CN105280989A - Aluminum-air battery stack - Google Patents
Aluminum-air battery stack Download PDFInfo
- Publication number
- CN105280989A CN105280989A CN201510579150.7A CN201510579150A CN105280989A CN 105280989 A CN105280989 A CN 105280989A CN 201510579150 A CN201510579150 A CN 201510579150A CN 105280989 A CN105280989 A CN 105280989A
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- China
- Prior art keywords
- purchasing ore
- battery
- grid
- thick
- air
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M12/00—Hybrid cells; Manufacture thereof
- H01M12/04—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
- H01M12/06—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode
- H01M12/065—Hybrid cells; Manufacture thereof composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type with one metallic and one gaseous electrode with plate-like electrodes or stacks of plate-like electrodes
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/04—Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
- H01M8/04276—Arrangements for managing the electrolyte stream, e.g. heat exchange
- H01M8/04283—Supply means of electrolyte to or in matrix-fuel cells
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
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- Engineering & Computer Science (AREA)
- Manufacturing & Machinery (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Electrochemistry (AREA)
- General Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Hybrid Cells (AREA)
Abstract
The invention discloses an aluminum-air battery pile which is composed of a front panel, a thick grid, a grid, an air electrode, a reinforcing grid, a battery outer framework, a thick battery outer framework, an aluminum electrode seat, a rear cover and an air flow channel. When the battery works, electrolyte enters the liquid inlet of the pile through the electrolyte pump, the electrolyte enters each single battery through each single liquid inlet flow channel, after each single reaction cavity is full of the electrolyte, the electrolyte flows out of each single battery through the liquid outlet flow channel, the electrolyte is recycled through the liquid outlet, and the circuitous design of the liquid inlet flow channel, the design of the one-way valve and the design of the liquid outlet effectively avoid the problem of liquid connection between each single battery. Air is blown into the air flow channel through the fan, so that oxygen in the air can generate electrochemical reaction with the aluminum electrode through the air electrode, and electric energy is provided. The electric pile provided by the invention can be connected with a plurality of single batteries in series, so that the battery structure is greatly simplified, and the voltage and the power of the battery are improved.
Description
Technical field
The present invention relates to a kind of pile, be specifically related to a kind of aluminum-air cell pile.
Background technology
Present Global energy resource supply is increasingly deficient, and people are trying to explore the new energy.Fuel cell due to plurality of advantages such as it are efficient, clean, one of exploitation focus having become world today's new energy field.Aluminium-air cell, as a kind of fuel cell, has energy density large, and aluminium anodes material source enriches, and the advantages such as pollution-free, reliability is high, and fail safe is good, thus show one's talent in numerous fuel cell battery, its application prospect is had an optimistic view of by countries in the world.The states such as the U.S., Canada, Former Yugoslavia, India, Britain are all carrying out active research.Because the air electrode of superperformance is successfully developed, the research of aluminium-air cell is made great progress.Abroad make great progress in the research of large, medium and small power aluminium-air cell.
Summary of the invention
The object of this invention is to provide a kind of aluminum-air cell pile, adopt this structure can to connect multiple cell, thus improve voltage and the power of battery.
