TWI692038B - Three-dimensional stacked semiconductor device and method of manufacturing the same - Google Patents

Three-dimensional stacked semiconductor device and method of manufacturing the same Download PDF

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TWI692038B
TWI692038B TW108102914A TW108102914A TWI692038B TW I692038 B TWI692038 B TW I692038B TW 108102914 A TW108102914 A TW 108102914A TW 108102914 A TW108102914 A TW 108102914A TW I692038 B TWI692038 B TW I692038B
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conductive layers
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TW202029353A (en
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李冠儒
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旺宏電子股份有限公司
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Abstract

A three-dimensional stacked semiconductor device includes a patterned multi-layered stacks formed in an array area of a substrate, wherein one of the patterned multi-layered stacks includes insulating layers and conductive layers arranged alternately, and a top gate layer is disposed above the conductive layers; a vertical channel structure disposed between the patterned multi-layered stacks and comprising a tunneling layer on the patterned multi-layered stacks and a channeling layer on the tunneling layer, wherein lateral sides of the top gate layer of one patterned multi-layered stack directly contact the tunneling layer; and discrete confined structures formed in recess regions adjacent to sidewalls of the conductive layers of the patterned multi-layered stacks, wherein one discrete confined structure includes a blocking layer formed as a liner in the recess region and a charge chapping element in contact with the blocking layer and the tunneling layer.

Description

三維堆疊半導體裝置及其製造方法 Three-dimensional stacked semiconductor device and manufacturing method thereof

本發明是有關於一種三維堆疊半導體裝置及其製造方法,且特別是有關於一種三維堆疊半導體裝置的資料儲存結構表面均勻一致及其製造方法。 The present invention relates to a three-dimensional stacked semiconductor device and a method for manufacturing the same, and in particular to a uniform storage surface of a three-dimensional stacked semiconductor device and a method for manufacturing the same.

非揮發性記憶體裝置在設計上有一個很大的特性是,當記憶體裝置失去或移除電源後仍能保存資料狀態的完整性。目前業界已經提出許多不同型態的非揮發性記憶體裝置。但相關業者仍不斷研發新的設計或是結合現有技術,進行記憶胞平面的堆疊以達到具有更高儲存容量的記憶體裝置。例如已有一些三維堆疊反及閘(NAND)型快閃記憶體裝置被提出。然而,傳統的三維堆疊記憶體裝置仍有一些問題需要被解決。 A great feature of the design of non-volatile memory devices is that when the memory device loses or removes power, it can still preserve the integrity of the data state. Many different types of non-volatile memory devices have been proposed in the industry. However, related companies continue to develop new designs or combine existing technologies to stack memory cell planes to achieve memory devices with higher storage capacity. For example, some three-dimensional stacked NAND flash memory devices have been proposed. However, the conventional three-dimensional stacked memory device still has some problems to be solved.

例如,對於三維堆疊反及閘型記憶體裝置來說,特別是對於電荷捕捉層在沿著多層導電層和多層絕緣層交替堆疊的方向上延伸的結構,未斷開的電荷捕捉層(例如氮化層)對於記憶體裝置的儲存時間(Retention)是一個重要的問題。根據傳統製造三維堆疊記憶體裝置的製造方式,多晶矽回拉(poly pull-back) 是製得侷限結構(confined structures)的一種常見步驟。然而,它的缺點是,用以形成侷限結構的凹陷區域其凹陷量並不均勻,因而導致侷限結構的側壁和電荷捕捉層的表面呈現波浪狀,進而影響三維堆疊記憶體裝置的電性表現。 For example, for a three-dimensional stacked anti-gate memory device, especially for a structure in which a charge trapping layer extends in a direction in which multiple conductive layers and multiple insulating layers are alternately stacked, an unbroken charge trapping layer (such as nitrogen Layer) is an important issue for the storage time (Retention) of the memory device. According to the traditional manufacturing method of manufacturing three-dimensional stacked memory devices, poly pull-back It is a common step to make confined structures. However, its disadvantage is that the recessed area used to form the confined structure has an uneven amount of recession, thus causing the side walls of the confined structure and the surface of the charge trapping layer to appear wavy, which further affects the electrical performance of the three-dimensional stacked memory device.

本發明係有關於一種三維堆疊半導體裝置及其製造方法。根據實施例之製造方法,係提供一種半導體裝置包括有表面均勻一致之元件或層,進而改善三維堆疊記憶體裝置之電性表現的可靠度。 The invention relates to a three-dimensional stacked semiconductor device and a manufacturing method thereof. According to the manufacturing method of the embodiment, a semiconductor device is provided that includes elements or layers with uniform surfaces, thereby improving the reliability of electrical performance of a three-dimensional stacked memory device.

根據一實施例,係提出一種三維堆疊半導體裝置,包括:一基板,具有一陣列區域(array area)和一階梯區域(staircase area);複數個圖案化多層堆疊(patterned multi-layered stacks)形成於基板上方和位於陣列區域內,且圖案化多層堆疊係彼此相距,其中圖案化多層堆疊之一係包括複數個絕緣層(insulating layers)和複數個導電層(conductive layers)交替地設置,且一頂部閘極層(top gate layer)形成於導電層的上方;一垂直通道結構(vertical channel structure),位於圖案化多層堆疊之間,且垂直通道結構包括一穿隧層(tunneling layer)形成於圖案化多層堆疊上以及一通道層(channeling layer)形成於穿隧層上,其中圖案化多層堆疊前述之一者的頂部閘極層之側面(lateral sides)係直接接觸穿隧層;和分離的侷限結構(discrete confined structures),係形成於鄰近圖案化多層堆疊的導電層之 側壁(sidewalls)的凹陷區域中(recessed regions),且該些分離的侷限結構各包括一阻擋層(blocking layer)襯裡式地形成於凹陷區域中以及一電荷捕捉元件(charge chapping element)與阻擋層和穿隧層接觸。 According to an embodiment, a three-dimensional stacked semiconductor device is proposed, including: a substrate having an array area and a staircase area; a plurality of patterned multi-layered stacks are formed on Above the substrate and in the array area, and the patterned multilayer stacks are spaced apart from each other, wherein one of the patterned multilayer stacks includes a plurality of insulating layers and a plurality of conductive layers alternately arranged, and a top A top gate layer is formed above the conductive layer; a vertical channel structure is located between the patterned multilayer stacks, and the vertical channel structure includes a tunneling layer formed on the patterned A multi-layer stack and a channeling layer are formed on the tunneling layer, wherein the lateral sides of the top gate layer of one of the aforementioned patterned multi-layer stacks directly contact the tunneling layer; and the separated confinement structure (discrete confined structures), formed in the conductive layer adjacent to the patterned multilayer stack The recessed regions of the sidewalls, and the separate confinement structures each include a blocking layer lined in the recessed region and a charge chapping element and blocking layer Contact with the tunneling layer.

