TWI694522B - Microwave assisted parallel plate e-field applicator - Google Patents
Microwave assisted parallel plate e-field applicator Download PDFInfo
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本發明的實施例可以提供一種利用產業的微波加熱以及平行板反應來退火一例如是半導體的目標基板之退火系統及方法。 Embodiments of the present invention can provide an annealing system and method for annealing a target substrate, such as a semiconductor, using industrial microwave heating and parallel plate reaction.
在半導體裝置的小型化上的進步已經導致許多電子裝置有更佳的效能以及增大的儲存容量。在半導體裝置的製造中係牽涉到許多製程步驟。一步驟是半導體基板的摻雜以形成源極/汲極接面。離子植入係被用來藉由特定的摻雜物雜質到半導體晶圓表面中的植入,以修改該半導體基板的電性特徵。普遍使用的摻雜物是硼、砷以及磷。在離子植入的使用下,一種後退火處理是所要的,以完成活化製程並且修復任何對於經植入的區域相關的損壞。根據植入劑量(被植入在該表面中的原子的量)以及植入能量(原子進入該表面中的深度),各種的退火技術可被使用。例如,退火技術可包含爐處理、快速熱處理(RTP)、毫秒退火(MSA)以及包含雷射退火的各種其它的版本。然而,存在有和這些技術的每一個相關的缺點,即如同在美國專利號7,928,021中所敘述者,該美國專利係在此以其整體被納入作為參考。 Advances in miniaturization of semiconductor devices have led to many electronic devices having better performance and increased storage capacity. Many process steps are involved in the manufacture of semiconductor devices. One step is the doping of the semiconductor substrate to form the source/drain junction. Ion implantation is used to modify the electrical characteristics of the semiconductor substrate by implanting specific dopant impurities into the semiconductor wafer surface. Commonly used dopants are boron, arsenic and phosphorus. With the use of ion implantation, a post-annealing process is desired to complete the activation process and repair any damage related to the implanted area. Depending on the implantation dose (the amount of atoms implanted in the surface) and the implantation energy (depth of atoms entering the surface), various annealing techniques can be used. For example, annealing techniques may include furnace processing, rapid thermal processing (RTP), millisecond annealing (MSA), and various other versions including laser annealing. However, there are disadvantages associated with each of these technologies, namely, as described in US Patent No. 7,928,021, which is hereby incorporated by reference in its entirety.
對於此種退火製程利用微波加熱的實驗已經在固態裝置產業內被進行,但是微波加熱的使用係遭受到一些缺點。對於微波加熱而言, 一種多模式的反應室係被用來加熱/處理一目標基板,該目標基板係比所用的微波的波長相對大許多。在一種多模式的室內,該微波能量係透過模式激勵來耦合以管理該局部的微波場,其亦被稱為一電場(E-field)。該電場亦可能會受到在該多模式的室內之被加熱的目標基板的介電性質的影響。若目標基板是由一種具有適當的介電質之材料所做成的,則微波將會以較高的濃度流動至該目標基板。根據微波的電磁性質以及在該多模式的室內的目標基板的集膚效應,該目標基板根據其導電度而可以形成一穿過其或是在其表面上的電流流動。 Experiments using microwave heating for this annealing process have been conducted in the solid-state device industry, but the use of microwave heating suffers from some shortcomings. For microwave heating, A multi-mode reaction chamber is used to heat/process a target substrate, which is relatively larger than the wavelength of the microwave used. In a multi-mode room, the microwave energy is coupled through mode excitation to manage the local microwave field, which is also known as an electric field (E-field). The electric field may also be affected by the dielectric properties of the heated target substrate in the multi-mode chamber. If the target substrate is made of a material with an appropriate dielectric, the microwave will flow to the target substrate at a higher concentration. According to the electromagnetic properties of the microwave and the skin effect of the target substrate in the multi-mode room, the target substrate can form a current flow through or on its surface according to its electrical conductivity.
