TWI525890B - Multifunctional module of integrated flow battery - Google Patents

Multifunctional module of integrated flow battery Download PDF

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TWI525890B
TWI525890B TW104106116A TW104106116A TWI525890B TW I525890 B TWI525890 B TW I525890B TW 104106116 A TW104106116 A TW 104106116A TW 104106116 A TW104106116 A TW 104106116A TW I525890 B TWI525890 B TW I525890B
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electrolyte
positive
negative
battery
item
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TW201631830A (en
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呂永方
謝錦隆
許中耀
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行政院原子能委員會核能研究所
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
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    • Y02E60/30Hydrogen technology
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Description

多功能整合型液流電池模組Multifunctional integrated flow battery module

本發明係有關於一種多功能整合型液流電池模組,尤指涉及一種可攜帶型之液流電池結構之移動電源系統,特別係指具流動性可抽換式電解液之特性,不僅可節省充電時程與降低儲能成本而發揮最大效益,更可用於電動載具上,以直接置換電解液完成短時間內充電,進而有效提升充電效率者。The invention relates to a multifunctional integrated flow battery module, in particular to a portable power supply system of a portable flow battery structure, in particular to a fluid exchangeable electrolyte, which is not only It saves the charging time and reduces the energy storage cost to maximize the benefits. It can also be used on electric vehicles to directly replace the electrolyte to complete the charging in a short time, thus effectively improving the charging efficiency.

液流電池(Flow battery)之構造通常係兩個巨大容器,內有電解質,以幫浦抽送至電池堆,電池堆內有一薄膜,兩種電解質隔著薄膜反應,產生電力,充電時,則逆向反應。其發展已經相當久,惟液流電池之主要缺點係體積往往極為龐大,不適用於行動裝置或汽車使用,因此發展雖早,卻無開花結果。The structure of the flow battery is usually two huge containers with electrolyte inside, pumped to the battery stack, a film inside the battery, two electrolytes reacting through the film to generate electricity, and when charging, reverse reaction. It has been developing for a long time, but the main disadvantage of the flow battery is that it is extremely bulky and is not suitable for use in mobile devices or automobiles. Therefore, although the development is early, there is no flowering result.

近年來,隨著可再生能源發展,能源儲存需求浮現,液流電池又再度重回目光焦點。液流電池只要增加電解質儲槽之容量就能增加能源儲存總容量,也沒有固液相轉換之問題,因此不會產生像是枝狀結晶等造成壽命問題之困擾,幾乎可無限次使用,而也因此省去了許多維護需求,安全性與穩定性高,過充也沒有起火或爆炸之虞,而且,若作為電網之能源儲存裝置,成為固定設施,體積與可攜性就不那麼重要,反而是液流電池的其他特性成為優勢,因此又開始有許多新創事業投入。In recent years, with the development of renewable energy, energy storage demand has emerged, and the flow battery has once again returned to the focus of attention. As long as the flow battery increases the capacity of the electrolyte storage tank, it can increase the total energy storage capacity, and there is no problem of solid-liquid phase conversion. Therefore, it does not cause life problems such as dendritic crystals, and can be used almost infinitely. Therefore, many maintenance requirements are saved, safety and stability are high, and there is no fire or explosion after overcharging. Moreover, if it is used as a power storage device of the power grid and becomes a fixed facility, volume and portability are not so important, but instead It is the other characteristics of the flow battery that has become an advantage, so there are many new ventures.

目前,隨著儲能電池與電動車市場之興起,以液流電池發展為行動電源,藉此提升電動載具之使用率,並取代傳統昂貴且有起火疑慮之鋰系電池,已是現代儲能產業之發展趨勢。以往電動車之價格係其發展之主要障礙之一,若在電動車上裝上液流電池,則其價格只要鋰系電池之四分之一,並由於液流電池兩極之電解液係分開存放,相互滲漏之機會小,自身放電之機會也小,且安全性高,使得能量可長久儲存。然而,雖然在安全性與價格上有優勢,但目前液流電池仍舊是應用於變電站調峰調頻與太陽光電、風力發電儲能之固定型,若使用於液流電池電動車則無法像鋰系電池一樣,以直接抽換之方式快速充電,且對電池堆進行充放電之控制,亦是採用人工而非自動。再者,電池在充電與放電過程之電壓電流係為直流單向進行,無法同步雙向動作。At present, with the rise of the energy storage battery and electric vehicle market, the development of flow battery as a mobile power source, thereby increasing the utilization rate of electric vehicles and replacing the traditional lithium battery with high cost and doubts, is a modern storage. The development trend of the industry. In the past, the price of electric vehicles was one of the main obstacles to its development. If a liquid battery is installed on an electric vehicle, the price is only one quarter of that of the lithium battery, and the electrolyte of the two ends of the flow battery is separately stored. The opportunity for mutual leakage is small, the chance of self-discharge is small, and the safety is high, so that energy can be stored for a long time. However, although there are advantages in safety and price, current flow batteries are still used in the fixed type of substation peaking and frequency modulation and solar photovoltaic, wind power storage, if used in liquid flow battery electric vehicles can not be like lithium Like the battery, it is quickly charged by direct exchange, and the control of charging and discharging the battery stack is also manual rather than automatic. Furthermore, the voltage and current of the battery during the charging and discharging processes are DC unidirectional, and the two-way operation cannot be synchronized.

故,ㄧ般習用者係無法符合使用者於實際使用時將液流電池發展為行動電源而提升電動車之使用率,並能同時進行充放電功用之所需。Therefore, the user-like users cannot meet the needs of the user to develop the flow battery as a mobile power source during actual use, thereby increasing the utilization rate of the electric vehicle and simultaneously performing charging and discharging functions.

本發明之主要目的係在於,克服習知技藝所遭遇之上述問題並提供一種利用具流動性可抽換式電解液之特性,不僅可藉由導入流動與儲存能量方式,視不同儲能運用情境調整電池系統之輸出功率與能量,以節省充電時程與降低儲能成本而發揮最大效益,更可依應用之目的,可實現整合成完整之行動式電源系統(如電動載具、移動式電源系統)或完整之固定式電源系統(如電力儲能、液流電池充放電與流量管理系統);當施用於電動載具上時,可直接置換電解液完成短時間內充電,以達到有效提升充電效率,並透過電解液可以快速更換充填,因此可對各種不同種類之液流電池模組進行測試與應用,同時亦可藉由多組電池堆、多組循環泵、及其循環管路之組合,可實現充放電同步之應用,並藉由不同之操作策略及控制參數,以作準確之操控及安全監控之多功能整合型液流電池模組。The main object of the present invention is to overcome the above problems encountered in the prior art and to provide a fluid exchangeable electrolyte characteristic, which can be used not only by introducing flow and storage energy, but also by different energy storage application scenarios. Adjust the output power and energy of the battery system to save the charging time and reduce the energy storage cost to maximize the benefits. It can be integrated into a complete mobile power system (such as electric vehicle and mobile power supply) according to the application. System) or a complete fixed power system (such as power storage, flow battery charge and discharge and flow management system); when applied to electric vehicles, can directly replace the electrolyte to complete charging in a short time, in order to achieve effective improvement Charging efficiency, and can quickly change the filling through the electrolyte, so it can test and apply various kinds of liquid flow battery modules, and also through multiple sets of battery stacks, multiple sets of circulating pumps, and their circulation pipelines. Combination, which can realize the application of charge and discharge synchronization, with different operation strategies and control parameters for accurate control and safety monitoring Multi-function integrated flow battery module.

