TWI679310B - Power supply method and power supply device for electrolytic ozone generator - Google Patents

Power supply method and power supply device for electrolytic ozone generator Download PDF

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TWI679310B
TWI679310B TW107124591A TW107124591A TWI679310B TW I679310 B TWI679310 B TW I679310B TW 107124591 A TW107124591 A TW 107124591A TW 107124591 A TW107124591 A TW 107124591A TW I679310 B TWI679310 B TW I679310B
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capacitor
cathode
resistor
anode
electrolytic
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TW202006192A (en
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徐名勇
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大陸商百特環保科技(煙臺)有限公司
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Abstract

本發明電解臭氧發生器緩升緩降的供電方法及供電裝置,其利用對電解臭氧發生器的供電及撤除以階梯升降方式或緩慢升降方式進行。其供電裝置包括AC/DC電源變換器、微型控制晶片MCU、恆流產生電路、臭氧發生器和電解水桶;本發明提高發生器使用壽命,結構簡單實用、使用者安裝和更換方便。 The power supply method and power supply device for the electrolytic ozone generator of the present invention are gradually raised and lowered, and the power supply and removal of the electrolytic ozone generator are performed in a stepwise lifting mode or a slow lifting mode. The power supply device includes an AC / DC power converter, a micro-control chip MCU, a constant current generating circuit, an ozone generator, and an electrolytic water bucket. The invention improves the service life of the generator, has a simple and practical structure, and is convenient for users to install and replace.

Description

電解臭氧發生器緩升緩降的供電方法及供電裝置 Power supply method and power supply device for electrolytic ozone generator

本發明涉及一種以水為原料的電解臭氧發生器緩升緩降的供電方法及供電裝置,其屬於電解臭氧發生器之技術領域。 The invention relates to a power supply method and a power supply device for an electrolytic ozone generator that uses water as a raw material, and belongs to the technical field of electrolytic ozone generators.

坊間目前以水為原料的電解臭氧發生器的供電方式,是使用時暫態上電且停止使用時為即時斷電方式或者是發生器持續供電。其有如下缺點:在很多應用領域發生器不能持續供電,若採用即時斷電方式,則在斷電瞬間膜兩側積聚的氫、氧離子會向相反方向擴散形成反向電流,而反方向擴散的氫、氧離子會對陽極、陰極的催化劑層產生破壞,因而造成發生器使用壽命會大幅度降低。並且目前以水為原料的電解臭氧發生器採用外裝式結構,其有如下缺點:在一些應用領域外裝式結構發生器的安裝和更換比較繁瑣,而且陰極會有少量水排出,給使用者造成不便。 The current power supply method of electrolytic ozone generators using water as a raw material is to power on temporarily when in use, and to immediately power off when the device is stopped, or to continuously supply power to the generator. It has the following disadvantages: in many fields of application, the generator cannot continue to supply power. If an instant power-off method is used, the hydrogen and oxygen ions accumulated on both sides of the membrane at the moment of power-off will diffuse in the opposite direction to form a reverse current, and the opposite direction will diffuse. The hydrogen and oxygen ions will damage the catalyst layers of the anode and cathode, which will cause the service life of the generator to be greatly reduced. Moreover, the current electrolytic ozone generator using water as the raw material adopts an external structure, which has the following disadvantages: in some application fields, the installation and replacement of the external structure generator is cumbersome, and a small amount of water will be discharged from the cathode to the user. cause inconvenience.

發明人有鑑於此,特以研創成本案,期能藉本 案之提出,俾改進現有缺點,期使該產品之功能得以更臻完善且理想,符合實際需求。 In view of this, the inventor specially researched the cost case and hoped to borrow The proposal proposes to improve the existing shortcomings, so that the function of the product can be more perfect and ideal, and meet the actual needs.

本發明的目的在於克服上述已有技術的不足而提供一種提高發生器使用壽命,結構簡單實用、使用者安裝和更換方便的電解臭氧發生器緩升緩降的供電方法及供電裝置。 The purpose of the present invention is to overcome the shortcomings of the prior art and provide a power supply method and a power supply device for an electrolytic ozone generator that has a long service life, a simple and practical structure, and is easy to install and replace by a user.

本發明可以通過如下措施來達到:一種電解臭氧發生器緩升緩降的供電方法,其特徵在於其包括如下步驟:在為電解臭氧發生器供電初始,首先提供1.5V到2.3V的初始電壓,然後逐漸提高電壓至發生器恆流供電區域,此後將以恆定電流為發生器供電;在為電解臭氧發生器供電結束時,首先逐漸降低電壓脫離發生器恆流供電區域,直至初始電壓值,然後停止電解臭氧發生器供電或長時間維持1.5V到2.3V的初始電壓值供電。 The present invention can be achieved by the following measures: A method for power supply of an electrolytic ozone generator that is slowly rising and falling, which is characterized in that it includes the following steps: at the beginning of supplying power to the electrolytic ozone generator, an initial voltage of 1.5V to 2.3V is first provided, Then gradually increase the voltage to the constant current power supply area of the generator, and then power the generator with a constant current; at the end of powering the electrolytic ozone generator, first gradually reduce the voltage and leave the constant current power supply area of the generator until the initial voltage value, and then Stop the power supply of the electrolytic ozone generator or maintain the initial voltage value of 1.5V to 2.3V for a long time.

為了進一步實現本發明的目的,所述的初始電壓為1.5V到2.3V,所述逐漸提高電壓至發生器恆流供電區域的過程為5秒,所述逐漸降低電壓脫離發生器恆流供電區域,直至初始電壓值的過程為10秒,然後維持至少3分鐘,然後停止電解臭氧發生器供電或長時間維持1.5V到2.3V的初始電壓值供電。 In order to further achieve the purpose of the present invention, the initial voltage is 1.5V to 2.3V, the process of gradually increasing the voltage to the constant current power supply area of the generator is 5 seconds, and the gradually decreasing voltage leaves the constant current power supply area of the generator The process until the initial voltage value is 10 seconds, then it is maintained for at least 3 minutes, and then the power supply of the electrolytic ozone generator is stopped or the power supply of the initial voltage value of 1.5V to 2.3V is maintained for a long time.

