TWI692405B - Flame-retardant water proof fabric and manufacturing method thereof - Google Patents

Flame-retardant water proof fabric and manufacturing method thereof Download PDF

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TWI692405B
TWI692405B TW108100553A TW108100553A TWI692405B TW I692405 B TWI692405 B TW I692405B TW 108100553 A TW108100553 A TW 108100553A TW 108100553 A TW108100553 A TW 108100553A TW I692405 B TWI692405 B TW I692405B
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flame
weight
parts
retardant
fabric
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TW108100553A
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TW202026165A (en
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許秉叡
徐正己
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厚生股份有限公司
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Abstract

The prevent invention discloses a flame-retardant waterproof fabric including a base fabric and a polyamidamine layer, wherein the base fabric denier is between 70 and 200D, and the polyamidamine layer includes 100 parts by weight of polyurethane resin, 10 to 15 parts by weight of flame retardant, 0.5 to 2 parts by weight of catalyst, 2 to 5 parts by weight of crosslinking agent, and 10 to 100 parts by weight of solvent. The prevent invention further discloses a method for manufacturing a flame-retardant waterproof fabric, including: mixing a polyamidamide compound mixture, coating a polyamidamide compound mixture on one side of a base fabric by a floating knife coater to obtain a polyamidamine layer, and heating and drying the polyamidamine layer. The present invention provides a lighter and thinner flame-retardant waterproof fabric, having water pressure 5000mmH2O and stable flame retardancy by one time coating.

Description

阻燃防水織物及其製造方法 Flame retardant waterproof fabric and its manufacturing method

本發明涉及一種織物及其製造方法,特別是涉及一種阻燃防水織物及其製造方法。 The invention relates to a fabric and a manufacturing method thereof, in particular to a flame-retardant and waterproof fabric and a manufacturing method thereof.

現有技術的阻燃防水織物加工方法是使用浮刀式裱糊加工織物,提供織物特定性能,而浮刀式裱糊加工主要分為接著層加工與面層加工,因此,必須進行兩刀塗佈,才能達到所預期的阻燃防水效果。 The processing method of the flame retardant waterproof fabric in the prior art is to use floating knife type paper processing fabric to provide specific properties of the fabric, and the floating knife type paper processing is mainly divided into subsequent layer processing and surface layer processing, therefore, two knife coating must be carried out in order to Achieve the expected flame retardant and waterproof effect.

然而,近年來,輕量化已成為目前織物的主要訴求,顧,如何透過設計改良,來提升阻燃防水織物的輕量化,並維持阻燃防水能力,已成為該項事業所欲解決的重要課題之一。 However, in recent years, light weight has become the main demand of fabrics at present. Gu, how to improve the weight of flame retardant and waterproof fabrics through design improvements and maintain the flame retardant and waterproof ability has become an important issue to be solved by this business. one.

本發明所要解決的技術問題在於,針對現有技術的不足提供一種阻燃防水織物及其製造方法。 The technical problem to be solved by the present invention is to provide a flame-retardant waterproof fabric and a manufacturing method thereof in view of the deficiencies of the prior art.

為了解決上述的技術問題,本發明所採用的其中一技術方案是,提供一種阻燃防水織物,其包括:一基布,所述基布丹尼數是介於70至200D之間;以及一聚醯胺層,其設置於所述基布上;其中,所述聚醯胺層包含100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑。 In order to solve the above technical problems, one of the technical solutions adopted by the present invention is to provide a flame-retardant waterproof fabric, which includes: a base fabric, the base fabric Danny number is between 70 and 200D; and a A polyamide layer, which is provided on the base fabric; wherein, the polyamide layer comprises 100 parts by weight of a polyamide resin, 10 to 15 parts by weight of a flame retardant, 0.5 to 2 parts by weight of a catalyst, 2 to 5 parts by weight of crosslinking agent and 10 to 100 parts by weight of solvent.

