TWI518795B - Manufacturing method for semiconductor device having metal gate - Google Patents

Manufacturing method for semiconductor device having metal gate Download PDF

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TWI518795B
TWI518795B TW101116571A TW101116571A TWI518795B TW I518795 B TWI518795 B TW I518795B TW 101116571 A TW101116571 A TW 101116571A TW 101116571 A TW101116571 A TW 101116571A TW I518795 B TWI518795 B TW I518795B
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layer
gate trench
semiconductor device
gate
metal
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TW101116571A
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TW201347044A (en
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賴建銘
黃瑞民
黃同雋
許哲華
陳奕文
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聯華電子股份有限公司
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具有金屬閘極之半導體元件之製造方法Method for manufacturing semiconductor element having metal gate

本發明是有關於一種具有金屬閘極之半導體元件的製造方法。The present invention relates to a method of fabricating a semiconductor device having a metal gate.

金氧半電晶體是一種廣泛使用於諸如是記憶元件、影像感測器或是顯示器等各種半導體元件的基本結構。隨著電子元件輕、薄、短、小的需求,為了維持互補型金氧半電晶體(CMOS)持續的微縮,高介電常數介電層(High-K)與金屬閘電極(Metal gate)技術已成為邏輯CMOS製程技術的趨勢。為能在金屬閘電極與閘極介電層的介面提供正確適當的功函數值,通常在NMOS與PMOS的金屬閘極與高介電常數介電層之間必須提供不同的功函數金屬層。Gold oxide semi-transistors are a basic structure widely used in various semiconductor elements such as memory elements, image sensors, or displays. High dielectric constant dielectric (High-K) and metal gate (Metal gate) in order to maintain the continuous miniaturization of complementary metal oxide semi-transistors (CMOS) with the demand for light, thin, short, and small electronic components. Technology has become a trend in logic CMOS process technology. In order to provide a proper and appropriate work function value at the interface between the metal gate electrode and the gate dielectric layer, a different work function metal layer must be provided between the metal gate of the NMOS and PMOS and the high-k dielectric layer.

然而,功函數金屬層易在閘極溝渠開口處形成懸突部(overhang),使得閘極溝渠開口的縮小,造成填充金屬層無法順利填入,或導致填充金屬層在閘極溝渠中產生縫隙,而影響元件的可靠度。However, the work function metal layer easily forms an overhang at the opening of the gate trench, which causes the opening of the gate trench to shrink, causing the filling metal layer to not be filled smoothly, or causing the filling metal layer to create a gap in the gate trench. And affect the reliability of the component.

本發明提供一種具有金屬閘極之半導體元件的製造方法,其可以在NMOS與PMOS的金屬閘極與高介電常數介電層之間提供不同的功函數金屬層,且可以使得填充金屬層可以順利填入閘極溝渠之中。The present invention provides a method of fabricating a semiconductor device having a metal gate, which can provide a different work function metal layer between a metal gate of a NMOS and a PMOS and a high-k dielectric layer, and can make the filler metal layer Successfully filled into the gate ditches.

本發明提供一種具有金屬閘極之半導體元件之製造方法。首先,提供一基底,基底表面形成有第一半導體元件與第二半導體元件,且第一半導體元件與第二半導體元件中分別形成有第一閘極溝渠與第二閘極溝渠。然後,於第一閘極溝渠與第二閘極溝渠中形成第一功函數金屬層。接著,於基底上形成第一遮蔽層。之後,進行第一次移除部分第一遮蔽層之步驟,使留下的第一遮蔽層位於第二閘極溝渠的底部並且填滿第一閘極溝渠。繼之,進行第二次移除部分第一遮蔽層之步驟,留下位於第一閘極溝渠底部的第一遮蔽層,使第二閘極溝渠以及第一閘極溝渠側壁的第一功函數金屬層裸露出來。然後,以第一遮蔽層為罩幕,移除未被第一遮蔽層覆蓋的第一功函數金屬層,只留下第一閘極溝渠底部的第一功函數金屬層。接著,移除第一遮蔽層。The present invention provides a method of fabricating a semiconductor device having a metal gate. First, a substrate is provided, the first semiconductor element and the second semiconductor element are formed on the surface of the substrate, and the first gate trench and the second gate trench are respectively formed in the first semiconductor component and the second semiconductor component. Then, a first work function metal layer is formed in the first gate trench and the second gate trench. Next, a first shielding layer is formed on the substrate. Thereafter, the step of removing a portion of the first shielding layer is performed for the first time, so that the remaining first shielding layer is located at the bottom of the second gate trench and fills the first gate trench. Then, the second step of removing a portion of the first shielding layer is performed, leaving a first shielding layer at the bottom of the first gate trench, so that the first working function of the second gate trench and the sidewall of the first gate trench The metal layer is bare. Then, with the first shielding layer as a mask, the first work function metal layer not covered by the first shielding layer is removed, leaving only the first work function metal layer at the bottom of the first gate trench. Next, the first obscuring layer is removed.