本發明之次要目的係在於,提供一種透過恆溫槽可將整體模組溫控至所需溫度範圍,不僅可維持在恆溫狀態下,並可配合外在環境溫度高低而調整系統溫度,以適應各種嚴苛之環境需求之多功能整合型液流電池模組。A secondary object of the present invention is to provide a temperature control system for temperature control of a whole module to a desired temperature range, which can be maintained not only at a constant temperature but also with an external ambient temperature to adjust the system temperature to suit A versatile integrated flow battery module for a variety of demanding environmental needs.

為達以上之目的,本發明係一種多功能整合型液流電池模組,係包括:至少一以上電池堆,其根據一正極電解液與一負極電解液進行電化學反應以產生及/或放出直流電能,並輸出反應後之正極電解液與負極電解液;一正極熱交換器,係與該些電池堆連接,用以對反應後之正極電解液進行熱量交換;一負極熱交換器,係與該些電池堆連接,用以對反應後之負極電解液進行熱量交換;一正極電解液槽,其內存放有該正極電解液,係透過一第一循環泵系統將該正極電解液從該正極電解液槽抽出,通過一流量控制單元調整流量後,注入該些電池堆,在該些電池堆內完成電化學反應以產生及/或放出直流電能,反應後之正極電解液進入該正極熱交換器,使該反應後之正極電解液保持在最佳工作溫度範圍內,再送回該正極電解液槽,令該正極電解液槽與該正極熱交換器及該些電池堆形成一正極電解液之循環系統,以完成電池之充放電過程;一負極電解液槽,其內存放有該負極電解液,係透過一第二循環泵系統將該負極電解液從該負極電解液槽抽出,通過該流量控制單元調整流量後,注入該些電池堆,在該些電池堆內完成電化學反應以產生及/或放出直流電能,反應後之負極電解液進入該負極熱交換器,使該反應後之負極電解液保持在最佳工作溫度範圍內,再送回該負極電解液槽,令該負極電解液槽與該負極熱交換器及該些電池堆形成一負極電解液之循環系統,以完成電池之充放電過程;一恆溫槽,係分別與該正、負極熱交換器及該正、負極電解液槽連接,用以控制該正、負極電解液與該些電池堆之溫度範圍,不僅可維持在恆溫狀態下,並可配合外在環境溫度高低而調整系統溫度,以適應各種嚴苛之環境需求;一充放電系統,係與該些電池堆連接,用以對該些電池堆進行充放電,當充電時,可與市電或再生能源作連結,以直流/交流轉換之方式進行充電,當放電時,係以直流/交流轉換之方式,連接至任一負載進行放電;以及一監控系統,用以自動監控該流量控制單元,且透過指令控制該流量控制單元之流量、閥體之開關、壓力調整、或循環泵之頻率之作動,並可透過壓力及循環泵之頻率進行多功能之控制,在不同充放電之荷電狀態(State Of Charge, SOC)下調整流量、壓力或循環泵之頻率。For the purpose of the above, the present invention is a multi-functional integrated flow battery module comprising: at least one battery stack, which electrochemically reacts with a negative electrolyte to generate and/or emit DC electric energy, and outputting the positive electrode electrolyte and the negative electrode electrolyte after the reaction; a positive electrode heat exchanger is connected to the battery stacks for heat exchange of the positive electrode electrolyte after the reaction; Connected to the battery stacks for heat exchange of the reacted negative electrode electrolyte; a positive electrode electrolyte tank in which the positive electrode electrolyte is stored, the positive electrode electrolyte is discharged from the first circulating pump system The positive electrolyte tank is withdrawn, and the flow rate is adjusted by a flow control unit, and then injected into the battery stacks, and electrochemical reactions are completed in the battery stacks to generate and/or discharge DC power, and the positive electrode electrolyte after the reaction enters the positive electrode heat. The exchanger keeps the positive electrode electrolyte after the reaction in an optimal working temperature range, and then returns it to the positive electrode electrolyte tank to make the positive electrode electrolyte tank and the positive electrode The exchanger and the battery stack form a positive electrolyte circulating system to complete the charging and discharging process of the battery; a negative electrolyte tank in which the negative electrolyte is stored, the negative electrode is passed through a second circulating pump system The electrolyte is withdrawn from the negative electrolyte solution tank, and after the flow rate is adjusted by the flow control unit, the battery stack is injected, and an electrochemical reaction is completed in the battery stack to generate and/or discharge DC power, and the negative electrode electrolyte after the reaction Entering the negative heat exchanger, keeping the negative electrode electrolyte after the reaction in an optimal working temperature range, and returning the negative electrode electrolyte solution to the negative electrode electrolyte tank to form the negative electrode heat exchanger and the battery stacks a circulating system of a negative electrolyte to complete the charging and discharging process of the battery; a constant temperature tank is respectively connected with the positive and negative heat exchangers and the positive and negative electrolyte tanks for controlling the positive and negative electrolytes The temperature range of these battery stacks can be maintained not only at a constant temperature, but also with the temperature of the external environment to adjust the system temperature to adapt to various harsh environments. A charge and discharge system is connected to the battery stacks for charging and discharging the battery stacks. When charging, it can be connected with mains or renewable energy, and charged by DC/AC conversion. When discharging, it is connected to any load for discharging by DC/AC conversion; and a monitoring system for automatically monitoring the flow control unit, and controlling the flow of the flow control unit, the switch of the valve body through the command, Pressure adjustment, or the frequency of the circulating pump, and multi-function control through the pressure and the frequency of the circulating pump, adjusting the flow, pressure or circulating pump frequency under different state of charge (SOC) .

於本發明上述實施例中,更包括一直流/交流轉換器,用以將該電池堆輸出之直流電能轉換為交流電能後,提供給該監控系統、該第一循環泵系統、該第二循環泵系統、該流量控制單元、及該恆溫槽使用。In the above embodiment of the present invention, the method further includes a DC/AC converter for converting the DC power outputted by the battery stack into AC power, and then providing the monitoring system, the first circulation pump system, and the second cycle. The pump system, the flow control unit, and the thermostat are used.

於本發明上述實施例中,更包括一外部電源,用以在初始運轉時,作為電力供給源,提供交流電能給該監控系統、該第一循環泵系統、該第二循環泵系統、該流量控制單元、及該恆溫槽使用。In the above embodiment of the present invention, an external power source is further included to provide AC power to the monitoring system, the first circulating pump system, the second circulating pump system, and the flow as a power supply source during initial operation. The control unit and the thermostat are used.

