TWI556455B - Solar cell, module comprising the same and method of manufacturing the same - Google Patents

Solar cell, module comprising the same and method of manufacturing the same Download PDF

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TWI556455B
TWI556455B TW103107211A TW103107211A TWI556455B TW I556455 B TWI556455 B TW I556455B TW 103107211 A TW103107211 A TW 103107211A TW 103107211 A TW103107211 A TW 103107211A TW I556455 B TWI556455 B TW I556455B
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line pattern
pattern portion
conductive layer
solid line
solar cell
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TW103107211A
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TW201535754A (en
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賴政豪
柳彥志
張冠綸
陳哲宏
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茂迪股份有限公司
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

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Description

太陽能電池、其模組及其製造方法 Solar battery, module thereof and manufacturing method thereof

本發明是有關於一種太陽能電池、其模組及其製造方法,特別是指一種矽晶太陽能電池、其模組及其製造方法。 The invention relates to a solar cell, a module thereof and a manufacturing method thereof, in particular to a twinned solar cell, a module thereof and a manufacturing method thereof.

參閱圖1,已知的矽晶太陽能電池主要包含:一用於將光能轉換成電能的電池本體91,以及用於傳導電流的一正面電極92與一背面電極(圖未示)。其中,該正面電極92包括數個呈長條形的匯流電極(Bus Bar Electrode)921,以及數個橫向連接該匯流電極921的指狀電極(Finger Electrode)922。該數個指狀電極922主要用於收集電流,而該數個匯流電極921可於模組封裝時分別與一圖未示的焊帶導線(Ribbon)焊接,以將指狀電極922收集到的電流傳送到外部,因此匯流電極921的寬度通常較寬。 Referring to Fig. 1, a known twinned solar cell mainly comprises: a battery body 91 for converting light energy into electrical energy, and a front electrode 92 and a back electrode (not shown) for conducting current. The front electrode 92 includes a plurality of elongated bus electrodes (921) and a plurality of finger electrodes 922 that are laterally connected to the bus electrodes 921. The plurality of finger electrodes 922 are mainly used for collecting current, and the plurality of bus electrodes 921 can be respectively soldered to a ribbon (Ribbon) not shown in the module package to collect the finger electrodes 922. The current is transmitted to the outside, so the width of the bus electrode 921 is usually wide.

該匯流電極921與該數個指狀電極922在製造上,可透過網版印刷方式將導電漿料塗布於該電池本體91的受光面,並經過高溫燒結(Firing)使導電漿料固化而成型。但隨著導電漿料(例如含銀之漿料)的價格不斷升高, 並且因為匯流電極921的寬度較寬、漿料用量大,造成電池的生產成本高。為了節省材料成本,目前有一種作法是使用導電率較低、成本較低的導電漿料來製成該數個匯流電極921,但如此會造成指狀電極922與該數個匯流電極921連接處的電流收集效果變差。 The bus electrode 921 and the plurality of finger electrodes 922 are manufactured by applying a conductive paste to a light-receiving surface of the battery body 91 by screen printing, and curing the conductive paste by high-temperature sintering (Firing). . But as the price of conductive pastes (such as silver-containing slurries) continues to rise, Moreover, since the width of the bus electrode 921 is wide and the amount of the slurry is large, the production cost of the battery is high. In order to save material cost, there is currently a method of forming the plurality of bus electrodes 921 using a conductive paste having a lower conductivity and a lower cost, but this causes the finger electrodes 922 to be connected to the plurality of bus electrodes 921. The current collection effect is worse.

此外,網版進行多次網印後容易有漿料塞網問題,造成網印形成的該數個匯流電極921兩側邊緣容易因印刷不均勻而出現孔洞,如此會影響傳導電流效果與焊接結合力。為了避免上述問題,網版使用一段時間後就必須擦拭以去除沾附在其上的漿料,而網版多次擦拭則會造成生產速度下降。 In addition, after the screen printing is performed multiple times, it is easy to have a slurry plugging problem, and the edges of the plurality of bus electrodes 921 formed by the screen printing are easily caused by uneven printing, which affects the conduction current effect and the welding. force. In order to avoid the above problem, the screen must be wiped to remove the slurry adhered thereto after a period of use, and the screen is repeatedly wiped to cause a decrease in production speed.

因此,本發明之目的,即在提供一種結構創新、可降低生產成本與提升生產效率,並可兼顧電流收集效能的太陽能電池、其模組及其製造方法。 Accordingly, it is an object of the present invention to provide a solar cell, a module thereof, and a method of fabricating the same that is structurally innovative, can reduce production costs, and improve production efficiency, and can take into account current collection efficiency.

於是,本發明太陽能電池的製造方法,包含:準備一基板,該基板具有相對之一第一表面與一第二表面。形成一第一電極與一第二電極並分別位於該第一表面上與該第二表面上。其中,形成該第一電極的步驟包括:以網印方式形成一第一導電層於該第一表面上,該第一導電層具有數個沿一第一方向延伸的指狀部、一沿一不同於該第一方向的第二方向延伸的第一實線圖案部,以及一沿該第二方向延伸的第一虛線圖案部;再以網印方式形成一第二導電層於該第一導電層與該第一表面上,該第二導電層 的材料異於該第一導電層,且該第二導電層具有一沿該第二方向延伸的匯流部,該匯流部重疊於該第一虛線圖案部且接觸該第一實線圖案部。 Thus, a method of fabricating a solar cell of the present invention comprises: preparing a substrate having a first surface and a second surface. Forming a first electrode and a second electrode and respectively on the first surface and the second surface. The step of forming the first electrode includes: forming a first conductive layer on the first surface by screen printing, the first conductive layer having a plurality of fingers extending along a first direction, and a a first solid line pattern portion extending in a second direction different from the first direction, and a first dotted line pattern portion extending along the second direction; forming a second conductive layer on the first conductive layer by screen printing a layer and the first surface, the second conductive layer The material is different from the first conductive layer, and the second conductive layer has a bus portion extending in the second direction, the bus portion overlapping the first dotted pattern portion and contacting the first solid line pattern portion.

