TWI590426B - Manufacturing method of photosensing unit of photosensing array and structure thereof - Google Patents
Manufacturing method of photosensing unit of photosensing array and structure thereof Download PDFInfo
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- TWI590426B TWI590426B TW104140041A TW104140041A TWI590426B TW I590426 B TWI590426 B TW I590426B TW 104140041 A TW104140041 A TW 104140041A TW 104140041 A TW104140041 A TW 104140041A TW I590426 B TWI590426 B TW I590426B
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- 238000004519 manufacturing process Methods 0.000 title claims description 33
- 239000010410 layer Substances 0.000 claims description 227
- 230000004888 barrier function Effects 0.000 claims description 78
- 239000004065 semiconductor Substances 0.000 claims description 60
- 239000011241 protective layer Substances 0.000 claims description 50
- 239000000758 substrate Substances 0.000 claims description 25
- 239000007769 metal material Substances 0.000 claims description 14
- 238000000034 method Methods 0.000 claims description 13
- 230000000873 masking effect Effects 0.000 claims 1
- 229910052739 hydrogen Inorganic materials 0.000 description 26
- 239000001257 hydrogen Substances 0.000 description 26
- -1 hydrogen ions Chemical class 0.000 description 26
- 238000009792 diffusion process Methods 0.000 description 13
- 239000000463 material Substances 0.000 description 13
- ZOKXTWBITQBERF-UHFFFAOYSA-N Molybdenum Chemical compound [Mo] ZOKXTWBITQBERF-UHFFFAOYSA-N 0.000 description 12
- 238000010586 diagram Methods 0.000 description 12
- 229910052751 metal Inorganic materials 0.000 description 12
- 239000002184 metal Substances 0.000 description 12
- 229910052750 molybdenum Inorganic materials 0.000 description 12
- 239000011733 molybdenum Substances 0.000 description 12
- 239000004020 conductor Substances 0.000 description 11
- 239000010936 titanium Substances 0.000 description 11
- 229910052782 aluminium Inorganic materials 0.000 description 10
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 10
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 description 9
- 229910052719 titanium Inorganic materials 0.000 description 9
- 229910045601 alloy Inorganic materials 0.000 description 7
- 239000000956 alloy Substances 0.000 description 7
- JAONJTDQXUSBGG-UHFFFAOYSA-N dialuminum;dizinc;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[Al+3].[Al+3].[Zn+2].[Zn+2] JAONJTDQXUSBGG-UHFFFAOYSA-N 0.000 description 6
- 229910044991 metal oxide Inorganic materials 0.000 description 6
- 150000004706 metal oxides Chemical class 0.000 description 6
- AJNVQOSZGJRYEI-UHFFFAOYSA-N digallium;oxygen(2-) Chemical compound [O-2].[O-2].[O-2].[Ga+3].[Ga+3] AJNVQOSZGJRYEI-UHFFFAOYSA-N 0.000 description 5
- 229910001195 gallium oxide Inorganic materials 0.000 description 5
- YVTHLONGBIQYBO-UHFFFAOYSA-N zinc indium(3+) oxygen(2-) Chemical compound [O--].[Zn++].[In+3] YVTHLONGBIQYBO-UHFFFAOYSA-N 0.000 description 5
- AMGQUBHHOARCQH-UHFFFAOYSA-N indium;oxotin Chemical compound [In].[Sn]=O AMGQUBHHOARCQH-UHFFFAOYSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 3
- KWXIRYKCFANFRC-UHFFFAOYSA-N [O--].[O--].[O--].[Al+3].[In+3] Chemical compound [O--].[O--].[O--].[Al+3].[In+3] KWXIRYKCFANFRC-UHFFFAOYSA-N 0.000 description 3
- GPBUGPUPKAGMDK-UHFFFAOYSA-N azanylidynemolybdenum Chemical compound [Mo]#N GPBUGPUPKAGMDK-UHFFFAOYSA-N 0.000 description 3
- 239000010408 film Substances 0.000 description 3
- 229910021389 graphene Inorganic materials 0.000 description 3
- 229910001092 metal group alloy Inorganic materials 0.000 description 3
- NQBRDZOHGALQCB-UHFFFAOYSA-N oxoindium Chemical compound [O].[In] NQBRDZOHGALQCB-UHFFFAOYSA-N 0.000 description 3
- XLOMVQKBTHCTTD-UHFFFAOYSA-N zinc oxide Inorganic materials [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 3
- 230000000903 blocking effect Effects 0.000 description 2
- 230000000052 comparative effect Effects 0.000 description 2
- 229910052732 germanium Inorganic materials 0.000 description 2
- GNPVGFCGXDBREM-UHFFFAOYSA-N germanium atom Chemical compound [Ge] GNPVGFCGXDBREM-UHFFFAOYSA-N 0.000 description 2
- 150000002739 metals Chemical class 0.000 description 2
- 239000010409 thin film Substances 0.000 description 2
- 239000011787 zinc oxide Substances 0.000 description 2
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 1
- GYHNNYVSQQEPJS-UHFFFAOYSA-N Gallium Chemical compound [Ga] GYHNNYVSQQEPJS-UHFFFAOYSA-N 0.000 description 1
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000005530 etching Methods 0.000 description 1
- 229910052733 gallium Inorganic materials 0.000 description 1
- 239000011521 glass Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 150000004767 nitrides Chemical class 0.000 description 1
- 229920000620 organic polymer Polymers 0.000 description 1
- KYKLWYKWCAYAJY-UHFFFAOYSA-N oxotin;zinc Chemical compound [Zn].[Sn]=O KYKLWYKWCAYAJY-UHFFFAOYSA-N 0.000 description 1
- 230000003071 parasitic effect Effects 0.000 description 1
- 230000000149 penetrating effect Effects 0.000 description 1
- 229910021420 polycrystalline silicon Inorganic materials 0.000 description 1
- 229920005591 polysilicon Polymers 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 229910052709 silver Inorganic materials 0.000 description 1
- 239000004332 silver Substances 0.000 description 1
- XOLBLPGZBRYERU-UHFFFAOYSA-N tin dioxide Chemical compound O=[Sn]=O XOLBLPGZBRYERU-UHFFFAOYSA-N 0.000 description 1
- 229910001887 tin oxide Inorganic materials 0.000 description 1
- WFKWXMTUELFFGS-UHFFFAOYSA-N tungsten Chemical compound [W] WFKWXMTUELFFGS-UHFFFAOYSA-N 0.000 description 1
- 229910052721 tungsten Inorganic materials 0.000 description 1
- 239000010937 tungsten Substances 0.000 description 1
Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14683—Processes or apparatus peculiar to the manufacture or treatment of these devices or parts thereof
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L27/00—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate
- H01L27/14—Devices consisting of a plurality of semiconductor or other solid-state components formed in or on a common substrate including semiconductor components sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation
- H01L27/144—Devices controlled by radiation
- H01L27/146—Imager structures
- H01L27/14601—Structural or functional details thereof
- H01L27/1463—Pixel isolation structures
Description
本發明是有關於一種感測單元的製造方法,且特別是有關於一種光感測陣列之光感測單元的製造方法及其結構。The present invention relates to a method of fabricating a sensing unit, and more particularly to a method of fabricating a light sensing unit of a light sensing array and a structure thereof.
