TWI545229B - Ozone generating system by water electrolysis and ozone producing device thereof - Google Patents

Description

Super oxygen generation system for water electrolysis and super oxygen production device thereof

The present invention relates to a super-oxygen generation system for water electrolysis, and more particularly to a super-oxygen generation system for water electrolysis using a super-oxygen production apparatus.

In recent years, in the medical technology, superoxide is a recognized safe, clean and powerful oxidant, which has been widely used in the manufacture of disinfection or detoxification. It has a wide range of applications and personal oral hygiene, home cleaning and washing. Even more in industrial processing or wastewater treatment.

Conventionally, the method for rapidly manufacturing super oxygen can be roughly classified into an ultraviolet method, a silent discharge method, a tip discharge method, and the like. The ultraviolet method uses ultraviolet rays to act on oxygen molecules (O ₂ ) in the air to generate a trace amount of superoxide, which is a substance (O ₃ ) in which an oxygen molecule (O ₂ ) and an oxygen atom (O) are combined to form a trioxygen atom. . The silent discharge method utilizes a quartz glass tube, a heat-resistant glass, a ceramic, a stainless steel or the like. When a DC high-voltage high-frequency current passes, a discharge corona phenomenon is generated with the ground electrode, and a decomposition reaction is generated by the air passing through the electricity, and the oxygen molecule is generated. The chain bond of (O ₂ ) collapses to form an oxygen atom (from 3O ₂ to 2O ₃ (to obtain ozone. The tip discharge method uses an electronic transformer to generate high voltage, and uses a plurality of metal needles to form a tip discharge to form an ionization effect like a lightning bolt). The oxygen bond (O ₂ ) is cleaved to form a negatively charged oxygen atom (O), and the oxygen atom is combined with oxygen molecules in the air to obtain ozone (O ₃ ).

However, the above-mentioned ultraviolet method, silent discharge method or even tip discharge method utilizes oxygen molecules in the air as raw materials to be decomposed into negatively charged oxygen by electric shock. Atoms, in addition to oxygen in the air, there is a large amount of nitrogen, so in the electric shock dissociation, it will also strike the nitrogen in the air to produce nitrogen oxides, which is more likely to be harmful to the human body due to the moisture in the air. Nitrous acid.

Embodiments of the present invention provide a super-oxygen generation system for water electrolysis, which is disposed in a body, the body has a voltage source and a first fluid input end, and the super-oxygen generation system for water electrolysis comprises a super-oxygen production device and a gas collection device, and the gas collection device Connected to a super oxygen manufacturing unit. The superoxide manufacturing apparatus includes an anode catalyst layer, a cathode catalyst layer, a proton exchange membrane, an anode gas diffusion layer, a cathode gas diffusion layer, a microporous layer, and a resist layer. The anode catalyst layer and the cathode catalyst layer respectively receive a positive voltage and a negative voltage of the voltage source to form a loop, the proton exchange membrane is disposed between the anode catalyst layer and the cathode catalyst layer, and the anode gas diffusion layer is disposed on the anode catalyst layer On the same side, the cathode gas diffusion layer is disposed on the same side of the cathode catalyst layer, the microporous layer is disposed between the cathode catalyst layer and the cathode gas diffusion layer, and the resist layer is disposed on the anode gas diffusion layer and the anode catalyst layer between. The super-oxygen production device electrolyzes pure water poured through the first fluid input end, and generates super-oxygen and hydrogen gas respectively in the anode catalyst layer and the cathode catalyst layer. The gas collection device receives super oxygen and hydrogen generated by the oxygen production device.