本發明太陽能電池,包含:一具有相對之一第一表面與一第二表面的基板,以及分別位於該第一表面上與該第二表面上的一第一電極與一第二電極。其中,該第一電極包括一第一導電層與一第二導電層。該第一導電層具有數個沿一第一方向延伸的指狀部、一沿一不同於該第一方向的第二方向延伸的第一實線圖案部,以及一沿該第二方向延伸的第一虛線圖案部。該第二導電層位於該第一導電層上且材料異於該第一導電層,該第二導電層具有一沿該第二方向延伸的匯流部,該匯流部重疊於該第一虛線圖案部且接觸該第一實線圖案部。 The solar cell of the present invention comprises: a substrate having a first surface and a second surface, and a first electrode and a second electrode on the first surface and the second surface, respectively. The first electrode includes a first conductive layer and a second conductive layer. The first conductive layer has a plurality of fingers extending along a first direction, a first solid line pattern extending along a second direction different from the first direction, and a second extending along the second direction The first dotted line pattern portion. The second conductive layer is located on the first conductive layer and is different from the first conductive layer. The second conductive layer has a confluent portion extending in the second direction, and the confluent portion is overlapped with the first dashed pattern portion. And contacting the first solid line pattern portion.

本發明太陽能電池模組,包含:相對設置的一第一板材與一第二板材、數個如上述且排列於該第一板材與該第二板材之間的太陽能電池,及一封裝材。該封裝材位於該第一板材與該第二板材之間,並包覆在該數個太陽能電池的周圍。 The solar cell module of the present invention comprises: a first plate and a second plate disposed oppositely, a plurality of solar cells as described above and arranged between the first plate and the second plate, and a package. The encapsulant is located between the first plate and the second plate and is wrapped around the plurality of solar cells.

本發明之功效:藉由網印形成的該第一導電層具有第一實線圖案部與第一虛線圖案部,使後續再以網印形成的該第二導電層的匯流部可重疊於第一虛線圖案部,並且接觸第一實線圖案部。再配合該第二導電層的材料異於該第一導電層,使本發明之電池結構創新、電流收集效能佳,並能降低生產成本與提升生產效率。 The effect of the present invention: the first conductive layer formed by screen printing has a first solid line pattern portion and a first dotted line pattern portion, so that the confluent portion of the second conductive layer formed by subsequent screen printing can overlap a dotted pattern portion and contacting the first solid line pattern portion. The material of the second conductive layer is different from the first conductive layer, so that the battery structure of the invention is innovative, current collecting efficiency is good, and the production cost and the production efficiency can be reduced.

11‧‧‧第一板材 11‧‧‧ first plate

12‧‧‧第二板材 12‧‧‧Second plate

13‧‧‧封裝材 13‧‧‧Package

14‧‧‧焊帶導線 14‧‧‧welding wire

2‧‧‧太陽能電池 2‧‧‧Solar battery

21‧‧‧基板 21‧‧‧Substrate

211‧‧‧第一表面 211‧‧‧ first surface

212‧‧‧第二表面 212‧‧‧ second surface

213‧‧‧射極層 213‧‧ ‧ emitter layer

214‧‧‧抗反射層 214‧‧‧Anti-reflective layer

22‧‧‧第一電極 22‧‧‧First electrode

23‧‧‧第二電極 23‧‧‧second electrode

24‧‧‧第一導電層 24‧‧‧First conductive layer

25‧‧‧第二導電層 25‧‧‧Second conductive layer

251‧‧‧匯流部 251‧‧ ‧ Confluence Department

252‧‧‧側邊 252‧‧‧ side

26‧‧‧指狀部 26‧‧‧ finger

27‧‧‧電極圖案組 27‧‧‧Electrode pattern group

271‧‧‧第一實線圖案部 271‧‧‧The first solid line pattern department

272‧‧‧第二實線圖案部 272‧‧‧Second solid line pattern department

273‧‧‧第一虛線圖案部 273‧‧‧First dotted line pattern

274‧‧‧第二虛線圖案部 274‧‧‧second dotted line

275‧‧‧第一圖案單元 275‧‧‧First pattern unit

276‧‧‧第二圖案單元 276‧‧‧second pattern unit

277‧‧‧短邊 277‧‧‧ Short side

278‧‧‧短邊 278‧‧‧ Short side

31‧‧‧第一方向 31‧‧‧First direction

32‧‧‧第二方向 32‧‧‧second direction

41、42、43、431、432‧‧‧步驟 41, 42, 43, 431, 432‧ ‧ steps

50‧‧‧第一網版 50‧‧‧First Screen

5‧‧‧第一阻擋層 5‧‧‧First barrier

51‧‧‧指狀開口 51‧‧‧ finger openings

52‧‧‧開口圖案單元 52‧‧‧Open pattern unit

521‧‧‧第一實線開口 521‧‧‧First solid line opening

522‧‧‧第二實線開口 522‧‧‧Second solid opening

523‧‧‧第一開口組 523‧‧‧First opening group

524‧‧‧第二開口組 524‧‧‧Second opening group

525‧‧‧第一子開口 525‧‧‧ first child opening

526‧‧‧第二子開口 526‧‧‧Second sub-opening

60‧‧‧第二網版 60‧‧‧ Second Screen

6‧‧‧第二阻擋層 6‧‧‧second barrier

61‧‧‧匯流開口 61‧‧‧ confluence opening

本發明之其他的特徵及功效,將於參照圖式的實施方式中清楚地呈現,其中:圖1是一種已知太陽能電池的俯視示意圖;圖2是本發明太陽能電池模組之一第一較佳實施例的局部剖視示意圖;圖3是該第一較佳實施例的一太陽能電池的俯視示意圖;圖4是圖3的局部放大圖,且圖4將一匯流部以假想線示意以清楚顯示該匯流部下方的一第一導電層,圖中該匯流部以斜線區域示意,該第一導電層以點狀區域示意;圖5是沿圖3之A-A線所取的剖視圖;圖6是本發明太陽能電池的製造方法之一第一較佳實施例的步驟流程圖;圖7是該製造方法之第一較佳實施例各步驟進行時的示意圖;圖8是一第一網版的一第一阻擋層的示意圖,該第一網版用於網印形成本發明該太陽能電池的第一導電層;圖9是一第二網版的一第二阻擋層的示意圖,該第二網版用於網印形成本發明該太陽能電池的一第二導電層;圖10是本發明太陽能電池模組之一第二較佳實施例的一太陽能電池的局部俯視示意圖,且圖10將一匯流部以假想線示意以清楚顯示該匯流部下方的一第一導電層;及圖11是本發明太陽能電池模組之一第三較佳實施例的 一太陽能電池的局部俯視示意圖,且圖11將一匯流部以假想線示意以清楚顯示該匯流部下方的一第一導電層。 Other features and effects of the present invention will be apparent from the following description of the drawings, wherein: FIG. 1 is a top view of a known solar cell; FIG. 2 is a first comparison of the solar cell module of the present invention. Figure 3 is a top plan view of a solar cell of the first preferred embodiment; Figure 4 is a partial enlarged view of Figure 3, and Figure 4 shows a confluence with an imaginary line to clear A first conductive layer is disposed under the confluence portion, wherein the confluent portion is indicated by a hatched area, the first conductive layer is indicated by a dotted region; FIG. 5 is a cross-sectional view taken along line AA of FIG. 3; The flow chart of the first preferred embodiment of the method for manufacturing a solar cell of the present invention; FIG. 7 is a schematic view of the steps of the first preferred embodiment of the manufacturing method; FIG. 8 is a first screen version Schematic diagram of a first barrier layer for screen printing to form a first conductive layer of the solar cell of the present invention; FIG. 9 is a schematic diagram of a second barrier layer of a second screen, the second screen Used for screen printing to form the sun of the present invention a second conductive layer of the battery; FIG. 10 is a partial top plan view of a solar cell according to a second preferred embodiment of the solar cell module of the present invention, and FIG. 10 shows a confluence portion on an imaginary line to clearly show the confluence a first conductive layer under the portion; and FIG. 11 is a third preferred embodiment of the solar cell module of the present invention A partial top view of a solar cell, and FIG. 11 shows a confluence with an imaginary line to clearly show a first conductive layer below the confluence.