一種電解臭氧發生器緩升緩降供電裝置,其特徵在於其包括AC/DC電源變換器、微型控制晶片MCU、恆流產生電路、臭氧發生器和電解水桶;AC/DC電源變換器分別 連接微型控制晶片MCU、恆流產生電路,微型控制晶片MCU連接恆流產生電路,恆流產生電路連接臭氧發生器,臭氧發生器連接電解水桶。 An electrolytic ozone generator slowly rising and falling power supply device is characterized in that it includes an AC / DC power converter, a micro control chip MCU, a constant current generating circuit, an ozone generator, and an electrolytic water bucket; the AC / DC power converters are respectively The micro control chip MCU and the constant current generating circuit are connected, the micro control chip MCU is connected to the constant current generating circuit, the constant current generating circuit is connected to an ozone generator, and the ozone generator is connected to an electrolytic bucket.

為了進一步實現本發明的目的,所述的所述恆流產生電路包括與微型控制晶片MCU相連的電阻R1、電阻R9,電阻R1分別連接電容C2的一端、三極管N2的基極,電容C2的另一端連接三極管N2的發射極,三極管N2的集電極連接電阻R4的一端,電阻R4的另一端分別連接電容C3的一端、電阻R5的一端,降壓型直流電源變換晶片U2(XL4016)的2腳,電容C3的另一端、電阻R5的另一端分別連接三極管N2的發射極、電容C1的一端、集成運算放大器U1(LM321)的2腳,降壓型直流電源變換晶片U2(XL4016)的2腳分別連接二極體D7的負極、電阻R6的一端,降壓型直流電源變換晶片U2(XL4016)的5腳分別連接電容C5的一端、電容C4的一端、電解電容E1的一端、電感ID2的一端,降壓型直流電源變換晶片U2(XL4016)的4腳連接電容C5的另一端,降壓型直流電源變換晶片U2(XL4016)的3腳分別連接電阻R7的一端、穩壓二極體D6的負極、電感ID4的一端,電阻R7的另一端連接電容C6的一端,電感ID4的另一端分別連接電容C7的一端、電解電容E2的一端、電阻R6的另一端、電容C8的一端、電解電容E3的一端,電解電容E1的另一端、電容C4的另一端、降壓型直流電源變換晶片U2(XL4016)的1腳、電容C6的另一端、穩壓二極體D6的正極、電容C7的另一端、電解電容E2的另一端、電阻R8的一端相連,電阻R8的另一端、集成運算放大器U1(LM321)的1腳、電容C8的另一端、電解電容E3的另一端、繼電器JD1的動觸點相連; 集成運算放大器U1(LM321)的5腳連接電感ID2的另一端、電容C1的另一端,集成運算放大器U1(LM321)的4腳連接二極體D7的正極、電位器RV1的一端,集成運算放大器U1(LM321)的3腳連接電阻R3的一端、電阻R2的一端,電位器RV1的另一端與電阻R2的另一端相連;電阻R9的另一端連接電容C19的一端、三極管N1的基極,電容C19的另一端和三極管N1的發射極相連,三極管N1的集電極與繼電器JD1的線圈一端連接,繼電器JD1的常開點連接臭氧發生器OG的陰極,臭氧發生器OG的陽極連接電解電容E3的一端。 In order to further achieve the purpose of the present invention, the constant current generating circuit includes a resistor R1 and a resistor R9 connected to the micro control chip MCU, and the resistor R1 is respectively connected to one end of the capacitor C2 and the base of the transistor N2. One end is connected to the emitter of transistor N2, the collector of triode N2 is connected to one end of resistor R4, the other end of resistor R4 is connected to one end of capacitor C3 and one end of resistor R5, and two pins of step-down DC power conversion chip U2 (XL4016) The other end of capacitor C3 and the other end of resistor R5 are respectively connected to the emitter of transistor N2, one end of capacitor C1, two feet of integrated operational amplifier U1 (LM321), and two feet of step-down DC power conversion chip U2 (XL4016). Connect the negative terminal of diode D7 and one end of resistor R6 respectively. Pin 5 of the step-down DC power conversion chip U2 (XL4016) is connected to one end of capacitor C5, one end of capacitor C4, one end of electrolytic capacitor E1, and one end of inductor ID2. , 4 pins of the step-down DC power conversion chip U2 (XL4016) are connected to the other end of the capacitor C5, and 3 pins of the step-down DC power conversion chip U2 (XL4016) are connected to one end of the resistor R7 and the voltage regulator diode D6 respectively. Negative electrode, one end of inductor ID4, the other end of resistor R7 is connected to one end of capacitor C6, the other end of inductor ID4 is connected to one end of capacitor C7, one end of electrolytic capacitor E2, the other end of resistor R6, one end of capacitor C8, and electrolytic capacitor E3 One end of electrolytic capacitor E1, the other end of capacitor C4, one pin of step-down DC power conversion chip U2 (XL4016), the other end of capacitor C6, the positive pole of voltage regulator diode D6, and the other of capacitor C7 One end is connected to the other end of electrolytic capacitor E2 and one end of resistor R8. The other end of resistor R8, one pin of integrated operational amplifier U1 (LM321), the other end of capacitor C8, the other end of electrolytic capacitor E3, and the moving contact of relay JD1. Point connected The 5 pin of the integrated operational amplifier U1 (LM321) is connected to the other end of the inductor ID2 and the other end of the capacitor C1. The 4 pin of the integrated operational amplifier U1 (LM321) is connected to the anode of the diode D7 and one end of the potentiometer RV1. The integrated operational amplifier Pin 3 of U1 (LM321) is connected to one end of resistor R3 and one end of resistor R2, the other end of potentiometer RV1 is connected to the other end of resistor R2; the other end of resistor R9 is connected to one end of capacitor C19, the base of transistor N1, and the capacitor The other end of C19 is connected to the emitter of transistor N1. The collector of transistor N1 is connected to one end of the coil of relay JD1. The normally open point of relay JD1 is connected to the cathode of ozone generator OG. The anode of ozone generator OG is connected to electrolytic capacitor E3. One end.

