TWI549976B - 改質共軛二烯系聚合物、其製造方法、聚合物組成物、交聯聚合物以及輪胎 - Google Patents
改質共軛二烯系聚合物、其製造方法、聚合物組成物、交聯聚合物以及輪胎 Download PDFInfo
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- TWI549976B TWI549976B TW101148783A TW101148783A TWI549976B TW I549976 B TWI549976 B TW I549976B TW 101148783 A TW101148783 A TW 101148783A TW 101148783 A TW101148783 A TW 101148783A TW I549976 B TWI549976 B TW I549976B
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- Prior art keywords
- conjugated diene
- group
- compound
- diene polymer
- hydrocarbon group
- Prior art date
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- NROKBHXJSPEDAR-UHFFFAOYSA-M potassium fluoride Inorganic materials [F-].[K+] NROKBHXJSPEDAR-UHFFFAOYSA-M 0.000 description 1
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- KUAZQDVKQLNFPE-UHFFFAOYSA-N thiram Chemical compound CN(C)C(=S)SSC(=S)N(C)C KUAZQDVKQLNFPE-UHFFFAOYSA-N 0.000 description 1
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- WVLBCYQITXONBZ-UHFFFAOYSA-N trimethyl phosphate Chemical compound COP(=O)(OC)OC WVLBCYQITXONBZ-UHFFFAOYSA-N 0.000 description 1
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Classifications
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- C08F8/00—Chemical modification by after-treatment
- C08F8/42—Introducing metal atoms or metal-containing groups
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- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
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- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
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- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0025—Compositions of the sidewalls
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B60—VEHICLES IN GENERAL
- B60C—VEHICLE TYRES; TYRE INFLATION; TYRE CHANGING; CONNECTING VALVES TO INFLATABLE ELASTIC BODIES IN GENERAL; DEVICES OR ARRANGEMENTS RELATED TO TYRES
- B60C1/00—Tyres characterised by the chemical composition or the physical arrangement or mixture of the composition
- B60C1/0041—Compositions of the carcass layers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/22—Incorporating nitrogen atoms into the molecule
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08C—TREATMENT OR CHEMICAL MODIFICATION OF RUBBERS
- C08C19/00—Chemical modification of rubber
- C08C19/30—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule
- C08C19/42—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups
- C08C19/44—Addition of a reagent which reacts with a hetero atom or a group containing hetero atoms of the macromolecule reacting with metals or metal-containing groups of polymers containing metal atoms exclusively at one or both ends of the skeleton
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F8/00—Chemical modification by after-treatment
- C08F8/30—Introducing nitrogen atoms or nitrogen-containing groups
- C08F8/32—Introducing nitrogen atoms or nitrogen-containing groups by reaction with amines
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L15/00—Compositions of rubber derivatives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L91/00—Compositions of oils, fats or waxes; Compositions of derivatives thereof
Landscapes
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- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
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- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
- Compositions Of Macromolecular Compounds (AREA)
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| WO2016039386A1 (ja) * | 2014-09-10 | 2016-03-17 | 住友化学株式会社 | 共役ジエン重合体及び共役ジエン重合体組成物 |
| KR101759402B1 (ko) * | 2014-12-11 | 2017-07-19 | 주식회사 엘지화학 | 변성 공역디엔계 중합체, 이의 제조방법, 및 이를 포함하는 고무 조성물 |
| KR101653574B1 (ko) | 2014-12-11 | 2016-09-08 | 주식회사 엘지화학 | 변성 공역디엔계 중합체, 이를 포함하는 변성 고무 조성물 및 변성 공역디엔계 중합체의 제조방법 |
| WO2017004395A1 (en) * | 2015-07-01 | 2017-01-05 | Bridgestone Corporation | Copolymer end-functionalized with functional silane, compositions thereof and related processes |
| EP3336108B1 (en) * | 2015-08-10 | 2019-06-26 | JSR Corporation | Conjugated diene polymer and method for producing same, polymer composition, crosslinked polymer, and tire |
