TWI620924B - Shell container for complex probe and complex probe - Google Patents

Shell container for complex probe and complex probe Download PDF

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Publication number
TWI620924B
TWI620924B TW104130748A TW104130748A TWI620924B TW I620924 B TWI620924 B TW I620924B TW 104130748 A TW104130748 A TW 104130748A TW 104130748 A TW104130748 A TW 104130748A TW I620924 B TWI620924 B TW I620924B
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Taiwan
Prior art keywords
molten metal
receiving chamber
chamber
container
temperature
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TW104130748A
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Chinese (zh)
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TW201617594A (en
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李萬業
鄭義星
金孝相
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又進電子騎士有限公司
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    • GPHYSICS
    • G01MEASURING; TESTING
    • G01KMEASURING TEMPERATURE; MEASURING QUANTITY OF HEAT; THERMALLY-SENSITIVE ELEMENTS NOT OTHERWISE PROVIDED FOR
    • G01K13/00Thermometers specially adapted for specific purposes
    • G01K13/12Thermometers specially adapted for specific purposes combined with sampling devices for measuring temperatures of samples of materials

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  • Physics & Mathematics (AREA)
  • General Physics & Mathematics (AREA)
  • Investigating And Analyzing Materials By Characteristic Methods (AREA)
  • Sampling And Sample Adjustment (AREA)
  • Carbon Steel Or Casting Steel Manufacturing (AREA)

Abstract

本發明揭示一種用於複合探針的殼體容器。該殼體容器浸入熔融金屬內,以允許該熔融金屬導入其中,該殼體容器包含:一流入孔,其定義在該殼體容器之側表面內,以允許該熔融金屬導入其中;一鋼接收腔室以及一收集腔室,其中該熔融金屬透過該流入孔導入其中而充滿其中;一鋼接收流道,其將該流入孔連接至該鋼接收腔室;以及一收集流道,其將該流入孔連接至該收集腔室。該熔融金屬探針另包含一第一溫度感測器,其包含放置於該鋼接收腔室內之一溫度測量部分,並且在該鋼接收腔室的內表面上形成有不平整的圖案。 The invention discloses a shell container for a composite probe. The shell container is immersed in the molten metal to allow the molten metal to be introduced therein. The shell container includes: an inflow hole defined in a side surface of the shell container to allow the molten metal to be introduced thereinto; A chamber and a collection chamber, wherein the molten metal is introduced thereinto through the inflow hole to fill it; a steel receiving flow channel that connects the inflow hole to the steel receiving chamber; and a collection flow channel that An inflow hole is connected to the collection chamber. The molten metal probe further includes a first temperature sensor including a temperature measurement portion placed in the steel receiving chamber, and an uneven pattern is formed on an inner surface of the steel receiving chamber.

Description

用於複合探針之殼體容器以及複合探針 Housing container for composite probe and composite probe

本發明係關於用於複合探針之殼體容器及複合探針,尤其係關於浸入熔融金屬來測量該熔融金屬溫度或凝固溫度的複合探針之殼體容器及複合探針。 The present invention relates to a housing container and a composite probe for a composite probe, and more particularly, to a housing container and a composite probe for a composite probe immersed in a molten metal to measure the temperature of the molten metal or the solidification temperature.

複合探針已經浸入熔融鋼內,像是利用升降裝置的一轉爐(例如一子吹管),然後取出用來分析該熔融鋼的成份。 The composite probe has been immersed in the molten steel, such as a converter (for example, a sub-blowing tube) using a lifting device, and then taken out to analyze the composition of the molten steel.

一探針本體包含定義在其側表面內的一流入孔,允許熔融鋼導入其中。已經導入探針本體內的熔融鋼會在熔融鋼充滿鋼接收腔室之狀態下凝固,一溫度感測器放置在該鋼接收腔室內,用來測量該熔融鋼的凝固溫度。該溫度感測器的溫度測量部分放置朝向一部分,就是當熔融鋼從熔融鋼邊緣逐漸凝固時該熔融鋼的最後凝固部分,以提供凝固溫度資料來評估該熔融鋼內的含碳量。另外,提供已凝固的熔融鋼當成儀器分析的樣本,像是發射光譜化學分析或燃燒化學分析。 A probe body contains an inflow hole defined in its side surface, allowing molten steel to be introduced therein. The molten steel that has been introduced into the probe body will solidify when the molten steel fills the steel receiving chamber. A temperature sensor is placed in the steel receiving chamber to measure the solidification temperature of the molten steel. The temperature measurement part of the temperature sensor is placed towards a part, that is, the last solidified part of the molten steel when the molten steel gradually solidifies from the edge of the molten steel, so as to provide the solidification temperature data to evaluate the carbon content in the molten steel. In addition, solidified molten steel is provided as a sample for instrumental analysis, such as emission spectrochemical analysis or combustion chemical analysis.

最近在轉爐操作中,一吹風模式多樣化來處理許多種鋼鐵,並且必須處理高品質鐵礦逐漸枯竭並且低成本原料逐漸增加使用以及鐵水比(HMR,hot metal ratio)通常隨廢鋼供需情形而波動之情況。另外,因為吹風技術會隨客戶所追求的冶煉週期(T-T)時間縮減、成本縮減以及設施效率 而變得複雜,所以用於測量時間與環境的探針要多樣化。 Recently in converter operation, a variety of blowing modes have been adopted to process many types of steel, and high-quality iron ore must be gradually depleted and low-cost raw materials are increasingly used. The hot metal ratio (HMR) usually varies with the supply and demand of scrap steel. Fluctuations. In addition, because the blowing technology will reduce the smelting cycle (T-T) time, cost and facility efficiency It becomes complicated, so probes for measuring time and environment are diversified.

本發明提供用於複合探針之殼體以及複合探針,其可精確測量熔融金屬的凝固溫度。 The invention provides a housing for a composite probe and a composite probe, which can accurately measure the solidification temperature of a molten metal.

本發明也提供用於複合探針之殼體以及複合探針,其可提高熔融金屬的冷卻率,來縮短熔融金屬的凝固時間。 The present invention also provides a housing for a composite probe and a composite probe, which can increase the cooling rate of the molten metal and shorten the solidification time of the molten metal.

本發明也提供一種用於複合探針的殼體容器以及複合探針,其允許熔融金屬順暢地導入其中。 The present invention also provides a housing container for a composite probe and a composite probe, which allows a molten metal to be smoothly introduced thereinto.

本發明的具體實施例提供一種用於複合探針的殼體容器,其浸入熔融金屬內允許熔融金屬導入其中,該殼體包含:一流入孔,其定義在該殼體容器側表面內,以允許該熔融金屬導入其中;一鋼接收腔室以及一收集腔室,其中該熔融金屬透過該流入孔導入其中而充滿其中;一鋼接收流道,其將該流入孔連接至該鋼接收腔室;以及一收集流道,其將該流入孔連接至該收集腔室,其中該熔融金屬探針另包含一第一溫度感測器,其包含位於該鋼接收腔室內之一溫度測量部分,並且在該鋼接收腔室的內表面上形成不平整的圖案。 A specific embodiment of the present invention provides a housing container for a composite probe, which is immersed in molten metal to allow the molten metal to be introduced therein. The housing includes: an inflow hole defined in a side surface of the housing container to The molten metal is allowed to be introduced therein; a steel receiving chamber and a collecting chamber, wherein the molten metal is introduced thereinto through the inflow hole and filled therein; a steel receiving flow channel that connects the inflow hole to the steel receiving chamber And a collecting flow channel connecting the inflow hole to the collecting chamber, wherein the molten metal probe further includes a first temperature sensor including a temperature measuring portion located in the steel receiving chamber, and An uneven pattern is formed on the inner surface of the steel receiving chamber.

在某些具體實施例內,該鋼接收腔室可具有長方體形,並且該圖案可形成於該鋼接收腔室內表面沿著縱向方向所定義的一縱向短表面上,該縱向短表面遠離該鋼接收腔室的中央部分。 In some specific embodiments, the steel receiving cavity may have a rectangular parallelepiped shape, and the pattern may be formed on a longitudinal short surface defined by an inner surface of the steel receiving cavity along a longitudinal direction, the longitudinal short surface being away from the steel The central part of the receiving chamber.

