TWI666810B - Fuel cell device - Google Patents

Fuel cell device Download PDF

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Publication number
TWI666810B
TWI666810B TW105128232A TW105128232A TWI666810B TW I666810 B TWI666810 B TW I666810B TW 105128232 A TW105128232 A TW 105128232A TW 105128232 A TW105128232 A TW 105128232A TW I666810 B TWI666810 B TW I666810B
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zinc
fuel cell
air fuel
connection port
cell device
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TW105128232A
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TW201810796A (en
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廖文煌
賴添義
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有生科技有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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Abstract

本發明燃料電池裝置,包含連通座及複數個鋅空氣燃料電池,連通座具有複數個的組接部,且連通座的內部設有複數個通道連接每一個組接部,使組接部分別形成有入料口及出料口,鋅空氣燃料電池具有開放狀態的反應空間,鋅空氣燃料電池分別安裝於組接部,使反應空間形成密閉狀態,且反應空間的內部設有鋅材料,使得反應空間分隔成反應區及氣隔區,而出料口位於反應區內,入料口位於氣隔區內,據此,由連通座內部的通道將鋅空氣燃料電池之間相互連接導通,供鋅空氣燃料電池內能夠產生氧化還原反應的化學材料能夠於透過通道流通於不同的鋅空氣燃料電池中。The fuel cell device of the present invention includes a connecting base and a plurality of zinc-air fuel cells. The connecting base has a plurality of connecting parts, and the inside of the connecting base is provided with a plurality of channels to connect each of the connecting parts, so that the connecting parts are formed separately. There are inlets and outlets. Zinc-air fuel cells have open reaction spaces. Zinc-air fuel cells are separately installed in the assembly part to make the reaction space closed, and the inside of the reaction space is provided with zinc materials to make the reaction. The space is divided into a reaction zone and a gas compartment, and the discharge outlet is located in the reaction area and the inlet is located in the gas compartment. According to this, the channels inside the communication seat connect and connect the zinc air fuel cells to each other to supply zinc. Chemical materials that can produce redox reactions in air fuel cells can flow through different zinc-air fuel cells through the passages.

Description

燃料電池裝置Fuel cell device

本發明有關於一種鋅空氣燃料電池,尤指一種透過氣壓作為驅動源,進行持續性或間歇性推動化學反應原料之燃料電池裝置。The present invention relates to a zinc-air fuel cell, and more particularly to a fuel cell device that continuously or intermittently advances a chemical reaction raw material by using air pressure as a driving source.

幾世紀以來,由於人類大量地應用科技、製造工業,使得應用能源的面向及需求量急劇地增加,而傳統自然能源的開採及使用,例如:煤炭、石油、天然氣、火力等消耗量持續性地升高,人類造成地球出現一嚴重且不可逆反修復的環境污染及破壞,並間接地導致溫室效應、酸雨、與林消失、空氣汙染等自然現象持續性地存續與惡化。For centuries, due to the large-scale application of technology and manufacturing industries by human beings, the application and demand for applied energy have increased dramatically, while the extraction and use of traditional natural energy, such as coal, oil, natural gas, and firepower, have continued to be consumed. As people rise, humans cause a serious and irreversible environmental pollution and damage to the earth, and indirectly cause natural phenomena such as the greenhouse effect, acid rain, disappearance of forests, and air pollution to persist and worsen.

而基於人類清楚意識到並體認天然能源的存取量有限,將於不久後的未來消耗殆盡,再加上普遍環保意識的抬頭,讓許多國家鼓勵研究學者致力於合成、開採或研發替代性能源,而以尋求零污染或低汙染的環境友好能源為目標。Based on human beings' clear awareness and appreciation of the limited access to natural energy, which will be exhausted in the near future, coupled with the rise of general environmental awareness, many countries encourage research scholars to commit to synthesis, mining or research and development alternatives. Performance source, and the goal is to seek zero or low pollution environmentally friendly energy.

其中,燃料電池即為其中一種已開發且具發展潛力及實用價值的替代性能源,其具有能量轉換效率高、排出物質為乾淨氣體、低環境噪音等優點。Among them, the fuel cell is one of the alternative energy sources that has been developed and has development potential and practical value. It has the advantages of high energy conversion efficiency, clean exhaust gas, and low environmental noise.

本發明之主要目的在於,提供一能夠同時組接複數個鋅空氣燃料電池單元,並能夠使得複數個鋅空氣燃料電池單元彼此之間相互連接導通之定位裝置。The main object of the present invention is to provide a positioning device capable of assembling a plurality of zinc-air fuel cell units at the same time and enabling the plurality of zinc-air fuel cell units to be connected and conducted with each other.

本發明之主要目的在於,提供一種由氣體壓力作為驅動源,進行間歇性或持續性地以正壓或負壓驅動鋅空氣燃料電池單元內部的鋅原料流動的燃料電池裝置。A main object of the present invention is to provide a fuel cell device that uses gas pressure as a driving source to intermittently or continuously drive the flow of zinc raw materials in a zinc-air fuel cell unit with positive or negative pressure.

本發明之再一目的在於,設計一能夠供驅動氣體及鋅原料通過的導流路徑,氣體能夠於導流路徑中斷開每一鋅空氣燃料電池單元之間的電性連接,使得每一鋅空氣燃料電池分別獨立呈現為一接近真空氣密的樣態,致能夠加成每一鋅空氣燃料電池單元所產電量,能夠應用於小至3C電子產品、大至電動車的能源供給。Another object of the present invention is to design a diversion path that can drive gas and zinc raw materials to pass through. The gas can disconnect the electrical connection between each zinc air fuel cell unit in the diversion path, so that each zinc Air fuel cells are independently presented as close to vacuum and airtight, which can increase the amount of electricity produced by each zinc air fuel cell unit, which can be applied to the energy supply of electronic products as small as 3C and as large as electric vehicles.

本發明之另一目的在於,由持續性/間歇式流動的鋅原料依序地流經作為充電或放電效果的鋅空氣燃料電池單元,且每一鋅空氣燃料電池單元的結構完全相同,便可達到無須抽換、補充或增加鋅空氣燃料電池內部的化學原料之效果。Another object of the present invention is to continuously and intermittently flow the zinc raw material sequentially through the zinc-air fuel cell as a charging or discharging effect, and the structure of each zinc-air fuel cell is completely the same. To achieve the effect of no need to exchange, supplement or increase the chemical raw materials inside the zinc air fuel cell.