為了進一步實現本發明的目的,所述的臭氧發生器包括陰極結構和陽極結構,陰極結構包括下加強鈦板,下加強鈦板上接有陽極導電螺柱,下加強鈦板上設有陰極框體,陰極框體上加工有陰極導水導氣孔,陰極框體上設有陰極導電板,陰極導電板上加工有導水導氣孔,陰極導電板連接有陰極導電螺柱,陰極導電板上設有陰極微孔鈦板,陰極微孔鈦板上設有陰極催化劑層,陰極催化劑層上設有質子交換膜,質子交換膜與陰極框體之間設有O型密封圈;陽極結構包括上加強鈦板,上加強鈦板上加工陽極有導水導氣孔,上加強鈦板下設有陽極框體,陽極框體內設有陽極微孔鈦板,陽極微孔鈦板下設有陽極催化劑層;下加強鈦板、陰極框體、陰極導電板、O型密封圈、陰極微孔鈦板、陰極催化劑層、質子交換膜與陽極催化劑層、陽極微孔鈦板、陽極框體、上加強鈦板通過螺絲緊固在一起。 In order to further achieve the objective of the present invention, the ozone generator includes a cathode structure and an anode structure. The cathode structure includes a lower reinforced titanium plate, an anode conductive stud is connected to the lower reinforced titanium plate, and a cathode frame is provided on the lower reinforced titanium plate. The cathode frame is provided with a cathode water-conducting air hole. The cathode frame is provided with a cathode conductive plate. The cathode conductive plate is processed with a water-conducting air hole. The cathode conductive plate is connected with a cathode conductive stud. The cathode conductive plate is provided with a cathode. A microporous titanium plate, a cathode microporous titanium plate is provided with a cathode catalyst layer, a proton exchange membrane is provided on the cathode catalyst layer, and an O-shaped seal ring is provided between the proton exchange membrane and the cathode frame; the anode structure includes an upper reinforced titanium plate In the upper reinforced titanium plate, the anode has water and air holes. The anode frame is arranged under the upper reinforced titanium plate. The anode microporous titanium plate is arranged in the anode frame. The anode catalyst layer is arranged under the anode microporous titanium plate. Plate, cathode frame, cathode conductive plate, O-ring seal, cathode microporous titanium plate, cathode catalyst layer, proton exchange membrane and anode catalyst layer, anode microporous titanium plate, anode frame, upper Strong titanium screws are fastened together.

為了進一步實現本發明的目的,所述的陰極結構通過陰極導電螺柱經過電解水桶底部通入桶外;陽極結 構通過陽極導電螺柱通過電解水桶底部通入桶外並通過螺帽緊固;陰極導電柱與恆流產生電路的電解電容E相連,陽極導電螺柱與恆流產生電路的繼電器JD1的常開點相連。 In order to further achieve the objective of the present invention, the cathode structure is passed through the bottom of the electrolytic water bucket through the cathode conductive stud to the outside of the bucket; the anode junction The anode conductive stud passes through the bottom of the electrolytic water bucket to the outside of the bucket and is fastened by a nut; the cathode conductive stud is connected to the electrolytic capacitor E of the constant current generating circuit, and the anode conductive stud is normally open to the relay JD1 of the constant current generating circuit. Connected.

本發明與已有技術相比具有如下積極效果:由於本發明的供電裝置實現供電的緩升緩降,在發生器開啟時的供電初期,緩慢提高發生器的供電電壓,發生器質子交換膜兩側逐漸建立氫、氧離子的梯度分佈,在發生器關閉時的供電的末期,緩慢降低發生器的供電電壓,發生器膜兩側逐漸降低氫、氧離子的梯度分佈,從而避免氫、氧離子的反方向擴散,也就避免了氫、氧離子對催化劑產生破壞,因此在間斷使用的應用領域,可大幅提高發生器使用壽命。且本發明的電解臭氧發生器為沒入式結構,結構簡單實用、使用者安裝和更換操作簡便。 Compared with the prior art, the present invention has the following positive effects: Because the power supply device of the present invention realizes the slowly rising and falling power supply, the power supply voltage of the generator is slowly increased during the initial power supply period when the generator is turned on, and the generator proton exchange membrane The gradient distribution of hydrogen and oxygen ions is gradually established on the side. At the end of the power supply when the generator is turned off, the power supply voltage of the generator is slowly reduced. The gradient distribution of hydrogen and oxygen ions is gradually reduced on both sides of the generator membrane to avoid hydrogen and oxygen ions. Diffusion in the opposite direction prevents hydrogen and oxygen ions from damaging the catalyst. Therefore, in the field of intermittent use, the service life of the generator can be greatly improved. In addition, the electrolytic ozone generator of the present invention has a submerged structure, which has a simple and practical structure, and is easy for users to install and replace.