根據一實施例,係提出一種三維堆疊半導體裝置之製造方法,包括:形成複數個圖案化多層堆疊於一基板上方和位於基板的一陣列區域內,其中此些圖案化多層堆疊係彼此相距,且通道孔(channel holes)形成於相鄰設置的圖案化多層堆疊之間,圖案化多層堆疊其中之一係包括複數個絕緣層和複數個導電層交替地設置;於圖案化多層堆疊之前述一者的導電層之上方形成一頂部閘極層(top gate layer),且形成複數個分離的侷限結構於鄰近圖案化多層堆疊的導電層之側壁的凹陷區域中,其中各個分離的侷限結構包括一阻擋層襯裡式地形成於凹陷區域中以及一電荷捕捉元件與阻擋層接觸;和形成一垂直通道結構於圖案化多層堆疊上,其中垂直通道結構包括一穿隧層設置於圖案化多層堆疊上以及一通道層形成於穿隧層上;其中該些圖案化多層堆疊之一者的頂部閘極層之側面係直接接觸穿隧層。 According to an embodiment, a method for manufacturing a three-dimensional stacked semiconductor device is proposed, including: forming a plurality of patterned multilayer stacks above a substrate and within an array region of the substrate, wherein the patterned multilayer stacks are spaced apart from each other, and Channel holes are formed between adjacently arranged patterned multilayer stacks. One of the patterned multilayer stacks includes a plurality of insulating layers and a plurality of conductive layers alternately arranged; the aforementioned one of the patterned multilayer stacks A top gate layer is formed above the conductive layer, and a plurality of separate confinement structures are formed in the recessed regions adjacent to the sidewalls of the conductive layers of the patterned multilayer stack, wherein each separate confinement structure includes a barrier Layer lining is formed in the recessed area and a charge trapping element is in contact with the barrier layer; and forming a vertical channel structure on the patterned multilayer stack, wherein the vertical channel structure includes a tunneling layer disposed on the patterned multilayer stack and a The channel layer is formed on the tunneling layer; wherein the side of the top gate layer of one of the patterned multilayer stacks directly contacts the tunneling layer.

為了對本發明之上述及其他方面有更佳的瞭解,下文特舉實施例,並配合所附圖式詳細說明如下: In order to have a better understanding of the above and other aspects of the present invention, the following examples are specifically described in conjunction with the accompanying drawings as follows:

10:基板 10: substrate

11M:多層堆疊 11M: Multi-layer stack

11M’:堆疊柱體 11M’: stacked cylinders

11MP:圖案化多層堆疊 11MP: patterned multilayer stack

111:絕緣層 111: Insulation

111L:最底絕緣層 111 L : the lowest insulating layer

111U:最上層絕緣層 111 U : uppermost insulating layer

111Ua:最上層絕緣層之上表面 111 Ua : upper surface of the uppermost insulating layer

112:導電層 112: conductive layer

112B:第一導電層 112 B : the first conductive layer

112WL:第二導電層 112 WL : second conductive layer

112S1:第一側壁 112S1: First side wall

111S2:第二側壁 111S2: second side wall

12:孔洞 12: Hole

HC:通道孔 H C : channel hole

13:凹陷區域 13: sunken area

AA:陣列區域 A A : Array area

AS:階梯區域 A S : stepped area

140:阻擋膜 140: barrier film

150:電荷捕捉膜 150: charge trapping membrane

1120:頂部導電膜 1120: Top conductive film

112T:頂部閘極層 112T: top gate layer

112T-S:頂部閘極層的側面 112T-S: the side of the top gate layer

SC:分離的侷限結構 S C : Separated limited structure

14:阻擋層 14: barrier

15:電荷捕捉元件 15: charge trapping element

151S:電荷捕捉元件的側面 151S: The side of the charge trapping element

16:穿隧層 16: Tunneling layer

17:通道層 17: channel layer

18:介電層 18: Dielectric layer

t1:第一厚度 t1: first thickness

t2:第二厚度 t2: second thickness

t3:第三厚度 t3: third thickness

WR:凹陷區域之寬度 W R : width of the recessed area

W1:第一寬度 W1: first width

W2:第二寬度 W2: second width

D1:第一方向 D1: First direction

D2:第二方向 D2: Second direction

第1A~1I圖繪示根據本發明一實施例之三維堆疊半導體裝置之製造方法。 FIGS. 1A-1I illustrate a method of manufacturing a three-dimensional stacked semiconductor device according to an embodiment of the invention.

第2圖繪示本發明一實施例之三維堆疊半導體裝置之示意圖。 FIG. 2 is a schematic diagram of a three-dimensional stacked semiconductor device according to an embodiment of the invention.

在此揭露內容之實施例中,係提出一種三維堆疊半導體裝置及其製造方法。根據實施例之製法,可使三維堆疊半導體裝置的資料儲存結構(data storage structures),例如包括阻擋層(the blocking layers)、電荷捕捉元件(charge chapping elements)和穿隧層(tunneling layer),其具有均勻一致的表面(uniform surfaces),而可解決在傳統三維堆疊半導體裝置中於資料儲存結構產生波浪表面的問題。於一實施例,在形成一頂部導電層(top conductive film)之前(此頂部導電層係於之後步驟中製成頂部選擇閘極),係沈積一電荷捕捉層(charge chapping film)以填滿圖案化多層堆疊(patterned multi-layered stacks)之間的區域,且之後進行移除製程(例如蝕刻步驟)以隔絕該些電荷捕捉元件,並在鄰近於圖案化多層堆疊的導電層側壁處的凹陷區域中(recessed regions)形成侷限結構(confined structures)。因此,沒有侷限結構形成於鄰近實施例之頂部導電層的側面處。實施例之製造方法可使製得之一裝置其元件具有均勻且廓形一致之表面,進而改善三維堆疊記憶體裝置之電性表現的可靠度。再者,實施例方法不會對裝置中的相關層和元件造成損傷,且實施例方法亦 適合用於製造大量堆疊層的三維堆疊記憶體裝置而不影響實施例之裝置的構型。 In the embodiment disclosed herein, a three-dimensional stacked semiconductor device and a manufacturing method thereof are proposed. According to the manufacturing method of the embodiment, data storage structures of a three-dimensional stacked semiconductor device, for example, including the blocking layers, charge chapping elements, and tunneling layer, which It has uniform surfaces, and can solve the problem of generating a wavy surface in the data storage structure in the conventional three-dimensional stacked semiconductor device. In one embodiment, before forming a top conductive film (the top conductive layer is made into a top selection gate in a later step), a charge trapping film is deposited to fill the pattern Patterned multi-layered stacks, and then perform a removal process (such as an etching step) to isolate the charge trapping elements, and the recessed areas adjacent to the sidewalls of the conductive layers of the patterned multi-layer stack Recessed regions form confined structures. Therefore, no confinement structure is formed adjacent to the side of the top conductive layer of the embodiment. The manufacturing method of the embodiment can make a device with a uniform and uniform surface of the device, thereby improving the reliability of the electrical performance of the three-dimensional stacked memory device. Furthermore, the embodiment method does not cause damage to the relevant layers and components in the device, and the embodiment method also The three-dimensional stacked memory device suitable for manufacturing a large number of stacked layers does not affect the configuration of the device of the embodiment.

