TWI615373B - Glass sheet having a high transmission in the infrared - Google Patents

Abstract

The invention relates to a glass sheet with high infrared transmittance, which can be especially used in a touch screen, a touch panel or a touch panel. More specifically, the present invention relates to a glass sheet having a composition comprising the following, the amount of which is expressed as a percentage of the total weight of the glass: And the selenium content (expressed as Se) in the range of 0.001% to 1%.

Description

Glass with high infrared transmittance

The present invention relates to a glass sheet having a high infrared transmittance. The general technical field of the invention is an optical touch panel placed over a surface area of a display.

In particular, the glass sheet according to the present invention can be advantageously used in a touch screen, a touch panel or a touch panel by virtue of high infrared (IR) transmittance, the touch screen, the touch panel or the touch panel. Using an optical technique called Planar Scattering Detection (PSD) or even Frustrated Total Internal Reflection (FTIR) (or any other technique that requires high infrared transmittance) to detect one or more of the surface of the sheet The location of an object, such as a finger or stylus.

The invention therefore also relates to a touch screen, touch panel or trackpad comprising such a glass sheet.

PSD and FTIR technologies allow for a multi-touch touchscreen/panel that is inexpensive and can have a relatively large touch surface (for example, 3 to 100 inches in size) and a small thickness.

The two techniques include: (i) emitting infrared (IR) line radiation from one or more edge/edge faces (eg, using LEDs) into a substrate that is transparent in the infrared; (ii) by means of total internal reflection optical effects (no radiation "escapes" the substrate), infrared radiation propagates inside the substrate (which then acts as a waveguide); (iii) causes the surface of the substrate to contact a certain type of object (such as a finger or stylus), thereby Local interference is produced by the scattering of radiation in all directions; some off-radiation will thus be able to "escape" the substrate.

In FTIR technology, the off-radiation forms an infrared spot on the lower surface of the substrate (i.e., on the surface opposite the touch surface). These offset rays are detected by a special camera located behind the device.

As for the PSD technique, it comprises two additional steps after steps (i) to (iii): (iv) analyzing the resulting infrared radiation at the edge of the substrate using a detector; and (v) calculating from the detected radiation The method calculates the position of the object in contact with the surface. This technique is described inter alia in document US 2013/021300 A1.

Basically, glass is a material of choice for touch panels due to its mechanical properties, durability, scratch resistance, optical clarity, and because it can be chemically or thermally toughened.

For glass panels used in PSD or FTIR technology and having a very large area and therefore a relatively large length/width, the optical path of the emitted infrared radiation is longer. In this case, the absorption of infrared radiation through the glass material thus has a significant effect on the sensitivity of the touch panel, which can then unduly reduce the length/width of the panel. For glass panels used in PSD or FTIR technology and having a smaller area and thus the emitted infrared radiation has a shorter optical path, the absorption of infrared radiation through the glass material also has an effect, especially for devices incorporating glass panels. Consumption.

Therefore, a glass sheet which is extremely transparent in infrared rays is extremely suitable for this case, so as to ensure that the entire touch surface has no drop or satisfactory sensitivity when the area of the surface is large. In particular, glass sheets having an absorption coefficient equal to or even less than 1 m ^-1 at a wavelength of 1050 nm, which is commonly used in such techniques, are desirable.