光感測單元是一種普遍用於手機、平板電腦、筆記型電腦或醫療診斷輔助工具等電子裝置的光感元件。傳統上,光感測單元的製造流程是在形成氧化物半導體層後,再形成對應的光感測單元。然而,在進行光感測單元的沉積步驟時,會因為氫離子的產生而對氧化物半導體元件造成電性不穩定或電性退化的現象。基於氫離子對於氧化物半導體層的電性影響,現有的光感測單元的製造流程會衍生良率下降的問題並且造成製造成本的增加。另外,現有的氧化物半導體元件亦容易受到水氣的影響,造成半導體元件的電性不穩定。因此,如何改善光感測單元的製造流程及半導體元件的結構避免氫離子及水氣所帶來的影響為目前極須克服的一個重要課題。The light sensing unit is a light sensing element commonly used in electronic devices such as mobile phones, tablet computers, notebook computers, or medical diagnostic aids. Conventionally, the manufacturing process of the photo sensing unit is to form a corresponding photo sensing unit after forming the oxide semiconductor layer. However, when the deposition step of the photo sensing unit is performed, the oxide semiconductor element is electrically unstable or electrically degraded due to the generation of hydrogen ions. Based on the electrical influence of hydrogen ions on the oxide semiconductor layer, the manufacturing process of the existing photo sensing unit may cause a problem of a decrease in yield and cause an increase in manufacturing cost. Further, the conventional oxide semiconductor device is also susceptible to moisture and causes electrical instability of the semiconductor device. Therefore, how to improve the manufacturing process of the photo sensing unit and the structure of the semiconductor element to avoid the influence of hydrogen ions and water vapor is an important subject that must be overcome at present.
本發明提供一種光感測陣列之光感測單元的製造方法及其結構,可用以解決氫離子以及水氣所帶來的電性影響問題。The invention provides a method for manufacturing a light sensing unit of a light sensing array and a structure thereof, which can be used to solve the problem of electrical influence caused by hydrogen ions and moisture.
本發明的光感測陣列之光感測單元的製造方法,包括提供基板,基板上具有至少一單元區域。在基板上之單元區域內形成主動元件。在基板上的單元區域內形成第一電極層,所述第一電極層與主動元件電性連接。在主動元件上形成保護層。在保護層上形成遮蔽層,以遮蔽主動元件。於形成遮蔽層之後,在單元區域內之保護層上形成光感測層,以及,於光感測層上形成第二電極層。A method of fabricating a light sensing unit of a light sensing array of the present invention includes providing a substrate having at least one unit region thereon. An active element is formed in the cell area on the substrate. A first electrode layer is formed in the cell region on the substrate, and the first electrode layer is electrically connected to the active device. A protective layer is formed on the active component. A shielding layer is formed on the protective layer to shield the active components. After forming the shielding layer, a photo sensing layer is formed on the protective layer in the cell region, and a second electrode layer is formed on the photo sensing layer.
本發明另提供一種光感測陣列之光感測單元,包括基板、主動元件、第一電極層、保護層、遮蔽層、光感測層以及第二電極層。所述基板包括至少一單元區域。主動元件位於基板之單元區域內。第一電極層位於單元區域內且與主動元件電性連接。保護層覆蓋主動元件以及第一電極層。遮蔽層位於保護層上,其中遮蔽層遮蔽主動元件且遮蔽整個單元區域。光感測層位於保護層上且與第一電極層電性連接。第二電極層位於光感測層上。The invention further provides a light sensing unit of a light sensing array, comprising a substrate, an active component, a first electrode layer, a protective layer, a shielding layer, a light sensing layer and a second electrode layer. The substrate includes at least one unit region. The active component is located in the cell area of the substrate. The first electrode layer is located in the cell region and is electrically connected to the active device. The protective layer covers the active component and the first electrode layer. The shielding layer is located on the protective layer, wherein the shielding layer shields the active component and shields the entire unit area. The light sensing layer is located on the protective layer and is electrically connected to the first electrode layer. The second electrode layer is on the photo sensing layer.
基於上述,本發明的製造方法所形成的光感測陣列之光感測單元包括了第一電極層、遮蔽層以及阻隔牆之結構。因此,在後續步驟形成光感測層時,所述結構可用以阻擋氫離子或是水氣的擴散行為,避免造成對半導體元件的電性影響。Based on the above, the light sensing unit of the light sensing array formed by the manufacturing method of the present invention includes the structures of the first electrode layer, the shielding layer, and the barrier wall. Therefore, when the photo sensing layer is formed in a subsequent step, the structure can be used to block the diffusion behavior of hydrogen ions or moisture, thereby avoiding an electrical influence on the semiconductor element.
為讓本發明的上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。The above described features and advantages of the invention will be apparent from the following description.
圖1是依照本發明一實施例的光感測陣列示意圖。在本實施例中,光感測陣列包括多個光感測單元。每一光感測單元位於多條資料線DL以及多條閘極線GL所定義的區域(亦即單元區域R)內。基於導電性的考量,閘極線 GL與資料線DL一般是使用金屬材料。然,本發明不限於此,根據其他實施例,閘極線GL與資料線DL也可以使用其他導電材料。例如:合金、金屬材料的氮化物、金屬材料的氧化物、金屬材料的氮氧化物、或其它合適的材料、或是金屬材料與其它導材料的堆疊層。另外,每一光感測單元各自包括主動元件TFT與光感測層PS,其中,主動元件TFT分別與資料線DL、閘極線GL以及光感測層PS電性連接。以下,將針對單元區域R中之一部份的光感測單元的製造流程進行說明,如圖2A至圖2F以及圖3A至圖3G所示。1 is a schematic diagram of a light sensing array in accordance with an embodiment of the present invention. In this embodiment, the light sensing array includes a plurality of light sensing units. Each of the light sensing units is located in a region defined by the plurality of data lines DL and the plurality of gate lines GL (ie, the unit region R). Based on the conductivity considerations, the gate line GL and the data line DL are generally made of a metal material. However, the present invention is not limited thereto, and according to other embodiments, other conductive materials may be used for the gate line GL and the data line DL. For example: alloys, nitrides of metallic materials, oxides of metallic materials, oxynitrides of metallic materials, or other suitable materials, or stacked layers of metallic materials and other conductive materials. In addition, each of the light sensing units includes an active device TFT and a photo sensing layer PS, wherein the active device TFT is electrically connected to the data line DL, the gate line GL, and the photo sensing layer PS, respectively. Hereinafter, a manufacturing flow of the photo sensing unit of one of the unit regions R will be described, as shown in FIGS. 2A to 2F and FIGS. 3A to 3G.