An embodiment of the present invention provides a super oxygen production device for a super-oxygen generation system for water electrolysis. The super-oxygen generation system is disposed in the body and has a voltage source and a gas collection device. The body has a first fluid input end, and the super-oxygen production device The anode catalyst layer, the cathode catalyst layer, the proton exchange membrane, the anode gas diffusion layer, the cathode gas diffusion layer, the microporous layer, and the resist layer are included. The anode catalyst layer and the cathode catalyst layer respectively receive a positive voltage and a negative voltage of the voltage source, the proton exchange membrane is disposed between the anode catalyst layer and the cathode catalyst layer, and the anode gas diffusion layer is disposed on the same side of the anode catalyst layer The cathode gas diffusion layer is disposed on the same side of the cathode catalyst layer, the microporous layer is disposed between the cathode catalyst layer and the cathode gas diffusion layer, and the resist layer is disposed on the anode gas diffusion layer and the anode catalyst Between the layers. After the super-oxygen production device is filled with pure water through the first fluid input end, pure water is electrolyzed to the anode catalyst layer and the cathode catalyst layer to generate super oxygen and hydrogen, respectively. The gas collection device receives super oxygen and hydrogen generated by the super oxygen production device.

In summary, the super-oxygen generation system and the super-oxygen production device for water electrolysis provided by the embodiments of the present invention protect the structure of the anode gas diffusion layer by using the provided resist layer in a high voltage environment, thereby avoiding the occurrence of the generated Superoxide destruction and a decrease in superoxide production concentration. At the same time, it can effectively improve the service life of the overall super oxygen manufacturing device and reduce the cost of super oxygen generation.

The detailed description of the present invention and the accompanying drawings are to be understood by the claims The scope is subject to any restrictions.

1, 2, 314, 414‧‧‧ super oxygen manufacturing equipment

313, 413‧‧‧ gas collection device

3131, 4131‧‧‧ Hydrogen storage subunit

3132, 4132‧‧‧ superoxide storage subunit

415‧‧‧Superoxide water generator

416‧‧‧ Hydrogen-rich water generating device

3‧‧‧Super Oxygen Generation System

4‧‧‧Superoxide water generation system

11, 21, 311, 411‧‧ ‧ voltage source

12, 22‧‧‧ Proton exchange membrane

13a, 23a‧‧‧Anode catalyst layer

13b, 23b‧‧‧ Cathode catalyst layer

14, 24, 312, 412a‧‧‧ first fluid input

412b‧‧‧Second fluid input

412c‧‧‧ third fluid input

15a, 25a‧‧‧ anode gas diffusion layer

15b, 25b‧‧‧ cathode gas diffusion layer

16, 17, 26, 27‧‧‧ gas output

28‧‧‧resist

29‧‧‧Microporous layer

31, 41‧‧‧ ontology

311a, 411a‧‧‧ positive voltage terminal

311b, 411b‧‧‧ negative voltage terminal

1 is a schematic view of a conventional super oxygen production apparatus; FIG. 2A is a schematic diagram of a super oxygen production apparatus according to an embodiment of the present invention; FIG. 2B is a schematic diagram of internal components of the super oxygen production apparatus shown in FIG. 2A; Schematic diagram of a water electrolysis super-oxygen generation system; FIG. 4 is a schematic diagram of a water electrolysis super-oxygen water generation system according to an embodiment of the present invention.

The present invention utilizes water electrolysis to produce super oxygen to avoid the harm caused by the above-mentioned superoxide production. Please refer to FIG. 1. FIG. 1 is a schematic view of a conventional super oxygen manufacturing apparatus. The super gas production apparatus 1 includes an anode catalyst layer 13a, a cathode catalyst layer 13b, and a proton exchange membrane 12. The anode catalyst layer 13a and the cathode catalyst layer 13b are respectively connected to the positive and negative voltages of the voltage source 11 to constitute a loop. An anode gas diffusion layer 15a and a cathode gas diffusion layer 15b are provided in the anode catalyst layer 13a and the cathode catalyst layer 13b, respectively. In general, in the environment where water is electrolyzed to generate oxygen and hydrogen, the voltage source 11 usually only needs to be manufactured between 2.0 volts and 2.5 volts and obtains a high concentration of oxygen and a trace amount of superoxide gas at the gas output end 16 (and Oxygen content is negligible compared to) and hydrogen is obtained at gas output 17 Gas, but in a low-voltage environment, does not conform to the manufacture of super-oxygen gas, because the amount of super-oxygen gas produced is too low. Therefore, although water electrolysis has been widely used for gas generation, it has been a subject of research and development in the art to apply superoxide gas and to manufacture a new super-oxygen production apparatus and related super-oxygen generation system.