在其他具體實施例內,該鋼接收腔室可具有其中體積除以表面積為大約4至大約4.5之體積比。 In other specific embodiments, the steel receiving chamber may have a volume ratio in which the volume divided by the surface area is from about 4 to about 4.5.

仍舊在其他具體實施例內,該收集腔室可沿著該殼體容器的 縱向方向放置,並且該收集流道可具有形狀為圓弧的轉角部分。 In still other specific embodiments, the collection chamber may be along the It is placed in the longitudinal direction, and the collecting flow path may have a corner portion having a shape of an arc.

甚至在其他具體實施例內,該鋼接收流道可從該流入孔往遠離該第一溫度感測器的方向傾斜,並且該殼體容器的橫截面與該鋼接收流道之間的一傾斜角度大約在20°至60°之間。 Even in other specific embodiments, the steel receiving runner may be inclined from the inflow hole in a direction away from the first temperature sensor, and an inclination between the cross section of the housing container and the steel receiving runner The angle is between approximately 20 ° and 60 °.

尚且在其他具體實施例內,該流入孔可包含:一鋼接收注入口(steel receiving sprue),其設置成與該鋼接收腔室連通;以及一收集注入口,其設置成與該收集腔室連通,其中該鋼接收注入口和該收集注入口可彼此分隔。 In still other specific embodiments, the inflow hole may include: a steel receiving sprue configured to communicate with the steel receiving chamber; and a collection injection port configured to communicate with the collection chamber Communication, wherein the steel receiving injection port and the collecting injection port may be separated from each other.

在進一步具體實施例內,該鋼接收注入口可具有大約20mm至大約25mm的直徑。 In a further specific embodiment, the steel receiving injection port may have a diameter of about 20 mm to about 25 mm.

仍舊在進一步具體實施例內,該熔融金屬探針可另包含一第二溫度感測器,其位於該殼體容器的一前端,來測量該熔融金屬的溫度。 In still further embodiments, the molten metal probe may further include a second temperature sensor located at a front end of the housing container to measure the temperature of the molten metal.

甚至在進一步具體實施例內,該收集腔室與該鋼接收腔室都可沿著該殼體容器的一縱向與橫向方向放置,彼此不重疊。 In even further specific embodiments, the collection chamber and the steel receiving chamber can be placed along a longitudinal and lateral direction of the housing container without overlapping each other.

尚且在進一步具體實施例內,該熔融金屬探針可另包含一第二溫度感測器,其位於該殼體容器的一前端,來測量該熔融金屬的溫度,並且該注入口可定義在距離該殼體容器的該前端,往該殼體容器的該縱向方向大約200mm之處。 In a further specific embodiment, the molten metal probe may further include a second temperature sensor located at a front end of the housing container to measure the temperature of the molten metal, and the injection port may be defined at a distance The front end of the shell container is about 200 mm toward the longitudinal direction of the shell container.

在本發明的其他具體實施例內,一複合探針包含:一主分支管,其設置成在該主分支管已浸入熔融金屬的狀態下,允許該熔融金屬透過該管側邊部分內定義的一開口導入該複合探針;一外分支管,其位於該主分支管的外側部分上以關閉該開口;一殼體容器,其內建於該主分支管 內;第一和第二溫度感測器,其位於該殼體容器上;以及一連接器,其電連接至該等第一和第二溫度感測器之每一者,其中該殼體容器包含:一流入孔,其定義在該殼體容器側表面內,以與該開口連通來允許該熔融金屬導入其中;一鋼接收腔室以及一收集腔室,其中該熔融金屬透過該流入孔導入其中而充滿其中;一鋼接收流道,其將該流入孔連接至該鋼接收腔室;以及一收集流道,其將該流入孔連接至該收集腔室,其中該第一溫度感測器的一溫度測量部分位於該鋼接收腔室內,以及該第二溫度感測器位於該殼體容器的一前端上,在該鋼接收腔室的一內壁上形成一不平整圖案。 In other specific embodiments of the present invention, a composite probe includes: a main branch tube configured to allow the molten metal to pass through a defined side portion of the tube in a state where the main branch tube has been immersed in the molten metal. An opening introduces the composite probe; an outer branch tube is located on the outer part of the main branch tube to close the opening; a shell container is built in the main branch tube Inside; first and second temperature sensors on the housing container; and a connector electrically connected to each of the first and second temperature sensors, wherein the housing container Including: an inflow hole defined in the side surface of the shell container to communicate with the opening to allow the molten metal to be introduced therein; a steel receiving chamber and a collection chamber, wherein the molten metal is introduced through the inflow hole It is filled with it; a steel receiving runner that connects the inflow hole to the steel receiving chamber; and a collection runner that connects the inflow hole to the collection chamber, wherein the first temperature sensor A temperature measuring portion of the steel receiving chamber is located in the steel receiving chamber, and the second temperature sensor is located on a front end of the housing container, and an uneven pattern is formed on an inner wall of the steel receiving chamber.

1‧‧‧探針本體 1‧‧‧ probe body

2‧‧‧主分支管 2‧‧‧main branch pipe

3a‧‧‧鋼接收注入口/流入孔/開口 3a‧‧‧Steel receiving inlet / inlet / opening

3b‧‧‧收集注入口/流入孔/開口 3b‧‧‧ collection inlet / inlet / opening

4‧‧‧外分支管 4‧‧‧ Outer branch pipe

9‧‧‧鋼接收流道 9‧‧‧steel receiving runner

9r‧‧‧轉角部份 9r‧‧‧ Corner section

10‧‧‧鋼接收腔室 10‧‧‧steel receiving chamber

10a‧‧‧波形圖案(圓形突出物) 10a‧‧‧Wave pattern (circular protrusion)