The object of the invention is to be achieved through the following technical solutions:
A kind of aluminum-air cell pile, is made up of front panel, thick grid, grid, air electrode, reinforcement grid, battery purchasing ore, thick battery purchasing ore, aluminium electrode, aluminium electrode tip holder, bonnet and air flow channel, wherein:
Be provided with battery purchasing ore and thick battery purchasing ore between described front panel and bonnet, the number of battery purchasing ore is at least one, and the number of thick battery purchasing ore is one;
Thick grid, air electrode and reinforcement grid is all disposed with between described front panel and battery purchasing ore, between bonnet and thick battery purchasing ore;
Be disposed with between described battery purchasing ore and thick battery purchasing ore and strengthen grid, air electrode, grid, grid, air electrode and reinforcement grid;
Described aluminium electrode is inserted on aluminium electrode tip holder, and aluminium electrode tip holder is inserted in the top of battery purchasing ore and thick battery purchasing ore;
The boss face front panel of described thick grid and bonnet, and form air flow channel between front panel and bonnet;
The boss of two grids between described battery purchasing ore and thick battery purchasing ore is oppositely arranged formation air flow channel;
The described boss being positioned at the reinforcement grid of battery purchasing ore and thick battery purchasing ore both sides is staggered relatively in aluminium electrode both sides, forms the cavity that air flow channel forms electrolyte circulation;
Described battery purchasing ore and thick battery purchasing ore comprise inlet, feed liquor runner, cell reaction chamber, fluid runner and liquid outlet;
The charging aperture of described front panel is communicated with the charging aperture of battery purchasing ore with thick battery purchasing ore, and the discharging opening of front panel is communicated with the discharging opening of battery purchasing ore with thick battery purchasing ore.
Time battery operated, electrolyte enters pile inlet by cell liquor pump, electrolyte enters each cell by the feed liquor runner of each monomer, after each monomer reaction chamber is full of electrolyte, electrolyte flows out each monomer by fluid runner, and by liquid outlet, electrolyte is reclaimed, the design of the roundabout design of feed liquor runner and the design of unidirectional valve and liquid outlet effectively avoids the problem connecting liquid between each cell.Air blasts air flow channel by fan, like this, the oxygen in air by air electrode can with aluminium electrode generation electrochemical reaction, thus provide electric energy.
Pile provided by the invention can be connected multiple cell, and air electrode and battery purchasing ore form seal cavity, and electrolyte and aluminium electrode are in seal cavity.Whole pile injects from an inlet the normal work that electrolyte just can maintain whole pile, greatly simplify battery structure, improves voltage and the power of battery.
Accompanying drawing explanation
Fig. 1 is each modular construction design drawing of aluminum-air cell;
Fig. 2 aluminum-air cell electric pile structure design drawing;
Fig. 3 aluminum-air cell purchasing ore cutaway view.
Embodiment
Below in conjunction with accompanying drawing, technical scheme of the present invention is further described; but be not limited thereto; everyly technical solution of the present invention modified or equivalent to replace, and not departing from the spirit and scope of technical solution of the present invention, all should be encompassed in protection scope of the present invention.
Embodiment one: as shown in Figure 1, aluminum-air cell pile provided by the invention is made up of front panel 1, thick grid 2, grid 3, air electrode 4, reinforcement grid 5, battery purchasing ore 6, thick battery purchasing ore 7, aluminium electrode 8, aluminium electrode tip holder 9, bonnet 10 and air flow channel 11, wherein:
A battery purchasing ore 6 and a thick battery purchasing ore 7 is provided with between described front panel 1 and bonnet 10;
All be disposed with thick grid 2, air electrode 4 between described front panel 1 and battery purchasing ore 6, between bonnet 10 and thick battery purchasing ore 7 and strengthen grid 5;
Be disposed with between described battery purchasing ore 6 and thick battery purchasing ore 7 and strengthen grid 5, air electrode 4, grid 3, grid 3, air electrode 4 and strengthen grid 5;
Described aluminium electrode 8 is inserted on aluminium electrode tip holder 9, and aluminium electrode tip holder 9 is inserted in the top of battery purchasing ore 6 and thick battery purchasing ore 7;
The boss face front panel 1 of described thick grid 2 and bonnet 10, and form air flow channel 11 between front panel 1 and bonnet 10;
The boss of two grids 3 between described battery purchasing ore 6 and thick battery purchasing ore 7 is oppositely arranged, and forms air flow channel 11;
The described boss cavity forming electrolyte circulation in aluminium electrode 8 both sides staggered relatively being positioned at the reinforcement grid 5 of battery purchasing ore 6 and thick battery purchasing ore 7 both sides, for the position of fixing aluminium electrode 8, support the cell reaction cavity between aluminium electrode 8 and air electrode 4, ensure the distance between air electrode 4 and aluminium electrode 8, ensure the smooth circulation of electrolyte, prevent battery short circuit.