然而,電場濃度可能是難以監測及控制的。例如,若該電場的濃度是足夠強的,則其可能會造成與微波的介電質反應無關的非所要的熱失控及電弧,其可能會造成在該多模式的反應室內的目標基板之非均勻的加熱以及可能的損壞。攪拌器以及旋轉板已經被用來嘗試使得該電場更均勻,並且金屬箔層亦已經被用來改變被加熱的目標基板之局部的場能量。然而,這些方法的每一個都面臨到嘗試管理、最小化、或是消除渦電流的形成之挑戰,以避免傳統上因為渦電流的形成所造成之不均勻的加熱。 However, the electric field concentration may be difficult to monitor and control. For example, if the concentration of the electric field is strong enough, it may cause undesirable thermal runaway and arcs unrelated to the dielectric reaction of microwaves, which may cause non-target substrates in the multi-mode reaction chamber. Even heating and possible damage. Stirrers and rotating plates have been used to try to make the electric field more uniform, and metal foil layers have also been used to change the local field energy of the heated target substrate. However, each of these methods faces the challenge of trying to manage, minimize, or eliminate the formation of eddy currents to avoid the uneven heating traditionally caused by the formation of eddy currents.
另一種加熱該目標基板之方法是一種平行板反應器,其最普遍被使用於射頻(RF),此主要是由於在較高頻之技術上的限制之緣故。因此,該獨立的平行板反應器一般是受限於在該RF頻帶內的頻率,並且由於所用的波長而在該目標基板中產生一有限的反應。在習知技術中的RF加熱僅曾經被引入到固態市場作為一基體加熱器,而在加熱上相較於其它例如是紅外線與類似者的傳統的加熱方法並沒有真正的差異。 Another method of heating the target substrate is a parallel plate reactor, which is most commonly used in radio frequency (RF), mainly due to technical limitations in higher frequencies. Therefore, the independent parallel-plate reactor is generally limited to frequencies in the RF band, and due to the wavelength used, produces a limited response in the target substrate. RF heating in the conventional technology has only been introduced to the solid-state market as a matrix heater, and there is no real difference in heating compared to other traditional heating methods such as infrared and the like.
本發明的實施例係解決上述的問題,並且提供在退火半導體材料的技術中的顯著的進步。明確地說,本發明的實施例可以提供一種利用產業的微波加熱以及平行板反應來退火一例如是半導體的目標基板之退火系統及方法。 Embodiments of the present invention solve the aforementioned problems and provide significant advances in the technology of annealing semiconductor materials. Specifically, embodiments of the present invention can provide an annealing system and method for annealing a target substrate, such as a semiconductor, using industrial microwave heating and parallel plate reaction.
在本發明的某些實施例中,該退火系統可包含一均勻的微波場產生器;兩個被保持彼此接近及/或平行的板;以及一轉盤裝置,其係被耦接至在該均勻的微波場之內的該兩個板以及該目標基板。該均勻的微波場產生器可以產生一均勻的微波場,並且該兩個板可以在該均勻的微波場產生器之內被保持彼此間隔開一距離。明確地說,該些板可以被足夠靠近在一起地間隔開,以在該均勻的微波場之內的該些板之間形成一電容效應。該轉盤可以旋轉在該均勻的微波場之內的該些板以及該目標基板,此係在從該均勻的微波場被施加至該目標基板的微波的極性上產生一週期性的變化,藉此使得渦電流垂直於該些板以及該目標基板來流動。 In some embodiments of the invention, the annealing system may include a uniform microwave field generator; two plates held close to and/or parallel to each other; and a turntable device, which is coupled to the uniform The two plates within the microwave field and the target substrate. The uniform microwave field generator can generate a uniform microwave field, and the two plates can be kept spaced apart from each other within the uniform microwave field generator. In particular, the plates can be spaced sufficiently close together to create a capacitive effect between the plates within the uniform microwave field. The turntable can rotate the plates and the target substrate within the uniform microwave field, which produces a periodic change in the polarity of the microwave applied from the uniform microwave field to the target substrate, thereby The eddy current flows perpendicular to the plates and the target substrate.