在本發明被詳細描述之前,應當注意在以下的說明內容中,類似的元件是以相同的編號來表示。 Before the present invention is described in detail, it should be noted that in the following description, similar elements are denoted by the same reference numerals.

參閱圖2,本發明太陽能電池模組之一第一較佳實施例包含:上下相對設置的一第一板材11與一第二板材12、數個陣列式排列於該第一板材11與該第二板材12間的太陽能電池2、至少一位於該第一板材11及該第二板材12間並包覆在該數個太陽能電池2周圍的封裝材13,以及數條用於串接該數個太陽能電池2的焊帶導線(Ribbon)14。 Referring to FIG. 2, a first preferred embodiment of the solar cell module of the present invention comprises: a first plate 11 and a second plate 12 disposed opposite each other, and a plurality of arrays arranged on the first plate 11 and the first a solar cell 2 of two sheets 12, at least one package 13 between the first plate 11 and the second plate 12 and wrapped around the plurality of solar cells 2, and a plurality of strips for serially connecting the plurality of A ribbon 14 of the solar cell 2.

該第一板材11與該第二板材12在實施上沒有特殊限制,可以使用玻璃或塑膠板材,而且位於電池受光面的一側的板材必須為可透光;若為雙面受光電池,則該第一板材11與該第二板材12都必須可透光。該封裝材13的材質例如可透光的乙烯醋酸乙烯共聚物(EVA),或其他可用於太陽能電池模組封裝的相關材料。 The first plate 11 and the second plate 12 are not particularly limited in implementation, and a glass or plastic plate may be used, and the plate on one side of the light receiving surface of the battery must be permeable; if it is a double-sided light receiving battery, Both the first sheet 11 and the second sheet 12 must be permeable to light. The material of the package material 13 is, for example, a light transmissive ethylene vinyl acetate copolymer (EVA), or other related materials that can be used for solar cell module packaging.

該數個太陽能電池2的結構都相同,以下僅以其中一個為例而進行說明。但在同一模組中的數個電池不以結構相同為必要。 The structures of the plurality of solar cells 2 are the same, and only one of them will be described below as an example. However, it is necessary that several batteries in the same module are not identical in structure.

參閱圖3、4、5,該太陽能電池2包含:一基板21、一第一電極22,以及一第二電極23。 Referring to FIGS. 3, 4, and 5, the solar cell 2 includes a substrate 21, a first electrode 22, and a second electrode 23.

該基板21具有相對之一第一表面211與一第二 表面212。本實施例之第一表面211為受光面,該第二表面212為背面,若應用於雙面入光電池時,該第二表面212亦可受光。本實施例在該第一表面211處的內側設有一射極層213。該射極層213上,亦即該第一表面211上還可選擇性地設置一抗反射層214。其中,該基板21例如半導體矽基板,且該基板21與該射極層213的其中一個為n型半導體,另一個為p型半導體,進而形成p-n接面,使該基板21可吸收光能並轉換成電能。該抗反射層214的材料例如氮化矽,可用於降低光反射以提高入光量。 The substrate 21 has a first surface 211 and a second Surface 212. The first surface 211 of the embodiment is a light receiving surface, and the second surface 212 is a back surface. When applied to a double-sided light-emitting battery, the second surface 212 can also receive light. In this embodiment, an emitter layer 213 is disposed on the inner side of the first surface 211. An anti-reflection layer 214 may also be selectively disposed on the first surface 211 of the emitter layer 213. The substrate 21 is, for example, a semiconductor germanium substrate, and one of the substrate 21 and the emitter layer 213 is an n-type semiconductor, and the other is a p-type semiconductor, thereby forming a pn junction, so that the substrate 21 can absorb light energy. Converted to electrical energy. The material of the anti-reflective layer 214, such as tantalum nitride, can be used to reduce light reflection to increase the amount of light incident.

該第一電極22位於該基板21的第一表面211上,並包括一第一導電層24與一第二導電層25。該第一導電層24具有數個沿一第一方向31延伸的指狀部26,以及數個沿該第一方向31間隔排列的電極圖案組27。 The first electrode 22 is located on the first surface 211 of the substrate 21 and includes a first conductive layer 24 and a second conductive layer 25. The first conductive layer 24 has a plurality of fingers 26 extending along a first direction 31 and a plurality of electrode pattern groups 27 spaced along the first direction 31.

每一電極圖案組27具有沿該第一方向31間隔排列的一第一實線圖案部271與一第二實線圖案部272,以及位於該第一實線圖案部271與第二實線圖案部272之間的一第一虛線圖案部273與一第二虛線圖案部274。該第一實線圖案部271與該第二實線圖案部272皆為長條直線狀,並且皆沿一不同於該第一方向31的第二方向32延伸。在本實施例中,該第一方向31垂直該第二方向32。該第一虛線圖案部273與該第二虛線圖案部274沿該第一方向31間隔排列,且兩者皆沿該第二方向32延伸呈長條虛線狀。 Each of the electrode pattern groups 27 has a first solid line pattern portion 271 and a second solid line pattern portion 272 arranged at intervals along the first direction 31, and the first solid line pattern portion 271 and the second solid line pattern. A first dotted line pattern portion 273 and a second broken line pattern portion 274 between the portions 272. The first solid line pattern portion 271 and the second solid line pattern portion 272 are both long linear and extend in a second direction 32 different from the first direction 31. In the present embodiment, the first direction 31 is perpendicular to the second direction 32. The first dotted line pattern portion 273 and the second dotted line pattern portion 274 are spaced apart along the first direction 31, and both extend in the second direction 32 in a long dotted line shape.