為了解決上述的技術問題,本發明所採用的另外一技術方案是,提供一種阻燃防水織物的製造方法,其包括:(a)混合一聚醯胺膠料,所述聚醯胺膠料包括100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑;(b)以浮刀式裱糊機塗佈所述聚醯胺膠料於一基布的其中一面,以形成一聚醯胺層;以及(c)加熱乾燥所述聚醯胺層,以得到所述阻燃防水織物。 In order to solve the above technical problems, another technical solution adopted by the present invention is to provide a method for manufacturing a flame-retardant waterproof fabric, which includes: (a) mixing a polyamido compound, the polyamido compound includes 100 parts by weight of polyamide resin, 10 to 15 parts by weight of flame retardant, 0.5 to 2 parts by weight of catalyst, 2 to 5 parts by weight of crosslinking agent, and 10 to 100 parts by weight of solvent; (b) to float A knife-type pasting machine coats the polyamide compound on one side of a base fabric to form a polyamide layer; and (c) heat drying the polyamide layer to obtain the flame-retardant waterproof fabric .

本發明的其中一有益效果在於,本發明所提供的阻燃防水織物及其製作方法,其能通過“所述基布丹尼數是介於70至200D之間”以及“聚醯胺層包含100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑”的技術方案,以得到更輕薄的阻燃防水織物,且一刀塗佈即可達到水壓5000mmH2O的防水性效果,並提升阻燃穩定性。 One of the beneficial effects of the present invention is that the flame-retardant and waterproof fabric provided by the present invention and the manufacturing method thereof can pass the "the base cloth Danni number is between 70 and 200D" and "polyamide layer contains "100 parts by weight of polyamide resin, 10 to 15 parts by weight of flame retardant, 0.5 to 2 parts by weight of catalyst, 2 to 5 parts by weight of crosslinking agent and 10 to 100 parts by weight of solvent" technical solution, to A lighter and thinner flame-retardant waterproof fabric is obtained, and the water-repellent effect of the water pressure of 5000mmH 2 O can be achieved by one-pass coating, and the flame retardant stability is improved.

為使能更進一步瞭解本發明的特徵及技術內容,請參閱以下有關本發明的詳細說明與圖式,然而所提供的圖式僅用於提供參考與說明,並非用來對本發明加以限制。 In order to further understand the features and technical contents of the present invention, please refer to the following detailed description and drawings of the present invention. However, the drawings provided are for reference and explanation only, and are not intended to limit the present invention.

F:阻燃防水織物 F: Flame retardant waterproof fabric

1:基布 1: base cloth

2:聚醯胺層 2: Polyamide layer

圖1為本發明一實施例的阻燃防水織物的示意圖。 FIG. 1 is a schematic diagram of a flame retardant waterproof fabric according to an embodiment of the invention.

圖2為本發明一實施例的阻燃防水織物的製造方法的流程圖。 2 is a flowchart of a method for manufacturing a flame-retardant waterproof fabric according to an embodiment of the invention.

以下是通過特定的具體實施例來說明本發明所公開有關“阻燃防水織物及其製造方法”的實施方式,本領域技術人員可由本說明書所公開的內容瞭解本發明的優點與效果。本發明可通過其他不同的具體實施例加以施行或應用,本說明書中的各項細節也可基於不同觀點與應用,在不悖離本發明的構思下進行各種修改 與變更。另外,本發明的附圖僅為簡單示意說明,並非依實際尺寸的描繪,事先聲明。以下的實施方式將進一步詳細說明本發明的相關技術內容,但所公開的內容並非用以限制本發明的保護範圍。 The following are specific specific examples to illustrate the implementation of the "flame retardant waterproof fabric and its manufacturing method" disclosed by the present invention. Those skilled in the art can understand the advantages and effects of the present invention from the content disclosed in this specification. The present invention can be implemented or applied through other different specific embodiments. The details in this specification can also be based on different views and applications, and various modifications can be made without departing from the concept of the present invention. And change. In addition, the drawings of the present invention are merely schematic illustrations, and are not drawn according to actual sizes, and are declared in advance. The following embodiments will further describe the related technical content of the present invention, but the disclosed content is not intended to limit the protection scope of the present invention.

