SU1671625A1 - Yellow glass - Google Patents

Yellow glass Download PDF

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Publication number
SU1671625A1
SU1671625A1 SU874212431A SU4212431A SU1671625A1 SU 1671625 A1 SU1671625 A1 SU 1671625A1 SU 874212431 A SU874212431 A SU 874212431A SU 4212431 A SU4212431 A SU 4212431A SU 1671625 A1 SU1671625 A1 SU 1671625A1
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SU
USSR - Soviet Union
Prior art keywords
glass
order
group
component
additionally contains
Prior art date
Application number
SU874212431A
Other languages
Russian (ru)
Inventor
Олег Гургенович Галустян
Валерий Сергеевич Иванов
Валентина Борисовна Латова
Майя Михайловна Маврина
Александр Александрович Шелудченко
Таисия Васильевна Селезнева
Original Assignee
Государственный научно-исследовательский институт стекла
Стеклозавод "Красный Луч"
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
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Application filed by Государственный научно-исследовательский институт стекла, Стеклозавод "Красный Луч" filed Critical Государственный научно-исследовательский институт стекла
Priority to SU874212431A priority Critical patent/SU1671625A1/en
Application granted granted Critical
Publication of SU1671625A1 publication Critical patent/SU1671625A1/en

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Classifications

    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C3/00—Glass compositions
    • C03C3/04—Glass compositions containing silica
    • C03C3/076—Glass compositions containing silica with 40% to 90% silica, by weight
    • C03C3/11—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen
    • C03C3/112—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine
    • C03C3/115—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron
    • C03C3/118—Glass compositions containing silica with 40% to 90% silica, by weight containing halogen or nitrogen containing fluorine containing boron containing aluminium
    • C—CHEMISTRY; METALLURGY
    • C03—GLASS; MINERAL OR SLAG WOOL
    • C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
    • C03C4/00—Compositions for glass with special properties
    • C03C4/02—Compositions for glass with special properties for coloured glass

Abstract

Изобретение относитс  к составам цветных стекол и может быть использовано в производстве светотехнических изделий. С целью снижени  чистоты цвета при доминирующей длине волны λд = 570 - 590 нм стекло содержит, мас.%: SIO2 53,0 - 76,0, AL2O3 0,1 - 7,0, B2O3 1,0 - 10,0, ZNO 3,0 - 15,0, CAO 0,1 - 10,0, MGO 0,1 - 8,0, NA2O 1,0 - 18,0, K2O 1,0 - 11,0, CDO 0,15 - 3,0, S2- и/или SE 0,05 - 1,25, CDS 0,1 - 5,0, SNO2 0,01 - 1,2, FE2O3 0,02 - 0,5, FЪ 0,01 - 0,75 и/или CL - 0,01 - 0,75, по крайней мере один компонент из группы TIO2 0,01 - 6,0, BAO 0,01 - 6,0, SRO 0,01 - 6,0. Стекло с целью повышени  температуры выработки дополнительно содержит по крайней мере один из оксидов, мас.%: LI2O 0,1 - 5,0, P2O5 0,1 - 5,0. 3. С целью ускорени  процесса наводки стекло дополнительно содержит один компонент из группы, мас.%: NIO 0,001 - 0,08, COO 0,001 - 0,08, CIO 0,001 - 0,08. Стекло с целью стабилизации желтой окраски и повышени  показател  преломлени , оно дополнительно содержит по крайней мере один компонент из группы, мас.%: CEO2 0,05 - 3,5, LA2O3 0,05 - 3,5, ND2O3 0,05 - 3,5, PR2O3 0,05 - 3,5. Температура варки 1300 - 1450°С, температура выработки 920 - 1180°С , чистота цвета при ист. A 50 - 95%, длина волны λд 570 - 590 нм, показатель преломлени , Nд 1,508 - 1,528, светопропускание при λд 65 - 85%, врем  наводки 0,08 - 0,67 ч, температура выработки 1190 - 1300°С, врем  наводки 0,01 - 0,06 ч, п. 4 показатель преломлени  Nд 1,530 - 1,550. 3 з.п. ф-лы, 5 табл.The invention relates to compositions of colored glass and can be used in the manufacture of lighting products. In order to reduce the color purity with the dominant wavelength λ d = 570 - 590 nm, the glass contains, in wt.%: SIO 2 53.0 - 76.0, AL 2 O 3 0.1 - 7.0, B 2 O 3 1 , 0 - 10.0, ZNO 3.0 - 15.0, CAO 0.1 - 10.0, MGO 0.1 - 8.0, NA 2 O 1.0 - 18.0, K 2 O 1, 0 - 11.0, CDO 0.15 - 3.0, S 2- and / or SE 0.05 - 1.25, CDS 0.1 - 5.0, SNO 2 0.01 - 1.2, FE 2 O 3 0.02 - 0.5, Fb 0.01 - 0.75 and / or CL - 0.01 - 0.75, at least one component from the TIO 2 group 0.01 - 6.0, BAO 0.01 - 6.0, SRO 0.01 - 6.0. Glass in order to increase the temperature of production additionally contains at least one of the oxides, wt.%: LI 2 O 0.1 - 5.0, P 2 O 5 0.1 - 5.0. 3. In order to speed up the process of setting, the glass additionally contains one component from the group, wt.%: NIO 0.001 - 0.08, COO 0.001 - 0.08, CIO 0.001 - 0.08. Glass in order to stabilize the yellow color and increase the refractive index, it additionally contains at least one component from the group, wt.%: CEO 2 0.05 - 3.5, LA 2 O 3 0.05 - 3.5, ND 2 O 3 0.05 - 3.5, PR 2 O 3 0.05 - 3.5. The cooking temperature is 1300 - 1450 ° С, the temperature of generation is 920 - 1180 ° С, the purity of the color at the East. A 50 - 95%, λ d 570 - 590 nm wavelength, refractive index, N d 1,508 - 1,528, light transmission at λ d 65 - 85%, pickup time 0.08 - 0.67 h, generation temperature 1190 - 1300 ° C, pickup time 0.01–0.06 h, p. 4, the refractive index N d 1.530 - 1.550. 3 hp f-ly, 5 tab.