其中,該第一虛線圖案部273具有數個與該第 一實線圖案部271間隔且沿該第二方向32間隔排列的第一圖案單元275。該第二虛線圖案部274的設計與該第一虛線圖案部273相同,並具有數個與該第二實線圖案部272間隔且沿該第二方向32間隔排列的第二圖案單元276。本實施例的每一第一圖案單元275與每一第二圖案單元276大致為長方形;但實施時不需限定其形狀。 Wherein, the first dotted line pattern portion 273 has a plurality of A solid pattern portion 271 is spaced apart and spaced apart in the second direction 32 by the first pattern unit 275. The second dotted line pattern portion 274 is identical in design to the first broken line pattern portion 273 and has a plurality of second pattern units 276 spaced apart from the second solid line pattern portion 272 and spaced apart along the second direction 32. Each of the first pattern units 275 and each of the second pattern units 276 of the embodiment is substantially rectangular; however, the shape thereof is not limited in implementation.

該數個指狀部26彼此間沿該第二方向32平行間隔排列,每一指狀部26連接該數個電極圖案組27,也連接該第二導電層25。 The plurality of fingers 26 are arranged in parallel with each other along the second direction 32. Each of the fingers 26 connects the plurality of electrode pattern groups 27 and also connects the second conductive layer 25.

該第二導電層25位於該第一導電層24上且材料異於該第一導電層24。該第二導電層25受到該抗反射層214間隔而與該第一表面211隔開。該第二導電層25具有數個沿該第一方向31間隔排列且皆沿該第二方向32延伸的匯流部251,每一匯流部251具有二個間隔且沿該第二方向32延伸的側邊252。而本實施例的每一指狀部26連接該數個匯流部251。 The second conductive layer 25 is located on the first conductive layer 24 and is different in material from the first conductive layer 24. The second conductive layer 25 is spaced apart from the first surface 211 by the anti-reflective layer 214. The second conductive layer 25 has a plurality of confluences 251 arranged along the first direction 31 and extending along the second direction 32. Each of the confluences 251 has two spaces extending along the second direction 32. Side 252. Each of the fingers 26 of the embodiment is connected to the plurality of confluences 251.

該數個匯流部251皆為長條狀,並分別對應該數個電極圖案組27而設置。該數個匯流部251的寬度大於該數個指狀部26的寬度,也大於第一實線圖案部271與第二實線圖案部272的寬度。在本實施例中,每一匯流部251重疊於與其對應的該電極圖案組27的該第一虛線圖案部273與第二虛線圖案部274,且接觸該第一實線圖案部271與該第二實線圖案部272。所述匯流部251接觸該第一實線圖案部271,可以是指匯流部251與第一實線圖案部 271重疊,或者是匯流部251僅以其側邊252與該第一實線圖案部271相接。所述重疊可以是指匯流部251將該第一實線圖案部271完全覆蓋住或僅局部覆蓋。而匯流部251接觸該第二實線圖案部272的方式,亦可如同上述各種方式,可為重疊或側邊相接。 The plurality of busbars 251 are each elongated and are provided corresponding to the plurality of electrode pattern groups 27, respectively. The width of the plurality of bus bars 251 is larger than the width of the plurality of finger portions 26 and larger than the width of the first solid line pattern portion 271 and the second solid line pattern portion 272. In the present embodiment, each of the bus bars 251 is overlapped with the first dotted line pattern portion 273 and the second broken line pattern portion 274 of the electrode pattern group 27 corresponding thereto, and is in contact with the first solid line pattern portion 271 and the first Two solid line pattern portions 272. The bus bar 251 is in contact with the first solid line pattern portion 271, and may be referred to as a bus bar portion 251 and a first solid line pattern portion. 271 is overlapped, or the bus bar 251 is in contact with the first solid line pattern portion 271 only by its side 252. The overlap may mean that the bus bar 251 completely covers or only partially covers the first solid line pattern portion 271. The manner in which the bus bar portion 251 contacts the second solid line pattern portion 272 may be overlapped or side-contacted as in the above various modes.

該第二電極23位於該基板21的第二表面212上,用於與該第一電極22配合將電池的電能輸出至外部。 The second electrode 23 is located on the second surface 212 of the substrate 21 for cooperating with the first electrode 22 to output electrical energy of the battery to the outside.

參閱圖4、6、7,本發明太陽能電池的製造方法之一第一較佳實施例,包含:步驟41:準備該基板21,該基板21具有相對之該第一表面211與該第二表面212。利用擴散製程或其他摻雜方式於該第一表面211形成該射極層213,以使該基板21形成半導體p-n接面。 Referring to Figures 4, 6, and 7, a first preferred embodiment of the method for fabricating a solar cell of the present invention comprises: Step 41: preparing the substrate 21, the substrate 21 having the first surface 211 and the second surface opposite thereto 212. The emitter layer 213 is formed on the first surface 211 by a diffusion process or other doping method to form the substrate 21 to form a semiconductor p-n junction.

步驟42:利用例如真空鍍膜方式,形成該抗反射層214於該第一表面211上。該真空鍍膜方式可包含物理氣相沉積(PVD)、化學氣相沉積(CVD)等方式。 Step 42: Form the anti-reflective layer 214 on the first surface 211 by, for example, vacuum coating. The vacuum coating method may include physical vapor deposition (PVD), chemical vapor deposition (CVD), and the like.