應理解,雖然本文中可能使用術語第一、第二、第三等來描述各種元件或者信號,但這些元件或者信號不應受這些術語的限制。這些術語主要是用以區分一元件與另一元件,或者一信號與另一信號。另外,本文中所使用的術語“或”,應視實際情況可能包括相關聯的列出項目中的任一個或者多個的組合。 It should be understood that although the terms first, second, third, etc. may be used herein to describe various elements or signals, these elements or signals should not be limited by these terms. These terms are mainly used to distinguish one component from another component, or one signal from another signal. In addition, the term "or" as used herein may include any combination of any one or more of the associated listed items, depending on the actual situation.

請參閱圖1所示,圖1為本發明的阻燃防水織物的示意圖。由上述圖中可知,本發明的阻燃防水織物F包括:基布1以及聚醯胺層2設置於基布1上。具體而言,基布1的丹尼數是介於70至200D之間,而聚醯胺層2包含100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑。 Please refer to FIG. 1, which is a schematic diagram of the flame-retardant and waterproof fabric of the present invention. As can be seen from the above figures, the flame-retardant and waterproof fabric F of the present invention includes the base fabric 1 and the polyamide layer 2 disposed on the base fabric 1. Specifically, the Danny number of the base cloth 1 is between 70 and 200D, and the polyamide layer 2 includes 100 parts by weight of the polyamide resin, 10 to 15 parts by weight of the flame retardant, and 0.5 to 2 parts by weight. Parts of catalyst, 2 to 5 parts by weight of crosslinking agent, and 10 to 100 parts by weight of solvent.

具體來說,基布1的丹尼數是介於70至200D之間,若丹尼數太高則阻燃效果不佳,基布1可以選自聚酯布、尼龍布、棉布、聚酯尼龍混紡紗布之至少一者,且基布可以是平織布、橫紋、格子布、斜紋布、緹花布、N/T交織布、色紗交織布、塔夫塔、牛津布或緞紋布。然而,本發明的基布層1的種類及材料不在此限制。 Specifically, the Danny number of the base fabric 1 is between 70 and 200D. If the Danny number is too high, the flame retardant effect is not good. The base fabric 1 can be selected from polyester cloth, nylon cloth, cotton cloth, polyester At least one of nylon blended gauze, and the base fabric can be plain weave, horizontal weave, plaid, twill, jacquard, N/T interwoven, colored yarn interwoven, taffeta, oxford or satin . However, the types and materials of the base fabric layer 1 of the present invention are not limited thereto.

更詳細來說,聚醯胺層2為一單層結構,相較於現有技術需要以接著層以及面層的兩刀塗佈有所不同,僅需要一刀塗佈即可附著於基布上。 In more detail, the polyamide layer 2 has a single-layer structure. Compared with the prior art, the two-layer coating of the adhesive layer and the surface layer is different, and it only needs one-layer coating to be attached to the base fabric.

聚醯胺層2的組份中,聚醯胺樹脂是1.5液型聚醯胺樹脂,且具有疏水性官能基,如長鏈-CH2-疏水鏈,舉例而言,疏水性官能基可以是C10至C20的烴基、含有雙鍵的烴基、含有芳基、酯基、醚基、胺基或醯胺基團的烴基。較佳地,阻燃劑包括三氧化二銻 以及十溴二苯乙烷,且其比例是介於1:3,使用介於上述比例範圍內的阻燃劑(十溴二苯乙烷)與助阻燃劑(三氧化二銻),可以獲得最佳的阻燃效果。催化劑可採用有機系列及無機系列,交聯劑可為帶有NCO官能基的樹脂,可提供較佳的防水性以及抗老化特性。 Among the components of the polyamide layer 2, the polyamide resin is a 1.5-liquid type polyamide resin, and has a hydrophobic functional group, such as a long-chain -CH 2 -hydrophobic chain. For example, the hydrophobic functional group may be C10 to C20 hydrocarbon group, double bond-containing hydrocarbon group, aryl group, ester group, ether group, amine group or amide group. Preferably, the flame retardant includes antimony trioxide and decabromodiphenylethane, and the ratio is between 1:3, using a flame retardant (decabromodiphenylethane) within the range of the above ratio The auxiliary flame retardant (antimony trioxide) can obtain the best flame retardant effect. The catalyst can use organic series and inorganic series, the crosslinking agent can be a resin with NCO functional group, which can provide better waterproof and anti-aging characteristics.