1‧‧‧AC/DC電源變換器 1‧‧‧AC / DC power converter

2‧‧‧微型控制晶片MCU 2‧‧‧Microcontroller MCU

3‧‧‧恆流產生電路 3‧‧‧Constant current generating circuit

4‧‧‧臭氧發生器 4‧‧‧Ozone generator

4-10‧‧‧下加強鈦板 4-10‧‧‧ lower reinforced titanium plate

4-10-1‧‧‧陽極導電螺柱 4-10-1‧‧‧Anode conductive studs

4-1‧‧‧陰極框體 4-1‧‧‧ cathode frame

4-1-1‧‧‧陰極導水導氣孔 4-1-1‧‧‧cathode water-conducting and air-conducting holes

4-11‧‧‧O型密封圈 4-11‧‧‧O-ring

4-12‧‧‧陰極導電板 4-12‧‧‧ cathode conductive plate

4-12-1‧‧‧陰極導電螺柱 4-12-1‧‧‧ cathode conductive stud

4-12-2‧‧‧導水導氣孔 4-12-2‧‧‧ Water and air holes

4-2‧‧‧陽極框體 4-2‧‧‧Anode frame

4-3‧‧‧螺絲 4-3‧‧‧Screw

4-4‧‧‧陽極微孔鈦板 4-4‧‧‧Anode microporous titanium plate

4-5‧‧‧陽極催化劑層 4-5‧‧‧Anode catalyst layer

4-6‧‧‧質子交換膜 4-6‧‧‧ proton exchange membrane

4-7‧‧‧陰極微孔鈦板 4-7‧‧‧ cathode microporous titanium plate

4-8‧‧‧陰極催化劑層 4-8‧‧‧ cathode catalyst layer

4-9‧‧‧上加強鈦板 4-9‧‧‧upper reinforced titanium plate

4-9-1‧‧‧導水導氣孔 4-9-1‧‧‧ Water and air holes

5‧‧‧電解水桶 5‧‧‧electrolytic bucket

6‧‧‧螺帽 6‧‧‧nut

第一圖為本發明的供電裝置的結構示意圖;第二圖為本發明供電裝置的微型控制晶片MCU和恆流產生電路部分的電路原理圖;第三圖為本發明的階梯升降方式供電的電壓波形曲線;第四圖為本發明的緩慢升降方式供電的電壓波形曲線;第五圖為本發明的長時間維持初始電壓值的階梯升降方式供電的電壓波形曲線; 第六圖為本發明的長時間維持初始電壓值的緩慢升降方式供電的電壓波形曲線;第七圖為本發明的臭氧發生器的結構示意圖;第八圖為本發明的臭氧發生器與電解水桶的安裝結構示意圖。 The first diagram is a schematic structural diagram of a power supply device according to the present invention; the second diagram is a circuit schematic diagram of a micro control chip MCU and a constant current generating circuit part of the power supply device according to the present invention; Waveform curve; the fourth graph is the voltage waveform curve of the power supply in the slow rise and fall mode of the present invention; the fifth graph is the voltage waveform curve of the power supply in the stepwise rise and fall mode of maintaining the initial voltage value for a long time according to the present invention; The sixth figure is a voltage waveform curve of the power supply in a slow rise and fall mode that maintains the initial voltage value for a long time according to the present invention; the seventh figure is a schematic diagram of the structure of the ozone generator of the present invention; the eighth figure is the ozone generator and the electrolytic water bucket of the present invention Schematic diagram of the installation structure.

茲謹就本發明電解臭氧發生器緩升緩降的供電方法及供電裝置其結構組成,及所能產生的功效,配合圖式,舉一本案之較佳實施例詳細說明如下。 The structure and composition of the power supply method and power supply device of the electrolytic ozone generator according to the present invention are described in detail as follows.

如實施例,該種電解臭氧發生器緩升緩降的供電方法,其具體包括如下步驟:在為電解臭氧發生器供電初始,首先提供較低的初始電壓(1.5V到2.3V的電壓,優選1.9V),然後逐漸提高電壓至發生器恆流供電區域(上升過程優選5秒),此後將以恆定電流為電解臭氧發生器供電。在為電解臭氧發生器供電結束時,首先逐漸降低電壓脫離發生器恆流供電區域,直至初始電壓值(下降過程優選10秒),然後維持一段時間(優選3分鐘),然後停止電解臭氧發生器供電。 As shown in the embodiment, the power supply method of the electrolytic ozone generator is as follows, which includes the following steps: at the beginning of supplying power to the electrolytic ozone generator, a lower initial voltage (a voltage of 1.5V to 2.3V is preferred, preferably 1.9V), and then gradually increase the voltage to the constant current power supply area of the generator (the rising process is preferably 5 seconds), after which the electrolytic ozone generator will be powered with a constant current. At the end of powering the electrolytic ozone generator, first gradually reduce the voltage and leave the constant current power supply area of the generator until the initial voltage value (decreasing process is preferably 10 seconds), then maintain it for a period of time (preferably 3 minutes), and then stop the electrolytic ozone generator powered by.

一種電解臭氧發生器緩升緩降供電裝置(參見第一圖與第二圖),其包括AC/DC電源變換器1、微型控制晶片MCU2、恆流產生電路3、臭氧發生器4和電解水桶5。AC/DC電源變換器1分別連接微型控制晶片MCU2、恆流產生電路 3,微型控制晶片MCU2連接恆流產生電路3,恆流產生電路3連接臭氧發生器4,臭氧發生器4通過螺帽6與電解水桶5連接。 An electrolytic ozone generator slowly rising and falling power supply device (see first and second figures), which includes an AC / DC power converter 1, a micro control chip MCU2, a constant current generating circuit 3, an ozone generator 4, and an electrolytic water bucket. 5. AC / DC power converter 1 is connected to micro control chip MCU2 and constant current generation circuit respectively 3. The micro control chip MCU2 is connected to the constant current generating circuit 3, the constant current generating circuit 3 is connected to the ozone generator 4, and the ozone generator 4 is connected to the electrolytic bucket 5 through the nut 6.