為達上述目的,本發明燃料電池裝置,包含:一連通座,具有複數個的組接部,且內部設有複數個通道連接每一個組接部,使上述組接部分別形成有一入料口以及一出料口;以及複數個鋅空氣燃料電池,具有一開放狀態的反應空間,並分別安裝於上述連通座的每一組接部,使上述反應空間形成一密閉狀態,且上述反應空間內部設有一能夠產生氧化還原反應的鋅材料,使得上述反應空間分隔成一一反應區以及一未包含鋅材料的氣隔區;其中,上述連通座的出料口位於上述反應空間的反應區內,而上述連通座的入料口則位於上述反應空間的氣隔區內。In order to achieve the above object, the fuel cell device of the present invention includes: a communication base, which has a plurality of assembling parts, and is provided with a plurality of channels to connect each assembling part, so that the assembling part is formed with a feeding port respectively. And a discharge port; and a plurality of zinc-air fuel cells, which have an open reaction space, and are respectively installed at each connection part of the communication seat, so that the reaction space forms a closed state, and the inside of the reaction space A zinc material capable of generating a redox reaction is provided, so that the above reaction space is divided into a reaction zone and an air separation zone not containing zinc material; wherein the outlet of the communication seat is located in the reaction zone of the reaction space, The inlet of the communication seat is located in the air compartment of the reaction space.

其中,上述燃料電池裝置進一步包含一壓差產生器,而上述連通座由上述複數通道形成有與上述壓差產生器安裝的一第一連接口以及一第二連接口,上述壓差產生器將上述第一連接口與第二連接口之間形成一壓力差,進而驅使每一鋅空氣燃料電池的鋅材料透過上述通道流動至另一鋅空氣燃料電池。Wherein, the fuel cell device further includes a pressure difference generator, and the communication seat is formed by the plurality of channels with a first connection port and a second connection port installed with the pressure difference generator, and the pressure difference generator will A pressure difference is formed between the first connection port and the second connection port, thereby driving the zinc material of each zinc-air fuel cell to flow through the channel to another zinc-air fuel cell.

於一較佳可行實施例中,上述連通座的複數個出料口分別位於各自對應反應區的高度位置皆不相同,且上述鋅空氣燃料電池與其他鋅空氣燃料電池彼此之間的反應區高度位置亦不相同。In a preferred and feasible embodiment, the plurality of outlets of the communication seat are located at different heights of their corresponding reaction zones, respectively, and the heights of the reaction zones between the zinc air fuel cell and other zinc air fuel cells are different. The locations are also different.

而且,上述通道包含一形成於連通座內部的連通段以及一突出於上述組接部的延伸段,而進入上述鋅空氣燃料電池內部的延伸段與其他鋅空氣燃料電池內部的延伸段彼此之間的相對高度位置皆不相同。Moreover, the channel includes a communication section formed inside the communication seat and an extension section protruding from the assembly part, and the extension section entering the inside of the zinc air fuel cell and the extension sections of other zinc air fuel cells are between each other. The relative height positions are different.

又,本發明作為驅動源的壓差產生器有三種較佳實施態樣,於一第一較佳可行實施例中,由上述第一連接口或第二連接口其中之一與一真空罐連通,而另一者直接與大氣壓力導通共同構成上述壓力差,而於一第二較佳可行實施例中,上述壓力差設為一同時連通於上述第一連接口及一第二連接口的真空罐,另於一第三較佳可行實施例中,上述壓力差設為一同時連通於上述第一連接口及一第二連接口的磁軸馬達。In addition, there are three preferred embodiments of the pressure difference generator of the present invention as a driving source. In a first preferred embodiment, one of the first connection port or the second connection port communicates with a vacuum tank. While the other directly constitutes the above-mentioned pressure difference with the atmospheric pressure conduction, and in a second preferred feasible embodiment, the above-mentioned pressure difference is set to a vacuum which is simultaneously connected to the first connection port and a second connection port In a third preferred embodiment, the pressure difference is a magnetic shaft motor connected to the first connection port and the second connection port.

此外,本發明鋅材料有兩種較佳實施態樣,於一第一較佳可行實施例中,上述鋅材料設為一可流動並呈現為泥狀樣態的鋅泥電極,由鋅泥電極依序地持續性流通於上述連通座的通道中以及不同的鋅空氣燃料電池中,而於一第二較佳可行實施例中,上述鋅材料設為一呈現為顆粒樣態或粉狀樣態或其混合構成的鋅砂,由於上述鋅砂留滯於鋅空氣燃料電池的反應區,於是配合一電解液持續性地流通於上述連通座的通道中以及不同的鋅空氣燃料電池中,上述電解液進入上述鋅空氣燃料電池中的反應區,並與上述鋅砂接觸後,共同產生化學充電或放電之氧化還原反應。In addition, the zinc material of the present invention has two preferred implementation modes. In a first preferred feasible embodiment, the above zinc material is set as a zinc mud electrode which can flow and present in a mud-like state. Continuously circulates sequentially in the channels of the above-mentioned communication seat and in different zinc-air fuel cells, and in a second preferred embodiment, the zinc material is set to be in a granular or powder state. Because the zinc sand stays in the reaction area of the zinc-air fuel cell due to the zinc sand or a mixture thereof, an electrolytic solution is continuously circulated in the channel of the communication seat and in different zinc-air fuel cells. After the liquid enters the reaction zone in the above zinc-air fuel cell and comes into contact with the above zinc sand, a redox reaction of chemical charging or discharging occurs together.

最後,為了配合上述鋅材料的第二較佳實施例,達到避免上述鋅砂進入上述連通座的通道中,遂於上述出料口進一步設有一過濾件,由上述過濾件限制上述鋅砂於反應空間中,並僅供上述電解液通過,而能夠從上述反應空間流入上述通道。Finally, in order to cooperate with the second preferred embodiment of the zinc material to prevent the zinc sand from entering the passage of the communication seat, a filter is further provided at the discharge port, and the filter limits the zinc sand to the reaction by the filter. The space is only allowed to pass through the electrolyte, and can flow into the channel from the reaction space.

由前述說明可知,本發明的特點在於:透過一具有通道的連通座將複數個鋅空氣燃料電池組裝,而上述鋅空氣燃料電池內部的鋅材料能夠透過上述通道依序的持續性/間歇性於上述通道及不同的鋅空氣燃料電池中流通移動,當上述鋅材料進入鋅空氣燃料電池中時,由上述鋅材料與鋅空氣燃料電池的電極管產生一氧化還原反應,而完成充電或放電的效果。As can be seen from the foregoing description, the present invention is characterized in that a plurality of zinc-air fuel cells are assembled through a communication seat with a channel, and the zinc material inside the zinc-air fuel cell can sequentially / continuously pass through the channels in a continuous / intermittent manner. The above channels and different zinc-air fuel cells circulate and move. When the zinc material enters the zinc-air fuel cell, the zinc material and the electrode tube of the zinc-air fuel cell produce a redox reaction to complete the effect of charging or discharging. .

