TWI588101B - Apparatus and methods for providing a clean glass-making environment - Google Patents

Apparatus and methods for providing a clean glass-making environment Download PDF

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Publication number
TWI588101B
TWI588101B TW101143718A TW101143718A TWI588101B TW I588101 B TWI588101 B TW I588101B TW 101143718 A TW101143718 A TW 101143718A TW 101143718 A TW101143718 A TW 101143718A TW I588101 B TWI588101 B TW I588101B
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Taiwan
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glass
muffle
conduit
outer casing
chamber
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TW101143718A
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Chinese (zh)
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TW201326061A (en
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戴利亞羅伯特
柯卡圖倫布倫特
馬可漢沙恩瑞秋
普菲佛卡爾派翠克
史羅德麥可安德魯
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康寧公司
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    • CCHEMISTRY; METALLURGY
    • C03GLASS; MINERAL OR SLAG WOOL
    • C03BMANUFACTURE, SHAPING, OR SUPPLEMENTARY PROCESSES
    • C03B17/00Forming molten glass by flowing-out, pushing-out, extruding or drawing downwardly or laterally from forming slits or by overflowing over lips
    • C03B17/06Forming glass sheets
    • C03B17/064Forming glass sheets by the overflow downdraw fusion process; Isopipes therefor

Description

用於提供乾淨玻璃製造環境的設備與方法 Apparatus and method for providing a clean glass manufacturing environment 【相關申請案之交叉引用】 [Cross-reference to related applications]

本申請案主張於2011年11月28日提出申請之美國臨時申請案第61/563,927號的優先權權益,該臨時申請案之內容為本案所依據且以引用之方式整體併入本文。 The present application claims priority to U.S. Provisional Application No. 61/563,927, filed on Nov. 28, 2011, the content of which is hereby incorporated by reference.

本發明係關於用於製造玻璃的設備與方法,且更特定而言係關於用於藉由下拉式製程製造玻璃段的設備與方法。 This invention relates to apparatus and methods for making glass, and more particularly to apparatus and methods for making glass segments by a pull-down process.

由於具有產生優良玻璃表面品質的能力,玻璃片生產之熔融製程已成為形成玻璃的較佳方法。在熔融製程中,玻璃溢出成形體以使兩股獨立熔融流融合成一個玻璃帶且藉此保持兩個外表面的表面品質。玻璃表面品質對於使用玻璃製造顯示器(例如,平板顯示器、液晶顯示器(LCDs)、OLED顯示器、電漿顯示器及場發射顯示器)的顧客而言是極其重要的。即使是小的表面缺陷也可能引起延遲差異或終端使用者(例如,電視觀眾)可能認為是缺陷的其他問題(如, 圖片中的暗點或亮點)。典型的液晶晶胞間隙在<5 μm的範圍中,因此即使1 μm的表面人工因素也會造成來自周圍區域之光之路徑長度20%的變化。在極端情況下,表面缺陷可能大到足夠完全橋接晶胞間隙,造成短路。高品質LCD面板需要玻璃組件的優良表面品質。表面缺陷的影響對於大型世代(Gen)尺寸面板(例如,第8代及第10代)是極其顯著的,在該等大型世代尺寸面板中,即使一個缺陷也可能造成整個片材不可用。一種類型的此玻璃缺陷被稱作「附著融合顆粒(onclusion)」。 Due to its ability to produce excellent glass surface quality, the melting process of glass sheet production has become a preferred method of forming glass. In the melt process, the glass overflows the shaped body to fuse the two separate melt streams into one glass ribbon and thereby maintain the surface quality of the two outer surfaces. Glass surface quality is extremely important to customers who use glass to manufacture displays such as flat panel displays, liquid crystal displays (LCDs), OLED displays, plasma displays, and field emission displays. Even small surface defects can cause delay differences or other problems that end users (eg, television viewers) may consider to be defects (eg, Dark spots or highlights in the picture). A typical liquid crystal cell gap is in the range of <5 μm, so even a surface artificial factor of 1 μm causes a 20% change in the path length of light from the surrounding area. In extreme cases, surface defects may be large enough to completely bridge the cell gap, causing a short circuit. High quality LCD panels require excellent surface quality of the glass components. The effects of surface defects are extremely significant for large-scale (Gen) size panels (eg, 8th and 10th generations) in which even one defect can cause the entire sheet to be unusable. One type of this glass defect is referred to as "onclusion".

附著融合顆粒係在玻璃帶成形期間附著於熔融玻璃表面並可能部分地嵌入玻璃的顆粒類型缺陷。附著融合顆粒係對缺陷之性質的通用術語,且可能有許多根源。用於製造玻璃的熔融拉製機(fusion draw machine;FDM)在底部開口且空氣自該拉製機底部向上自由流通。此空氣可將顆粒物質(該等顆粒物質引起缺陷)向上傳送並傳送至熔融玻璃上。另外,FDM本身的一般性耐火組件可能由於蒸氣或溫度而脫落或被攪動,從而產生挾帶在FDM內之空氣流中或以其他方式形成玻璃表面上之缺陷的顆粒物質。所有此等顆粒物質均符合附著融合顆粒類別,並造成玻璃損耗。此等顆粒物質在片材表面上的位置使附著融合顆粒成為重要缺陷類別。 The attached fused particles are particle type defects that adhere to the surface of the molten glass during the formation of the glass ribbon and may be partially embedded in the glass. Adhesion fusion particles are a general term for the nature of defects and may have many sources. A fusion draw machine (FDM) for making glass is open at the bottom and air is freely circulated upward from the bottom of the draw machine. This air can transport the particulate matter (the particulate matter causes defects) upward and transfer it to the molten glass. Additionally, the general refractory components of the FDM itself may be detached or agitated by vapor or temperature, thereby creating particulate matter that entrains the air stream within the FDM or otherwise forms defects on the glass surface. All of these particulate materials conform to the class of adherent fused particles and cause glass loss. The location of such particulate matter on the surface of the sheet makes the attachment of the fused particles an important class of defects.

已經嘗試藉由所謂的煙囪效應降低自FDM之底部向上浮動之空氣的量,藉此嘗試降低附著融合顆粒的量。一般而言,此等嘗試涉及控制FDM中的壓力。 Attempts have been made to reduce the amount of air that floats upward from the bottom of the FDM by the so-called chimney effect, thereby attempting to reduce the amount of adhering fused particles. In general, such attempts involve controlling the pressure in the FDM.

本發明者已發現僅僅控制FDM內的壓力不足以維持玻璃表面上低含量的附著融合顆粒。另外,控制FDM內的壓力之方式影響加壓以在維持厚度控制(亦即,維持跨玻璃寬度的低厚度變化)的同時減少附著融合顆粒的能力。具體而言,本發明者已發現在在附著融合顆粒可能形成的點處形成FDM內乾淨的空氣環境時的加壓係用於獲得附著融合顆粒減少的穩健且可持續的方式。可藉由適當地選擇傳送氣體以加壓FDM經由的設備、依據在氣體中包含的顆粒物質之該氣體本身的品質以及氣體傳送至FDM的位置來在FDM內形成乾淨的空氣環境,該設備、該品質及該位置之每一者影響減少附著融合顆粒的能力。本揭示案係關於用於適當地(亦即,在形成乾淨的空氣環境時)增加FDM內的壓力並藉此在維持厚度控制的同時減少附著融合顆粒的設備與方法。 The inventors have discovered that merely controlling the pressure within the FDM is insufficient to maintain a low level of adherent fused particles on the glass surface. Additionally, the manner in which the pressure within the FDM is controlled affects the pressurization to reduce the ability to adhere to the fused particles while maintaining thickness control (i.e., maintaining a low thickness variation across the glass width). In particular, the inventors have discovered that pressurization at the point of forming a clean air environment within the FDM at the point where adhesion of the fused particles is likely to be formed is a robust and sustainable way to achieve a reduction in adherent fused particles. A clean air environment can be formed in the FDM by appropriately selecting a device through which the transfer gas is pressurized to press the FDM, a quality of the gas itself according to the particulate matter contained in the gas, and a position at which the gas is delivered to the FDM, the device, This quality and each of the locations affects the ability to reduce the attachment of fused particles. The present disclosure is directed to an apparatus and method for increasing the pressure within an FDM, and thereby reducing adhesion of the fused particles while maintaining thickness control, suitably (i.e., when forming a clean air environment).