另外,除了上述組分之外,也可依據實際需求加入其他種類的添加劑,例如:軟化油、色料等等。舉例而言,在加入色料(例如染料或顏料)可呈現所欲的顏色,以符合特殊用途或增加美觀性。 In addition, in addition to the above components, other types of additives can also be added according to actual needs, such as: softening oil, colorants, etc. For example, the addition of colorants (such as dyes or pigments) can show the desired color to meet special purposes or increase aesthetics.

請進一步參閱圖2,圖2為本發明阻燃防水織物的製造方法的流程圖,其包括:步驟S100混合聚醯胺膠料;步驟S200以浮刀式裱糊機塗佈所述聚醯胺膠料於基布的其中一面,以形成聚醯胺層;步驟S300加熱乾燥聚醯胺層,得到本發明的阻燃防水織物。 Please further refer to FIG. 2. FIG. 2 is a flowchart of a method for manufacturing a flame-retardant waterproof fabric of the present invention, which includes: step S100 mixing a polyamide compound; step S200 coating the polyamide glue with a floating knife type laminating machine It is prepared on one side of the base fabric to form a polyamide layer; in step S300, the polyamide layer is heated and dried to obtain the flame-retardant waterproof fabric of the present invention.

具體而言,於步驟S100混合聚醯胺膠料中,聚醯胺膠料包括100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑。而步驟S100的混合溫度不可超過催化劑以及交聯劑的分解溫度,較佳是介於40至80℃之間,混合時間是介於15至25分鐘。 Specifically, in the mixed polyamide compound in step S100, the polyamide compound includes 100 parts by weight of the polyamide resin, 10 to 15 parts by weight of the flame retardant, 0.5 to 2 parts by weight of the catalyst, and 2 to 5 parts by weight of crosslinking agent and 10 to 100 parts by weight of solvent. The mixing temperature in step S100 cannot exceed the decomposition temperature of the catalyst and the crosslinking agent, preferably between 40 and 80°C, and the mixing time is between 15 and 25 minutes.

詳細來說,步驟S100混合聚醯胺膠料,較佳是將阻燃劑先進行研磨,再加入混合的聚醯胺膠料,以達到較佳的分散性。 In detail, in step S100, the polyamide compound is mixed, preferably the flame retardant is first ground, and then the mixed polyamide compound is added to achieve better dispersibility.

於本發明的一實施例中,基布是經過壓光處理(Calendaring)的基布,且壓光處理的溫度是介於140至160℃之間,壓力是50公斤/平方公尺,速度是25公尺/分鐘。經過壓光處理的基布,可提高平整度,有益於聚醯胺膠料以浮刀式裱糊的平整性。 In an embodiment of the present invention, the base fabric is a calendar-treated base fabric, and the temperature of the calendering is between 140 and 160°C, the pressure is 50 kg/m², and the speed is 25 meters/minute. The calendered base fabric can improve the flatness, which is beneficial to the flatness of the polyamide compound with the floating knife.

於步驟S200中,相較於現有技術需要以接著層以及面層的兩刀塗佈,本發明步驟S200的聚醯胺膠料以浮刀式裱糊機一次塗佈方式形成於所述基布上,且塗佈量是80克/碼。 In step S200, as compared with the prior art, which requires two-layer coating of the adhesive layer and the surface layer, the polyamide compound of step S200 of the present invention is formed on the base fabric by a floating knife-type laminator in a one-time coating method , And the coating amount is 80 g/yard.

於步驟S300中,加熱乾燥聚醯胺層的溫度是介於80至150℃之間,加熱時間是介於30至120秒。 In step S300, the temperature of heating and drying the polyamide layer is between 80 and 150°C, and the heating time is between 30 and 120 seconds.