步驟43:形成該第一電極22與該第二電極23並分別位於該第一表面211上與該第二表面212上。參閱圖6、7、8、9,形成該第一電極22的步驟包括:(1)步驟431:先以網印方式形成該第一導電層24於該第一表面211上,本步驟主要是搭配一第一網版50進行,將用於形成該第一導電層24的導電漿料塗布在該第一表面211上,此時該第一導電層24位於該抗反射層214表面(如圖7的第三道流程),接著經過烘烤使該第一導電層24初步乾燥。(2) 步驟432:再以網印方式形成該第二導電層25於該第一導電層24與該第一表面211上,本步驟主要是搭配一第二網版60進行,將用於形成該第二導電層25的導電漿料塗布在該第一表面211上,並位於該第一導電層24上(如圖7的第四道流程)。接著同樣可利用網印方式形成該第二電極23於該第二表面212上(如圖7的第五道流程)。最後經過高溫燒結(Firing)使導電漿料乾燥固化,即可形成該第一導電層24、該第二導電層25與該第二電極23,且燒結過程中該第一導電層24可燒穿該抗反射層214,燒結後該第一導電層24即穿過該抗反射層214而接觸該射極層213。 Step 43: The first electrode 22 and the second electrode 23 are formed on the first surface 211 and the second surface 212, respectively. Referring to FIGS. 6, 7, 8, and 9, the step of forming the first electrode 22 includes: (1) Step 431: first forming the first conductive layer 24 on the first surface 211 by screen printing. This step is mainly The conductive paste for forming the first conductive layer 24 is coated on the first surface 211, and the first conductive layer 24 is located on the surface of the anti-reflective layer 214 (as shown in FIG. The third process of 7) is followed by baking to preliminarily dry the first conductive layer 24. (2) Step 432: The second conductive layer 25 is formed on the first conductive layer 24 and the first surface 211 by screen printing. This step is mainly performed with a second screen 60, which will be used to form the second layer. A conductive paste of the conductive layer 25 is coated on the first surface 211 and located on the first conductive layer 24 (as in the fourth flow of FIG. 7). The second electrode 23 can then be formed on the second surface 212 by screen printing (as in the fifth flow of FIG. 7). Finally, the first conductive layer 24, the second conductive layer 25 and the second electrode 23 are formed by high-temperature sintering (Firing) to dry and solidify the conductive paste, and the first conductive layer 24 can be burned through during sintering. The anti-reflective layer 214, after sintering, passes through the anti-reflective layer 214 to contact the emitter layer 213.

需要說明的是,本發明該第一電極22與第二電極23的網印順序不須限制,因為也可以先網印該第二電極23後再網印該第一電極22,最後再一起燒結。此外,該第二電極23實際上也包括至少一個呈長條狀的匯流部,只是圖中未示意出。 It should be noted that the screen printing sequence of the first electrode 22 and the second electrode 23 of the present invention need not be limited, because the second electrode 23 can be screen printed first, then the first electrode 22 is screen printed, and finally sintered together. . Further, the second electrode 23 actually includes at least one elongated bus bar, which is not shown in the drawings.

接著具體說明該第一網版50與第二網版60的構造。參閱圖4、7、8,該第一網版50包括一圖未示出的第一網布,以及一結合在該第一網布上的第一阻擋層5。該第一阻擋層5包括數個沿該第一方向31延伸的指狀開口51,以及數個沿該第一方向31間隔排列的開口圖案單元52,每一開口圖案單元52包括沿該第一方向31間隔排列且皆沿該第二方向32延伸的一第一實線開口521與一第二實線開口522,以及位於該第一實線開口521與第二實線開口522之間的一第一開口組523與一第二開口組524,該 第一開口組523與該第二開口組524分別鄰近但未接觸該第一實線開口521與該第二實線開口522。該第一開口組523具有數個沿該第二方向32間隔排列的第一子開口525,該第二開口組524具有數個沿該第二方向32間隔排列的第二子開口526。 Next, the configuration of the first halftone 50 and the second halftone 60 will be specifically described. Referring to Figures 4, 7, and 8, the first screen 50 includes a first web, not shown, and a first barrier layer 5 bonded to the first web. The first barrier layer 5 includes a plurality of finger openings 51 extending along the first direction 31, and a plurality of opening pattern units 52 spaced along the first direction 31. Each of the opening pattern units 52 includes along the first a first solid line opening 521 and a second solid line opening 522 extending in the direction 31 and extending along the second direction 32, and a first between the first solid line opening 521 and the second solid line opening 522 a first opening group 523 and a second opening group 524, The first opening group 523 and the second opening group 524 are respectively adjacent to but not contacting the first solid line opening 521 and the second solid line opening 522. The first opening group 523 has a plurality of first sub-openings 525 spaced along the second direction 32. The second opening group 524 has a plurality of second sub-openings 526 spaced along the second direction 32.

該第一阻擋層5的開口圖案與預定形成的第一導電層24圖案對應,因此利用該第一網版50進行網印時,通過該數個第一實線開口521與第二實線開口522的導電漿料,即對應地於該基板21的第一表面211上形成該數個第一實線圖案部271與第二實線圖案部272;通過第一開口組523與第二開口組524的導電漿料,則分別對應地形成該第一虛線圖案部273與第二虛線圖案部274,且本實施例的第一虛線圖案部273與該第一實線圖案部271間隔而不相連,第二虛線圖案部274與該第二實線圖案部272間隔而不相連;通過該數個指狀開口51的導電漿料,對應地形成該數個指狀部26。 The opening pattern of the first barrier layer 5 corresponds to the pattern of the first conductive layer 24 to be formed. Therefore, when the first screen 50 is used for screen printing, the first solid line opening 521 and the second solid line opening are opened. The conductive paste of 522, that is, the plurality of first solid line pattern portions 271 and the second solid line pattern portion 272 are formed on the first surface 211 of the substrate 21; through the first opening group 523 and the second opening group The conductive paste of 524 is correspondingly formed with the first dotted line pattern portion 273 and the second broken line pattern portion 274, respectively, and the first broken line pattern portion 273 of the embodiment is spaced apart from the first solid line pattern portion 271 without being connected. The second dotted line pattern portion 274 is spaced apart from the second solid line pattern portion 272 and is not connected; the plurality of finger portions 26 are correspondingly formed by the conductive paste of the plurality of finger openings 51.

參閱圖4、7、9,該第二網版60包括一圖未示出的第二網布,以及一結合在該第二網布上的第二阻擋層6。該第二阻擋層6包括數個沿該第二方向32延伸呈直線狀的匯流開口61。該第二阻擋層6的開口圖案與預定形成的第二導電層25圖案對應,因此利用該第二網版60進行網印時,通過該數個匯流開口61的導電漿料,即對應地於該第一導電層24上形成該第二導電層25的該數個匯流部251,且該數個匯流部251會重疊於該第一虛線圖案部273 與第二虛線圖案部274上,並且接觸該第一實線圖案部271與第二實線圖案部272。 Referring to Figures 4, 7, and 9, the second screen 60 includes a second web, not shown, and a second barrier layer 6 bonded to the second web. The second barrier layer 6 includes a plurality of confluence openings 61 extending linearly in the second direction 32. The opening pattern of the second barrier layer 6 corresponds to the pattern of the second conductive layer 25 to be formed. Therefore, when the second screen 60 is used for screen printing, the conductive paste passing through the plurality of bus openings 61 is correspondingly The plurality of confluent portions 251 of the second conductive layer 25 are formed on the first conductive layer 24, and the plurality of confluent portions 251 are overlapped with the first dotted pattern portion 273. And the second dotted line pattern portion 274 is in contact with the first solid line pattern portion 271 and the second solid line pattern portion 272.