將在以下詳細描述中闡述額外的特徵結構及優點,熟習此項技術者將從描述中顯而易見部分該等特徵結構及優點,或藉由實踐如書面描述與隨附圖式所例示的各態樣,熟習此項技術者將認識到部分該等特徵結構及優點。應瞭解,上文的一般性描述及下文的詳細描述兩者僅是對各個態樣的示例性描述,並意欲提供概述或框架來理解本發明所主張的本發明之性質與特徵。 Additional features and advantages will be set forth in the <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; </ RTI> <RTIgt; Those skilled in the art will recognize some of these features and advantages. The above general description and the following detailed description are merely illustrative of the various aspects of the invention, and are intended to provide an overview or a framework to understand the nature and features of the invention as claimed.

隨附圖式被包括在內以提供對本發明之原則的進一步理解,且該等隨附圖式被併入並組成此說明書的一部分。圖式說明一或更多個實施例,並以舉例之方式和描述一起用來闡明本發明之原則與操作。應瞭解,在此說明書中及 在該等圖式中所揭示的各個特徵結構可用於任何或所有組合。經由非限制性實例的方式,如在下文態樣中所闡述,各個特徵結構可彼此組合:根據第一態樣,提供下拉式玻璃製造設備,該設備包含:外殼;成形體,該成形體設置在該外殼內;入口管,該入口管經設置以輸送熔融玻璃至成形體;及導管,該導管具有出口,且該導管經設置以輸送流體至外殼,藉此可加壓外殼,其中導管由在成形體附近上方於FDM中之溫度下不反應或不受腐蝕的材料製成。 The drawings are included to provide a further understanding of the principles of the invention, and are incorporated in and constitute a part of this specification. The drawings illustrate one or more embodiments and are used to illustrate the principles and operation of the invention. It should be understood that in this specification and The various features disclosed in the figures can be used in any or all combinations. By way of non-limiting example, as set forth in the following aspects, various features may be combined with one another: according to a first aspect, a drop-down glass manufacturing apparatus is provided, the apparatus comprising: a casing; a shaped body, the shaped body setting In the outer casing; an inlet pipe disposed to convey molten glass to the shaped body; and a conduit having an outlet, and the conduit is configured to deliver fluid to the outer casing, whereby the outer casing can be pressurized, wherein the conduit is Made of a material that does not react or is not corroded at temperatures in the FDM above the shaped body.

根據第二態樣,提供根據態樣1之設備,其中導管由陶瓷、玻璃陶瓷、玻璃、鉑、銥、鈀、銠或鎳製成。 According to a second aspect, there is provided apparatus according to aspect 1, wherein the conduit is made of ceramic, glass ceramic, glass, platinum, rhodium, palladium, rhodium or nickel.

根據第三態樣,提供根據態樣1或態樣2之設備,該設備進一步包含連接至導管的氣體源,其中氣體源經配置以輸送空浮顆粒潔淨等級100級或更潔淨的氣體。 According to a third aspect, there is provided apparatus according to Aspect 1 or Aspect 2, the apparatus further comprising a source of gas coupled to the conduit, wherein the source of gas is configured to deliver a level of airborne particulate cleanliness class 100 or cleaner.

根據第四態樣,提供根據態樣1至態樣3之任何一個態樣的設備,其中導管位於與成形體相同的高度處。 According to a fourth aspect, there is provided an apparatus according to any one of Aspect 1 to Aspect 3, wherein the conduit is located at the same height as the shaped body.

根據第五態樣,提供根據態樣1至態樣4之任何一個態樣的設備,其中外殼係馬弗腔室,該馬弗腔室包括位於馬弗腔室底部之馬弗(muffle)門,藉由成形體形成的玻璃經由該馬弗門離開馬弗腔室,其中導管之出口位於馬弗腔室內且位於馬弗門外。 According to a fifth aspect, there is provided an apparatus according to any one of Aspect 1 to Aspect 4, wherein the outer casing is a muffle chamber including a muffle door at the bottom of the muffle chamber The glass formed by the shaped body exits the muffle chamber via the muffle door, wherein the outlet of the conduit is located within the muffle chamber and outside the muffle door.

根據第六態樣,提供根據態樣5的設備,其中馬弗門包括面向根部的前面板,其中前面板由具有高熱導率的材料製成,且該設備進一步包含馬弗門腔室,該馬弗門腔室設置在前面板之一側上,根部設置在與該側相對的前面板之側上。 According to a sixth aspect, there is provided apparatus according to aspect 5, wherein the muffle door comprises a front panel facing the root, wherein the front panel is made of a material having a high thermal conductivity, and the apparatus further comprises a muffle door chamber, The muffle door chamber is disposed on one side of the front panel, and the root is disposed on the side of the front panel opposite the side.

根據第七態樣,提供製造玻璃段的方法,該方法包含以下步驟:在設置於外殼內之成形體的上方流動熔融玻璃,以使熔融玻璃以帶之形式自該成形體向下流動;經由導管輸送流體至外殼以加壓外殼,其中導管由在成形體附近上方於FDM中之溫度下不反應或不受腐蝕的材料製成。 According to a seventh aspect, there is provided a method of producing a glass segment, the method comprising the steps of: flowing molten glass above a shaped body disposed within a casing such that molten glass flows downwardly from the shaped body in the form of a belt; The conduit delivers fluid to the outer casing to pressurize the outer casing, wherein the conduit is made of a material that does not react or is not corroded at temperatures above the shaped body in the FDM.

使帶流出外殼;及切割帶以形成玻璃段。 Passing the tape out of the outer casing; and cutting the tape to form a glass segment.

根據第八態樣,提供態樣7之方法,其中導管由陶瓷、玻璃陶瓷、玻璃、鉑、銥、鈀、銠或鎳製成。 According to an eighth aspect, the method of aspect 7, wherein the conduit is made of ceramic, glass ceramic, glass, platinum, rhodium, palladium, iridium or nickel.

根據第九態樣,提供態樣7或態樣8之方法,其中流體係空浮顆粒潔淨等級100級或更潔淨的氣體。 According to a ninth aspect, there is provided a method of aspect 7 or aspect 8, wherein the flow system air-floating particles are cleaned to a grade 100 or cleaner gas.

根據第十態樣,提供態樣7至態樣9之任何一個態樣的方法,該方法進一步包含以下步驟:在成形體之高度處輸送流體。 According to a tenth aspect, there is provided a method of any one of Aspect 7 to Aspect 9, the method further comprising the step of delivering a fluid at a height of the shaped body.

根據第十一態樣,提供態樣7至態樣10之任何一個態樣的方法,其中外殼係具有馬弗門的馬弗腔室,帶經由該馬弗門離開該馬弗腔室,且該方法進一步包含以下步 驟:在馬弗腔室內且在馬弗門外輸送流體。 According to an eleventh aspect, there is provided a method of any one of aspect 7 to aspect 10, wherein the outer casing has a muffle chamber of a muffled door, the belt exiting the muffle chamber via the muffle door, and The method further includes the following steps Step: Transfer fluid in the muffle chamber and outside the muffle door.

根據第十二態樣,提供態樣11的方法,其中馬弗門包括面向根部的前面板,其中前面板由具有高熱導率的材料製成,且該設備進一步包含馬弗門腔室,該馬弗門腔室設置在前面板之一側上,根部設置在與該側相對的前面板之側上。 According to a twelfth aspect, the method of aspect 11, wherein the muffle door comprises a front panel facing the root, wherein the front panel is made of a material having a high thermal conductivity, and the apparatus further comprises a muffle door chamber, The muffle door chamber is disposed on one side of the front panel, and the root is disposed on the side of the front panel opposite the side.

根據第十三態樣,提供下拉式玻璃製造設備,該設備包含:外殼;成形體,該成形體設置在該外殼內;入口管,該入口管經設置以輸送熔融玻璃至成形體;及導管,該導管具有出口,且該導管經設置以輸送流體至外殼,藉此可加壓外殼;及連接至導管的氣體源,其中氣體源經配置以輸送空浮顆粒潔淨等級100級或更潔淨的氣體。 According to a thirteenth aspect, a pull-down glass manufacturing apparatus is provided, the apparatus comprising: an outer casing; a shaped body disposed within the outer casing; an inlet pipe configured to convey molten glass to the formed body; and a conduit The conduit has an outlet, and the conduit is configured to deliver fluid to the outer casing, whereby the outer casing can be pressurized; and a source of gas coupled to the conduit, wherein the gas source is configured to deliver an empty particle cleanliness class 100 or cleaner gas.