本發明的另一實施例係包含一種用於退火半導體材料之方法,其係包含在一均勻的微波場之內將一由該半導體材料所做成的目標基板設置在兩個板之間,以及在從該均勻的微波場被施加至該目標基板的微波的極性上產生一週期性的變化。該週期性的變化係提供渦電流相對於該目標基板以及該些板之垂直的流動。 Another embodiment of the present invention includes a method for annealing semiconductor material, which includes placing a target substrate made of the semiconductor material between two plates in a uniform microwave field, and A periodic change occurs in the polarity of the microwave applied from the uniform microwave field to the target substrate. The periodic change provides vertical flow of eddy current relative to the target substrate and the plates.
在本發明的又一實施例中,一種用於退火半導體材料之方法係包含摻雜平行板,並且接著在一均勻的微波場之內將一由該半導體材料所做成的目標基板設置在該些平行板之間的步驟。該摻雜可以是足以使得該些平行板對該均勻的微波場起反應,並且該些平行板可以是足夠靠近在 一起地間隔開,以在該均勻的微波場之內的該些平行板之間形成一電容效應。該目標基板可包含被摻雜雜質的該半導體材料。該均勻的微波場可包含在一900MHz到26GHz的範圍內的頻率。接著,該方法可包含旋轉在該均勻的微波場之內的該些平行板以及目標基板的一步驟,藉此在從該均勻的微波場被施加至該目標基板的微波的極性上產生一週期性的變化。該週期性的變化可以提供渦電流相對於該目標基板以及該些平行板之垂直的流動,因此提供該目標基板的均勻的加熱以及選擇性地加熱在該目標基板中的缺陷。 In yet another embodiment of the present invention, a method for annealing semiconductor material includes doping parallel plates, and then disposing a target substrate made of the semiconductor material on the substrate within a uniform microwave field Between the parallel plates. The doping may be sufficient to allow the parallel plates to react to the uniform microwave field, and the parallel plates may be sufficiently close to They are spaced together to form a capacitive effect between the parallel plates within the uniform microwave field. The target substrate may contain the semiconductor material doped with impurities. The uniform microwave field may contain frequencies in the range of 900MHz to 26GHz. Next, the method may include a step of rotating the parallel plates and the target substrate within the uniform microwave field, thereby generating a period on the polarity of the microwave applied from the uniform microwave field to the target substrate Sexual changes. The periodic change can provide vertical flow of eddy currents relative to the target substrate and the parallel plates, thus providing uniform heating of the target substrate and selectively heating defects in the target substrate.
此發明內容係被提供來以一種簡化的形式介紹一些挑選出來的概念,該些概念係進一步在以下的詳細說明中加以敘述。此發明內容並不欲指明所主張的標的之關鍵特點或重要的特點、也不欲被用來限制所主張的標的之範疇。本發明的其它特點及優點從以下的實施方式以及所附的圖式來看將會是明顯的。 This summary of the invention is provided to introduce selected concepts in a simplified form, which are further described in the following detailed description. This summary of the invention is not intended to indicate the key features or important features of the claimed subject matter, nor is it intended to be used to limit the scope of the claimed subject matter. Other features and advantages of the present invention will be apparent from the following embodiments and accompanying drawings.