所述恆流產生電路3包括與微型控制晶片MCU2相連的電阻R1、電阻R9,電阻R1分別連接電容C2的一端、三極管N2的基極,電容C2的另一端連接三極管N2的發射極,三極管N2的集電極連接電阻R4的一端,電阻R4的另一端分別連接電容C3的一端、電阻R5的一端,降壓型直流電源變換晶片U2(XL4016)的2腳,電容C3的另一端、電阻R5的另一端分別連接三極管N2的發射極、電容C1的一端、集成運算放大器U1(LM321)的2腳,降壓型直流電源變換晶片U2(XL4016)的2腳分別連接二極體D7的負極、電阻R6的一端,降壓型直流電源變換晶片U2(XL4016)的5腳分別連接電容C5的一端、電容C4的一端、電解電容E1的一端、電感ID2的一端,降壓型直流電源變換晶片U2(XL4016)的4腳連接電容C5的另一端,降壓型直流電源變換晶片U2(XL4016)的3腳分別連接電阻R7的一端、穩壓二極體D6的負極、電感ID4的一端,電阻R7的另一端連接電容C6的一端,電感ID4的另一端分別連接電容C7的一端、電解電容E2的一端、電阻R6的另一端、電容C8的一端、電解電容E3的一端,電解電容E1的另一端、電容C4的另一端、降壓型直流電源變換晶片U2(XL4016)的1腳、電容C6的另一端、穩 壓二極體D6的正極、電容C7的另一端、電解電容E2的另一端、電阻R8的一端相連,電阻R8的另一端、集成運算放大器U1(LM321)的1腳、電容C8的另一端、電解電容E3的另一端、繼電器JD1的動觸點相連;集成運算放大器U1(LM321)的5腳連接電感ID2的另一端、電容C1的另一端,集成運算放大器U1(LM321)的4腳連接二極體D7的正極、電位器RV1的一端,集成運算放大器U1(LM321)的3腳連接電阻R3的一端、電阻R2的一端,電位器RV1的另一端與電阻R2的另一端相連;電阻R9的另一端連接電容C19的一端、三極管N1的基極,電容C19的另一端和三極管N1的發射極相連,三極管N1的集電極與繼電器JD1的線圈一端連接,繼電器JD1的常開點連接臭氧發生器OG的陰極,臭氧發生器OG的陽極連接電解電容E3的一端。 The constant current generating circuit 3 includes a resistor R1 and a resistor R9 connected to the micro control chip MCU2. The resistor R1 is connected to one end of the capacitor C2 and the base of the transistor N2, and the other end of the capacitor C2 is connected to the emitter of the transistor N2 and the transistor N2. The collector is connected to one end of resistor R4, and the other end of resistor R4 is connected to one end of capacitor C3 and one end of resistor R5, two pins of a step-down DC power conversion chip U2 (XL4016), the other end of capacitor C3, and resistor R5 The other end is connected to the emitter of the transistor N2, one end of the capacitor C1, and two pins of the integrated operational amplifier U1 (LM321), and two pins of the step-down DC power conversion chip U2 (XL4016) are respectively connected to the anode and resistor of the diode D7. One end of R6, 5 pins of step-down DC power conversion chip U2 (XL4016) are connected to one end of capacitor C5, one end of capacitor C4, one end of electrolytic capacitor E1, one end of inductor ID2, and step-down DC power conversion chip U2 ( 4 pins of XL4016) are connected to the other end of capacitor C5, and 3 pins of step-down DC power conversion chip U2 (XL4016) are connected to one end of resistor R7, the negative pole of voltage regulator diode D6, one end of inductor ID4, and the end of resistor R7. another Connect one end of capacitor C6 and the other end of inductor ID4 to one end of capacitor C7, one end of electrolytic capacitor E2, the other end of resistor R6, one end of capacitor C8, one end of electrolytic capacitor E3, the other end of electrolytic capacitor E1, and capacitor C4 The other end of the step-down DC power conversion chip U2 (XL4016), the other end of the capacitor C6, stable The anode of the diode D6, the other end of the capacitor C7, the other end of the electrolytic capacitor E2, one end of the resistor R8, the other end of the resistor R8, the one pin of the integrated operational amplifier U1 (LM321), the other end of the capacitor C8, The other end of the electrolytic capacitor E3 is connected to the moving contact of the relay JD1; the 5 pin of the integrated operational amplifier U1 (LM321) is connected to the other end of the inductor ID2 and the other end of the capacitor C1 is connected to the 4 pin of the integrated operational amplifier U1 (LM321). The positive electrode of the polar body D7, one end of the potentiometer RV1, the three pins of the integrated operational amplifier U1 (LM321) are connected to one end of the resistor R3 and one end of the resistor R2, and the other end of the potentiometer RV1 is connected to the other end of the resistor R2; The other end is connected to one end of capacitor C19 and the base of transistor N1. The other end of capacitor C19 is connected to the emitter of transistor N1. The collector of transistor N1 is connected to one end of the coil of relay JD1. The normally open point of relay JD1 is connected to the ozone generator. The cathode of OG and the anode of ozone generator OG are connected to one end of electrolytic capacitor E3.

採用本發明,在使用時,微型控制晶片MCU控制三極管N2先處於完全截止的狀態,三極管N1導通使繼電器JD1閉合為發生器OG供電。降壓型直流電源變換晶片U2(XL4016)的第2腳電壓恆定為1.25V,這時的供電電壓由電阻R5及電阻R6的數值確定(調整R5及R6的數值控制電壓在1.5V到2.3V的範圍,優選R5=20KΩ、R6=10KΩ,初始供電電壓約1.9V,),此時發生器OG只有微弱電流流過。然後微型控制晶片MCU輸出PWM波形控制三極管N2的導通截止的占空比,這時的供電電壓由電阻R5及電阻R6的數值以及N2 和R4等效阻值確定(優選的:R5=20KΩ、R6=10KΩ、R4=3KΩ),隨著三極管N2的導通截止的占空比的提高,為發生器OG供電的電壓逐漸提高,當達到發生器OG的額定工作電流時,供電電路進入恆流供電模式,恆流供電電流由集成運算放大器U1(LM321)控制,數值由採樣電阻R8及電阻R2、電阻R3及電位器RV1確定。停止使用時,微型控制晶片MCU輸出PWM波形控制三極管N2的導通截止的占空比逐漸降低,為發生器OG供電的電壓逐漸降低,直到三極管N2進入完全截止的狀態,同樣此時發生器OG也只有微弱電流流過。繼續等待一段時間(優選3分鐘),然後MCU控制三極管N1截止使繼電器斷開完全停止為發生器OG供電。階梯式供電波形如第三圖、第五圖所示,緩慢升降式供電波形如圖第四圖、第六圖所示。 With the present invention, when in use, the micro control chip MCU controls the transistor N2 to be completely cut off first, and the transistor N1 is turned on to close the relay JD1 to supply power to the generator OG. The voltage of pin 2 of the step-down DC power conversion chip U2 (XL4016) is constant to 1.25V. At this time, the power supply voltage is determined by the values of resistor R5 and resistor R6 (adjust the values of R5 and R6 to control the voltage between 1.5V and 2.3V. Range, preferably R5 = 20KΩ, R6 = 10KΩ, the initial supply voltage is about 1.9V,), at this time, only a weak current flows through the generator OG. Then the micro-control chip MCU outputs a PWM waveform to control the on-off duty ratio of the transistor N2. At this time, the power supply voltage is determined by the values of the resistors R5 and R6 and N2. And R4 equivalent resistance is determined (preferably: R5 = 20KΩ, R6 = 10KΩ, R4 = 3KΩ). As the duty cycle of the transistor N2 increases, the voltage that supplies the generator OG gradually increases. When the rated operating current of the generator OG, the power supply circuit enters the constant current power supply mode. The constant current power supply current is controlled by the integrated operational amplifier U1 (LM321), and the value is determined by the sampling resistor R8 and resistor R2, resistor R3 and potentiometer RV1. When discontinued, the micro-control chip MCU outputs PWM waveforms to control the duty cycle of the transistor N2 on and off gradually, and the voltage that supplies the generator OG gradually decreases until the transistor N2 enters a completely off state. At the same time, the generator OG also Only a weak current flows. Continue to wait for a period of time (preferably 3 minutes), and then the MCU controls the transistor N1 to turn off, so that the relay is disconnected and completely stops powering the generator OG. The stepped power supply waveform is shown in the third and fifth figures, and the slowly lifting power supply waveform is shown in the fourth and sixth figures.

優選的,供電爬升時間5-30秒,供電下降時間10-300秒。 Preferably, the power supply climb time is 5-30 seconds, and the power supply drop time is 10-300 seconds.