11‧‧‧收集流道 11‧‧‧ collection runner

14‧‧‧第一安裝空間 14‧‧‧First installation space

17‧‧‧輔助分支管 17‧‧‧Auxiliary branch pipe

18‧‧‧收集腔室 18‧‧‧ collection chamber

20‧‧‧容納空間 20‧‧‧accommodation space

22‧‧‧第一溫度感測器 22‧‧‧The first temperature sensor

22a‧‧‧本體部分 22a‧‧‧Body

22b‧‧‧溫度測量管 22b‧‧‧Temperature measuring tube

22c‧‧‧溫度測量部分 22c‧‧‧Temperature measurement section

23‧‧‧收集容器 23‧‧‧ collection container

23a‧‧‧金屬容器本體 23a‧‧‧ metal container body

24‧‧‧第二溫度感測器 24‧‧‧Second Temperature Sensor

24a‧‧‧本體部分 24a‧‧‧Body

24b‧‧‧溫度測量管 24b‧‧‧Temperature measuring tube

24c‧‧‧金屬蓋 24c‧‧‧metal cover

26‧‧‧導引管 26‧‧‧ Guide tube

33a‧‧‧開口 33a‧‧‧ opening

33b‧‧‧開口 33b‧‧‧ opening

107‧‧‧殼體容器 107‧‧‧shell container

107a‧‧‧分割區塊 107a‧‧‧ split block

107b‧‧‧分割區塊 107b‧‧‧ split block

A‧‧‧脫氧劑 A‧‧‧Deoxidizer

C‧‧‧連接器 C‧‧‧ connector

f1,f2,f3‧‧‧側表面 f1, f2, f3‧‧‧side surface

h‧‧‧固定器 h‧‧‧ holder

p2‧‧‧波形圖案 p2‧‧‧wave pattern

p3‧‧‧凹陷圖案 p3‧‧‧ sunken pattern

S1,S2,S3‧‧‧樣本 S1, S2, S3 ‧‧‧ samples

在此包含附圖來進一步了解本發明,並且併入以及構成此說明書的一部分。圖式例示本發明的示範具體實施例,並且在搭配內容說明之後可用來解釋本發明原理。圖式中:第一圖為根據本發明具體實施例的一熔融金屬探針之剖面圖;第二圖為第一圖中該熔融金屬探針的分解透視圖;第三圖為切開第一圖中該熔融金屬探針一部分的透視圖;第四圖為例示第一圖內一殼體容器的比較範例之圖式;第五圖為例示一樣本在第四圖內該殼體容器內凝固之圖式;第六圖為例示第一圖內該殼體容器的第一具體實施例之圖式;第七圖為例示一樣本在第六圖內該殼體容器內凝固之圖式;第八圖為例示第一圖內該殼體容器的第二具體實施例之圖 式;第九圖為例示一樣本在第八圖內該殼體容器內凝固之圖式;第十圖和第十一圖為顯示透過該第一溫度感測器測量的該熔融金屬之溫度比較結果圖示;第十二圖和第十三圖為顯示透過成分分析與凝固溫度所評估的該熔融金屬內碳含量之圖式;以及第十四圖和第十五圖為顯示根據鋼接收注入口直徑的一樣本狀態之圖式。 The accompanying drawings are included to further understand the present invention, and are incorporated in and constitute a part of this specification. The drawings illustrate exemplary embodiments of the present invention, and can be used to explain the principles of the present invention after the description of the contents. In the drawings: the first diagram is a cross-sectional view of a molten metal probe according to a specific embodiment of the present invention; the second diagram is an exploded perspective view of the molten metal probe in the first diagram; the third diagram is a first diagram cut away A perspective view of a part of the molten metal probe in the fourth figure; the fourth figure is a diagram illustrating a comparative example of a shell container in the first figure; the fifth figure is a sample illustrating the solidification of the sample in the shell container in the fourth figure The sixth diagram is a diagram illustrating the first specific embodiment of the shell container in the first diagram; the seventh diagram is a diagram illustrating the solidification of the shell in the shell container in the sixth diagram; the eighth The figure illustrates a second specific embodiment of the shell container in the first figure The ninth figure is an example of the solidification of the sample in the shell container in the eighth figure; the tenth and eleventh figures are comparisons showing the temperature of the molten metal measured through the first temperature sensor Result graphs; graphs twelve and thirteen are graphs showing the carbon content in the molten metal as assessed by composition analysis and solidification temperature; and graphs fourteen and fifteen are graphs showing Inlet diameter drawing of the same state.

此後將透過參照附圖說明的下列具體實施例,來闡明本發明的其他目的及其實施方法。 Hereinafter, other objects and methods of implementation of the present invention will be explained through the following specific embodiments described with reference to the drawings.

此後,將參照第一圖至第十五圖來詳細說明本發明的較佳具體實施例。不過,本發明可以不同形式具體實施,並且不受限於此處公佈的具體實施例。而是提供這些具體實施例,如此所揭示範圍更完整,並且將本發明範疇完整傳達給精通此技術的人士。如此在圖式中,為了清晰起見所以誇大了層與區域的尺寸。 Hereinafter, preferred embodiments of the present invention will be described in detail with reference to the first to fifteenth drawings. However, the present invention may be embodied in different forms and is not limited to the specific embodiments disclosed herein. Rather, these specific embodiments are provided so that the scope of the disclosure is more complete and the scope of the invention will be fully conveyed to those skilled in the art. Thus, in the drawings, the dimensions of layers and regions are exaggerated for clarity.

第一圖為根據本發明一具體實施例的熔融金屬探針之剖面圖;並且第二圖為第一圖中該熔融金屬探針的分解透視圖。第三圖為切開第一圖中該熔融金屬探針一部分的透視圖。 The first figure is a cross-sectional view of a molten metal probe according to a specific embodiment of the present invention; and the second figure is an exploded perspective view of the molten metal probe in the first figure. The third figure is a perspective view cut through a portion of the molten metal probe in the first figure.

如第一圖至第三圖所例示,一探針本體1包含一主分支管2。主分支管2允許熔融金屬,例如熔融鋼,透過主分支管2之側邊部分內定義的開口33a和33b,導入探針本體1。一外分支管4位於主分支管2的外側部分 上,以關閉開口33a和33b。探針本體1固定在一固定器h上,該固定器h連接至一升降裝置,像是一子吹管(sub lance),並浸入該熔融金屬,例如轉爐(converter)內的熔融鋼,然後抽出。在浸入時,外分支管4通過一爐渣層,並且當外分支管4到達一熔融金屬浴內時,外分支管4會消失。在此,開口33a和33b被開啟,以允許該熔融金屬導入探針本體1內。一連接器C允許探針本體1,尤其是稍後將說明的第一和第二溫度感測器22和24,以電性及機械性方式連接至該固定器h。 As illustrated in the first to third figures, a probe body 1 includes a main branch pipe 2. The main branch pipe 2 allows molten metal, such as molten steel, to be introduced into the probe body 1 through openings 33 a and 33 b defined in the side portions of the main branch pipe 2. An outer branch pipe 4 is located on the outer part of the main branch pipe 2 To close the openings 33a and 33b. The probe body 1 is fixed on a holder h, which is connected to a lifting device, such as a sub lance, and immersed in the molten metal, such as molten steel in a converter, and then withdrawn . During immersion, the outer branch pipe 4 passes through a slag layer, and when the outer branch pipe 4 reaches a molten metal bath, the outer branch pipe 4 disappears. Here, the openings 33 a and 33 b are opened to allow the molten metal to be introduced into the probe body 1. A connector C allows the probe body 1, particularly the first and second temperature sensors 22 and 24 to be described later, to be electrically and mechanically connected to the holder h.

一殼體容器107內建於主分支管2內。在殼體容器107內,定義一朝向開口33a打開之鋼接收注入口3a、從鋼接收注入口3a朝向與開口33a相對的方向延伸之一鋼接收流道9,並且從鋼接收流道9的方向切換為朝向一前端延伸之一鋼接收腔室10。另外在殼體容器107內,定義一朝向開口33b打開之一收集注入口3b、從收集注入口3b朝向與開口33b相對的方向延伸之一收集流道11,並且從收集流道11的方向切換為朝向該前端延伸之一收集腔室18。 A shell container 107 is built in the main branch pipe 2. In the shell container 107, a steel receiving injection port 3a opened toward the opening 33a, a steel receiving flow path 9 extending from the steel receiving injection port 3a toward the direction opposite to the opening 33a, and The direction is switched to a steel receiving chamber 10 extending toward a front end. In addition, in the housing container 107, one collection injection port 3b which is opened toward the opening 33b, and one collection flow path 11 which extends from the collection injection port 3b in a direction opposite to the opening 33b, and is switched from the direction of the collection flow path 11 A collection chamber 18 is one extending towards the front end.

在本說明書內,鋼接收腔室10與收集腔室18都可沿著殼體容器107的一縱向方向放置,彼此不重疊。當與鋼接收腔室10比較時,收集腔室18與殼體容器107的前端相鄰。類似地,當與鋼接收注入口3a和鋼接收流道9比較時,收集注入口3b和收集流道11與殼體容器的該前端相鄰。另外,鋼接收腔室10與收集腔室18都可沿著殼體容器107的一橫向方向放置,彼此不重疊。當與鋼接收腔室10比較時,收集腔室18與其中定義流入孔3a和3b的該探針本體之側表面相鄰。 In this specification, both the steel receiving chamber 10 and the collecting chamber 18 can be placed along a longitudinal direction of the housing container 107 without overlapping each other. When compared with the steel receiving chamber 10, the collection chamber 18 is adjacent to the front end of the housing container 107. Similarly, when compared with the steel receiving injection port 3a and the steel receiving flow path 9, the collecting injection port 3b and the collecting flow path 11 are adjacent to the front end of the housing container. In addition, both the steel receiving chamber 10 and the collecting chamber 18 can be placed along a lateral direction of the housing container 107 without overlapping each other. When compared with the steel receiving chamber 10, the collection chamber 18 is adjacent to the side surface of the probe body in which the inflow holes 3a and 3b are defined.