圖2A至圖2F為本發明一實施例的光感測單元之製造流程的上視示意圖。圖3A至圖3G為本發明一實施例的光感測單元之製造流程的剖面示意圖。圖3A至圖3F分別為對應圖2A至圖2F的剖面示意圖。首先,請參考圖2A以及圖3A,本實施例的光感測陣列之光感測單元的製造方法包括提供基板Sub,所述基板Sub上具有至少一單元區域R(如圖1所標示)。基板Sub之材質可為玻璃、石英、有機聚合物或是金屬等等。2A to 2F are schematic top views of a manufacturing process of a light sensing unit according to an embodiment of the present invention. 3A to 3G are schematic cross-sectional views showing a manufacturing process of a photo sensing unit according to an embodiment of the present invention. 3A to 3F are schematic cross-sectional views corresponding to Figs. 2A to 2F, respectively. First, referring to FIG. 2A and FIG. 3A, the manufacturing method of the photo sensing unit of the photo sensing array of the present embodiment includes providing a substrate Sub having at least one unit region R (as indicated in FIG. 1). The material of the substrate Sub may be glass, quartz, organic polymer or metal or the like.
於基板Sub上之單元區域R內形成主動元件。所述主動元件的形成方法包括在基板Sub上形成閘極G以及與閘極G連接的閘極線GL,並且在閘極G以及閘極線GL上形成絕緣層GI。接著,在絕緣層GI上形成半導體層AL。特別是,半導體層AL可為氧化物半導體材料,包括例如氧化銦鎵鋅(Indium-Gallium-Zinc Oxide, IGZO)、氧化鋅(ZnO) 氧化錫(SnO)、氧化銦鋅(Indium-Zinc Oxide, IZO)、氧化鎵鋅(Gallium-Zinc Oxide, GZO)、氧化鋅錫(Zinc-Tin Oxide, ZTO)或氧化銦錫(Indium-Tin Oxide, ITO)等等,但不限於此。半導體層AL也可以是非晶矽、多晶矽或是其他半導體材料。An active element is formed in the cell region R on the substrate Sub. The method of forming the active device includes forming a gate G and a gate line GL connected to the gate G on the substrate Sub, and forming an insulating layer GI on the gate G and the gate line GL. Next, a semiconductor layer AL is formed on the insulating layer GI. In particular, the semiconductor layer AL may be an oxide semiconductor material including, for example, Indium-Gallium-Zinc Oxide (IGZO), zinc oxide (ZnO) tin oxide (SnO), and indium-zinc oxide (Indium-Zinc Oxide, IZO), Gallium-Zinc Oxide (GZO), Zinc-Tin Oxide (ZTO) or Indium-Tin Oxide (ITO), etc., but are not limited thereto. The semiconductor layer AL may also be an amorphous germanium, a polysilicon or other semiconductor material.
承上所述,請參考圖2B以及圖3B,在半導體層AL以及絕緣層GI的上方形成蝕刻終止層ES。蝕刻終止層ES中具有開口V1以及第一溝渠T1。特別是,所述第一溝渠T1是貫穿蝕刻終止層ES以及絕緣層GI以延伸至基板Sub的表面,且第一溝渠T1將半導體層AL以及閘極G包圍(如圖2B所示)。As described above, referring to FIG. 2B and FIG. 3B, an etch stop layer ES is formed over the semiconductor layer AL and the insulating layer GI. The etch stop layer ES has an opening V1 and a first trench T1. In particular, the first trench T1 is a surface extending through the etch stop layer ES and the insulating layer GI to extend to the substrate Sub, and the first trench T1 surrounds the semiconductor layer AL and the gate G (as shown in FIG. 2B).
接著,請參考圖2C以及圖3C,在蝕刻終止層ES上形成源極S以及汲極D,並且同時在基板Sub上之單元區域R內形成第一電極層M1。在本實施例中,第一電極層M1與源極S以及汲極D是同時形成,且屬於同一膜層。另外,源極S以及汲極D是透過開口V1與半導體層AL接觸。所述第一電極層M1是與汲極D電性連接。如圖3C所標示,上述閘極G、源極S、汲極D以及半導體層AL組成主動元件TFT。於本實施例中,於主動元件TFT的周圍形成阻隔牆BW0,其中阻隔牆BW0包括第一阻隔牆BW1。在形成第一電極層M1、源極S以及汲極D的同時,更包括於絕緣層GI以及蝕刻終止層ES之第一溝渠T1內形成第一阻隔牆BW1。第一阻隔牆BW1材料可包括金屬氧化物導電材料例如氧化銦錫(ITO)、氧化銦鋅(IZO)、氧化鋁鋅(AZO)、氧化鋁銦、氧化銦(InO)、氧化鎵(gallium oxide, GaO)或其它金屬氧化物導電材料、石墨烯、金屬材料例如鉬(Mo)、鈦(Ti)或其它金屬材料,金屬合金例如氮化鉬(MoN)、上述材料之組合、或者其它具有低阻值的導電材料。第一電極層M1為金屬材料包括金屬例如鋁、鈦/鋁/鈦、鉬、鉬/鋁/鉬、上述金屬組成之合金或其它適合之金屬或合金於本實施例中。第一阻隔牆BW1與第一電極層M1可為相同步驟形成。第一阻隔牆BW1是填入第一溝渠T1中,且所述第一阻隔牆BW1圍繞主動元件TFT。本實施例中,第一阻隔牆BW1與第一電極層M1可為不同步驟形成,且材料可為不同,然此並非用以限制本發明。由於第一阻隔牆BW1圍繞主動元件TFT,因此,於後續製程步驟中,可避免氫離子以及水氣擴散而使主動元件TFT的電性受到影響。在本實施例中,主動元件TFT是以底部閘極型薄膜電晶體為例來說明,但本發明不限於此。根據其他實施例,所述主動元件TFT可以是頂部閘極型薄膜電晶體。Next, referring to FIG. 2C and FIG. 3C, the source S and the drain D are formed on the etch stop layer ES, and at the same time, the first electrode layer M1 is formed in the cell region R on the substrate Sub. In the present embodiment, the first electrode layer M1 is formed simultaneously with the source S and the drain D, and belongs to the same film layer. Further, the source S and the drain D are in contact with the semiconductor layer AL through the opening V1. The first electrode layer M1 is electrically connected to the drain D. As indicated in FIG. 3C, the gate G, the source S, the drain D, and the semiconductor layer AL constitute an active device TFT. In the embodiment, the barrier wall BW0 is formed around the active device TFT, wherein the barrier wall BW0 includes the first barrier wall BW1. The first barrier layer BW1 is formed in the first trench T1 further including the insulating layer GI and the etch stop layer ES while forming the first electrode layer M1, the source S, and the drain D. The first barrier wall BW1 material may include a metal oxide conductive material such as indium tin oxide (ITO), indium zinc oxide (IZO), aluminum zinc oxide (AZO), aluminum oxide indium, indium oxide (InO), gallium oxide (gallium oxide). , GaO) or other metal oxide conductive material, graphene, metal material such as molybdenum (Mo), titanium (Ti) or other metal materials, metal alloys such as molybdenum nitride (MoN), combinations of the above materials, or others having a low Conductive material with resistance. The first electrode layer M1 is a metal material including a metal such as aluminum, titanium/aluminum/titanium, molybdenum, molybdenum/aluminum/molybdenum, an alloy of the above metals, or other suitable metal or alloy in this embodiment. The first barrier wall BW1 and the first electrode layer M1 may be formed in the same step. The first barrier wall BW1 is filled in the first trench T1, and the first barrier wall BW1 surrounds the active device TFT. In this embodiment, the first barrier wall BW1 and the first electrode layer M1 may be formed in different steps, and the materials may be different, which is not intended to limit the present invention. Since the first barrier wall BW1 surrounds the active device TFT, in the subsequent process steps, hydrogen ions and water vapor diffusion can be avoided to affect the electrical properties of the active device TFT. In the present embodiment, the active device TFT is exemplified by a bottom gate type thin film transistor, but the present invention is not limited thereto. According to other embodiments, the active device TFT may be a top gate type thin film transistor.