於本發明上述實施例中,該流量控制單元係包含一流量計、一比例式控制閥、、一壓力感測器、及一頻率變動器。In the above embodiment of the present invention, the flow control unit comprises a flow meter, a proportional control valve, a pressure sensor, and a frequency variator.

於本發明上述實施例中,該正、負極電解液槽之間連通之管路上設有一閥體,係依據該正、負極電解液之成份及液位進行開關。In the above embodiment of the present invention, a valve body is disposed on the pipeline connecting the positive and negative electrolyte tanks, and the switch is performed according to the composition and liquid level of the positive and negative electrolytes.

於本發明上述實施例中,該正、負極電解液之成份相同時,該閥體係經由設定開啟週期控制開啟時程,當該正、負極電解液槽內液位發生變化而不同高時,係透過該閥體之開啟而使其液面回復相同。In the above embodiment of the present invention, when the components of the positive and negative electrolytes are the same, the valve system controls the opening time interval by setting the opening period, and when the liquid level in the positive and negative electrolyte tanks changes and is different, the system is different. The liquid level returns to the same through the opening of the valve body.

於本發明上述實施例中,該正、負極電解液之成份不相同時,該閥體係設定為常關( alwaysoff)。In the above embodiment of the present invention, when the components of the positive and negative electrolytes are different, the valve system is set to always off.

於本發明上述實施例中,該閥體係連接有一加壓裝置。In the above embodiment of the invention, the valve system is coupled to a pressurizing device.

於本發明上述實施例中,該正極電解液槽內設有一正極混合管,用以將回流之正極電解液先灌入管中,再與槽內之正極電解液混合。In the above embodiment of the present invention, a positive electrode mixing tube is disposed in the positive electrode electrolyte tank for injecting the reflux positive electrode electrolyte into the tube and then mixing with the positive electrode electrolyte in the tank.

於本發明上述實施例中,該負極電解液槽內設有一負極混合管,用以將回流之負極電解液先灌入管中,再與槽內之負極電解液混合。In the above embodiment of the present invention, a negative electrode mixing tube is disposed in the negative electrode electrolyte tank for injecting the refluxed negative electrode electrolyte into the tube and then mixing with the negative electrode electrolyte in the tank.

於本發明上述實施例中,該第一循環泵系統及該第二循環泵系統各由至少一組以上循環泵及至少一套以上循環管路組成。In the above embodiment of the present invention, the first circulating pump system and the second circulating pump system each consist of at least one set of circulating pumps and at least one set of circulating lines.

於本發明上述實施例中,該些電池堆同時進行產生直流電能,或同時進行放出直流電能時,該正極電解液與該負極電解液係可選擇各自之第一循環泵系統與該第二循環泵系統中任意循環泵及循環管路進行運轉,或可同時進行運轉。In the above embodiment of the present invention, when the battery stacks simultaneously generate DC power or simultaneously discharge DC power, the cathode electrolyte and the anode electrolyte may select respective first circulation pump systems and the second cycle. Any circulating pump and circulation line in the pump system can be operated or can be operated at the same time.

於本發明上述實施例中,該些電池堆中分別以其中一電池堆進行產生直流電能,另一電池堆進行放出直流電能時,該正極電解液與該負極電解液係將各自之第一循環泵系統與該第二循環泵系統中以二組循環泵及二套循環管路分開運轉。In the above embodiment of the present invention, when one of the battery stacks generates DC power by one of the battery stacks, and the other battery stack emits DC power, the positive electrode electrolyte and the negative electrode electrolyte system will each have a first cycle. The pump system and the second circulating pump system are operated separately by two sets of circulating pumps and two sets of circulating lines.

於本發明上述實施例中,該正、負極電解液槽、該些循環管路、及該些電池堆之位置設有一液體洩漏收集槽,用以將洩漏之正、負極電解液收集。In the above embodiment of the present invention, the positive and negative electrolyte tanks, the circulation lines, and the positions of the battery stacks are provided with a liquid leakage collection tank for collecting the leaked positive and negative electrolytes.

於本發明上述實施例中,更包括一緊急停機裝置,用以當發生緊急狀況時,可進行立即停機處理。In the above embodiment of the present invention, an emergency stop device is further included for performing an immediate shutdown process when an emergency situation occurs.

10‧‧‧集裝箱10‧‧‧ container

11、11a‧‧‧電池堆11, 11a‧‧‧ battery stack

12‧‧‧正極熱交換器12‧‧‧ positive heat exchanger

13‧‧‧負極熱交換器13‧‧‧Negative heat exchanger

14‧‧‧正極電解液槽14‧‧‧ positive electrolyte tank

141‧‧‧正極電解液141‧‧‧ positive electrolyte

142‧‧‧第一循環泵系統142‧‧‧First Circulating Pump System

1421、1422‧‧‧循環泵1421, 1422‧‧ ‧Circulating pump

143‧‧‧正極混合管143‧‧‧Positive mixing tube

15‧‧‧負極電解液槽15‧‧‧Negative electrolyte tank

151‧‧‧負極電解液151‧‧‧Negative electrolyte

152‧‧‧第二循環泵系統152‧‧‧Second Circulating Pump System

1521、1522‧‧‧循環泵1521, 1522‧‧ Circulating pump

153‧‧‧負極混合管153‧‧‧Negative mixing tube

16‧‧‧恆溫槽16‧‧‧ thermostatic bath

17‧‧‧充放電系統17‧‧‧Charge and discharge system

18‧‧‧直流/交流轉換器18‧‧‧DC/AC Converter

19‧‧‧監控系統19‧‧‧Monitoring system

20‧‧‧流量控制單元20‧‧‧Flow Control Unit

21‧‧‧外部電源21‧‧‧External power supply

22‧‧‧閥體22‧‧‧ valve body

第1圖,係本發明多功能整合型液流電池模組之架構示意圖。FIG. 1 is a schematic structural view of a multi-functional integrated flow battery module of the present invention.

第2圖,係本發明正、負極電解液槽之配件示意圖。Fig. 2 is a schematic view showing the fittings of the positive and negative electrolyte tanks of the present invention.

