TWI624080B - Light emitting diode chip - Google Patents

Light emitting diode chip Download PDF

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TWI624080B
TWI624080B TW103120945A TW103120945A TWI624080B TW I624080 B TWI624080 B TW I624080B TW 103120945 A TW103120945 A TW 103120945A TW 103120945 A TW103120945 A TW 103120945A TW I624080 B TWI624080 B TW I624080B
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pattern
emitting diode
convex pattern
concave
convex
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TW103120945A
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TW201513393A (en
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金艺瑟
金京完
柳龍禑
李珍雄
林亨鎭
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首爾偉傲世有限公司
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/20Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L33/00Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L33/02Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies
    • H01L33/20Semiconductor devices having potential barriers specially adapted for light emission; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof characterised by the semiconductor bodies with a particular shape, e.g. curved or truncated substrate
    • H01L33/22Roughened surfaces, e.g. at the interface between epitaxial layers

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  • Engineering & Computer Science (AREA)
  • Manufacturing & Machinery (AREA)
  • Computer Hardware Design (AREA)
  • Microelectronics & Electronic Packaging (AREA)
  • Power Engineering (AREA)
  • Led Devices (AREA)

Abstract

在此揭露發光二極體晶片。發光二極體晶片包括基底以及半導體堆疊,半導體堆疊形成於基底上且包括第一導電型半導體層、主動層以及第二導電型半導體層,半導體堆疊具有第一側面以及設置於第一側面之下方的第二表面,其中第一側面為以平臺蝕刻的半導體堆疊之外側面,第二側面為第一導電型半導體層之外側面,且第一側面及第二側面的至少其中之一具有凸面圖案。因此,本發明之發光二極體晶片能藉凸面圖案改善橫向光提取。 A light emitting diode wafer is disclosed herein. The light emitting diode chip includes a substrate and a semiconductor stack formed on the substrate and including a first conductive type semiconductor layer, an active layer, and a second conductive type semiconductor layer, the semiconductor stack having a first side and disposed under the first side a second surface, wherein the first side is an outer side of the semiconductor stack etched by the platform, the second side is an outer side of the first conductive type semiconductor layer, and at least one of the first side and the second side has a convex pattern . Therefore, the light-emitting diode wafer of the present invention can improve lateral light extraction by a convex pattern.

Description

發光二極體晶片 Light-emitting diode chip

本發明是有關於一種發光二極體晶片,且特別是有關於一種能夠改善發光效能的發光二極體晶片。 The present invention relates to a light-emitting diode wafer, and more particularly to a light-emitting diode wafer capable of improving light-emitting efficiency.

一般發光二極體晶片包括形成於基板(例如藍寶石基板)之上方的半導體堆疊,以及形成於半導體堆疊之上方的電極。為了克服一般發光二極體晶片因產生在半導體堆疊中的主動層中的光的全反射所致的光損失,在基板上的凸-凹圖案結構因而被提出。然而,此結構仍具有因全反射所致的光損失的惡化問題。 A typical light emitting diode wafer includes a semiconductor stack formed over a substrate (eg, a sapphire substrate), and electrodes formed over the semiconductor stack. In order to overcome the light loss of a general light-emitting diode wafer due to the total reflection of light generated in the active layer in the semiconductor stack, a convex-concave pattern structure on the substrate is thus proposed. However, this structure still has a problem of deterioration of light loss due to total reflection.

本發明的一態樣提供一種能夠改善發光效應的發光二極體晶片。 One aspect of the present invention provides a light emitting diode wafer capable of improving a light emitting effect.

根據本發明的一態樣,發光二極體晶片包括:基底;以及半導體堆疊,形成於基底上,且包括第一導電型半導體層、主 動層以及第二導電型半導體層,半導體堆疊具有第一側面以及設置於第一側面之下方的第二側面,其中第一側面為半導體堆疊之外側面以進行平臺蝕刻(mesa-etching),第二側面為第一導電型半導體層之外側面,且第一側面及第二側面兩者至少其中之一具有凸面圖案。因此,本發明的發光二極體晶片可以藉由凸面圖案來改善橫向出光(lateral light extraction)。 According to an aspect of the invention, a light emitting diode wafer includes: a substrate; and a semiconductor stack formed on the substrate and including a first conductive type semiconductor layer, a main And a second conductive type semiconductor layer, the semiconductor stack has a first side and a second side disposed under the first side, wherein the first side is an outer side of the semiconductor stack for mesa-etching, The two sides are outer sides of the first conductive semiconductor layer, and at least one of the first side and the second side has a convex pattern. Therefore, the light-emitting diode wafer of the present invention can improve lateral light extraction by a convex pattern.

第一側面及第二側面兩者至少其中之一更包括凹面圖案。凹面圖案包括平板形狀,凹面圖案與凸面圖案交錯排列。 At least one of the first side and the second side further includes a concave pattern. The concave pattern includes a flat plate shape, and the concave pattern and the convex pattern are staggered.

第一側面及第二側面的每一者更包括凹面圖案。凹面圖案包括平板形狀,凹面圖案與凸面圖案交錯排列。 Each of the first side and the second side further includes a concave pattern. The concave pattern includes a flat plate shape, and the concave pattern and the convex pattern are staggered.

第一側面及第二側面兩者至少其中之一包括微透鏡圖案。微透鏡圖案與凸面圖案交錯排列。 At least one of the first side and the second side includes a microlens pattern. The microlens pattern is staggered with the convex pattern.

凸面圖案可包括圓突出圖案、三角突出圖案及矩形突出圖案中至少其中二者,其彼此交錯排列。 The convex pattern may include at least two of a circular protruding pattern, a triangular protruding pattern, and a rectangular protruding pattern, which are staggered with each other.

