈦合金被廣泛應用於航太、汽車、精密機械及自行車等領域,其中常見的代表便是Ti-6Al-4V合金,其是由6wt%的鋁、4wt%的釩,及不可避免的雜質及鈦組成,然而此材質比強度不足,難以承受擊球時瞬間升高的力道,且不利於重新調整配重,因而已無法滿足目前的高爾夫球桿頭之設計。Due to its light weight and high strength, titanium alloys are widely used in aerospace, automobiles, precision machinery and bicycles. The common representative is Ti-6Al-4V alloy, which is made of 6wt% aluminum and 4wt% It is composed of vanadium, and inevitable impurities and titanium. However, this material has insufficient specific strength, which makes it difficult to withstand the instantaneous increase in force when hitting the ball, and is not conducive to re-adjusting the weight. Therefore, it cannot meet the current golf club head design.

因此,本發明之目的,即在提供一種具高強度、高韌度及低密度等特性,以能應用於高爾夫球桿頭的組成合金。Therefore, the object of the present invention is to provide an alloy with high strength, high toughness and low density, which can be applied to golf club heads.

於是,本發明高爾夫球桿頭之組成合金,包含7.0wt%~8.0wt %的鋁、0.15~0.3wt%的矽、1.8wt%~2.2wt%的鉻、0.8wt%~1.2wt%的釩、2.3wt%~2.7wt%的鉬、0.3wt%~0.7wt%的鐵,其餘為不可避免的雜質及用以平衡且含量不為0的鈦。Therefore, the composition alloy of the golf club head of the present invention contains 7.0wt%~8.0wt% aluminum, 0.15~0.3wt% silicon, 1.8wt%~2.2wt% chromium, 0.8wt%~1.2wt% vanadium , 2.3wt%~2.7wt% molybdenum, 0.3wt%~0.7wt% iron, the rest are unavoidable impurities and titanium for balance and the content is not zero.

本發明之功效在於:本發明具有高韌性及強度,能承受高爾夫球桿頭擊球瞬間的局部高速撞擊而不破裂、不變形,且本發明同時具有低密度之特色,能減輕桿頭重量,使配重分佈能有更大的彈性,以能針對不同的彈道需求、使用者特性來進行重心的調整,達到最適化的桿頭設計。The effect of the present invention is that the present invention has high toughness and strength, can withstand the local high-speed impact of the golf club head at the moment of hitting the ball without breaking or deforming, and the present invention also has the characteristics of low density and can reduce the weight of the club head. The weight distribution can be more flexible, so that the center of gravity can be adjusted according to different ballistic requirements and user characteristics to achieve the most suitable club head design.

參閱圖1,本發明高爾夫球桿頭之組成合金的一實施例,包含7.0wt%~8.0wt%的鋁、0.15~0.3wt%的矽、1.8wt%~2.2wt%的鉻、0.8wt%~1.2wt%的釩、2.3wt%~2.7wt%的鉬、0.3wt%~0.7wt%的鐵,其餘為不可避免的雜質,及用以平衡且含量不為0的鈦。其中矽的含量較佳為0.18wt%。本發明透過添加0.18wt%的矽,能有利於防止氣孔形成、增進收縮作用,及增加金屬液之流動性,從而能提升合金鑄件之鑄造性。加入1.8wt%~2.2wt%的鉻,可提升合金材料硬化能及強度。加入0.8wt%~1.2wt%的釩,可使合金晶粒細化與析出強化,有助於提升合金機械性質。加入2.3wt%~2.7wt%的鉬,能增加強度但不致降低可塑性及韌性。圖1所顯示的是本發明的晶相SEM(掃描式電子顯微鏡,Scanning Electron Microscope,簡稱 SEM )圖。Referring to Figure 1, an embodiment of the alloy of the golf club head of the present invention includes 7.0wt%~8.0wt% aluminum, 0.15~0.3wt% silicon, 1.8wt%~2.2wt% chromium, 0.8wt% ~1.2wt% of vanadium, 2.3wt% to 2.7wt% of molybdenum, 0.3wt% to 0.7wt% of iron, the rest are unavoidable impurities, and are used to balance titanium with a non-zero content. The content of silicon is preferably 0.18wt%. By adding 0.18wt% of silicon, the present invention can help prevent the formation of pores, enhance the shrinkage effect, and increase the fluidity of the molten metal, thereby improving the castability of alloy castings. Adding 1.8wt%~2.2wt% of chromium can improve the hardening ability and strength of alloy materials. The addition of 0.8wt% to 1.2wt% of vanadium can refine the alloy grains and strengthen the precipitation, which helps to improve the mechanical properties of the alloy. Adding 2.3wt%~2.7wt% molybdenum can increase the strength but not reduce the plasticity and toughness. Figure 1 shows the crystal phase SEM (Scanning Electron Microscope, SEM for short) image of the present invention.