In order to obtain high penetration in the infrared (and in visible light), it is known to reduce the total amount of iron in the glass (in terms of Fe ₂ O ₃ , according to standard practice in the field) and thus to obtain a low iron content Glass (or "low iron" glass). Tellurite glass always contains iron because the latter exists as an impurity in most of the batch materials used (sand, limestone, dolomite, etc.). Iron exists in the structure of the glass in the form of ferric ion Fe ³⁺ and divalent iron ion Fe ²⁺ . The presence of the ferric iron ion Fe ³⁺ causes weak absorption of the glass at shorter wavelengths in visible light and strong absorption in the near ultraviolet (the absorption band is centered at 380 nm), while the divalent iron ion Fe ²⁺ (sometimes expressed The presence of FeO oxide) causes strong absorption in the near infrared rays (the absorption band is centered at 1050 nm). Therefore, increasing the total amount of iron (in the form of iron formed by both of them) enhances absorption in visible light and infrared rays. In addition, the high concentration of the divalent iron ion Fe ²⁺ reduces the penetration rate in the infrared rays (especially in the near infrared rays). However, in order to obtain a sufficiently low absorption coefficient at a wavelength of 1050 nm for a touch application by merely changing the total amount of iron, a large reduction in the total amount of iron will be required, and thus (i) it will lead to production. The cost is too high because of the need for very pure batch materials (in some cases even no material of sufficient purity), and (ii) it will cause production problems (especially premature wear of the furnace and/or in the furnace) Difficult to heat the glass).

In order to further increase the transmittance of glass, it is also known to oxidize iron present in glass, that is, to reduce the amount of divalent iron ions to increase ferric ions. The degree of oxidation of the glass redox ratio specified, is defined as the weight of Fe ²⁺ atoms with respect to the total weight of iron atoms present in the glass in the ratio, i.e., Fe ²⁺ / total Fe.

In order to reduce the redox ratio of the glass, it is known to add an oxidizing agent to the blend of batch materials. However, most of the known oxidants (sulfates, nitrates, etc.) do not have sufficient oxidizing power to obtain the infrared transmittance values sought in touch panel applications utilizing FTIR or PSD techniques.

One object of the present invention, in at least one embodiment thereof, is to provide a glass sheet having high infrared transmittance. In particular, it is an object of the present invention to provide a glass sheet having a high near infrared transmittance.

Another object of the present invention is, in at least one embodiment thereof, to provide a glass sheet, When used as a touch surface in a large-area touch screen, touch panel or touch panel, the sensitivity of the touch function is hardly reduced or not reduced at all.

Another object of the present invention, in at least one embodiment thereof, is to provide a glass sheet that consumes energy for the device when used as a touch surface in a more appropriately sized touch screen, touch panel or trackpad. Has a beneficial effect.

Another object of the present invention, in at least one embodiment thereof, is to provide a glass sheet having high infrared transmittance and having an appearance acceptable for the selected application.

Finally, another object of the present invention is to provide a glass sheet having a high infrared transmittance and which is inexpensive to produce.

根據一個特定實施例，該組成另外包含相對於玻璃之總重量，按重量計在0.001%至1%範圍內之硒含量(以Se形式表示)。 The present invention relates to a glass sheet having a composition comprising the following, the amount of which is expressed as a percentage of the total weight of the glass:

According to a particular embodiment, the composition additionally comprises a selenium content (expressed as Se) in the range of 0.001% to 1% by weight relative to the total weight of the glass.

Accordingly, the present invention is based on a completely novel and inventive method as it solves the technical problems. In particular, the inventor has surprisingly proved that By combining a low content of iron in the glass composition with selenium in a specific content range (especially referred to as a strong colorant in the so-called "selective" colored glass composition) to obtain a very transparent in infrared light and the appearance and color are not A piece of glass that is subject to too many negative effects.

Throughout this article, when a range is specified, its limits are included. In addition, individual and every integer value and sub-interval within the numerical range are explicitly included as if explicitly stated. Moreover, throughout this document, the percentages or amounts are by weight relative to the total weight of the glass.

Other features and advantages of the present invention will become more apparent upon reading the following embodiments.

According to the invention, the term "glass" is understood to mean a completely amorphous material, thus excluding any crystalline material, even partially crystalline material (such as, for example, glass crystal or glass ceramic material).