此揭露內容之實施例其應用十分廣泛,可應用在許多三維堆疊半導體裝置之製程。舉例來說,實施例可應用在三維垂直通道(vertical-channel,VC)式之半導體裝置,但本揭露並不以此應用為限。以下係提出相關實施例,配合圖示以詳細說明本揭露所提出之三維堆疊半導體裝置及其製造方法。然而本揭露並不僅限於此。實施例中之敘述,如細部結構、製程步驟和材料應用等等,僅為舉例說明之用,本揭露欲保護之範圍並非僅限於所述之態樣。 The disclosed embodiments are widely used, and can be used in many three-dimensional stacked semiconductor devices. For example, the embodiment can be applied to a three-dimensional vertical-channel (VC) type semiconductor device, but the disclosure is not limited to this application. The following are related embodiments, which are illustrated in detail to illustrate the three-dimensional stacked semiconductor device and the manufacturing method thereof provided in the present disclosure. However, this disclosure is not limited to this. The descriptions in the embodiments, such as detailed structure, process steps, material application, etc., are for illustrative purposes only, and the scope of protection to be disclosed in the present disclosure is not limited to the described state.

需注意的是,本揭露並非顯示出所有可能的實施例,相關領域者可在不脫離本揭露之精神和範圍內對實施例之結構和製程加以變化與修飾,以符合實際應用所需。因此,未於本揭露提出的其他實施態樣也可能可以應用。再者,圖式係已簡化以利清楚說明實施例之內容,圖式上的尺寸比例並非按照實際產品等比例繪製。因此,說明書和圖示內容僅作敘述實施例之用,而非作為限縮本揭露保護範圍之用。 It should be noted that this disclosure does not show all possible embodiments, and those skilled in the relevant arts can change and modify the structure and process of the embodiments without departing from the spirit and scope of this disclosure to meet the needs of practical applications. Therefore, other implementations not mentioned in this disclosure may also be applicable. Furthermore, the drawings have been simplified to clearly explain the contents of the embodiments, and the size ratios on the drawings are not drawn according to the actual products. Therefore, the description and illustrations are only used to describe the embodiments, not to limit the scope of disclosure of the present disclosure.

再者,說明書與請求項中所使用的序數例如”第一”、”第二”、”第三”等之用詞,是為了修飾請求項之元件,其本身並不意含及代表該請求元件有任何之前的序數,也不代表某一請求元件與另一請求元件的順序、或是製造方法上的順序,該些序數的使用僅用來使具有某命名的一請求元件得以和另一具有相 同命名的請求元件能作出清楚區分。 In addition, the ordinal numbers used in the specification and the request items, such as "first", "second", "third", etc., are used to modify the element of the request item, which does not mean and represent the request element itself. The presence of any previous ordinal numbers does not mean the order of a request element and another request element, or the order of manufacturing method. The use of these ordinal numbers is only to enable a request element with a certain name to phase Request elements with the same name can be clearly distinguished.

第1A~1I圖繪示根據本發明一實施例之三維堆疊半導體裝置之製造方法。如第1A圖所示,一多層堆疊(a multi-layered stack)11M形成於一基板10上,且基板10具有一陣列區域(array area)AA和一階梯區域(staircase area)AS,多層堆疊11M包括複數個絕緣層(insulating layers)111和複數個導電層(conductive layers)112沿著垂直於基板10之一第二方向D2(例如Z方向)交替堆疊。一實施例中,絕緣層111例如是氧化層,導電層112例如是多晶矽層(例如N型重摻雜多晶矽層或P型重摻雜多晶矽層)。 FIGS. 1A-1I illustrate a method of manufacturing a three-dimensional stacked semiconductor device according to an embodiment of the invention. As shown in FIG. 1A, a multi-layered stack 11M is formed on a substrate 10, and the substrate 10 has an array area A A and a staircase area A S , The multi-layer stack 11M includes a plurality of insulating layers 111 and a plurality of conductive layers 112 alternately stacked along a second direction D2 (eg, Z direction) perpendicular to one of the substrates 10. In one embodiment, the insulating layer 111 is, for example, an oxide layer, and the conductive layer 112 is, for example, a polysilicon layer (for example, an N-type heavily doped polysilicon layer or a P-type heavily doped polysilicon layer).

於一示例中(但不以此為限),位於基板10之陣列區域AA中的多層堆疊11M之其中一者的導電層112係包括複數個第一導電層112B和複數個第二導電層112WL。於一示例中,第一導電層112B形成於基板10上方且作為一底部閘極層(abottom gate layer)之用,第二導電層112WL形成於第一導電層112B之上方可作為裝置的字元線之用。 In an example (but not limited to), the conductive layer 112 of one of the multilayer stacks 11M in the array area A A of the substrate 10 includes a plurality of first conductive layers 112 B and a plurality of second conductive layers Layer 112 WL . In one example, the first conductive layer 112 B is formed on the substrate 10 and serves as a bottom gate layer, and the second conductive layer 112 WL is formed on the first conductive layer 112 B as a device For the character line.

之後,對多層堆疊11M進行圖案化,例如蝕刻方式,以形成多個孔洞(holes)12,如第1B圖所示。於一示例中,孔洞12向下延伸並穿過第二導電層112WL和第一導電層112B,並暴露出一最底絕緣層111L(例如一埋置氧化層形成於基板10上)。 After that, the multilayer stack 11M is patterned, for example, by etching to form a plurality of holes 12, as shown in FIG. 1B. In an example, the hole 12 extends downward and passes through the second conductive layer 112 WL and the first conductive layer 112 B , and exposes a bottommost insulating layer 111 L (for example, a buried oxide layer is formed on the substrate 10) .

如第1C圖所示,使導電層112,包括第一導電層 112B和第二導電層112WL,相對於絕緣層111而向內凹陷,以形成複數個堆疊柱體(stacked pillars)11M’垂直延伸於基板10上。因此,相鄰於此些堆疊柱體11M’之導電層112的側壁(sidewalls)係形成凹陷區域13。於一實施例中,導電層112具有第一側壁(first sidewalls)112S1,絕緣層111具有第二側壁(second sidewalls)111S2,其中此些第一側壁112S1係相對地內凹於此些第二側壁111S2,以定義出該些凹陷區域13。 As shown in FIG. 1C, the conductive layer 112, including the first conductive layer 112 B and the second conductive layer 112 WL , is recessed inward relative to the insulating layer 111 to form a plurality of stacked pillars 11M′ It extends vertically on the substrate 10. Therefore, the side walls of the conductive layer 112 adjacent to the stacked pillars 11M′ form the recessed area 13. In one embodiment, the conductive layer 112 has first sidewalls 112S1, and the insulating layer 111 has second sidewalls 111S2, wherein the first sidewalls 112S1 are relatively recessed in the second sidewalls 111S2 to define the concave regions 13.

另外,凹陷區域13的凹陷程度可視實際應用之需求而決定和修飾。於一示例中,凹陷區域13在平行於一第一方向D1(如第1C圖所示之X方向)上具有一寬度WR,其中此寬度WR可以小於或約等於凹陷步驟後剩餘導電層112的寬度(例如第1I圖所示之第二寬度W2)。然而本揭露並不以此為限。再者,第一導電層112B其中之一係具有一第一厚度t1(沿第二方向D2;例如Z-方向),第二導電層112WL其中之一係具有一第二厚度t2;於一示例中,第一厚度t1實質上等於第二厚度t2,但本揭露並不以此為限。 In addition, the degree of depression of the depression region 13 can be determined and modified according to actual application requirements. In an example, the recessed region 13 has a width W R parallel to a first direction D1 (the X direction shown in FIG. 1C), where the width W R may be less than or approximately equal to the remaining conductive layer after the recess step The width of 112 (for example, the second width W2 shown in FIG. 1I). However, this disclosure is not limited to this. Furthermore, one of the first conductive layers 112 B has a first thickness t1 (along the second direction D2; for example, Z-direction), and one of the second conductive layers 112 WL has a second thickness t2; In an example, the first thickness t1 is substantially equal to the second thickness t2, but the disclosure is not limited thereto.