[實施例的有益效果] [Beneficial effect of embodiment]

本發明的其中一有益效果在於,本發明所提供的阻燃防水織物及其製作方法,其能通過“所述基布丹尼數是介於70至200D之間”以及“聚醯胺層包含100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑”的技術方案,以得到更輕薄的阻燃防水織物,且一刀塗佈即可達到水壓5000mm H2O的防水性效果,並提升阻燃穩定性。 One of the beneficial effects of the present invention is that the flame-retardant and waterproof fabric provided by the present invention and the manufacturing method thereof can pass the "the base cloth Danni number is between 70 and 200D" and "polyamide layer contains "100 parts by weight of polyamide resin, 10 to 15 parts by weight of flame retardant, 0.5 to 2 parts by weight of catalyst, 2 to 5 parts by weight of crosslinking agent and 10 to 100 parts by weight of solvent" technical solution, to A lighter and thinner flame-retardant waterproof fabric is obtained, and the water-repellent effect of the water pressure of 5000 mm H 2 O can be achieved by one-pass coating, and the flame retardant stability is improved.

更進一步來說,現有技術的浮刀式裱糊機塗佈聚醯胺膠料需要兩刀塗佈才可達到水壓5000mm H2O的防水性效果,本發明的阻燃防水織物一刀即可達到,因此,省略了現有技術兩刀塗佈的接著層,可減少阻燃防水織物每平方5至10克的重量,有效降低成本,提高生產速率,並提供輕量化及優異的防水阻燃性能。 Furthermore, the prior art floating knife-type laminating machine coated with polyamide compound needs two coatings to achieve the water resistance of 5000mm H 2 O. The flame retardant waterproof fabric of the present invention can be achieved with one knife Therefore, the omission of the two-coating adhesive layer of the prior art can reduce the weight of the flame retardant waterproof fabric by 5 to 10 grams per square, effectively reduce the cost, increase the production rate, and provide lightweight and excellent waterproof flame retardant performance.

以上所公開的內容僅為本發明的優選可行實施例,並非因此侷限本發明的申請專利範圍,所以凡是運用本發明說明書及圖式內容所做的等效技術變化,均包含於本發明的申請專利範圍內。 The content disclosed above is only a preferred and feasible embodiment of the present invention, and therefore does not limit the scope of the patent application of the present invention, so any equivalent technical changes made by using the description and drawings of the present invention are included in the application of the present invention. Within the scope of the patent.

F:阻燃防水織物 F: Flame retardant waterproof fabric

1:基布 1: base cloth

2:聚醯胺層 2: Polyamide layer

Claims (10)