根據第十四態樣,提供根據態樣13的設備,其中導管位於與成形體相同的高度處。 According to a fourteenth aspect, there is provided an apparatus according to aspect 13, wherein the conduit is located at the same height as the shaped body.

根據第十五態樣,提供根據態樣13或態樣14的設備,其中外殼係馬弗腔室,該馬弗腔室包括位於馬弗腔室底部之馬弗門,藉由成形體形成的玻璃經由該馬弗門離開馬弗腔室,其中導管之出口位於馬弗腔室內且位於馬弗門外。 According to a fifteenth aspect, there is provided apparatus according to aspect 13 or aspect 14, wherein the outer casing is a muffle chamber comprising a muffle door at the bottom of the muffle chamber formed by the shaped body The glass exits the muffle chamber via the Mavage door, with the outlet of the conduit located inside the muffle chamber and outside the Ma Fu door.

根據第十六態樣,提供製造玻璃段的方法,該方法包含以下步驟:在設置於外殼內之成形體的上方流動熔融玻璃,以使熔 融玻璃以帶之形式自該成形體向下流動;經由導管輸送流體至外殼以加壓外殼,其中流體係空浮顆粒潔淨等級100級或更潔淨的氣體;使帶流出外殼;及切割帶以形成玻璃段。 According to a sixteenth aspect, there is provided a method of manufacturing a glass segment, the method comprising the steps of: flowing a molten glass over a shaped body disposed within the outer casing to melt The molten glass flows downwardly from the shaped body in the form of a belt; the fluid is delivered to the outer casing via a conduit to pressurize the outer casing, wherein the flow system floats the particles to a level 100 or cleaner gas; the strip is discharged out of the outer casing; and the cutting belt is Form a glass segment.

根據第十七態樣,提供態樣16的方法,該方法進一步包含以下步驟:在成形體之高度處輸送流體。 According to a seventeenth aspect, the method of aspect 16 is provided, the method further comprising the step of delivering a fluid at a height of the shaped body.

根據第十八態樣,提供態樣16或態樣17的方法,其中外殼係具有馬弗門的馬弗腔室,帶經由該馬弗門離開該馬弗腔室,且該方法進一步包含以下步驟:在馬弗腔室內且在馬弗門外輸送流體。 According to an eighteenth aspect, a method of aspect 16 or aspect 17, wherein the outer casing has a muffle chamber of a muffled door, the belt exits the muffle chamber via the muffle, and the method further comprises the following Step: Transfer fluid in the muffle chamber and outside the muffle door.

4‧‧‧玻璃帶 4‧‧‧glass ribbon

6‧‧‧厚度 6‧‧‧ thickness

8‧‧‧玻璃片 8‧‧‧Stainless glass

10‧‧‧FDM 10‧‧‧FDM

12‧‧‧馬弗腔室 12‧‧‧Maff room

13‧‧‧箭頭 13‧‧‧ arrow

14‧‧‧下外殼 14‧‧‧ Lower casing

16‧‧‧下開口 16‧‧‧ opening

20‧‧‧馬弗門殼體 20‧‧‧Muffle door shell

22‧‧‧前面板 22‧‧‧ front panel

24‧‧‧馬弗門腔室 24‧‧‧Muffle door chamber

26‧‧‧管 26‧‧‧ tube

28‧‧‧流體源 28‧‧‧ Fluid source

30‧‧‧成形體 30‧‧‧Formed body

32‧‧‧收縮側 32‧‧‧ Contraction side

34‧‧‧根部 34‧‧‧ Root

36‧‧‧入口 36‧‧‧ Entrance

40‧‧‧導管 40‧‧‧ catheter

42‧‧‧出口 42‧‧‧Export

44‧‧‧流體源 44‧‧‧ Fluid source

100‧‧‧玻璃製造系統 100‧‧‧Glass manufacturing system

110‧‧‧熔融容器 110‧‧‧fusion vessel

112‧‧‧箭頭 112‧‧‧ arrow

115‧‧‧澄清容器 115‧‧‧Clarification container

120‧‧‧混合容器 120‧‧‧Mixed container

122‧‧‧連接管 122‧‧‧Connecting tube

125‧‧‧輸送容器 125‧‧‧Transport container

126‧‧‧熔融玻璃 126‧‧‧Solid glass

127‧‧‧連接管 127‧‧‧Connecting tube

130‧‧‧降流管 130‧‧‧ downflow tube

140‧‧‧牽拉輥組件 140‧‧‧Drawing roller assembly

第1圖係熔融拉製機的示意圖。 Figure 1 is a schematic view of a melt drawing machine.

第2圖係附著融合顆粒之數目與馬弗外殼中之壓力之間的關係的示意圖。 Figure 2 is a graphical representation of the relationship between the number of attached fused particles and the pressure in the muffle shell.

第3圖係厚度變化量與馬弗門中之壓力之間的關係的示意圖。 Fig. 3 is a schematic diagram showing the relationship between the amount of thickness variation and the pressure in the muffle.

第4圖係玻璃製造設備的示意圖。 Figure 4 is a schematic view of a glass manufacturing facility.

在下文詳細描述中,為說明之目的而非限制,闡述揭示具體細節的示例性實施例以提供對本發明之各個原則的透徹理解。然而,對於受益於本揭示案的一般技術者而言,將顯而易見的是,可在脫離本文所揭示之具體細節的其他實施例中實踐本發明。此外,可省略對熟知之裝置、方法及材 料的描述,以免混淆對本發明之各個原則的描述。最後,在任何適用的情形下,相同元件符號係指相同元件。 In the following detailed description, exemplary embodiments of the present invention However, it will be apparent to those skilled in the art that the present invention may be practiced in other embodiments. In addition, well-known devices, methods, and materials may be omitted. Description of the material in order to avoid obscuring the description of the various principles of the invention. Finally, in any applicable case, the same component symbols refer to the same components.

僅參照如所繪示之諸圖作出本文所使用的方向性術語(例如,上、下、右、左、前、後、頂、底),而不意欲暗示絕對定向。 The directional terminology (eg, up, down, right, left, front, back, top, bottom) as used herein is made with reference only to the figures as illustrated, and is not intended to imply an absolute orientation.

除非明確說明,否則決不意欲認為本文闡述之任何方法要求以特定順序執行該方法的步驟。因此,在方法請求項實際上不敘述該方法之步驟所遵循的順序或者在請求項或描述中不另外特別說明步驟局限於特定順序的情況下,決不意欲在任何方面推斷順序。此情況適用於任何可能的非明確性解釋基礎,該等基礎包括:關於步驟或操作流程之佈置的邏輯事項;來源於語法組織或標點的普通含義;說明書中所描述之實施例的數目或類型。 Unless expressly stated otherwise, it is not intended that any of the methods set forth herein require that the steps of the method be performed in a particular order. Thus, the order in which the method claims are not actually described in the steps of the method, or in the case of the claims or the description. This applies to any possible basis for non-clear interpretation, including: logical matters relating to the arrangement of steps or operational flows; common meanings derived from grammatical organization or punctuation; number or type of embodiments described in the specification .

如本文所使用,除非本文另有明確規定,否則單數形式「一」與「該」包括複數個指涉物。因此,例如,除非本文另有明確規定,否則對「組件」之提及包括具有二或更多個此類組件的態樣。 As used herein, the singular forms """ Thus, for example, reference to "a component" includes the aspect of having two or more such components unless the context clearly dictates otherwise.

本揭示案係關於用於在附著融合顆粒可能形成的點處在熔融拉製機(FDM)內形成乾淨的空氣環境的同時加壓的設備與方法,且該設備與方法提供用於獲得附著融合顆粒減少的穩健且可持續的方式。 The present disclosure relates to apparatus and methods for pressurizing while forming a clean air environment within a fusion draw machine (FDM) at points where adhesion of fused particles is likely to be formed, and the apparatus and method provide for obtaining adhesion fusion A robust and sustainable way to reduce particles.

