CN106384861B - Metal-air battery - Google Patents

Metal-air battery Download PDF

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Publication number
CN106384861B
CN106384861B CN201611109661.3A CN201611109661A CN106384861B CN 106384861 B CN106384861 B CN 106384861B CN 201611109661 A CN201611109661 A CN 201611109661A CN 106384861 B CN106384861 B CN 106384861B
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China
Prior art keywords
electrolyte
metal
cover plate
plate
cathode layer
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CN106384861A (en
Inventor
董正豪
刘兆平
苗鹤
孙珊珊
张勤号
薛业建
王勤
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Ningbo Institute of Material Technology and Engineering of CAS
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Ningbo Institute of Material Technology and Engineering of CAS
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M12/00Hybrid cells; Manufacture thereof
    • H01M12/08Hybrid cells; Manufacture thereof composed of a half-cell of a fuel-cell type and a half-cell of the secondary-cell type
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Hybrid Cells (AREA)

Abstract

The invention discloses a kind of metal-air batteries, including single battery, the upper cover plate being set at the top of the single battery and the lower cover plate for being set to the single battery bottom;The single battery includes the drainage plate being fixedly connected sequentially, cathode layer, electrolyte container and anode plate, the cathode layer and anode plate are fitted in the two sides of the electrolyte container respectively and can be bonded with the cathode layer away from the side of the electrolyte container with the electrolyte contacts in the electrolyte container, the drainage plate;It is provided with inlet on the upside of the upper cover plate, liquid outlet is provided on the downside of the lower cover plate, electrolyte can enter the electrolyte container through the inlet and the electrolyte container is discharged through the liquid outlet.The metal-air battery can efficiently solve the loosely organized problem of metal-air battery.