第一側面及第二側面兩者至少其中之一可更包括凹面圖案。凹面圖案包括圓溝槽形狀,凹面圖案與凸面圖案交錯排列。 At least one of the first side and the second side may further include a concave pattern. The concave pattern includes a circular groove shape, and the concave pattern and the convex pattern are staggered.

第一表面與第二側面的每一者可具有固定傾斜角度。 Each of the first surface and the second side may have a fixed angle of inclination.

第一導電型半導體層可更包括在第一導電型半導體層的外側面處形成於第二側面上的第三側面。 The first conductive type semiconductor layer may further include a third side surface formed on the second side surface at an outer side surface of the first conductive type semiconductor layer.

凸面圖案可包括位於第一側面上的第一凸面圖案;位於第二側面之上方的第二凸面圖案;以及位於第三側面之上方的第三凸面圖案。 The convex pattern may include a first convex pattern on the first side; a second convex pattern above the second side; and a third convex pattern above the third side.

第一側面可包括與第一凸面圖案交錯排列的第一平面圖案,第二側面可包括與第二凸面圖案交錯排列的第二平面圖案,以及第三側面可包括與第三凸面圖案交錯排列的第三平面圖案。 The first side may include a first planar pattern staggered with the first convex pattern, the second side may include a second planar pattern staggered with the second convex pattern, and the third side may include a staggered arrangement with the third convex pattern The third planar pattern.

發光二極體晶片可更包括位於第二導電型半導體層之上方的透明電極層。在此,透明電極層之外側面是包括在第一側面之中。 The light emitting diode chip may further include a transparent electrode layer located above the second conductive type semiconductor layer. Here, the outer side of the transparent electrode layer is included in the first side.

第一側面可對應於藉由平臺蝕刻透明電極層以及半導體堆疊所形成之區域。 The first side may correspond to a region formed by etching the transparent electrode layer and the semiconductor stack by the platform.

第一側面可具有對應於用於平臺蝕刻的罩幕的邊緣的形狀。 The first side may have a shape corresponding to an edge of the mask for platform etching.

第二側面可對應於在單元胞分割製程(unit cell dividing process)中所蝕刻的第一導電型半導體層的區域。 The second side may correspond to a region of the first conductive type semiconductor layer etched in the unit cell dividing process.

第二側面可具有對應於用於單元胞分割製程的罩幕的邊緣的形狀。 The second side may have a shape corresponding to an edge of the mask for the unit cell division process.

依據本發明之實施例,發光二極體晶片藉由凸面圖案減低光在其一側邊的全反射,從而提供優異的光提取效率,此凸面圖案形成在藉由檯面蝕刻透明電極層以及半導體堆疊所形成的第一側面以及藉由使用單元胞分割製程蝕刻第一導電型半導體層所形成的第二側面中的至少一者上。 According to an embodiment of the present invention, a light-emitting diode wafer reduces total reflection of light on one side thereof by a convex pattern, thereby providing excellent light extraction efficiency, and the convex pattern is formed by etching a transparent electrode layer and a semiconductor stack by mesa The formed first side surface and at least one of the second side surfaces formed by etching the first conductive type semiconductor layer by using a cell division process.

除此之外,發光二極體晶片具有位在第一側面及第二側面中至少一者的上方的與凸面圖案交錯排列的平面圖案、與凸面 圖案交錯排列的凹面圖案、與凹面圖案交錯排列的微透鏡圖案或與凸面圖案交錯排列的三角圖案,從而提供優異的光提取效率。 In addition, the light emitting diode wafer has a planar pattern and a convex surface staggered with the convex pattern positioned above at least one of the first side surface and the second side surface A concave pattern in which the patterns are staggered, a microlens pattern staggered with the concave pattern, or a triangular pattern staggered with the convex pattern to provide excellent light extraction efficiency.

隨著第一側面及第二側面的這些結構,本發明的發光二極體晶片已經改善了光提取效率,從而改善發光效能。 With these structures of the first side and the second side, the light-emitting diode wafer of the present invention has improved light extraction efficiency, thereby improving luminous efficiency.

100、200、300、400‧‧‧發光二極體晶片 100, 200, 300, 400‧‧‧Light Emitting Diode Wafers

110‧‧‧基板 110‧‧‧Substrate

111‧‧‧凸-凹圖案 111‧‧‧ convex-concave pattern

120‧‧‧第一導電型半導體層 120‧‧‧First Conductive Semiconductor Layer

130‧‧‧主動層 130‧‧‧Active layer

140‧‧‧第二導電型半導體層 140‧‧‧Second conductive semiconductor layer

150‧‧‧透明電極層 150‧‧‧Transparent electrode layer

160、260、460、560、660、760‧‧‧第二側面 160, 260, 460, 560, 660, 760‧‧‧ second side

170、470、570、670、770‧‧‧第一側面 First side of 170, 470, 570, 670, 770‧‧

171、261、361、461、471、561、571‧‧‧凹面圖案 171, 261, 361, 461, 471, 561, 571 ‧ ‧ concave pattern

173、263、363、463、473、563、573、663、673、773、761、763、771‧‧‧凸面圖案 173, 263, 363, 463, 473, 563, 573, 663, 673, 773, 761, 763, 771 ‧ ‧ convex patterns

180‧‧‧第一電極 180‧‧‧First electrode

190‧‧‧第二電極 190‧‧‧second electrode

360‧‧‧第三側面 360‧‧‧ third side

661、671‧‧‧微透鏡圖案 661, 671‧‧‧ microlens pattern

圖1是依據本發明第一實施例之發光二極體晶片的簡要平面圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic plan view of a light emitting diode wafer in accordance with a first embodiment of the present invention.

圖2是圖1中沿線段I-I’之發光二極體晶片的剖面圖。 Figure 2 is a cross-sectional view of the light-emitting diode wafer of Figure 1 along line I-I'.

圖3是依據本發明第二實施例之發光二極體晶片的簡要平面圖。 Figure 3 is a schematic plan view of a light emitting diode wafer in accordance with a second embodiment of the present invention.