之後,沈積一阻擋膜(blocking film)140以於此些凹陷區域13中形成阻擋襯裡(blocking liners);以及沈積一電荷捕捉膜(charge chapping film)150於阻擋膜140上,其中電荷捕捉膜150完全地填滿該些堆疊柱體11M’之間的空間,例如完全地填滿該些堆疊柱體11M’處阻擋膜140之相對兩襯裡部分(opposite liner portions)之間的空間,如第1D圖所示。再者, 阻擋膜140和形成於其上之電荷捕捉膜150係覆蓋最上層絕緣層111UAfterwards, a blocking film 140 is deposited to form blocking liners in the recessed regions 13; and a charge chapping film 150 is deposited on the blocking film 140, wherein the charge trapping film 150 Completely fill the space between the stacked pillars 11M′, for example, completely fill the space between the opposing two liner portions of the barrier film 140 at the stacked pillars 11M′, as in the 1D The picture shows. Furthermore, the barrier film 140 and the charge trapping film 150 formed thereon cover the uppermost insulating layer 111 U.

阻擋膜140可以是包括多層膜層之一種組合,以優化抹除飽和(optimize erase saturation)。舉例來說,多層膜層可包括材料層例如高介電係數(相較於二氧化矽是高介電係數)的介電材料、覆蓋型氮化矽(capped SiN)、雙重捕捉型BE-SONOS(能隙工程矽-氧化物-氮化物-氧化物-矽)之ONO(氧化物-氮化物-氧化物)。於一示例中,電荷捕捉膜150的材料一般包括氮化矽(silicon nitride,SiN)。於其他示例中,電荷捕捉膜150可包括SiON、HfO2、Al2O3等等。於實施例之示例圖示中,係繪示一整合層以表示電荷捕捉膜150,以簡化圖示而利於清楚說明。 The barrier film 140 may be a combination including multiple layers to optimize erase saturation. For example, the multilayer film layer may include material layers such as high dielectric constant (higher dielectric constant than silicon dioxide), capped SiN, and double-trapped BE-SONOS (Energy gap engineering silicon-oxide-nitride-oxide-silicon) ONO (oxide-nitride-oxide). In an example, the material of the charge trapping film 150 generally includes silicon nitride (SiN). In other examples, the charge trapping film 150 may include SiON, HfO 2 , Al 2 O 3 and so on. In the example illustration of the embodiment, an integration layer is shown to represent the charge trapping film 150 to simplify the illustration and facilitate clear explanation.

然後,回蝕(etch back)電荷捕捉膜150以暴露出最上層絕緣層111U之上表面111Ua,如第1E圖所示。如第1F圖所示,一頂部導電膜(top conductive film)1120形成於電荷捕捉膜150、阻擋膜140和該些堆疊柱體11M’上。並且,沈積另一絕緣層111於頂部導電膜1120上方以覆蓋頂部導電膜1120。 Then, the charge trapping film 150 is etched back to expose the upper surface 111 Ua of the uppermost insulating layer 111 U , as shown in FIG. 1E. As shown in FIG. 1F, a top conductive film 1120 is formed on the charge trapping film 150, the barrier film 140, and the stacked pillars 11M'. And, another insulating layer 111 is deposited over the top conductive film 1120 to cover the top conductive film 1120.

之後,如第1G圖所示,移除部分的頂部導電膜1120、移除位於堆疊柱體之間的電荷捕捉膜150之一部份、與移除部分的阻擋膜140,以形成多個通道孔HC,此些通道孔HC係暴露出絕緣層111之側壁(亦即第二側壁111S2),其中通道孔HC係沿著第二方向D2(例如Z-方向)延伸並垂直於基板10之一延伸平面的方向。因此,多個圖案化多層堆疊11MP因而形成於基板 10上。 Then, as shown in FIG. 1G, a portion of the top conductive film 1120 is removed, a portion of the charge trapping film 150 between the stacked pillars, and the portion of the barrier film 140 are removed to form a plurality of channels Holes H C. The channel holes H C expose the sidewalls of the insulating layer 111 (that is, the second sidewall 111S2 ). The channel holes H C extend along the second direction D2 (eg, Z-direction) and are perpendicular to the substrate One of 10 extends the direction of the plane. Therefore, a plurality of patterned multilayer stacks 11MP are thus formed on the substrate 10.

請參照第1F圖和第1G圖,根據一實施例,在基板10的陣列區域AA內,頂部導電膜1120的一些部分、位於堆疊柱體之間的電荷捕捉膜150之部份與阻擋膜140的部分,可藉由一個步驟而移除,例如利用單一蝕刻步驟而移除,因而形成頂部閘極層(top gate layers)112T於導電層112的上方,以及形成分離的侷限結構(discrete confined structures)SC於鄰近多個圖案化多層堆疊11MP的導電層112之側壁(例如第一側壁112S1)的凹陷區域13中。再者,所形成之通道孔HC係暴露出最底絕緣層111L(例如一埋置氧化層形成於基板10上)。於一示例中,如第1F圖所示之頂部導電膜1120係沿著基板10之延伸平面中的第一方向D1延伸(例如X-方向),且蝕刻步驟係如第1G圖所示透過沿著第二方向D2(例如Z-方向)切除相關材料層的方式進行。其中第二方向D2係垂直於第一方向D1。根據實施例,圖案化多層堆疊11MP具有均勻一致的廓形(uniformed profiles),亦即圖案化多層堆疊11MP的相關元件(例如頂部閘極層112T、導電層112和絕緣層111)不會形成波浪狀的側表面。 Referring to FIGS. 1F and 1G, according to an embodiment, in the array area A A of the substrate 10, some portions of the top conductive film 1120, the portion of the charge trapping film 150 between the stacked pillars and the barrier film The part of 140 can be removed in one step, for example, by a single etching step, thereby forming a top gate layer 112T above the conductive layer 112, and forming a discrete confined structure structures) S C 11MP stacked sidewall conductive layer 112 adjacent to the plurality of patterned multilayer (e.g., the first side wall 112S1) recessed area 13. Furthermore, the formed via hole H C exposes the bottommost insulating layer 111 L (for example, a buried oxide layer is formed on the substrate 10 ). In one example, the top conductive film 1120 shown in FIG. 1F extends along the first direction D1 (for example, X-direction) in the extension plane of the substrate 10, and the etching step is shown in FIG. 1G through the edge The relevant material layer is cut in the second direction D2 (for example, Z-direction). The second direction D2 is perpendicular to the first direction D1. According to an embodiment, the patterned multilayer stack 11MP has uniform profiles, that is, the relevant elements of the patterned multilayer stack 11MP (such as the top gate layer 112T, the conductive layer 112, and the insulating layer 111) do not form waves Shaped side surface.