另外,一第一安裝空間14定義在鋼接收腔室10底下(請參閱 第一圖)。第一溫度感測器22的一本體部分22a(稍後將說明)位於第一安裝空間14內。一容納空間20與收集腔室18平行,並且開口朝向殼體容器107的前端。第二溫度感測器24的一本體部分24a容納在容納空間20內。 In addition, a first installation space 14 is defined under the steel receiving chamber 10 (see First picture). A body portion 22 a (to be described later) of the first temperature sensor 22 is located in the first installation space 14. An accommodating space 20 is parallel to the collection chamber 18, and the opening faces the front end of the housing container 107. A body portion 24 a of the second temperature sensor 24 is accommodated in the accommodation space 20.

如第二圖內所例示,殼體容器107可包含分割區塊107a和107b,沿著參考表面分區。分割區塊107a和107b可相對於該參考表面對稱,亦即該參考表面沿著殼體容器107的縱向方向,分割上述之鋼接收腔室10、收集腔室18、鋼接收流道9以及收集流道11。如第二圖內所例示,因為已分割的鋼接收腔室10、收集腔室18、鋼接收流道9和收集流道11中之每一者都為鋼接收腔室10、收集腔室18、鋼接收流道9和收集流道11中之每一者的一半,而分割區塊107a和107b之內鋼接收腔室10、收集腔室18、鋼接收流道9和收集流道11中之每一者都用新增參考符號H來代表。分割區塊107a和107b被插入一輔助分支管17內。第一和第二溫度感測器22和24以及一收集容器23都與殼體容器107組裝在一起,形成一熔融金屬探針的探針本體1。 As exemplified in the second figure, the shell container 107 may include divided blocks 107a and 107b, which are partitioned along the reference surface. The divided blocks 107a and 107b may be symmetrical with respect to the reference surface, that is, the reference surface is along the longitudinal direction of the shell container 107, and divides the steel receiving chamber 10, the collecting chamber 18, the steel receiving channel 9 and the collecting Runner 11. As illustrated in the second figure, because each of the divided steel receiving chamber 10, collection chamber 18, steel receiving runner 9 and collecting runner 11 is the steel receiving chamber 10, the collecting chamber 18 Half of each of the steel receiving runner 9 and the collecting runner 11, while the steel receiving chamber 10, the collecting chamber 18, the steel receiving runner 9 and the collecting runner 11 are within the divided blocks 107a and 107b. Each of them is represented by a newly added reference symbol H. The divided blocks 107a and 107b are inserted into an auxiliary branch pipe 17. The first and second temperature sensors 22 and 24 and a collection container 23 are assembled with the housing container 107 to form a probe body 1 of a molten metal probe.

在第一溫度感測器22內,一U形溫度測量管22b從本體部分22a延伸出來,並且一熱電耦位於溫度測量管22b內。一溫度測量部分22c位於溫度測量管22b的前端上,如此在其中溫度測量部分22c已經插入鋼接收腔室10的正確地點之狀態下,本體部分22a位於第一安裝空間14內。在本說明書中,連接至本體部分22a的一導線被連接至連接器C。 In the first temperature sensor 22, a U-shaped temperature measuring tube 22b extends from the body portion 22a, and a thermocouple is located in the temperature measuring tube 22b. A temperature measurement portion 22c is located on the front end of the temperature measurement tube 22b, so that the body portion 22a is located in the first installation space 14 in a state where the temperature measurement portion 22c has been inserted into the correct position of the steel receiving chamber 10. In this specification, a wire connected to the body portion 22a is connected to the connector C.

收集容器23為一扁平容器,用於收集來自該熔融金屬的碟形凝固樣本。收集容器23包含一金屬容器本體23a以及一導引管26,導引管26可由石英材料形成。金屬容器本體23a容納在收集腔室18內。 The collecting container 23 is a flat container for collecting a dish-shaped solidified sample from the molten metal. The collection container 23 includes a metal container body 23a and a guide tube 26. The guide tube 26 may be formed of a quartz material. The metal container body 23 a is contained in the collection chamber 18.

在第二溫度感測器24內,由一U形石英管形成的一溫度測量 管24b從本體部分24a延伸出來,並且一熱電耦位於溫度測量管24b內。一金屬蓋24c覆蓋溫度測量管24b。本體部分24a被插入容納空間20內,金屬蓋24c從殼體容器107的前端突出,連接至本體部分24a的一導線被連接至連接器C。 In the second temperature sensor 24, a temperature measurement formed by a U-shaped quartz tube The tube 24b extends from the body portion 24a, and a thermocouple is located in the temperature measuring tube 24b. A metal cover 24c covers the temperature measuring tube 24b. The body portion 24a is inserted into the accommodation space 20, the metal cover 24c protrudes from the front end of the case container 107, and a wire connected to the body portion 24a is connected to the connector C.

在鋼接收腔室10內裝入脫氧劑A。當用該升降裝置,例如子吹管,將探針本體1朝向該熔融金屬下降時,探針本體1通過該爐渣層並且浸入該熔融金屬浴內。如此,第二溫度感測器24的金屬蓋24c消失來測量該熔融金屬的溫度。另外,當外分支管4消失,並且開口3a和3b開啟時,該熔融金屬被導入探針本體1來朝向鋼接收腔室10以及收集腔室18移動。 The steel receiving chamber 10 is filled with a deoxidizing agent A. When the probe body 1 is lowered toward the molten metal with the lifting device, such as a sub-blow pipe, the probe body 1 passes through the slag layer and is immersed in the molten metal bath. In this way, the metal cover 24c of the second temperature sensor 24 disappears to measure the temperature of the molten metal. In addition, when the outer branch pipe 4 disappears and the openings 3 a and 3 b are opened, the molten metal is introduced into the probe body 1 to move toward the steel receiving chamber 10 and the collecting chamber 18.

導入鋼接收腔室10的該熔融金屬可透過裝入鋼接收腔室10內的脫氧劑A有效脫氧。該熔融金屬在填入鋼接收腔室10之後立刻凝固,並且逐漸固化。第一溫度感測器22的溫度測量部分22c幾乎位於鋼接收腔室10的中央部分上,也就是在具有優異熱平衡的位置上,來測量該熔融金屬的溫度,以穩固測量溫度值的平坦部分。 The molten metal introduced into the steel receiving chamber 10 can be effectively deoxidized by the deoxidizing agent A charged into the steel receiving chamber 10. This molten metal solidifies immediately after filling in the steel receiving chamber 10 and gradually solidifies. The temperature measurement portion 22c of the first temperature sensor 22 is located almost at the center portion of the steel receiving chamber 10, that is, at a position having excellent thermal balance, to measure the temperature of the molten metal to stabilize the flat portion of the temperature value .

當該熔融金屬被導入鋼接收腔室10時,利用該熔融金屬的導入溫度與該熔融金屬凝固時該熔融金屬的凝固溫度間之差異,來產生一峰值(或過度加熱度)。在本說明書內,由於可能產生凝固潛熱,所以其上該凝固溫度穩定的一凝固溫度平坦部分會維持一段預定時間。在該熔融金屬內存在一些碳,如此透過凝固溫度資料以及其上該熔融金屬的凝固溫度維持恆等值之該凝固溫度平坦部分,可評估該熔融金屬。利用該熔融金屬的凝固潛熱釋放之穩定度與時間,可影響該凝固溫度平坦部分。因此,該穩定度與時間可根據該熔融金屬的溫度與成份以及鋼接收腔室10的狀態與材料 而變。 When the molten metal is introduced into the steel receiving chamber 10, the difference between the introduction temperature of the molten metal and the solidification temperature of the molten metal when the molten metal is solidified is used to generate a peak (or degree of overheating). In this specification, since a latent heat of solidification may be generated, a solidified temperature flat portion on which the solidified temperature is stable is maintained for a predetermined time. There is some carbon in the molten metal, and thus the molten metal can be evaluated through the solidification temperature data and the flat part of the solidification temperature at which the solidification temperature of the molten metal maintains a constant value. The flatness of the solidification temperature can be affected by the stability and time of the latent heat release of the molten metal. Therefore, the stability and time can be based on the temperature and composition of the molten metal and the state and material of the steel receiving chamber 10 And change.