請參閱『第1圖及第2圖』所示,係分別為本發明多功能整合型液流電池模組之架構示意圖、及本發明正、負極電解液槽之配件示意圖。如圖所示:本發明係一種多功能整合型液流電池模組,包括由二電池堆11、11a(或其中之一)、一正極熱交換器12、一負極熱交換器13、一正極電解液槽14、一負極電解液槽15、一恆溫槽16、一充放電系統17、一直流/交流轉換器18、以及一監控系統19所構成為例說明。然而,需注意的是,上述電池堆之設置數目係配合使用需求所決定,在此僅用作為舉例,不可限制本發明,而可視應用需要加以調整。Please refer to FIG. 1 and FIG. 2, which are schematic diagrams of the structure of the multi-functional integrated flow battery module of the present invention, and the accessories of the positive and negative electrolyte tanks of the present invention. As shown in the figure: the present invention is a multifunctional integrated flow battery module comprising two battery stacks 11, 11a (or one of them), a positive heat exchanger 12, a negative heat exchanger 13, and a positive electrode. The electrolyte tank 14, a negative electrolyte tank 15, a constant temperature tank 16, a charge and discharge system 17, a DC/AC converter 18, and a monitoring system 19 are exemplified. However, it should be noted that the number of the above-mentioned battery stacks is determined in accordance with the use requirements, and is merely used as an example, and the present invention is not limited, and the visual application needs to be adjusted.

上述所提之電池堆11、11a係根據一正極電解液141與一負極電解液151進行電化學反應以產生及/或放出直流電能,並輸出反應後之正極電解液與負極電解液。The above-mentioned battery stacks 11 and 11a are electrochemically reacted with a negative electrode electrolyte 151 to generate and/or discharge direct current electric energy, and output the reacted positive electrode electrolyte and negative electrode electrolyte.

該正、負極熱交換器12、13係分別與該些電池堆11、11a連接,用以對反應後之正、負極電解液進行熱量交換。The positive and negative heat exchangers 12 and 13 are connected to the battery stacks 11 and 11a, respectively, for exchanging heat between the positive and negative electrode electrolytes after the reaction.

該正極電解液槽14內存放有該正極電解液141,係透過一第一循環泵系統142中循環泵及循環管路將該正極電解液141從該正極電解液槽14抽出,通過一流量控制單元20調整流量後,注入該些電池堆11、11a,在該些電池堆11、11a內完成電化學反應以產生及/或放出直流電能,反應後之正極電解液進入該正極熱交換器12,使該反應後之正極電解液保持在最佳工作溫度範圍內,再將其抽送回該正極電解液槽14,令該正極電解液槽14與該正極熱交換器12及該些電池堆11、11a形成一正極電解液之循環系統,以完成電池之充放電過程。其中,該第一循環泵系統142係由至少一組以上循環泵及至少一套以上循環管路組成;於本實施例中,本發明配合該些電池堆11、11a之數量,係以二組循環泵1421、1422(或其一)及至少一套以上循環管路組成該第一循環泵系統142為例。The positive electrode electrolyte solution 141 is stored in the positive electrode electrolyte tank 14, and the positive electrode electrolyte solution 141 is withdrawn from the positive electrode electrolyte solution tank 14 through a circulation pump and a circulation line in the first circulation pump system 142, and is controlled by a flow rate. After adjusting the flow rate, the unit 20 injects the battery stacks 11 and 11a, and completes an electrochemical reaction in the battery stacks 11 and 11a to generate and/or discharge DC power, and the reacted positive electrode electrolyte enters the positive electrode heat exchanger 12 . The positive electrode electrolyte after the reaction is maintained in an optimal working temperature range, and then pumped back to the positive electrode electrolyte tank 14, so that the positive electrode electrolyte tank 14 and the positive electrode heat exchanger 12 and the battery stacks 11 are 11a forms a circulation system of a positive electrode electrolyte to complete the charging and discharging process of the battery. The first circulating pump system 142 is composed of at least one set of circulating pumps and at least one set of circulating pipelines. In the present embodiment, the present invention cooperates with the number of the battery stacks 11 and 11a, and is divided into two groups. The circulation pump 1421, 1422 (or one thereof) and at least one set of circulation lines constitute the first circulation pump system 142 as an example.

該負極電解液槽15內存放有該負極電解液151,係透過一第二循環泵系統152中循環泵及循環管路將該負極電解液151從該負極電解液槽15抽出,通過該流量控制單元20調整流量後,注入該些電池堆11、11a,在該些電池堆11、11a內完成電化學反應以產生及/或放出直流電能,反應後之負極電解液進入該負極熱交換器13,使該反應後之負極電解液保持在最佳工作溫度範圍內,再將其抽送回該負極電解液槽15,令該負極電解液槽15與該負極熱交換器13及該些電池堆11、11a形成一負極電解液之循環系統,以完成電池之充放電過程。其中,該第二循環泵系統152係由至少一組以上循環泵及至少一套以上循環管路組成;於本實施例中,本發明配合該些電池堆11、11a之數量,係以二組循環泵1521、1522(或其一)及至少一套以上循環管路組成該第二循環泵系統152為例。The negative electrode electrolyte 151 is stored in the negative electrode solution tank 15, and the negative electrode electrolyte 151 is taken out from the negative electrode electrolyte tank 15 through a circulation pump and a circulation line in a second circulation pump system 152, and the flow rate is controlled. After adjusting the flow rate, the unit 20 injects the battery stacks 11 and 11a, and completes an electrochemical reaction in the battery stacks 11 and 11a to generate and/or discharge direct current electric energy, and the reacted negative electrode electrolyte enters the negative electrode heat exchanger 13 . After the reaction, the negative electrode electrolyte is maintained in an optimal working temperature range, and then pumped back to the negative electrode electrolyte tank 15, and the negative electrode electrolyte tank 15 and the negative electrode heat exchanger 13 and the battery stacks 11 are 11a forms a circulation system of a negative electrolyte to complete the charging and discharging process of the battery. The second circulating pump system 152 is composed of at least one set of circulating pumps and at least one set of circulating pipelines. In the present embodiment, the present invention cooperates with the number of the battery stacks 11 and 11a, and is divided into two groups. The circulation pump 1521, 1522 (or one thereof) and at least one set of circulation lines constitute the second circulation pump system 152 as an example.