而且,本發明能夠供鋅材料進行循環充電,放電,故無須重新置換或填充鋅空氣燃料電池內部中新的鋅材料。In addition, the invention can provide zinc materials for cyclic charging and discharging, so there is no need to replace or fill new zinc materials in the zinc air fuel cell.

另外,當壓差產生器以間歇性或持續性方式,利用正壓或負壓驅動氣體推動鋅泥電極或電解液,而鋅泥電極或電解液進入通道的過程中,氣體能夠將不同的鋅空氣燃料電池之間的通道加以區隔,使得不同的鋅空氣燃料電池之間的鋅泥電極或電解液彼此斷開,讓每一鋅空氣燃料電極分別獨立地成為單一充電或放電的電極管,如此一來,本發明燃料電池裝置便能夠加總每一鋅空氣燃料電極所產電量。In addition, when the differential pressure generator uses a positive or negative pressure to drive the zinc mud electrode or electrolyte in an intermittent or continuous manner, and the zinc mud electrode or electrolyte enters the channel, the gas can transfer different zinc The channels between the air fuel cells are separated, so that the zinc slime electrodes or electrolytes between different zinc air fuel cells are disconnected from each other, so that each zinc air fuel electrode independently becomes a single charged or discharged electrode tube, In this way, the fuel cell device of the present invention can sum up the amount of electricity produced by each zinc-air fuel electrode.

茲為便於更進一步對本發明之構造、使用及其特徵有更深一層明確、詳實的認識與瞭解,爰舉出較佳實施例,配合圖式詳細說明如下:In order to facilitate a deeper and clearer and more detailed understanding and understanding of the structure, use and characteristics of the present invention, the preferred embodiments are given below, and the detailed description in conjunction with the drawings is as follows:

請參照圖1至圖4所示,本發明燃料電池裝置1主要包含有一連通座2以及複數個鋅空氣燃料電池3兩大部分,上述連通座2的一側向內凹陷形成有複數個的組接部20,於一較佳實施例中,上述組接部20的內側形成一公螺紋201。Please refer to FIG. 1 to FIG. 4. The fuel cell device 1 of the present invention mainly includes a communication base 2 and a plurality of zinc-air fuel cells 3. One side of the communication base 2 is recessed inward to form a plurality of In a preferred embodiment, a male thread 201 is formed on the inner side of the aforementioned assembly portion 20.

而且,上述連通座2的內部形成有複數個通道21,上述通道21包含一形成於連通座2內部的連通段210以及一延伸突出於上述組接部20的延伸段211,由上述複數個通道21將每兩個組接部20彼此之間相互連接導通,使得上述通道21的末端於上述組接部20中分別形成有一入料口202以及一出料口203。Moreover, a plurality of channels 21 are formed inside the communication seat 2, and the channel 21 includes a communication section 210 formed inside the communication seat 2 and an extension section 211 extending and protruding from the assembling portion 20. 21 connects and connects each of the two assembling portions 20 with each other, so that an end of the channel 21 is formed in the assembling portion 20 with an inlet 202 and an outlet 203, respectively.

上述鋅空氣燃料電池3包含一殼體30、一容置於上述殼體30中的電極管31以及一容置於上述電極管31中的鋅材料4,上述電極管31的一端呈現一開放狀態,於一較佳實施例中,上述殼體30的一端形成有一對應於上述公螺紋201的母螺紋300,使得上述殼體30能夠與上述組接部20相互對應組接連結,並使得上述電極管31呈現一密閉狀態。The zinc-air fuel cell 3 includes a casing 30, an electrode tube 31 accommodated in the casing 30, and a zinc material 4 accommodated in the electrode tube 31. One end of the electrode tube 31 is in an open state. In a preferred embodiment, a female thread 300 corresponding to the male thread 201 is formed at one end of the casing 30, so that the casing 30 and the assembling portion 20 can be connected to each other in a corresponding combination, and the electrode is formed. The tube 31 assumes a closed state.

其中,如圖4所示,上述電極管31由內而外依序設為一反應空間32、一完整包覆於上述反應空間32外圍的金屬集電管33、一完整包覆於上述金屬集電管33外圍的隔離膜34以及一完整包覆於上述隔離膜34外圍的空氣電極35所構成,而上述殼體30套設組接於上述空氣電極35的外圍,且上述殼體30具有複數個供空氣進入上述空氣電極35的通孔301,上述殼體30與電極管31之間具有一簍空空間36與殼體30外部的空氣連接導通,其中,上述金屬集電管33的材料設為由銅或鎳其中之一所製成。Among them, as shown in FIG. 4, the above-mentioned electrode tube 31 is sequentially set from the inside to the outside as a reaction space 32, a metal current collector tube 33 completely covered on the periphery of the reaction space 32, and a metal sheath completely covered on the metal collector. The insulating film 34 on the periphery of the electric tube 33 and an air electrode 35 completely covering the periphery of the above-mentioned isolation film 34 are formed, and the casing 30 is sleeved and assembled on the periphery of the air electrode 35, and the casing 30 has a plurality of There are three through holes 301 for air to enter the air electrode 35. A hollow space 36 between the casing 30 and the electrode tube 31 is connected to the air outside the casing 30. The material of the metal collector tube 33 is provided. Made of either copper or nickel.

上述電極管31的反應空間32內部裝填一能夠配合上述殼體30及電極管31產生氧化還原反應的鋅材料4,使得上述反應空間32分隔成一置放上述鋅材料4的反應區320以及一未包含上述鋅材料4的氣隔區321,於本發明圖1至圖5D所示第一較佳可行實施例中,上述鋅材料4設為一可流動並呈現為泥狀樣態的鋅泥電極40。The reaction space 32 of the electrode tube 31 is filled with a zinc material 4 capable of cooperating with the casing 30 and the electrode tube 31 to generate a redox reaction, so that the reaction space 32 is divided into a reaction area 320 in which the zinc material 4 is placed and a The air separation region 321 including the zinc material 4 described above. In the first preferred feasible embodiment shown in FIG. 1 to FIG. 5D of the present invention, the zinc material 4 is set as a zinc mud electrode that is flowable and presents a mud-like state. 40.