In the present invention, described air flow channel 11 can allow air to pass through from air cell 4 surface.
In the present invention, described battery purchasing ore 6 and thick battery purchasing ore 7 are configured with two and strengthen grid 5, two air electrodes, 4, thick grid, 2, grid 3 and an aluminium electrode 8 and an aluminium electrode tip holder 9.
In the present invention, described aluminium electrode 8 and air electrode 4 are tabular.
In the present invention, described air electrode 8 and form the cell reaction chamber of sealing between battery purchasing ore 6 and thick battery purchasing ore 7, makes electrolyte to reveal.
In the present invention, described aluminium electrode tip holder 9 and being sealed by sealing joint strip or fluororesin between battery purchasing ore 6 and thick battery purchasing ore 7, and fixed by the holding screw of both sides, prevent electrolyte from revealing.
As shown in Figure 3, in the present invention, described battery purchasing ore 6 and thick battery purchasing ore 7 comprise inlet 12, feed liquor runner 13, cell reaction chamber, fluid runner 14 and liquid outlet 15, and inlet 12 and liquid outlet 13 are all sealed by sealing ring.Feed liquor runner 13 and fluid runner 14 are built-in runner, are integrated with battery purchasing ore 6 and thick battery purchasing ore 7.
In the present invention, inlet and the liquid outlet of described battery purchasing ore 6 are one-sided, that is: only boss is had to design in battery purchasing ore side, and boss surface is a groove, can place sealing ring, when each cell is connected, each inlet and each liquid outlet of each cell can well link together, and the inlet of thick battery purchasing ore 7 and liquid outlet all have boss structure in battery purchasing ore both sides, when contacting with cell rear cover, play the effect of hermetic electrolyte liquid.Electrolyte only need be injected by the inlet of front panel 1, electrolyte just can enter each cell reaction chamber along the inlet of purchasing ore and feed liquor runner, thus realize carrying out smoothly of electrode reaction, the design greatly simplify battery structure, make electrolyte only can enter pile from an inlet, a liquid outlet flows out pile, and each cell that just can be whole pile provides electrolyte.
As shown in Figure 3, inlet 12 is positioned at the position of right boss, feed liquor runner 13 one end communicates with inlet 12, and the other end communicates with cell reaction chamber, and what feed liquor runner 13 adopted is the roundabout mode entered, simultaneously containing unidirectional valve 16, ensure that electrolyte can only enter cell reaction chamber and can not flow backwards, when electrolyte stops supply, one-way cock 16 is closed, each monomer can fully be isolated, and avoids monomer to connect the problem of liquid completely.Feed liquor runner 13 is positioned at bottom, cell reaction chamber, and fluid runner 14 is positioned on the left of cell reaction chamber, and fluid runner 14 runner upper end communicates with cell reaction chamber, and the other end is connected with liquid outlet 15, and liquid outlet 15 is positioned at the position of configured left boss.
In order to avoid in design or reduce the company's liquid problem between monomer, feed liquor runner 13 enters monomer wherein from monomer lower end by the roundabout mode pumped into, and fluid runner 14 caliber is 2 times of feed liquor runner 13 caliber.Inlet 12 flows into electrolyte, flows into cell reaction chamber by feed liquor runner 13, after liquid to be electrolysed fills cell reaction chamber, flows out electrolyte, and reclaim by liquid outlet 15.