The glass piece according to the present invention can be made of glass belonging to various categories. The glass may thus be soda lime bismuth glass, aluminosilicate glass, borosilicate glass or the like. Preferably, and for reasons of reduced production costs, the glass sheet according to the invention is a sheet of soda lime glass. In the preferred embodiment, the composition of the glass sheet may comprise the following items, the amount of which is expressed as a percentage of the total weight of the glass:

The glass piece according to the present invention may be processed by a float process, a draw process or a roll process Or any other known glass sheet obtained for the process of making a glass sheet from a molten glass composition. According to a preferred embodiment of the invention, the glass sheet is a float glass sheet. The expression "float glass sheet" is understood to mean a glass sheet formed by a float process which comprises pouring molten glass onto a molten tin bath under reducing conditions. It is well known that a float glass sheet has a so-called "tin side", i.e., a glass region on the side that is close to the surface of the sheet is rich in tin. The expression "rich in tin" is understood to mean an increase in the tin concentration relative to the composition of the glass core, which may be substantially zero (without tin) or not zero.

The glass sheets according to the present invention can be of various sizes and relatively large. For example, it may have a range of up to 3.21 m x 6 m or 3.21 m x 5.50 m or 3.21 m x 5.10 m or 3.21 m x 4.50 m ("PLF" glass flakes) or even for example 3.21 m x 2.55 m or 3.21 m x 2.25 m ( The size of the "DLF" glass piece).

The thickness of the glass sheet according to the invention may be between 0.1 mm and 25 mm. Advantageously, in the case of touch panel applications, the thickness of the glass sheet according to the invention may be between 0.1 mm and 6 mm. Preferably, for touch screen applications, the thickness of the glass sheet according to the present invention will be from 0.1 mm to 2.2 mm for weight reasons.

According to the invention, the composition of the invention comprises the total amount of iron (in terms of Fe ₂ O ₃ ) in the range from 0.002% to 0.06% by weight, relative to the total weight of the glass. The total amount of iron (expressed as Fe ₂ O ₃ ) of less than or equal to 0.06% by weight causes the infrared transmittance of the glass sheet to be further increased. The minimum ensures that the cost of the glass does not increase much, as such low iron values often require very pure and expensive batch materials or purification of the batch materials. Preferably, the composition comprises the total amount of iron (expressed as Fe ₂ O ₃ ) in the range of 0.002% to 0.04% by weight relative to the total weight of the glass. Most preferably, the composition comprises the total amount of iron (expressed as Fe ₂ O ₃ ) in the range of 0.002% to 0.02% by weight relative to the total weight of the glass.

According to one embodiment of the invention, the composition of the invention comprises a selenium content (expressed as Se) in the range of 0.005% to 1% by weight, relative to the total weight of the glass.

According to an advantageous embodiment of the invention, the composition of the invention comprises from 0.001% to 0.5% by weight, and preferably from 0.001% to 0.2% or even 0.001% by weight, relative to the total weight of the glass. The selenium content (in terms of Se) is in the range of 0.1%, indeed even in the range of 0.001% to 0.05% or even in the range of 0.001% to 0.02%. These selenium content ranges allow for high infrared transmittance without unduly compromising the aesthetic appearance and coloration of the glass sheet.

According to another advantageous embodiment of the invention, the composition of the invention comprises from 0.005% to 0.5% by weight, preferably from 0.005% to 0.2% or 0.005% by weight, relative to the total weight of the glass. The selenium content (expressed as Se) in the range of 0.1%, or even better, in the range of 0.005% to 0.05%. Most preferably, the composition of the invention comprises a selenium content (expressed in the form of se) in the range of 0.002% to 0.1% or in the range of 0.002% to 0.05%, or even more preferably in the range of 0.002% to 0.02%. These selenium content ranges allow for even better infrared transmittance.

According to another embodiment of the invention, the composition comprises a Fe ²⁺ content (expressed as FeO) of less than 20 ppm. This range of content allows to obtain extremely satisfactory properties, especially in terms of infrared transmittance. Preferably, the composition comprises a Fe ²⁺ content (expressed as FeO) of less than 10 ppm. Most preferably, the composition comprises a Fe ²⁺ content (expressed as FeO) of less than 5 ppm.

According to the invention, the glass sheet has a high infrared transmittance. More specifically, the glass piece of the present invention has a high near infrared ray transmittance.