參閱下表1,為本發明與其他7種常見的高強度鈦合金材料的成分組成,下表2則是這8種材料的機械性質比較,由表2中可清楚看到,本實施例有較高的強度、韌度及硬度,因此做為高爾夫球桿頭的材料,本實施例可承受擊球瞬間的高速撞擊,而能不破裂且不變形。參閱圖2,圖2為表1中的8種鈦合金特性的散點圖,其中橫坐標為應力除以彈性係數,縱座標則為應力除以密度,據此可將圖1區分為四個區域,左下的區域代表強度低且密度高,其並不適合作為高爾夫球桿頭之材料,右下的區域代表密度高,其不利於結構設計及配重調整,左上的區域代表強度高但彈性係數也高,其材質較脆而導致球頭容易破裂,右上的區域代表強度高但密度較低,其在保持高強度及韌度的情況下,還能擁有較低的密度,可維持設計及重心配置的靈活度,而本案實施例相較於其他材料而言,是位於右上方的區域,也就是維持高強度及高韌度的同時,能有較低的密度,因此利於調整配重,且能承受擊球瞬間的高速撞擊,適合製成高爾夫球桿頭。Refer to Table 1 below for the composition of the present invention and other 7 common high-strength titanium alloy materials. Table 2 below is a comparison of the mechanical properties of these 8 materials. It can be clearly seen from Table 2 that this embodiment has With high strength, toughness and hardness, as the material of the golf club head, this embodiment can withstand high-speed impact at the moment of hitting the ball without breaking or deforming. Refer to Figure 2. Figure 2 is a scatter plot of the characteristics of the eight titanium alloys in Table 1. The abscissa is the stress divided by the coefficient of elasticity, and the ordinate is the stress divided by the density. Accordingly, Figure 1 can be divided into four Area, the lower left area represents low strength and high density, which is not suitable for golf club head materials, the lower right area represents high density, which is not conducive to structural design and weight adjustment, the upper left area represents high strength but elastic coefficient It is also high, and its material is brittle, which makes the ball head easy to break. The upper right area represents high strength but low density. While maintaining high strength and toughness, it can also have a lower density and maintain the design and center of gravity. The flexibility of configuration. Compared with other materials, the embodiment of this case is located in the upper right area, that is, while maintaining high strength and high toughness, it can have a lower density, so it is beneficial to adjust the weight, and It can withstand the high-speed impact at the moment of hitting the ball and is suitable for making golf club heads.

表1 材料名稱 組成成分(%)   Al Cr Mo V Sn Zr Si Fe Ti 本實施例 7.6 2 2.5 1 - - 0.18 0.5 Bal. 6-4Ti 6 - - 4 - - - - Bal. Ti62222 6 2 2 - 2 2 - - Bal. T10 5 1 0.7 - - - - 1 Bal. 15-3-3-3 3 3 - 15 3 - - - Bal. SP700 4.5 - 2 3 - - - 2 Bal. DAT55G 4 6 - 16 - - - - Bal. TA15 6.5 - 1 1 - - - - Bal. Table 1 Material name Composition(%) Al Cr Mo V Sn Zr Si Fe Ti This embodiment 7.6 2 2.5 1 - - 0.18 0.5 Bal. 6-4Ti 6 - - 4 - - - - Bal. Ti62222 6 2 2 - 2 2 - - Bal. T10 5 1 0.7 - - - - 1 Bal. 15-3-3-3 3 3 - 15 3 - - - Bal. SP700 4.5 - 2 3 - - - 2 Bal. DAT55G 4 6 - 16 - - - - Bal. TA15 6.5 - 1 1 - - - - Bal.