[Embodiment of Superoxide Manufacturing Apparatus]

2A and 2B, FIG. 2A is a schematic diagram of a super oxygen manufacturing apparatus according to an embodiment of the present invention. FIG. 2B is a schematic view showing the internal components of the super oxygen manufacturing apparatus 2 of FIG. 2A. 2A shows a superoxide manufacturing apparatus 2 including an anode catalyst layer 23a, a cathode catalyst layer 23b, a proton exchange membrane 22, an anode gas diffusion layer 25a, a cathode gas diffusion layer 25b, a microporous layer 29, and a resist layer 28. The anode catalyst layer 23a receives the positive voltage of the voltage source 21, the cathode catalyst layer 23b receives the negative voltage of the voltage source 21, and the proton exchange membrane 22 is disposed between the anode catalyst layer 23a and the cathode catalyst layer 23b, and the anode gas diffusion layer 25a is disposed on the same side of the anode catalyst layer 23a, the cathode gas diffusion layer 25b is disposed on the same side of the cathode catalyst layer 23b, and the microporous layer 29 is disposed between the cathode catalyst layer 23a and the cathode gas diffusion layer 25b, and is resistant. The etch layer 28 is disposed between the anode gas diffusion layer 25a and the anode catalyst layer 23a. The super-oxygen production apparatus has a plurality of shims and a casing (not shown) for fixing the connection structure of the anode catalyst layer 23a, the cathode catalyst layer 23b, the anode gas diffusion layer 25a, and the cathode gas diffusion layer 25b.

Referring again to Figure 2B, it can be seen more clearly from Figure 2B that the proton exchange membrane 22 is located in the middle. In the figure, the left side of the proton exchange membrane 22 is the anode side receiving the positive voltage of the voltage source 21, and the right side of the proton exchange membrane 22 is the cathode side receiving the negative voltage of the voltage source 21. The anode catalyst layer 23a on the anode side and the cathode catalyst layer 23b on the cathode side closest to the intermediate proton exchange membrane 22, and the anode gas diffusion layer 25a and the cathode gas diffusion layer 25b are respectively on the anode catalyst layer 23a and the cathode catalyst. The outside of layer 23b. Further, a resist layer 28 is provided beside the anode gas diffusion layer 25a. Specifically, the resist layer 28 is provided on the right side of the anode gas diffusion layer 25a and the left side of the anode catalyst layer 23a.

In the environment where water electrolysis generates super oxygen, the super-oxygen concentration generated by a voltage of generally between 2.0 volts and 2.5 volts is not good, which is not economical, and therefore the present invention is implemented. The voltage source 21 used in the example is between 3 volts and 6 volts to increase the concentration of super oxygen generated by the water electrolysis reaction.

In the present embodiment, the proton exchange membrane 21 is mainly composed of a highly fluorinated ion exchange resin (Nafion) and is an electrolyte membrane for transporting protons. On both sides of the proton exchange membrane 21 are an anode catalyst layer 23a and a cathode catalyst layer 23b, respectively. The anode catalyst layer 23a is usually made of lead dioxide, and the cathode catalyst layer 23b is usually made of platinum/carbon. Made of granules. The electrochemical reaction of the anode catalyst layer 23a and the cathode catalyst layer 23b is performed in the two layers, respectively, so that the anode catalyst layer 23a and the cathode catalyst layer 23b generate super oxygen and hydrogen, respectively. The following is a female, the anode reaction: Half-reaction at the _{anode: 3H 2 O → O 3 +} 6H + + 6e - (1.51V), the cathode half ^{reaction: 2H + + 2e - → H} 2.