In the present invention, described thick grid 2 is different with the boss height that the main distinction of grid 3 is on rib, and therefore, thick grid 2 and grid 3 are applied to the diverse location of battery pile respectively.Thick grid 2, at front panel 1 and battery purchasing ore 6 and between battery purchasing ore 7 and bonnet 10, is used for fixing air electrode 4 and the air flow channel 11 supported between front panel 1 and the air flow channel 11 between battery purchasing ore 7 and bonnet 10.Grid 3, between battery purchasing ore 6 and thick battery purchasing ore 7, is used for fixing the air flow channel 11 between air electrode 4 and battery purchasing ore 7.
In the present invention, described reinforcement grid 5 is positioned at aluminium electrode 8 both sides, and between aluminium electrode 8 and air electrode 4, its effect is the position of fixing aluminium electrode 8 and air electrode 4, supports the space between aluminium electrode 8 and air electrode 4 simultaneously, ensures that electrolyte circulates smoothly.
In the present invention, the fluid runner 14 of described battery purchasing ore 6 and thick battery purchasing ore 7 act as the passage of gas discharging simultaneously, considers in cell operations, may there is aerogenesis phenomenon, and fluid runner 14 can serve as the exhaust passage in pile simultaneously.
In the present invention, between described air electrode 4 and battery purchasing ore 6, thick battery purchasing ore 7, air electrode 4 and thick grid 2, grid 3, strengthen between grid 5 and battery purchasing ore 6 and being sealed by sealing joint strip, silicon rubber or fluororesin between thick battery purchasing ore 7 and aluminium electrode tip holder 9, wherein, the fluororesin film that fluororesin solution does rear formation has the hydrophobic material consistent with air electrode waterproof ventilative layer, can play good sealing effectiveness.There is provided pressure by lacing wire and holding screw, ensure to closely cooperate between the inner each assembly of each monomer and each monomer, the leakage of electrolyte can be suppressed.
In the present invention, described whole aluminum-air cell pile is except air electrode 4 and aluminium electrode 8, all the other structures all adopt ABS engineering plastics or PP material to be formed by Digit Control Machine Tool processing and fabricating, ensure that the structural strength of pile, alkaline electrolyte can be avoided simultaneously to pile the corrosion failure of electric pile structure, the useful life of pile can be improved.
Embodiment two: present embodiment and embodiment one unlike, the present invention does not limit to and two cells, and wherein, battery purchasing ore 6 can have multiple series connection, thick battery purchasing ore 7 has and only has one, for the cooperation between other monomer and bonnets.Be disposed with between adjacent two battery purchasing ore 6 and strengthen grid 5, air electrode 4, grid 3, grid 3, air electrode 4 and reinforcement grid 5, the boss of two grids 3 is oppositely arranged and forms air flow channel 11, such formation battery cell, in cell after assembling, the boss of thick grid 2 just in time protrudes battery purchasing ore 6 surface, namely grid 3 between two cells supports by boss, and form air flow channel, simultaneously, the inlet of battery purchasing ore 6 and liquid outlet projection section are configured with O type rubber ring, can link together under the effect of the pressure, pressure is that the holding screw by being connected on each cell surrounding realizes.
Embodiment three: as shown in Figure 2, present embodiment and embodiment two unlike, the number of described battery purchasing ore 6 is 11.
Claims (9)
1. an aluminum-air cell pile, is characterized in that described pile is made up of front panel, thick grid, grid, air electrode, reinforcement grid, battery purchasing ore, thick battery purchasing ore, aluminium electrode, aluminium electrode tip holder, bonnet and air flow channel, wherein:
Be provided with battery purchasing ore and thick battery purchasing ore between described front panel and bonnet, the number of battery purchasing ore is at least one, and the number of thick battery purchasing ore is one;
Thick grid, air electrode and reinforcement grid is all disposed with between described front panel and battery purchasing ore, between bonnet and thick battery purchasing ore;
Be disposed with between described battery purchasing ore and thick battery purchasing ore and strengthen grid, air electrode, grid, grid, air electrode and reinforcement grid;
Described aluminium electrode is inserted on aluminium electrode tip holder, and aluminium electrode tip holder is inserted in the top of battery purchasing ore and thick battery purchasing ore;
The boss face front panel of described thick grid and bonnet, and form air flow channel between front panel and bonnet;
The boss of two grids between described battery purchasing ore and thick battery purchasing ore is oppositely arranged formation air flow channel;
The described boss being positioned at the reinforcement grid of battery purchasing ore and thick battery purchasing ore both sides is staggered relatively in aluminium electrode both sides, forms the cavity that air flow channel forms electrolyte circulation;
Described battery purchasing ore and thick battery purchasing ore comprise inlet, feed liquor runner, cell reaction chamber, fluid runner and liquid outlet;
The charging aperture of described front panel is communicated with the charging aperture of battery purchasing ore with thick battery purchasing ore, and the discharging opening of front panel is communicated with the discharging opening of battery purchasing ore with thick battery purchasing ore.