再者,於單一蝕刻步驟後,係於凹陷區域13中形成分離的侷限結構(discrete confined structures)SC,如第1G圖所示,其中該些分離的侷限結構SC係以之間的絕緣層111而彼此隔離。於一示例中,各個分離的侷限結構SC係包括一阻擋層(blocking layer)14如一襯裡(liner)的形成於凹陷區域13中,以 及一電荷捕捉元件(charge chapping element)15於阻擋層14之間,其中電荷捕捉元件15係與阻擋層14接觸。 Further, after the single etching step, based on the recessed areas 13 form separate structural limitations (discrete confined structures) S C, as shown on FIG. 1G, wherein the plurality of separate structural limitations S C to the insulation between the lines Layer 111 is isolated from each other. In one example, each separated limitations structure S C lines include 14 is formed like a liner (Liner) a barrier layer (blocking layer) to 13, and a charge trapping element (charge chapping element) recessed region 15 on the barrier layer 14 In between, the charge trapping element 15 is in contact with the barrier layer 14.

在形成通道孔HC之後,係沈積一穿隧層(tunneling layer)16於圖案化多層堆疊11MP上並覆蓋圖案化多層堆疊11MP,如第1H圖所示。穿隧層16並沿著圖案化多層堆疊11MP的側壁沈積。然後,形成一通道層(channeling layer)17於穿隧層16上。第1H圖中,各個圖案化多層堆疊11MP的頂部閘極層112T係埋置於穿隧層16內。根據實施例,穿隧層16係直接接觸圖案化多層堆疊11MP之頂部閘極層112T的側面(lateral sides)112T-S。於第1H圖中,例如,頂部閘極層112T的兩個相對側面112T-S係完全接觸穿隧層16並被穿隧層16完全地覆蓋。再者,於實施例中,穿隧層16直接接觸圖案化多層堆疊11MP之絕緣層111的側壁(亦即第二側壁111S2),且直接接觸分離的侷限結構SC;例如,穿隧層16直接接觸電荷捕捉元件15的側面151S。 After forming the via hole H C , a tunneling layer 16 is deposited on the patterned multilayer stack 11MP and covers the patterned multilayer stack 11MP, as shown in FIG. 1H. The tunnel layer 16 is deposited along the sidewalls of the patterned multilayer stack 11MP. Then, a channeling layer 17 is formed on the tunneling layer 16. In FIG. 1H, the top gate layer 112T of each patterned multilayer stack 11MP is buried in the tunneling layer 16. According to an embodiment, the tunneling layer 16 directly contacts the lateral sides 112T-S of the top gate layer 112T of the patterned multilayer stack 11MP. In FIG. 1H, for example, the two opposite sides 112T-S of the top gate layer 112T completely contact the tunnel layer 16 and are completely covered by the tunnel layer 16. Further, in the embodiment, the side wall 16 in direct contact with the patterned multilayer stack 11MP tunneling layer of the insulating layer 111 (i.e., a second side wall 111S2), and in direct contact limitations separation structure S C; e.g., tunneling layer 16 The side surface 151S of the charge trapping element 15 is directly contacted.

於一實施例中,穿隧層16可包括一能隙工程複合穿隧介電層(bandgap engineered composite tunneling dielectric layer),其包括一二氧化矽層。於一示例中(但不以此為限),複合穿隧介電層係由一超薄氧化矽層、一超薄氮化矽層與一超薄氧化矽層所組成。再者,於一實施例中通道層17例如包括多晶矽。 In one embodiment, the tunneling layer 16 may include a bandgap engineered composite tunneling dielectric layer (bandgap engineered composite tunneling dielectric layer), which includes a silicon dioxide layer. In an example (but not limited to this), the composite tunneling dielectric layer is composed of an ultra-thin silicon oxide layer, an ultra-thin silicon nitride layer, and an ultra-thin silicon oxide layer. Furthermore, in one embodiment, the channel layer 17 includes polysilicon, for example.

之後,沈積一介電層(dielectric layer)18於圖案 化多層堆疊11MP上,且介電層18填滿相鄰的圖案化多層堆疊11MP之間的剩餘空間,如第1I圖所示。於一示例中,介電層18接觸位於圖案化多層堆疊11MP之間的通道層17。於一示例中,介電層18可包括氧化物。 After that, a dielectric layer 18 is deposited on the pattern On the multi-layer stack 11MP, and the dielectric layer 18 fills the remaining space between the adjacent patterned multi-layer stack 11MP, as shown in FIG. 1I. In one example, the dielectric layer 18 contacts the channel layer 17 between the patterned multilayer stack 11MP. In an example, the dielectric layer 18 may include oxide.

第2圖繪示根據本發明一實施例之三維堆疊半導體裝置之示意圖。第2圖僅繪示一種形成於基板10之陣列區域AA中之三維堆疊半導體裝置之一構型,以利清楚說明。於第2圖中,陣列區域AA中的複數個圖案化多層堆疊11MP形成於基板10上方,且該些圖案化多層堆疊11MP彼此相距。圖案化多層堆疊11MP其中一者係包括複數個絕緣層111和複數個導電層112交替地設置,且一頂部閘極層(top gate layer)112T形成於該些導電層112的上方。再者,一垂直通道結構(vertical channel structure)係設置於圖案化多層堆疊11MP之間,其中此垂直通道結構包括一穿隧層16形成於圖案化多層堆疊11MP上,以及一通道層17形成於穿隧層16上。於實施例中,圖案化多層堆疊11MP其中之一的頂部閘極層112T之側面112T-S係直接接觸穿隧層16。再者,於實施例之三維堆疊半導體裝置中,分離的侷限結構SC係形成於鄰近圖案化多層堆疊11MP的導電層112之側壁(亦即第一側壁112S1)的凹陷區域13中,且各分離的侷限結構SC係包括一阻擋層(blocking layer)14如一襯裡的形成於凹陷區域13中,以及包括一電荷捕捉元件(charge chapping element)15與阻擋層14和穿隧層16接觸。於一示例中,一實施例之三維堆 疊半導體裝置的資料儲存結構(data storage structures)包括阻擋層14、電荷捕捉元件15和穿隧層16。 FIG. 2 is a schematic diagram of a three-dimensional stacked semiconductor device according to an embodiment of the invention. FIG. 2 only shows a configuration of a three-dimensional stacked semiconductor device formed in the array area A A of the substrate 10 for clear description. In FIG. 2, a plurality of patterned multilayer stacks 11MP in the array area A A are formed above the substrate 10, and the patterned multilayer stacks 11MP are spaced apart from each other. One of the patterned multi-layer stack 11MP includes a plurality of insulating layers 111 and a plurality of conductive layers 112 arranged alternately, and a top gate layer 112T is formed above the conductive layers 112. Furthermore, a vertical channel structure is disposed between the patterned multilayer stack 11MP, wherein the vertical channel structure includes a tunneling layer 16 formed on the patterned multilayer stack 11MP, and a channel layer 17 formed on On the tunneling layer 16. In the embodiment, the side 112T-S of the top gate layer 112T of one of the patterned multilayer stacks 11MP directly contacts the tunneling layer 16. Further, in the embodiment of the three-dimensional stacked semiconductor device of the embodiment, the isolated structure S C-based limitations recessed region formed adjacent to the patterned multilayer stack sidewalls (i.e., a first side wall 112S1) 11MP 112 of the conductive layer 13, and each limitations isolated structure S C comprises 13 lines, and in contact with the recessed area comprises a charge trapping element (charge chapping element) 15 and the barrier layer 14 and the tunneling layer 16 is formed of a barrier 14 such as a liner layer (blocking layer). In an example, the data storage structures of the three-dimensional stacked semiconductor device of an embodiment include a barrier layer 14, a charge trapping element 15 and a tunneling layer 16.