Description

Изобретение относитс  к составам цветных стекол и может быть использовано в производстве светотехни-- ческих изделий.The invention relates to compositions of colored glass and can be used in the manufacture of lighting products.

Цель изобретени  - обеспечение чистоты цвета менее 0,095 при доминирующей длине волны А 570-590 нм, повышение температуры выработки и ускорение процесса наводки.The purpose of the invention is to ensure a color purity of less than 0.095 with the dominant wavelength of A 570-590 nm, an increase in the temperature of generation and acceleration of the pickup process.

Составы стекол и их свойства приведены в табл. 1-5.The compositions of glasses and their properties are given in table. 1-5.

Дл  синтеза стекла примен ют следующие основные сырьевые материалы: кварцевый песок, глинозем, борную кислоту , мел, доломит, соду, поташ, оксиды цинка, кадми , олова, титана, бари , стронци , серу, криолит, углекислый кадмий, селен и др. ВаркуThe following basic raw materials are used to synthesize glass: quartz sand, alumina, boric acid, chalk, dolomite, soda, potash, zinc oxides, cadmium, tin, titanium, barium, strontium, sulfur, cryolite, cadmium carbonate, selenium, etc. Bark

316316

стекол осуществл ют в ванных или горшковых печах при 1320-1470 С.the glasses are carried out in bath or pot furnaces at 1320-1470 C.

Дл  изготовлени  изделий используют различные методы формовани . For the manufacture of products using various methods of molding.

Синтезированные желтые стекла имеют высокое светопропускание (65- 85%), широкий диапазон чистоты цвета (0,5-0,95) при доминирующей длине в.олны Ао 570-590 нм, координаты цвет- ности стёкол лежат в пределах, ограниченных угловыми точками на границе цветности относительно источника А: Точка 1 ,500, ,430 Точка 2 ,440, ,490 Точка 3 ,475, ,525 Точка 4 ,550, ,455 Предлагаемый состав стекла обеспечивает получение стеклоизделий с чистотой цвета менее 95% при домини- рующей длине волныЪа 570-590 нм. Кроме того, имеетс  возможность изготовлени  изделий сложного профил  при повышенных температурах выработки , ускорить процесс термической об- работки стекла (наводки), получать стекла с высоким показателем преломлени , со стабильной желтой окраской Предлагаемое стекло может использоватьс  в производстве светотехниче ких изделий, например, автомобильных рассеивателей.Synthesized yellow glass has a high light transmission (65–85%), a wide range of color purity (0.5–0.95) with a dominant wavelength of Ao 570–590 nm, and the color coordinates of the glass lie within the limits of the angular points. on the border of chromaticity relative to the source A: Point 1, 500,, 430 Point 2, 440,, 490 Point 3, 475,, 525 Point 4, 550,, 455 The proposed glass composition provides glassware with a color purity of less than 95% with a dominant wavelength of 570-590 nm. In addition, it is possible to manufacture products of a complex profile at elevated temperatures, to accelerate the process of heat treatment of glass (pickup), to produce glasses with a high refractive index, with a stable yellow color. The proposed glass can be used in the manufacture of lighting products, for example, automotive diffusers. .