在現有熔融金屬探針的案例中,因為由於該熔融金屬的冷卻不均勻,因而在鋼接收腔室10之內發生局部相態轉換,則該凝固溫度平坦部分可傾斜,或凝固的開始時間可延遲,如此無法精準偵測該熔融金屬的凝固溫度。 In the case of the existing molten metal probe, because the molten metal is cooled unevenly, a local phase transition occurs within the steel receiving chamber 10, the flat portion of the solidification temperature may be inclined, or the start time of solidification may Delay, so it is impossible to accurately detect the solidification temperature of the molten metal.

尤其是,在吹送操作的稍後部分內,例如快速直接出鋼(QDT,quick direct tapping),由於高熔融鋼溫度,所以導入具有過熱程度的熔融鋼,如此延後產生該凝固溫度的平坦部分。如此,難以在測量時間之內精準評估碳含量,或由於發生凝固時間延遲造成熔融鋼冷卻不均勻,如此可平緩產生該凝固溫度平坦部分。也就是當該熔融金屬的過熱程度過高,則該熔融金屬的溫度逐漸下降,如此不會產生該凝固溫度平坦部分。如此,一控制單元透過計算邏輯,決定該凝固開始之前的錯誤溫度當成一凝固溫度。在此案例中,碳的估計值不高,導致測量誤差或測量精準度退化。如此,需要縮短該熔融金屬的凝固時間。 In particular, in the later part of the blowing operation, such as quick direct tapping (QDT), due to the high molten steel temperature, molten steel with a degree of overheating is introduced, so that a flat portion of the solidification temperature is generated after this delay . In this way, it is difficult to accurately evaluate the carbon content within the measurement time, or the cooling of the molten steel is uneven due to the delay of the solidification time, so that the flat part of the solidification temperature can be gently generated. That is, when the degree of overheating of the molten metal is too high, the temperature of the molten metal gradually decreases, so that the flat portion of the solidification temperature is not generated. In this way, a control unit determines the error temperature before the start of solidification as a solidification temperature through calculation logic. In this case, the estimated value of carbon is not high, leading to measurement errors or measurement accuracy degradation. In this way, it is necessary to shorten the solidification time of the molten metal.

當該熔融金屬被導入鋼接收腔室10時,則導入的熔融金屬利用傳導、對流與輻射,將熱能發出至外界。這用Chvorinov法則表示如下。 When the molten metal is introduced into the steel receiving chamber 10, the introduced molten metal emits thermal energy to the outside by conduction, convection, and radiation. This is expressed by Chvorinov's law as follows.

t ʃ=c(體積(V c )/表面積(A c ))2(t ʃ=凝固溫度,V c =體積,A c =表面積並且c=常數) t ʃ = c (volume ( V c ) / surface area ( A c )) 2 ( t ʃ = freezing temperature, V c = volume, A c = surface area and c = constant)

根據上面的等式,可縮短凝固時間的鋼接收腔室10之理想形狀為多邊柱形狀,像是矩形柱狀而非圓形形狀。當溫度測量部分22c位於鋼接收腔室10的中央部分內,則正六面體或圓柱體形狀就足以保證表面積,而不用是長方體形,如此可很容易均勻成核。 According to the above equation, the ideal shape of the steel receiving chamber 10 that can shorten the solidification time is a polygonal column shape, such as a rectangular column shape rather than a circular shape. When the temperature measurement portion 22c is located in the central portion of the steel receiving chamber 10, the shape of a regular hexahedron or a cylinder is sufficient to ensure the surface area, instead of a rectangular parallelepiped shape, so that it can easily nucleate uniformly.

不過,由於殼體容器107的內部空間限制,鋼接收腔室10的形狀會有所限制。另外,因為鋼接收腔室10的體積必須高於一預定尺寸,以確保該凝固溫度平坦部分,所以長方體形的鋼接收腔室10可對應為最佳設計。 However, the shape of the steel receiving chamber 10 may be limited due to the internal space limitation of the shell container 107. In addition, because the volume of the steel receiving chamber 10 must be higher than a predetermined size to ensure a flat part of the solidification temperature, the rectangular steel receiving chamber 10 can be designed optimally.

根據上面的等式,因為凝固時間與體積比(模數=體積/表面積)的平方成正比,所以該體積比必須降低來縮短該凝固時間。因此,必須提高該鋼接收腔室的表面積。尤其是,在縱向短表面上處理一波形或壓花圖案,其遠離該鋼接收腔室的溫度感測器22a之溫度測量部分22c,以加速熱的釋放,藉此縮短該凝固時間。因為鋼接收腔室10具有長方體形,所以鋼接收腔室10具有沿著其縱向方向定義的一縱向短表面以及一縱向長表面,加上與鋼接收流道9和第一安裝空間14相鄰的表面。填入鋼接收腔室10內的該熔融金屬可透過該縱向短表面與該縱向長表面釋出熱量,並因此凝固。在本說明書內,因為第一溫度感測器22的溫度測量部分22c位於鋼接收腔室10的該中央部分內,並且該縱向短表面的表面積小於該縱向長表面的表面積,並且與該縱向長表面比較時,遠離鋼接收腔室10的該中央部分,則與該縱向長表面比較時,該熔融金屬透過該縱向短表面釋出的熱量會延遲。如此,必須透過圖案處理來增加表面積。另外,鋼接收腔室10的體積縮小,將凝固樣本的尺寸縮小大約20%或以上。 According to the above equation, because the solidification time is proportional to the square of the volume ratio (modulus = volume / surface area), the volume ratio must be reduced to shorten the solidification time. Therefore, it is necessary to increase the surface area of the steel receiving chamber. In particular, a wavy or embossed pattern is processed on the longitudinal short surface away from the temperature measuring portion 22c of the temperature sensor 22a of the steel receiving chamber to accelerate the release of heat, thereby shortening the solidification time. Because the steel receiving chamber 10 has a rectangular parallelepiped shape, the steel receiving chamber 10 has a longitudinal short surface and a longitudinal long surface defined along its longitudinal direction, and is adjacent to the steel receiving runner 9 and the first installation space 14 s surface. The molten metal filled in the steel receiving chamber 10 can release heat through the longitudinal short surface and the longitudinal long surface, and thus solidify. In this specification, because the temperature measurement portion 22c of the first temperature sensor 22 is located in the central portion of the steel receiving chamber 10, and the surface area of the longitudinal short surface is smaller than that of the longitudinal long surface, and is longer than the longitudinal length When the surface is compared, the central portion far from the steel receiving chamber 10 is delayed when compared with the longitudinal long surface, the heat released by the molten metal through the longitudinal short surface. As such, the surface area must be increased by patterning. In addition, the volume of the steel receiving chamber 10 is reduced, reducing the size of the solidified sample by about 20% or more.

第四圖為例示第一圖中一殼體容器的比較範例之圖式,並且第五圖為例示在第四圖中該殼體容器內凝固的樣本之圖式。第六圖為例示第一圖中該殼體容器的第一具體實施例之圖式,並且第七圖為例示在第六圖中該殼體容器內凝固的樣本之圖式。第八圖為例示第一圖中該殼體容器 的第二具體實施例之圖式,並且第九圖為例示在第八圖中該殼體容器內凝固的樣本之圖式。 The fourth diagram is a diagram illustrating a comparative example of a shell container in the first diagram, and the fifth diagram is a diagram illustrating a sample solidified in the shell container in the fourth diagram. The sixth diagram is a diagram illustrating a first specific embodiment of the shell container in the first diagram, and the seventh diagram is a diagram illustrating a sample solidified in the shell container in the sixth diagram. The eighth figure is an illustration of the shell container in the first figure The second specific embodiment is a drawing, and the ninth drawing is a drawing illustrating a sample solidified in the shell container in the eighth drawing.