接著,請參考圖2D以及圖3D,在主動元件TFT上形成第一保護層PL1,其中第一電極層M1是位於第一保護層PL1之下方。第一保護層PL1具有第二溝渠T2以及開口V2。所述第二溝渠T2是貫穿保護層PL1並延伸至第一電極層M1的表面,且第二溝渠T2圍繞上述主動元件TFT(如圖2D所示)。Next, referring to FIG. 2D and FIG. 3D, a first protective layer PL1 is formed on the active device TFT, wherein the first electrode layer M1 is located below the first protective layer PL1. The first protective layer PL1 has a second trench T2 and an opening V2. The second trench T2 is a surface penetrating the protective layer PL1 and extending to the first electrode layer M1, and the second trench T2 surrounds the active device TFT (as shown in FIG. 2D).
再來,請參考圖2E以及圖3E,在保護層PL1上形成遮蔽層SD,以遮蔽主動元件TFT。所述遮蔽層SD遮蔽整個單元區域R中的主動元件TFT,且遮蔽層SD是由不透光金屬所組成。所述金屬材料包括金屬例如鋁、鈦/鋁/鈦、鉬、鉬/鋁/鉬、上述金屬組成之合金或其它適合之金屬或合金於本實施例中。另外,在形成遮蔽層SD的同時,更包括於保護層PL1之第二溝渠T2內形成阻隔牆BW0,其中阻隔牆BW0包括第二阻隔牆BW2,且所述第二阻隔牆BW2圍繞主動元件TFT。第二阻隔牆BW2的材料可包括金屬氧化物導電材料例如氧化銦錫(ITO)、氧化銦鋅(IZO)、氧化鋁鋅(AZO)、氧化鋁銦、氧化銦(InO)、氧化鎵(gallium oxide, GaO)或其它金屬氧化物導電材料、石墨烯、金屬材料例如鉬(Mo)、鈦(Ti)或其它金屬材料,金屬合金例如氮化鉬(MoN)、上述材料之組合、或者其它具有低阻值的導電材料。另外,第二阻隔牆BW2與遮蔽層SD可為相同步驟形成,且第二阻隔牆BW2與遮蔽層SD屬於同一膜層。然而,於本實施例中,第二阻隔牆BW2與遮蔽層SD可為不同步驟形成,且材料可為不同,然此並非用以限制本發明。由於第一阻隔牆BW1以及第二阻隔牆BW2圍繞主動元件TFT,因此,於後續製程步驟中,可進一步避免氫離子以及水氣的擴散而使主動元件TFT的電性受到影響。Referring to FIG. 2E and FIG. 3E, a shielding layer SD is formed on the protective layer PL1 to shield the active device TFT. The shielding layer SD shields the active device TFTs in the entire cell region R, and the shielding layer SD is composed of an opaque metal. The metal material includes a metal such as aluminum, titanium/aluminum/titanium, molybdenum, molybdenum/aluminum/molybdenum, an alloy of the above metals, or other suitable metal or alloy in this embodiment. In addition, while forming the shielding layer SD, the barrier wall BW0 is further formed in the second trench T2 of the protective layer PL1, wherein the barrier wall BW0 includes the second barrier wall BW2, and the second barrier wall BW2 surrounds the active device TFT . The material of the second barrier wall BW2 may include a metal oxide conductive material such as indium tin oxide (ITO), indium zinc oxide (IZO), aluminum zinc oxide (AZO), aluminum oxide indium, indium oxide (InO), gallium oxide (gallium). Oxide, GaO) or other metal oxide conductive material, graphene, metal material such as molybdenum (Mo), titanium (Ti) or other metal materials, metal alloys such as molybdenum nitride (MoN), combinations of the above materials, or others Low resistance conductive material. In addition, the second barrier wall BW2 and the shielding layer SD may be formed in the same step, and the second barrier wall BW2 and the shielding layer SD belong to the same film layer. However, in the present embodiment, the second barrier wall BW2 and the shielding layer SD may be formed in different steps, and the materials may be different, which is not intended to limit the present invention. Since the first barrier wall BW1 and the second barrier wall BW2 surround the active device TFT, the diffusion of hydrogen ions and moisture can be further prevented in the subsequent process steps, and the electrical properties of the active device TFT are affected.
再來,請參考圖2F以及圖3F,於形成遮蔽層SD之後,在單元區域R內形成光感測層PS,其中,光感測層PS是填入保護層PL1的開口V2中。光感測層PS是透過開口V2與第一電極層M1電性連接。於形成光感測層PS之後,可在光感測層PS的上方分別形成第二保護層PL2、第二電極層M2以及第三保護層PL3以形成如圖3G所示的光感測單元結構。Referring to FIG. 2F and FIG. 3F, after forming the shielding layer SD, a photo sensing layer PS is formed in the cell region R, wherein the photo sensing layer PS is filled in the opening V2 of the protective layer PL1. The light sensing layer PS is electrically connected to the first electrode layer M1 through the opening V2. After forming the photo sensing layer PS, the second protective layer PL2, the second electrode layer M2, and the third protective layer PL3 may be respectively formed over the photo sensing layer PS to form a photo sensing unit structure as shown in FIG. 3G. .
詳細來說,圖3G所示的光感測單元結構可對應於本發明一實施例的半導體元件,且為對應於圖2F延剖線X-X’的剖面示意圖。參考圖3G,半導體元件包括基板Sub、主動元件TFT、保護層PL1以及第一阻隔牆BW1。主動元件TFT位於基板Sub上。特別是,主動元件TFT包括閘極G、絕緣層GI、半導體層AL、蝕刻終止層ES、源極S以及汲極D。承上所述,絕緣層GI覆蓋閘極G。半導體層AL位於閘極G上方。蝕刻終止層ES覆蓋半導體層AL。源極S以及汲極D位於蝕刻終止層ES上,且與半導體層AL電性接觸。In detail, the light sensing unit structure shown in Fig. 3G can correspond to the semiconductor element of one embodiment of the present invention, and is a schematic cross-sectional view corresponding to the extension line X-X' of Fig. 2F. Referring to FIG. 3G, the semiconductor element includes a substrate Sub, an active device TFT, a protective layer PL1, and a first barrier rib BW1. The active device TFT is located on the substrate Sub. In particular, the active device TFT includes a gate G, an insulating layer GI, a semiconductor layer AL, an etch stop layer ES, a source S, and a drain D. As described above, the insulating layer GI covers the gate G. The semiconductor layer AL is located above the gate G. The etch stop layer ES covers the semiconductor layer AL. The source S and the drain D are located on the etch stop layer ES and are in electrical contact with the semiconductor layer AL.