表2 材料名稱 斷裂強度 (MPa) 密度 (g/cm) 降伏強度 (MPa) 延伸率 (%) 硬度 (HRC) 本實施例 1300 4.59 1200 10 43 6-4Ti 900 4.46 830 10 36 Ti62222 1150 4.66 1130 10 37 T10 1100 4.52 1048 13 33 15-3-3-3 1220 4.86 1100 10 41 SP700 1200 4.66 1050 10 40 DAT55G 830 4.85 770 26 20 TA15 1100 4.5 950 12 35 Table 2 Material name Breaking strength (MPa) Density (g/cm) Yield strength (MPa) Elongation (%) Hardness (HRC) This embodiment 1300 4.59 1200 10 43 6-4Ti 900 4.46 830 10 36 Ti62222 1150 4.66 1130 10 37 T10 1100 4.52 1048 13 33 15-3-3-3 1220 4.86 1100 10 41 SP700 1200 4.66 1050 10 40 DAT55G 830 4.85 770 26 20 TA15 1100 4.5 950 12 35

綜上所述,本發明的組成合金能在具備高強度及高韌性的同時,擁有相對較低的密度,不但能提升作為高爾夫球桿頭的耐用度,也能提高其結構設計及配重的自由度和機動性,故確實能達成本發明之目的。In summary, the alloy of the present invention can have high strength and high toughness, while having a relatively low density, not only can improve the durability as a golf club head, but also improve its structural design and weight The degree of freedom and mobility can indeed achieve the purpose of the invention.

惟以上所述者,僅為本發明之實施例而已,當不能以此限定本發明實施之範圍,凡是依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。However, the above are only examples of the present invention. When the scope of implementation of the present invention cannot be limited by this, all simple equivalent changes and modifications made in accordance with the scope of the patent application of the present invention and the content of the patent specification still belong to This invention patent covers the scope.

no

本發明之其它的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中: 圖1是一SEM圖,說明本發明凹爾夫球桿頭之組成合金的晶相;及 圖2是一散點圖,說明表1中的八種鈦合金之特性。 Other features and effects of the present invention will be clearly presented in the embodiments with reference to the drawings, in which: Fig. 1 is a SEM image illustrating the crystal phase of the alloy of the concave club head of the present invention; and Figure 2 is a scatter diagram illustrating the characteristics of the eight titanium alloys in Table 1.

Claims (2)

一種高爾夫球桿頭之組成合金,包含: 7.0wt%~8.0wt%的鋁、0.15~0.3wt%的矽、1.8wt%~2.2wt%的鉻、0.8wt%~1.2wt%的釩、2.3wt%~2.7wt%的鉬、0.3wt%~0.7wt%的鐵,其餘為不可避免的雜質及用以平衡且含量不為0的鈦。 A component alloy of golf club heads, including: 7.0wt%~8.0wt% aluminum, 0.15~0.3wt% silicon, 1.8wt%~2.2wt% chromium, 0.8wt%~1.2wt% vanadium, 2.3wt%~2.7wt% molybdenum, 0.3wt% %~0.7wt% of iron, the rest are unavoidable impurities and titanium that is used to balance and whose content is not zero. 如請求項1所述高爾夫球桿頭之組成合金,其中,矽的重量百分比為0.18wt%。The composition alloy of the golf club head according to claim 1, wherein the weight percentage of silicon is 0.18 wt%.
TW109100751A 2020-01-09 2020-01-09 Composition alloy of golf club head TWI704235B (en)

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CN202010205725.XA CN113215440A (en) 2020-01-09 2020-03-23 Alloy composition of golf club head

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CN115505785A (en) * 2021-06-03 2022-12-23 复盛应用科技股份有限公司 Golf club head alloy and manufacturing method of golf club head

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TW200714318A (en) * 2005-09-23 2007-04-16 Ming-Jui Chiang Low-density alloy for making a golf club head
TW200932920A (en) * 2008-01-16 2009-08-01 Advanced Int Multitech Co Ltd Titanium aluminum alloy applied in golf club head
TW201014918A (en) * 2008-10-09 2010-04-16 Univ Nat Pingtung Sci & Tech Low Cr-containing and high-strength Fe-based alloy for golf club head
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Publication number Priority date Publication date Assignee Title
TW200714318A (en) * 2005-09-23 2007-04-16 Ming-Jui Chiang Low-density alloy for making a golf club head
JP5287062B2 (en) * 2007-09-14 2013-09-11 大同特殊鋼株式会社 Low specific gravity titanium alloy, golf club head, and method for manufacturing low specific gravity titanium alloy parts
TW200932920A (en) * 2008-01-16 2009-08-01 Advanced Int Multitech Co Ltd Titanium aluminum alloy applied in golf club head
TW201014918A (en) * 2008-10-09 2010-04-16 Univ Nat Pingtung Sci & Tech Low Cr-containing and high-strength Fe-based alloy for golf club head
WO2013125038A1 (en) * 2012-02-24 2013-08-29 新日鐵住金株式会社 Titanium alloy for use in golf-club face
CN109154037A (en) * 2016-03-10 2019-01-04 钛金属公司 With improved high-temperature behavior and superplastic alpha-beta titanium alloy

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