是以,為實現本模組所具有之多組電池堆之充放電同步功能,可經由整體模組之控制選擇,控制該電池堆11與該電池堆11a係同時充電或同時放電,亦或一充電另一放電。當該電池堆11與該電池堆11a進行同樣的充電或放電功能時,該正極電解液141之第一循環泵系統142中,該循環泵1421與其循環管路及該循環泵1422與其循環管路,以及該負極電解液151之第二循環泵系統152中,該循環泵1521與其循環管路及該循環泵1522與其循環管路,係可選擇各自之任意循環泵及循環管路來進行運轉,或亦可同時進行運轉;當該電池堆11與該電池堆11a分別進行一充電而另一放電時,則該正極電解液141之第一循環泵系統142中,該循環泵1421與其循環管路及該循環泵1422與其循環管路,以及該負極電解液151之第二循環泵系統152中,該循環泵1521與其循環管路及該循環泵1522與其循環管路,需分成二組循環泵及二套循環管路來分開運轉。由於本模組可依需求串連至少一套以上之多套電池堆組合,因此可配合電池堆之數量整合多組循環管路與循環泵,之後可依需求進行不同組合之充放電同步運轉。Therefore, in order to realize the charge and discharge synchronization function of the plurality of battery stacks of the module, the battery stack 11 and the battery stack 11a can be controlled to be simultaneously charged or simultaneously discharged through the control selection of the overall module, or a Charge another discharge. When the battery stack 11 performs the same charging or discharging function as the battery stack 11a, the circulating pump system 1412 of the positive electrode electrolyte 141, the circulating pump 1421 and the circulating pipe thereof, and the circulating pump 1422 and its circulating pipeline And the second circulating pump system 152 of the negative electrode electrolyte 151, the circulating pump 1521 and the circulating pipe thereof, the circulating pump 1522 and the circulating pipe thereof can be operated by selecting any of the circulating pumps and the circulating pipes. Alternatively, the battery stack 11 and the battery stack 11a are charged separately and the other battery is discharged. In the first circulating pump system 142 of the positive electrode electrolyte 141, the circulating pump 1421 and the circulating circuit thereof are And the circulation pump 1422 and its circulation line, and the second circulation pump system 152 of the negative electrolyte 151, the circulation pump 1521 and its circulation pipeline and the circulation pump 1522 and its circulation pipeline are divided into two groups of circulation pumps and Two sets of circulation lines run separately. Since the module can be connected with at least one set of more than one set of battery stacks according to requirements, multiple sets of circulating pipelines and circulating pumps can be integrated with the number of battery stacks, and then different combinations of charging and discharging can be synchronously operated according to requirements.

該恆溫槽16係分別與該正、負極熱交換器12、13及該正、負極電解液槽14、15連接,用以控制該正、負極電解液141、151與該些電池堆11、11a之溫度範圍,不僅可維持在恆溫之狀態下,並可配合外在環境溫度高低而調整系統溫度,以適應各種嚴苛之環境需求。The constant temperature tank 16 is connected to the positive and negative electrode heat exchangers 12 and 13 and the positive and negative electrolyte tanks 14 and 15 respectively for controlling the positive and negative electrolytes 141 and 151 and the battery stacks 11 and 11a. The temperature range can be maintained not only at a constant temperature, but also with the temperature of the external environment to adjust the system temperature to meet various harsh environmental requirements.

該充放電系統17係與該些電池堆11、11a連接,用以對該些電池堆11、11a進行充放電。當充電時,可與市電或再生能源作連結,以直流/交流轉換之方式進行本模組之充電;當放電時,係以直流/交流轉換之方式,連接至任一負載進行放電。The charge and discharge system 17 is connected to the battery stacks 11 and 11a for charging and discharging the battery stacks 11 and 11a. When charging, it can be connected with mains or renewable energy to charge the module in DC/AC conversion mode; when discharging, it is connected to any load for discharging by DC/AC conversion.

該監控系統19係用以自動監控該流量控制單元20之流量計、比例式控制閥、壓力感測器、或頻率變動器,且透過指令控制該流量控制單元20之流量、閥體之開關、壓力調整、或循環泵之頻率之作動,並透過壓力及循環泵之頻率進行多功能之控制,在不同充放電之荷電狀態(State Of Charge, SOC)下調整流量、壓力或循環泵之頻率以達到最佳節電及操作效率之目的。The monitoring system 19 is configured to automatically monitor the flow meter, proportional control valve, pressure sensor, or frequency variator of the flow control unit 20, and control the flow of the flow control unit 20, the switch of the valve body through commands, Pressure adjustment, or the frequency of the circulating pump, and multi-function control through the pressure and the frequency of the circulating pump, adjusting the flow rate, pressure or circulating pump frequency under different state of charge (SOC) To achieve the best energy saving and operational efficiency.

上述多功能整合型液流電池模組更包括一外部電源21,其可為市電或太陽光電、風力發電等再生能源。當初始運轉時,係以該外部電源21作為電力供給源,提供交流電能給該監控系統19、該第一循環泵系統142、該第二循環泵系統152、該流量控制單元20、及該恆溫槽16使用。當帶動整體液流電池模組作動至產生直流電能後,則透過該直流/交流轉換器18,將該些電池堆11、11a輸出之直流電能轉換為交流電能,再以本模組生產之交流電能提供給該監控系統19、該第一循環泵系統142、該第二循環泵系統152、該流量控制單元20、及該恆溫槽16使用。The multi-functional integrated flow battery module further includes an external power source 21, which can be a renewable energy source such as a commercial power or a solar photovoltaic or a wind power generation. When the initial operation is performed, the external power source 21 is used as a power supply source to provide AC power to the monitoring system 19, the first circulation pump system 142, the second circulation pump system 152, the flow control unit 20, and the constant temperature. The slot 16 is used. After the whole liquid flow battery module is activated to generate DC power, the DC power outputted from the battery stacks 11 and 11a is converted into AC power through the DC/AC converter 18, and the AC power produced by the module is used. The monitoring system 19, the first circulating pump system 142, the second circulating pump system 152, the flow control unit 20, and the thermostat 16 can be used.

上述多功能整合型液流電池模組更包括一緊急停機裝置(圖中未示),用以當發生緊急狀況時,可進行立即停機處理。The multifunctional integrated flow battery module further includes an emergency stop device (not shown) for performing an immediate shutdown process in the event of an emergency.

上述正、負極電解液槽14、15之間連通之管路上設有一閥體22,其係依據該正、負極電解液141、151之成份及液位進行開關。當該正、負極電解液141、151之成份相同時,該閥體22係經由設定開啟週期控制開啟時程,在該正、負極電解液槽14、15內液位發生變化而不同高時,透過該閥體22之開啟使該正、負極電解液槽14、15相通,進而使其液面相同;當該正、負極電解液141、151之成份不相同時,該閥體22係設定為常關( alwaysoff)。此外,該閥體22可連接有一加壓裝置(圖中未示),透過加壓使流速加快,促使液位加速相同。A valve body 22 is disposed on the pipeline communicating between the positive and negative electrolyte tanks 14, 15 and is switched according to the components and liquid levels of the positive and negative electrolytes 141 and 151. When the components of the positive and negative electrolytes 141 and 151 are the same, the valve body 22 controls the opening time period by setting the opening period, and when the liquid level changes in the positive and negative electrolyte tanks 14 and 15 and is different, The positive and negative electrolyte tanks 14, 15 are communicated through the opening of the valve body 22, so that the liquid level is the same; when the components of the positive and negative electrolytes 141, 151 are different, the valve body 22 is set to Always off ( alwaysoff). In addition, the valve body 22 can be connected with a pressurizing device (not shown), and the flow rate is accelerated by pressurization, so that the liquid level acceleration is the same.

上述正、負極電解液槽14、15內各設有一正、負極混合管143、153,用以將回流之正、負極電解液先灌入管中,再與槽內之正、負極電解液141、151混合。The positive and negative electrolyte tanks 14 and 15 are respectively provided with a positive and negative electrode mixing tubes 143 and 153 for injecting the positive and negative electrolytes flowing back into the tube, and then the positive and negative electrolytes 141 in the tank. 151 mixed.