另外,保護層PL1用以覆蓋主動元件TFT,且第一阻隔牆BW1圍繞主動元件TFT。在圖3G的實施例中,半導體元件更包括第一電極層M1、遮蔽層SD、光感測層PS、第二電極層M2以及第二阻隔牆BW2(見圖3E)。承上所述,第一電極層M1與主動元件TFT電性連接,且保護層PL1覆蓋第一電極層M1。第二阻隔牆BW2位於保護層PL1內,且圍繞主動元件TFT。遮蔽層SD位於保護層PL1上,且遮蔽主動元件TFT。光感測層PS位於保護層PL1上,且與第一電極層M1電性連接。另外,第二電極層M2位於光感測層PL1上。In addition, the protective layer PL1 is used to cover the active device TFT, and the first barrier wall BW1 surrounds the active device TFT. In the embodiment of FIG. 3G, the semiconductor element further includes a first electrode layer M1, a shielding layer SD, a photo sensing layer PS, a second electrode layer M2, and a second barrier wall BW2 (see FIG. 3E). As described above, the first electrode layer M1 is electrically connected to the active device TFT, and the protective layer PL1 covers the first electrode layer M1. The second barrier wall BW2 is located in the protective layer PL1 and surrounds the active device TFT. The shielding layer SD is located on the protective layer PL1 and shields the active device TFT. The photo sensing layer PS is located on the protective layer PL1 and is electrically connected to the first electrode layer M1. In addition, the second electrode layer M2 is located on the light sensing layer PL1.
在圖3G的半導體元件中,由於第一阻隔牆BW1以及第二阻隔牆BW2圍繞主動元件TFT,因此,可進一步避免氫離子以及水氣的擴散而使主動元件TFT的電性受到影響。In the semiconductor element of FIG. 3G, since the first barrier rib BW1 and the second barrier rib BW2 surround the active device TFT, diffusion of hydrogen ions and moisture can be further prevented to affect the electrical properties of the active device TFT.
圖4為本發明另一實施例的光感測單元示意圖。圖4的光感測單元結構與圖3G的光感測單元結構類似,且同樣為對應於圖2F延剖線X-X’之剖面,因此,相同元件以相同標號表示,且不予贅述。圖4與圖3G的光感測單元差異在於,圖4的光感測單元之製造方法更包括於保護層PL1上形成平坦層PN,且遮蔽層SD是位於保護層PL1以及平坦層PN上,並遮蔽主動元件TFT且遮蔽整個單元區域R。由於增加了平坦層PN,因此可以減少第一電極層M’1與主動元件TFT寄生電容的發生機會,同時也可以確保光感應層PS的平坦性。第一電極層M’1是位於平坦層PN上,且第一電極層M’1與遮蔽層SD是同時形成。換言之,第一電極層M’1與遮蔽層SD是屬於同一膜層。另外,相較於圖3G的光感測單元結構,光感測層PS是曡層於主動元件TFT上,因此增加了光感測層PS的感測面積。在本實施例中,由於第一電極層M’1與遮蔽層SD是同時形成於主動元件TFT的上方,因此,在形成光感測層PS時,可避免氫離子以及水氣的擴散而使主動元件TFT的電性受到影響。4 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. The structure of the photo-sensing unit of FIG. 4 is similar to that of the photo-sensing unit of FIG. 3G, and is also a cross-section corresponding to the X-X' of FIG. 2F. Therefore, the same elements are denoted by the same reference numerals and will not be described again. The difference between the photo sensing unit of FIG. 4 and FIG. 3G is that the manufacturing method of the photo sensing unit of FIG. 4 further includes forming a flat layer PN on the protective layer PL1, and the shielding layer SD is located on the protective layer PL1 and the flat layer PN. And shielding the active device TFT and shielding the entire cell region R. Since the flat layer PN is added, the occurrence of the parasitic capacitance of the first electrode layer M'1 and the active device TFT can be reduced, and the flatness of the photo-sensing layer PS can be ensured. The first electrode layer M'1 is located on the flat layer PN, and the first electrode layer M'1 and the shielding layer SD are simultaneously formed. In other words, the first electrode layer M'1 and the shielding layer SD belong to the same film layer. In addition, compared to the photo sensing unit structure of FIG. 3G, the photo sensing layer PS is layered on the active device TFT, thus increasing the sensing area of the photo sensing layer PS. In this embodiment, since the first electrode layer M'1 and the shielding layer SD are simultaneously formed on the active device TFT, when the photo sensing layer PS is formed, diffusion of hydrogen ions and moisture can be avoided. The electrical properties of the active device TFT are affected.
圖5為本發明另一實施例的光感測單元示意圖。圖5實施例的光感測單元是以類似於圖4光感測單元的製造方法所形成。圖5的光感測單元結構與圖4的光感測單元結構類似,且同樣為對應於圖2F延剖線X-X’之剖面,因此,相同元件以相同標號表示,且不予贅述。圖5與圖4的光感測單元差異在於,圖5的光感測單元之製造方法更包括於主動元件TFT的周圍形成第一阻隔牆BW’1。在本實施例中,由於第一阻隔牆BW’1圍繞主動元件TFT,因此,於後續製程步驟中,可避免氫離子以及水氣的擴散而使主動元件TFT的電性受到影響。FIG. 5 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. The light sensing unit of the embodiment of Fig. 5 is formed in a manufacturing method similar to the light sensing unit of Fig. 4. The structure of the photo-sensing unit of FIG. 5 is similar to that of the photo-sensing unit of FIG. 4, and is also a cross-section corresponding to the X-X' of FIG. 2F. Therefore, the same elements are denoted by the same reference numerals and will not be described again. The difference between the photo sensing unit of FIG. 5 and FIG. 4 is that the manufacturing method of the photo sensing unit of FIG. 5 further includes forming a first barrier wall BW'1 around the active device TFT. In the present embodiment, since the first barrier wall BW'1 surrounds the active device TFT, in the subsequent process steps, diffusion of hydrogen ions and moisture can be avoided and the electrical properties of the active device TFT are affected.
圖6為本發明另一實施例的光感測單元示意圖。圖6實施例的光感測單元是以類似於圖5光感測單元的製造方法所形成。圖6的光感測單元結構與圖5的光感測單元結構類似,且同樣為對應於圖2F延剖線X-X’之剖面,因此,相同元件以相同標號表示,且不予贅述。圖6與圖5的光感測單元差異在於,圖6的光感測單元之製造方法更包括於平坦層PN內形成第二阻隔牆BW’2,其中,第二阻隔牆BW’2圍繞主動元件TFT。在本實施例中,由於第一阻隔牆BW’1以及第二阻隔牆BW’2圍繞主動元件TFT,因此,於後續製程步驟中,可進一步避免氫離子以及水氣的擴散而使主動元件TFT的電性受到影響。FIG. 6 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. The light sensing unit of the embodiment of Fig. 6 is formed in a manufacturing method similar to that of the light sensing unit of Fig. 5. The structure of the photo-sensing unit of FIG. 6 is similar to that of the photo-sensing unit of FIG. 5, and is also a cross-section corresponding to the X-X' of FIG. 2F. Therefore, the same elements are denoted by the same reference numerals and will not be described again. The difference between the light sensing unit of FIG. 6 and FIG. 5 is that the manufacturing method of the light sensing unit of FIG. 6 further includes forming a second barrier wall BW'2 in the flat layer PN, wherein the second barrier wall BW'2 surrounds the active Component TFT. In this embodiment, since the first barrier wall BW'1 and the second barrier wall BW'2 surround the active device TFT, in the subsequent process steps, diffusion of hydrogen ions and moisture can be further avoided to cause the active device TFT. The electrical properties are affected.