10‧‧‧退火系統 10‧‧‧Annealing system
12‧‧‧均勻的微波場產生器 12‧‧‧Uniform microwave field generator
14‧‧‧支撐元件 14‧‧‧Support element
16‧‧‧板 16‧‧‧ board
18‧‧‧轉盤裝置 18‧‧‧Turntable device
20‧‧‧目標基板 20‧‧‧Target substrate
22‧‧‧半導體層 22‧‧‧Semiconductor layer
24‧‧‧基座層 24‧‧‧Base
26‧‧‧表面電流(渦電流) 26‧‧‧Surface current (eddy current)
28‧‧‧矽晶格 28‧‧‧Silicon lattice
30‧‧‧缺陷 30‧‧‧ Defect
32‧‧‧微波 32‧‧‧Microwave
34‧‧‧內部的熱 34‧‧‧Internal heat
200‧‧‧方法 200‧‧‧Method
202、204、206、208‧‧‧區塊 202, 204, 206, 208‧‧‧
本發明的實施例係在以下參考所附的圖式被詳細地描述,其中:圖1是根據本發明的各種實施例所建構的一種退火系統的概要圖;圖2是一將在圖1的退火系統中被加熱之範例的目標基板的立體的概要視圖;圖3是另一將在圖1的退火系統中被加熱之範例的目標基板的立體的概要視圖;圖4是根據本發明的各種實施例的一種退火方法的流程圖; 圖5是針對於目標基板的不同的半導體材料之能帶間隙相對於基體遷移率的圖表;圖6是一進行習知技術傳統的微波加熱之目標基板的概要視圖,其中渦電流係集中在該目標基板的邊緣,並且實質平行於該目標基板的表面來流動;圖7是一在該兩個板之間的目標基板利用圖4的方法來進行遷移率退火的概要視圖,其中渦電流係垂直於該目標基板來流動;圖8是具有一於其中帶有一缺陷的矽晶格之一目標基板的概要視圖;圖9是圖8的目標基板進行習知技術傳統的微波加熱的概要視圖,其中渦電流是在該目標基板的表面以及平行於該表面來流動;以及圖10是圖8的目標基板利用圖4的方法來進行遷移率退火的概要視圖,其中渦電流係流入到該目標基板中並且與其為垂直的。 The embodiments of the present invention are described in detail below with reference to the accompanying drawings, in which: FIG. 1 is a schematic diagram of an annealing system constructed according to various embodiments of the present invention; FIG. 2 is a 3D schematic view of an example target substrate heated in an annealing system; FIG. 3 is a perspective view of another example target substrate to be heated in the annealing system of FIG. 1; FIG. 4 is a variety of A flowchart of an annealing method according to an embodiment; FIG. 5 is a graph of band gaps of different semiconductor materials with respect to the substrate mobility for the target substrate; FIG. 6 is a schematic view of a target substrate subjected to conventional microwave heating of a conventional technology, in which eddy currents are concentrated in the The edge of the target substrate, and flows substantially parallel to the surface of the target substrate; FIG. 7 is a schematic view of the target substrate between the two plates using the method of FIG. 4 for mobility annealing, wherein the eddy current is vertical 8 is a schematic view of a target substrate having a silicon lattice with a defect therein; FIG. 9 is a schematic view of a conventional microwave heating of the target substrate of FIG. Eddy current flows on the surface of the target substrate and parallel to the surface; and FIG. 10 is a schematic view of the target substrate of FIG. 8 using the method of FIG. 4 to perform mobility annealing, wherein the eddy current flows into the target substrate And perpendicular to it.
該圖式並未限制本發明至在此揭露及敘述的特定實施例。該圖式並不一定是按照比例的,而是強調於清楚地描繪本發明的原理。 The drawings do not limit the invention to the specific embodiments disclosed and described herein. This drawing is not necessarily to scale, but emphasizes clearly describing the principles of the present invention.
本發明之以下的詳細說明係參照所附的圖式,該圖式係描繪本發明可被實施於其中的特定實施例。該些實施例係欲以充分的細節來描述本發明的特點,以使得熟習此項技術者能夠實施本發明。其它實施例亦可被利用,並且可以在不脫離本發明的範疇下做出改變。因此,以下的詳細說明並非以限制性的意思視之。本發明的範疇僅藉由所附的申請專利範圍、以及此種申請專利範圍被授予的等同物之完整範疇來加以界定。 The following detailed description of the invention refers to the accompanying drawings, which depict specific embodiments in which the invention may be implemented. These embodiments are intended to describe the features of the present invention in sufficient detail to enable those skilled in the art to implement the present invention. Other embodiments can also be utilized, and changes can be made without departing from the scope of the present invention. Therefore, the following detailed description is not intended to be limiting. The scope of the present invention is only defined by the complete scope of the attached patent application scope and the equivalents granted by such patent application scope.