2. aluminum-air cell pile according to claim 1, is characterized in that described aluminium electrode and air electrode are tabular.
3. aluminum-air cell pile according to claim 1, is characterized in that boss face front panel and the bonnet of described thick grid.
4. aluminum-air cell pile according to claim 1, be is characterized in that described aluminium electrode tip holder and is sealed by sealing joint strip or fluororesin between battery purchasing ore and thick battery purchasing ore, and being fixed by the holding screw of both sides.
5. aluminum-air cell pile according to claim 1, is characterized in that described inlet and liquid outlet are all sealed by sealing ring; Feed liquor runner and fluid runner are built-in runner, are integrated with battery purchasing ore and thick battery purchasing ore.
6. aluminum-air cell pile according to claim 1 or 5, is characterized in that described fluid runner caliber is 2 times of feed liquor runner caliber.
7. aluminum-air cell pile according to claim 1 or 5, is characterized in that described feed liquor runner is built-in with one-way cock.
8. aluminum-air cell pile according to claim 1 or 5, it is characterized in that there is boss described battery purchasing ore side, all there is boss the both sides of thick battery purchasing ore, inlet is positioned at the position of right boss, liquid outlet is positioned at the position of configured left boss, feed liquor runner is positioned at bottom, cell reaction chamber, fluid runner is positioned on the left of cell reaction chamber, feed liquor runner one end communicates with inlet, the other end communicates with cell reaction chamber, fluid runner upper end communicates with cell reaction chamber, and the other end is connected with liquid outlet.
9. aluminum-air cell pile according to claim 1, when it is characterized in that the number of described battery purchasing ore is multiple, be disposed with between adjacent two battery purchasing ore and strengthen grid, air electrode, grid, grid, air electrode and reinforcement grid, the boss of two grids is oppositely arranged formation air flow channel.
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105958160A (en) * | 2016-07-15 | 2016-09-21 | 郑州佛光发电设备有限公司 | Compact aluminum-air fuel cell stack with built-in liquid path |
CN106025448A (en) * | 2016-07-15 | 2016-10-12 | 郑州佛光发电设备有限公司 | Liquid pipeline built-in compact type aluminum-air fuel cell monomer |
CN106384861A (en) * | 2016-12-06 | 2017-02-08 | 中国科学院宁波材料技术与工程研究所 | Metal air battery |
CN108134162A (en) * | 2018-02-07 | 2018-06-08 | 长沙锦锋新能源科技有限公司 | A kind of magnesium air fuel cell monomer |
EP3506415A1 (en) * | 2017-12-28 | 2019-07-03 | Shuxiong Zhang | A metal air fuel cell and its system |
CN110233314A (en) * | 2019-06-28 | 2019-09-13 | 江苏大学 | Double electrolyte aluminium-air cells |
CN110299582A (en) * | 2019-07-29 | 2019-10-01 | 空天科技有限公司 | A kind of aluminium air power generation module group unit |
CN110676423A (en) * | 2019-09-24 | 2020-01-10 | 北京北交思远科技发展有限公司 | Aluminum air fuel battery monomer |