在本發明之一實施例中,上述方法更包括:移除部分第一遮蔽層之前,於第一遮蔽層上形成圖案化的罩幕層,圖案化的罩幕層覆蓋第一半導體元件,裸露出第二半導體元件;以圖案化的罩幕層為罩幕,進行第一次移除部分第一遮蔽層步驟,移除第二半導體元件上的部分第一遮蔽層;以及移除圖案化的罩幕層。In an embodiment of the invention, the method further includes: forming a patterned mask layer on the first shielding layer before removing a portion of the first shielding layer, the patterned mask layer covering the first semiconductor component, bare a second semiconductor component; using a patterned mask layer as a mask, performing a first removal of a portion of the first masking layer, removing a portion of the first masking layer on the second semiconductor component; and removing the patterned Cover layer.

在本發明之一實施例中,進行第一次移除部分第一遮蔽層之上述步驟的方法包括蝕刻法。In one embodiment of the invention, the method of performing the first step of removing a portion of the first masking layer for the first time comprises an etching process.

在本發明之一實施例中,進行第二次移除部分第一遮蔽層之上述步驟的方法包括蝕刻法。In one embodiment of the invention, the method of performing the second step of removing a portion of the first masking layer comprises etching.

在本發明之一實施例中,上述第一遮蔽層包括介電抗反射塗層(dielectric anti-reflection coating,DARC)、光吸收氧化(light absorbing oxide,DUO)層、底部抗反射塗層(bottom anti-reflective coating,BARC)或犧牲吸光材料(sacrificial light absorbing material,SLAM)層。In an embodiment of the invention, the first shielding layer comprises a dielectric anti-reflection coating (DARC), a light absorbing oxide (DUO) layer, and a bottom anti-reflective coating (bottom). Anti-reflective coating (BARC) or sacrificial light absorbing material (SLAM) layer.

在本發明之一實施例中,上述第一功函數金屬層的材料包括氮化鈦、碳化鈦、氮化鉭、碳化鉭、碳化鎢或氮化鋁鈦。In an embodiment of the invention, the material of the first work function metal layer comprises titanium nitride, titanium carbide, tantalum nitride, tantalum carbide, tungsten carbide or aluminum titanium nitride.

在本發明之一實施例中,上述之具有金屬閘極之半導體元件之製造方法,更包括於第一閘極溝渠與第二閘極溝渠中形成第二功函數金屬層。In an embodiment of the invention, the method for fabricating a semiconductor device having a metal gate further includes forming a second work function metal layer in the first gate trench and the second gate trench.

在本發明之一實施例中,上述第二功函數金屬層包括鋁化鈦層、鋁化鋯層、鋁化鎢層、鋁化鉭層或鋁化鉿層。In an embodiment of the invention, the second work function metal layer comprises a titanium aluminide layer, a zirconium aluminide layer, a tungsten aluminide layer, a tantalum aluminide layer or a tantalum aluminide layer.

在本發明之一實施例中,上述之具有金屬閘極之半導體元件之製造方法,更包括形成填充金屬層,以填滿第一閘極溝渠與第二閘極溝渠。In an embodiment of the invention, the method for fabricating a semiconductor device having a metal gate further includes forming a fill metal layer to fill the first gate trench and the second gate trench.

在本發明之一實施例中,上述填充金屬層包括鋁、鋁化鈦或氧化鋁鈦。In an embodiment of the invention, the filler metal layer comprises aluminum, titanium aluminide or titanium oxide.

在本發明之一實施例中,上述方法更包括於第一閘極溝渠與第二閘極溝渠中形成頂部阻障層,覆蓋該第一功函數金屬層。In an embodiment of the invention, the method further includes forming a top barrier layer in the first gate trench and the second gate trench to cover the first work function metal layer.

在本發明之一實施例中,上述頂部阻障層的材料包括氮化鈦。In an embodiment of the invention, the material of the top barrier layer comprises titanium nitride.

在本發明之一實施例中,於形成頂部阻障層之前,上述方法更包括於該第一閘極溝渠與該第二閘極溝渠中形成一第二功函數金屬層。In an embodiment of the invention, before the forming the top barrier layer, the method further includes forming a second work function metal layer in the first gate trench and the second gate trench.

在本發明之一實施例中,上述方法更包括形成填充金屬層,以填滿第一閘極溝渠與第二閘極溝渠。In an embodiment of the invention, the method further includes forming a fill metal layer to fill the first gate trench and the second gate trench.

在本發明之一實施例中,於形成第一功函數金屬層之前,上述方法更包括於第一閘極溝渠與第二閘極溝渠內形成底部阻障層。In an embodiment of the invention, before the forming the first work function metal layer, the method further comprises forming a bottom barrier layer in the first gate trench and the second gate trench.

在本發明之一實施例中,上述底部阻障層的材料包括氮化鈦。In an embodiment of the invention, the material of the bottom barrier layer comprises titanium nitride.

在本發明之一實施例中,於形成第一功函數金屬層之前,上述方法更包括於底部阻障層上形成蝕刻停止層。In an embodiment of the invention, before the forming the first work function metal layer, the method further comprises forming an etch stop layer on the bottom barrier layer.

在本發明之一實施例中,上述蝕刻停止層的材料包括氮化鉭。In an embodiment of the invention, the material of the etch stop layer comprises tantalum nitride.