Description

Metal-air battery
Technical field
The present invention relates to battery technology fields, more specifically to a kind of metal-air battery.
Background technique
It as cathode, with the oxygen in air is anode, with neutral or alkaline water that metal-air battery, which is using metal alloy, Solution is the power supply unit of electrolyte, and metal alloy reacts under the action of cathod catalyst with the water in electrolyte, and metal closes Golden oxygenolysis continues externally to export electric energy at oxide.Metal-air battery has abundant raw materials, safety and environmental protection, energy The series of advantages such as density height, referred to as " new green energy geared to the 21st century ".
However metal-air battery currently on the market is loosely organized, volume is larger, and occupied space is larger.
It is current art technology in conclusion how to efficiently solve the loosely organized problem of metal-air battery Personnel's urgent problem.
Summary of the invention
In view of this, the structure of the metal-air battery is set the purpose of the present invention is to provide a kind of metal-air battery Meter can efficiently solve the loosely organized problem of metal-air battery.
In order to achieve the above object, the invention provides the following technical scheme:
A kind of metal-air battery including single battery, the upper cover plate being set at the top of the single battery and is set to The lower cover plate of the single battery bottom;
The single battery includes the drainage plate being fixedly connected sequentially, cathode layer, electrolyte container and anode plate, the yin Pole layer and anode plate are fitted in the two sides of the electrolyte container respectively and can connect with the electrolyte in the electrolyte container Touching, the drainage plate are bonded with the cathode layer away from the side of the electrolyte container;
It is provided with inlet on the upside of the upper cover plate, liquid outlet is provided on the downside of the lower cover plate, electrolyte can Enter the electrolyte container through the inlet and the electrolyte container is discharged through the liquid outlet.
Preferably, in above-mentioned metal-air battery, the electrolyte container is specially electrolyte box, and its both-side opening, The cathode layer and anode plate are fitted in the two sides of the electrolyte box respectively to block the opening;The cathode layer and anode Plate is connect by way of hot pressing with the electrolyte box, or,
The cathode layer and anode plate are interference fitted with the electrolyte box.
Preferably, in above-mentioned metal-air battery, the cathode layer and anode plate are respectively two of the electrolyte box Side wall is provided with sealing ring between the cathode layer and anode plate and the electrolyte box.
Preferably, in above-mentioned metal-air battery, the quantity of the single battery is multiple, and multiple single batteries After the part single battery is in parallel in serial or parallel connection or multiple single batteries with single battery string described in remaining Connection.
Preferably, in above-mentioned metal-air battery, be provided on the downside of the upper cover plate be connected to the inlet it is more A liquid separating port, and multiple liquid separating ports are connected to the electrolyte box of multiple single batteries inside respectively;
The multiple liquid collection openings being connected to the liquid outlet, and multiple liquid collection openings point are provided on the upside of the lower cover plate It is not connected to the electrolyte box of multiple single batteries inside.
Preferably, in above-mentioned metal-air battery, the top and bottom of the electrolyte box of multiple single batteries It is equipped with through-hole, the upper cover plate and lower cover plate are provided with the protrusion that can be caught in the through-hole, and the liquid separating port is located at In protrusion on the upper cover plate, the liquid collection opening is located in the protrusion of the lower cover plate.
Preferably, in above-mentioned metal-air battery, when multiple single batteries are connected, multiple single batteries are successively Connection, and the side away from the electrolyte box of the anode plate of the last one single battery is fitted with drainage plate.
Preferably, in above-mentioned metal-air battery, the electrolyte container is specially cube structure, and it is water-absorption material Matter.
It preferably, further include the lamina reticularis being folded between the drainage plate and cathode layer in above-mentioned metal-air battery, And the lamina reticularis is fitted closely with the drainage plate and cathode layer.
Preferably, in above-mentioned metal-air battery, nut cap, and the row of beginning in the nut cap are provided at the inlet Stomata is covered with one-way ventilating hydrophobic membrane at the gas vent.
Metal-air battery provided by the invention includes single battery, upper cover plate and lower cover plate.Wherein, upper cover plate is located at single Body battery top, lower cover plate are located at single battery bottom, and upper cover plate and lower cover plate are fixedly connected with single battery.Single battery Including drainage plate, cathode layer, electrolyte container and the anode plate being fixedly connected sequentially, cathode layer and anode plate are fitted in electricity respectively Solve liquid container two sides and can be with the electrolyte contacts in electrolyte container.Drainage plate and cathode layer are away from electrolyte container Side fitting.I.e. drainage plate, cathode layer, electrolyte container and anode plate successively fit closely.
In addition, be provided with inlet on the upside of upper cover plate, be provided with liquid outlet on the downside of lower cover plate, electrolyte can through into Liquid mouth enters electrolyte container and electrolyte container is discharged through liquid outlet.Inlet and liquid outlet with connect inside electrolyte container Logical, electrolyte flows through inlet and enters electrolyte container, and the liquid in electrolyte container is discharged through liquid outlet.
From the foregoing, it will be observed that all parts of single battery fit closely, so in metal-air battery provided by the invention The structure of the metal-air battery is more compact, and occupied space is smaller, and can design electrolyte container according to actual needs Volume, to adapt to various power demands.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
Fig. 1 is the explosive view of single battery provided in an embodiment of the present invention;
Fig. 2 is the assembling schematic diagram of two single batteries provided in an embodiment of the present invention;
Fig. 3 is the structural schematic diagram of upper cover plate provided in an embodiment of the present invention;
Fig. 4 is the sectional view of upper cover plate provided in an embodiment of the present invention;