在此說明中,對於"一實施例"或是"多個實施例"的參照係表 示所論及的一或多個特點係內含在該技術的至少一實施例中。除非是如此陳述且/或除了熟習此項技術者從該說明來看將會是相當明顯的之外,否則在此說明中對於"一實施例"或是"多個實施例"之個別的參照並不一定是指相同的實施例,而且也不是互斥的。例如,在一實施例中敘述的一特點、結構、動作、等等亦可被納入在其它實施例中,但是並非必要被納入。因此,目前的技術可包含在此所述的實施例的各種組合及/或整合。 In this description, the reference frame for "one embodiment" or "multiple embodiments" The one or more features discussed are included in at least one embodiment of the technology. Unless so stated and/or except for those skilled in the art will be quite obvious from the description, individual references to "one embodiment" or "multiple embodiments" in this description It does not necessarily refer to the same embodiment, and it is not mutually exclusive. For example, a feature, structure, action, etc. described in one embodiment may also be included in other embodiments, but it is not necessary to be included. Therefore, the current technology may include various combinations and/or integrations of the embodiments described herein.
本發明的實施例係有關於退火系統。本發明的特定的實施例係有關於產業的微波加熱,其係利用一均勻的微波場以及平行板以控制渦電流至一目標基板20的施加。
The embodiment of the present invention relates to an annealing system. A specific embodiment of the present invention relates to industrial microwave heating, which utilizes a uniform microwave field and parallel plates to control the application of eddy current to a
如同在圖1中所繪的,本發明的一種退火系統10可包括一均勻的微波場產生器12、支撐元件14、兩個被保持彼此間隔開的關係之板16、以及一轉盤裝置18,其係被配置以在該均勻的微波場產生器12中之一均勻的微波場之內旋轉該兩個板16以及目標基板20。儘管在此係描述一組平行板16,但注意到的是,許多額外的板也可以垂直地堆疊以形成一批次反應(亦即,一次運作多個目標基板)。
As depicted in FIG. 1, an
該目標基板20可以是一種具有任何此項技術中已知的幾何之基板材料,例如是一半導體裝置、一經離子植入的晶圓、及/或一矽晶圓,並且可以具有一平坦的板或晶圓的幾何。例如,該目標基板20可以是一被摻雜特定的摻雜物雜質(例如,硼、砷、磷)以形成源極/汲極接面之半導體基板。在本發明的某些實施例中,該目標基板20可以是一電晶體,即如同在圖2及3中概要地描繪者。額外或替代的是,該目標基板20可包含複數個位於在此所述的板16之間的目標基板,例如是多個經離子植入的晶圓。該
目標基板20的一退火處理可被用來完成其之活化,並且修復任何對於經植入的區域之相關的損壞,即如同在以下詳細地敘述者。
The
該均勻的微波場產生器12可以是單一模式或是多模式的室、或是可以替代地包含一波導埠,其係被配置以用於在以下所述的板16周圍及/或之間形成一微波場。在本發明的某些實施例中,藉由該均勻的微波場產生器12所產生的微波頻率範圍可以是在一大約900MHz到26GHz的範圍內。例如,藉由該微波場產生器12所產生的頻率可以是約915MHz、約2.45GHz、或是約5.8GHz或24GHz。然而,該均勻的微波場產生器12可被配置以產生任何所要的微波頻率,而不脫離本發明的範疇。在本發明的某些實施例中,藉由該均勻的微波場產生器12所產生的熱可以是在一大約400℃到800℃的範圍內。然而,其它溫度亦可被使用,而不脫離本發明的範疇。
The uniform