In the present embodiment, the anode gas diffusion layer 25a and the cathode gas diffusion layer 25b are respectively disposed outside the anode catalyst layer 23a and the cathode catalyst layer 23b, and the anode gas diffusion layer 25a and the cathode gas diffusion layer 25b are usually made of carbon paper or A low-porosity, porous structure of hydrophilic or hydrophobic material such as carbon cloth to prevent moisture from clogging the gas passage, hindering gas transmission, and uniformly reacting the anode catalyst layer 23a and the cathode catalyst layer 23b to increase the reaction rate. . The reactants are transmitted to the anode catalyst layer 23a and the cathode catalyst layer 23b via the anode gas diffusion layer 25a and the cathode gas diffusion layer 25b, and the products of the anode catalyst layer 23a and the cathode catalyst layer 23b also pass through the anode gas diffusion layer. 25a is discharged from the cathode gas diffusion layer 25b.

For example, as shown in FIG. 2, the super-oxygen manufacturing apparatus 2 inputs pure water through the first fluid input end 24, and transmits it to the anode catalyst layer 23a and the cathode catalyst via the anode gas diffusion layer 25a and the cathode gas diffusion layer 25b. Layer 23b. The pure water is electrolyzed through the electrolytic reaction generated by the anode catalyst layer 23a and the cathode catalyst layer 23b and the circuit formed by the voltage source 21, and super oxygen and hydrogen are generated in the anode catalyst layer 23a and the cathode catalyst layer 23b, respectively. The generated super oxygen and hydrogen are also discharged through the anode gas diffusion layer 25a and the cathode gas diffusion layer 25b. At this time, superoxide and hydrogen are collected by the gas output ends 26 and 27, respectively.

On the other hand, in order to increase the mechanical strength of the structure in the use of the gas diffusion layer, polytetrafluoroethylene (PTFE) may be appropriately added to make the structure between the carbon fibers tight, and the film is not easily damaged. The anode gas diffusion layer 25a and the cathode gas diffusion layer 25b described in the present embodiment are described by carbon paper or carbon cloth only, and are not limited thereto, and may be a material having excellent conductivity such as a carbon nanotube. The main substrate of the gas diffusion layer.

Further, the microporous layer 29 provided between the cathode catalyst layer 23b and the cathode gas diffusion layer 25b serves to further improve the problem that the cathode gas diffusion layer 25b is blocked by water during the reaction. In the embodiment of the present invention, the microporous layer 29 is sprayed on the inner side of the cathode gas diffusion layer 25b with a platinum material. However, factors such as the amount, thickness, electrical resistance, gas permeability, density, etc. of the spray affect the influence of the microporous layer 29 on the cathode gas diffusion layer 25b.

In order to increase the superoxide generation rate, the voltage of the voltage source 21 is increased between 3 volts and 6 volts in the embodiment, and after the anode gas diffusion layer 25a and the cathode gas diffusion layer 25b are increased, the speed of the reactants can be increased. However, because the super oxygen concentration generated on the side of the anode catalyst layer 23a is increased, the superoxide has strong corrosiveness and the destructive force increases as the concentration increases, and the anode gas diffusion layer 25a structure is also formed. It suffers from damage and loses its original function, and even causes moisture to block the gas passage and the adverse effect of obstructing gas transmission.

Therefore, in the present embodiment, the resist layer 28 is further provided between the anode gas diffusion layer 25a and the anode catalyst layer 23a to prevent the structure of the anode gas diffusion layer 25a from being destroyed by the increase in the superoxide concentration. The resist layer 28 is made of a metal material such as a carbon nanotube or a crucible, and the resist layer 28 is uniformly adhered to the side of the anode gas diffusion layer 25a close to the anode catalyst layer 23a with a conductive adhesive. The present invention is only used as an example and is not intended to be limiting.

[Example of Super Oxygen Generation System for Water Electrolysis]

Please refer to FIG. 3 and FIG. 2 together. FIG. 3 is a schematic diagram of a super-oxygen generation system for water electrolysis according to an embodiment of the present invention. The super-oxygen generation system 3 for water electrolysis is disposed in the body 31. The body 31 has a voltage source 311 and a first fluid input end 312. The super-oxygen of water electrolysis The generation system includes a super oxygen production device 314 and a gas collection device 313.