其中,上述連通座2的出料口203位於上述反應空間32的反應區320內,而上述連通座2的入料口202位於上述反應空間32的氣隔區321內,於一較佳可行實施例中,本發明連通座2對應於每一管鋅空氣燃料電池3的延伸段211的長度皆不同,且每一管鋅空氣燃料電池3包含有鋅材料4的反應區320大小亦不同,此將進一步導致每一管鋅空氣燃料電池3中的上述出料口203對應於各自管中的反應區320的高度位置皆不相同的結果。The outlet 203 of the communication seat 2 is located in the reaction zone 320 of the reaction space 32, and the inlet 202 of the communication seat 2 is located in the air compartment 321 of the reaction space 32. In the example, the length of the extension section 211 corresponding to each tube of the zinc-air fuel cell 3 in the communication seat 2 of the present invention is different, and the reaction area 320 of each tube of the zinc-air fuel cell 3 containing the zinc material 4 is also different in size. This will further result in that the above-mentioned discharge outlets 203 in each tube of the zinc-air fuel cell 3 correspond to different height positions of the reaction zones 320 in the respective tubes.

如此一來,本發明燃料電池裝置1便能夠透過上述連通座2的組接部20與上述複數個鋅空氣燃料電池3組接連結,並透過上述連通座2的通道21分別將上述呈現為密閉狀態的鋅空氣燃料電池3彼此之間相互連接導通。In this way, the fuel cell device 1 of the present invention can be connected to the plurality of zinc-air fuel cells 3 through the assembly portion 20 of the communication seat 2, and the above are presented as closed through the channels 21 of the communication seat 2. The zinc-air fuel cells 3 in a state are connected to each other and conducted.

請接續參閱圖5A至圖5D所示,為本發明燃料電池裝置1的第一較佳實施例進一步配合一壓差產生器5之使用狀態說明,於此實施例中以四管組合的鋅空氣燃料電池3進行說明,上述四管組合的鋅空氣燃料電池3能夠透過一位於上述連通座2側面的導通孔24,將兩組各為兩管的鋅空氣燃料電池3完成四管組合的樣態,或者是由單一組四管樣態的鋅空氣燃料電池3完成四管組合的樣態,而上述導通孔24的兩端分別設為一導通於大氣壓力的第一導通孔以及一導通於其中一延伸段211的第二導通孔。但凡兩管、四管等其他偶數管組合的燃料電池裝置1皆能夠完成並實施本發明之目的。Please refer to FIG. 5A to FIG. 5D for a description of a first preferred embodiment of the fuel cell device 1 according to the present invention, further explaining a use state of a differential pressure generator 5. In this embodiment, a four-tube combination of zinc air is used. The fuel cell 3 will be described. The above-mentioned four-tube combination zinc-air fuel cell 3 can pass through a through hole 24 located on the side of the communication seat 2 to complete the four-tube combination of two sets of zinc-air fuel cells 3 each having two tubes. Or, a single-group four-tube zinc-air fuel cell 3 is used to complete a four-tube combination, and the two ends of the above-mentioned via 24 are respectively set as a first via that conducts to atmospheric pressure and a conductor in it. A second through hole of an extension section 211. Any other combination of even-numbered tubes, such as two-tube, four-tube, fuel cell device 1 can complete and implement the purpose of the present invention.

上述連通座2的外部形成有一第一連接口22及一第二連接口23,上述第一連接口22與第二連接口23分別與上述連通座2內部的通道21相互連接導通,上述第一連接口22對應設於第一管的鋅空氣燃料電池3的上方位置,而第二連接口23對應設於最末管(第四管)的鋅空氣燃料電池3的上方位置,於圖5A至圖5D所示上述壓差產生器5之第一較佳可行實施例為,上述壓差產生器5設為一真空罐50。A first connection port 22 and a second connection port 23 are formed on the outside of the communication seat 2. The first connection port 22 and the second connection port 23 are connected to the channel 21 inside the communication seat 2 to communicate with each other. The connection port 22 corresponds to a position above the zinc-air fuel cell 3 of the first tube, and the second connection port 23 corresponds to a position above the zinc-air fuel cell 3 of the last tube (fourth tube). The first preferred feasible embodiment of the pressure difference generator 5 shown in FIG. 5D is that the pressure difference generator 5 is set as a vacuum tank 50.

由上述第一連接口22或第二連接口23其中之一者與上述真空罐50安裝連通,而另一者直接與大氣壓力導通進而共同構成一介於上述第一管的鋅空氣燃料電池3以及最末管(第四管)的鋅空氣燃料電池3之間的壓力差,上述壓力差可設為一吸入或打入空氣氣體的負壓差或正壓差。One of the first connection port 22 or the second connection port 23 is installed in communication with the vacuum tank 50, and the other is directly connected to the atmospheric pressure to form a zinc-air fuel cell 3 interposed between the first tube and the first tube. The pressure difference between the zinc-air fuel cells 3 in the last tube (the fourth tube) can be set to a negative pressure difference or a positive pressure difference of the air gas drawn in or driven in.

如此一來,由上述真空罐50與大氣壓力構成的壓力差,迫使大氣壓力中的氣體從上述第一連接口22依序地進入上述連通座2的通道21、連通段210、第一管的鋅空氣燃料電池3的反應空間32、上述連通座2的延伸段211、連通段210、其他管的鋅空氣燃料電池3的反應空間32、上述連通座2的延伸段211、連通段210、最末管(第四管)的鋅空氣燃料電池3的反應空間32、上述連通座2的延伸段211、上述第二連接口23、以及上述真空罐50。In this way, the pressure difference formed by the vacuum tank 50 and the atmospheric pressure forces the gas in the atmospheric pressure to sequentially enter the channel 21, the communication section 210, and the first tube of the communication seat 2 from the first connection port 22 The reaction space 32 of the zinc-air fuel cell 3, the extension section 211 of the above-mentioned communication seat 2, the communication section 210, the reaction space 32 of the zinc-air fuel cell 3 of other pipes, the extension section 211 of the above-mentioned communication seat 2, the communication section 210, the most The reaction space 32 of the zinc-air fuel cell 3 of the last pipe (the fourth pipe), the extension 211 of the communication seat 2, the second connection port 23, and the vacuum tank 50.