| WO2017047451A1 (ja) | 2015-09-14 | 2017-03-23 | Jsr株式会社 | 水添共役ジエン系重合体の製造方法、水添共役ジエン系重合体、重合体組成物、架橋重合体及びタイヤ |
| KR101943408B1 (ko) * | 2015-11-02 | 2019-01-30 | 주식회사 엘지화학 | 유기 리튬 화합물, 이를 이용한 변성 공액디엔계 중합체 제조 방법 및 변성 공액디엔계 중합체 |
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| WO2018092843A1 (ja) * | 2016-11-16 | 2018-05-24 | Jsr株式会社 | 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、重合体組成物、架橋物及びタイヤ |
| WO2019035443A1 (ja) * | 2017-08-18 | 2019-02-21 | Jsr株式会社 | ゴム組成物の製造方法 |
| KR102447713B1 (ko) * | 2018-12-03 | 2022-09-26 | 가부시키가이샤 에네오스 마테리아루 | 중합체 조성물 및 그의 제조 방법, 가교체 및 그의 제조 방법, 그리고 타이어 |
| JP7346543B2 (ja) * | 2019-03-07 | 2023-09-19 | 株式会社Ｅｎｅｏｓマテリアル | 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、重合体組成物、架橋体及びタイヤ |
| JP2020196803A (ja) * | 2019-05-31 | 2020-12-10 | Jsr株式会社 | 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、重合体組成物、架橋体及びタイヤ |
| IT201900019795A1 (it) | 2019-10-25 | 2021-04-25 | Pirelli | Composizione elastomerica per mescole di pneumatici per ruote di veicoli e pneumatici che la comprendono |
| WO2023085309A1 (ja) * | 2021-11-10 | 2023-05-19 | 株式会社Ｅｎｅｏｓマテリアル | 変性共役ジエン系重合体の製造方法、変性共役ジエン系重合体、重合体組成物、架橋体及びタイヤ |
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| JP4126533B2 (ja) | 2002-06-20 | 2008-07-30 | Ｊｓｒ株式会社 | 共役ジオレフィン（共）重合ゴム、該（共）重合ゴムの製造方法、ゴム組成物およびタイヤ |
| JP4159993B2 (ja) | 2001-12-03 | 2008-10-01 | 株式会社ブリヂストン | 変性重合体の製造方法、その方法で得られた変性重合体及びゴム組成物 |
| JP2005290355A (ja) | 2004-03-11 | 2005-10-20 | Sumitomo Chemical Co Ltd | 変性ジエン系重合体ゴム及びその製造方法 |
| DE102005057801A1 (de) | 2005-01-20 | 2006-08-03 | Degussa Ag | Mercaptosilane |
| JP2008285558A (ja) * | 2007-05-16 | 2008-11-27 | Asahi Kasei Chemicals Corp | 油展共役ジエン系重合体組成物 |
| US8227562B2 (en) | 2008-03-15 | 2012-07-24 | Bridgestone Corporation | Functionalized polymers and initiators for making same |
| CN102177185A (zh) * | 2008-10-14 | 2011-09-07 | 旭化成化学株式会社 | 改性共轭二烯系聚合物、其制造方法、改性共轭二烯系聚合物组合物及轮胎 |
| JP5466473B2 (ja) * | 2008-10-16 | 2014-04-09 | 住友ゴム工業株式会社 | ゴム組成物およびそれを用いたタイヤ |
| JP2010116553A (ja) * | 2008-10-16 | 2010-05-27 | Sumitomo Rubber Ind Ltd | ゴム組成物およびそれを用いたスタッドレスタイヤ |
| HUE035042T2 (en) * | 2009-10-21 | 2018-05-02 | Jsr Corp | Process for the production of modified conjugated diene gum, modified conjugated diene rubber and rubber composition |
| JP5196070B2 (ja) * | 2010-03-31 | 2013-05-15 | Ｊｓｒ株式会社 | 変性共役ジエン系ゴムの製造方法、変性共役ジエン系ゴム、及びゴム組成物 |
| TWI508978B (zh) * | 2011-08-31 | 2015-11-21 | Jsr Corp | 改質共軛二烯系聚合物及其製造方法、聚合物組成物、交聯聚合物以及輪胎 |
-
2012
- 2012-12-19 US US14/367,533 patent/US20140357784A1/en not_active Abandoned
- 2012-12-19 IN IN4702CHN2014 patent/IN2014CN04702A/en unknown
- 2012-12-19 EP EP12859170.8A patent/EP2796479B1/en active Active
- 2012-12-19 WO PCT/JP2012/082885 patent/WO2013094629A1/ja not_active Ceased
- 2012-12-19 SG SG11201403457YA patent/SG11201403457YA/en unknown
- 2012-12-19 KR KR1020147013312A patent/KR101938580B1/ko active Active
- 2012-12-19 BR BR112014015698A patent/BR112014015698B8/pt active IP Right Grant
- 2012-12-19 CN CN201280063584.6A patent/CN104011093A/zh active Pending
- 2012-12-19 HU HUE12859170A patent/HUE037617T2/hu unknown
- 2012-12-19 JP JP2013550300A patent/JP5871011B2/ja active Active
- 2012-12-20 TW TW101148783A patent/TWI549976B/zh active
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101724127A (zh) * | 2008-10-16 | 2010-06-09 | 住友橡胶工业株式会社 | 聚合物、橡胶组合物及使用该橡胶组合物的轮胎 |
Also Published As
| Publication number | Publication date |
|---|---|
| SG11201403457YA (en) | 2014-09-26 |
| TW201331242A (zh) | 2013-08-01 |
| CN104011093A (zh) | 2014-08-27 |
| EP2796479A4 (en) | 2015-09-02 |
| EP2796479A1 (en) | 2014-10-29 |
| BR112014015698B8 (pt) | 2023-04-18 |
| BR112014015698B1 (pt) | 2020-12-29 |
| KR20140107198A (ko) | 2014-09-04 |
| JP5871011B2 (ja) | 2016-03-01 |
| BR112014015698A2 (pt) | 2017-06-13 |
| HUE037617T2 (hu) | 2018-09-28 |
| KR101938580B1 (ko) | 2019-01-15 |
| JPWO2013094629A1 (ja) | 2015-04-27 |
| WO2013094629A1 (ja) | 2013-06-27 |
| IN2014CN04702A (enExample) | 2015-09-18 |
| EP2796479B1 (en) | 2018-02-28 |
| US20140357784A1 (en) | 2014-12-04 |
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