臭氧發生器(4)(參見第七圖、第八圖),所述的臭氧發生器4包括陰極結構和陽極結構,陰極結構包括下加強鈦板4-10,下加強鈦板4-10上接有陽極導電螺柱4-10-1,下加強鈦板4-10上設有陰極框體4-1,陰極框體4-1上加工有陰極導水導氣孔4-1-1,陰極框體4-1上設有陰極導電板4-12,陰極導電板4-12上加工有導水導氣孔4-12-2,陰極導電板4-12連接有陰極導電螺柱4-12-1,陰 極導電板4-12上設有陰極微孔鈦板4-7,陰極微孔鈦板4-7上設有陰極催化劑層4-8,陰極催化劑層4-8上設有質子交換膜4-6,質子交換膜4-6與陰極框體4-1之間設有O型密封圈4-11;陽極結構包括上加強鈦板4-9,上加強鈦板4-9上加工陽極有導水導氣孔4-9-1,上加強鈦板4-9下設有陽極框體4-2,陽極框體4-2內設有陽極微孔鈦板4-4,陽極微孔鈦板4-4下設有陽極催化劑層4-5;下加強鈦板4-10、陰極框體4-1、陰極導電板4-12、O型密封圈4-11、陰極微孔鈦板4-7、陰極催化劑層4-8、質子交換膜4-6與陽極催化劑層4-5、陽極微孔鈦板4-4、陽極框體4-2、上加強鈦板4-9通過螺絲4-3緊固在一起。陰極結構通過陰極導電螺柱4-12-1通過電解水桶5底部通入桶外;陽極結構通過陽極導電螺柱4-10-1通過電解水桶5底部通入桶外並通過螺帽6緊固;陰極導電柱4-12-1與恆流產生電路3的電解電容E相連,陽極導電螺柱4-10-1與恆流產生電路3的繼電器JD1的常開點相連。使用前將純淨水加入電解水桶中使發生器完全沒入水中,然後接通發生器供電裝置,使用過程中陰極排水還是留在桶中。在結構上由於陰陽極完全隔離,陰極導水導氣孔4-1-1記憶體留氣體使水斷開,避免形成導電通路,因此使用完成以後,斷開發生器供電裝置,發生器完全沒入水中,陰陽極間也是電氣絕緣的,從而保證發生器的使用壽命。當發生器出現異常需要更換時只需拆卸固定螺帽即 可。省時省力,快捷方便。 Ozone generator (4) (see Figures 7 and 8). The ozone generator 4 includes a cathode structure and an anode structure. The cathode structure includes a lower reinforced titanium plate 4-10 and a lower reinforced titanium plate 4-10. Connected with anode conductive studs 4-10-1, a cathode frame 4-1 is provided on the lower reinforced titanium plate 4-10, and cathode water guide air holes 4-1-1 are processed on the cathode frame 4-1. The cathode frame The body 4-1 is provided with a cathode conductive plate 4-12, the cathode conductive plate 4-12 is processed with a water conducting hole 4-12-2, and the cathode conductive plate 4-12 is connected with a cathode conductive stud 4-12-1, Overcast The cathode conductive plate 4-12 is provided with a cathode microporous titanium plate 4-7, the cathode microporous titanium plate 4-7 is provided with a cathode catalyst layer 4-8, and the cathode catalyst layer 4-8 is provided with a proton exchange membrane 4- 6. An O-ring 4-11 is provided between the proton exchange membrane 4-6 and the cathode frame 4-1; the anode structure includes an upper reinforced titanium plate 4-9, and the processed anode is provided with water conduction Air holes 4-9-1, anode frame 4-2 is provided on the upper reinforced titanium plate 4-9, anode microporous titanium plate 4-4, anode microporous titanium plate 4- 4 under the anode catalyst layer 4-5; lower reinforced titanium plate 4-10, cathode frame 4-1, cathode conductive plate 4-12, O-ring 4-11, cathode microporous titanium plate 4-7, The cathode catalyst layer 4-8, the proton exchange membrane 4-6 and the anode catalyst layer 4-5, the anode microporous titanium plate 4-4, the anode frame 4-2, and the upper reinforced titanium plate 4-9 are tightened by screws 4-3. Fixed together. The cathode structure passes through the bottom of the electrolytic water bucket 5 through the cathode conductive stud 4-12-1 and the anode structure passes through the bottom of the electrolytic water bucket 5 through the anode conductive stud 4-10-1 and is fastened through the nut 6 The cathode conductive post 4-12-1 is connected to the electrolytic capacitor E of the constant current generating circuit 3, and the anode conductive stud 4-10-1 is connected to the normally open point of the relay JD1 of the constant current generating circuit 3. Add pure water to the electrolytic water bucket before use to completely submerge the generator in water, and then connect the generator power supply device. The cathode drainage remains in the bucket during use. In terms of structure, the cathode and anode are completely isolated, and the cathode water-conducting air holes 4-1-1 retain the gas in the memory to disconnect the water to avoid the formation of a conductive path. Therefore, after the use is completed, the generator power supply device is disconnected and the generator is completely submerged in water. The anode and cathode are also electrically insulated to ensure the life of the generator. When the generator is abnormal and needs to be replaced, just remove the fixed nut can. Save time and effort, fast and convenient.

以上的實施例僅僅是對本發明的優選實施方式進行描述,並非對本發明的範圍進行限定,在不脫離本發明設計精神的前提下,本領域普通工程技術人員對本發明的技術方案作出的各種變形和改進,均應落入本發明的權利要求書確定的保護範圍內。 The above embodiments are merely descriptions of the preferred embodiments of the present invention, and are not intended to limit the scope of the present invention. Without departing from the design spirit of the present invention, various modifications and modifications made to the technical solution of the present invention by those skilled in the art can be made. Improvements should all fall within the protection scope determined by the claims of the present invention.