Claims (4)

1. Желтое стекло, включающее SiO, А1г03, Вг03, ZnO, CaO, MgO, Na20, K20, CdO, 52 и/или -Se, отличающеес  тем, что, с целью обеспечени  чистоты цвета менее 0,95 при доминирующей длине волны fla 570-590 нм, оно дополнительно Содержит CdS, SnO, РегО3, F и/или С1 и по крайней мере один компонент из группы ТiO, BaO, SrO при следую 0 5 1. Yellow glass, including SiO, A1g03, Br03, ZnO, CaO, MgO, Na20, K20, CdO, 52 and / or -Se, characterized in that, in order to ensure color purity of less than 0.95 at the dominant wavelength fla 570-590 nm, it additionally contains CdS, SnO, RegO3, F and / or C1 and at least one component from the group of TiO, BaO, SrO with the following 0 5 5five 00 по крайней мере один компонент из группыat least one component of the group Т10г 0,01-6,0T10g 0.01-6.0 BaO0,01-6,0BaO0.01-6.0 SrO0,01-6,0SrO0.01-6.0 2.Стекло по п. 1, отличающеес  тем, что, с целью повышени  температуры выработки, оно дополнительно содержит по крайней мере один из оксидов, мас.%:2.Glass according to claim 1, characterized in that, in order to increase the temperature of generation, it additionally contains at least one of the oxides, in wt.%: Li200,1-5,0Li200.1-5.0 P-jOj-0,1-5,0P-jOj-0.1-5.0 3.Стекло по п. 1, отличающеес  тем, что, с целью ускорени  процесса наводки, оно дополнительно содержит по крайней мере один компонент из группы, мас.%:3.Glass according to claim 1, characterized in that, in order to accelerate the pickup process, it additionally contains at least one component from the group, in wt.%: NiO 0,001-0,08 СоО 0,001-0,08 СиО 0,001-0,08NiO 0.001-0.08 CoO 0.001-0.08 CuO 0.001-0.08 4.Стекло по п. 1, отличающеес  тем, что, с целью стабилизации желтой окраски и повышени  показател  преломлени , оно дополнительно содержит по крайней мере один компонент из группы, мас.%:4.Glass according to claim 1, characterized in that, in order to stabilize the yellow color and increase the refractive index, it additionally contains at least one component from the group, in wt.%: Се02 0,05-3,5 La205 0,05-3,5 Ргг.0, 0,05-3,5Ce02 0.05-3.5 La205 0.05-3.5 Prg.0, 0.05-3.5 Таблица 3Table 3 Показатель преломлени  t 1.550 1.545 1,542 1,540 1.541Refractive index t 1.550 1.545 1,542 1,540 1.541 ПЛSubmarine I.5J8 1,540 1,536 1,534 1,530 1,537 1,534 1,535I.5J8 1,540 1,536 1,534 1,530 1,537 1,534 1,535 Таблица 5Table 5
SU874212431A 1987-03-19 1987-03-19 Yellow glass SU1671625A1 (en)

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Cited By (15)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4235311A1 (en) * 1992-10-20 1994-04-21 Dieter Pfaff Calibration agent for photometric determination of bilirubin
CN1045078C (en) * 1996-05-29 1999-09-15 广州市荔湾区广发玻璃工艺公司 Golden series matrix colored glass
EP1285889A1 (en) * 2001-08-22 2003-02-26 Schott Glas Optical colored glass, its use and sharp skirt optical filter
EP1285890A1 (en) * 2001-08-22 2003-02-26 Schott Glas Optical colored glass, its use and sharp skirt optical filter
EP1285888A3 (en) * 2001-08-22 2004-01-07 Schott Glas Method for the production of optical glasses and colored glasses at low temperatures
EP1439151A1 (en) * 2003-01-10 2004-07-21 L. Electric Glass Co., Ltd. Lead free glass and a glass tube made therefrom
EP1042246A4 (en) * 1997-12-02 2005-01-19 Corning Inc Rare earth element-halide environments in oxyhalide glasses
US7140202B2 (en) 2001-08-22 2006-11-28 Schott Ag Method for manufacturing optical glasses and colored glasses at low temperatures
WO2006120663A3 (en) * 2005-05-13 2007-01-18 Heye Res And Dev Ltd Soda lime glass compositions and process for manufacturing containers from said compositions
WO2009150382A3 (en) * 2008-06-12 2010-02-11 Saint-Gobain Emballage Object made of hollow glass
CN102295408A (en) * 2011-06-13 2011-12-28 福耀玻璃工业集团股份有限公司 Heat absorbing float glass
US8623776B2 (en) 2008-02-26 2014-01-07 Corning Incorporated Silicate glasses having low seed concentration
WO2014146941A1 (en) * 2013-03-20 2014-09-25 Agc Glass Europe Glass sheet having high infrared radiation transmission
CN104140204A (en) * 2013-05-09 2014-11-12 成都光明光电股份有限公司 Optical glass, optical preform and optical element
CN106430970A (en) * 2015-08-07 2017-02-22 费罗公司 Nickel-free and chromium-free forehearth colors for glass tanks