在FDM中形成乾淨的空氣環境的一種方式涉及經由設備之氣體輸送,該設備本身不會產生將形成附著融合顆粒的顆粒。可藉由適當選擇用於製造導管之材料來完成此 舉,氣體經由該導管輸送至FDM以加壓FDM之區域。整個導管不必均由此材料製成,只要該導管之流體輸送內腔由此材料製成即可。本發明者已發現,由高熔點材料製成的導管在與富氮或富氧的流體源接觸時,在成形體附近上方於FDM中通常存在的溫度(例如,900℃至1300℃)下不會發生將導致顆粒產生的反應、降解或腐蝕,該導管非常適於輸送氣體而該導管本身不會產生導致附著融合顆粒的顆粒。舉例而言,導管可由陶瓷、玻璃陶瓷或玻璃製成。又,導管可由金屬製成,例如,鉑、銥、銠、鈀或鎳。 One way to create a clean air environment in an FDM involves gas delivery via the device, which itself does not produce particles that will form adherent fused particles. This can be done by appropriate selection of the material used to make the catheter The gas is delivered to the FDM via the conduit to pressurize the area of the FDM. The entire catheter need not be made of this material as long as the fluid delivery lumen of the catheter is made of this material. The present inventors have discovered that a conduit made of a high melting point material, when in contact with a nitrogen-rich or oxygen-rich fluid source, is not present in the vicinity of the shaped body at temperatures typically present in the FDM (e.g., 900 ° C to 1300 ° C). A reaction, degradation or corrosion that would result in the generation of particles would occur, the conduit being very suitable for transporting gas without the conduit itself producing particles that would cause adhesion of the fused particles. For example, the conduit can be made of ceramic, glass ceramic or glass. Also, the conduit can be made of a metal such as platinum, rhodium, ruthenium, palladium or nickel.

在FDM中形成乾淨的空氣環境的第二種方式涉及使用本身不包括導致附著融合顆粒之大量顆粒的氣體。本發明者已發現,符合如藉由名稱為「空浮顆粒潔淨等級(Airborne Particulate Cleanliness Classes)」之美國聯邦標準209E(可取自美國伊利諾斯州芒特普羅斯佩克特鎮60056西北公路東940號(940 East Northwest Highway,Mount Prospect,IL,60056,USA)的環境科學與技術研究所(Institute of Environmental Sciences and Technology))量測之空浮顆粒潔淨等級為100級(M3.5)或更潔淨之氣體適於增加FDM內的壓力,而該氣體本身不是導致附著融合顆粒之顆粒源。 A second way to create a clean air environment in FDM involves the use of a gas that does not itself include a large amount of particles that cause attachment of the fused particles. The inventors have discovered that it conforms to the US Federal Standard 209E by the name "Airborne Particulate Cleanliness Classes" (available from Northwest Highway 60056, Mount Prospekt, Illinois, USA). Airborne Particle Cleanliness Level 100 (M3.5) measured by the Institute of Environmental Sciences and Technology, 940 East Northwest Highway (Mount Prospect, IL, 60056, USA) A cleaner gas is suitable to increase the pressure within the FDM, which is not itself a source of particles that cause adhesion of the fused particles.

在FDM中形成乾淨的空氣環境的第三種方式涉及輸送至FDM的氣體所處的位置。更特定言之,本發明者已發現,在馬弗腔室中但在馬弗門外,在成形體的位準處輸送氣體至FDM導致低位準的附著融合顆粒。 A third way to create a clean air environment in the FDM involves the location of the gas delivered to the FDM. More specifically, the inventors have discovered that in the muffle chamber but outside the muffle, delivery of gas to the FDM at the level of the shaped body results in a low level of adherent fused particles.

將參照第1圖闡明包括乾淨的空氣環境之熔融拉 製機(FDM)的一個實施例。FDM 10包括上外殼或馬弗腔室12及下外殼14,玻璃帶4形成在該上外殼或馬弗腔室12中,經由該下外殼14拉製並熱調節玻璃帶4直到玻璃帶4在下開口16處離開FDM 10。隨後使用本領域中已知的技術將玻璃片8自帶4之下端分割。儘管片材8圖示為自帶4分割,但反而在玻璃片8自帶4之剩餘部分分割之前(例如,在捲繞玻璃時)可形成任何長度的帶4。因此,應瞭解僅為了方便參照而在說明書中使用「玻璃片」,且此術語亦可包括捲繞的玻璃段。 The fusion of the clean air environment will be explained with reference to Figure 1. An embodiment of a machine (FDM). The FDM 10 includes an upper casing or a muffle chamber 12 and a lower casing 14, in which the glass ribbon 4 is formed, through which the glass ribbon 4 is drawn and thermally adjusted until the glass ribbon 4 is under The FDM 10 exits the opening 16. The glass sheet 8 is then separated from the lower end of the strip 4 using techniques known in the art. Although the sheet 8 is illustrated as being self-contained in 4 divisions, the strip 4 of any length may be formed before the glass sheet 8 is separated from the remainder of the strip 4 (e.g., when the glass is wound). Therefore, it should be understood that the "glass sheet" is used in the specification for convenience of reference only, and the term may also include a wrapped glass segment.

馬弗腔室12環繞形成玻璃帶4的成形體30。成形體30自入口管36接收熔融玻璃。玻璃以兩股獨立流在成形體30之相對收縮側32上方流動,該兩股獨立流在成形體30之根部34處再結合以形成具有厚度6的玻璃帶4。 The muffle chamber 12 surrounds the formed body 30 forming the glass ribbon 4. The formed body 30 receives molten glass from the inlet pipe 36. The glass flows over the opposite contracting side 32 of the shaped body 30 in two separate streams which are recombined at the root 34 of the shaped body 30 to form a glass ribbon 4 having a thickness of 6.

一對馬弗門殼體20位於馬弗腔室12之底部,且該對馬弗門殼體20用於控制跨玻璃帶4(亦即,在進入及離開第1圖之平面的方向上)之厚度6的變化。在帶4之每一側上設置有一個馬弗門殼體20,藉以使馬弗門殼體20形成開口,玻璃帶4經由該開口延伸至下外殼14。各馬弗門殼體20具有相同的結構,且因此僅詳細描述一個馬弗門殼體20。類似地,可結合所圖示的馬弗門殼體20中之一者闡明各個原則,同時應理解彼等相同的原則可同樣應用於其他馬弗門殼體20。馬弗門殼體20經設置以面向成形體30,且在玻璃帶4具有高於玻璃帶4之軟化點的黏度時面向玻璃帶4。馬弗門殼體20包括前面板22、馬弗門腔室24及複數個管26。管26之每一者包括馬弗門腔室24內的一出口。 A pair of muffle door housings 20 are located at the bottom of the muffle chamber 12, and the pair of muffle door housings 20 are used to control the thickness across the glass ribbon 4 (i.e., in the direction of entering and exiting the plane of Figure 1). 6 changes. A muffle door housing 20 is provided on each side of the belt 4, whereby the muffle door housing 20 is formed with an opening through which the glass ribbon 4 extends to the lower outer casing 14. Each of the muffle door housings 20 has the same structure, and thus only one muffle door housing 20 will be described in detail. Similarly, the various principles can be illustrated in conjunction with one of the illustrated MacPherson housings 20, while it is understood that the same principles can be equally applied to other Mavage door housings 20. The muffle door housing 20 is disposed to face the formed body 30, and faces the glass ribbon 4 when the glass ribbon 4 has a viscosity higher than the softening point of the glass ribbon 4. The muffle door housing 20 includes a front panel 22, a muffle door chamber 24, and a plurality of tubes 26. Each of the tubes 26 includes an outlet within the muffle door chamber 24.

前面板22由在時間及溫度變化下具有恆定高導電率、低熱膨脹率及高發射率的材料形成。較佳地,前面板22由碳化矽平板形成,且前面板22之背表面除了劃界邊緣外不接觸可能引起平板之面上熱不連續的任何支承結構。 The front panel 22 is formed of a material having a constant high electrical conductivity, a low thermal expansion rate, and a high emissivity under time and temperature changes. Preferably, the front panel 22 is formed from a silicon carbide crucible, and the back surface of the front panel 22 does not contact any support structure that may cause thermal discontinuities on the face of the panel, except for the demarcated edges.