圖7為本發明另一實施例的光感測單元示意圖。圖7實施例的光感測單元是以類似於圖4光感測單元的製造方法所形成。圖7的光感測單元結構與圖4的光感測單元結構類似,且同樣為對應於圖2F延剖線X-X’之剖面,因此,相同元件以相同標號表示,且不予贅述。圖7與圖4的光感測單元差異在於,圖7的光感測單元不包括平坦層PN,且光感測層PS直接形成於第一電極層M’1與遮蔽層SD的上方,並且曡層於主動元件TFT上。在本實施例中,由於第一電極層M’1與遮蔽層SD是同時形成於主動元件TFT的上方,因此,在形成光感測層PS時,可避免氫離子以及水氣的擴散而使主動元件TFT的電性受到影響。FIG. 7 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. The light sensing unit of the embodiment of Fig. 7 is formed in a manufacturing method similar to the light sensing unit of Fig. 4. The structure of the photo-sensing unit of FIG. 7 is similar to that of the photo-sensing unit of FIG. 4, and is also a cross-section corresponding to the cross-sectional line X-X' of FIG. 2F. Therefore, the same elements are denoted by the same reference numerals and will not be described again. The difference between the photo sensing unit of FIG. 7 and FIG. 4 is that the photo sensing unit of FIG. 7 does not include the flat layer PN, and the photo sensing layer PS is directly formed over the first electrode layer M'1 and the shielding layer SD, and The germanium layer is on the active device TFT. In this embodiment, since the first electrode layer M'1 and the shielding layer SD are simultaneously formed on the active device TFT, when the photo sensing layer PS is formed, diffusion of hydrogen ions and moisture can be avoided. The electrical properties of the active device TFT are affected.
圖8為本發明另一實施例的光感測單元示意圖。圖8實施例的光感測單元是以類似於圖7光感測單元的製造方法所形成。圖8的光感測單元結構與圖7的光感測單元結構類似,且同樣為對應於圖2F延剖線X-X’之剖面,因此,相同元件以相同標號表示,且不予贅述。圖8與圖7的光感測單元差異在於,圖8的光感測單元之製造方法更包括於主動元件TFT的周圍形成第一阻隔牆BW’1。在本實施例中,由於第一阻隔牆BW’1圍繞主動元件TFT,因此,於後續製程步驟中,可避免氫離子以及水氣的擴散而使主動元件TFT的電性受到影響。FIG. 8 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. The light sensing unit of the embodiment of Fig. 8 is formed in a manufacturing method similar to the light sensing unit of Fig. 7. The structure of the photo-sensing unit of FIG. 8 is similar to that of the photo-sensing unit of FIG. 7, and is also a cross-section corresponding to the cross-sectional line X-X' of FIG. 2F. Therefore, the same elements are denoted by the same reference numerals and will not be described again. 8 is different from the photo sensing unit of FIG. 7 in that the manufacturing method of the photo sensing unit of FIG. 8 further includes forming a first barrier wall BW'1 around the active device TFT. In the present embodiment, since the first barrier wall BW'1 surrounds the active device TFT, in the subsequent process steps, diffusion of hydrogen ions and moisture can be avoided and the electrical properties of the active device TFT are affected.
圖9A為本發明另一實施例的光感測單元之半導體元件的上視示意圖。圖9B為圖9A延剖線A-A’的剖面示意圖。圖9C為圖9A延剖線B-B’的剖面示意圖。請同時參考圖9A、圖9B以及圖9C。在本實施例的光感測單元之半導體元件包括基板Sub、主動元件TFT、保護層PL1以及遮蔽層SD。主動元件TFT位於基板Sub上,且主動元件TFT包括閘極G、絕緣層GI、半導體層AL、蝕刻終止層ES、源極S以及汲極D。承上所述,絕緣層GI覆蓋閘極G,半導體層AL位於閘極G上方。蝕刻終止層ES覆蓋半導體層AL。源極S以及汲極D位於蝕刻終止層ES上,且與半導體層AL電性接觸。9A is a top plan view of a semiconductor component of a photo sensing unit according to another embodiment of the present invention. Fig. 9B is a schematic cross-sectional view taken along line A-A' of Fig. 9A. Fig. 9C is a schematic cross-sectional view taken along line B-B' of Fig. 9A. Please refer to FIG. 9A, FIG. 9B and FIG. 9C at the same time. The semiconductor element of the photo sensing unit of the present embodiment includes a substrate Sub, an active device TFT, a protective layer PL1, and a shielding layer SD. The active device TFT is disposed on the substrate Sub, and the active device TFT includes a gate G, an insulating layer GI, a semiconductor layer AL, an etch stop layer ES, a source S, and a drain D. As described above, the insulating layer GI covers the gate G, and the semiconductor layer AL is located above the gate G. The etch stop layer ES covers the semiconductor layer AL. The source S and the drain D are located on the etch stop layer ES and are in electrical contact with the semiconductor layer AL.
在本實施例中,半導體元件更包括平坦層PLN位於保護層PL1的上方。開口OP圍繞主動元件TFT,並位於平坦層PLN以及保護層PL1中。遮蔽層SD位於該保護層PL1上,其中遮蔽層SD遮蔽主動元件TFT,且遮蔽層SD遮蔽整個單元區域。遮蔽層SD是由不透光金屬所組成,所述金屬材料包括金屬例如鋁、鈦/鋁/鈦、鉬、鉬/鋁/鉬、上述金屬組成之合金或其它適合之金屬或合金於本實施例中。另外,於剖線A-A’之剖面中,阻隔牆BW0會填入平坦層PLN以及保護層PL1的開口OP。但值得注意的是,於剖線B-B’之剖面中,開口OP透過平坦層PLN並延伸至保護層PL1的表面。換言之,於剖線B-B’之剖面中,遮蔽層SD僅會填入平坦層PLN的開口OP,以使其與資料線DL電性絕緣。In the present embodiment, the semiconductor element further includes a flat layer PLN located above the protective layer PL1. The opening OP surrounds the active device TFT and is located in the flat layer PLN and the protective layer PL1. The shielding layer SD is located on the protective layer PL1, wherein the shielding layer SD shields the active device TFT, and the shielding layer SD shields the entire cell region. The shielding layer SD is composed of an opaque metal including a metal such as aluminum, titanium/aluminum/titanium, molybdenum, molybdenum/aluminum/molybdenum, an alloy of the above metal or other suitable metal or alloy in the present embodiment. In the example. Further, in the cross section of the line A-A', the barrier wall BW0 fills the flat layer PLN and the opening OP of the protective layer PL1. It is to be noted, however, that in the section of the line B-B', the opening OP passes through the flat layer PLN and extends to the surface of the protective layer PL1. In other words, in the cross section of the line B-B', the shielding layer SD is only filled in the opening OP of the flat layer PLN to be electrically insulated from the data line DL.