Fig. 5 is the structural schematic diagram of lower cover plate provided in an embodiment of the present invention;
Fig. 6 is the structural schematic diagram of nut cap provided in an embodiment of the present invention;
Fig. 7 is the structural schematic diagram of cathode layer provided in an embodiment of the present invention.
In figures 1-7:
A- single battery, 1- drainage plate, 2- lamina reticularis, 3- cathode layer, 3b- Catalytic Layer, 3a- hot pressing layer, 4- electrolyte box, 5- sealing ring, 6- anode plate, 7- upper cover plate, 7a- inlet, 7b- liquid separation slot, 7c- groove, 7d- flow-stopping plate, 7e- liquid separating port, 8- Protrusion, 9- lower cover plate, 9a- liquid collection opening, 9b- liquid outlet, 10- nut cap, 11- one-way ventilating hydrophobic membrane, 12- bolt.
Specific embodiment
The purpose of the present invention is to provide a kind of metal-air battery, the structure design of the metal-air battery can be effective Ground solves the problems, such as the loosely organized of metal-air battery.
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
Please refer to Fig. 1-Fig. 6, metal-air battery provided in an embodiment of the present invention include single battery A, upper cover plate 7 and under Cover board 9.Wherein, upper cover plate 7 is located at the top of single battery A, and lower cover plate 9 is located at the bottom single battery A, upper cover plate 7 and lower cover plate 9 It is fixedly connected with single battery A.Single battery A include the drainage plate 1 being fixedly connected sequentially, cathode layer 3, electrolyte container and Anode plate 6, cathode layer 3 and anode plate 6 are fitted in the two sides of electrolyte container respectively and can be with the electrolysis in electrolyte container Liquid contact.Drainage plate 1 is bonded with cathode layer 3 away from the side of electrolyte container.That is drainage plate 1, cathode layer 3, electrolyte container It is successively fitted closely with anode plate 6.
In addition, the upside of upper cover plate 7 is provided with inlet 7a, the downside of lower cover plate 9 is provided with liquid outlet 9b, electrolyte energy It is enough to enter electrolyte container through inlet 7a and electrolytic vessel is discharged through liquid outlet 9b.Inlet 7a and liquid outlet 9b with electrolysis Connection, electrolyte flow through inlet 7a and enter electrolyte container inside liquid container, and the liquid in electrolyte container is through liquid outlet 9b Discharge.
From the foregoing, it will be observed that all parts of single battery A closely paste in metal-air battery provided in an embodiment of the present invention It closes, the structure of such metal-air battery is more compact, and occupied space is smaller, and can design electrolysis according to actual needs The volume of liquid container, to adapt to various power demands.
Wherein, anode plate 6 can be the alloy materials such as lithium metal, magnesium, aluminium, zinc, and the thickness of anode gold can be according to capacitor Amount is to adjust.Cathode layer 3 include Catalytic Layer and hot pressing layer, wherein Catalytic Layer can be carbon-based or non-carbon, Catalytic Layer 3b and Hot pressing layer 3a hot pressing together, can only Catalytic Layer 3b side have hot pressing layer 3a, can also be all provided with the two sides of Catalytic Layer 3b It is equipped with hot pressing layer 3a.Hot pressing layer 3a can be plastic frame, be not limited thereto.Wherein, electrolyte container can be specially electricity Liquid box 4 is solved, the both-side opening of electrolyte box 4, cathode layer 3 and anode plate 6 are fitted in the two sides of electrolyte box 4 respectively to block out Mouthful, the electrolyte in such electrolyte box 4 can be contacted with cathode layer 3 and anode plate 6.Drainage plate 1 and cathode layer 3 are away from electrolysis The side of liquid box 4 is bonded.I.e. drainage plate 1, cathode layer 3, electrolyte box 4 and anode plate 6 successively fit closely.
After electric discharge, inlet 7a can be directly connected to cleaning pipeline, and inside easy to clean guarantees to put when internal dead Empty and clean state.
Preferably, in above-described embodiment cathode layer 3 and anode plate 6 can by by hot pressing in a manner of connect with electrolyte box 4 It connects, can so guarantee being bonded and being fixedly connected for cathode layer 3 and anode plate 6 and electrolyte box 4.
In addition, cathode layer 3 and anode plate 6 can also be interference fitted with electrolyte box 4, it is not limited thereto.
The leakage of electrolyte in order to prevent is wherein provided with sealing between cathode layer 3 and anode plate 6 and electrolyte box 4 Circle 5.It is provided with sealing ring 5 i.e. between cathode layer 3 and electrolyte box 4 and between anode plate 6 and electrolyte box 4, to improve The leakproofness of electrolyte box 4.Sealing ring 5 can be rubber, be specifically as follows ethylene propylene diene rubber.
In order to increase the contact area of cathode layer 3 and anode plate 6 and electrolyte, cathode layer 3 and anode plate 6 are respectively to be electrolysed The two side walls of liquid box 4.That is the two sides of electrolyte box 4 are not provided with side wall, and frame only is arranged in the side surrounding of electrolyte box 4, Cathode layer 3 and anode plate 6 are fixedly connected with frame.Electrolyte box 4 is cube shape at this, certainly can also be other shapes, It is not limited thereto.
In order to meet different voltage power demands, wherein the quantity of single battery A is multiple.Multiple single battery A strings Connection is in parallel.Or it can be to connect after the A parallel connection of partial monosomy battery with remaining single battery A in multiple single battery A.Specifically It can be designed the electrical connection of multiple single battery A, according to the actual situation to meet different voltages power output.
It can be connected by bolt 12 between multiple single battery A, bolt 12 both passes through the drainage of multiple single battery A Plate.The nut at adjustment bolt both ends may be implemented to fasten multiple single battery A, compress sealing material.
Battery inside is dummy status in a non-operative state, and electrolyte starting electricity is added only in the case where needing current conditions Pond operation.
For the ease of the flowing of electrolyte, wherein the downside of upper cover plate 7 is provided with the multiple liquid separations being connected to inlet 7a Mouth 7e, and multiple liquid separating port 7e are connected to inside the electrolyte box 4 of multiple single battery A respectively.I.e. electrolyte is through inlet 7a It after, flow at multiple liquid separating port 7e, and is flow in multiple electrolyte boxes 4 respectively through multiple liquid separating port 7e.Likewise, lower cover The upside of plate 9 is provided with the multiple liquid collection opening 9a being connected to liquid outlet 9b, and multiple liquid collection opening 9a respectively with multiple single battery A Electrolyte box 4 inside be connected to.Liquid in multiple electrolyte boxes 4 can the liquid collection opening 9a discharge through communicating therewith, Jin Erjing Liquid outlet 9b discharge.