耦接流體源28以輸送流體至管26。儘管在成形體30之每一側上僅圖示一個管26,但是通常存在沿玻璃帶4之寬度方向設置的複數個管26;在成形體30之每一側上可使用任何適合數目的管26,其中該數目一般而言取決於玻璃帶4之寬度。流體可為例如空氣、壓縮空氣、任何其他適合的氣體。在整個說明書中,為方便而使用術語「空氣」或「空氣流」,但是該等術語意欲包括所有適合類型的氣體或其他流體。從流體源28經由管26將流體輸送進入馬弗門腔室24,以使流體衝擊在前面板22上並局部控制前面板22之溫度。前面板22上之定點的局部溫度隨後影響玻璃帶4之鄰近部分的溫度、因而影響玻璃帶4之鄰近部分的黏度及相應的厚度。可以此項技術中已知的方式個別地調節流經每一管26的流體的流量,以控制跨越帶4的厚度梯度。 Fluid source 28 is coupled to deliver fluid to tube 26. Although only one tube 26 is illustrated on each side of the shaped body 30, there are typically a plurality of tubes 26 disposed along the width of the glass ribbon 4; any suitable number of tubes can be used on each side of the shaped body 30. 26, wherein the number generally depends on the width of the glass ribbon 4. The fluid can be, for example, air, compressed air, any other suitable gas. Throughout the specification, the terms "air" or "air flow" are used for convenience, but such terms are intended to include all suitable types of gases or other fluids. Fluid is delivered from fluid source 28 via tube 26 into Marvel gate chamber 24 to cause fluid to impinge on front panel 22 and locally control the temperature of front panel 22. The local temperature at the fixed point on the front panel 22 then affects the temperature of the adjacent portion of the glass ribbon 4, thereby affecting the viscosity of the adjacent portions of the glass ribbon 4 and the corresponding thickness. The flow of fluid through each tube 26 can be individually adjusted in a manner known in the art to control the thickness gradient across the strip 4.

在下外殼14內,存在以向下的方向移動及/或導引玻璃帶4的各個結構,然為了圖解簡單化的目的未圖示此等結構。又,可能有存在於外殼14中用於在帶4移動穿過外殼14時熱調節帶4或控制帶4之熱損耗的各個其他結構。 In the lower casing 14, there are various structures for moving and/or guiding the glass ribbon 4 in the downward direction, but such structures are not illustrated for the purpose of simplification of illustration. Again, there may be various other structures present in the outer casing 14 for heat loss of the thermal conditioning belt 4 or the control belt 4 as the belt 4 moves through the outer casing 14.

在馬弗腔室12及下外殼14內,存在允許空氣自FDM 10洩漏的各個開口。此等開口可包括(例如,用於電連接、用於流體連接,用於進入及/或進出FDM 10內之設備、 用於水冷卻埠、用於電阻加熱器、用於供熱耦合使用之線圈繞組及/或用於管26的)所欲開口及/或不欲之裂縫或孔。即使在為經由所欲開口插入之裝置提供密封時,在密封處仍然可能存在允許流體流出FDM 10的漏隙。因為自FDM 10洩漏的空氣以及FDM 10本身內的熱梯度,所以存在以箭頭13的方向向上流動的流。此流拖拉空氣穿過底部開口16,並可能使空氣攜帶有來自FDM 10之外部區域或來自下外殼14內之顆粒產生源的顆粒。若顆粒向上行進穿過FDM 10至馬弗門殼體20之區域,則該等顆粒可能黏著至玻璃帶4或以其他方式嵌入到玻璃帶4內,藉此形成如上文闡明的附著融合顆粒。因而期望最小化FDM 10中的尤其是馬弗門殼體20之區域中的上升流。 Within the muffle chamber 12 and the lower outer casing 14, there are various openings that allow air to leak from the FDM 10. Such openings may include (eg, for electrical connections, for fluid connections, for accessing and/or accessing equipment within the FDM 10, For water cooling crucibles, for electric resistance heaters, coil windings for heat coupling use and/or for openings 26 and/or unwanted cracks or holes. Even when a seal is provided for the device inserted through the desired opening, there may still be a leak at the seal that allows fluid to flow out of the FDM 10. Because of the air leaking from the FDM 10 and the thermal gradient within the FDM 10 itself, there is a flow that flows upward in the direction of the arrow 13. This stream draws air through the bottom opening 16 and may cause the air to carry particles from the outer region of the FDM 10 or from the source of particulates within the lower outer casing 14. If the particles travel up through the FDM 10 to the area of the muffle door housing 20, the particles may adhere to the glass ribbon 4 or otherwise be embedded within the glass ribbon 4, thereby forming the adherent fused particles as set forth above. It is therefore desirable to minimize the upflow in the FDM 10, particularly in the region of the Marvel door housing 20.

最小化FDM 10中的尤其是馬弗門殼體20之區域中的流的一種方式係加壓馬弗腔室12。然而,僅加壓馬弗腔室12不足以減少附著融合顆粒。另外,應形成乾淨的空氣環境。可藉由適當選擇以下事物在馬弗腔室12內形成經加壓的乾淨空氣環境:設備,經由該設備輸送氣體以加壓馬弗腔室12;氣體本身的品質;及氣體輸送的位置,該設備、該品質及該位置之每一者影響減少附著融合顆粒的能力。 One way to minimize flow in the FDM 10, particularly in the region of the Mavage door housing 20, is to pressurize the muffle chamber 12. However, merely pressing the muffle chamber 12 is not sufficient to reduce the attachment of the fused particles. In addition, a clean air environment should be formed. A pressurized clean air environment can be formed within the muffle chamber 12 by appropriate selection of equipment through which gas is delivered to pressurize the muffle chamber 12; the quality of the gas itself; and the location of the gas delivery, Each of the device, the quality, and the location affects the ability to reduce the attachment of the fused particles.

在FDM中形成乾淨的空氣環境的一種方式涉及經由設備之氣體輸送,該設備本身不會產生將形成附著融合顆粒的顆粒。可藉由適當選擇用於製造導管之材料來完成此舉,將氣體經由該導管輸送至FDM以加壓FDM之區域。整個導管不必均由此材料製成,只要該導管之流體輸送內腔由 此材料製成即可。本發明者已發現,由高熔點材料製成的導管在與富氮或富氧的流體源接觸時,在成形體附近上方於FDM中通常存在的溫度(例如,900℃至1300℃)下不會發生將導致顆粒產生的反應、降解或腐蝕,該導管非常適於輸送氣體而該導管本身不會產生導致附著融合顆粒的顆粒。舉例而言,導管可由陶瓷、玻璃陶瓷或玻璃製成。又,導管可由金屬製成,例如,鉑、銥、銠、鈀或鎳。實際情況是,應選擇熔點高於FDM中最高的預計溫度之材料;但是此要求係最低的。另外,如上所述,經選擇的材料應為在與富氮或富氧的流體源接觸時不會反應、降解或腐蝕的一種材料,因為此類反應、降解或腐蝕將產生導致附著融合顆粒形成的顆粒。藉由使用本身不產生將形成附著融合顆粒之顆粒的導管,用於調節及/或過濾將被輸送之流體(以確保該流體不包括導致附著融合顆粒形成的顆粒)的設備可設置在FDM之高溫環境之外。此舉不但延長了設備壽命,而且此舉使在設備上執行維修服務更加容易。 One way to create a clean air environment in an FDM involves gas delivery via the device, which itself does not produce particles that will form adherent fused particles. This can be accomplished by appropriate selection of the material used to make the catheter, through which gas is delivered to the FDM to pressurize the area of the FDM. The entire catheter need not be made of this material as long as the fluid delivery lumen of the catheter is This material can be made. The present inventors have discovered that a conduit made of a high melting point material, when in contact with a nitrogen-rich or oxygen-rich fluid source, is not present in the vicinity of the shaped body at temperatures typically present in the FDM (e.g., 900 ° C to 1300 ° C). A reaction, degradation or corrosion that would result in the generation of particles would occur, the conduit being very suitable for transporting gas without the conduit itself producing particles that would cause adhesion of the fused particles. For example, the conduit can be made of ceramic, glass ceramic or glass. Also, the conduit can be made of a metal such as platinum, rhodium, ruthenium, palladium or nickel. The actual situation is that materials with a melting point higher than the highest expected temperature in the FDM should be chosen; however, this requirement is the lowest. Additionally, as noted above, the selected material should be a material that does not react, degrade, or corrode when contacted with a nitrogen-rich or oxygen-rich fluid source, as such reactions, degradation, or corrosion will result in the formation of adherent fused particles. particle. By using a conduit that does not itself produce particles that will form adherent fused particles, the device for conditioning and/or filtering the fluid to be delivered (to ensure that the fluid does not include particles that result in the formation of adherent fused particles) can be placed in the FDM Outside the high temperature environment. This not only extends equipment life, but it also makes it easier to perform maintenance services on the equipment.