圖4是圖3中沿線段I-I’之發光二極體晶片的剖面圖。 Figure 4 is a cross-sectional view of the light-emitting diode wafer of Figure 1 along line I-I'.

圖5是依據本發明第三實施例之發光二極體晶片的簡要平面圖。 Figure 5 is a schematic plan view of a light emitting diode wafer in accordance with a third embodiment of the present invention.

圖6是圖5中沿線段I-I’之發光二極體晶片的剖面圖。 Figure 6 is a cross-sectional view of the light-emitting diode wafer of Figure 1 along line I-I'.

圖7是依據本發明第四實施例之發光二極體晶片的簡要平面圖。 Figure 7 is a schematic plan view of a light emitting diode wafer in accordance with a fourth embodiment of the present invention.

圖8是圖7中沿線段I-I’之發光二極體晶片的剖面圖。 Figure 8 is a cross-sectional view of the light emitting diode chip taken along line I-I' of Figure 7.

圖9至圖11是依據本發明其他實施例之發光二極體晶片的示意圖。 9 through 11 are schematic views of a light emitting diode wafer in accordance with other embodiments of the present invention.

以下,本發明的範例實施例將以相關的附加圖式做說明。應被理解的是,其下方關於本發明的實施例僅是提供給熟知此領域的技術人員參考。因此,本發明並不受限於下方之實施例且當可作不同的操作。除此之外,類似的構件將以類似的元件符號標示在說明書中,且某些元件、膜層或特徵的寬度、長度及厚度為了清楚而會被誇大。 Hereinafter, exemplary embodiments of the present invention will be described with reference to the accompanying drawings. It is to be understood that the embodiments of the invention below are merely provided to those skilled in the art. Therefore, the present invention is not limited to the embodiments below and when different operations are possible. In addition, similar components will be denoted by the same reference numerals in the description, and the width, length and thickness of some elements, layers or features may be exaggerated for clarity.

圖1是依據本發明第一實施例之發光二極體晶片的簡要平面圖,且圖2是圖1中沿線段I-I’之發光二極體晶片的剖面圖。 BRIEF DESCRIPTION OF THE DRAWINGS Figure 1 is a schematic plan view of a light-emitting diode wafer according to a first embodiment of the present invention, and Figure 2 is a cross-sectional view of the light-emitting diode wafer of Figure 1 along line I-I'.

請參考圖1及圖2,根據本發明第一實施例中的發光二極體晶片100包括基板110、半導體堆疊、透明電極層150、第一電極180以及第二電極190。 Referring to FIG. 1 and FIG. 2, a light emitting diode wafer 100 according to a first embodiment of the present invention includes a substrate 110, a semiconductor stack, a transparent electrode layer 150, a first electrode 180, and a second electrode 190.

基板110可為用於氮化鎵型化合物半導體層(gallium nitride based compound semiconductor layer)成長的成長基板,例如為藍寶石基板、尖晶石(spinel)基板、氮化鎵(gallium nitride)基板、碳化矽(silicon carbide)基板或矽(silicon)基板,其相關材料不加以限制。 The substrate 110 may be a growth substrate for growth of a gallium nitride based compound semiconductor layer, such as a sapphire substrate, a spinel substrate, a gallium nitride substrate, or tantalum carbide. A (silicon carbide) substrate or a silicon substrate, the related materials are not limited.

基板110包括形成於其上表面上的凸-凹圖案111。凸-凹圖案111供以改善發光效能。凸-凹圖案111將朝基板110的表面導向的光線折射至基板的外部。凸-凹圖案111形成為突出條狀型半圓柱形。 The substrate 110 includes a convex-concave pattern 111 formed on an upper surface thereof. The convex-concave pattern 111 is provided to improve luminous efficacy. The convex-concave pattern 111 refracts light directed toward the surface of the substrate 110 to the outside of the substrate. The convex-concave pattern 111 is formed to protrude into a strip-shaped semi-cylindrical shape.

雖然凸-凹圖案111是畫成具有突出條狀型半圓柱形,惟 應被理解在此並非用以限制本發明。另外,凸-凹圖案111可為孤島型半圓球形或是其他多邊形。 Although the convex-concave pattern 111 is drawn to have a protruding strip-shaped semi-cylindrical shape, It should be understood that this is not intended to limit the invention. In addition, the convex-concave pattern 111 may be an island-shaped semi-spherical shape or other polygonal shape.

半導體堆疊包括第一導電型半導體層120、主動層130以及第二導電型半導體層140。 The semiconductor stack includes a first conductive type semiconductor layer 120, an active layer 130, and a second conductive type semiconductor layer 140.

主動層130插在第一導電型半導體層120以及第二導電型半導體層140之間,且可具有單一量子井結構(single quantum well structure)或多量子井結構(multi-quantum well structure)。主動層130的構成元素以及比例經決定以發射具有期望波長的光,例如,紫外線(UV)或可見光。 The active layer 130 is interposed between the first conductive type semiconductor layer 120 and the second conductive type semiconductor layer 140, and may have a single quantum well structure or a multi-quantum well structure. The constituent elements and proportions of the active layer 130 are determined to emit light having a desired wavelength, such as ultraviolet (UV) or visible light.

第一導電型半導體層120可包括N型氮化鎵(GaN),且第二導電型半導體層140可包括P型氮化鎵。另外,第一及第二導電型半導體層可分別由P型及N型GaN所形成。第一導電型半導體層120及第二導電型半導體層140可各別形成為單層或多層。 The first conductive type semiconductor layer 120 may include N-type gallium nitride (GaN), and the second conductive type semiconductor layer 140 may include P-type gallium nitride. Further, the first and second conductive semiconductor layers may be formed of P-type and N-type GaN, respectively. The first conductive semiconductor layer 120 and the second conductive semiconductor layer 140 may be formed in a single layer or a plurality of layers, respectively.