阻隔牆BW0的材料可包括金屬氧化物導電材料例如氧化銦錫(ITO)、氧化銦鋅(IZO)、氧化鋁鋅(AZO)、氧化鋁銦、氧化銦(InO)、氧化鎵(gallium oxide, GaO)或其它金屬氧化物導電材料、石墨烯、金屬材料例如鎢、鉬、鈦、銅、鋁或銀或其它金屬材料,金屬合金例如氮化鉬(MoN)、上述材料之組合、或者其它具有低阻值的導電材料。遮蔽層SD與阻隔牆BW0可為相同步驟形成,然而,本發明不限於此。於本實施例中,阻隔牆BW0與遮蔽層SD可為不同步驟形成,且材料可為不同,然此並非用以限制本發明。The material of the barrier wall BW0 may include a metal oxide conductive material such as indium tin oxide (ITO), indium zinc oxide (IZO), aluminum zinc oxide (AZO), aluminum oxide indium, indium oxide (InO), gallium oxide (gallium oxide, GaO) or other metal oxide conductive material, graphene, metal material such as tungsten, molybdenum, titanium, copper, aluminum or silver or other metal materials, metal alloys such as molybdenum nitride (MoN), combinations of the above materials, or others Low resistance conductive material. The shielding layer SD and the barrier wall BW0 may be formed in the same step, however, the invention is not limited thereto. In this embodiment, the barrier wall BW0 and the shielding layer SD may be formed in different steps, and the materials may be different, which is not intended to limit the present invention.
參考圖9A至圖9C,阻隔牆BW0是圍繞主動元件TFT。也就是說,阻隔牆BW0是填入開口OP並且環繞著主動元件TFT的側邊,且遮蔽層SD覆蓋主動元件TFT的上邊。阻隔牆BW0藉由開口OP之接觸孔CH與主動元件TFT的汲極D接觸。另外,遮蔽層SD的厚度是大於100奈米。在本實施例中,由於阻隔牆BW0會圍繞主動元件TFT,因此,可阻擋氫離子以及水氣的擴散,避免主動元件TFT的電性受到影響。另外,於圖9A至圖9C的所示的半導體元件中,可於阻隔牆BW0上方形成光感測層,使光感測層曡層於主動元件TFT上,以達成本發明另一實施例的光感測單元結構。 實例 Referring to FIGS. 9A to 9C, the barrier wall BW0 surrounds the active device TFT. That is, the barrier wall BW0 is filled in the opening OP and surrounds the side of the active device TFT, and the shielding layer SD covers the upper side of the active device TFT. The barrier wall BW0 is in contact with the drain D of the active device TFT through the contact hole CH of the opening OP. In addition, the thickness of the shielding layer SD is greater than 100 nm. In the present embodiment, since the barrier wall BW0 surrounds the active device TFT, diffusion of hydrogen ions and moisture can be blocked, and electrical properties of the active device TFT are prevented from being affected. In addition, in the semiconductor device shown in FIG. 9A to FIG. 9C, a photo sensing layer may be formed over the barrier wall BW0, and the photo sensing layer is layered on the active device TFT to achieve another embodiment of the present invention. Light sensing unit structure. Instance
為了證明本發明光感測單元的半導體元件可用以阻擋氫離子以及水氣的擴散,避免主動元件TFT的電性受到影響,特別以下列實例作為說明。In order to prove that the semiconductor element of the photo sensing unit of the present invention can be used to block the diffusion of hydrogen ions and moisture, the electrical properties of the active device TFT are prevented from being affected, particularly by the following examples.
圖10A為習知的半導體元件之IV曲線圖(Ids-Vgs curve)。於圖10A的實施例中,是在無任何氫離子以及水氣的狀態下,針對習知的半導體元件量測電壓與電流關係的IV曲線圖。由圖10A可得知,在無任何氫離子以及水氣的狀態下,一般的半導體元件之主動元件在不同的電壓VD下(0.1V與10V),皆可正常的進行開關。FIG. 10A is an IV graph (Ids-Vgs curve) of a conventional semiconductor device. In the embodiment of Fig. 10A, an IV graph of voltage versus current is measured for a conventional semiconductor component in the absence of any hydrogen ions and moisture. As can be seen from FIG. 10A, in the absence of any hydrogen ions and moisture, the active components of a general semiconductor device can be normally switched at different voltages VD (0.1 V and 10 V).
圖10B為本發明一實施例的光感測單元之半導體元件之IV曲線圖。圖10B是在具有氫離子以及水氣的狀態下,針對圖9A至圖9C的光感測單元之半導體元件,也就是具有阻隔牆BW0的半導體元件所量測的電壓與電流關係之IV曲線圖。由圖10B的實驗結果發現,即使在具有氫離子以及水氣的狀態下,圖9A至圖9C的半導體元件的IV曲線圖與圖10A的IV曲線圖無異。也就是說,本發明的半導體元件由於包括了阻隔牆BW0用以阻擋氫離子以及水氣對主動元件TFT的影響,因此,其電壓與電流關係與正常狀態下無異。換言之,在具有氫離子以及水氣的狀態下,本發明的半導體元件之主動元件TFT在不同的電壓VD下(0.1V與10V),皆可正常的進行開關。FIG. 10B is an IV graph of a semiconductor device of a photo sensing unit according to an embodiment of the invention. FIG. FIG. 10B is an IV graph showing voltage and current measured for the semiconductor element of the photo sensing unit of FIGS. 9A to 9C, that is, the semiconductor element having the barrier wall BW0, in the state of having hydrogen ions and moisture. . From the experimental results of FIG. 10B, it is found that the IV graph of the semiconductor element of FIGS. 9A to 9C is the same as the IV graph of FIG. 10A even in the state of having hydrogen ions and moisture. That is to say, the semiconductor element of the present invention includes the barrier wall BW0 for blocking the influence of hydrogen ions and water vapor on the active device TFT, and therefore, the relationship between voltage and current is the same as in the normal state. In other words, in the state of having hydrogen ions and moisture, the active device TFT of the semiconductor device of the present invention can be normally switched at different voltages VD (0.1 V and 10 V).
圖10C為本發明一比較例的光感測單元之半導體元件之IV曲線圖。圖10C是在具有氫離子以及水氣的狀態下,針對習知的半導體元件,也就是不包括阻隔牆BW0的半導體元件所量測的電壓與電流關係之IV曲線圖。由圖10C的實驗結果發現,在具有氫離子以及水氣的狀態下,習知的半導體元件之主動元件的電性特性會受到的影響。詳細來說,由於習知的半導體元件不包括阻隔牆BW0,因此,無法有效的阻擋氫離子以及水氣的擴散。換言之,在具有氫離子以及水氣的狀態下,習知的半導體元件之主動元件在不同的電壓VD下(0.1V與10V),無法正常的進行開關。10C is a graph showing the IV of a semiconductor element of a photo sensing unit according to a comparative example of the present invention. Fig. 10C is an IV graph showing the relationship between voltage and current measured for a conventional semiconductor element, that is, a semiconductor element not including the barrier wall BW0, in a state having hydrogen ions and moisture. From the experimental results of Fig. 10C, it is found that the electrical characteristics of the active elements of the conventional semiconductor element are affected in the state of having hydrogen ions and moisture. In detail, since the conventional semiconductor element does not include the barrier wall BW0, it is impossible to effectively block the diffusion of hydrogen ions and moisture. In other words, in the state of having hydrogen ions and water vapor, the active elements of the conventional semiconductor elements cannot be normally switched at different voltages VD (0.1 V and 10 V).