該些支撐元件14可以是由一種例如是石英的絕緣體材料所做成的,並且可被配置以用於保持及/或支撐該些板16以及目標基板20。例如,該些支撐元件14可被固定到該轉盤裝置18的一旋轉元件。或者是,該些支撐元件14可以附接至該均勻的微波場產生器12之內壁或是其它部分。再者,該些支撐元件14可包括槽、夾箝、或是其它配置,以用於將該些板16以及目標基板20固定在彼此相隔預先定義的距離處。在本發明的某些實施例中,該些支撐元件14可以是選擇性地可調整的,使得不同的間隔可被使用於具有不同的幾何及/或不同的材料之不同的板16及/或不同的目標基板20。
The
該些板16可以是彼此實質平行的,並且分別可包含一半導
體層22以及一基座(susceptor)層24。該基座層24可被設置為最靠近該目標基板20的,其中該些半導體層22的每一個係從該兩個基座層24面向外的。然而,在本發明的某些實施例中,該基座層24可被省略。
The
該半導體層22可被配置以在較低的溫度下作用為一介電質,並且在較高的溫度下作用為一金屬。因此,該半導體層22係隨著在溫度上的增加而在導電度上增加,此係產生一電容場以在該兩個半導體層22之間產生一電容電場平面。因此,該些板16係合作地作用為一平行板電容器。然而,在本發明的某些實施例中,該半導體層22或者是可以被一由金屬所做成、或是其它在溫度增加時變成導電的此種導電材料的導體層所取代,只要此種金屬以及其它材料如同在此所述的被加熱時是落在一能夠載有一表面電流流動的導電度範圍內即可。
The
該些基座層24可被用來預先加熱位在兩者之間的目標基板20。明確地說,該些基座層24可以是由被配置以吸收該微波的材料所做成的,並且因此在兩者之間合作地產生一均勻的微波場。然而,在本發明的某些替代的實施例中,若該均勻的微波場是以另外的方式被產生在該兩個半導體層22之間及/或周圍,則該些基座層24可被省略。
The pedestal layers 24 can be used to pre-heat the
該些板16可以具有任何此項技術中已知的尺寸及幾何。在本發明的某些實施例中,該些板16可以是碟狀、方形、或是矩形。再者,該些板16可以是薄的平坦碟片,其係具有一大致相關於在該固態產業中的一板或是碟片之厚度。該些板16可以具有彼此相隔一約0.5mm到約5mm的間隔。該些板16較佳的可以是盡可能薄的,只要不薄到在安裝於該些支撐元件14上時、及/或在該均勻的微波場產生器12之內被加熱時犧牲到其
結構的完整性即可。在本發明的某些實施例中,該些板16可以是間隔開大約1mm到10mm。然而,其它間隔的距離亦可被使用,而不脫離本發明的範疇。明確地說,該些板16應該被足夠靠近在一起地間隔開以形成一電容效應,並且因此是足夠靠近以讓該表面電流(亦即,渦電流)來反應,即如同在此所述者。
The
在本發明的某些實施例中,該些板16在該均勻的微波場之內可被設置在任何朝向上,例如是水平的、垂直的、或者是其它朝向。該些板16通常可以相對於彼此的平行朝向來加以配置。然而,在本發明的某些替代的實施例中,該些板16可以用彼此且/或與該目標基板20非平行的關係來加以設置,只要該些板16是足夠靠近以形成在此所述的電容效應即可。
In some embodiments of the present invention, the
該轉盤裝置18可以是此項技術中已知用於產生附接至其的物品的旋轉的任何機構。例如,該轉盤裝置18可包含一位在該均勻的微波場產生器的外部的旋轉馬達。再者,上述的支撐元件14中之一可以附接至該旋轉馬達的一旋轉軸,並且可以延伸到該均勻的微波場產生器12中,以將該些板16及/或目標基板20可旋轉地支撐在所要的位置以及彼此所要的間隔處。在該均勻的微波場之內,該兩個板16以及目標基板20的旋轉可以改變被施加至其的微波的極性,此係模擬習知技術的方法的RF切換。例如,該退火系統10可被配置成使得該目標基板20的旋轉可以每15°改變被施加至其的微波的極性。其它切換該微波極性的方法可以替代地被使用,而不脫離本發明的範疇。
The
該轉盤裝置18可被配置以用於任何並不會造成該些板16及
/或目標基板20的分離之速率。在本發明的某些實施例中,該轉盤裝置18可以在每分鐘一轉(rpm)的一最小的速率以及一10rpm的最大的速率下旋轉該些板16及/或目標基板20。例如,該轉盤裝置18可以在一大約2rpm的速率下旋轉該些板16及/或目標基板20。然而,其它速率亦可被使用,而不脫離本發明的範疇。
The
在使用中,該目標基板20可以在該均勻的微波場產生器12之內被置放在該些板16之間,並且在該均勻的微波場之內藉由該轉盤裝置18來加以旋轉,因此在被施加至該目標基板20的微波的極性上產生一週期性的變化。該目標基板20將會主要根據其本身的介電性質而被加熱,其係轉換該微波成為熱,且/或在該目標基板20的表面上產生渦電流。如同在以下敘述的,該渦電流係以垂直於該些板16來流動作為反應,其係均勻地加熱該目標基板20。在本發明的某些實施例中,該些板16可能需要摻雜,以對該均勻的微波場起反應。
In use, the
圖4是描繪根據本發明的各種實施例的在一種用於利用一均勻的微波場以及平行板反應來退火半導體材料之方法200中的步驟。該方法200的步驟可以用如同在圖4中所示的順序來加以執行、或是它們可以用一不同的順序而被執行。再者,相對於依序地執行,某些步驟可以同時加以執行。此外,某些步驟可以不被執行。該些步驟中的某些個可以代表上述的電腦程式或應用程式之碼區段或是可執行的指令。