在本發明之一實施例中,在形成頂部阻障層之前,上述方法更包括:於基底上形成第二遮蔽層,覆蓋第一半導體元件與第二半導體元件;部分移除第二遮蔽層,裸露出第一閘極溝渠與第二閘極溝渠側壁的蝕刻停止層;以留下的第二遮蔽層為罩幕,移除裸露出的部分蝕刻停止層以及部分底部阻障層;以及移除第二遮蔽層。In an embodiment of the present invention, before the forming the top barrier layer, the method further includes: forming a second shielding layer on the substrate, covering the first semiconductor element and the second semiconductor element; and partially removing the second shielding layer, Excluding an etch stop layer of the sidewalls of the first gate trench and the second gate trench; removing the exposed portion of the etch stop layer and a portion of the bottom barrier layer by using the remaining second mask layer as a mask; and removing The second shielding layer.

在本發明之一實施例中,以留下的第二遮蔽層為罩幕,移除部分蝕刻停止層以及部分底部阻障層之後,留下的蝕刻停止層以及底部阻障層的頂部低於第一閘極溝渠頂部以及第二閘極溝渠頂部。In an embodiment of the present invention, after the second shielding layer is left as a mask, after removing a portion of the etch stop layer and a portion of the bottom barrier layer, the remaining etch stop layer and the top of the bottom barrier layer are lower than The top of the first gate trench and the top of the second gate trench.

在本發明之一實施例中,上述第二遮蔽層包括介電抗反射塗層、光吸收氧化層、底部抗反射塗層層或犧牲吸光材料層。In an embodiment of the invention, the second shielding layer comprises a dielectric anti-reflective coating, a light absorbing oxide layer, a bottom anti-reflective coating layer or a sacrificial light absorbing material layer.

本發明之具有金屬閘極之半導體元件的製造方法可以在NMOS與PMOS的金屬閘極與高介電常數介電層之間提供不同的功函數金屬層,且可以使得填充金屬層可以順利填入閘極溝渠之中。The method for fabricating a semiconductor device having a metal gate of the present invention can provide different work function metal layers between the metal gate of the NMOS and the PMOS and the high-k dielectric layer, and the filling metal layer can be smoothly filled in. In the gate ditches.

為讓本發明之上述特徵和優點能更明顯易懂,下文特舉實施例,並配合所附圖式作詳細說明如下。The above described features and advantages of the present invention will be more apparent from the following description.

圖1A至圖1K係為本發明第一實施例之一種具有金屬閘極之半導體元件之製造方法之剖面示意圖。1A to 1K are schematic cross-sectional views showing a method of fabricating a semiconductor device having a metal gate according to a first embodiment of the present invention.

請參照圖1A,本實施例首先提供基底100,例如矽基底、含矽基底、或矽覆絕緣(silicon-on-insulator,SOI)基底。基底100上形成有第一半導體元件110與第二半導體元件112,而第一半導體元件110與第二半導體元件112之間的基底100內係形成有提供電性隔離的淺溝隔離(shallow trench isolation,STI)結構102。第一半導體元件110具有第一導電型,而第二半導體元件112具有第二導電型,且第一導電型與第二導電型互補(complementary)。在本實施例中,第一半導體元件110係為p型半導體元件;而第二半導體元件112係為n型半導體元件。Referring to FIG. 1A, this embodiment first provides a substrate 100, such as a germanium substrate, a germanium-containing substrate, or a silicon-on-insulator (SOI) substrate. A first semiconductor element 110 and a second semiconductor element 112 are formed on the substrate 100, and a shallow trench isolation is provided in the substrate 100 between the first semiconductor element 110 and the second semiconductor element 112 to provide electrical isolation. , STI) structure 102. The first semiconductor element 110 has a first conductivity type, and the second semiconductor element 112 has a second conductivity type, and the first conductivity type and the second conductivity type are complementary. In the present embodiment, the first semiconductor element 110 is a p-type semiconductor element; and the second semiconductor element 112 is an n-type semiconductor element.

請繼續參照圖1A,第一半導體元件110與第二半導體元件112分別具有第一閘極溝渠150與第二閘極溝渠152。第一半導體元件110與第二半導體元件112分別包括閘極介電層104、底部阻障層(lower barrier layer) 106與蝕刻停止層(etch stop layer) 108。此外,第一半導體元件110包括第一輕摻雜汲極(light doped drain,LDD) 120與第一源極/汲極130以及間隙壁124;第二半導體元件112包括第二LDD 122與第二源極/汲極132以及間隙壁124。另外,第一源極/汲極130與第二源極/汲極132之表面係分別選擇性地包含有金屬矽化物134。Referring to FIG. 1A , the first semiconductor element 110 and the second semiconductor element 112 respectively have a first gate trench 150 and a second gate trench 152 . The first semiconductor element 110 and the second semiconductor element 112 respectively include a gate dielectric layer 104, a lower barrier layer 106, and an etch stop layer 108. In addition, the first semiconductor component 110 includes a first light doped drain (LDD) 120 and a first source/drain 130 and a spacer 124; the second semiconductor component 112 includes a second LDD 122 and a second Source/drain 132 and spacer 124. In addition, the surface of the first source/drain 130 and the second source/drain 132 respectively selectively include a metal telluride 134.