The super oxygen production apparatus 314 is the same as the super oxygen production apparatus 2 shown in FIG. The superoxide manufacturing apparatus 314 includes an anode catalyst layer 23a, a cathode catalyst layer 23b, a proton exchange membrane 22, an anode gas diffusion layer 25a, a cathode gas diffusion layer 25b, a microporous layer 29, and a resist layer 28. The anode catalyst layer 23a receives the voltage source positive voltage, the cathode catalyst layer 23b receives the negative voltage to form a loop, the proton exchange membrane 22 is disposed between the anode catalyst layer 23a and the cathode catalyst layer 23b, and the anode gas diffusion layer 25a is disposed at On the same side of the anode catalyst layer 23a, the cathode gas diffusion layer 25b is disposed on the same side of the cathode catalyst layer 23b, the microporous layer 29 is disposed between the cathode catalyst layer 23b and the cathode gas diffusion layer 25b, and the resist layer 28 It is disposed between the anode gas diffusion layer 25a and the anode catalyst layer 23a. The super-oxygen production apparatus 2 has a plurality of spacers and a casing (not shown) for fixing the connection structure of the anode catalyst layer 23a, the cathode catalyst layer 23b, the anode gas diffusion layer 25a, and the cathode gas diffusion layer 25b.

The super oxygen and hydrogen generated by the super oxygen production device 314 are collected and stored via the gas collection device 313 connected to the super oxygen production device 314. The gas collection device 313 further includes a super-oxygen storage sub-unit 3132 and a hydrogen storage sub-unit 3131, which are respectively connected to the gas output ends 26, 27 of the super-oxygen production device 314 for receiving the super-oxygen and hydrogen generated by the storage super-oxygen production device 314. . The super-oxygen storage subunit 3131 and the hydrogen storage subunit 3132 may be, for example, gas storage devices such as high pressure, low temperature cylinders. For example, when the superoxide manufacturing device 314 is connected to the positive voltage terminal 311a of the voltage source 311 through the anode catalyst layer 23a and the negative voltage terminal 311b of the cathode catalyst layer 23b connected to the voltage source 311, the electrolysis reaction is respectively After the anode catalyst layer 23a generates super oxygen and generates hydrogen gas in the cathode catalyst layer 23b, the super oxygen and hydrogen generated by the reaction are separately transferred to the super-oxygen storage sub-unit 3132 and the hydrogen storage sub-unit 3131 for collection for subsequent utilization. .

[Example of Superhydrogen Water Production System for Water Electrolysis]

Please refer to FIG. 2 and FIG. 4 simultaneously. FIG. 4 is a schematic diagram of a super-hydrogen water generating system for water electrolysis according to an embodiment of the present invention. The super-hydrogen water generating system 4 for water electrolysis is disposed on the body 41 The body 41 has a voltage source 411 and a first fluid input end 412a. The super-oxygen generation system for water electrolysis includes a super-oxygen production device 414, a gas collection device 413, and a super-oxygen water generation device 415.

The super oxygen production apparatus 414 is the same as the super oxygen production apparatus 2 shown in FIG. The superoxide manufacturing apparatus 414 includes an anode catalyst layer 23a, a cathode catalyst layer 23b, a proton exchange membrane 22, an anode gas diffusion layer 25a, a cathode gas diffusion layer 25b, a microporous layer 29, and a resist layer 28. The anode catalyst layer 23a receives the positive voltage terminal 411a of the voltage source 411, the cathode catalyst layer 23b receives the negative voltage terminal 411b of the voltage source 411, and the proton exchange membrane 22 is disposed between the anode catalyst layer 23a and the cathode catalyst layer 23b. The anode gas diffusion layer 25a is disposed on the same side of the anode catalyst layer 23a, the cathode gas diffusion layer 25a is disposed on the same side of the cathode catalyst layer 23b, and the microporous layer 29 is disposed on the cathode catalyst layer 23b and the cathode gas diffusion layer 25b. The resist layer 28 is disposed between the anode gas diffusion layer 25a and the anode catalyst layer 23a.