而且透過適當的網版開口圖案設計,可使網印形成的每一匯流部251之大部分位於與其對應的該第一實線圖案部271及該第二實線圖案部272之間。此定義主要是指匯流部251整體大致保持在該兩實線圖案部271、272間或重疊於上,但並不排除匯流部251可能有局部位於該兩實線圖案部271、272之外(且該局部不與實線圖案部271、272重疊),此時該匯流部251位於該兩實線圖案部271、272之外的部位的面積總和,小於該兩實線圖案部271、272的面積總和。 Moreover, most of each of the confluent portions 251 formed by the screen printing can be located between the first solid line pattern portion 271 and the second solid line pattern portion 272 corresponding thereto by an appropriate screen opening pattern design. This definition mainly means that the confluence portion 251 is substantially maintained between the two solid line pattern portions 271 and 272 or overlapped thereon, but it is not excluded that the confluence portion 251 may be partially located outside the two solid line pattern portions 271 and 272 ( And the portion does not overlap with the solid line pattern portions 271 and 272. At this time, the total area of the portion of the bus bar portion 251 located outside the two solid line pattern portions 271 and 272 is smaller than the two solid line pattern portions 271 and 272. The sum of the areas.

參閱圖7、8、9,補充說明,本實施例可藉由選用適當的導電漿料,使該第一導電層24能在高溫燒結製程中燒穿(Firing Through)該抗反射層214而連接該第一表面211,又或者,可先於該抗反射層214之預定形成該第一導電層24的部位進行開孔製程,此時該第一導電層24的導電漿料不限於使用可燒穿該抗反射層214之漿料,即可使該第一導電層24穿過該抗反射層214而連接該第一表面211。而該抗反射層214則將該第一表面211與該第二導電層25隔開。 Referring to FIGS. 7, 8, and 9, in addition, the first conductive layer 24 can be connected to the anti-reflective layer 214 by a suitable high-temperature sintering process by selecting an appropriate conductive paste. The first surface 211 may be subjected to an opening process prior to the portion of the anti-reflective layer 214 where the first conductive layer 24 is formed. The conductive paste of the first conductive layer 24 is not limited to being burnable. The first conductive layer 24 is passed through the anti-reflective layer 214 to connect the first surface 211 by the slurry of the anti-reflective layer 214. The anti-reflective layer 214 separates the first surface 211 from the second conductive layer 25.

本發明實施時,每一電極圖案組27也可以省略設置該第二實線圖案部272與第二虛線圖案部274。而本實施例的太陽能電池2的匯流部251的數量為三個,但實施時也可以為一個或其他數量。該第一網版50的第一阻擋 層5與第二網版60的第二阻擋層6的開口圖案,則視欲形成的電極圖案而設計。 In the implementation of the present invention, each of the electrode pattern groups 27 may also omit the second solid line pattern portion 272 and the second dotted line pattern portion 274. However, the number of the confluent portions 251 of the solar cell 2 of the present embodiment is three, but it may be one or other quantities when implemented. The first block of the first screen 50 The opening pattern of the second barrier layer 6 of the layer 5 and the second screen 60 is designed according to the electrode pattern to be formed.

參閱圖4、5、8,由於本發明該第一電極22的第一導電層24與第二導電層25分成兩次網印,因此可以使用不同材料網印成型。其中因為該第一導電層24的指狀部26用於收集電流,故可以使用導電率較佳之漿料,而該第二導電層25的匯流部251則可以使用導電率較低之漿料,以降低材料成本。當然,該第一導電層24與第二導電層25的材料選用,也可以因其他考量而有數種不同搭配方式。該數個第一實線圖案部271與第二實線圖案部272分別設置於該數個匯流部251的兩側,可幫助收集電流,從而提升各匯流部251與指狀部26連接部位的電流收集效果,而且匯流部251接觸第一實線圖案部271與第二實線圖案部272,使其表面外觀上大致形成一體。另外,藉由第一網版50的第一開口組523與第二開口組524設計,可讓導電漿料通過,以形成該第一虛線圖案部273與第二虛線圖案部274,如此使後續形成的匯流部251可重疊於第一虛線圖案部273與第二虛線圖案部274上,尤其是匯流部251之兩長側邊處可與第一虛線圖案部273與第二虛線圖案部274重疊,從而可避免以往因網版塞網而造成網印出的匯流電極有側邊孔洞之問題。因此,本發明藉由匯流部251、第一虛線圖案部273與第二虛線圖案部274的整體配合,可避免匯流部251產生孔洞之問題,本發明之製法進行時,可降低擦拭網版之次數,如此可提升生產效率。 Referring to Figures 4, 5, and 8, the first conductive layer 24 and the second conductive layer 25 of the first electrode 22 of the present invention are divided into two screen printings, so that different materials can be used for screen printing. Because the finger portion 26 of the first conductive layer 24 is used for collecting current, a slurry having a better conductivity can be used, and the bus portion 251 of the second conductive layer 25 can use a slurry having a lower conductivity. To reduce material costs. Of course, the materials of the first conductive layer 24 and the second conductive layer 25 are selected, and there may be several different matching manners due to other considerations. The plurality of first solid line pattern portions 271 and the second solid line pattern portion 272 are respectively disposed on both sides of the plurality of confluence portions 251 to help collect currents, thereby improving the connection portions of the confluent portions 251 and the fingers 26 The current collecting effect is achieved, and the bus bar portion 251 contacts the first solid line pattern portion 271 and the second solid line pattern portion 272 so that the surface thereof is substantially integrally formed. In addition, by designing the first opening group 523 and the second opening group 524 of the first screen 50, the conductive paste can be passed to form the first dotted line pattern portion 273 and the second broken line pattern portion 274, thus enabling subsequent The formed confluence portion 251 may overlap the first dotted line pattern portion 273 and the second broken line pattern portion 274, and in particular, the two long sides of the confluence portion 251 may overlap with the first dotted line pattern portion 273 and the second broken line pattern portion 274 Therefore, it is possible to avoid the problem that the bus electrodes printed on the screen have side holes in the past due to the screen sewn. Therefore, according to the present invention, the integration of the first flow line portion 251, the first broken line pattern portion 273, and the second broken line pattern portion 274 can avoid the problem of holes in the bus portion 251. When the method of the present invention is performed, the wiping screen can be reduced. The number of times, which can increase production efficiency.