FIG. 4 depicts the steps in a
在本發明的某些實施例中,如同在區塊202中所繪的,該方法200可包含摻雜該些板16以對該均勻的微波場起反應的一步驟。例如,在室溫的本質矽可能主要是微波通透的,因而可被摻雜以對該微波電場起
反應。摻雜該矽材料可以改變在室溫的導電度,因此容許微波能夠在室溫加熱/與該些矽氧樹脂(silicone)平行板起反應。在此例子中,一旦該些矽氧樹脂板被加熱後,其之導電度可以根據該外來的矽材料的一能帶間隙而減低。一描繪各種材料的能帶間隙以及其基體遷移率的圖係在圖5中提供。此在導電度上的減低可以達成一微波反應/貫穿,並且當該溫度或是導電度在範圍內時,其係在一微波場內產生一平行板電場。在此所述的平行板電場內,產生自一微波反應的渦電流將會垂直於該目標基板20來流動(如同在圖10中所繪),而不是按照傳統的金屬的微波反應而平行於該表面來流動(如同在圖9中所繪)。
In some embodiments of the invention, as depicted in
在本發明的某些實施例中,如同在區塊204中所繪的,該方法200可以選配地包含根據用於該些板以及目標基板中的至少一個的幾何及材料來調整在該些板16之間的一距離的一步驟。例如,如上所述,該些支撐元件14可以是選擇性地可調整的,使得不同的間隔可被使用於具有不同的幾何及/或不同的材料之不同的板16及/或不同的目標基板20。
In some embodiments of the present invention, as depicted in
如同在區塊206中所繪的,該方法200可以進一步包含在該均勻的微波場(例如,多模式的室)之內將該目標基板20設置在該些板16之間的一步驟。如上所述,該些板16彼此間的間隔可以是約0.5mm到約5mm或10mm。如上所述,該目標基板20以及該些板16可以藉由一種例如是石英的絕緣體材料所做成的支撐元件14來加以懸吊及支承。
As depicted in
接著,如同在區塊208中所繪的,該方法200可包含在該均勻的微波場之內,利用該轉盤裝置18來旋轉該些板16及/或該目標基板20的一步驟,因此在被施加至該目標基板20的微波的極性上產生一週期性的
變化。該目標基板20將會主要根據其本身的介電性質而被加熱,此係轉換該微波成為熱,且/或在該目標基板20的表面上產生渦電流。傳統上,如同在圖6中所繪,表面電流或渦電流26係被形成在一微波場之內的一平坦的板及/或該目標基板20的邊緣或邊界處。然而,如同在圖7中所繪,在此揭露的旋轉板的配置係提供渦電流26相對於該目標基板20之垂直的流動,此係產生其之均勻的加熱、以及如同在圖10中所繪的選擇性地加熱在該目標基板20的矽晶格中的缺陷。相反地,傳統的加熱方法(例如是在圖9中描繪之簡單的微波加熱)並未選擇性地加熱在該些矽晶格之內的缺陷。
Then, as depicted in
明確地說,圖8是概要地描繪該目標基板20,其中一矽晶格28係具有一缺陷30,此亦以一具有遷移率縮減的區域著稱。圖9是描繪同一矽晶格28僅藉由微波32而被加熱,其中所產生的渦電流26係平行於該目標基板20來流動。圖9亦描繪在該矽晶格28中藉由該微波32所產生的內部的熱34。
Specifically, FIG. 8 is a schematic depiction of the
圖10係描繪該矽晶格28是經由上述且在圖4中描繪的方法200而被加熱,其中所產生的內部的熱34係進一步經由垂直地流入該目標基板20的渦電流26而在體積上針對其中的缺陷30。該渦電流26的改變方向係容許介面的極化能夠發生在該目標基板20中的其中該渦電流26被禁止的選擇的點之處(例如,晶粒缺陷、雜質、以及其它缺陷30)。該缺陷30的極化在本身中可能不會造成一實質的反應,但是現在極化的缺陷30亦遭受到早已存在的微波場(例如,微波32),此係容許該缺陷30能夠"選擇性地"被加熱。此係表示相較於該目標基板20(在此亦被稱為基體材料)的其餘部分,該缺陷30的溫度將會高出許多的。此基體材料可以作用為一散熱器,
其係耗散在該目標基板20的基體材料內的熱。
FIG. 10 depicts that the
因此,在此所述的加熱方法200係完成一活化製程,並且修復任何相關該目標基板20的經植入或摻雜的區域之損壞,而無習知技術的微波退火方法之非所要的熱失控及電弧。有利的是,其並非是如同在習知技術的微波方法中嘗試管理、最小化、或是消除渦電流的形成,而是本發明改變所產生的渦電流流動所在的方向,藉此避免不均勻的加熱並且有效地修復在該目標基板20中的缺陷。
Therefore, the
儘管本發明已經參考在所附的圖式中描繪的實施例來加以敘述,但應注意的是在此可以採用等同物並且做成替換,而不脫離如同在申請專利範圍中所闡述的本發明的範疇。 Although the present invention has been described with reference to the embodiments depicted in the accompanying drawings, it should be noted that equivalents and substitutions can be used here without departing from the invention as set forth in the scope of the patent application Category.