於第2圖中,阻擋層14可被視為形成於相鄰兩絕緣層111之間。再者,分離的侷限結構SC之電荷捕捉元件15亦沿著第二方向D2(例如Z方向)分隔開來地設置。根據實施例之製造方法,圖案化多層堆疊11MP的頂部閘極層112T以及分離的侷限結構SC可同時形成;例如,利用同一蝕刻步驟而同時形成,如第1G圖所示。因此,圖案化多層堆疊11MP的頂部閘極層112T之側面112T-S係實質上齊平於電荷捕捉元件15之側面151S。 In FIG. 2, the barrier layer 14 can be regarded as being formed between two adjacent insulating layers 111. Furthermore, the separated charge limited structure S C of the catch element 15 is also provided spaced apart along a second direction D2 (e.g. the Z direction). According to the manufacturing method of the embodiment, patterned multilayer stack on top of the gate layer and the separation 112T 11MP limitations structure S C may be formed at the same time; for example, using the same etching step simultaneously formed, as shown on FIG. 1G. Therefore, the side surface 112T-S of the top gate layer 112T of the patterned multilayer stack 11MP is substantially flush with the side surface 151S of the charge trapping element 15.

再者,根據實施例之方法所製得之裝置,圖案化多層堆疊11MP其中一者的頂部導電層112T具有一第一寬度(first width)W1平行於第一方向D1(例如X-方向),且圖案化多層堆疊11MP的導電層112(沿著第二方向D2例如Z-方向堆疊)係具有一第二寬度(second width)W2平行於第一方向D1。其中第一寬度W1係大於第二寬度W2。於導電層112和頂部導電層112T之一示例(但非限制性的)構型中,第一導電層112B其中之一係具有一第一厚度t1(沿著第二方向D2;例如Z-方向),第二導電層112WL其中之一係具有一第二厚度t2(沿著第二方向D2),其中第一厚度t1實質上等於第二厚度t2,且第一厚度t1或第二厚度t2實質上小於頂部閘極層112T之厚度t3(沿著第二方向D2)。 Furthermore, according to the device manufactured by the method of the embodiment, the top conductive layer 112T of one of the patterned multilayer stacks 11MP has a first width W1 parallel to the first direction D1 (eg X-direction), The conductive layer 112 of the patterned multilayer stack 11MP (stacked along the second direction D2 such as the Z-direction) has a second width W2 parallel to the first direction D1. The first width W1 is greater than the second width W2. In an exemplary (but non-limiting) configuration of the conductive layer 112 and the top conductive layer 112T, one of the first conductive layers 112 B has a first thickness t1 (along the second direction D2; for example, Z- Direction), one of the second conductive layers 112WL has a second thickness t2 (along the second direction D2), wherein the first thickness t1 is substantially equal to the second thickness t2, and the first thickness t1 or the second thickness t2 It is substantially smaller than the thickness t3 of the top gate layer 112T (along the second direction D2).

根據上述實施例提出三維堆疊半導體裝置及其製造方法,於一實施例,在形成一頂部導電層(top conductive film) 之前(此頂部導電層於之後步驟中製成頂部選擇閘極),係沈積一電荷捕捉層以填滿圖案化多層堆疊(patterned multi-layered stacks)之間的區域,且之後進行移除製程(例如蝕刻步驟)以隔絕該些電荷捕捉元件,並在鄰近於圖案化多層堆疊的導電層側壁處的凹陷區域中形成侷限結構(confined structures)。因此,沒有侷限結構形成於鄰近實施例之頂部導電層的側面處。根據實施例之一種三維堆疊半導體裝置的製造方法,三維堆疊半導體裝置的資料儲存結構(data storage structures),例如包括阻擋層14、電荷捕捉元件15和穿隧層16(如第2圖所示),其具有均勻一致的表面,而可解決在傳統三維堆疊半導體裝置中於資料儲存結構產生波浪表面的問題。因此,實施例之製造方法可使製得之一裝置其元件具有均勻且廓形一致之表面,進而改善三維堆疊記憶體裝置之電性表現的可靠度。再者,實施例方法不會對裝置中的相關層和元件造成損傷,且實施例方法亦適合用於製造大量堆疊層的三維堆疊記憶體裝置而不影響實施例之裝置的構型(亦即,實施例之裝置具有穩固的架構、相關元件和層具有完整構型)。再者,實施例之三維堆疊記憶體裝置係採用不費時和非昂貴之製程進行製作,十分適合量產。 According to the above embodiment, a three-dimensional stacked semiconductor device and a manufacturing method thereof are proposed. In one embodiment, a top conductive film is formed Before (the top conductive layer was made into the top selective gate in the next step), a charge trapping layer was deposited to fill the area between the patterned multi-layered stacks, and then the removal process was performed ( For example, an etching step) to isolate the charge trapping elements and form confined structures in the recessed regions adjacent to the sidewalls of the conductive layers of the patterned multilayer stack. Therefore, no confinement structure is formed adjacent to the side of the top conductive layer of the embodiment. According to a method for manufacturing a three-dimensional stacked semiconductor device according to an embodiment, data storage structures of the three-dimensional stacked semiconductor device include, for example, a barrier layer 14, a charge trapping element 15, and a tunneling layer 16 (as shown in FIG. 2) It has a uniform surface, and can solve the problem of generating a wavy surface in the data storage structure in the conventional three-dimensional stacked semiconductor device. Therefore, the manufacturing method of the embodiment can make a device with a device having a uniform and uniform surface, thereby improving the reliability of the electrical performance of the three-dimensional stacked memory device. Furthermore, the embodiment method does not cause damage to related layers and components in the device, and the embodiment method is also suitable for manufacturing a three-dimensional stacked memory device with a large number of stacked layers without affecting the configuration of the device of the embodiment (i.e. , The device of the embodiment has a stable architecture, and the related components and layers have a complete configuration). Furthermore, the three-dimensional stacked memory device of the embodiment is manufactured by a time-consuming and non-expensive process, which is very suitable for mass production.

如上述圖示之結構和步驟,是用以敘述本揭露之部分實施例或應用例,本揭露並不限制於上述結構和步驟之範圍與應用態樣。其他不同結構態樣之實施例,例如不同內部組件的已知構件都可應用,其示例之結構和步驟可根據實際應用之需求而 調整。因此圖示之結構僅為舉例說明之用,而非限制之用。通常知識者當知,應用本揭露之相關結構和步驟過程,例如三維堆疊半導體裝置中於陣列區域的相關元件和層的排列方式或構型,或製造步驟細節等,都可能以依實際應用樣態所需而可能有相應的調整和變化。 The structures and steps shown above are used to describe some embodiments or application examples of the present disclosure, and the present disclosure is not limited to the scope and application of the above structures and steps. Other embodiments of different structural aspects, such as known components of different internal components, can be applied, and the example structure and steps can be based on actual application requirements. Adjustment. Therefore, the illustrated structure is for illustrative purposes only, not for limitation. Generally, the knowledgeable person knows that the related structures and steps of the present disclosure, such as the arrangement or configuration of related elements and layers in the array area in the three-dimensional stacked semiconductor device, or the details of the manufacturing steps, etc., may be based on the actual application. There may be corresponding adjustments and changes required by the state.