主動層130、第一導電型半導體層120以及第二導電型半導體層140可由金屬有機化學氣相沈積法(metallorganic chemical vapor deposition,MOCVD)或分子束磊晶法(molecular beam epitaxy,MBE)所形成。 The active layer 130, the first conductive semiconductor layer 120, and the second conductive semiconductor layer 140 may be formed by metalorganic chemical vapor deposition (MOCVD) or molecular beam epitaxy (MBE). .

透明電極層150形成於第二導電型半導體層140之上方。透明電極層150可由透明氧化物形成,例如是銦錫氧化物(indiumtin oxide,ITO)、氧化鋅(ZnO)、摻氟氧化錫(Fluorine-doped Tin Oxide,FTO)、摻鎵氧化鋅(gallium doped zinc oxide,GZO)、石墨烯(graphene)、碳奈米管(carbon nanotube,CNT)、鎳/金等類 似的物質,且透明電極層150與第二導電型半導體層140形成歐姆接觸。雖然未繪示於圖式中,電流阻隔層(未繪示)可形成於透明電極層150及第二導電型半導體層140之間。電流阻隔層供以增強透明電極層150及第二導電型半導體層140之間的電流散佈。 The transparent electrode layer 150 is formed over the second conductive type semiconductor layer 140. The transparent electrode layer 150 may be formed of a transparent oxide such as indium tin oxide (ITO), zinc oxide (ZnO), Fluorine-doped Tin Oxide (FTO), gallium doped zinc oxide (gallium doped). Zinc oxide, GZO), graphene, carbon nanotube (CNT), nickel/gold, etc. Like the substance, the transparent electrode layer 150 forms an ohmic contact with the second conductive type semiconductor layer 140. Although not shown in the drawings, a current blocking layer (not shown) may be formed between the transparent electrode layer 150 and the second conductive type semiconductor layer 140. The current blocking layer is provided to enhance current spreading between the transparent electrode layer 150 and the second conductive type semiconductor layer 140.

在發光二極體晶片100中,第一導電型半導體層120與透明電極層150、第二導電型半導體層140以及主動層130藉平臺蝕刻而一起被部份蝕刻,以暴露第一導電型半導體層120。透明電極層150以及半導體堆疊的受到平臺蝕刻的外側面定義為第一側面170。第一側面170形成有凸面圖案173及凹面圖案171,其增強橫向光提取效率。 In the light-emitting diode wafer 100, the first conductive semiconductor layer 120 and the transparent electrode layer 150, the second conductive semiconductor layer 140, and the active layer 130 are partially etched together by platform etching to expose the first conductive semiconductor. Layer 120. The transparent electrode layer 150 and the platform-etched outer side of the semiconductor stack are defined as a first side 170. The first side surface 170 is formed with a convex pattern 173 and a concave pattern 171 which enhance lateral light extraction efficiency.

凸面圖案173及凹面圖案171沿第一側面170交錯形成,且凸面圖案173具有圓突出形狀。凸面圖案173及凹面圖案171可在使用光阻的罩幕製程中形成。換句話說,罩幕(未繪示)的外側面具有與凸面圖案173及凹面圖案171相同的形狀。 The convex pattern 173 and the concave pattern 171 are alternately formed along the first side surface 170, and the convex pattern 173 has a rounded shape. The convex pattern 173 and the concave pattern 171 can be formed in a mask process using photoresist. In other words, the outer side surface of the mask (not shown) has the same shape as the convex pattern 173 and the concave pattern 171.

發光二極體晶片100被分割成在基板110上的單元胞,且單元胞藉由切割而彼此分割開,從而提供單一發光二極體晶片100,如圖1及圖2所示。 The light-emitting diode wafer 100 is divided into unit cells on the substrate 110, and the unit cells are separated from each other by cutting, thereby providing a single light-emitting diode wafer 100, as shown in FIGS. 1 and 2.

在此,分割發光二極體晶片100為單元胞的步驟中,第一導電型半導體層120也是藉由蝕刻以分割成單元胞,因此基板110的上表面可以在第一導電型半導體層120的邊緣處暴露出。 Here, in the step of dividing the light-emitting diode wafer 100 into unit cells, the first conductive type semiconductor layer 120 is also divided into unit cells by etching, and thus the upper surface of the substrate 110 may be in the first conductive type semiconductor layer 120. The edges are exposed.

分割成單元胞的第一導電型半導體層120的外側面定義為第二側面160。第二側面160具有平坦結構。 The outer side surface of the first conductive type semiconductor layer 120 divided into unit cells is defined as a second side surface 160. The second side 160 has a flat structure.

在上述依據本發明的第一實施例的發光二極體晶片100中,凸面圖案173及凹面圖案171是交錯形成在透明電極層150及半導體堆疊的第一側面170之上,藉以減低在發光二極體晶片100的側面的全反射,從而使發光二極體晶片有優異的光提取。 In the above-described light emitting diode wafer 100 according to the first embodiment of the present invention, the convex pattern 173 and the concave pattern 171 are alternately formed on the transparent electrode layer 150 and the first side surface 170 of the semiconductor stack, thereby reducing the light emission The total reflection of the side faces of the polar body wafer 100 allows the light-emitting diode wafer to have excellent light extraction.

圖3是依據本發明第二實施例之發光二極體晶片的簡要平面圖,圖4是圖3中沿線段I-I’所切割出之發光二極體晶片的剖面圖。 3 is a schematic plan view of a light-emitting diode wafer according to a second embodiment of the present invention, and FIG. 4 is a cross-sectional view of the light-emitting diode wafer cut along line I-I' of FIG.