而且,於氣體依循前述說明路徑流動行運的過程中,由於上述每一鋅空氣燃料電池3與連通座2安裝組接之下分別呈現為一密閉狀態,而且,上述通道21的延伸段211延伸進入上述第一管鋅空氣燃料電池3中包含有上述鋅泥電極40的反應區320內,故上述鋅泥電極40將受到前述氣體驅動進一步依循氣體的路徑流動,亦即是,由上述壓差產生器5於上述第一連接口22與第二連接口23之間形成一壓力差,驅使每一鋅空氣燃料電池3的鋅材料4透過上述通道21流動至另一鋅空氣燃料電池3。Moreover, in the process that the gas flows along the path described above, each of the zinc-air fuel cells 3 and the communication base 2 are installed in a sealed state under the installation and assembly, and the extension section 211 of the channel 21 extends. Enter the reaction zone 320 of the first tube zinc-air fuel cell 3 containing the zinc slime electrode 40, so the zinc slime electrode 40 will be driven by the gas to further follow the path of the gas, that is, by the pressure difference The generator 5 forms a pressure difference between the first connection port 22 and the second connection port 23 to drive the zinc material 4 of each zinc air fuel cell 3 to flow through the passage 21 to another zinc air fuel cell 3.

請再參照圖5A至圖5D所示,第一管鋅空氣燃料電池3透過上述第一連接口22與大氣壓力連接導通,而最末管(第四管)的鋅空氣燃料電池3透過上述第二連接口23組接於上述真空罐50,於上述真空罐50尚未啟動且尚未以負壓方式驅動氣體推動鋅泥電極40之狀態下,第一管的鋅空氣然電池3的反應區320中鋅泥電極40的位置高度最高,上述鋅泥電極40的位置依序遞減至最末管(第四管)的鋅空氣燃料電池3的反應區320中鋅泥電極40的位置高度最低,而第一管的鋅空氣然電池3的延伸段211的長度最長且出料口203相對於反應區320的位置最低(第一管的鋅空氣燃料電池3的延伸段211位於上述反應區320中,且上述延伸段211中同樣容納有上述鋅泥電極40)。Please refer to FIG. 5A to FIG. 5D again. The first tube of zinc air fuel cell 3 is connected to the atmospheric pressure through the first connection port 22, and the zinc tube of the last tube (fourth tube) passes through the first tube. The two connection ports 23 are connected to the above-mentioned vacuum tank 50. In a state where the above-mentioned vacuum tank 50 has not been started and the gas has not been driven by the negative pressure to push the zinc mud electrode 40, the first tube of zinc air is in the reaction zone 320 of the battery 3 The position of the zinc slime electrode 40 is the highest, and the position of the above zinc slime electrode 40 is sequentially decreased to the position of the last tube (fourth tube) of the zinc-air fuel cell 3 in the reaction zone 320 of the zinc slime electrode 40 having the lowest height. The length of the extension section 211 of a tube of zinc air battery 3 is the longest and the position of the discharge port 203 relative to the reaction zone 320 is the lowest (the extension section 211 of the first tube of zinc air fuel cell 3 is located in the above reaction zone 320, and The extension section 211 also contains the zinc mud electrode 40).

上述延伸段211的長度依序遞減至最末管(第四管)的鋅空氣燃料電池3的延伸段211的長度最短且出料口203相對於反應區320的位置最高(由於最末管(第四管)的鋅空氣燃料電池3的延伸段211可設為剛好與反應區320的高度相同或並未與上述反應區320接觸,故上述延伸段211中並不會容納有上述鋅泥電極40)。The length of the extension section 211 is sequentially reduced to the last tube (the fourth tube). The length of the extension section 211 of the zinc-air fuel cell 3 is the shortest and the position of the discharge port 203 relative to the reaction zone 320 is the highest (because the last tube ( (Fourth tube) The extension section 211 of the zinc-air fuel cell 3 can be set to be exactly the same height as the reaction zone 320 or not in contact with the reaction zone 320, so the zinc mud electrode will not be accommodated in the extension section 211. 40).

於此狀態下,上述鋅泥電極40皆能夠與每一管鋅空氣燃料電池3發生一氧化還原反應,並產生電力可進行充電或放電作業。In this state, the zinc slime electrodes 40 described above can all undergo a redox reaction with each tube of zinc-air fuel cell 3 and generate electricity for charging or discharging operations.

如圖5A所示,為啟動上述真空罐50,並以負壓方式驅動氣體推動上述鋅泥電極40之狀態,大氣壓力中氣體由上述連通座2的第一連接口22進入上述入料口202後再接續進入上述第一管鋅空氣燃料電池3的氣隔區321,在氣密狀態的鋅空氣燃料電池3中,上述氣體迫使第一管的鋅空氣燃料電池3中鋅泥電極40進入上述延伸段211再接續進入上述連通段210,再進一步將上述鋅泥電極40帶動進入其他管鋅空氣燃料電池3中(如圖5B所示),依據此種負壓氣體推動上述鋅泥電極40進入不同的鋅空氣燃料電池3的流動路徑,便能夠將第一管的鋅空氣燃料電池3中鋅泥電極40作為其他管鋅空氣燃料電池3的鋅材料4補充材料,於此循環之下,便無需由燃料電池裝置1的外部進行額外補充上述鋅材料4的作業。As shown in FIG. 5A, in order to start the vacuum tank 50 and drive the gas to push the zinc mud electrode 40 in a negative pressure manner, the gas in atmospheric pressure enters the inlet 202 through the first connection port 22 of the communication seat 2 After that, it enters into the air compartment 321 of the first tube of zinc-air fuel cell 3. In the zinc-air fuel cell 3 in an airtight state, the gas forces the zinc slime electrode 40 in the first tube of zinc-air fuel cell 3 into the above. The extension section 211 continues into the above-mentioned communication section 210, and further drives the zinc mud electrode 40 into the other tube zinc-air fuel cell 3 (as shown in FIG. 5B). According to this negative pressure gas, the zinc mud electrode 40 is pushed into The flow paths of different zinc-air fuel cells 3 can use the zinc slime electrode 40 in the first tube of zinc-air fuel cell 3 as a supplementary material for the zinc material 4 of other tube-zinc-air fuel cells 3. Under this cycle, It is not necessary to perform the supplementary operation of the zinc material 4 described above from the outside of the fuel cell device 1.