上述正、負極電解液槽14、15、該些循環管路、及該些電池堆11、11a之位置設有一液體洩漏收集槽(圖中未示),用以將洩漏之正、負極電解液收集。如是,藉由上述揭露之結構構成一全新之多功能整合型液流電池模組。The positive and negative electrolyte tanks 14, 15 , the circulation lines, and the positions of the battery stacks 11 and 11a are provided with a liquid leakage collecting tank (not shown) for leaking the positive and negative electrolytes. collect. If so, a new multi-functional integrated flow battery module is constructed by the above disclosed structure.

於一具體實施例中,本模組係可組裝於一集裝箱10內,形成可攜帶型之液流電池結構,利用該集裝箱10作為外殼,可架設在船舶、底盤車、貨車、或鐵路車輛上運輸;如此,可依應用之目的,實現整合成完整之行動式電源系統(如電動載具、移動式電源系統)或完整之固定式電源系統(如電力儲能、液流電池充放電與流量管理系統)。當運用時,本模組可提供所需的電力容量,利用具流動性可抽換式電解液之特性,不僅可藉由導入流動與儲存能量方式,視不同儲能運用情境調整電池系統之輸出功率與能量,以節省充電時程與降低儲能成本而發揮最大效益,更可透過直流/交流轉換器轉換成家庭用電,或以充放電系統提供市電之交流(AC)充電,之後轉換成直流(DC)供電用於電動車或電動載具上,以直接置換電解液完成短時間內充電,達到有效提升充電效率,並且該電池堆可進一步放置不同種類之液流電池,其電解液亦隨著液流電池之種類直接進行抽換,透過電解液可以快速更換充填,因此可以更方便地使用在各種不同之液流電池,並可對各種不同種類之液流電池模組進行測試;此外,本發明藉由一組以上之多組電池堆、循環泵及其循環管路之組合,係可實現充放電同步之應用,並藉由不同之操作策略及控制參數,經由系統來作準確之操控及安全監控。再者,亦可透過恆溫槽將整體模組溫控至所需溫度範圍,不僅可維持在恆溫狀態下,並可配合外在環境溫度高低而調整系統溫度,以適應各種嚴苛之環境需求。In a specific embodiment, the module can be assembled in a container 10 to form a portable flow battery structure, and the container 10 can be used as a casing to be mounted on a ship, a chassis, a truck, or a railway vehicle. Transportation; thus, integration into a complete mobile power system (such as electric vehicles, mobile power systems) or complete fixed power systems (such as power storage, flow battery charging and discharging, and flow) Management system). When used, this module can provide the required power capacity, using the characteristics of the fluid exchangeable electrolyte, not only by introducing the flow and storage energy, but also adjusting the output of the battery system according to different energy storage scenarios. Power and energy, to save the charging time and reduce energy storage costs to maximize the benefits, can be converted to household electricity through DC / AC converter, or provide AC (AC) charging of the mains with a charging and discharging system, and then converted into The direct current (DC) power supply is used on the electric vehicle or the electric vehicle to directly replace the electrolyte to complete the charging in a short time, thereby effectively improving the charging efficiency, and the battery stack can further be placed with different types of liquid flow batteries, and the electrolyte thereof is also As the flow battery is directly exchanged, the filling can be quickly replaced by the electrolyte, so that it can be more conveniently used in a variety of different flow batteries, and various types of flow battery modules can be tested; The invention can realize the application of charging and discharging synchronization by a combination of more than one group of battery stacks, circulating pumps and circulating pipes thereof. And by the different operating strategies and control parameters, through manipulation of the system to make accurate and security monitoring. In addition, the whole module can be temperature controlled to the required temperature range through the constant temperature bath, not only can be maintained at a constant temperature, but also can adjust the system temperature in accordance with the external environment temperature to meet various harsh environmental requirements.

綜上所述,本發明係一種多功能整合型液流電池模組,可有效改善習用之種種缺點,利用具流動性可抽換式電解液之特性,不僅可藉由導入流動與儲存能量方式,視不同儲能運用情境調整電池系統之輸出功率與能量,以節省充電時程與降低儲能成本而發揮最大效益,更可用於電動載具上,以直接置換電解液完成短時間內充電,達到有效提升充電效率,並透過電解液可以快速更換充填,因此可對各種不同種類之液流電池模組進行測試;再者,透過恆溫槽係可將整體模組溫控至所需溫度範圍,不僅可維持在恆溫狀態下,並可配合外在環境溫度高低而調整系統溫度,以適應各種嚴苛之環境需求;此外,藉由一組以上之多組電池堆、循環泵及其循環管路之組合,可實現充放電同步之應用,並藉由不同之操作策略及控制參數,經由系統來作準確之操控及安全監控。在應用上,依應用之目的,可實現整合成完整之行動式電源系統或完整之固定式電源系統;可透過直流/交流轉換器轉換成家庭用電,或以充放電系統提供市電之交流充電,之後轉換成直流供電用於電動車或電動載具上,進而使本發明之産生能更進步、更實用、更符合使用者之所須,確已符合發明專利申請之要件,爰依法提出專利申請。In summary, the present invention is a multifunctional integrated flow battery module, which can effectively improve various shortcomings of the conventional use, and utilizes the characteristics of the fluid exchangeable electrolyte, not only by introducing flow and storage energy. According to different storage energy use scenarios, the output power and energy of the battery system are adjusted to save the charging time and reduce the energy storage cost to maximize the benefits, and can be used on the electric vehicle to directly replace the electrolyte to complete the charging in a short time. It can effectively improve the charging efficiency and can quickly change the filling through the electrolyte. Therefore, various types of flow battery modules can be tested. Furthermore, the whole module can be temperature controlled to the required temperature range through the constant temperature tank system. Not only can it be kept at a constant temperature, but also can adjust the system temperature to meet the harsh environment requirements with the external environment temperature; in addition, with more than one group of battery stacks, circulating pumps and their circulation pipelines The combination can realize the application of charge and discharge synchronization, and through the different operation strategies and control parameters, the system can be used for accurate control and safety. Control. In application, for the purpose of application, it can be integrated into a complete mobile power system or a complete fixed power system; it can be converted into household power through a DC/AC converter, or AC charging can be provided in a charging and discharging system. And then converted into DC power for use on electric vehicles or electric vehicles, so that the invention can be made more progressive, more practical, and more in line with the needs of the user. It has indeed met the requirements of the invention patent application, and patented according to law. Application.

惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍;故,凡依本發明申請專利範圍及發明說明書內容所作之簡單的等效變化與修飾,皆應仍屬本發明專利涵蓋之範圍內。However, the above is only the preferred embodiment of the present invention, and the scope of the present invention is not limited thereto; therefore, the simple equivalent changes and modifications made in accordance with the scope of the present invention and the contents of the invention are modified. All should remain within the scope of the invention patent.