如圖3及圖4所示,依據本發明第二實施例的發光二極體晶片200與依據本發明第一實施例的發光二極體晶片100(參照圖1)除了第二側面260之外具有相同的結構。因此,相同的構件將以相同的元件符號標示,且細部的說明在此將會被省略。 As shown in FIG. 3 and FIG. 4, the light-emitting diode wafer 200 according to the second embodiment of the present invention and the light-emitting diode wafer 100 (refer to FIG. 1) according to the first embodiment of the present invention are apart from the second side surface 260. Have the same structure. Therefore, the same components will be denoted by the same reference numerals, and the description of the details will be omitted herein.

第一側面170包括第一凸面圖案173及第一凹面圖案171。凸面圖案173及凹面圖案171沿第一側面170交錯形成。 The first side surface 170 includes a first convex pattern 173 and a first concave pattern 171. The convex pattern 173 and the concave pattern 171 are alternately formed along the first side surface 170.

第二側面260是由第一導電型半導體層120的外側面所定義出,並且包括第二凸面圖案263及第二凹面圖案261。第二凸面圖案263及第二凹面圖案261沿第二側面260交錯形成。第二凸面圖案263及第二凹面圖案261供以改善發光二極體晶片300的橫向光提取。第二凸面圖案263具有圓突出形狀。第二凸面圖案263及第二凹面圖案261可在使用光阻的罩幕製程之中形成。換句話說,罩幕(未繪示)的外側面具有與第二凸面圖案263及第二凹面圖案261相同的形狀。第二凸面圖案263以及第二凹面圖案261由單元胞分割製程所形成。 The second side surface 260 is defined by the outer side surface of the first conductive type semiconductor layer 120 and includes a second convex pattern 263 and a second concave pattern 261. The second convex pattern 263 and the second concave pattern 261 are alternately formed along the second side 260. The second convex pattern 263 and the second concave pattern 261 are provided to improve lateral light extraction of the light emitting diode wafer 300. The second convex pattern 263 has a rounded shape. The second convex pattern 263 and the second concave pattern 261 may be formed in a mask process using photoresist. In other words, the outer side surface of the mask (not shown) has the same shape as the second convex pattern 263 and the second concave pattern 261. The second convex pattern 263 and the second concave pattern 261 are formed by a cell division process.

在根據上述本發明的第二實施例的發光二極體晶片200中,第一凸面圖案173及第一凹面圖案171交錯形成於第一側面170上,其藉平臺蝕刻透明電極層150以及半導體堆疊所形成,且第二凸面圖案263以及第二凹面圖案261交錯形成於由單元胞分割製程蝕刻的第一導電型半導體層120的第二側面260上,藉以減低發光二極體晶片200的側面處的全反射,從而使發光二極體晶片有優異的光提取。 In the light emitting diode wafer 200 according to the second embodiment of the present invention, the first convex pattern 173 and the first concave pattern 171 are alternately formed on the first side surface 170, which etches the transparent electrode layer 150 and the semiconductor stack by the platform. Formed, and the second convex pattern 263 and the second concave pattern 261 are alternately formed on the second side surface 260 of the first conductive type semiconductor layer 120 etched by the cell division process, thereby reducing the side surface of the light emitting diode wafer 200 The total reflection, so that the light-emitting diode wafer has excellent light extraction.

圖5是依據本發明第三實施例之發光二極體晶片的簡要平面圖,圖6是圖5中沿線段I-I’所切割出之發光二極體晶片的剖面圖。 Figure 5 is a schematic plan view of a light-emitting diode wafer according to a third embodiment of the present invention, and Figure 6 is a cross-sectional view of the light-emitting diode wafer cut along line I-I' of Figure 5 .

如圖5及圖6所示,依據本發明第三實施例的發光二極體晶片300與依據本發明第一實施例的發光二極體晶片100(參照圖1)除了第二側面260及第三側面360之外具有相同的結構。因此,相同的構件將以相同的元件符號標示,且細部的說明在此將會被省略。 As shown in FIG. 5 and FIG. 6, a light-emitting diode wafer 300 according to a third embodiment of the present invention and a light-emitting diode wafer 100 (refer to FIG. 1) according to the first embodiment of the present invention are provided with the second side 260 and the The three sides 360 have the same structure. Therefore, the same components will be denoted by the same reference numerals, and the description of the details will be omitted herein.

第一側面170包括第一凸面圖案173及第一凹面圖案171。第一凸面圖案173及第一凹面圖案171沿第一側面170交錯形成。 The first side surface 170 includes a first convex pattern 173 and a first concave pattern 171. The first convex pattern 173 and the first concave pattern 171 are alternately formed along the first side surface 170.

第二側面260被定義為第一導電型半導體層120的外側面,並且包括第二凸面圖案263及第二凹面圖案261。第二凸面圖案263及第二凹面圖案261沿第二側面260交錯形成。第二凸面圖案263及第二凹面圖案261供以改善發光二極體晶片300的橫 向光提取。第二凸面圖案263具有圓突出形狀。 The second side surface 260 is defined as an outer side surface of the first conductive type semiconductor layer 120 and includes a second convex pattern 263 and a second concave pattern 261. The second convex pattern 263 and the second concave pattern 261 are alternately formed along the second side 260. The second convex pattern 263 and the second concave pattern 261 are provided to improve the horizontal direction of the LED wafer 300 Extract to light. The second convex pattern 263 has a rounded shape.

第三側表面360定義為第一導電型半導體層120的外側面,且是置於第二側面260之上。第三側面360包括第三凸面圖案363及第三凹面圖案361。第三凸面圖案363及第三凹面圖案361沿第三側面360交錯形成。第三凸面圖案363及第三凹面圖案361供以改善發光二極體晶片300的橫向光提取。第三凸面圖案363具有圓突出形狀。 The third side surface 360 is defined as an outer side surface of the first conductive type semiconductor layer 120 and is disposed on the second side surface 260. The third side 360 includes a third convex pattern 363 and a third concave pattern 361. The third convex pattern 363 and the third concave pattern 361 are alternately formed along the third side 360. The third convex pattern 363 and the third concave pattern 361 are provided to improve lateral light extraction of the light emitting diode wafer 300. The third convex pattern 363 has a rounded shape.