而且在第一半導體元件110與第二半導體元件112上,係依序形成有接觸窗蝕刻停止層(contact etch stop layer,CESL) 140與內層介電(inter-layer dielectric,ILD)層142。上述元件之製造步驟以及材料選擇,甚至是半導體業界中為提供應力作用更改善電性表現而實施選擇性磊晶成長(selective epitaxial growth,SEG)方法形成源極/汲極130、132等,皆為該領域之人士所熟知,故於此皆不再贅述。Further, on the first semiconductor element 110 and the second semiconductor element 112, a contact etch stop layer (CESL) 140 and an inter-layer dielectric (ILD) layer 142 are sequentially formed. The manufacturing steps and material selection of the above components, and even the selective epitaxial growth (SEG) method for forming the source/drain electrodes 130, 132, etc. in the semiconductor industry to provide stress and improve electrical performance. It is well known to those skilled in the art and will not be described here.

上述閘極介電層104可為二氧化矽層、高介電常數(high dielectric constant,high-k)閘極介電層(介電常數大於4)或其組合。高介電常數材料之介電常數大於4,其可以是金屬氧化物層,例如稀土金屬氧化物層。具有高介電常數材料可選自氧化鉿(hafnium oxide,HfO2)、矽酸鉿氧化合物(hafnium silicon oxide,HfSiO4)、矽酸鉿氮氧化合物(hafnium silicon oxynitride,HfSiON)、氧化鋁(aluminum oxide,Al2O3)、氧化鑭(lanthanum oxide,La2O3)、氧化鉭(tantalum oxide,Ta2O5)、氧化釔(yttrium oxide,Y2O3)、氧化鋯(zirconium oxide,ZrO2)、鈦酸鍶(strontium titanate oxide,SrTiO3)、矽酸鋯氧化合物(zirconium silicon oxide,ZrSiO4)、鋯酸鉿(hafnium zirconium oxide,HfZrO4)、鍶鉍鉭氧化物(strontium bismuth tantalate,SrBi2Ta2O9,SBT)、鋯鈦酸鉛(lead zirconate titanate,PbZrxTi1-xO3,PZT)與鈦酸鋇鍶(barium strontium titanate,BaxSr1-xTiO3,BST)所組成之族群,其中x為介於0與1之間的數值。在高介電常數閘極介電層104與基底100之間,還可設置介面層(interfacial layer)103。介面層103之材質例如是氧化矽。底部阻障層106則包含氮化鈦(titanium nitride,TiN),其形成的方法例如是原子層沉積法。蝕刻停止層108可包含氮化鉭,其形成的方法例如是原子層沉積法,但不限於此。The gate dielectric layer 104 can be a hafnium oxide layer, a high dielectric constant (high-k) gate dielectric layer (dielectric constant greater than 4), or a combination thereof. The high dielectric constant material has a dielectric constant greater than 4, which may be a metal oxide layer, such as a rare earth metal oxide layer. The material having a high dielectric constant may be selected from the group consisting of hafnium oxide (HfO 2 ), hafnium silicon oxide (HfSiO 4 ), hafnium silicon oxynitride (HfSiON), and aluminum oxide (HfSiO). Aluminum oxide, Al 2 O 3 ), lanthanum oxide (La 2 O 3 ), tantalum oxide (Ta 2 O 5 ), yttrium oxide (Y 2 O 3 ), zirconium oxide , ZrO 2 ), strontium titanate oxide (SrTiO 3 ), zirconium silicon oxide (ZrSiO 4 ), hafnium zirconium oxide (HfZrO 4 ), strontium oxide Bismuth tantalate, SrBi 2 Ta 2 O 9 , SBT), lead zirconate titanate (PbZr x Ti 1-x O 3 , PZT) and barium strontium titanate (Ba x Sr 1-x TiO 3 , BST) consisting of a group, where x is a value between 0 and 1. An interfacial layer 103 may also be disposed between the high dielectric constant gate dielectric layer 104 and the substrate 100. The material of the interface layer 103 is, for example, cerium oxide. The bottom barrier layer 106 then comprises titanium nitride (TiN), which is formed by, for example, atomic layer deposition. The etch stop layer 108 may include tantalum nitride, and the method of forming it is, for example, an atomic layer deposition method, but is not limited thereto.

本實施例可與「後高介電常數閘極介電層(high-k last)製程」整合。亦即,上述第一半導體元件110與第二半導體元件112的閘極介電層104為高介電常數材料,且係在虛置閘極形成且移除之後才形成。更詳細地說,其製程方法係在基底100上先形成介面材料層,再形成虛置閘極層。虛置閘極層的材料例如是多晶矽,但不限於此。之後,將介面材料層以及虛置閘極層圖案化,形成圖案化的介面材料層以及虛置閘極。接著,形成CESL 140與ILD層142,並藉由平坦化製程移除部分的CESL 140與ILD層142,直至暴露出第一半導體元件110與第二半導體元件112之虛置閘極。隨後利用適合之蝕刻製程移除第一半導體元件110與第二半導體元件112之虛置閘極,而同時於第一半導體元件110與第二半導體元件112內分別形成第一閘極溝渠150與第二閘極溝渠152。隨後可選擇性地移除介面材料層並重新成長介面層103,然後於基底100上形成高介電常數閘極介電層104。之後,再形成底部阻障層106及/或蝕刻停止層108。This embodiment can be integrated with a "post-high dielectric constant gate-high-k last process". That is, the gate dielectric layer 104 of the first semiconductor element 110 and the second semiconductor element 112 is a high dielectric constant material, and is formed after the dummy gate is formed and removed. In more detail, the process method is to form a layer of interface material on the substrate 100 to form a dummy gate layer. The material of the dummy gate layer is, for example, polycrystalline germanium, but is not limited thereto. Thereafter, the interface material layer and the dummy gate layer are patterned to form a patterned interface material layer and a dummy gate. Next, the CESL 140 and ILD layer 142 are formed, and a portion of the CESL 140 and ILD layer 142 are removed by a planarization process until the dummy gates of the first semiconductor component 110 and the second semiconductor component 112 are exposed. Then, the dummy gates of the first semiconductor element 110 and the second semiconductor element 112 are removed by a suitable etching process, and the first gate trenches 150 and the first semiconductor trenches 110 and the second semiconductor components 112 are respectively formed. Two gate ditches 152. The interface material layer can then be selectively removed and the interface layer 103 re-grown, and then a high dielectric constant gate dielectric layer 104 is formed over the substrate 100. Thereafter, a bottom barrier layer 106 and/or an etch stop layer 108 are formed.