For the ease of the connection of upper cover plate 7 and lower cover plate 9, the top and bottom of the electrolyte box 4 of plurality of single battery A Portion is equipped with through-hole, and upper cover plate 7 and lower cover plate 9 are provided with the protrusion 8 that can be caught in through-hole.It is more on such upper cover plate 7 A raised 8 are caught in the top through-hole of the electrolyte box 4 of multiple single battery A, to realize upper cover plate 7 and multiple single battery A Be fixedly connected.In the bottom through-hole of multiple raised 8 electrolyte boxes 4 for being caught in multiple single battery A on lower cover plate 9, with reality Now cover board 9 and multiple single battery A are fixedly connected.Its protrusions 8 can be generally trapezoidal, i.e. two sides of protrusion 8 For inclined surface, after protrusion 8 is caught in through-hole, protrusion 8 and the hole wall of through-hole are fitted closely, and protrusion 8, which is realized, determines single battery A Position and fixation.When needing to dismantle, protrusion 8 is extracted to the disassembly that upper cover plate 7 and lower cover plate 9 can be realized from through-hole.
It is groove 7c between two protrusions 8, single battery A is caught in groove 7c.
Further, liquid separating port 7e is located in the protrusion 8 on upper cover plate 7, and liquid collection opening 9a is located in the protrusion 8 of lower cover plate 9, It is simpler that structure is arranged such.Protrusion 8 on upper cover plate 7 can be the roof of electrolyte box 4, and the protrusion 8 on lower cover plate 9 can Think the bottom wall of electrolyte box 4.Flow-stopping plate 7d can be set inside liquid separating port 7e, to guarantee uniform divided flows.It is preferably carried out Can also include in example, in single battery A be folded in lamina reticularis 2 between drainage plate 1 and cathode layer 3, and lamina reticularis 2 with draw Flowing plate 1 and cathode layer 3 fit closely.Such lamina reticularis 2 can uniformly drain reaction charge, substantially reduce contact resistance. Lamina reticularis 2 can be foaming structure, 0.5~3mm of thickness, preferably 1mm or so.And after setting lamina reticularis 2, the oxygen in air Gas can enter directly into cathode, save cathode and need moving air void space.Lamina reticularis 2 is used as current collector layer, can be The gaps such as nickel foam or metal mesh metal structure.
In single battery A, the side away from electrolyte box 4 of anode plate 6 can also be fitted with drainage plate 1.
Metal-air battery cannot store electrolyte for a long time, can only before every use into battery be added electrolyte with It is reacted.Metal-air battery in the prior art, the battery then must be used disposably completely after electrolyte is added, and be made With inconvenience, flexibility ratio is low.And metal-air battery provided by the present application is used, electrolyte is poured into electrolyte box 4 every time, is supplied Remaining electrolyte can be discharged through liquid outlet 9b, be recycled after electricity.
In addition, metal-air battery can generate sediment when being reacted, using metal-air battery provided by the present application, The liquid in electrolyte box 4 can be discharged after power supply, and then sediment is discharged.
Further, when multiple single battery A connect, multiple single battery A can be sequentially connected, i.e., multiple single batteries A successively arranges, and the side away from electrolyte box 4 of the anode plate 6 of the last one single battery A is fitted with drainage plate 1.Such as The two sides of this entire metal-air battery are provided with drainage plate 1, in order to be electrically connected with other components.
When the quantity of single battery A is one, the side away from electrolyte box 4 of the anode plate 6 of single battery A It should be fitted with drainage plate 1, to be attached.When multiple single battery A parallel connections, the anode plate 6 of each single battery A Drainage plate 1 should be also fitted with away from the side of electrolyte box 4.
Liquid separation slot 7b is provided with inside upper cover plate 7 and lower cover plate 9, so as to liquid communication.
Wherein, electrolyte container is specially cube structure, and it is water suction material, and such electrolyte container adsorbs electrolyte It is stored.The thickness that the electrolyte container of water suction material can be designed according to actual needs, can be as thin as paper sheet thickness, with Minicell is made.
Metal-air battery can generate gas in reaction, and the gas generated in each electrolyte box 4 can be through liquid separating port 7e and inlet 7a discharge.Nut cap 10 wherein can be set at inlet 7a, and begun with gas vent in nut cap 10.In order to The spilling of electrolyte is prevented, one-way ventilating hydrophobic membrane 11 is also covered at gas vent, while preventing ambient atmos to single battery A Internal influence.It can certainly open up multiple with gas vent that is being connected to inside electrolyte box 4, not limit herein on the cover board It is fixed.
Camping illumination or field emergency alarm lamp can be using seawater or edible when small-power charging unit demand Salt water can preferentially select magnesium alloy as electrolyte, anode plate 6, can be AZ-31 AZ-60 magnesium alloy, directly plus water Power generation, has used, has directly outwelled dissolution.When anode plate 6 is magnesium plate, magnesium plate uses width 5mm, thickness 1mm.Lamina reticularis 2 is bubble Foam nickel, with a thickness of 0.8mm.When electrolyte box 4 is water suction material, water suction material can be cotton-wool or blotting paper, thickness 1mm.When needing voltage 3.7V to power, the thickness of the metal-air battery can accomplish only 2 cm thicks, can put any one into When battery uses in kind lighting apparatus;The width and height for increasing cathode and anode plate 6, can be used for high power electric power supply system.
It is high-power in use, anode plate 6 use AL alloy, electrolyte use sodium hydroxide or potassium hydroxide solution, electricity It solves 4 capacity of liquid box to increase, so as to be used in the large-scale circulatory system.When anode plate 6 is using kirsite, can do can charge-discharge battery It uses, it is only necessary to which replacing cathode and anode plate 6 can continue to use.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with other The difference of embodiment, the same or similar parts in each embodiment may refer to each other.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention. Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one The widest scope of cause.