第二凸面圖案263、第二凹面圖案261以及第三凸面圖案363和第三凹面圖案361可在使用光阻的罩幕製程中形成。換句話說,罩幕(未繪示)的外側面具有與第二凸面圖案263、第二凹面圖案261、第三凸面圖案363以及第三凹面圖案361相同的形狀。第二凸面圖案263、第二凹面圖案261、第三凸面圖案363以及第三凹面圖案361由單元胞分割製程所形成。在此,第二凸面圖案263、第二凹面圖案261、第三凸面圖案363以及第三凹面圖案361可由單一罩幕製程所形成。換句話說,第二凸面圖案263、第二凹面圖案261、第三凸面圖案363以及第三凹面圖案361可以用繞射式罩幕(diffraction mask)或半調式罩幕(halftone mask)形成。 The second convex pattern 263, the second concave pattern 261, and the third convex pattern 363 and the third concave pattern 361 may be formed in a mask process using photoresist. In other words, the outer side surface of the mask (not shown) has the same shape as the second convex pattern 263, the second concave pattern 261, the third convex pattern 363, and the third concave pattern 361. The second convex pattern 263, the second concave pattern 261, the third convex pattern 363, and the third concave pattern 361 are formed by a unit cell division process. Here, the second convex pattern 263, the second concave pattern 261, the third convex pattern 363, and the third concave pattern 361 may be formed by a single mask process. In other words, the second convex pattern 263, the second concave pattern 261, the third convex pattern 363, and the third concave pattern 361 may be formed using a diffraction mask or a halftone mask.

在上述根據本發明的第三實施例的發光二極體晶片300中,第一凸面圖案173及第一凹面圖案171交錯形成於第一側面170上,其藉由平臺蝕刻透明電極層150以及半導體堆疊所形成,第二凸面圖案263以及第二凹面圖案261交錯形成於由單元胞分割製程蝕刻的第一導電型半導體層120的第二側面260上,且第 三凸面圖案363以及第三凹面圖案361交錯形成於第三側面360上,藉以減低發光二極體晶片300的側面處的全反射,從而使發光二極體晶片有優異的光提取。 In the above-described light emitting diode wafer 300 according to the third embodiment of the present invention, the first convex pattern 173 and the first concave pattern 171 are alternately formed on the first side surface 170, which etches the transparent electrode layer 150 and the semiconductor by the terrace. Formed by the stack, the second convex pattern 263 and the second concave pattern 261 are alternately formed on the second side 260 of the first conductive semiconductor layer 120 etched by the cell division process, and The three convex surface pattern 363 and the third concave surface pattern 361 are alternately formed on the third side surface 360, thereby reducing total reflection at the side surface of the light emitting diode wafer 300, thereby providing excellent light extraction of the light emitting diode wafer.

圖7是依據本發明第四實施例之發光二極體晶片的簡要平面圖,圖8是圖7中沿線段I-I’所切割出之發光二極體晶片的剖面圖。 Figure 7 is a schematic plan view of a light-emitting diode wafer in accordance with a fourth embodiment of the present invention, and Figure 8 is a cross-sectional view of the light-emitting diode wafer cut along line I-I' of Figure 7.

如圖7及圖8所示,依據本發明第四實施例的發光二極體晶片400與依據本發明第二實施例的發光二極體晶片200(參照圖3)除了第一側面470及第二側面460之外具有相同的結構。因此,相同的構件將以相同的元件符號標示,且細部的說明在此將會被省略。 As shown in FIG. 7 and FIG. 8, a light-emitting diode wafer 400 according to a fourth embodiment of the present invention and a light-emitting diode chip 200 (refer to FIG. 3) according to the second embodiment of the present invention are provided with the first side 470 and the The two sides 460 have the same structure. Therefore, the same components will be denoted by the same reference numerals, and the description of the details will be omitted herein.

第一側面470包括第一凸面圖案473以及第一凹面圖案471。第一凸面圖案473及第一凹面圖案471沿第一側面470交錯形成。第一側面470具有固定傾斜角度。 The first side surface 470 includes a first convex pattern 473 and a first concave pattern 471. The first convex pattern 473 and the first concave pattern 471 are alternately formed along the first side surface 470. The first side 470 has a fixed angle of inclination.

第二側面460包括第二凸面圖案463以及第二凹面圖案461。第二凸面圖案463以及第二凹面圖案461沿第二側面460交錯形成。第二側面460具有固定傾斜角度。 The second side surface 460 includes a second convex pattern 463 and a second concave pattern 461. The second convex pattern 463 and the second concave pattern 461 are alternately formed along the second side 460. The second side 460 has a fixed angle of inclination.

在根據本發明上方的第四實施例的發光二極體晶片400中,第一凸面圖案473及第一凹面圖案471交錯形成於第一側面470上,其藉平臺蝕刻透明電極層150以及半導體堆疊所形成,第二凸面圖案463以及第二凹面圖案461交錯形成於由單元胞分割製程蝕刻的第一導電型半導體層120的第二側面460上,且第一 側面470以及第二側面460具有固定傾斜角度,從而加以改善發光二極體晶片100的橫向光提取。 In the LED array 400 according to the fourth embodiment of the present invention, the first convex pattern 473 and the first concave pattern 471 are alternately formed on the first side surface 470, which etches the transparent electrode layer 150 and the semiconductor stack by the platform. Formed, the second convex pattern 463 and the second concave pattern 461 are alternately formed on the second side 460 of the first conductive semiconductor layer 120 etched by the cell division process, and first The side surface 470 and the second side surface 460 have a fixed tilt angle to improve lateral light extraction of the light emitting diode wafer 100.