綜上所述,藉由網印形成該第一導電層24,且該第一導電層24具有第一實線圖案部271與第一虛線圖案部273,使後續再以網印形成的該第二導電層25的匯流部251可重疊於第一虛線圖案部273且接觸第一實線圖案部271,再配合該第二導電層25的材料異於該第一導電層24,使本發明之電池結構創新、電流收集效能佳,並能降低生產成本與提升生產效率。 In summary, the first conductive layer 24 is formed by screen printing, and the first conductive layer 24 has a first solid line pattern portion 271 and a first broken line pattern portion 273, so that the first The confluent portion 251 of the two conductive layers 25 may overlap the first dotted line pattern portion 273 and contact the first solid line pattern portion 271, and the material of the second conductive layer 25 is different from the first conductive layer 24, so that the present invention The battery structure is innovative, the current collection efficiency is good, and the production cost can be reduced and the production efficiency can be improved.

參閱圖10,本發明太陽能電池模組之一第二較佳實施例,與該第一較佳實施例大致相同,不同的地方在於第一虛線圖案部273與第二虛線圖案部274的結構。本實施例的每一第一虛線圖案部273具有數個與該第一實線圖案部271相連的第一圖案單元275,該數個第一圖案單元275皆為沿該第一方向31延伸的長方形,所述每一第一圖案單元275以該長方形的一短邊277(圖中以虛線示意其中一第一圖案單元275的該短邊277)連接該第一實線圖案部271。類似地,本實施例的每一第二虛線圖案部274具有數個與該第二實線圖案部272相連的第二圖案單元276,該數個第二圖案單元276皆為沿該第一方向31延伸的長方形,所述每一第二圖案單元276以該長方形的一短邊277(圖中以虛線示意其中一第二圖案單元276的該短邊277)連接該第二實線圖案部272。 Referring to FIG. 10, a second preferred embodiment of the solar cell module of the present invention is substantially the same as the first preferred embodiment except for the structure of the first dotted line pattern portion 273 and the second broken line pattern portion 274. Each of the first dotted line patterns 273 of the embodiment has a plurality of first pattern units 275 connected to the first solid line pattern portion 271 , and the plurality of first pattern units 275 are all extending along the first direction 31 . Each of the first pattern units 275 is connected to the first solid line pattern portion 271 by a short side 277 of the rectangle (the short side 277 of one of the first pattern units 275 is indicated by a broken line in the figure). Similarly, each second dotted line pattern portion 274 of the embodiment has a plurality of second pattern units 276 connected to the second solid line pattern portion 272, and the plurality of second pattern units 276 are along the first direction. 31 extending rectangles, each of the second pattern units 276 connecting the second solid line pattern portion 272 with a short side 277 of the rectangle (the short side 277 of one of the second pattern units 276 is indicated by a broken line in the figure). .

本實施例的製造方法與該第一較佳實施例相同,只是必須使用不同開口圖案的第一網版,以網印形成本實施例之第一導電層24圖案。 The manufacturing method of this embodiment is the same as that of the first preferred embodiment except that the first screen of different opening patterns must be used to form the pattern of the first conductive layer 24 of the present embodiment by screen printing.

補充說明的是,實施時,第一圖案單元275也可以與該第一實線圖案部271間隔;第二圖案單元276也可以與該第二實線圖案部272間隔。 It should be noted that, when implemented, the first pattern unit 275 may also be spaced apart from the first solid line pattern portion 271; the second pattern unit 276 may also be spaced apart from the second solid line pattern portion 272.

本實施例同樣可以達到與該第一較佳實施例相同之功效,在此不再說明。 This embodiment can also achieve the same effects as the first preferred embodiment, and will not be described here.

參閱圖11,本發明太陽能電池模組之一第三較佳實施例,與該第二較佳實施例大致相同,不同的地方在於:本實施例的每一第一圖案單元275為三角形,所述每一第一圖案單元275以該三角形的其中一邊連接該第一實線圖案部271。類似地,本實施例的每一第二圖案單元276為三角形,所述每一第二圖案單元276以該三角形的其中一邊連接該第二實線圖案部272。 Referring to FIG. 11, a third preferred embodiment of the solar cell module of the present invention is substantially the same as the second preferred embodiment. The difference is that each first pattern unit 275 of the embodiment is a triangle. Each of the first pattern units 275 connects the first solid line pattern portion 271 with one side of the triangle. Similarly, each of the second pattern units 276 of the present embodiment is a triangle, and each of the second pattern units 276 connects the second solid line pattern portion 272 with one side of the triangle.

本實施例的製造方法與該第一較佳實施例相同,只是必須使用不同開口圖案的第一網版。另外,於實施時,本實施例的第一圖案單元275也可以與該第一實線圖案部271間隔;第二圖案單元276也可以與該第二實線圖案部272間隔。 The manufacturing method of this embodiment is the same as the first preferred embodiment except that the first screen of different opening patterns must be used. In addition, in the implementation, the first pattern unit 275 of the embodiment may be spaced apart from the first solid line pattern portion 271; the second pattern unit 276 may also be spaced apart from the second solid line pattern portion 272.

惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及專利說明書內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。 The above is only the preferred embodiment of the present invention, and the scope of the present invention is not limited thereto, that is, the simple equivalent changes and modifications made by the patent application scope and patent specification content of the present invention, All remain within the scope of the invention patent.

2‧‧‧太陽能電池 2‧‧‧Solar battery

21‧‧‧基板 21‧‧‧Substrate

211‧‧‧第一表面 211‧‧‧ first surface

214‧‧‧抗反射層 214‧‧‧Anti-reflective layer

22‧‧‧第一電極 22‧‧‧First electrode

24‧‧‧第一導電層 24‧‧‧First conductive layer

25‧‧‧第二導電層 25‧‧‧Second conductive layer

251‧‧‧匯流部 251‧‧ ‧ Confluence Department

252‧‧‧側邊 252‧‧‧ side

26‧‧‧指狀部 26‧‧‧ finger

27‧‧‧電極圖案組 27‧‧‧Electrode pattern group

271‧‧‧第一實線圖案部 271‧‧‧The first solid line pattern department

272‧‧‧第二實線圖案部 272‧‧‧Second solid line pattern department

273‧‧‧第一虛線圖案部 273‧‧‧First dotted line pattern

274‧‧‧第二虛線圖案部 274‧‧‧second dotted line

275‧‧‧第一圖案單元 275‧‧‧First pattern unit

276‧‧‧第二圖案單元 276‧‧‧second pattern unit

31‧‧‧第一方向 31‧‧‧First direction

32‧‧‧第二方向 32‧‧‧second direction

Claims (12)