請參照圖5C及圖5D所示,當上述真空罐50進行間歇性負壓方式驅動氣體推動上述鋅泥電極40時,上述真空罐50短暫地暫停負壓驅動作業時,原先朝向上述其他管鋅空氣燃料電池3的單一方向流動之鋅泥電極40,將短暫地失去被氣體驅動的力量,而原先流動於上述通道21中的鋅泥電極40,將受到自然重力影響,而分別朝向第一管鋅空氣燃料電池3的延伸段211以及朝向另一管鋅空氣燃料電池3的連通段210兩種不同的流動路徑,進而流進不同的鋅空氣燃料電池3的反應空間32內,據此,第一管鋅空氣燃料電池3內的鋅泥電極40的高度位置將下降,而另一管鋅空氣燃料電池3內的鋅泥電極40的高度位置將上升。Please refer to FIG. 5C and FIG. 5D, when the vacuum tank 50 is intermittently driven by a negative pressure to drive the gas to push the zinc mud electrode 40, the vacuum tank 50 temporarily suspends the negative pressure driving operation, and originally faces the other tube zinc. The zinc slime electrode 40 flowing in a single direction of the air fuel cell 3 will temporarily lose the power driven by the gas, and the zinc slime electrode 40 originally flowing in the above-mentioned channel 21 will be affected by natural gravity and will face the first tube respectively. There are two different flow paths of the extended section 211 of the zinc-air fuel cell 3 and the connecting section 210 toward the other tube of the zinc-air fuel cell 3, and then they flow into the reaction spaces 32 of the different zinc-air fuel cells 3. The height position of the zinc slime electrode 40 in one tube of the zinc air fuel cell 3 will decrease, and the height position of the zinc slime electrode 40 in the other tube of zinc air fuel cell 3 will rise.

依據前述說明段落以此類推,前述氣體及鋅泥電極40的流動方式及流動方向將持續性地循環進行於第一管、第二管、第三管及最末管(第四管)鋅空氣燃料電池3之間,反之,若上述第一管鋅空氣燃料電池3透過上述第一連接口22組接於上述真空罐50,而最末管(第四管)的鋅空氣燃料電池3透過上述第二連接口23與大氣壓力連接導通,上述氣體及鋅泥電極40的流動方向將變為由最末管(第四管)鋅空氣燃料電池3朝向第一管鋅空氣燃料電池3移動。According to the foregoing description and so on, the flow mode and flow direction of the gas and the zinc mud electrode 40 will be continuously circulated in the first tube, the second tube, the third tube, and the last tube (fourth tube) zinc air. Between the fuel cells 3, if the first tube of zinc-air fuel cell 3 is connected to the vacuum tank 50 through the first connection port 22, the zinc-air fuel cell 3 of the last tube (fourth tube) passes through the above. The second connection port 23 is connected to the atmospheric pressure, and the flow direction of the gas and the zinc mud electrode 40 will be changed from the last tube (fourth tube) zinc air fuel cell 3 toward the first tube zinc air fuel cell 3.

另外,上述壓差產生器5設為一同時連通於上述連通座2的第一連接口22以及一第二連接口23的真空罐50(圖未示),亦能夠構成上述壓力差,並完成相同於前述氣體及鋅泥電極40的流動方式及流動方向之結果。In addition, the pressure difference generator 5 is a vacuum tank 50 (not shown) connected to the first connection port 22 and the second connection port 23 of the communication seat 2 at the same time, and can also constitute the pressure difference and complete the process. The result is the same as the flow mode and flow direction of the gas and the zinc mud electrode 40 described above.

請參照圖6至圖8所示,為本發明燃料電池裝置1的第二較佳實施例,於此實施例中以六管組合的鋅空氣燃料電池3進行說明,上述六管組合的鋅空氣燃料電池3能夠同樣地透過一位於上述連通座2側面的導通孔24,將三組各為兩管的鋅空氣燃料電池3完成六管組合的樣態,或將一組兩管以及一組四管的鋅空氣燃料電池3完成六管組合的樣態,而上述導通孔24的兩端分別設為一導通於大氣壓力的第一導通孔以及一導通於其中一延伸段211的第二導通孔。Please refer to FIG. 6 to FIG. 8, which is a second preferred embodiment of the fuel cell device 1 of the present invention. In this embodiment, a six-tube combination zinc-air fuel cell 3 is used for description. The fuel cell 3 can similarly pass through a through hole 24 located on the side of the communication seat 2 to complete three groups of two tubes of zinc-air fuel cells 3 to complete a combination of six tubes, or a group of two tubes and a group of four The zinc-air fuel cell 3 of the tube completes a six-tube combination, and the two ends of the above-mentioned via hole 24 are respectively set as a first via hole for conducting to atmospheric pressure and a second via hole for one of the extension sections 211. .

此實施例中與前述第一較佳實施例不同點在於,上述鋅材料4設為一呈現為顆粒樣態或粉狀樣態其中之一或其混合構成的鋅砂41,上述鋅砂41沉澱留置於上述鋅空氣燃料電池3內的反應空間32中,並不會隨著前述氣體的流動進而改變位置,為了避免氧化還原過程中體積逐漸縮小的鋅砂41透過的延伸段211進入上述通道21中並進一步影響本發明燃料電池裝置1的充電或放電功效,而進一步於上述連通座2的出料口203位置設有一過濾件204,透過上述過濾件204將上述鋅砂41限制在上述反應空間32內,於一較佳可行實施例中,上述過濾件204設為一不織布材質構成的阻擋面並能夠將上述連通座2的出料口203完整地包覆。The difference between this embodiment and the aforementioned first preferred embodiment is that the zinc material 4 is a zinc sand 41 which is present in one of a granular state or a powder state or a mixture thereof, and the zinc sand 41 is precipitated. It is left in the reaction space 32 in the zinc-air fuel cell 3 and does not change its position with the flow of the gas. In order to prevent the zinc sand 41, which gradually shrinks in volume during the redox process, from extending into the channel 21, And further affects the charging or discharging efficiency of the fuel cell device 1 of the present invention, and a filter 204 is further provided at the position of the outlet 203 of the communication seat 2 to restrict the zinc sand 41 to the reaction space through the filter 204 In 32, in a preferred feasible embodiment, the filter element 204 is set as a blocking surface made of a non-woven material and can completely cover the outlet 203 of the communication seat 2.

據此,此實施例中鋅砂41須配合一電解液42遂能夠完成相同於前述第一較佳實施例之結果,由上述電解液42進入上述反應空間32並流入上述通道21中,進行相同於前述第一較佳實施例中之鋅泥電極40的動作。According to this, in this embodiment, zinc sand 41 must be combined with an electrolyte 42 to achieve the same result as the first preferred embodiment. The electrolyte 42 enters the reaction space 32 and flows into the channel 21 to perform the same. The operation of the zinc mud electrode 40 in the aforementioned first preferred embodiment.