綜上所述,本發明的製造方法所形成的光感測陣列之光感測單元包括了第一電極層M1(M’1)、遮蔽層SD、阻隔牆BW0(包括第一、第二阻隔牆)結構。特別是,第一電極層M1(M’1)以及遮蔽層SD是形成於主動元件TFT的上方,用以遮蔽主動元件TFT。另外,阻隔牆BW0會將主動元件TFT包圍。因此,在後續形成光感測層PS的步驟時,上述結構可用以阻擋氫離子或是水氣的擴散效應避免主動元件TFT的電性受到影響。另外,在上述的實施例中,由於光感測層PS是在第一電極層M1(M’1)以及遮蔽層SD之後形成,因此,可避免在光感測層PS的蝕刻過程中,所使用的電漿對主動元件TFT之通道產生的損壞。In summary, the light sensing unit of the light sensing array formed by the manufacturing method of the present invention includes a first electrode layer M1 (M'1), a shielding layer SD, and a barrier wall BW0 (including the first and second barriers). Wall) structure. In particular, the first electrode layer M1 (M'1) and the shielding layer SD are formed over the active device TFT to shield the active device TFT. In addition, the barrier wall BW0 will surround the active device TFT. Therefore, in the subsequent step of forming the photo sensing layer PS, the above structure can be used to block the diffusion effect of hydrogen ions or moisture to prevent the electrical properties of the active device TFT from being affected. In addition, in the above-described embodiment, since the photo sensing layer PS is formed after the first electrode layer M1 (M'1) and the shielding layer SD, it is possible to avoid the etching process of the photo sensing layer PS. The plasma used is damaged by the channel of the active element TFT.
雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明的精神和範圍內,當可作些許的更動與潤飾,故本發明的保護範圍當視後附的申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the present invention, and any one of ordinary skill in the art can make some changes and refinements without departing from the spirit and scope of the present invention. The scope of the invention is defined by the scope of the appended claims.
DL:資料線 GL:閘極線 TFT:主動元件 PS:光感測層 R:單元區域 Sub:基板 G:閘極DL: data line GL: gate line TFT: active element PS: light sensing layer R: unit area Sub: substrate G: gate
GI‧‧‧絕緣層 GI‧‧‧Insulation
AL‧‧‧半導體層 AL‧‧‧Semiconductor layer
ES‧‧‧蝕刻終止層 ES‧‧‧etch stop layer
V1、V2、OP‧‧‧開口 V1, V2, OP‧‧‧ openings
T1‧‧‧第一溝渠 T1‧‧‧first ditches
T2‧‧‧第二溝渠 T2‧‧‧Second Ditch
S‧‧‧源極 S‧‧‧ source
D‧‧‧汲極 D‧‧‧汲
M1、M’1‧‧‧第一電極層 M1, M'1‧‧‧ first electrode layer
M2‧‧‧第二電極層 M2‧‧‧Second electrode layer
BW0‧‧‧阻隔牆 BW0‧‧‧ blocking wall
BW1、BW’1‧‧‧第一阻隔牆 BW1, BW’1‧‧‧ first barrier wall
BW2、BW’2‧‧‧第二阻隔牆 BW2, BW'2‧‧‧ second barrier wall
PL1‧‧‧第一保護層 PL1‧‧‧ first protective layer
PL2‧‧‧第二保護層 PL2‧‧‧ second protective layer
PL3‧‧‧第三保護層 PL3‧‧‧ third protective layer
SD‧‧‧遮蔽層 SD‧‧‧shading layer
PN、PLN‧‧‧平坦層 PN, PLN‧‧‧ flat layer
CH‧‧‧接觸孔 CH‧‧‧Contact hole
圖1是依照本發明一實施例的光感測陣列示意圖。 圖2A至圖2F為本發明一實施例的光感測單元之製造流程的上視示意圖。 圖3A至圖3G為本發明一實施例的光感測單元之製造流程的剖面示意圖。 圖4為本發明另一實施例的光感測單元示意圖。 圖5為本發明另一實施例的光感測單元示意圖。 圖6為本發明另一實施例的光感測單元示意圖。 圖7為本發明另一實施例的光感測單元示意圖。 圖8為本發明另一實施例的光感測單元示意圖。 圖9A為本發明另一實施例的光感測單元之半導體元件的上視示意圖。 圖9B為圖9A延剖線A-A’的剖面示意圖。 圖9C為圖9A延剖線B-B’的剖面示意圖。 圖10A為習知的半導體元件之IV曲線圖。 圖10B為本發明一實施例的光感測單元之半導體元件之IV曲線圖。 圖10C為本發明一比較例的光感測單元之半導體元件之IV曲線圖。1 is a schematic diagram of a light sensing array in accordance with an embodiment of the present invention. 2A to 2F are schematic top views of a manufacturing process of a light sensing unit according to an embodiment of the present invention. 3A to 3G are schematic cross-sectional views showing a manufacturing process of a photo sensing unit according to an embodiment of the present invention. 4 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. FIG. 5 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. FIG. 6 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. FIG. 7 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. FIG. 8 is a schematic diagram of a light sensing unit according to another embodiment of the present invention. 9A is a top plan view of a semiconductor component of a photo sensing unit according to another embodiment of the present invention. Fig. 9B is a schematic cross-sectional view taken along line A-A' of Fig. 9A. Fig. 9C is a schematic cross-sectional view taken along line B-B' of Fig. 9A. Fig. 10A is an IV graph of a conventional semiconductor device. FIG. 10B is an IV graph of a semiconductor device of a photo sensing unit according to an embodiment of the invention. FIG. 10C is a graph showing the IV of a semiconductor element of a photo sensing unit according to a comparative example of the present invention.
TFT:主動元件 Sub:基板 G:閘極 GI:絕緣層 AL:半導體層 ES:蝕刻終止層 S:源極 D:汲極 M1:第一電極層 M2:第二電極層 PL1:第一保護層 PL2:第二保護層 PL3:第三保護層 PS:光感測層 SD:遮蔽層 BW0:阻隔牆 BW1:第一阻隔牆 BW2:第二阻隔牆TFT: active element Sub: substrate G: gate GI: insulating layer AL: semiconductor layer ES: etch stop layer S: source D: drain M1: first electrode layer M2: second electrode layer PL1: first protective layer PL2: second protective layer PL3: third protective layer PS: light sensing layer SD: shielding layer BW0: barrier wall BW1: first barrier wall BW2: second barrier wall
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