請參照圖1B,在形成蝕刻停止層108後,於基底100上形成第一功函數金屬層160,第一功函數金屬層160填入於第一閘極溝渠150與第二閘極溝渠152內。第一功函數金屬層160可為具有p型導電型的p型功函數金屬層,例如氮化鈦(titanium nitride,TiN)、碳化鈦(titanium carbide,TiC)、氮化鉭(tantalum nitride,TaN)、碳化鉭(tantalum carbide,TaC)、碳化鎢(tungsten carbide,WC)、或氮化鋁鈦(aluminum titanium nitride,TiAlN),但不限於此。第一功函數金屬層160可為單層結構或複合層結構。第一功函數金屬層160的形成方法例如是化學氣相沈積(chemical vapor deposition,CVD)製程、物理氣相沈積(physical vapor deposition,PVD)製程、或原子層沉積(atomic layer deposition,ALD)製程。Referring to FIG. 1B, after the etch stop layer 108 is formed, a first work function metal layer 160 is formed on the substrate 100, and the first work function metal layer 160 is filled in the first gate trench 150 and the second gate trench 152. . The first work function metal layer 160 may be a p-type work function metal layer having a p-type conductivity type, such as titanium nitride (TiN), titanium carbide (TiC), tantalum nitride (TaN) ), tantalum carbide (TaC), tungsten carbide (WC), or aluminum titanium nitride (TiAlN), but is not limited thereto. The first work function metal layer 160 may be a single layer structure or a composite layer structure. The method for forming the first work function metal layer 160 is, for example, a chemical vapor deposition (CVD) process, a physical vapor deposition (PVD) process, or an atomic layer deposition (ALD) process. .

接著,於基底100上形成第一遮蔽層169與罩幕層170。第一遮蔽層169可以是填洞能力良好的膜層,例如是介電抗反射塗層(dielectric anti-reflection coating,DARC)、光吸收氧化(light absorbing oxide,DUO)層、底部抗反射塗層(bottom anti-reflective coating,BARC)或犧牲吸光材料(sacrificial light absorbing material,SLAM)層等,但不限於此,其形成的方法例如是旋轉塗佈法。罩幕層170之材質例如是光阻。Next, a first shielding layer 169 and a mask layer 170 are formed on the substrate 100. The first shielding layer 169 may be a film layer with good hole filling ability, such as a dielectric anti-reflection coating (DARC), a light absorbing oxide (DUO) layer, and a bottom anti-reflection coating. (Bottom anti-reflective coating, BARC) or sacrificial light absorbing material (SLAM) layer, etc., but is not limited thereto, and the method of forming it is, for example, a spin coating method. The material of the mask layer 170 is, for example, a photoresist.

請參照圖1C,圖案化罩幕層170,以形成圖案化的罩幕層170a。圖案化的罩幕層170a覆蓋第一半導體元件110處之第一遮蔽層169,並暴露出第二半導體元件112處之第一遮蔽層169。之後,圖案化的罩幕層170a為罩幕,移除部分未被圖案化的罩幕層170a覆蓋的第一遮蔽層169,留下第二閘極溝渠152之中的第一遮蔽層169a以及第一半導體元件110處的第一遮蔽層169b。第二閘極溝渠152之中的第一遮蔽層169a的表面高度低於第二閘極溝渠152的頂端,使部分的第一功函數金屬層160裸露出來。移除部分未被圖案化的罩幕層170a覆蓋的第一遮蔽層169的方法可以利用合適之蝕刻劑來進行回蝕刻製程。Referring to FIG. 1C, the mask layer 170 is patterned to form a patterned mask layer 170a. The patterned mask layer 170a covers the first masking layer 169 at the first semiconductor component 110 and exposes the first masking layer 169 at the second semiconductor component 112. Thereafter, the patterned mask layer 170a is a mask, removing a portion of the first masking layer 169 that is not covered by the patterned mask layer 170a, leaving a first masking layer 169a among the second gate trenches 152 and The first obscuring layer 169b at the first semiconductor component 110. The surface height of the first shielding layer 169a in the second gate trench 152 is lower than the top end of the second gate trench 152, so that a portion of the first work function metal layer 160 is exposed. The method of removing a portion of the first masking layer 169 that is not covered by the patterned mask layer 170a may utilize an appropriate etchant for the etch back process.