一種太陽能電池的製造方法,包含:準備一基板,該基板具有相對之一第一表面與一第二表面;及形成一第一電極與一第二電極並分別位於該第一表面上與該第二表面上;其中,形成該第一電極的步驟包括:以網印方式形成一第一導電層於該第一表面上,該第一導電層具有數個沿一第一方向延伸的指狀部、一沿一不同於該第一方向的第二方向延伸的第一實線圖案部,以及一沿該第二方向延伸的第一虛線圖案部;及再以網印方式形成一第二導電層於該第一導電層與該第一表面上,該第二導電層的材料異於該第一導電層,且該第二導電層具有一沿該第二方向延伸的匯流部,該匯流部重疊於該第一虛線圖案部且接觸該第一實線圖案部。 A method of manufacturing a solar cell, comprising: preparing a substrate having a first surface and a second surface; and forming a first electrode and a second electrode on the first surface and the first The step of forming the first electrode includes: forming a first conductive layer on the first surface by screen printing, the first conductive layer having a plurality of fingers extending along a first direction a first solid line pattern portion extending along a second direction different from the first direction, and a first dotted line pattern portion extending along the second direction; and forming a second conductive layer by screen printing On the first conductive layer and the first surface, the material of the second conductive layer is different from the first conductive layer, and the second conductive layer has a confluence extending in the second direction, and the confluence overlaps The first dotted line pattern portion is in contact with the first solid line pattern portion. 如請求項1所述的太陽能電池的製造方法,還形成一抗反射層於該第一表面上,該第一導電層穿過該抗反射層而連接該第一表面。 The method of manufacturing a solar cell according to claim 1, further comprising forming an anti-reflection layer on the first surface, the first conductive layer passing through the anti-reflection layer to connect the first surface. 如請求項2所述的太陽能電池的製造方法,其中,該抗反射層將該第一表面與該第二導電層隔開。 The method of manufacturing a solar cell according to claim 2, wherein the anti-reflection layer separates the first surface from the second conductive layer. 如請求項1所述的太陽能電池的製造方法,其中,該第一虛線圖案部具有數個與該第一實線圖案部間隔的第 一圖案單元。 The method of manufacturing a solar cell according to claim 1, wherein the first dotted line pattern portion has a plurality of spaces spaced apart from the first solid line pattern portion A pattern unit. 如請求項1所述的太陽能電池的製造方法,其中,該第一虛線圖案部具有數個與該第一實線圖案部相連的第一圖案單元。 The method of manufacturing a solar cell according to claim 1, wherein the first dotted line pattern portion has a plurality of first pattern units connected to the first solid line pattern portion. 如請求項4或5所述的太陽能電池的製造方法,其中,所述每一第一圖案單元為三角形。 The method of manufacturing a solar cell according to claim 4, wherein each of the first pattern units is a triangle. 如請求項1所述的太陽能電池的製造方法,其中,該第一虛線圖案部具有數個為三角形的第一圖案單元,所述每一第一圖案單元以該三角形的其中一邊連接該第一實線圖案部。 The method of manufacturing a solar cell according to claim 1, wherein the first dotted line pattern portion has a plurality of first pattern units that are triangular, each of the first pattern units being connected to the first one of the triangles Solid line pattern section. 如請求項1所述的太陽能電池的製造方法,其中,該第一虛線圖案部具有數個為長方形的第一圖案單元,所述每一第一圖案單元以該長方形的一短邊連接該第一實線圖案部。 The method of manufacturing a solar cell according to claim 1, wherein the first dotted pattern portion has a plurality of first pattern units that are rectangular, and each of the first pattern units is connected to the short side of the rectangle. A solid line pattern section. 如請求項1所述的太陽能電池的製造方法,其中,該第一導電層還具有一沿該第二方向延伸並與該第一實線圖案部間隔的第二實線圖案部,以及一沿該第二方向延伸的第二虛線圖案部,該匯流部重疊於該第二虛線圖案部且接觸該第二實線圖案部。 The method of manufacturing a solar cell according to claim 1, wherein the first conductive layer further has a second solid line pattern portion extending in the second direction and spaced apart from the first solid line pattern portion, and an edge a second dotted line pattern portion extending in the second direction, the bus portion overlapping the second broken line pattern portion and contacting the second solid line pattern portion. 如請求項9所述的太陽能電池的製造方法,其中,該匯流部之大部分位於該第一實線圖案部及該第二實線圖案部之間。 The method of manufacturing a solar cell according to claim 9, wherein a majority of the bus bar is located between the first solid line pattern portion and the second solid line pattern portion. 一種太陽能電池,包含:一基板,具有相對之一第一表面與一第二表面;及 一第一電極與一第二電極,分別位於該第一表面上與該第二表面上;其中,該第一電極包括:一第一導電層,具有數個沿一第一方向延伸的指狀部、一沿一不同於該第一方向的第二方向延伸的第一實線圖案部,以及一沿該第二方向延伸的第一虛線圖案部;及一第二導電層,位於該第一導電層上且材料異於該第一導電層,該第二導電層具有一沿該第二方向延伸的匯流部,該匯流部重疊於該第一虛線圖案部且接觸該第一實線圖案部。 A solar cell comprising: a substrate having a first surface and a second surface; and a first electrode and a second electrode are respectively disposed on the first surface and the second surface; wherein the first electrode comprises: a first conductive layer having a plurality of fingers extending along a first direction a first solid line pattern portion extending along a second direction different from the first direction, and a first dotted line pattern portion extending along the second direction; and a second conductive layer located at the first The conductive layer is different from the first conductive layer, and the second conductive layer has a confluence extending in the second direction, the confluence is overlapped with the first dashed pattern portion and contacts the first solid pattern portion . 一種太陽能電池模組,包含:相對設置的一第一板材與一第二板材;數個如請求項11所述的太陽能電池,排列於該第一板材與該第二板材之間;及一封裝材,位於該第一板材與該第二板材之間,並包覆在該數個太陽能電池的周圍。 A solar cell module comprising: a first plate and a second plate disposed oppositely; a plurality of solar cells according to claim 11 arranged between the first plate and the second plate; and a package The material is located between the first plate and the second plate and is wrapped around the plurality of solar cells.
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