參照第1圖,根據一個實施例,具有出口42的導管40延伸進入馬弗腔室12。導管40之另一端設置在FDM內之高溫環境之外。出口42設置在馬弗腔室12內以輸送來自流體源44的氣體。導管40可由(例如)陶瓷、玻璃陶瓷、玻璃、鉑、銥、銠、鈀或鎳製成。儘管在成形體30之每一側上僅圖示一個導管40,但是任何適合數目之此等導管可用於實現馬弗腔室12之所要加壓。導管40可設置在沿馬弗腔室12之寬度方向(垂直於第1圖之平面而延伸)的各個點處。 另外,導管40可設置在馬弗腔室之末端處,亦即,以在平行於馬弗腔室12之寬度的方向上延伸。輸送進馬弗腔室12的氣體加壓馬弗腔室12藉以降低箭頭13的方向上之上升流的影響,並據此降低上升流中的顆粒形成玻璃帶4上之附著融合顆粒的概率。此外,因為用於輸送加壓空氣的設備(亦即,導管40)由本身不會產生形成附著融合顆粒之顆粒的材料製成,所以在馬弗腔室12內形成乾淨的空氣環境。 Referring to Figure 1, a catheter 40 having an outlet 42 extends into the muffle chamber 12, according to one embodiment. The other end of the conduit 40 is disposed outside of the high temperature environment within the FDM. An outlet 42 is disposed within the muffle chamber 12 to deliver gas from the fluid source 44. The conduit 40 can be made of, for example, ceramic, glass ceramic, glass, platinum, rhodium, ruthenium, palladium or nickel. Although only one conduit 40 is illustrated on each side of the shaped body 30, any suitable number of such conduits can be used to effect the desired pressurization of the muffle chamber 12. The duct 40 may be disposed at various points along the width direction of the muffle chamber 12 (extending perpendicular to the plane of Fig. 1). Additionally, the conduit 40 can be disposed at the end of the muffle chamber, that is, in a direction parallel to the width of the muffle chamber 12. The gas pressurized into the muffle chamber 12 pressurizes the muffle chamber 12 to reduce the effect of the upward flow in the direction of the arrow 13 and thereby reduce the probability of particles in the ascending flow forming the fused particles on the glass ribbon 4. In addition, since the apparatus for delivering pressurized air (i.e., the conduit 40) is made of a material that does not itself form particles that adhere to the fused particles, a clean air environment is formed within the muffle chamber 12.

在FDM中形成乾淨的空氣環境的第二種方式涉及用本身不包括導致附著融合顆粒之大量顆粒的氣體加壓FDM。本發明者已發現,符合如藉由美國聯邦標準209E量測之空浮顆粒潔淨等級為100級(M3.5)或更潔淨之氣體適於增加FDM內的壓力,而該氣體本身不是導致附著融合顆粒的顆粒源。流體源44經配置以輸送所述潔淨度(亦即,具有100級(M3.5)或更潔淨之空氣潔淨等級)的氣體至導管40。流體源44可為(例如)空氣壓縮機、泵、風扇、增壓器或其他空氣處理設備,該流體源44在流體源44之出口處具有足夠程度之高效顆粒吸引(HEPA)過濾,以輸送所述潔淨度的氣體。或者,若適合潔淨度的氣體係可容易取得的,則流體源44不必包括在流體源44之出口的過濾裝置。儘管流體源44圖示為連接至僅一個導管40,但是一個此流體源44可連接至儘可能實用的許多個導管40以輸送所要量的加壓氣體至馬弗腔室12。舉例而言,一個流體源44可連接至成形體30之兩側上的導管40。此外,儘管流體源44圖示為與流體源28分隔,但是此情況不必如此。亦即,流體源44可連接至導管40與 管26兩者。 A second way to form a clean air environment in FDM involves pressurizing the FDM with a gas that does not itself include a large amount of particles that cause attachment of the fused particles. The present inventors have discovered that a gas that meets the cleanliness rating of Class 100 (M3.5) or cleaner, as measured by US Federal Standard 209E, is suitable for increasing the pressure within the FDM, which gas itself does not cause adhesion. A source of particles that fuse the particles. The fluid source 44 is configured to deliver the cleanliness (i.e., a gas having a Class 100 (M3.5) or cleaner air clean rating) to the conduit 40. Fluid source 44 can be, for example, an air compressor, pump, fan, supercharger, or other air treatment device having a sufficient degree of high efficiency particle attraction (HEPA) filtration at the outlet of fluid source 44 for delivery. The cleanliness of the gas. Alternatively, fluid source 44 need not include a filtration device at the outlet of fluid source 44 if a gas system suitable for cleanliness is readily available. Although fluid source 44 is illustrated as being coupled to only one conduit 40, one such fluid source 44 can be coupled to a plurality of conduits 40 that are as practical as possible to deliver a desired amount of pressurized gas to the muffle chamber 12. For example, a fluid source 44 can be coupled to the conduit 40 on either side of the shaped body 30. Moreover, although fluid source 44 is illustrated as being separated from fluid source 28, this need not be the case. That is, the fluid source 44 can be coupled to the conduit 40 and Both tubes 26 are.

在FDM中形成乾淨的空氣環境的第三種方式涉及輸送至FDM的加壓氣體所處的位置。更特定言之,本發明者已發現,在馬弗腔室中但在馬弗門腔室外面,在靠近與成形體相同的高度處輸送氣體至FDM導致低位準的附著融合顆粒。 A third way to create a clean air environment in the FDM involves the location of the pressurized gas delivered to the FDM. More specifically, the inventors have discovered that transporting gas to the FDM near the same height as the shaped body in the muffle chamber but outside the muffle chamber results in a low level of adherent fused particles.

根據形成乾淨的空氣環境之第三種方式的一個態樣,參照第1圖,設置導管40以使出口42定位在FDM 10內,大體上與成形體30相同之高度處。亦即,成形體30設置在FDM 10內,在下開口16上方的高度處。在成形體30之高度處供應空氣增加靠近根部34及側部32的壓力,藉以在顆粒可形成玻璃表面上之附著融合顆粒的點處最小化達到玻璃的顆粒的量。 According to one aspect of the third way of forming a clean air environment, referring to Fig. 1, a conduit 40 is provided to position the outlet 42 within the FDM 10, substantially at the same height as the shaped body 30. That is, the formed body 30 is disposed within the FDM 10 at a height above the lower opening 16. The supply of air at the height of the shaped body 30 increases the pressure near the root 34 and the side 32, thereby minimizing the amount of particles reaching the glass at the point where the particles can form a fused particle on the glass surface.

根據形成乾淨的空氣環境之第三種方式的另一態樣,再次參照第1圖,出口42設置在馬弗腔室12內,而在馬弗門腔室24外。 According to another aspect of the third way of forming a clean air environment, referring again to Figure 1, the outlet 42 is disposed within the muffle chamber 12 and outside of the muffle door chamber 24.

供應空氣進入馬弗門腔室24以求加壓馬弗腔室12係非期望的。特定言之,隨著在馬弗門殼體20中空氣的總容積增加,馬弗腔室12中的壓力增加,此舉促進降低附著融合顆粒位準,如第2圖所示意性圖示。然而,供應進馬弗門殼體20中的額外空氣導致馬弗門腔室24中的壓力增加,藉以空氣以不受控的方式洩漏向玻璃帶4,造成局部化的厚度變化,如第3圖所示意性圖示。亦即,在馬弗門殼體20內(亦即,馬弗門腔室24內)的壓力用於增加馬弗腔室12內的總 壓力時,厚度變化受到負面影響。另一方面,在主動排空馬弗門腔室24以防止空氣向帶4洩漏時,觀察到附著融合顆粒位準的增加。因而,為了增加馬弗腔室12內的壓力(以減少附著融合顆粒)而不增加馬弗門殼體20內部的壓力(此增加導致不期望的厚度變化),可在馬弗腔室12內而在馬弗門腔室24外供應空氣。另外,此位置(在馬弗腔室內而在馬弗門殼體外)最小化對馬弗內之其他氣流單元的影響。 Supplying air into the muffle door chamber 24 to pressurize the muffle chamber 12 is undesirable. In particular, as the total volume of air in the muffle door housing 20 increases, the pressure in the muffle chamber 12 increases, which promotes a reduction in the level of adherent fused particles, as schematically illustrated in FIG. However, the additional air supplied into the muffle door housing 20 causes the pressure in the muffle door chamber 24 to increase, whereby air leaks into the glass ribbon 4 in an uncontrolled manner, resulting in localized thickness variations, such as the third The figure shows the schematic diagram. That is, the pressure within the muffle door housing 20 (i.e., within the muffle door chamber 24) is used to increase the total within the muffle chamber 12. Thickness changes are negatively affected by pressure. On the other hand, an increase in the level of the attached fused particles is observed when the muffle door chamber 24 is actively emptied to prevent air from leaking into the belt 4. Thus, in order to increase the pressure within the muffle chamber 12 (to reduce adhesion of the fused particles) without increasing the pressure inside the muffle door housing 20 (this increase results in undesirable thickness variations), it may be within the muffle chamber 12 Air is supplied outside the muffle door chamber 24. In addition, this position (outside the muffle door housing in the muffle chamber) minimizes the effects on other airflow units in the muffle.