10‧‧‧集裝箱 10‧‧‧ container

11、11a‧‧‧電池堆 11, 11a‧‧‧ battery stack

12‧‧‧正極熱交換器 12‧‧‧ positive heat exchanger

13‧‧‧負極熱交換器 13‧‧‧Negative heat exchanger

14‧‧‧正極電解液槽 14‧‧‧ positive electrolyte tank

141‧‧‧正極電解液 141‧‧‧ positive electrolyte

142‧‧‧第一循環泵系統 142‧‧‧First Circulating Pump System

1421、1422‧‧‧循環泵 1421, 1422‧‧ ‧Circulating pump

15‧‧‧負極電解液槽 15‧‧‧Negative electrolyte tank

151‧‧‧負極電解液 151‧‧‧Negative electrolyte

152‧‧‧第二循環泵系統 152‧‧‧Second Circulating Pump System

1521、1522‧‧‧循環泵 1521, 1522‧‧ Circulating pump

16‧‧‧恆溫槽 16‧‧‧ thermostatic bath

17‧‧‧充放電系統 17‧‧‧Charge and discharge system

18‧‧‧直流/交流轉換器 18‧‧‧DC/AC Converter

19‧‧‧監控系統 19‧‧‧Monitoring system

20‧‧‧流量控制單元 20‧‧‧Flow Control Unit

21‧‧‧外部電源 21‧‧‧External power supply

Claims (15)