CN110707343A (en) * | 2019-09-24 | 2020-01-17 | 北京北交思远科技发展有限公司 | Aluminum air fuel battery system |
CN111725589A (en) * | 2019-03-19 | 2020-09-29 | 四川康成博特机械制造有限公司 | Air fuel cell monomer structure and air cell |
CN112599893A (en) * | 2020-12-14 | 2021-04-02 | 唐山海港经济开发区北京理工大学机械与车辆学院转化研究中心 | Wall-embedded self-heating metal air fuel cell |
CN112787010A (en) * | 2019-10-22 | 2021-05-11 | 黄宗洪 | Metal-air battery and electric pile system thereof |
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CN104577262A (en) * | 2014-12-31 | 2015-04-29 | 中国人民解放军第二炮兵工程大学 | Liquid circuit built-in aluminium air fuel cell monomer and cell stack |
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Cited By (18)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105958160B (en) * | 2016-07-15 | 2019-07-02 | 郑州佛光发电设备有限公司 | Compact aluminum-air fuel cell stack with built-in liquid path |
CN106025448A (en) * | 2016-07-15 | 2016-10-12 | 郑州佛光发电设备有限公司 | Liquid pipeline built-in compact type aluminum-air fuel cell monomer |
CN105958160A (en) * | 2016-07-15 | 2016-09-21 | 郑州佛光发电设备有限公司 | Compact aluminum-air fuel cell stack with built-in liquid path |
CN106384861A (en) * | 2016-12-06 | 2017-02-08 | 中国科学院宁波材料技术与工程研究所 | Metal air battery |
CN106384861B (en) * | 2016-12-06 | 2019-06-28 | 中国科学院宁波材料技术与工程研究所 | Metal-air battery |
JP2019121584A (en) * | 2017-12-28 | 2019-07-22 | 北京頤源新能源科技有限公司Beijing Yiyuan New Energy Technology Co.,Ltd | Metal air fuel battery and system of the same |
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US11043710B2 (en) * | 2017-12-28 | 2021-06-22 | Beijing Yiyuan New Energy Technology Co., Ltd | Metal air fuel cell and its system |
CN108134162A (en) * | 2018-02-07 | 2018-06-08 | 长沙锦锋新能源科技有限公司 | A kind of magnesium air fuel cell monomer |
CN111725589A (en) * | 2019-03-19 | 2020-09-29 | 四川康成博特机械制造有限公司 | Air fuel cell monomer structure and air cell |
CN110233314A (en) * | 2019-06-28 | 2019-09-13 | 江苏大学 | Double electrolyte aluminium-air cells |
CN110299582A (en) * | 2019-07-29 | 2019-10-01 | 空天科技有限公司 | A kind of aluminium air power generation module group unit |
CN110676423A (en) * | 2019-09-24 | 2020-01-10 | 北京北交思远科技发展有限公司 | Aluminum air fuel battery monomer |
CN110707343A (en) * | 2019-09-24 | 2020-01-17 | 北京北交思远科技发展有限公司 | Aluminum air fuel battery system |
CN112787010A (en) * | 2019-10-22 | 2021-05-11 | 黄宗洪 | Metal-air battery and electric pile system thereof |
CN112787010B (en) * | 2019-10-22 | 2023-11-28 | 黄宗洪 | Metal-air battery and pile system thereof |
CN112599893A (en) * | 2020-12-14 | 2021-04-02 | 唐山海港经济开发区北京理工大学机械与车辆学院转化研究中心 | Wall-embedded self-heating metal air fuel cell |
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Effective date of registration: 20220518 Address after: 200000 building 4, No. 328, Luji Road, Pudong New Area, Shanghai Patentee after: SHANGHAI HANXING TECHNOLOGY Co.,Ltd. Address before: 150000 No. 92, West Da Zhi street, Nangang District, Harbin, Heilongjiang. Patentee before: HARBIN INSTITUTE OF TECHNOLOGY |