In order to quantify the good penetration of the glass in the infrared range, in the present specification, the absorption coefficient at a wavelength of 1050 nm will be utilized, in which case the absorption coefficient must be as low as possible in order to obtain a good transmittance. The absorption coefficient is defined by the ratio of the absorbance to the length of the optical path traveled by the electromagnetic radiation in a given medium. It is represented by m ^-1 . It is therefore independent of the material thickness, but it depends on the wavelength of the absorbed radiation and the chemical nature of the material.

In the case of glass, the absorption coefficient ( μ ) at the selected wavelength λ can be calculated from the measured value of the transmittance ( T ) and the refractive index n of the material ( thick = thickness), and the values of n, ρ and T depend on Selected wavelength λ:

Where ρ=(n-1) ² /(n+1) ²

Advantageously, the glass sheet according to the invention has an absorption coefficient of less than 5 m ^-1 at a wavelength of 1050 nm. Preferably, the glass sheet according to the present invention has an absorption coefficient of less than or equal to 2 m ^-1 at a wavelength of 1050 nm. Most preferably, the glass sheet according to the present invention has an absorption coefficient of less than or equal to 1 m ^-1 at a wavelength of 1050 nm.

It is also advantageous if the glass sheet according to the invention has an absorption coefficient of less than 5 m ^-1 at a wavelength of 950 nm. Preferably, the glass sheet according to the present invention has an absorption coefficient of less than or equal to 2 m ^-1 at a wavelength of 950 nm. Most preferably, the glass sheet according to the invention has an absorption coefficient of less than or equal to 1 m ^-1 at a wavelength of 950 nm.

It is also advantageous if the glass sheet according to the invention has an absorption coefficient of less than 5 m ^-1 at a wavelength of 850 nm. Preferably, the glass sheet according to the present invention has an absorption coefficient of less than or equal to 2 m ^-1 at a wavelength of 850 nm. Most preferably, the glass sheet according to the invention has an absorption coefficient of less than or equal to 1 m ^-1 at a wavelength of 850 nm.

According to one embodiment of the invention, in addition to containing impurities, which are especially included in the batch material, the composition of the glass sheet may also comprise a low proportion of additives (such as agents that promote glass melting or refining) or due to the formation of a furnace An element produced by the dissolution of a refractory material.

According to an advantageous embodiment of the invention, the composition of the glass sheet may additionally comprise an appropriate amount of one or more other colorants depending on the desired effect. This (these) colorants can be used, for example, to "neutralize" the color produced by the presence of selenium, and thus cause the coloring of the glass of the present invention to be more neutral, i.e., colorless. Alternatively, this (these) colorants can be used to obtain the desired color in addition to the color produced by the presence of selenium.

According to another advantageous embodiment of the invention which can be combined with the preceding embodiments, the glass sheet can be coated with a layer or film (for example a colored PVB film) which allows to alter or neutralize the production of selenium colour.

The glass sheets according to the invention can advantageously be tempered chemically or thermally.

According to an embodiment of the invention, the glass sheet is coated with at least one transparent and electrically conductive layer. The transparent and electrically conductive layer according to the invention may for example be a layer based on SnO ₂ :F, SnO ₂ :Sb or ITO (indium tin oxide), ZnO:Al or even ZnO:Ga.

According to a further advantageous embodiment of the invention, the glass sheet is coated with at least one anti-reflective (or anti-reflective) layer. This embodiment is clearly advantageous in the case where the glass piece of the present invention is used as the front surface of the screen. The antireflection layer according to the invention may be, for example, a layer based on a low refractive index porous ceria, or it may be made of a plurality of layers (multilayers), in particular may be made of a multilayer dielectric layer containing alternating low refractive indices Terminating with a high refractive index layer and with a low refractive index layer.