Claims (4)

一種電解臭氧發生器緩升緩降的供電方法,其特徵在於其包括如下步驟:在為電解臭氧發生器供電初始,首先提供1.5V到2.3V的初始電壓,然後逐漸提高電壓至發生器恆流供電區域,該過程為5秒;此後將以恆定電流為發生器供電;在為電解臭氧發生器供電結束時,首先逐漸降低電壓脫離發生器恆流供電區域,直至初始電壓值,該過程為10秒,然後維持至少3分鐘;然後停止電解臭氧發生器供電或長時間維持1.5V到2.3V的初始電壓值供電。An electrolytic ozone generator power supply method is characterized in that it includes the following steps: at the beginning of powering an electrolytic ozone generator, firstly provide an initial voltage of 1.5V to 2.3V, and then gradually increase the voltage to the generator constant current In the power supply area, the process is 5 seconds; thereafter, the generator will be supplied with a constant current; at the end of powering the electrolytic ozone generator, the voltage is gradually reduced from the generator constant current power supply area until the initial voltage value, and the process is 10 Seconds, and then maintain it for at least 3 minutes; then stop the power supply of the electrolytic ozone generator or maintain the initial voltage value of 1.5V to 2.3V for a long time. 一種電解臭氧發生器緩升緩降供電裝置,其特徵在於其包括AC/DC電源變換器(1)、微型控制晶片MCU(2)、恆流產生電路(3)、臭氧發生器(4)和電解水桶(5);AC/DC電源變換器(1)分別連接微型控制晶片MCU(2)、恆流產生電路(3),微型控制晶片MCU(2)連接恆流產生電路(3),恆流產生電路(3)連接臭氧發生器(4),臭氧發生器(4)連接電解水桶(5);其中,所述恆流產生電路(3)包括與微型控制晶片MCU(2)相連的電阻R1、電阻R9,電阻R1分別連接電容C2的一端、三極管N2的基極,電容C2的另一端連接三極管N2的發射極,三極管N2的集電極連接電阻R4的一端,電阻R4的另一端分別連接電容C3的一端、電阻R5的一端,降壓型直流電源變換晶片U2(XL4016)的2腳,電容C3的另一端、電阻R5的另一端分別連接三極管N2的發射極、電容C1的一端、集成運算放大器U1(LM321)的2腳,降壓型直流電源變換晶片U2(XL4016)的2腳分別連接二極體D7的負極、電阻R6的一端,降壓型直流電源變換晶片U2(XL4016)的5腳分別連接電容C5的一端、電容C4的一端、電解電容E1的一端、電感ID2的一端,降壓型直流電源變換晶片U2(XL4016)的4腳連接電容C5的另一端,降壓型直流電源變換晶片U2(XL4016)的3腳分別連接電阻R7的一端、穩壓二極體D6的負極、電感ID4的一端,電阻R7的另一端連接電容C6的一端,電感ID4的另一端分別連接電容C7的一端、電解電容E2的一端、電阻R6的另一端、電容C8的一端、電解電容E3的一端,電解電容E1的另一端、電容C4的另一端、降壓型直流電源變換晶片U2(XL4016)的1腳、電容C6的另一端、穩壓二極體D6的正極、電容C7的另一端、電解電容E2的另一端、電阻R8的一端相連,電阻R8的另一端、集成運算放大器U1(LM321)的1腳、電容C8的另一端、電解電容E3的另一端、繼電器JD1的動觸點相連;集成運算放大器U1(LM321)的5腳連接電感ID2的另一端、電容C1的另一端,集成運算放大器U1(LM321)的4腳連接二極體D7的正極、電位器RV1的一端,集成運算放大器U1(LM321)的3腳連接電阻R3的一端、電阻R2的一端,電位器RV1的另一端與電阻R2的另一端相連;電阻R9的另一端連接電容C19的一端、三極管N1的基極,電容C19的另一端和三極管N1的發射極相連,三極管N1的集電極與繼電器JD1的線圈一端連接,繼電器JD1的常開點連接臭氧發生器OG的陰極,臭氧發生器OG的陽極連接電解電容E3的一端。An electrolytic ozone generator slowly rising and falling power supply device is characterized in that it comprises an AC / DC power converter (1), a micro control chip MCU (2), a constant current generating circuit (3), an ozone generator (4), and Electrolytic water bucket (5); AC / DC power converter (1) is connected to micro control chip MCU (2) and constant current generating circuit (3), and micro control chip MCU (2) is connected to constant current generating circuit (3). The current generating circuit (3) is connected to the ozone generator (4), and the ozone generator (4) is connected to the electrolytic water bucket (5); wherein the constant current generating circuit (3) includes a resistor connected to the micro control chip MCU (2) R1, resistor R9, resistor R1 are connected to one end of capacitor C2 and the base of transistor N2, the other end of capacitor C2 is connected to the emitter of transistor N2, the collector of transistor N2 is connected to one end of resistor R4, and the other end of resistor R4 is respectively connected One end of capacitor C3 and one end of resistor R5, two pins of step-down DC power conversion chip U2 (XL4016), the other end of capacitor C3 and the other end of resistor R5 are connected to the emitter of transistor N2, one end of capacitor C1, and integrated Operational amplifier U1 (LM321) 2-pin, step-down DC power conversion chip U2 (XL4016) Pin 2 is connected to the negative electrode of diode D7 and one end of resistor R6 respectively. Pin 5 of the step-down DC power conversion chip U2 (XL4016) is connected to one end of capacitor C5, one end of capacitor C4, one end of electrolytic capacitor E1, and inductor ID2. One end of the step-down DC power conversion chip U2 (XL4016) is connected to the other end of the capacitor C5, and the other step of step-down DC power conversion chip U2 (XL4016) is connected to one end of the resistor R7 and the voltage regulator diode. The negative terminal of D6, one end of inductor ID4, the other end of resistor R7 is connected to one end of capacitor C6, the other end of inductor ID4 is connected to one end of capacitor C7, one end of electrolytic capacitor E2, the other end of resistor R6, one end of capacitor C8, and electrolysis One end of capacitor E3, the other end of electrolytic capacitor E1, the other end of capacitor C4, one pin of step-down DC power conversion chip U2 (XL4016), the other end of capacitor C6, the positive electrode of voltage regulator diode D6, and capacitor C7 The other end of the capacitor is connected to the other end of the electrolytic capacitor E2 and one end of the resistor R8. The other end of the resistor R8, pin 1 of the integrated operational amplifier U1 (LM321), the other end of the capacitor C8, the other end of the electrolytic capacitor E3, and the relay JD1. Moving contacts connected The 5 pin of the operational amplifier U1 (LM321) is connected to the other end of the inductor ID2 and the other end of the capacitor C1. The 4 pin of the integrated operational amplifier U1 (LM321) is connected to the anode of the diode D7 and one end of the potentiometer RV1, and the integrated operational amplifier U1 is connected. The 3 pin of (LM321) is connected to one end of resistor R3 and one end of resistor R2, and the other end of potentiometer RV1 is connected to the other end of resistor R2; the other end of resistor R9 is connected to one end of capacitor C19, the base of transistor N1, and capacitor C19 The other end is connected to the emitter of transistor N1. The collector of transistor N1 is connected to one end of the coil of relay JD1. The normally open point of relay JD1 is connected to the cathode of ozone generator OG. The anode of ozone generator OG is connected to one end of electrolytic capacitor E3. . 