之後,請參照圖1D,移除圖案化的罩幕層170a,使第一半導體元件110處的第一遮蔽層169b裸露出來。移除圖案化的罩幕層170a的方法可以利用乾式法或濕式法或其二者。由於第一閘極溝渠150與第二閘極溝渠152的底部分別有第一遮蔽層169b與169a覆蓋,因此,在後續的電漿蝕刻過程中可以避免電漿穿過第一功函數金屬層160而破壞蝕刻停止層108、底部阻障層106以及高介電常數的閘極介電層104。Thereafter, referring to FIG. 1D, the patterned mask layer 170a is removed to expose the first masking layer 169b at the first semiconductor component 110. The method of removing the patterned mask layer 170a may utilize a dry process or a wet process or both. Since the first gate trench 150 and the bottom of the second gate trench 152 are covered by the first shielding layers 169b and 169a, respectively, the plasma can be prevented from passing through the first work function metal layer 160 during the subsequent plasma etching process. The etch stop layer 108, the bottom barrier layer 106, and the high dielectric constant gate dielectric layer 104 are destroyed.

接著,請參照圖1E,部分移除第一遮蔽層169b,使第二閘極溝渠152之中的第一遮蔽層169a完全移除,留下第一閘極溝渠150底部的第一遮蔽層169c。第一遮蔽層169c的表面高度低於第一閘極溝渠150的頂端,較佳的第一遮蔽層169c的厚度盡可能薄,僅需可以在後續的蝕刻製程中保護位於第一閘極溝渠150底部的第一功函數金屬層160,並盡可能使第一閘極溝渠150側壁的第一功函數金屬層160可以裸露出來。部分移除第一遮蔽層169b的方法可以採用蝕刻法,例如是乾式蝕刻法。Next, referring to FIG. 1E, the first shielding layer 169b is partially removed, so that the first shielding layer 169a in the second gate trench 152 is completely removed, leaving the first shielding layer 169c at the bottom of the first gate trench 150. . The surface of the first shielding layer 169c is lower than the top end of the first gate trench 150. The thickness of the preferred first shielding layer 169c is as thin as possible, and only needs to be protected in the first gate trench 150 in a subsequent etching process. The first work function metal layer 160 at the bottom, and as far as possible, the first work function metal layer 160 on the sidewall of the first gate trench 150 can be exposed. The method of partially removing the first mask layer 169b may employ an etching method such as a dry etching method.

隨後,請參照圖1F,以第一遮蔽層169c為罩幕,利用合適之蝕刻劑移除未被第一遮蔽層169c保護的第一功函數金屬層160。在進行蝕刻時,盡可能移除第一閘極溝渠150側壁的第一功函數金屬層160,僅留下位於第一閘極溝渠150底部的第一功函數金屬層160a,使第一閘極溝渠150側壁的蝕刻停止層108裸露出來。在圖1F中,第一功函數金屬層160a呈U型。在另一實施例中,亦可以控制蝕刻時間,使第一功函數金屬層160a僅覆蓋第一閘極溝渠150的底部,而不會覆蓋第一閘極溝渠150的側壁。Subsequently, referring to FIG. 1F, with the first shielding layer 169c as a mask, the first work function metal layer 160 not protected by the first shielding layer 169c is removed by a suitable etchant. When etching is performed, the first work function metal layer 160 on the sidewall of the first gate trench 150 is removed as much as possible, leaving only the first work function metal layer 160a at the bottom of the first gate trench 150, so that the first gate The etch stop layer 108 on the sidewall of the trench 150 is exposed. In FIG. 1F, the first work function metal layer 160a is U-shaped. In another embodiment, the etching time can also be controlled such that the first work function metal layer 160a covers only the bottom of the first gate trench 150 without covering the sidewall of the first gate trench 150.

其後,請參照圖1G,移除第一遮蔽層169c,使第一功函數金屬層160a的表面裸露出來。移除第一遮蔽層169c的方法可以採用蝕刻法,例如是乾式蝕刻法。之後,於基底100上形成第二遮蔽層174。第二遮蔽層174可以是填洞能力良好的膜層,例如是介電抗反射塗層、光吸收氧化層、底部抗反射塗層層或犧牲吸光材料層等,但不限於此,其形成的方法例如是旋轉塗佈法。Thereafter, referring to FIG. 1G, the first shielding layer 169c is removed to expose the surface of the first work function metal layer 160a. The method of removing the first mask layer 169c may employ an etching method such as a dry etching method. Thereafter, a second shielding layer 174 is formed on the substrate 100. The second shielding layer 174 may be a film layer with good filling ability, such as a dielectric anti-reflective coating, a light absorbing oxide layer, a bottom anti-reflective coating layer or a sacrificial light-absorbing material layer, but is not limited thereto, and is formed by The method is, for example, a spin coating method.

之後,請參照圖1H,移除部分第二遮蔽層174,留下位於第一閘極溝渠150之中的第二遮蔽層174a以及第二閘極溝渠152之中的第二遮蔽層174b,裸露出側壁的蝕刻停止層108。移除部分第二遮蔽層174的方法可以利用合適之蝕刻劑來進行回蝕刻製程。第二遮蔽層174a與174b的厚度盡可能薄,僅需在後續的蝕刻製程中可以保護第一功函數金屬層160a的表面,使其不會遭受破壞即可。Thereafter, referring to FIG. 1H, a portion of the second shielding layer 174 is removed, leaving a second shielding layer 174a located in the first gate trench 150 and a second shielding layer 174b among the second gate trenches 152, bare. The etch stop layer 108 of the sidewall is exited. The method of removing a portion of the second masking layer 174 can utilize an appropriate etchant for the etch back process. The thickness of the second shielding layers 174a and 174b is as thin as possible, and it is only necessary to protect the surface of the first work function metal layer 160a from damage in a subsequent etching process.