而且,上述連通座2的第一連接口22對應於上述第一管鋅空氣燃料電池3的位置,且上述第二連接口23對應於上述最末管(第六管)鋅空氣燃料電池3的位置,前述氣體及鋅砂41的流動方式及流動方向將持續性地循環進行於第一管、第二管、第三管、第四管、第五管以及最末管(第六管)鋅空氣燃料電池3之間。Moreover, the first connection port 22 of the communication seat 2 corresponds to the position of the first tube zinc air fuel cell 3, and the second connection port 23 corresponds to the position of the last tube (sixth tube) zinc air fuel cell 3. Position, the flow mode and flow direction of the aforementioned gas and zinc sand 41 will be continuously circulated in the first pipe, the second pipe, the third pipe, the fourth pipe, the fifth pipe, and the last pipe (sixth pipe) zinc Between air fuel cells 3.

此外,請再參閱圖8所示,此實施例中能夠將上述壓差產生器5設為一同時連通於上述連通座2的第一連接口22以及一第二連接口23的磁軸馬達51,由上述磁軸馬達51構成介於上述第一連接口22以及一第二連接口23之間的壓力差,便能夠完成與上述真空罐50相同之功效,其他部分技術特徵皆與前述第一較佳實施例相同,於此便不再加以贅述。In addition, please refer to FIG. 8 again. In this embodiment, the pressure difference generator 5 can be a magnetic shaft motor 51 that is connected to the first connection port 22 and the second connection port 23 of the communication seat 2 at the same time. The pressure difference between the first connection port 22 and a second connection port 23 formed by the magnetic shaft motor 51 can complete the same effect as the vacuum tank 50 described above, and other technical features are the same as those of the first The preferred embodiments are the same, and will not be repeated here.

最後,請參閱圖9所示,為本發明燃料電池裝置1的第三較佳實施例,於此實施例中,以十六管組合的鋅空氣燃料電池3進行說明,與前述第一及第二較佳實施例不同點在於,上述連通座2的第一連接口22設於對應第一管鋅空氣燃料電池3的位置,而第一連接口22設於對應最末管(第十六管)鋅空氣燃料電池3的位置,並能夠將左側兩排(共八管組合)的鋅空氣燃料電池3設為進行放電功效,而相對於右側兩排(共八管組合)的鋅空氣燃料電池3設為進行充電功效,如此便可於此實施例燃料電池裝置1中持續性/間歇性循環同時完成充放電之效果,而無須改變上述磁軸馬達51組接於上述連通座2的第一連接口22以及第二連接口23的位置,或改變上述磁軸馬達51的電流方向。Finally, please refer to FIG. 9, which is a third preferred embodiment of the fuel cell device 1 of the present invention. In this embodiment, a sixteen-tube combination zinc-air fuel cell 3 is described. The difference between the two preferred embodiments is that the first connection port 22 of the above-mentioned communication seat 2 is provided at a position corresponding to the first tube of zinc-air fuel cell 3, and the first connection port 22 is provided at a corresponding end of the last tube (sixteenth tube). ) The position of the zinc-air fuel cell 3, and the zinc-air fuel cell 3 on the left two rows (a total of eight tubes) can be set to perform the discharge function, compared with the zinc-air fuel cell on the right two rows (a total of eight tubes) 3 is set to perform the charging effect, so that the effect of continuous charging / discharging can be completed simultaneously in the continuous / intermittent cycle in the fuel cell device 1 in this embodiment, without changing the first group of the magnetic shaft motor 51 connected to the first of the communication seat 2 The positions of the connection port 22 and the second connection port 23 may change the current direction of the magnetic shaft motor 51.

如此一來,由前述三種燃料電池裝置1的實施例可得知,透過本發明連通座2的設計,使得氣體能夠於每一通道21的連通段210中分別區隔開每一管鋅空氣燃料電池3之間的電性連接,使得每一管鋅空氣燃料電池3的鋅材料4能夠分別獨立各自進行充/放電作業,導致能夠將每一管鋅空氣燃料電池3所產電量加總,所產總電量足以應用於小至3C電子產品、大至電動車的能源供給。In this way, it can be known from the foregoing three embodiments of the fuel cell device 1 that through the design of the communication seat 2 of the present invention, the gas can separate each tube of zinc-air fuel in the communication section 210 of each channel 21 separately. The electrical connection between the batteries 3 enables the zinc material 4 of each tube of zinc-air fuel cell 3 to perform charging / discharging operations independently, resulting in the total amount of electricity generated by each tube of zinc-air fuel cell 3, so that The total power output is enough to apply to the energy supply of electronic products as small as 3C and as large as electric vehicles.

上述所舉實施例,僅用為方便說明本發明並非加以限制,在不離本發明精神範疇,熟悉此一行業技藝人士依本發明申請專利範圍及創作說明所作之各種簡易變形與修飾,均仍應含括於以下申請專利範圍中。The above-mentioned embodiments are only for the convenience of explanation of the present invention and are not limited. Without departing from the spirit of the present invention, various simple deformations and modifications made by those skilled in the industry in accordance with the scope of the patent application and creation description of the present invention should still be applied. Included in the scope of the following patent applications.