In the super oxygen production apparatus 414 of the present embodiment, the proton exchange membrane 22 electrolysis method is also employed, which generates a super oxygen generation system in the same manner as the water electrolysis super oxygen generation system. Hydrogen in pure water is separated to produce hydrogen and oxygen, and superoxide is produced by electrochemical principles. The superoxide manufacturing device 414 is filled with pure water through the first fluid input end 412a of the body 41, and receives positive and negative voltage sources 411 between 3 volts and 6 volts through the anode catalyst layer 23a and the cathode catalyst layer 23b, respectively. The voltage terminals 411a and 411b electrolyze pure water and generate super oxygen and hydrogen gas in the anode catalyst layer 23a and the cathode catalyst layer 23b, respectively.

The super oxygen and hydrogen generated by the super oxygen production device 414 are collected and stored via the gas collection device 413 connected to the super oxygen production device 414. The gas collection device 413 further includes a super-oxygen storage sub-unit 4132 and a hydrogen storage sub-unit 4131 connected to the gas output ends 26, 27 of the super-oxygen production device 414, respectively, for receiving the super-oxygen and hydrogen generated by the storage super-oxygen production device 414. . The super-oxygen storage subunit 4132 and the hydrogen storage subunit 4131 may be, for example, gas storage devices such as high pressure, low temperature cylinders. For example, when the super oxygen manufacturing device 414 is connected to the voltage source 411 through the anode catalyst layer 23a The circuit formed by the positive voltage terminal 411a and the cathode catalyst layer 23b connected to the negative voltage terminal 411b of the voltage source 411 is subjected to electrolytic reaction to generate superoxide in the anode catalyst layer 23a and hydrogen gas in the cathode catalyst layer 23b, respectively. The superoxide and hydrogen generated by the reaction are separately transferred to the super-oxygen storage subunit 4132 and the hydrogen storage subunit 4131 for collection.

The super-oxygen water generating system of the water electrolysis of the present embodiment further includes a super-oxygen water generating device 415 and a hydrogen-rich water generating device 416. The super-oxygen water generating device 415 is configured to mix the pure water into the super-oxygen stored in the super-oxygen storage sub-unit 4132 in the gas collecting device 413 through the second fluid input end 412b to form super-oxygen water. The hydrogen-rich water generating device 416 is configured to mix the pure water with the hydrogen stored in the hydrogen storage subunit 4131 in the gas collecting device 413 through the third fluid input terminal 412c to form hydrogen-rich water. It is worth mentioning that, by mixing the super-oxygen water, the super-oxygen concentration generated by the super-oxygen generation system of water electrolysis can be further measured by a measuring device.

[Effects of possible examples]

The resist layer proposed by the embodiment of the present invention can effectively protect the gas diffusion layer originally used for increasing the rate of reactant generation, and is not subjected to superoxide corrosive gas under the environment of high concentration of super oxygen generated by high voltage. The structure of the diffusion layer. Further, the benefits of providing a gas diffusion layer (such as improving water management, enhancing structural strength, and increasing electrical conductivity) are caused, but the water generated in the reaction is caused by a structure in which a high concentration of superoxide is destroyed to destroy the gas diffusion layer. The inability to transfer smoothly and the obstruction of gas transport causes the formation of superoxide concentration to drop, so that the concentration of superoxide generation cannot be maintained for a long time. In summary, the present invention can effectively solve the high cost and low efficiency of generating superoxide by water electrolysis for a long time, thereby further prolonging the service life of the super-oxygen production device and effectively reducing the cost of super-oxygen generation.

The above description is only the preferred embodiment of the present invention, but the features of the present invention are not limited thereto, and any one skilled in the art can easily change or modify it in the field of the present invention. Covered in the following patent scope of this case.