綜上所述,雖然本發明已以實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。 In summary, although the present invention has been disclosed as above with examples, it is not intended to limit the present invention. Those with ordinary knowledge in the technical field to which the present invention belongs can make various modifications and retouching without departing from the spirit and scope of the present invention. Therefore, the scope of protection of the present invention shall be deemed as defined by the scope of the attached patent application.

10:基板 10: substrate

11MP:圖案化多層堆疊 11MP: patterned multilayer stack

111:絕緣層 111: Insulation

111L:最底絕緣層 111 L : the lowest insulating layer

111U:最上層絕緣層 111 U : uppermost insulating layer

112:導電層 112: conductive layer

112B:第一導電層 112 B : the first conductive layer

112WL:第二導電層 112 WL : second conductive layer

112S1:第一側壁 112S1: First side wall

111S2:第二側壁 111S2: second side wall

HC:通道孔 H C : channel hole

112T:頂部閘極層 112T: top gate layer

112T-S:頂部閘極層的側面 112T-S: the side of the top gate layer

SC:分離的侷限結構 S C : Separated limited structure

14:阻擋層 14: barrier

15:電荷捕捉元件 15: charge trapping element

151S:電荷捕捉元件的側面 151S: The side of the charge trapping element

16:穿隧層 16: Tunneling layer

17:通道層 17: channel layer

18:介電層 18: Dielectric layer

W1:第一寬度 W1: first width

W2:第二寬度 W2: second width

t1:第一厚度 t1: first thickness

t2:第二厚度 t2: second thickness

t3:第三厚度 t3: third thickness

D1:第一方向 D1: First direction

D2:第二方向 D2: Second direction

Claims (10)