Claims (10)

1. a kind of metal-air battery, which is characterized in that including single battery (A), be set at the top of the single battery (A) Upper cover plate (7) and the lower cover plate (9) for being set to the bottom the single battery (A);
The single battery (A) includes the drainage plate (1) being fixedly connected sequentially, cathode layer (3), electrolyte container and anode plate (6), the cathode layer (3) and anode plate (6) be fitted in respectively the electrolyte container two sides and can be with the electrolyte Electrolyte contacts in container, the drainage plate (1) are bonded with the cathode layer (3) away from the side of the electrolyte container;
Electrolyte container is specially electrolyte box (4), the both-side opening of electrolyte box (4), cathode layer (3) and anode plate (6) point It is not fitted in the two sides of electrolyte box (4) to block opening, the electrolyte in such electrolyte box (4) can be with cathode layer (3) It is contacted with anode plate (6);
It is provided with inlet (7a) on the upside of the upper cover plate (7), is provided with liquid outlet (9b) on the downside of the lower cover plate (9), Electrolyte can enter the electrolyte container through the inlet (7a) and the electrolyte is discharged through the liquid outlet (9b) Container.
2. metal-air battery according to claim 1, which is characterized in that the cathode layer (3) and anode plate (6) are logical The mode for crossing hot pressing is connect with the electrolyte box (4), or,
The cathode layer (3) and anode plate (6) are interference fitted with the electrolyte box (4).
3. metal-air battery according to claim 2, which is characterized in that the cathode layer (3) and anode plate (6) are respectively For the two side walls of the electrolyte box (4), it is all provided between the cathode layer (3) and anode plate (6) and the electrolyte box (4) It is equipped with sealing ring (5).
4. metal-air battery according to claim 2, which is characterized in that the quantity of the single battery (A) be it is multiple, And the part single battery (A) in the multiple single battery (A) serial or parallel connections or multiple single batteries (A) It connects after parallel connection with single battery described in remaining (A).
5. metal-air battery according to claim 4, which is characterized in that be provided on the downside of the upper cover plate (7) with Multiple liquid separating ports (7e) of the inlet (7a) connection, and multiple liquid separating ports (7e) respectively with multiple single batteries (A) connection inside electrolyte box (4);
The multiple liquid collection openings (9a) being connected to the liquid outlet (9b) are provided on the upside of the lower cover plate (9), and multiple described Liquid collection opening (9a) is connected to the electrolyte box (4) of multiple single batteries (A) inside respectively.
6. metal-air battery according to claim 5, which is characterized in that the electricity of multiple single batteries (A) Through-hole is equipped at the top and bottom of solution liquid box (4), described in the upper cover plate (7) and lower cover plate (9) are provided with and can be caught in Protrusion (8) in through-hole, the liquid separating port (7e) are located in the protrusion (8) on the upper cover plate (7), liquid collection opening (9a) position In in the protrusion (8) of the lower cover plate (9).
7. metal-air battery according to claim 4, which is characterized in that more when multiple single batteries (A) are connected A single battery (A) is sequentially connected, and the anode plate (6) of the last one single battery (A) deviate from the electrolysis The side of liquid box (4) is fitted with drainage plate (1).
8. metal-air battery according to claim 1, which is characterized in that the electrolyte container is specially cube knot Structure, and it is water suction material.
9. metal-air battery according to claim 1 to 8, which is characterized in that further include being folded in described draw Lamina reticularis (2) between flowing plate (1) and cathode layer (3), and the lamina reticularis (2) and the drainage plate (1) and cathode layer (3) are tight Closely connected conjunction.
10. metal-air battery according to claim 1, which is characterized in that be provided with nut cap at the inlet (7a) (10), gas vent and in the nut cap (10) is begun with, one-way ventilating hydrophobic membrane (11) are covered at the gas vent.
CN201611109661.3A 2016-12-06 2016-12-06 Metal-air battery Active CN106384861B (en)