圖9至圖11是依據本發明其他實施例之發光二極體晶片的示意圖。 9 through 11 are schematic views of a light emitting diode wafer in accordance with other embodiments of the present invention.

請參考圖9,透明電極層以及半導體堆疊的第一側面570包括第一凸面圖案573以及第一凹面圖案571,且第一導電型半導體層以單元胞分割製程蝕刻的第二側面560包括第二凸面圖案563以及第二凹面圖案561。 Referring to FIG. 9, the first electrode 570 of the transparent electrode layer and the semiconductor stack includes a first convex pattern 573 and a first concave pattern 571, and the second side 560 of the first conductive semiconductor layer etched by the cell division process includes a second The convex pattern 563 and the second concave pattern 561.

第一凸面圖案573及第二凸面圖案563具有圓突出形狀,且第一凹面圖案571及第二凹面圖案561具有圓溝槽形狀。也就是說,第一側面570及第二側面560具有波浪狀圖案。 The first convex pattern 573 and the second convex pattern 563 have a rounded shape, and the first concave pattern 571 and the second concave pattern 561 have a circular groove shape. That is, the first side 570 and the second side 560 have a wavy pattern.

第一側面570及第二側面560藉由波浪狀圖案可改善發光二極體晶片的橫向光提取。 The first side 570 and the second side 560 can improve lateral light extraction of the LED wafer by a wavy pattern.

在本實施例中,波浪狀圖案如敘述形成在第一側邊570及第二側邊560上。然而,其並非用以限定本發明,且波浪狀圖案可形成在第一側邊570及第二側邊560至少其中一個上。 In the present embodiment, the wavy pattern is formed on the first side 570 and the second side 560 as described. However, it is not intended to limit the invention, and a wavy pattern may be formed on at least one of the first side 570 and the second side 560.

請參考圖10,透明電極層的第一側面670以及半導體堆疊包括第一凸面圖案673以及第一微透鏡圖案671,且以單元胞分割製程蝕刻的第一導電型半導體層的第二側面660包括第二凸面圖案663以及第二微透鏡圖案661。 Referring to FIG. 10, the first side 670 of the transparent electrode layer and the semiconductor stack include a first convex pattern 673 and a first microlens pattern 671, and the second side 660 of the first conductive semiconductor layer etched by the cell division process includes The second convex pattern 663 and the second microlens pattern 661.

藉由形成於第一側面670上的第一凸面圖案673以及第一微透鏡圖案671以及形成於第二側面660上的第二凸面圖案663 以及第二微透鏡圖案661,發光二極體晶片改善了橫向光提取。 The first convex pattern 673 and the first microlens pattern 671 formed on the first side 670 and the second convex pattern 663 formed on the second side 660 And the second microlens pattern 661, the light emitting diode wafer improves lateral light extraction.

在本實施例中,雖然第一凸面圖案673以及第一微透鏡圖案671如敘述形成於第一側面670上且第二凸面圖案663以及第二微透鏡圖案661如敘述形成於第二側面660上,但本發明並不限於此,而這些圖案也可只形成於第一側面670以及第二側面660其中之一上。 In the present embodiment, the first convex pattern 673 and the first microlens pattern 671 are formed on the first side 670 as described above, and the second convex pattern 663 and the second microlens pattern 661 are formed on the second side 660 as described. However, the present invention is not limited thereto, and these patterns may be formed only on one of the first side 670 and the second side 660.

請參考圖11,透明電極層以及半導體堆疊的第一側面770包括第一凸面圖案773以及第二凸面圖案771,且第一導電型半導體層由單元胞分割製程蝕刻的第二側面760包括第三凸面圖案763以及第四凸面圖案761。 Referring to FIG. 11 , the first electrode 770 of the transparent electrode layer and the semiconductor stack includes a first convex pattern 773 and a second convex pattern 771 , and the second side 760 of the first conductive semiconductor layer etched by the cell division process includes a third surface. The convex pattern 763 and the fourth convex pattern 761.

第一凸面圖案773以及第三凸面圖案763具有圓突出圖案,且第二凸面圖案771以及第四凸面圖案761具有三角突出圖案。 The first convex pattern 773 and the third convex pattern 763 have a circular protruding pattern, and the second convex pattern 771 and the fourth convex pattern 761 have a triangular protruding pattern.

藉由形成於第一側面770以及第二側面760上的第一凸面圖案773以及第二凸面圖案771與第三凸面圖案763以及第四凸面圖案761,發光二極體晶片改善了橫向光提取。 The light-emitting diode wafer improves lateral light extraction by the first convex pattern 773 and the second convex pattern 771 and the third convex pattern 763 and the fourth convex pattern 761 formed on the first side 770 and the second side 760.

在本實施例中,雖然第一凸面圖案773以及第二凸面圖案771與第三凸面圖案763以及第四凸面圖案761如敘述各自形成於第一側面770以及第二側面760上,但本發明並不限於此,而這些圖案也可只形成於第一側面770以及第二側面760其中之一上。此外,雖然凸面圖案如描述具有圓形狀或三角形狀,但凸面圖案的形狀只要能夠提供光提取的功能即可作許多的調整。 In this embodiment, although the first convex pattern 773 and the second convex pattern 771 and the third convex pattern 763 and the fourth convex pattern 761 are respectively formed on the first side 770 and the second side 760, the present invention Not limited thereto, these patterns may be formed only on one of the first side 770 and the second side 760. Further, although the convex pattern has a circular shape or a triangular shape as described, the shape of the convex pattern can be adjusted as much as long as it can provide a function of light extraction.

雖然本發明的一些實施例與特徵揭露如上,然其並非用以限定本發明,且可在不脫離本發明的範疇內可做各種變更。 While some embodiments and features of the invention are disclosed above, it is not intended to limit the invention, and various modifications may be made without departing from the scope of the invention.