第五圖內例示的一樣本S1具有形狀大體上與第四圖中鋼接收腔室10之形狀一致。兩側表面f1和f1都對應至位於彼此面對的一參考表面兩側上之內表面。第七圖內例示的一樣本S2具有形狀大體上與第六圖中鋼接收腔室10之形狀一致。兩側表面f2和f2都對應至位於彼此面對的一參考表面兩側上之內表面。亦即,因為第六圖的鋼接收腔室10在其內表面上具有不平整的波形圖案10a,因此該樣本S2具有不平整的波形圖案p2。第九圖內例示的一樣本S3具有形狀大體上與第八圖中鋼接收腔室10之形狀一致。兩側表面f3和f3都對應至位於彼此面對的一參考表面兩側上之內表面。亦即,因為第八圖的鋼接收腔室10在其內表面上具有圓形突出物10a,因此該樣本S3具有一圓形凹陷圖案p3。 The sample S1 illustrated in the fifth figure has a shape substantially consistent with the shape of the steel receiving chamber 10 in the fourth figure. Both side surfaces f1 and f1 correspond to inner surfaces on both sides of a reference surface facing each other. The sample S2 illustrated in the seventh figure has a shape substantially identical to that of the steel receiving chamber 10 in the sixth figure. Both side surfaces f2 and f2 correspond to inner surfaces on both sides of a reference surface facing each other. That is, because the steel receiving chamber 10 of the sixth figure has an uneven wave pattern 10a on its inner surface, the sample S2 has an uneven wave pattern p2. The sample S3 illustrated in the ninth figure has a shape substantially consistent with the shape of the steel receiving chamber 10 in the eighth figure. Both side surfaces f3 and f3 correspond to inner surfaces on both sides of a reference surface facing each other. That is, because the steel receiving chamber 10 of the eighth figure has a circular protrusion 10a on its inner surface, the sample S3 has a circular depression pattern p3.

第四圖至第九圖的該鋼接收腔室彙總顯示於底下的表格1內。 The steel receiving chambers of the fourth to ninth figures are summarized in Table 1 below.

請參閱上面表格1,當該模數4至4.5時,波形穩定性以及成份評估精確度都非常優異。當該模數小於4.0時,可發現在此範圍內可迅速冷卻,難以確保該凝固溫度平坦部分。當該模數高於4.5時,可發現由於延 遲冷卻而產生局部相態平衡情況,如此降低測量值的可靠度。 Please refer to Table 1 above. When the modulus is 4 to 4.5, the waveform stability and component evaluation accuracy are very good. When the modulus is less than 4.0, it can be found that rapid cooling can be performed within this range, and it is difficult to secure the flat portion of the solidification temperature. When the modulus is higher than 4.5, it can be found that Late cooling results in a local phase equilibrium situation, which reduces the reliability of the measured values.

雖然在第六圖與第八圖內已例示該不平整波形圖案以及不平整凹陷圖案,不過本發明的具體實施例將不受限於該等不平整圖案。例如:該波形圖案以及該凹陷圖案可彼此結合,可形成其他形狀的不平整圖案。 Although the uneven wave pattern and the uneven depression pattern have been exemplified in the sixth and eighth figures, the specific embodiments of the present invention are not limited to such uneven patterns. For example, the wavy pattern and the recessed pattern can be combined with each other to form uneven shapes in other shapes.

第十圖和第十一圖為顯示透過該第一溫度感測器測量的該熔融金屬之溫度比較結果圖示。第十圖和第十一圖每一者的綠色線都代表該熔融金屬的溫度,當該熔融金屬已經導入鋼接收腔室10時,該熔融金屬在其中透過第一溫度感測器22所測量的一波形因為該熔融金屬具有高溫而持續增加之狀態中開始凝固,然後建立該相態平均來代表凝固溫度。在第十圖的比較範例中,因為發生局部相態平衡情況,所以凝固溫度傾斜。不過在第十一圖的具體實施例2內,顯示其中測量波形在相對水平狀態下之凝固溫度。 The tenth graph and the eleventh graph are graphs showing the comparison result of the temperature of the molten metal measured by the first temperature sensor. The green line of each of the tenth and eleventh figures represents the temperature of the molten metal. When the molten metal has been introduced into the steel receiving chamber 10, the molten metal is measured through the first temperature sensor 22 therein. A wave form of the solid state begins to solidify in a state where the molten metal has a high temperature, and then the phase average is established to represent the solidification temperature. In the comparative example of the tenth figure, the solidification temperature is inclined because a local phase equilibrium occurs. However, in the specific embodiment 2 of the eleventh figure, the solidification temperature of the measured waveform in a relatively horizontal state is shown.

第十二圖和第十三圖為顯示透過成分分析與凝固溫度所評估的該熔融金屬內碳含量之圖式。在第十二圖和第十三圖的圖形中,水平軸代表依照碳分析(CA,carbon analysis)的已收集樣本之值,並且垂直軸代表估計的碳值。在第十二圖的比較範例中,可看見該碳含量偏離代表自藍色實線(當水平軸之值與垂直軸之值一致時)之一預定範圍(±0.06%)之紅色虛線。在另一方面,在第十三圖的具體實施例2內,可看見一穩定結果,其中該碳含量位於從該藍色實線的一預定範圍(±0.06%)內。 The twelfth and thirteenth graphs are graphs showing the carbon content in the molten metal as evaluated by the analysis of the composition and the solidification temperature. In the graphs of the twelfth and thirteenth graphs, the horizontal axis represents values of collected samples according to a carbon analysis (CA), and the vertical axis represents estimated carbon values. In the comparative example of Fig. 12, it can be seen that the carbon content deviates from the red dashed line representing a predetermined range (± 0.06%) from the solid blue line (when the value of the horizontal axis coincides with the value of the vertical axis). On the other hand, in the specific example 2 of the thirteenth figure, a stable result can be seen, wherein the carbon content lies within a predetermined range (± 0.06%) from the solid blue line.

雖然該熔融金屬已透過鋼接收注入口9導入鋼接收腔室10,不過當鋼接收注入口9具有相對較大角度時,發生其中該熔融金屬與鋼接收 注入口9的轉角部分碰撞之渦流現象,而形成亂流。如此空氣與氣體會混合在一起,因此鋼接收注入口9的轉角部分9r可具有圓弧形狀,避免發生渦流現象。 Although the molten metal has been introduced into the steel receiving chamber 10 through the steel receiving injection port 9, when the steel receiving injection port 9 has a relatively large angle, it occurs in which the molten metal and the steel receiving Note that the corner of the inlet 9 collides with the vortex phenomenon and forms a turbulent flow. In this way, air and gas are mixed together, so the corner portion 9r of the steel receiving injection port 9 can have a circular arc shape to avoid the occurrence of eddy currents.

另外如第六圖內所例示,雖然鋼接收腔室10與收集腔室18沿著殼體容器107的縱向方向放置而彼此未重疊,收集流道11可沿著殼體容器107的縱向方向與鋼接收腔室10重疊。如此,移動通過收集流道11的該熔融金屬之高溫熱量會影響位於鋼接收腔室10內第一溫度感測器22之溫度測量部分22c,如此無法精確測量該凝固溫度。因此,沿著殼體容器107的縱向方向重疊鋼接收腔室10之收集注入口11的轉角部分可處理成圓弧形,增加鋼接收腔室10與收集腔室18之間往遠離收集腔室18方向之分割壁厚度。透過如此,可將其中該熔融金屬流過收集流道11影響溫度測量部分22c之高溫熱量降至最低。另外,當收集流道11的該轉角部分為圓弧形,則導入該熔融金屬所發生的渦流現象可降至最低。 In addition, as illustrated in the sixth figure, although the steel receiving chamber 10 and the collecting chamber 18 are placed along the longitudinal direction of the housing container 107 without overlapping each other, the collecting flow channel 11 may be along the longitudinal direction of the housing container 107 and The steel receiving chambers 10 overlap. In this way, the high-temperature heat of the molten metal moving through the collecting channel 11 will affect the temperature measurement portion 22c of the first temperature sensor 22 located in the steel receiving chamber 10, so that the solidification temperature cannot be accurately measured. Therefore, the corner portion of the collection injection port 11 overlapping the steel receiving chamber 10 along the longitudinal direction of the shell container 107 can be processed into a circular arc shape, increasing the distance between the steel receiving chamber 10 and the collecting chamber 18 away from the collecting chamber. Partition wall thickness in 18 directions. By doing so, the high-temperature heat in which the molten metal flows through the collection flow channel 11 to affect the temperature measurement portion 22c can be minimized. In addition, when the corner portion of the collecting flow channel 11 is arc-shaped, the eddy current phenomenon caused by introducing the molten metal can be minimized.