為了逆向適應現有的FDM以實踐本文描述之概念,厚度控制所不需要的現有管26可用於根據上述概念協助減少附著融合顆粒。特定言之,管26可自該等管26之起始位置縮回使得該等管26的出口在馬弗門腔室24外部,但仍在馬弗腔室12內。隨後,可將來自源28的流體輸送至馬弗腔室12以增加馬弗腔室12中的壓力。另外,不使用來自源28的流體,流體源44(亦即,輸送100級或更潔淨之空浮顆粒潔淨等級之空氣的一個流體源)可連接至此等現有管26,此等管26已經使此等管26本身的出口在馬弗門腔室24外但仍在馬弗腔室12內。用此佈置,具有100級或更潔淨之空浮顆粒潔淨等級的空氣可被輸送至馬弗腔室12。因此,現有管26可用於協助產生FDM 10內乾淨的環境。 In order to retrofit existing FDMs to practice the concepts described herein, existing tubes 26 that are not required for thickness control can be used to assist in reducing adherent fusion particles in accordance with the above concepts. In particular, the tubes 26 can be retracted from the starting position of the tubes 26 such that the outlets of the tubes 26 are external to the Mavage chamber 24, but are still within the muffle chamber 12. The fluid from source 28 can then be delivered to the muffle chamber 12 to increase the pressure in the muffle chamber 12. Additionally, without the use of fluid from source 28, fluid source 44 (i.e., a fluid source that delivers 100 grade or cleaner airborne particulate clean grade air) can be coupled to such existing tubes 26, such tubes 26 have The outlets of these tubes 26 themselves are outside the muffle door chamber 24 but are still within the muffle chamber 12. With this arrangement, air having a clean grade of airborne particles of level 100 or cleaner can be delivered to the muffle chamber 12. Thus, the existing tube 26 can be used to assist in creating a clean environment within the FDM 10.

現將描述使用本文描述之概念製造玻璃片8的方法。 A method of making a glass sheet 8 using the concepts described herein will now be described.

第4圖圖示使用熔融製程的示例性玻璃製造系統100,且在該示例性玻璃製造系統100中,上述概念可用於製造玻璃片8。玻璃製造系統包括熔融容器110、澄清容器115 (例如,澄清管)、混合容器120(例如,攪拌腔室)、輸送容器125(例如,碗腔)及FDM 10。將玻璃材料如箭頭112所圖示引入到熔融容器110中並熔融該玻璃材料以形成熔融玻璃126。澄清容器115包括自熔融容器110接收熔融玻璃126的高溫處理區域(此處未圖示),並在該高溫處理區域中,自熔融玻璃126移除氣泡。藉由連接管122將澄清容器115連接至混合容器120。藉由連接管127將混合容器120連接至輸送容器125。輸送容器125輸送熔融玻璃126經由降流管130進入FDM 10,該FDM 10包括入口36、成形體30及牽拉輥組件140。熔融玻璃自降流管130流動進入入口36,該入口36導向成形體30。成形體30包括接收熔融玻璃126的凹槽,該熔融玻璃126隨後溢出並沿成形體30之兩側32往下流,隨後在根部34熔合在一起。根部34係兩側32結合在一起處,且在該根部34處兩股溢流或熔融玻璃126之壁再結合(例如,再熔合)以形成玻璃帶4,該玻璃帶4藉由牽拉輥組件140向下拉製。FDM 10之細節如上文結合第1圖所闡明。應注意,儘管描述示例性玻璃製造系統的某些細節,但是成形體及玻璃製造系統係本領域中已知的,且一般技術者可容易地選擇適當的成形體及/或玻璃製造系統。 FIG. 4 illustrates an exemplary glass manufacturing system 100 using a melt process, and in the exemplary glass manufacturing system 100, the above concepts can be used to fabricate a glass sheet 8. The glass manufacturing system includes a melting vessel 110 and a clarification vessel 115 (eg, a clarification tube), a mixing vessel 120 (eg, a mixing chamber), a delivery vessel 125 (eg, a bowl cavity), and an FDM 10. A glass material is introduced into the melting vessel 110 as illustrated by arrow 112 and the glass material is melted to form molten glass 126. The clarification vessel 115 includes a high temperature treatment zone (not shown) that receives the molten glass 126 from the smelting vessel 110, and in the high temperature treatment zone, bubbles are removed from the molten glass 126. The clarification vessel 115 is connected to the mixing vessel 120 by a connecting pipe 122. The mixing container 120 is connected to the conveying container 125 by a connecting pipe 127. The delivery container 125 transports the molten glass 126 into the FDM 10 via a downcomer 130 that includes an inlet 36, a shaped body 30, and a pulling roll assembly 140. The molten glass flows from the downflow tube 130 into the inlet 36, which is directed to the shaped body 30. The shaped body 30 includes a recess that receives the molten glass 126, which then overflows and flows down the sides 32 of the formed body 30, and then fuses together at the root 34. The root portion 34 is joined at both sides 32, and at the root portion 34 the two overflow or walls of the molten glass 126 are recombined (e.g., refused) to form a glass ribbon 4 by means of a pulling roller Component 140 is pulled down. The details of FDM 10 are as set forth above in connection with Figure 1. It should be noted that while certain details of an exemplary glass manufacturing system are described, shaped bodies and glass manufacturing systems are known in the art, and one of ordinary skill in the art can readily select suitable shaped bodies and/or glass making systems.

回頭參照第1圖,隨著將熔融玻璃輸送至成形體30,藉由適當地加壓FDM 10內的區域以降低顆粒到達玻璃之該等顆粒可能形成附著融合顆粒的點處的概率來形成FDM 10內乾淨的空氣環境。特定言之,可單獨使用或以任一或所有組合使用以下概念的任何一或更多者,以產生FDM內的此 乾淨的空氣環境:可經由導管40將氣體輸送至FDM 10以加壓FDM 10,該導管40由低顆粒發射材料(亦即,在與富氮的或富氧的流體源接觸時,在成形體附近於FDM中通常存在的溫度(900℃至1300℃)下不反應、降解或腐蝕的一種材料)(例如,陶瓷、玻璃陶瓷、玻璃、鉑、銥、銠、鈀或鎳)製成;可在與成形體30相同的高度處將氣體輸送至FDM 10以加壓FDM 10;可將氣體輸送至馬弗腔室12,但在馬弗門外殼24外,以加壓FDM 10;且輸送至FMD 10的氣體可具有100級或更潔淨之空浮顆粒潔淨等級。 Referring back to Figure 1, as the molten glass is delivered to the shaped body 30, FDM is formed by appropriately pressurizing the regions within the FDM 10 to reduce the probability that the particles reaching the glass may form points at which the fused particles are attached. 10 clean air environment. In particular, any one or more of the following concepts may be used alone or in any or all combinations to produce this within the FDM Clean air environment: Gas can be delivered to FDM 10 via conduit 40 to pressurize FDM 10 from a low particulate emissive material (i.e., in contact with a nitrogen-rich or oxygen-rich fluid source) Made of a material (such as ceramic, glass ceramic, glass, platinum, rhodium, ruthenium, palladium or nickel) that is not reactive, degraded or corroded at temperatures (900 ° C to 1300 ° C) that are usually present in FDM; Gas is delivered to the FDM 10 at the same height as the shaped body 30 to pressurize the FDM 10; gas can be delivered to the muffle chamber 12, but outside the muffle door outer casing 24, to pressurize the FDM 10; The FMD 10 gas can have a class 100 or cleaner airborne particle cleanliness rating.