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CN201611109661.3A CN106384861B (en) 2016-12-06 2016-12-06 Metal-air battery

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CN106384861B true CN106384861B (en) 2019-06-28

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Publication number Priority date Publication date Assignee Title
CN109216831A (en) * 2017-06-29 2019-01-15 中国科学院上海硅酸盐研究所 A kind of test metal-air redox flow battery device

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CN101814643A (en) * 2009-02-25 2010-08-25 中国科学院大连化学物理研究所 Metal-air battery system
CN204577542U (en) * 2015-05-14 2015-08-19 中国科学院宁波材料技术与工程研究所 Metal-air cell heap and battery cell thereof
CN204651437U (en) * 2015-05-11 2015-09-16 中国第一汽车股份有限公司 A kind of zinc-air cell
CN105280989A (en) * 2015-09-14 2016-01-27 哈尔滨工业大学 Aluminum-air battery stack

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Publication number Priority date Publication date Assignee Title
TWI429126B (en) * 2011-09-23 2014-03-01 High Tech Battery Inc Assembling member of metal-air cell and metal-air cell having the same

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101814643A (en) * 2009-02-25 2010-08-25 中国科学院大连化学物理研究所 Metal-air battery system
CN204651437U (en) * 2015-05-11 2015-09-16 中国第一汽车股份有限公司 A kind of zinc-air cell
CN204577542U (en) * 2015-05-14 2015-08-19 中国科学院宁波材料技术与工程研究所 Metal-air cell heap and battery cell thereof
CN105280989A (en) * 2015-09-14 2016-01-27 哈尔滨工业大学 Aluminum-air battery stack

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