另外為了擴展上述熔融金屬探針的可用範圍(也就是該熔融金屬的凝固溫度之測量範圍),即使導入具有低過熱程度的熔融金屬,還是可有效測量該凝固溫度。如此,可迅速導入該熔融金屬,讓其溫度下降減至最少,如此該熔融金屬到達鋼接收腔室10的溫度與該熔融金屬在該轉爐內之溫度大約相同。 In addition, in order to expand the usable range of the above-mentioned molten metal probe (that is, the measurement range of the solidification temperature of the molten metal), the solidification temperature can be effectively measured even if a molten metal having a low degree of superheat is introduced. In this way, the molten metal can be quickly introduced to minimize its temperature drop, so that the temperature at which the molten metal reaches the steel receiving chamber 10 is about the same as the temperature of the molten metal in the converter.

如此,需要將鋼接收注入口3a(及/或開口33a)的直徑(請參閱第四圖的參考符號d)最佳化。根據實驗結果,當鋼接收注入口3a的直徑大約為20mm至25mm,該熔融金屬具有良好的充滿效能(filling performance)。當鋼接收注入口3a的直徑大約20mm或以下時,該熔融金屬會在有效填入鋼 接收腔室10之前開始凝固,如此降低充滿效能。當鋼接收注入口3a的直徑大約25mm或以上時,填入鋼接收腔室10的該熔融金屬會回流,如此降低充滿效能。第十四圖和第十五圖為顯示根據鋼接收注入口直徑的一樣本狀態之圖式。第十四圖的鋼接收注入口直徑大約為17mm,並且第十五圖的鋼接收注入口直徑大約是24.5mm。 In this way, it is necessary to optimize the diameter of the steel receiving injection port 3a (and / or the opening 33a) (see reference symbol d in the fourth figure). According to the experimental results, when the diameter of the steel receiving injection port 3a is approximately 20 mm to 25 mm, the molten metal has a good filling performance. When the diameter of the steel receiving injection port 3a is about 20 mm or less, the molten metal will effectively fill the steel The receiving chamber 10 starts to solidify before, thus reducing the filling efficiency. When the diameter of the steel receiving injection port 3a is about 25 mm or more, the molten metal filled in the steel receiving chamber 10 will flow back, thus reducing the filling efficiency. The fourteenth and fifteenth drawings are diagrams showing a sample state according to the diameter of a steel receiving inlet. The diameter of the steel receiving injection port of FIG. 14 is about 17 mm, and the diameter of the steel receiving injection port of FIG. 15 is about 24.5 mm.

另外,鋼接收腔室10和收集腔室18可具有已分割的(或相隔的)鋼接收注入口3a和收集注入口3b,分別用於接收相對較大的鐵靜壓。這可達成,因為若鋼接收注入口3a和收集注入口3b彼此整合,而該熔融金屬分開流入鋼接收腔室10與該收集腔室,則會發生形成渦流的渦流現象而形成亂流,如此無法輕鬆導入該熔融金屬。尤其是,鋼接收流道9可從流入孔3a往遠離第一溫度感測器22的方向傾斜。在本說明書中,殼體容器107的橫斷面與鋼接收流道9間之傾斜角度θ可為大約20°至大約60°。當該傾斜角度θ為大約20°或以下時,鋼接收注入口3a遠離該熔融金屬探針的前端,如此非常有可能導入爐渣。當該傾斜角度θ大約是60°或以上時,會因為較大的傾斜角度,造成該熔融金屬的充滿效能降低。 In addition, the steel receiving chamber 10 and the collecting chamber 18 may have a divided (or separated) steel receiving injection port 3a and a collecting injection port 3b for receiving a relatively large iron static pressure, respectively. This can be achieved because if the steel receiving injection port 3a and the collecting injection port 3b are integrated with each other, and the molten metal flows into the steel receiving chamber 10 and the collecting chamber separately, a vortex phenomenon that forms a vortex occurs and a turbulent flow is formed. This molten metal cannot be easily imported. In particular, the steel receiving flow path 9 may be inclined from the inflow hole 3 a in a direction away from the first temperature sensor 22. In this specification, the inclination angle θ between the cross section of the housing container 107 and the steel receiving flow path 9 may be about 20 ° to about 60 °. When the inclination angle θ is about 20 ° or less, the steel receiving injection port 3 a is far away from the front end of the molten metal probe, so it is very likely to introduce slag. When the inclination angle θ is about 60 ° or more, the charging efficiency of the molten metal decreases due to the large inclination angle.

另外,鋼接收注入口3a和收集注入口3b可放置在距離該熔融金屬探針前端大約200mm之處。亦即,從該熔融金屬探針前端到鋼接收注入口3a的距離D大約是200mm。當該熔融金屬探針的浸入深度設定在大約500mm至大約600mm時,這樣可確保樣本健全度(sample soundness)以及充滿效能。 In addition, the steel receiving injection port 3a and the collecting injection port 3b may be placed approximately 200 mm from the front end of the molten metal probe. That is, the distance D from the front end of the molten metal probe to the steel receiving injection port 3a is about 200 mm. When the immersion depth of the molten metal probe is set to about 500 mm to about 600 mm, this can ensure sample soundness and full efficiency.

朝向收集腔室18移動的該熔融金屬會在收集容器23內凝固,如此當成凝固樣本用於分析,像是儀器分析。當從該熔融金屬浴抽出 而撞擊到探針本體1時,殼體容器107會由於撞擊而摧毀,並且收集腔室18會破裂,如此可輕易分離收集容器23。然後,利用輸送裝置輸送收集容器23,並提供用於分析,例如儀器分析。 The molten metal moving toward the collection chamber 18 will solidify in the collection container 23 and thus be used as a solidified sample for analysis, such as instrumental analysis. When drawn from the molten metal bath When the probe body 1 is impacted, the housing container 107 is destroyed due to the impact, and the collection chamber 18 is broken, so that the collection container 23 can be easily separated. The collection container 23 is then transported using a transport device and provided for analysis, such as instrumental analysis.

根據本發明的具體實施例,可提高該熔融金屬的冷卻率,以縮短該熔融金屬的凝固時間。如此,可精準估計具有過熱程度的該熔融金屬內之碳含量。例外,該熔融金屬可順暢導入該探針本體內。 According to a specific embodiment of the present invention, the cooling rate of the molten metal can be increased to shorten the solidification time of the molten metal. In this way, the carbon content in the molten metal with a degree of overheating can be accurately estimated. Exceptionally, the molten metal can be smoothly introduced into the probe body.

上述相關主題僅為說明並不設限,並且申請專利範圍意欲涵蓋位於本發明精神與範疇內的所有這種修改、增強以及其他具體實施例。如此,為了有最大的法律適用範圍,本發明範疇由下列申請專利範圍及其附屬項的最寬鬆允許解釋來決定,並且不受前面詳細說明所侷限或限制。 The above related subject matter is merely illustrative and not restrictive, and the scope of patent application is intended to cover all such modifications, enhancements, and other specific embodiments within the spirit and scope of the present invention. In this way, in order to have the maximum scope of legal application, the scope of the present invention is determined by the most permissive interpretation of the scope of the following patent applications and its appended items, and is not limited or restricted by the foregoing detailed description.