應強調的是,本發明之上述實施例,特別是任何「較佳」實施例僅是實施之可能的實例,僅為了對本發明之各個原則的清晰理解而闡述該等實施例。在實質上不脫離本發明之精神及各個原則的情況下,可對本發明之上述實施例作出許多變化及修改。所有此類修改及變化意欲被包括在本文中,於本揭示案及本發明的範疇內,並受下文申請專利範圍書的保護。 It should be emphasized that the above-described embodiments of the present invention, and in particular, the preferred embodiments of the present invention are only possible examples of the embodiments of the present invention. Many variations and modifications of the above-described embodiments of the invention are possible without departing from the spirit and scope of the invention. All such modifications and variations are intended to be included herein, within the scope of the present disclosure and the scope of the invention, and

舉例而言,儘管依據熔融拉製作出以上描述,但是狹縫拉製成形體亦可用作成形體30。 For example, although the above description has been made in accordance with the fusion drawing, the slit-drawn body can also be used as the formed body 30.

4‧‧‧玻璃帶 4‧‧‧glass ribbon

6‧‧‧厚度 6‧‧‧ thickness

8‧‧‧玻璃片 8‧‧‧Stainless glass

10‧‧‧FDM 10‧‧‧FDM

12‧‧‧馬弗腔室 12‧‧‧Maff room

13‧‧‧箭頭 13‧‧‧ arrow

14‧‧‧下外殼 14‧‧‧ Lower casing

16‧‧‧下開口 16‧‧‧ opening

20‧‧‧馬弗門殼體 20‧‧‧Muffle door shell

22‧‧‧前面板 22‧‧‧ front panel

24‧‧‧馬弗門腔室 24‧‧‧Muffle door chamber

26‧‧‧管 26‧‧‧ tube

28‧‧‧流體源 28‧‧‧ Fluid source

30‧‧‧成形體 30‧‧‧Formed body

32‧‧‧收縮側 32‧‧‧ Contraction side

34‧‧‧根部 34‧‧‧ Root

36‧‧‧入口 36‧‧‧ Entrance

40‧‧‧導管 40‧‧‧ catheter

42‧‧‧出口 42‧‧‧Export

44‧‧‧流體源 44‧‧‧ Fluid source

Claims (12)

一種下拉式玻璃製造設備,包含:一外殼;一成形體,該成形體設置在該外殼內;一入口管,該入口管經設置以輸送熔融玻璃至該成形體;及一導管,該導管具有一出口且該導管經設置以輸送流體至該外殼,藉此可加壓該外殼,其中該導管由一材料製成,該材料在與富氮的流體源或富氧的流體源接觸時,在900℃至1300℃之範圍內的溫度下不反應、降解或腐蝕。 A pull-down glass manufacturing apparatus comprising: a casing; a forming body disposed in the casing; an inlet pipe disposed to convey molten glass to the forming body; and a conduit having An outlet and the conduit is configured to deliver fluid to the outer casing whereby the outer casing can be pressurized, wherein the conduit is made of a material that is in contact with a nitrogen-rich fluid source or an oxygen-rich fluid source Does not react, degrade or corrode at temperatures in the range of 900 ° C to 1300 ° C. 一種下拉式玻璃製造設備,包含:一外殼;一成形體,該成形體設置在該外殼內;一入口管,該入口管經設置以輸送熔融玻璃至該成形體;及一導管,該導管具有一出口且該導管經設置以輸送流體至該外殼,藉此可加壓該外殼;及一氣體源,該氣體源連接至該導管,其中該氣體源經配置以輸送一空浮顆粒潔淨等級(airborne particulate cleanliness class)100級或更潔淨的氣體。 A pull-down glass manufacturing apparatus comprising: a casing; a forming body disposed in the casing; an inlet pipe disposed to convey molten glass to the forming body; and a conduit having An outlet and the conduit is configured to deliver fluid to the outer casing, whereby the outer casing can be pressurized; and a gas source coupled to the conduit, wherein the gas source is configured to deliver an airborne particulate cleanliness level (airborne Particulate cleanliness class) Class 100 or cleaner gas. 如請求項1所述之設備,其中該導管由陶瓷、玻璃陶瓷、 玻璃、鉑、銥、銠、鈀或鎳製成。 The device of claim 1, wherein the conduit is made of ceramic, glass ceramic, Made of glass, platinum, rhodium, ruthenium, palladium or nickel. 如請求項1或請求項3所述之設備,進一步包含一氣體源,該氣體源連接至該導管,其中該氣體源經配置以輸送一空浮顆粒潔淨等級100級或更潔淨的氣體。 The apparatus of claim 1 or claim 3, further comprising a gas source coupled to the conduit, wherein the gas source is configured to deliver an airborne particulate clean grade 100 or cleaner gas. 如請求項1或請求項2所述之設備,其中該導管位於與該成形體相同的高度處。 The apparatus of claim 1 or claim 2, wherein the conduit is located at the same height as the shaped body. 如請求項1或請求項2所述之設備,其中該外殼係一馬弗腔室(muffle chamber),該馬弗腔室包括一馬弗門,該馬弗門位在該馬弗腔室之一底部,藉由該成形體形成的玻璃經由該馬弗門離開該馬弗腔室,其中該導管之該出口位於該馬弗腔室內且位於該馬弗門外。 The apparatus of claim 1 or claim 2, wherein the outer casing is a muffle chamber, the muffle chamber including a muffle door, the muffle door being located in the muffle chamber At the bottom, the glass formed by the shaped body exits the muffle chamber via the muffle door, wherein the outlet of the conduit is located within the muffle chamber and outside the muffle door. 一種製造一玻璃段的方法,包含以下步驟:在設置於一外殼內之一成形體的上方流動熔融玻璃,以使熔融玻璃以一帶之形式自該成形體向下流動;經由一導管輸送流體至該外殼以加壓該外殼,其中該導管由一材料製成,該材料在與富氮的流體源或富氧的流體源接觸時,在900℃至1300℃之範圍內的溫度下不反應、降解或腐蝕;使該帶流出該外殼;及切割該帶以形成一玻璃段。 A method of making a glass segment, comprising the steps of: flowing molten glass over a shaped body disposed within a housing such that molten glass flows downwardly from the shaped body in a strip; the fluid is delivered via a conduit to The outer casing pressurizes the outer casing, wherein the conduit is made of a material that does not react at temperatures in the range of 900 ° C to 1300 ° C when in contact with a nitrogen-rich fluid source or an oxygen-rich fluid source, Degrading or corroding; causing the strip to flow out of the outer casing; and cutting the strip to form a glass segment. 一種製造一玻璃段的方法,包含以下步驟:在設置於一外殼內之一成形體的上方流動熔融玻璃,以使熔融玻璃以一帶之形式自該成形體向下流動;經由一導管輸送流體至該外殼以加壓該外殼,其中該流體係一空浮顆粒潔淨等級100級或更潔淨的氣體;使該帶流出該外殼;及切割該帶以形成一玻璃段。 A method of making a glass segment, comprising the steps of: flowing molten glass over a shaped body disposed within a housing such that molten glass flows downwardly from the shaped body in a strip; the fluid is delivered via a conduit to The outer casing pressurizes the outer casing, wherein the flow system cleans the gas of class 100 or cleaner by air-dried particles; causes the strip to flow out of the outer casing; and cuts the strip to form a glass segment. 如請求項7所述之方法,其中該導管由陶瓷、玻璃陶瓷、玻璃、鉑、銥、銠、鈀或鎳製成。 The method of claim 7, wherein the conduit is made of ceramic, glass ceramic, glass, platinum, rhodium, ruthenium, palladium or nickel. 如請求項7或請求項9所述之方法,其中該流體係一空浮顆粒潔淨等級100級或更潔淨的氣體。 The method of claim 7 or claim 9, wherein the flow system is a floating particle cleansing class 100 or cleaner gas. 如請求項7或請求項8所述之方法,進一步包含以下步驟:在該成形體之高度處輸送該流體。 The method of claim 7 or claim 8, further comprising the step of delivering the fluid at a height of the shaped body. 如請求項7或請求項8所述之方法,其中該外殼係一馬弗腔室,該馬弗腔室具有一馬弗門,該帶經由該馬弗門離開該馬弗腔室,且該方法進一步包含以下步驟:在該馬弗腔室內且在該馬弗門外輸送該流體。 The method of claim 7 or claim 8, wherein the outer casing is a muffle chamber, the muffle chamber having a muffle door, the belt leaving the muffle chamber via the muffle door, and the The method further includes the step of delivering the fluid within the muffle chamber and outside the muffle.
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