1‧‧‧燃料電池裝置1‧‧‧ fuel cell device

2‧‧‧連通座2‧‧‧ connecting seat

20‧‧‧組接部20‧‧‧Assembly Department

201‧‧‧公螺紋201‧‧‧ Male Thread

202‧‧‧入料口202‧‧‧Inlet

203‧‧‧出料口203‧‧‧Discharge port

204‧‧‧過濾件204‧‧‧Filter element

21‧‧‧通道21‧‧‧channel

210‧‧‧連通段210‧‧‧ connected section

211‧‧‧延伸段211‧‧‧extended

22‧‧‧第一連接口22‧‧‧First connection port

23‧‧‧第二連接口23‧‧‧Second connection port

24‧‧‧導通孔24‧‧‧via

3‧‧‧鋅空氣燃料電池3‧‧‧ zinc air fuel cell

30‧‧‧殼體30‧‧‧shell

300‧‧‧母螺紋300‧‧‧female thread

301‧‧‧通孔301‧‧‧through hole

31‧‧‧電極管31‧‧‧electrode tube

32‧‧‧反應空間32‧‧‧ Response space

320‧‧‧反應區320‧‧‧Reaction zone

321‧‧‧氣隔區321‧‧‧ air compartment

33‧‧‧金屬集電管33‧‧‧Metal Collector

34‧‧‧隔離膜34‧‧‧Isolation film

35‧‧‧空氣電極35‧‧‧air electrode

36‧‧‧簍空空間36‧‧‧ empty space

4‧‧‧鋅材料4‧‧‧ zinc material

40‧‧‧鋅泥電極40‧‧‧zinc mud electrode

41‧‧‧鋅砂41‧‧‧zinc sand

42‧‧‧電解液42‧‧‧ Electrolyte

5‧‧‧壓差產生器5‧‧‧pressure difference generator

50‧‧‧真空罐50‧‧‧vacuum tank

51‧‧‧磁軸馬達51‧‧‧ Magnetic shaft motor

圖1為燃料電池裝置的第一較佳實施例之立體圖; 圖2為圖1之分解圖; 圖3為通道之結構示意圖; 圖4為鋅空氣燃料電極之剖面示意圖; 圖5A至圖5D為圖1配合真空罐之使用狀態示意圖; 圖6為燃料電池裝置的第二較佳實施例之立體圖; 圖7為圖6之分解圖; 圖8為圖6配合磁軸馬達之使用狀態示意圖; 圖9為燃料電池裝置的第三較佳實施例之俯視圖。Figure 1 is a perspective view of a first preferred embodiment of a fuel cell device; Figure 2 is an exploded view of Figure 1; Figure 3 is a schematic structural view of a channel; Figure 4 is a schematic sectional view of a zinc air fuel electrode; Figures 5A to 5D are Fig. 1 is a schematic view of a use state of a vacuum tank; Fig. 6 is a perspective view of a second preferred embodiment of a fuel cell device; Fig. 7 is an exploded view of Fig. 6; Fig. 8 is a schematic view of a use state of a magnetic shaft motor in Fig. 6; 9 is a plan view of a third preferred embodiment of the fuel cell device.

Claims (10)

一種燃料電池裝置,包含:一連通座,具有複數個的組接部,且內部設有複數個通道連接每一個組接部,使上述組接部分別形成有一入料口以及一出料口;以及複數個鋅空氣燃料電池,具有一開放狀態的反應空間,並分別安裝於上述連通座的每一組接部,使上述反應空間形成一密閉狀態,且上述反應空間內部設有一能夠產生氧化還原反應的鋅材料,使得上述反應空間分隔成一反應區以及一未包含鋅材料的氣隔區;其中,上述連通座的出料口位於上述反應空間的反應區內,而上述連通座的入料口則位於上述反應空間的氣隔區內。A fuel cell device includes: a communication base having a plurality of assembling parts, and a plurality of channels are connected inside each of the assembling parts, so that the assembling parts are respectively formed with an inlet and an outlet; And a plurality of zinc-air fuel cells, each of which has an open reaction space, and is separately installed in each connection part of the communication seat, so that the reaction space is formed in a closed state, and an inside of the reaction space is provided with a capacity to generate redox. The reacted zinc material separates the reaction space into a reaction zone and a gas compartment that does not contain zinc material; wherein the outlet of the communication seat is located in the reaction zone of the reaction space, and the inlet of the communication seat is It is located in the air compartment of the reaction space. 如申請專利範圍第1項所述之燃料電池裝置,其中,上述燃料電池裝置進一步包含一壓差產生器,而上述連通座由上述複數通道形成有與上述壓差產生器安裝的一第一連接口以及一第二連接口,上述壓差產生器將上述第一連接口與第二連接口之間形成一壓力差,進而驅使每一鋅空氣燃料電池的鋅材料透過上述通道流動至另一鋅空氣燃料電池。The fuel cell device according to item 1 of the scope of the patent application, wherein the fuel cell device further includes a pressure difference generator, and the communication seat is formed by the plurality of channels with a first connection installed with the pressure difference generator. Interface and a second connection port, the pressure difference generator forms a pressure difference between the first connection port and the second connection port, thereby driving the zinc material of each zinc air fuel cell to flow through the channel to another zinc Air fuel cell. 如申請專利範圍第1項所述之燃料電池裝置,其中,上述連通座的複數個出料口分別位於各自對應反應區的高度位置皆不相同。The fuel cell device according to item 1 of the scope of patent application, wherein the plurality of outlets of the communication seat are located at different height positions of their corresponding reaction zones, respectively. 如申請專利範圍第1項所述之燃料電池裝置,其中,上述通道包含一形成於連通座內部的連通段以及一突出於上述組接部的延伸段。The fuel cell device according to item 1 of the scope of patent application, wherein the channel includes a communication section formed inside the communication seat and an extension section protruding from the assembly portion. 如申請專利範圍第2項所述之燃料電池裝置,其中,由上述第一連接口或第二連接口其中之一與一真空罐連通,而另一者直接與大氣壓力導通共同構成上述壓力差。The fuel cell device according to item 2 of the scope of patent application, wherein one of the first connection port or the second connection port communicates with a vacuum tank, and the other directly communicates with atmospheric pressure to form the pressure difference. . 如申請專利範圍第2項所述之燃料電池裝置,其中,上述壓差產生器設為一同時連通於上述第一連接口及一第二連接口的真空罐。The fuel cell device according to item 2 of the scope of patent application, wherein the pressure difference generator is a vacuum tank which is connected to the first connection port and the second connection port simultaneously. 如申請專利範圍第2項所述之燃料電池裝置,其中,上述壓差產生器設為一同時連通於上述第一連接口及一第二連接口的磁軸馬達。The fuel cell device according to item 2 of the scope of the patent application, wherein the pressure difference generator is a magnetic shaft motor that communicates with the first connection port and a second connection port simultaneously. 如申請專利範圍第1項所述之燃料電池裝置,其中,上述鋅材料設為一可流動並呈現為泥狀樣態的鋅泥電極。The fuel cell device according to item 1 of the scope of the patent application, wherein the zinc material is set as a zinc mud electrode that can flow and exhibit a muddy state. 如申請專利範圍第1項所述之燃料電池裝置,其中,上述鋅材料設為一呈現為顆粒樣態或粉狀樣態其中之一或其混合構成的鋅砂。The fuel cell device according to item 1 of the scope of the patent application, wherein the zinc material is a zinc sand which is present in one of a granular state or a powder state or a mixture thereof. 如申請專利範圍第9項所述之燃料電池裝置,其中,上述出料口進一步設有一過濾件,上述過濾件能夠將上述鋅砂限制在反應空間內。According to the fuel cell device according to item 9 of the scope of patent application, wherein the discharge port is further provided with a filter element, the filter element can limit the zinc sand in the reaction space.
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Citations (1)

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Publication number Priority date Publication date Assignee Title
TWI427856B (en) * 2010-12-14 2014-02-21 Univ Nat Pingtung Sci & Tech Zinc-air fuel cells for controlling electrolytes and its units

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TWI427856B (en) * 2010-12-14 2014-02-21 Univ Nat Pingtung Sci & Tech Zinc-air fuel cells for controlling electrolytes and its units

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