如請求項2所述的一種電解臭氧發生器緩升緩降供電裝置,其特徵在於所述的臭氧發生器(4)包括陰極結構和陽極結構,陰極結構包括下加強鈦板(4-10),下加強鈦板(4-10)上接有陽極導電螺柱(4-10-1),下加強鈦板(4-10)上設有陰極框體(4-1),陰極框體(4-1)上加工有陰極導水導氣孔(4-1-1),陰極框體(4-1)上設有陰極導電板(4-12),陰極導電板(4-12)上加工有導水導氣孔(4-12-2),陰極導電板(4-12)連接有陰極導電螺柱(4-12-1),陰極導電板(4-12)上設有陰極微孔鈦板(4-7),陰極微孔鈦板(4-7)上設有陰極催化劑層(4-8),陰極催化劑層(4-8)上設有質子交換膜(4-6),質子交換膜(4-6)與陰極框體(4-1)之間設有O型密封圈(4-11);陽極結構包括上加強鈦板(4-9),上加強鈦板(4-9)上加工陽極有導水導氣孔(4-9-1),上加強鈦板(4-9)下設有陽極框體(4-2),陽極框體(4-2)內設有陽極微孔鈦板(4-4),陽極微孔鈦板(4-4)下設有陽極催化劑層(4-5);下加強鈦板(4-10)、陰極框體(4-1)、陰極導電板(4-12)、O型密封圈(4-11)、陰極微孔鈦板(4-7)、陰極催化劑層(4-8)、質子交換膜(4-6)與陽極催化劑層(4-5)、陽極微孔鈦板(4-4)、陽極框體(4-2)、上加強鈦板(4-9)通過螺絲(4-3)緊固在一起。An electrolytic ozone generator ascending and descending power supply device according to claim 2, wherein the ozone generator (4) includes a cathode structure and an anode structure, and the cathode structure includes a lower reinforced titanium plate (4-10) An anode conductive stud (4-10-1) is connected to the lower reinforced titanium plate (4-10), and a cathode frame (4-1) and a cathode frame ( 4-1) is provided with a cathode water-conducting air-guiding hole (4-1-1), a cathode frame (4-1) is provided with a cathode conductive plate (4-12), and a cathode conductive plate (4-12) is processed The water conducting air hole (4-12-2), the cathode conductive plate (4-12) is connected with the cathode conductive stud (4-12-1), and the cathode conductive plate (4-12) is provided with a cathode microporous titanium plate ( 4-7), the cathode microporous titanium plate (4-7) is provided with a cathode catalyst layer (4-8), and the cathode catalyst layer (4-8) is provided with a proton exchange membrane (4-6) and a proton exchange membrane (4-6) An O-ring (4-11) is arranged between the cathode frame (4-1); the anode structure includes an upper reinforced titanium plate (4-9) and an upper reinforced titanium plate (4-9) The upper processing anode has water and air holes (4-9-1), an anode frame (4-2) is provided under the upper reinforced titanium plate (4-9), and anode microholes are provided in the anode frame (4-2). Titanium plate (4-4), anode microporous titanium plate ( 4-4) is provided with an anode catalyst layer (4-5); a lower reinforced titanium plate (4-10), a cathode frame (4-1), a cathode conductive plate (4-12), and an O-ring (4 -11), cathode microporous titanium plate (4-7), cathode catalyst layer (4-8), proton exchange membrane (4-6) and anode catalyst layer (4-5), anode microporous titanium plate (4- 4) The anode frame (4-2) and the upper reinforced titanium plate (4-9) are fastened together by screws (4-3). 如請求項3所述的一種電解臭氧發生器緩升緩降供電裝置,其特徵在於所述的陰極結構通過陰極導電螺柱(4-12-1)經過電解水桶(5)底部通入桶外;陽極結構通過陽極導電螺柱(4-10-1)通過電解水桶(5)底部通入桶外並通過螺帽(6)緊固;陰極導電柱(4-12-1)與恆流產生電路(3)的電解電容E相連,陽極導電螺柱(4-10-1)與恆流產生電路(3)的繼電器JD1的常開點相連。The slowly rising and falling power supply device for an electrolytic ozone generator according to claim 3, characterized in that the cathode structure passes through the bottom of the electrolytic water bucket (5) through the cathode conductive stud (4-12-1) to the outside of the bucket. ; The anode structure passes through the anode conductive stud (4-10-1) through the bottom of the electrolytic water bucket (5) to the outside of the barrel and is fastened by the screw cap (6); the cathode conductive stud (4-12-1) and constant current are generated The electrolytic capacitor E of the circuit (3) is connected, and the anode conductive stud (4-10-1) is connected to the normally open point of the relay JD1 of the constant current generating circuit (3).
TW107124591A 2018-07-17 2018-07-17 Power supply method and power supply device for electrolytic ozone generator TWI679310B (en)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI410526B (en) * 2009-09-03 2013-10-01
CN104018177A (en) * 2014-05-30 2014-09-03 李欣 New membrane electrode electrolysis ozone generator
CN105174386A (en) * 2015-10-10 2015-12-23 徐名勇 Tap water electrolysis device used for disinfection and sterilization and having electrode descaling function
CN106219691A (en) * 2016-10-09 2016-12-14 深圳欧威奇科技有限公司 A kind of ozonated water generator

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI410526B (en) * 2009-09-03 2013-10-01
CN104018177A (en) * 2014-05-30 2014-09-03 李欣 New membrane electrode electrolysis ozone generator
CN105174386A (en) * 2015-10-10 2015-12-23 徐名勇 Tap water electrolysis device used for disinfection and sterilization and having electrode descaling function
CN106219691A (en) * 2016-10-09 2016-12-14 深圳欧威奇科技有限公司 A kind of ozonated water generator

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