之後,請參照圖1I,以第二遮蔽層174a與174b為罩幕,利用合適之蝕刻劑移除未被第二遮蔽層174a與174b保護的蝕刻停止層108與底部阻障層106。此製程可以使第一閘極溝渠150側壁以及第二閘極溝渠152側壁部分的蝕刻停止層108與底部阻障層106移除,使第一閘極溝渠150側壁以及第二閘極溝渠152側壁的高k閘極介電層104裸露出來,留下位於第一閘極溝渠150以及第二閘極溝渠152之中的低高度的U型蝕刻停止層108a與低高度的U型底部阻障層106a。U型蝕刻停止層108a又可稱為第一U型金屬層;U型底部阻障層106a又可稱為第二U型金屬層。第一U型金屬層、第二U型金屬層及第一功函數金屬層160a的側壁高度可相同或不同,三者的高度也不一定如圖1I中所示,各層的高度可藉由蝕刻參數及第一遮蔽層169c與第二遮蔽層174a與174b的高度來調整之。Thereafter, referring to FIG. 1I, with the second shielding layers 174a and 174b as masks, the etch stop layer 108 and the bottom barrier layer 106 not protected by the second shielding layers 174a and 174b are removed by a suitable etchant. The process can remove the etch stop layer 108 and the bottom barrier layer 106 of the sidewalls of the first gate trench 150 and the sidewall portion of the second gate trench 152, such that the sidewalls of the first gate trench 150 and the sidewall of the second gate trench 152 The high-k gate dielectric layer 104 is exposed, leaving a low-level U-shaped etch stop layer 108a and a low-height U-type bottom barrier layer in the first gate trench 150 and the second gate trench 152. 106a. The U-type etch stop layer 108a may also be referred to as a first U-type metal layer; the U-type bottom barrier layer 106a may also be referred to as a second U-type metal layer. The heights of the sidewalls of the first U-shaped metal layer, the second U-shaped metal layer and the first work-function metal layer 160a may be the same or different, and the heights of the three are not necessarily as shown in FIG. 1I, and the height of each layer may be etched by etching. The parameters and the height of the first shielding layer 169c and the second shielding layers 174a and 174b are adjusted.

其後,請參照圖1J,移除第二遮蔽層174a與174b,裸露出第一閘極溝渠150中的第一功函數金屬層160a以及第二閘極溝渠152中的U型蝕刻停止層108a。之後,於基底100上形成第二功函數金屬層162。第二功函數金屬層162可為具有n型導電型之n型功函數金屬層,例如鋁化鈦(titanium aluminide,TiAl)層、鋁化鋯(zirconium aluminide,ZrAl)層、鋁化鎢(tungsten aluminide,WAl)層、鋁化鉭(tantalum aluminide,TaAl)層或鋁化鉿(hafnium aluminide,HfAl)層,但不限於此。此外,第二功函數金屬層162可為單層結構或複合層結構。第二功函數金屬層162可以CVD製程或PVD製程來形成。接下來,於基底100上形成填充金屬層168。所形成之填充金屬層168填入於第一閘極溝渠150與第二閘極溝渠152中。填充金屬層168係用以填滿第一閘極溝渠150與第二閘極溝渠152,可選擇具有優良填充能力與較低阻值的金屬或金屬氧化物,例如鋁(aluminum,Al)、鋁化鈦(titanium aluminide,TiAl)或氧化鋁鈦(titanium aluminum oxide,TiAlO),但不限於此。此外第二功函數金屬層162與填充金屬層168之間較佳可設置頂部阻障層163,頂部阻障層163可包含氮化鈦(TiN),其形成的方法例如是原子層沉積法,但不限於此。Thereafter, referring to FIG. 1J, the second shielding layers 174a and 174b are removed to expose the first work function metal layer 160a in the first gate trench 150 and the U-type etch stop layer 108a in the second gate trench 152. . Thereafter, a second work function metal layer 162 is formed on the substrate 100. The second work function metal layer 162 may be an n-type work function metal layer having an n-type conductivity type, such as a titanium aluminide (TiAl) layer, a zirconium aluminide (ZrAl) layer, and a tungsten aluminide (tungsten). Aluminide, WAl) layer, tantalum aluminide (TaAl) layer or hafnium aluminide (HfAl) layer, but is not limited thereto. Further, the second work function metal layer 162 may be a single layer structure or a composite layer structure. The second work function metal layer 162 can be formed by a CVD process or a PVD process. Next, a fill metal layer 168 is formed on the substrate 100. The formed fill metal layer 168 is filled in the first gate trench 150 and the second gate trench 152. The filling metal layer 168 is used to fill the first gate trench 150 and the second gate trench 152, and may select a metal or metal oxide having excellent filling ability and lower resistance, such as aluminum (aluminum, aluminum), aluminum. Titanium aluminide (TiAl) or titanium aluminum oxide (TiAlO), but is not limited thereto. In addition, a top barrier layer 163 may be disposed between the second work function metal layer 162 and the fill metal layer 168, and the top barrier layer 163 may include titanium nitride (TiN), which is formed by, for example, atomic layer deposition. But it is not limited to this.