一種三維堆疊半導體裝置,包括:一基板,具有一陣列區域(array area)和一階梯區域(staircase area);一最底絕緣層,形成於該基板上;複數個圖案化多層堆疊(patterned multi-layered stacks)形成於該最底絕緣層上方和位於該陣列區域內,且該些圖案化多層堆疊係彼此相距,其中該些圖案化多層堆疊之一係包括複數個絕緣層(insulating layers)和複數個導電層(conductive layers)交替地設置,且一頂部閘極層(top gate layer)形成於該些導電層的上方;一垂直通道結構(vertical channel structure),位於該些圖案化多層堆疊之間,且該垂直通道結構包括一穿隧層(tunneling layer)形成於該些圖案化多層堆疊上以及一通道層(channeling layer)形成於該穿隧層上,其中該些圖案化多層堆疊前述之一者的該頂部閘極層之側面(lateral sides)係直接接觸該穿隧層,其中該穿隧層的一底表面直接接觸該最底絕緣層;和分離的侷限結構(discrete confined structures),係形成於鄰近該些圖案化多層堆疊的該些導電層之側壁(sidewalls)的凹陷區域中(recessed regions),且該些分離的侷限結構各包括一阻擋層(blocking layer)襯裡式地形成於該凹陷區域中以及一電荷捕捉元件(charge chapping element)與該阻擋層和該穿隧層接觸。 A three-dimensional stacked semiconductor device includes: a substrate having an array area and a staircase area; a bottommost insulating layer formed on the substrate; a plurality of patterned multi-layer stacks (patterned multi- layered stacks) are formed above the bottom-most insulating layer and within the array area, and the patterned multilayer stacks are spaced apart from each other, wherein one of the patterned multilayer stacks includes a plurality of insulating layers and a plurality of insulating layers Conductive layers are alternately arranged, and a top gate layer is formed above the conductive layers; a vertical channel structure is located between the patterned multilayer stacks And the vertical channel structure includes a tunneling layer formed on the patterned multilayer stacks and a channeling layer formed on the tunneling layer, wherein the patterned multilayer stacks are one of the aforementioned The lateral sides of the top gate layer directly contact the tunneling layer, wherein a bottom surface of the tunneling layer directly contacts the bottommost insulating layer; and separate confined structures (discrete confined structures) are Formed in recessed regions adjacent to the sidewalls of the conductive layers of the patterned multilayer stacks, and the separate confinement structures each include a blocking layer lined in the A charge trapping element is in contact with the barrier layer and the tunneling layer in the recessed area. 如申請專利範圍第1項所述之三維堆疊半導體裝置,其中該些圖案化多層堆疊的該些導電層和該些絕緣層係分別具有第一側壁(first sidewalls)和第二側壁(second sidewalls),且該些第一側壁係相對地內凹於該些第二側壁,以定義出該些凹陷區域。 The three-dimensional stacked semiconductor device as described in item 1 of the patent application range, wherein the conductive layers and the insulating layers of the patterned multilayer stacks have first sidewalls and second sidewalls, respectively And the first side walls are relatively recessed in the second side walls to define the recessed areas. 如申請專利範圍第1項所述之三維堆疊半導體裝置,其中該穿隧層直接接觸該些圖案化多層堆疊之該些絕緣層的側壁(sidewalls)。 The three-dimensional stacked semiconductor device as described in item 1 of the scope of the patent application, wherein the tunneling layer directly contacts the sidewalls of the insulating layers of the patterned multilayer stacks. 如申請專利範圍第1項所述之三維堆疊半導體裝置,其中該些圖案化多層堆疊前述之一的該頂部導電層具有一第一寬度(first width)平行於一第一方向,且該些圖案化多層堆疊的該些導電層係沿著一第二方向堆疊,該第二方向係垂直於該第一方向,其中該些圖案化多層堆疊前述之一的該些導電層之一第二寬度(second width)係平行於該第一方向,且該第一寬度大於該第二寬度。 The three-dimensional stacked semiconductor device as described in item 1 of the patent application range, wherein the top conductive layer of the aforementioned one of the patterned multilayer stacks has a first width parallel to a first direction, and the patterns The conductive layers of the multi-layer stack are stacked along a second direction, which is perpendicular to the first direction, wherein the patterned multi-layer stack has one of the second widths of the conductive layers ( The second width is parallel to the first direction, and the first width is greater than the second width. 如申請專利範圍第1項所述之三維堆疊半導體裝置,其中該些圖案化多層堆疊前述之一的該些導電層係包括:複數個第一導電層(first conductive layers),形成於該基板上方且作為一底部閘極層(a bottom gate layer)之用;和複數個第二導電層(second conductive layers),形成於該些第一導電層之上方; 其中該些第一導電層其中之一係具有一第一厚度,該些第二導電層其中之一係具有一第二厚度,且該第一厚度實質上等於該第二厚度。 The three-dimensional stacked semiconductor device as described in item 1 of the patent application range, wherein the conductive layers of the aforementioned one of the patterned multilayer stacks include: a plurality of first conductive layers formed on the substrate And as a bottom gate layer (a bottom gate layer); and a plurality of second conductive layers (second conductive layers) formed on the first conductive layers; One of the first conductive layers has a first thickness, one of the second conductive layers has a second thickness, and the first thickness is substantially equal to the second thickness. 一種三維堆疊半導體裝置之製造方法,包括:形成一最底絕緣層於一基板上;形成複數個圖案化多層堆疊(patterned multi-layered stacks)於該最底絕緣層上方和位於該基板的一陣列區域(array region)內,其中該些圖案化多層堆疊係彼此相距,且通道孔(channel holes)形成於相鄰設置的該些圖案化多層堆疊之間,該些圖案化多層堆疊之一係包括複數個絕緣層(insulating layers)和複數個導電層(conductive layers)交替地設置;於該些圖案化多層堆疊之前述一者的該些導電層的上方形成一頂部閘極層(top gate layer),且形成複數個分離的侷限結構(discrete confined structures)於鄰近該些圖案化多層堆疊的該些導電層之側壁(sidewalls)的凹陷區域(recessed regions)中,其中該些分離的侷限結構各包括一阻擋層(blocking layer)襯裡式地形成於該凹陷區域中以及一電荷捕捉元件(charge chapping element)與該阻擋層接觸;和形成一垂直通道結構(vertical channel structure)於該些圖案化多層堆疊上,其中該垂直通道結構包括一穿隧層(tunneling layer)設置於該些圖案化多層堆疊上以及一通道層(channeling layer)形成於該穿隧層上,其中該穿隧層的一底表面直接接觸該最底絕緣層;其中該些圖案化多層堆疊前述之一者的該頂部閘極層之側面(lateral sides)係直接接觸該穿隧層。 A method for manufacturing a three-dimensional stacked semiconductor device, comprising: forming a bottommost insulating layer on a substrate; forming a plurality of patterned multi-layered stacks above the bottommost insulating layer and an array on the substrate In an array region, wherein the patterned multilayer stacks are spaced apart from each other, and channel holes are formed between the adjacently arranged patterned multilayer stacks, one of the patterned multilayer stacks includes A plurality of insulating layers and a plurality of conductive layers are alternately arranged; a top gate layer is formed above the conductive layers of the aforementioned one of the patterned multilayer stacks And a plurality of discrete confined structures are formed in recessed regions adjacent to the sidewalls of the conductive layers of the patterned multilayer stacks, wherein the discrete confined structures each include A blocking layer is lined in the recessed area and a charge chapping element is in contact with the blocking layer; and a vertical channel structure is formed on the patterned multilayer stacks The vertical channel structure includes a tunneling layer disposed on the patterned multilayer stacks and a channeling layer. layer) is formed on the tunneling layer, wherein a bottom surface of the tunneling layer directly contacts the bottommost insulating layer; wherein the patterned multilayer stacks one of the aforementioned lateral sides of the top gate layer It directly contacts the tunneling layer. 如申請專利範圍第6項所述之製造方法,其中該些圖案化多層堆疊的該些導電層和該些絕緣層係分別具有第一側壁(first sidewalls)和第二側壁(second sidewalls),且該些第一側壁係相對地內凹於該些第二側壁,以定義出該些凹陷區域。 The manufacturing method as described in item 6 of the patent application scope, wherein the conductive layers and the insulating layers of the patterned multilayer stacks have first sidewalls and second sidewalls, respectively, and The first side walls are relatively recessed in the second side walls to define the recessed regions. 如申請專利範圍第6項所述之製造方法,其中該些圖案化多層堆疊前述之一的該頂部導電層具有一第一寬度(first width)平行於一第一方向,且該些圖案化多層堆疊的該些導電層係沿著一第二方向堆疊,該第二方向係垂直於該第一方向,其中該些圖案化多層堆疊前述之一的該些導電層之一第二寬度係平行於該第一方向,且該第一寬度大於該第二寬度。 The manufacturing method as described in item 6 of the patent application scope, wherein the top conductive layer of one of the aforementioned patterned multilayer stacks has a first width parallel to a first direction, and the patterned multilayers The stacked conductive layers are stacked along a second direction that is perpendicular to the first direction, wherein the second widths of the conductive layers of the one of the patterned multilayer stacks are parallel to The first direction, and the first width is greater than the second width. 如申請專利範圍第6項所述之製造方法,其中該些圖案化多層堆疊前述之一的該些導電層係包括:複數個第一導電層(first conductive layers),形成於該基板上方且作為一底部閘極層(a bottom gate layer)之用;和複數個第二導電層(second conductive layers),形成於該些第一導電層之上方, 其中該些第一導電層其中之一係具有一第一厚度,該些第二導電層其中之一係具有一第二厚度,且該第一厚度實質上等於該第二厚度。 The manufacturing method as described in item 6 of the patent application scope, wherein the conductive layers of the patterned multilayer stack of the foregoing one include: a plurality of first conductive layers formed on the substrate and serving as A bottom gate layer (a bottom gate layer); and a plurality of second conductive layers (second conductive layers) formed on the first conductive layers, One of the first conductive layers has a first thickness, one of the second conductive layers has a second thickness, and the first thickness is substantially equal to the second thickness. 如申請專利範圍第6項所述之製造方法,其中形成該些圖案化多層堆疊於該基板上的步驟係包括:該些絕緣層與該些導電層係交替地形成於該基板上;使該些導電層相對地內凹於該些絕緣層,以形成複數個堆疊柱體(stacked pillars)於該基板上和該些凹陷區域相鄰於該些堆疊柱體之該些導電層的該些側壁;沈積一阻擋膜(blocking film)以於該些凹陷區域中形成阻擋襯裡(blocking liners);沈積一電荷捕捉膜(charge chapping film)於該阻擋膜上,且該電荷捕捉膜完全地填滿該些堆疊柱體之間的空間;形成一頂部導電膜(top conductive film)於該電荷捕捉膜、該阻擋膜和該些堆疊柱體上;以及移除部分的該頂部導電膜、位於該些堆疊柱體之間的該電荷捕捉膜之一部份與部分的該阻擋膜,以形成該些通道孔而暴露出該些絕緣層之側壁,其中該些通道孔係沿著垂直於該基板之一延伸平面的方向而延伸。 The manufacturing method as described in item 6 of the patent application range, wherein the step of forming the patterned multilayers stacked on the substrate includes: the insulating layers and the conductive layers are alternately formed on the substrate; The conductive layers are relatively recessed in the insulating layers to form a plurality of stacked pillars on the substrate and the recessed regions are adjacent to the sidewalls of the conductive layers of the stacked pillars Depositing a blocking film (blocking film) to form blocking linings (blocking liners) in the recessed areas; depositing a charge trapping film (charge chapping film) on the blocking film, and the charge trapping film completely fills the Spaces between the stacked pillars; forming a top conductive film on the charge trapping film, the barrier film, and the stacked pillars; and removing a portion of the top conductive film, located on the stacks A portion of the charge trapping film between the pillars and a portion of the barrier film to form the channel holes to expose the sidewalls of the insulating layers, wherein the channel holes are along one perpendicular to the substrate Extend in the direction of the extension plane.
TW108102914A 2019-01-25 2019-01-25 Three-dimensional stacked semiconductor device and method of manufacturing the same TWI692038B (en)

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