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
Авторское свидетельство СССР № 1044608, кл. С 03 С 3/095, 1982. Авторское свидетельство СССР 726042, кл. С 03 С 3/095, 1977. *

Cited By (26)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
DE4235311A1 (en) * 1992-10-20 1994-04-21 Dieter Pfaff Calibration agent for photometric determination of bilirubin
EP0594134A2 (en) * 1992-10-20 1994-04-27 Dieter Pfaff Calibrator for photometrical bilirubin assay
EP0594134A3 (en) * 1992-10-20 1994-10-19 Dieter Pfaff Calibrator for photometrical bilirubin assay.
CN1045078C (en) * 1996-05-29 1999-09-15 广州市荔湾区广发玻璃工艺公司 Golden series matrix colored glass
EP1042246A4 (en) * 1997-12-02 2005-01-19 Corning Inc Rare earth element-halide environments in oxyhalide glasses
EP1285890A1 (en) * 2001-08-22 2003-02-26 Schott Glas Optical colored glass, its use and sharp skirt optical filter
EP1285888A3 (en) * 2001-08-22 2004-01-07 Schott Glas Method for the production of optical glasses and colored glasses at low temperatures
US7140202B2 (en) 2001-08-22 2006-11-28 Schott Ag Method for manufacturing optical glasses and colored glasses at low temperatures
CN100455529C (en) * 2001-08-22 2009-01-28 肖特股份公司 Production of optical glass and colour glass under low-temperature
EP1285889A1 (en) * 2001-08-22 2003-02-26 Schott Glas Optical colored glass, its use and sharp skirt optical filter
EP1439151A1 (en) * 2003-01-10 2004-07-21 L. Electric Glass Co., Ltd. Lead free glass and a glass tube made therefrom
WO2006120663A3 (en) * 2005-05-13 2007-01-18 Heye Res And Dev Ltd Soda lime glass compositions and process for manufacturing containers from said compositions
US8623776B2 (en) 2008-02-26 2014-01-07 Corning Incorporated Silicate glasses having low seed concentration
US10626042B2 (en) 2008-02-26 2020-04-21 Corning Incorporated Fining agents for silicate glasses
US10040715B2 (en) 2008-02-26 2018-08-07 Corning Incorporated Silicate glasses having low seed concentration
US9073779B2 (en) 2008-02-26 2015-07-07 Corning Incorporated Fining agents for silicate glasses
WO2009150382A3 (en) * 2008-06-12 2010-02-11 Saint-Gobain Emballage Object made of hollow glass
US8828511B2 (en) 2008-06-12 2014-09-09 Saint-Gobain Emballage Object made of hollow glass
RU2500630C2 (en) * 2008-06-12 2013-12-10 Сэн-Гобэн Амбаллаж Hollow glass object
CN102295408B (en) * 2011-06-13 2012-12-26 福耀玻璃工业集团股份有限公司 Heat absorbing float glass
CN102295408A (en) * 2011-06-13 2011-12-28 福耀玻璃工业集团股份有限公司 Heat absorbing float glass
WO2014146941A1 (en) * 2013-03-20 2014-09-25 Agc Glass Europe Glass sheet having high infrared radiation transmission
CN105189387A (en) * 2013-03-20 2015-12-23 旭硝子欧洲玻璃公司 Glass sheet having high infrared radiation transmission
CN104140204A (en) * 2013-05-09 2014-11-12 成都光明光电股份有限公司 Optical glass, optical preform and optical element
CN106430970A (en) * 2015-08-07 2017-02-22 费罗公司 Nickel-free and chromium-free forehearth colors for glass tanks
CN106430970B (en) * 2015-08-07 2020-05-26 费罗公司 Nickel-free and chromium-free forehearth color for glass troughs

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