一種阻燃防水織物,其包括:一基布,所述基布丹尼數是介於70至200D之間;以及一聚醯胺層,其設置於所述基布上;其中,所述聚醯胺層包含100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑。 A flame-retardant waterproof fabric, comprising: a base fabric with a Danny number between 70 and 200D; and a polyamide layer disposed on the base fabric; wherein, the poly The amide layer contains 100 parts by weight of a polyamide resin, 10 to 15 parts by weight of a flame retardant, 0.5 to 2 parts by weight of a catalyst, 2 to 5 parts by weight of a crosslinking agent, and 10 to 100 parts by weight of a solvent. 如請求項1所述的阻燃防水織物,其中,所述聚醯胺層為一單層結構。 The flame-retardant and waterproof fabric according to claim 1, wherein the polyamide layer is a single-layer structure. 如請求項1所述的阻燃防水織物,其中,所述聚醯胺樹脂是1.5液型聚醯胺樹脂,且具有疏水性官能基。 The flame-retardant and waterproof fabric according to claim 1, wherein the polyamide resin is a 1.5-liquid type polyamide resin and has a hydrophobic functional group. 如請求項1所述的阻燃防水織物,其中,所述基布是一經過壓光處理的基布,且所述基布是選自聚酯布、尼龍布、棉布、聚酯尼龍混紡紗布之至少一者。 The flame-retardant and waterproof fabric according to claim 1, wherein the base fabric is a calendered base fabric, and the base fabric is selected from polyester fabric, nylon fabric, cotton fabric, polyester nylon blended yarn fabric At least one of them. 如請求項1所述的阻燃防水織物,其中,所述阻燃劑包括三氧化二銻以及十溴二苯乙烷,且其比例是1:3。 The flame-retardant and waterproof fabric according to claim 1, wherein the flame retardant includes antimony trioxide and decabromodiphenylethane, and the ratio thereof is 1:3. 一種阻燃防水織物的製造方法,其包括:(a)混合一聚醯胺膠料,所述聚醯胺膠料包括100重量份的聚醯胺樹脂、10至15重量份的阻燃劑、0.5至2重量份的催化劑、2至5重量份的交聯劑以及10至100重量份的溶劑;(b)以浮刀式裱糊機塗佈所述聚醯胺膠料於一基布的其中一面,以形成一聚醯胺層;以及(c)加熱乾燥所述聚醯胺層,以得到所述阻燃防水織物。 A method for manufacturing a flame-retardant and waterproof fabric, which includes: (a) mixing a polyamide compound, the polyamide compound including 100 parts by weight of a polyamide resin, 10 to 15 parts by weight of a flame retardant, 0.5 to 2 parts by weight of the catalyst, 2 to 5 parts by weight of the cross-linking agent and 10 to 100 parts by weight of the solvent; (b) apply the polyamide compound to a base cloth with a floating knife type laminator One side to form a polyamide layer; and (c) heating and drying the polyamide layer to obtain the flame retardant waterproof fabric. 如請求項6所述的阻燃防水織物的製造方法,其中,所述步驟(a)中,混合溫度是介於40至80℃之間,混合時間是介於15至25分鐘。 The method for manufacturing a flame-retardant waterproof fabric according to claim 6, wherein in the step (a), the mixing temperature is between 40 and 80°C, and the mixing time is between 15 and 25 minutes. 如請求項6所述的阻燃防水織物的製造方法,其中,所述步驟 (b)中,所述聚醯胺膠料以一次塗佈方式形成於所述基布上,且塗佈量是80克/碼。 The method for manufacturing a flame-retardant waterproof fabric according to claim 6, wherein the steps In (b), the polyamide compound is formed on the base fabric in a one-time coating method, and the coating amount is 80 g/yd. 如請求項6所述的阻燃防水織物的製造方法,其中,所述步驟(c)中,加熱溫度是介於80至150℃之間,加熱時間是介於30至120秒。 The method for manufacturing a flame-retardant waterproof fabric according to claim 6, wherein in the step (c), the heating temperature is between 80 and 150°C, and the heating time is between 30 and 120 seconds. 如請求項6所述的阻燃防水織物的製造方法,其中,所述基布是經過一壓光處理的基布,且所述壓光處理的溫度是介於140至160℃之間,壓力是50公斤/平方公尺,速度是25公尺/分鐘。 The method for manufacturing a flame-retardant waterproof fabric according to claim 6, wherein the base fabric is a base fabric subjected to a calendering treatment, and the temperature of the calendering treatment is between 140 and 160° C. It is 50 kg/m² and the speed is 25 m/min.
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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101498100A (en) * 2008-09-26 2009-08-05 浙江传化股份有限公司 Expansion type flame-retardant coatings glue and use thereof in textile finishing
WO2015119037A1 (en) * 2014-02-06 2015-08-13 小松精練株式会社 Waterproof fabric and textile product employing same
CN108651917A (en) * 2017-03-31 2018-10-16 陕西理工大学 A kind of full powder of detoxication of konjac is without sulphur wet processing method

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101498100A (en) * 2008-09-26 2009-08-05 浙江传化股份有限公司 Expansion type flame-retardant coatings glue and use thereof in textile finishing
WO2015119037A1 (en) * 2014-02-06 2015-08-13 小松精練株式会社 Waterproof fabric and textile product employing same
CN108651917A (en) * 2017-03-31 2018-10-16 陕西理工大学 A kind of full powder of detoxication of konjac is without sulphur wet processing method

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