【第1項】[Item 1] 一種多功能整合型液流電池模組,係包括:
至少一以上電池堆,其根據一正極電解液與一負極電解液進行電化學反應以產生及/或放出直流電能,並輸出反應後之正極電解液與負極電解液;
一正極熱交換器,係與該些電池堆連接,用以對反應後之正極電解液進行熱量交換;
一負極熱交換器,係與該些電池堆連接,用以對反應後之負極電解液進行熱量交換;
一正極電解液槽,其內存放有該正極電解液,係透過一第一循環泵系統將該正極電解液從該正極電解液槽抽出,通過一流量控制單元調整流量後,注入該些電池堆,在該些電池堆內完成電化學反應以產生及/或放出直流電能,反應後之正極電解液進入該正極熱交換器,使該反應後之正極電解液保持在最佳工作溫度範圍內,再送回該正極電解液槽,令該正極電解液槽與該正極熱交換器及該些電池堆形成一正極電解液之循環系統,以完成電池之充放電過程;
一負極電解液槽,其內存放有該負極電解液,係透過一第二循環泵系統將該負極電解液從該負極電解液槽抽出,通過該流量控制單元調整流量後,注入該些電池堆,在該些電池堆內完成電化學反應以產生及/或放出直流電能,反應後之負極電解液進入該負極熱交換器,使該反應後之負極電解液保持在最佳工作溫度範圍內,再送回該負極電解液槽,令該負極電解液槽與該負極熱交換器及該些電池堆形成一負極電解液之循環系統,以完成電池之充放電過程;
一恆溫槽,係分別與該正、負極熱交換器及該正、負極電解液槽連接,用以控制該正、負極電解液與該些電池堆之溫度範圍,不僅可維持在恆溫狀態下,並可配合外在環境溫度高低而調整系統溫度,以適應各種嚴苛之環境需求;
一充放電系統,係與該些電池堆連接,用以對該些電池堆進行充放電,當充電時,可與市電或再生能源作連結,以直流/交流轉換之方式進行充電,當放電時,係以直流/交流轉換之方式,連接至任一負載進行放電;以及
一監控系統,用以自動監控該流量控制單元,且透過指令控制該流量控制單元之流量、閥體之開關、壓力調整、或循環泵之頻率之作動,並透過壓力及循環泵之頻率進行多功能之控制,在不同充放電之荷電狀態(State Of Charge, SOC)下調整流量、壓力或循環泵之頻率。
A multifunctional integrated flow battery module includes:
At least one or more battery stacks are electrochemically reacted with a negative electrode electrolyte to generate and/or discharge DC power, and output the reacted positive electrode electrolyte and negative electrode electrolyte;
a positive heat exchanger connected to the plurality of battery stacks for performing heat exchange on the reacted positive electrode electrolyte;
a negative heat exchanger connected to the plurality of battery stacks for performing heat exchange on the reacted negative electrode electrolyte;
a positive electrolyte tank in which the positive electrode electrolyte is stored, the positive electrode electrolyte is withdrawn from the positive electrode electrolyte tank through a first circulation pump system, and the flow rate is adjusted by a flow control unit, and then injected into the battery stack Performing an electrochemical reaction in the battery stack to generate and/or discharge DC power, and the reacted positive electrode electrolyte enters the positive electrode heat exchanger to maintain the positive electrode electrolyte in the optimal operating temperature range. And returning to the positive electrolyte tank, so that the positive electrolyte tank and the cathode heat exchanger and the stacks form a positive electrolyte circulating system to complete the charging and discharging process of the battery;
a negative electrolyte tank in which the anode electrolyte is stored, the anode electrolyte is withdrawn from the anode electrolyte tank through a second circulation pump system, and the flow rate is adjusted by the flow control unit, and then injected into the battery stack Performing an electrochemical reaction in the battery stack to generate and/or discharge DC power, and the reacted anode electrolyte enters the anode heat exchanger to maintain the anode electrolyte in the optimal operating temperature range. And returning to the negative electrolyte tank, the anode electrolyte tank and the anode heat exchanger and the battery stacks form a circulation system of the anode electrolyte to complete the charging and discharging process of the battery;
a constant temperature tank is respectively connected to the positive and negative heat exchangers and the positive and negative electrolyte tanks for controlling the temperature ranges of the positive and negative electrolytes and the stacks, not only being maintained at a constant temperature, The system temperature can be adjusted according to the external environment temperature to meet various harsh environmental requirements;
A charging and discharging system is connected to the battery stacks for charging and discharging the battery stacks. When charging, it can be connected with mains or renewable energy, and charged by DC/AC conversion. Is connected to any load for discharging by DC/AC conversion; and a monitoring system for automatically monitoring the flow control unit, and controlling the flow of the flow control unit, the switch of the valve body, and the pressure adjustment through commands , or the frequency of the circulating pump, and through the pressure and the frequency of the circulating pump to control the multi-function, adjust the flow, pressure or circulating pump frequency under different state of charge (SOC).
【第2項】[Item 2] 依申請專利範圍第1項所述之多功能整合型液流電池模組,更包括一直流/交流轉換器,用以將該電池堆輸出之直流電能轉換為交流電能後,提供給該監控系統、該第一循環泵系統、該第二循環泵系統、該流量控制單元、及該恆溫槽使用。The multifunctional integrated flow battery module according to the first aspect of the patent application scope further includes a DC/AC converter for converting the DC power outputted from the battery stack into AC power, and then providing the monitoring system The first circulating pump system, the second circulating pump system, the flow control unit, and the thermostat are used. 【第3項】[Item 3] 依申請專利範圍第1項所述之多功能整合型液流電池模組,更包括一外部電源,用以在初始運轉時,作為電力供給源,提供交流電能給該監控系統、該第一循環泵系統、該第二循環泵系統、該流量控制單元、及該恆溫槽使用。The multifunctional integrated flow battery module according to claim 1 of the patent application scope further includes an external power source for supplying AC power to the monitoring system as the power supply source during initial operation, the first cycle The pump system, the second circulation pump system, the flow control unit, and the thermostat are used. 【第4項】[Item 4] 依申請專利範圍第1項所述之多功能整合型液流電池模組,其中,該流量控制單元係包含一流量計、一比例式控制閥、一壓力感測器、及一頻率變動器。The multi-functional integrated flow battery module according to claim 1, wherein the flow control unit comprises a flow meter, a proportional control valve, a pressure sensor, and a frequency variator. 【第5項】[Item 5] 依申請專利範圍第1項所述之多功能整合型液流電池模組,其中,該正、負極電解液槽之間連通之管路上設有一閥體,係依據該正、負極電解液之成份及液位進行開關。According to the multi-functional integrated flow battery module of claim 1, wherein the pipeline connecting the positive and negative electrolyte tanks is provided with a valve body according to the composition of the positive and negative electrolytes. And the liquid level is switched. 【第6項】[Item 6] 依申請專利範圍第5項所述之多功能整合型液流電池模組,其中,該正、負極電解液之成份相同時,該閥體係經由設定開啟週期控制開啟時程,當該正、負極電解液槽內液位發生變化而不同高時,係透過該閥體之開啟而使其液面回復相同。According to the multifunctional integrated flow battery module of claim 5, wherein when the components of the positive and negative electrolytes are the same, the valve system controls the opening time interval by setting the opening period, when the positive and negative electrodes are When the liquid level in the electrolyte tank changes and is different, the liquid level returns to the same through the opening of the valve body. 【第7項】[Item 7] 依申請專利範圍第5項所述之多功能整合型液流電池模組,其中,該正、負極電解液之成份不相同時,該閥體係設定為常關(always off)。According to the multifunctional integrated flow battery module of claim 5, wherein the components of the positive and negative electrolytes are different, the valve system is set to always off. 【第8項】[Item 8] 依申請專利範圍第5項所述之多功能整合型液流電池模組,其中,該閥體係連接有一加壓裝置。The multi-functional integrated flow battery module according to claim 5, wherein the valve system is connected with a pressurizing device. 【第9項】[Item 9] 依申請專利範圍第1項所述之多功能整合型液流電池模組,其中,該正極電解液槽內設有一正極混合管,用以將回流之正極電解液先灌入管中,再與槽內之正極電解液混合。According to the multi-functional integrated flow battery module described in claim 1, wherein the positive electrolyte tank is provided with a positive electrode mixing tube for injecting the reflux positive electrode electrolyte into the tube, and then the groove The positive electrode electrolyte inside is mixed. 【第10項】[Item 10] 依申請專利範圍第1項所述之多功能整合型液流電池模組,其中,該負極電解液槽內設有一負極混合管,用以將回流之負極電解液先灌入管中,再與槽內之負極電解液混合。According to the multi-functional integrated flow battery module of claim 1, wherein the negative electrolyte tank is provided with a negative electrode mixing tube for injecting the negative electrode electrolyte into the tube first, and then the groove The negative electrode electrolyte inside is mixed. 【第11項】[Item 11] 依申請專利範圍第1項所述之多功能整合型液流電池模組,其中,該第一循環泵系統及該第二循環泵系統各由至少一組以上循環泵及至少一套以上循環管路組成。The multi-functional integrated flow battery module according to claim 1, wherein the first circulating pump system and the second circulating pump system each have at least one set of circulating pumps and at least one set of circulating tubes Road composition. 【第12項】[Item 12] 依申請專利範圍第1或11項所述之多功能整合型液流電池模組,其中,該些電池堆同時進行產生直流電能,或同時進行放出直流電能時,該正極電解液與該負極電解液係可選擇各自之第一循環泵系統與該第二循環泵系統中任意循環泵及循環管路進行運轉,或可同時進行運轉。The multifunctional integrated flow battery module according to claim 1 or 11, wherein the positive electrode electrolyte and the negative electrode are electrolyzed when the battery stack simultaneously generates DC power or simultaneously discharges DC power. The liquid system can select the respective first circulating pump system and any circulating pump and circulating pipeline in the second circulating pump system to operate, or can operate simultaneously. 【第13項】[Item 13] 依申請專利範圍第1或11項所述之多功能整合型液流電池模組,其中,該些電池堆中分別以其中一電池堆進行產生直流電能,另一電池堆進行放出直流電能時,該正極電解液與該負極電解液係將各自之第一循環泵系統與該第二循環泵系統中以二組循環泵及二套循環管路分開運轉。The multifunctional integrated flow battery module according to claim 1 or 11, wherein each of the battery stacks generates DC power by one of the battery stacks, and when the other battery stack emits DC power, The positive electrode electrolyte and the negative electrode electrolyte system separate the first circulating pump system and the second circulating pump system in two sets of circulating pumps and two sets of circulating pipes. 【第14項】[Item 14] 依申請專利範圍第1或11項所述之多功能整合型液流電池模組,其中,該正、負極電解液槽、該些循環管路、及該些電池堆之位置設有一液體洩漏收集槽,用以將洩漏之正、負極電解液收集。The multifunctional integrated flow battery module according to claim 1 or 11, wherein the positive and negative electrolyte tanks, the circulation lines, and the positions of the battery stacks are provided with a liquid leakage collection. A tank for collecting the leaked positive and negative electrolytes. 【第15項】[Item 15] 依申請專利範圍第1項所述之多功能整合型液流電池模組,更包括一緊急停機裝置,用以當發生緊急狀況時,可進行立即停機處理。

The multifunctional integrated flow battery module according to claim 1 of the patent application scope further includes an emergency stop device for performing an immediate shutdown process in the event of an emergency.

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Cited By (2)

* Cited by examiner, † Cited by third party
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CN112803046A (en) * 2020-12-31 2021-05-14 大连融科储能装备有限公司 Flow battery pile with built-in SOC battery
CN114335647A (en) * 2021-12-31 2022-04-12 寰泰储能科技股份有限公司 Shutdown protection system and method for liquid flow energy storage system

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112803046A (en) * 2020-12-31 2021-05-14 大连融科储能装备有限公司 Flow battery pile with built-in SOC battery
CN112803046B (en) * 2020-12-31 2024-04-19 大连融科储能装备有限公司 Flow battery pile with built-in SOC battery
CN114335647A (en) * 2021-12-31 2022-04-12 寰泰储能科技股份有限公司 Shutdown protection system and method for liquid flow energy storage system
WO2023125673A1 (en) * 2021-12-31 2023-07-06 寰泰储能科技股份有限公司 Shutdown protection system and method for liquid flow energy storage system

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