至此已經敘述本發明的各種實施例,所主張為新穎而且希望受到專利證書保護者係包含以下: So far, various embodiments of the present invention have been described. Those who claim to be novel and wish to be protected by patent certificates include the following:
10‧‧‧退火系統 10‧‧‧Annealing system
12‧‧‧均勻的微波場產生器 12‧‧‧Uniform microwave field generator
14‧‧‧支撐元件 14‧‧‧Support element
16‧‧‧板 16‧‧‧ board
18‧‧‧轉盤裝置 18‧‧‧Turntable device
20‧‧‧目標基板 20‧‧‧Target substrate
22‧‧‧半導體層 22‧‧‧Semiconductor layer
24‧‧‧基座層 24‧‧‧Base
Claims (20)
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US7928021B2 (en) * | 2007-09-17 | 2011-04-19 | Dsgi, Inc. | System for and method of microwave annealing semiconductor material |
US20120034846A1 (en) * | 2010-08-04 | 2012-02-09 | Gaku Minamihaba | Semiconductor device manufacturing method |
US20120196453A1 (en) * | 2011-02-01 | 2012-08-02 | Arizona Board Of Regents For And On Behalf Of Arizona State University | Systems and Methods for Susceptor Assisted Microwave Annealing |
WO2013129037A1 (en) * | 2012-02-27 | 2013-09-06 | 東京エレクトロン株式会社 | Microwave heat-treatment device and treatment method |
US20140073065A1 (en) * | 2012-09-12 | 2014-03-13 | Kabushiki Kaisha Toshiba | Microwave annealing apparatus and method of manufacturing a semiconductor device |
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US7928021B2 (en) * | 2007-09-17 | 2011-04-19 | Dsgi, Inc. | System for and method of microwave annealing semiconductor material |
US20120034846A1 (en) * | 2010-08-04 | 2012-02-09 | Gaku Minamihaba | Semiconductor device manufacturing method |
US20120196453A1 (en) * | 2011-02-01 | 2012-08-02 | Arizona Board Of Regents For And On Behalf Of Arizona State University | Systems and Methods for Susceptor Assisted Microwave Annealing |
WO2013129037A1 (en) * | 2012-02-27 | 2013-09-06 | 東京エレクトロン株式会社 | Microwave heat-treatment device and treatment method |
US20140073065A1 (en) * | 2012-09-12 | 2014-03-13 | Kabushiki Kaisha Toshiba | Microwave annealing apparatus and method of manufacturing a semiconductor device |
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