Claims (14)

一種發光二極體晶片,包括:基底;半導體堆疊,形成於所述基底上,包括第一導電型半導體層、主動層以及第二導電型半導體層,所述半導體堆疊具有第一側面以及設置於所述第一側面之下方的第二表面,其中所述第一側面為以平臺蝕刻所述半導體堆疊之外側面,所述第二側面為所述第一導電型半導體層之外側面,且所述第一側面及所述第二側面的至少其中之一具有凸面圖案;以及透明電極層,形成於所述第二導電型半導體層之上方,所述透明電極層之外側面包括在所述第一側面之中,其中所述凸面圖案的一部分形成於所述透明電極層之所述外側面,且所述凸面圖案的所述部分環繞於所述透明電極層。 A light emitting diode wafer comprising: a substrate; a semiconductor stack formed on the substrate, comprising a first conductive semiconductor layer, an active layer and a second conductive semiconductor layer, the semiconductor stack having a first side and being disposed on a second surface below the first side surface, wherein the first side surface is an outer surface of the semiconductor stack by a platform, and the second side surface is an outer side surface of the first conductive type semiconductor layer, and At least one of the first side surface and the second side surface has a convex pattern; and a transparent electrode layer is formed over the second conductive type semiconductor layer, and the outer surface of the transparent electrode layer is included in the first In a side surface, a portion of the convex pattern is formed on the outer side surface of the transparent electrode layer, and the portion of the convex pattern surrounds the transparent electrode layer. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第一側面及各所述二側面的至少其中之一更包括凹面圖案,所述凹面圖案包括平板形,所述凹面圖案與所述凸面圖案交錯排列。 The illuminating diode chip of claim 1, wherein at least one of the first side and each of the two sides further comprises a concave pattern, the concave pattern comprising a flat shape, the concave pattern Interlaced with the convex pattern. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第一側面及所述二側面的每一者更包括凹面圖案,所述凹面圖案包括平板形,所述凹面圖案與所述凸面圖案交錯排列。 The light-emitting diode wafer of claim 1, wherein each of the first side surface and the two side surfaces further comprises a concave pattern, the concave surface pattern comprising a flat plate shape, the concave surface pattern and the concave surface pattern The convex patterns are staggered. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第一側面及所述第二側面的至少其中之一包括微透鏡圖案,所述微透鏡圖案與所述凸面圖案交錯排列。 The illuminating diode chip of claim 1, wherein at least one of the first side surface and the second side surface comprises a microlens pattern, and the microlens pattern is staggered with the convex pattern . 如申請專利範圍第1項所述的發光二極體晶片,其中所述凸面圖案包括圓突出圖案、三角突出圖案及矩形突出圖案中至少其中二者,其彼此交錯排列。 The light emitting diode chip of claim 1, wherein the convex pattern comprises at least two of a circular protruding pattern, a triangular protruding pattern, and a rectangular protruding pattern, which are staggered with each other. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第一側面及所述第二側面的至少其中之一更包括凹面圖案,所述凹面圖案包括圓溝槽形狀,所述凹面圖案與所述凸面圖案交錯排列。 The light emitting diode chip of claim 1, wherein at least one of the first side surface and the second side surface further comprises a concave pattern, the concave surface pattern comprising a circular groove shape, The concave pattern is staggered with the convex pattern. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第一表面與所述第二側面兩者具有固定傾斜角度。 The light-emitting diode wafer of claim 1, wherein the first surface and the second side have a fixed tilt angle. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第一導電型半導體層更包括在所述第一導電型半導體層的外側面處形成於所述第二側面上的第三側面。 The illuminating diode chip according to claim 1, wherein the first conductive semiconductor layer further includes a second surface formed on an outer side surface of the first conductive semiconductor layer Three sides. 如申請專利範圍第7項所述的發光二極體晶片,其中所述凸面圖案包括:第一凸面圖案,位於所述第一側面上;第二凸面圖案,位於所述第二側面上;以及第三凸面圖案,位於所述第三側面上。 The illuminating diode chip of claim 7, wherein the convex pattern comprises: a first convex pattern on the first side; a second convex pattern on the second side; A third convex pattern is located on the third side. 如申請專利範圍第9項所述的發光二極體晶片,其中所述第一側面包括與所述第一凸面圖案交錯排列的第一凹面圖案,所述第二側面包括與所述第二凸面圖案交錯排列的第二凹面圖案,以及所述第三側面包括與所述第三凸面圖案交錯排列的第三凹面圖案。 The illuminating diode chip of claim 9, wherein the first side surface comprises a first concave pattern staggered with the first convex pattern, and the second side includes the second convex surface a second concave pattern in which the patterns are staggered, and the third side includes a third concave pattern staggered with the third convex pattern. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第一側面對應於藉由平臺蝕刻所述透明電極層及所述半導體堆疊所形成之區域。 The light emitting diode chip of claim 1, wherein the first side corresponds to a region formed by etching the transparent electrode layer and the semiconductor stack by a platform. 如申請專利範圍第11項所述的發光二極體晶片,其中所述第一側面具有對應於用於所述平臺蝕刻的罩幕的邊緣的形狀。 The light-emitting diode wafer of claim 11, wherein the first side has a shape corresponding to an edge of a mask for etching the platform. 如申請專利範圍第1項所述的發光二極體晶片,其中所述第二側面對應於藉由單元胞分割製程所蝕刻之所述第一導電型半導體層之區域。 The light-emitting diode wafer according to claim 1, wherein the second side corresponds to a region of the first conductive type semiconductor layer etched by a cell division process. 如申請專利範圍第12項所述的發光二極體晶片,其中所述第二側面具有對應於用於所述單元胞分割製程的罩幕的邊緣之形狀。 The light-emitting diode wafer of claim 12, wherein the second side has a shape corresponding to an edge of a mask for the unit cell division process.
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