2‧‧‧Superoxide manufacturing equipment

21‧‧‧Voltage source

22‧‧‧Proton exchange membrane

23a‧‧‧Anode catalyst layer

23b‧‧‧ Cathode catalyst layer

24‧‧‧First fluid input

25a‧‧‧Anode gas diffusion layer

25b‧‧‧ Cathode gas diffusion layer

26, 27‧‧‧ gas output

28‧‧‧resist

29‧‧‧Microporous layer

Claims (12)

A super-oxygen generation system for water electrolysis is disposed in a body having a voltage source and a first fluid input end, the super-oxygen generation system for water electrolysis comprising: a super-oxygen production device comprising: an anode contact The medium layer receives a positive voltage of the voltage source; a cathode catalyst layer receives a negative voltage of the voltage source; a proton exchange membrane disposed between the anode catalyst layer and the cathode catalyst layer; an anode a gas diffusion layer disposed on the same side of the anode catalyst layer; a cathode gas diffusion layer disposed on the same side of the cathode catalyst layer; a microporous layer disposed on the cathode catalyst layer and the cathode gas diffusion layer Spraying over the inside of the cathode gas diffusion layer, wherein the thickness of the microporous layer is associated with a gas transport effect of the cathode gas diffusion layer; and a resist layer disposed on the anode gas diffusion layer and the anode Between the catalyst layers; wherein the super-oxygen production device electrolyzes pure water poured through the first fluid input end, and generates super-oxygen and hydrogen gas respectively from the anode catalyst layer and the cathode catalyst layer, and transmits the Corrosion Preventing the generated super-oxygen from destroying the structure of the anode gas diffusion layer; a gas collection device connected to the super-oxygen production device for receiving super-oxygen and hydrogen generated by the super-oxygen production device; and a super-oxygen water generating device, It is used to mix water with super oxygen stored in the gas collecting device to form super-oxygen water. The super-oxygen generation system for water electrolysis according to claim 1, wherein the anti-corrosion layer is made of a carbon nanotube or a conductive metal material. The super-oxygen generation system for water electrolysis according to claim 2, wherein the conductive metal material is ruthenium. The super-oxygen generation system for water electrolysis according to claim 2, wherein the resist layer has a porous structure. Such as the super-oxygen generation system for water electrolysis described in claim 1 of the patent scope, wherein the yang The polar gas diffusion layer and the cathode gas diffusion layer are carbon paper or carbon cloth. The super-oxygen generation system for water electrolysis according to claim 1, wherein the voltage of the voltage source is between 3 volts and 6 volts. The super-oxygen generation system for water electrolysis according to claim 1, further comprising: a hydrogen-rich water generating device connected to the gas collecting device for mixing the water with the hydrogen stored in the gas collecting device to make the rich Hydrogen water. A super oxygen manufacturing device is suitable for a gas collecting device and a super-oxygen water generating device, and is connected to a voltage source and a first fluid input terminal, the super-oxygen manufacturing device comprising: an anode catalyst layer, receiving the voltage source a positive voltage; a cathode catalyst layer receiving a negative voltage of the voltage source; a proton exchange membrane disposed between the anode catalyst layer and the cathode catalyst layer; an anode gas diffusion layer disposed on the anode a cathode gas diffusion layer disposed on the same side of the cathode catalyst layer; a microporous layer disposed between the cathode catalyst layer and the cathode gas diffusion layer, spray coated thereon An inner side of the cathode gas diffusion layer, wherein a thickness of the microporous layer is associated with a gas transport effect of the cathode gas diffusion layer; and a resist layer disposed between the anode gas diffusion layer and the anode catalyst layer; The super-oxygen production device electrolyzes the pure water poured through the first fluid input end, generates super-oxygen and hydrogen gas respectively in the anode catalyst layer and the cathode catalyst layer, and the gas collecting device receives the super-oxidation system. The super oxygen and hydrogen generated by the device are mixed with the super oxygen stored in the gas collecting device through the super-oxygen water generating device to form super-oxygen water, and the generated super-oxygen is prevented from being destroyed by the resist layer. The structure of the anode gas diffusion layer. The super-oxygen production apparatus according to claim 8, wherein the resist layer is made of a carbon nanotube or a conductive metal material. The super-oxygen production apparatus according to claim 9, wherein the conductive metal material is ruthenium. The super oxygen production apparatus according to claim 8, wherein the resist layer has a porous structure. The superoxide manufacturing apparatus of claim 8, wherein the voltage source has a voltage of between 3 volts and 6 volts.