According to another embodiment, the glass sheet is coated with at least one anti-fouling layer or has been treated to limit/prevent its contamination by stains. This embodiment is also advantageous in the case where the glass piece of the present invention is used as the front surface of a touch screen. Such layers or treatments can be combined with a thin layer of transparent and electrically conductive deposited on the opposite surface. Such a layer can be combined with an anti-reflective layer deposited on the same surface, the anti-fouling layer being placed on the outside of the multilayer and thus covering the anti-reflective layer.

Other layers may be deposited on one and/or the other surface of the glass sheet according to the present invention, depending on the desired application and/or characteristics.

The invention also relates to a touch screen or touch panel or touch panel comprising at least one glass sheet according to the invention for defining a touch surface. According to this embodiment, the touch screen or touch panel or trackpad advantageously uses FTIR or PSD optics. In particular, for the screen, the glass piece is advantageously placed over the surface of the display.

Finally, by virtue of the high infrared transmittance, the glass sheet according to the present invention can be advantageously used in a touch screen or a touch panel or a touch panel, and the touch screen or the touch panel or the touch panel utilizes a plane called a plane. Scattering detection (PSD) or even frustrated total internal reflection (FTIR) optical technology Technique to detect the position of one or more objects (such as a finger or stylus) on the surface of the sheet.

Instance

The batch materials were blended in powder form and placed in a crucible for melting, the blend having the base composition specified in the table below.

Multiple samples were prepared using different amounts of selenium, and the base composition remained the same. Sample 1 (comparative example) corresponds to the prior art selenium-free "low iron" glass (so-called "specially clear" glass). Samples 2-3 correspond to the composition of the glass flakes according to the present invention.

The optical properties of each of the glass samples in the form of flakes were measured and, in particular, measured at 1050 nm, 950 nm by means of a penetration measurement using a PerkinElmer Lambda 950 spectrophotometer equipped with a 150 mm diameter integrating sphere. The absorption coefficient at a wavelength of 850 nm, the sample is placed in the entrance aperture of the sphere for measurement.

The following table shows the relative difference (Δ) of the corresponding values obtained for the absorption coefficients obtained according to the sample 2-3 of the present invention at the wavelengths of 1050 nm, 950 nm and 850 nm with respect to the reference sample (i.e., sample 1).

These results show that the addition of selenium in the range of content according to the invention makes it at 1050 The absorption coefficients at each of the nm, 950 nm, and 850 nm wavelengths are significantly reduced, and thus the radiation absorption in the near infrared is generally reduced.

Claims (10)

A glass sheet having a composition comprising the following, the amount of which is expressed as a percentage of the total weight of the glass: It is characterized in that the composition comprises a selenium content (expressed as Se) in the range of 0.001% to 0.1% by weight relative to the total weight of the glass. A glass sheet according to claim 1, wherein the composition comprises a selenium content (in terms of Se) in the range of 0.002% to 0.05% by weight relative to the total weight of the glass. A glass sheet according to claim 2, wherein the composition comprises a selenium content (expressed as Se) in the range of 0.002% to 0.02% by weight relative to the total weight of the glass. The glass sheet of any one of claims 1 to 3, wherein the composition has a Fe ²⁺ content (expressed as FeO) of less than 20 ppm. A glass sheet according to claim 4, wherein the composition has a Fe ²⁺ content (expressed as FeO) of less than 10 ppm. A glass sheet according to claim 5, wherein the composition has a Fe ²⁺ content (expressed as FeO) of less than 5 ppm. The glass sheet of any one of claims 1 to 3, wherein the glass sheet is coated with at least one stain resistant The layer has been treated to limit/prevent its contamination by stains. A touch screen or touch panel or touch panel comprising at least one glass sheet according to any one of claims 1 to 7 for defining a touch surface. The touch screen or touch panel or touch panel of claim 8 utilizes FTIR or PSD optical technology. A use of the glass sheet of any one of claims 1 to 7 in a touch screen or a touch panel or a touch panel, the touch screen or the touch panel or the touch panel utilizing FTIR or PSD optical technology to detect The position of one or more objects on the surface of the sheet is measured.