Claims (10)

一種用於複合探針的殼體容器,其浸入熔融金屬內允許該熔融金屬導入其中,該殼體容器包含:一流入孔,其定義在該殼體容器之側表面內,以允許該熔融金屬導入其中;一接收腔室以及一收集腔室,其中該熔融金屬透過該流入孔導入而充滿其中;一接收流道,其將該流入孔連接至該接收腔室;以及一收集流道,其將該流入孔連接至該收集腔室,其中該殼體容器另包含一第一溫度感測器,其包含位於該接收腔室內的一溫度測量部分,以及一不平整圖案形成於該接收腔室的一內表面上;其中,該接收腔室具有一長方體形,該接收腔室並具有沿著一縱向方向所定義的一縱向短表面與一縱向長表面,該縱向短表面與該縱向長表面比較時係遠離該接收腔室的一中央部分,該圖案係形成於該接收腔室之該內表面之一縱向短表面上,該接收腔室具有其中體積除以表面積為大約4至大約4.5之體積比,以產生一凝固溫度平坦部分。 A housing container for a composite probe, which is immersed in a molten metal to allow the molten metal to be introduced therein. The housing container includes: an inflow hole defined in a side surface of the housing container to allow the molten metal Introduced into it; a receiving chamber and a collecting chamber, wherein the molten metal is introduced through the inflow hole to fill it; a receiving flow channel connecting the inflow hole to the receiving chamber; and a collecting flow channel, which The inflow hole is connected to the collection chamber, wherein the housing container further includes a first temperature sensor including a temperature measuring portion located in the receiving chamber, and an uneven pattern is formed in the receiving chamber. An inner surface of the receiving chamber; wherein the receiving chamber has a rectangular parallelepiped shape, and the receiving chamber has a longitudinal short surface and a longitudinal long surface defined along a longitudinal direction, the longitudinal short surface and the longitudinal long surface In comparison, a central portion away from the receiving chamber is formed on the longitudinal short surface of the inner surface of the receiving chamber. The receiving chamber has a volume divided by Surface area to volume ratio of from about 4 to about 4.5, the solidification temperature to produce a flat portion. 如申請專利範圍第1項之殼體容器,其中該收集腔室沿著該殼體容器的一縱向方向放置,以及該收集流道具有形狀為圓弧形的一轉角部分。 For example, the shell container of the scope of patent application, wherein the collection chamber is placed along a longitudinal direction of the shell container, and the collecting flow channel has a corner portion having a circular arc shape. 如申請專利範圍第1項之殼體容器,其中該接收流道從該流入孔往遠離該第一溫度感測器的方向傾斜,以及 該殼體容器的橫斷面與該接收流道間之傾斜角度為大約20°至大約60°。 For example, the shell container of the scope of patent application, wherein the receiving flow channel is inclined from the inflow hole in a direction away from the first temperature sensor, and The inclination angle between the cross-section of the housing container and the receiving runner is about 20 ° to about 60 °. 如申請專利範圍第1項之殼體容器,其中該流入孔包含:一接收注入口,其設置成與該接收腔室連通;以及一收集注入口,其設置成與該收集腔室連通,其中該接收注入口和該收集注入口彼此分隔。 For example, the shell container of the scope of patent application, wherein the inflow hole includes: a receiving injection port, which is arranged to communicate with the receiving chamber; and a collecting injection port, which is arranged to communicate with the collecting chamber, wherein The receiving injection port and the collecting injection port are separated from each other. 如申請專利範圍第4項之殼體容器,其中該接收注入口具有一直徑大約20mm至大約25mm。 For example, the shell container of the scope of patent application No. 4, wherein the receiving injection port has a diameter of about 20 mm to about 25 mm. 如申請專利範圍第4項之殼體容器,其中該殼體容器另包含一第二溫度感測器,其位於該殼體容器的一前端上,以測量該熔融金屬的溫度。 For example, the shell container of the patent application No. 4 wherein the shell container further includes a second temperature sensor located on a front end of the shell container to measure the temperature of the molten metal. 如申請專利範圍第5或6項之殼體容器,其中該收集腔室與該接收腔室都沿著該殼體容器的一縱向和橫向方向放置,彼此不重疊。 For example, the shell container of the fifth or sixth aspect of the patent application, wherein the collection chamber and the receiving chamber are both placed along a longitudinal and lateral direction of the shell container, and do not overlap each other. 如申請專利範圍第1項之殼體容器,其中該殼體容器另包含一第二溫度感測器,其位於該殼體容器的一前端上,以測量該熔融金屬的溫度,以及該流入孔定義在距離該殼體容器前端往該殼體容器縱向方向大約200mm之處。 For example, the shell container of the scope of patent application, wherein the shell container further includes a second temperature sensor located on a front end of the shell container to measure the temperature of the molten metal and the inflow hole. It is defined at a distance of about 200 mm from the front end of the shell container toward the longitudinal direction of the shell container. 一種複合探針,包含:一主分支管,其設置成在該主分支管已浸入熔融金屬的狀態下,允許該熔融金屬透過該主分支管之側邊部分內定義的一開口導入該複合探針;一外分支管,其位於該主分支管的外側部分上,以關閉該開口; 一殼體容器,其內建於該主分支管內;第一和第二溫度感測器,其位於該殼體容器上;以及一連接器,其電性連接至該第一溫度感測器和第二溫度感測器中之每一者,其中該殼體容器包含:一流入孔,其定義在該殼體容器之側表面內,與該開口連通來允許該熔融金屬導入其中;一接收腔室以及一收集腔室,其中該熔融金屬透過該流入孔導入其中而充滿其中;一接收流道,其將該流入孔連接至該接收腔室;以及一收集流道,其將該流入孔連接至該收集腔室,其中該第一溫度感測器的一溫度測量部分位於該接收腔室內,以及該第二溫度感測器位於該殼體容器的一前端上,一不平整圖案形成於該接收腔室的一內壁上,其中,該接收腔室具有一長方體形,該接收腔室並具有沿著一縱向方向所定義的一縱向短表面與一縱向長表面,該縱向短表面與該縱向長表面比較時係遠離該接收腔室的一中央部分,該圖案係形成於該接收腔室之該內表面之一縱向短表面上,該接收腔室具有其中體積除以表面積為大約4至大約4.5之體積比,以產生一凝固溫度平坦部分。 A composite probe includes: a main branch tube arranged to allow the molten metal to be introduced into the composite probe through an opening defined in a side portion of the main branch tube in a state where the main branch tube has been immersed in the molten metal. A needle; an outer branch tube located on an outer portion of the main branch tube to close the opening; A housing container built into the main branch pipe; first and second temperature sensors located on the housing container; and a connector electrically connected to the first temperature sensor And a second temperature sensor, wherein the housing container includes: an inflow hole defined in a side surface of the housing container, communicating with the opening to allow the molten metal to be introduced thereinto; a receiving A chamber and a collection chamber, wherein the molten metal is introduced thereinto through the inflow hole and filled therein; a receiving flow channel connecting the inflow hole to the receiving chamber; and a collection flow channel which connects the inflow hole Connected to the collection chamber, wherein a temperature measuring part of the first temperature sensor is located in the receiving chamber, and the second temperature sensor is located on a front end of the housing container, an uneven pattern is formed on On an inner wall of the receiving chamber, wherein the receiving chamber has a rectangular parallelepiped shape, the receiving chamber has a longitudinal short surface and a longitudinal long surface defined along a longitudinal direction, and the longitudinal short surface and The longitudinal table In comparison, a central portion away from the receiving chamber, the pattern is formed on a longitudinal short surface of the inner surface of the receiving chamber, the receiving chamber having a volume divided by a surface area of about 4 to about 4.5 The volume ratio to produce a flat portion at a solidification temperature. 如申請專利範圍第9項之複合探針,其中該收集腔室沿著該殼體容器的一縱向方向放置,以及該收集流道具有形狀為圓弧形的一轉角部分。 For example, the composite probe according to item 9 of the application, wherein the collection chamber is placed along a longitudinal direction of the housing container, and the collection flow channel has a corner portion having a circular arc shape.
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