最後,請參照圖1K,可再進行平坦化製程,例如CMP製程,用以移除ILD層142上多餘的填充金屬層168、頂部阻障層163以及第二功函數金屬層162,而完成第一金屬閘極168a與第二金屬閘極168b之製造。此外,本實施例亦可再選擇性去除ILD層142與CESL 140等,然後重新形成CESL與介電層,以有效提升半導體元件的電性表現。由於上述CMP製程等步驟係為該技術領域中具通常知識者所知,故於此係不再贅述。Finally, referring to FIG. 1K, a planarization process, such as a CMP process, can be performed to remove the excess fill metal layer 168, the top barrier layer 163, and the second work function metal layer 162 on the ILD layer 142. Fabrication of a metal gate 168a and a second metal gate 168b. In addition, the present embodiment can also selectively remove the ILD layer 142 and the CESL 140 and the like, and then reform the CESL and the dielectric layer to effectively improve the electrical performance of the semiconductor device. Since the above CMP process and the like are known to those of ordinary skill in the art, they are not described herein.

在以上的實施例中,透過第二遮蔽層174a、174b做為罩幕來移除第一閘極溝渠150與第二閘極溝渠152側壁的蝕刻停止層108與底部阻障層106的步驟(圖1I),係為能在第一閘極溝渠150與第二閘極溝渠152中順利填入第二功函數金屬層162、頂部阻障層163以及填充金屬層168。然而,若是第一閘極溝渠150與第二閘極溝渠152上部的尺寸夠大或是蝕刻停止層108與底部阻障層106的厚度夠薄而足以使得第二功函數金屬層162、頂部阻障層163以及填充金屬層168順利填入第一閘極溝渠150與第二閘極溝渠152之中,則無須再透過上述第二遮蔽層174a、174b做為罩幕來移除第一閘極溝渠150與第二閘極溝渠152側壁的蝕刻停止層108與底部阻障層106,因此,上述對應圖1G至1I之形成第二遮蔽層174至移除第一閘極溝渠150與第二閘極溝渠152側壁的蝕刻停止層108與底部阻障層106的步驟為選擇性,可以依照實際的需要調整之。In the above embodiment, the steps of removing the etch stop layer 108 and the bottom barrier layer 106 of the sidewalls of the first gate trench 150 and the second gate trench 152 by using the second shielding layer 174a, 174b as a mask ( FIG. 1I) is capable of smoothly filling the second work function metal layer 162, the top barrier layer 163, and the filling metal layer 168 in the first gate trench 150 and the second gate trench 152. However, if the size of the upper portion of the first gate trench 150 and the second gate trench 152 is sufficiently large or the thickness of the etch stop layer 108 and the bottom barrier layer 106 is sufficiently thin to make the second work function metal layer 162, the top resistor The barrier layer 163 and the filling metal layer 168 are smoothly filled into the first gate trench 150 and the second gate trench 152, so that the second gate layer 174a, 174b is not required to be used as a mask to remove the first gate. The etch stop layer 108 and the bottom barrier layer 106 of the sidewalls of the trench 150 and the second gate trench 152. Therefore, the second shielding layer 174 corresponding to FIGS. 1G to 1I is formed to remove the first gate trench 150 and the second gate. The steps of the etch stop layer 108 and the bottom barrier layer 106 on the sidewalls of the pole trench 152 are selective and can be adjusted according to actual needs.

另外,以上的實施例係以「後高介電常數閘極介電層製程」來說明,然而,本發明並不以此為限。另一實施例亦可與「先高介電常數閘極介電層(high-k first)製程」整合。In addition, the above embodiments are described by the "post-high dielectric constant gate dielectric layer process", however, the invention is not limited thereto. Another embodiment can also be integrated with a "high-k first process".

圖2A至圖2B係為本發明第二實施例之一種具有金屬閘極之半導體元件之製造方法之剖面示意圖。2A to 2B are schematic cross-sectional views showing a method of fabricating a semiconductor device having a metal gate according to a second embodiment of the present invention.

請參照圖2A,本實施例係與「先高介電常數閘極介電層(high-k first)製程」整合。亦即,第一半導體元件110與第二半導體元件112同樣分別具有第一閘極溝渠150與第二閘極溝渠152。並且各第一半導體元件110與第二半導體元件112分別包括閘極介電層104、底部阻障層(lower barrier layer) 106與蝕刻停止層(etch stop layer) 108。但是,高介電常數閘極介電層係在虛置閘極形成之前形成。更詳細地說,其製程方法係在基底100上先形成介面層103,再形成高介電常數閘極介電層104以及底部阻障層106,然後形成虛置閘極。之後,將介面層103、高介電常數閘極介電層104以及底部阻障層106圖案化成圖1A所示者。其後,在基底100上形成CESL 140與ILD層142,並藉由平坦化製程移除部分的CESL 140與ILD層142,直至暴露出第一半導體元件110與第二半導體元件112之虛置閘極。隨後利用適合之蝕刻製程移除第一半導體元件110與第二半導體元件112之虛置閘極,同時於第一半導體元件110與第二半導體元件112內分別形成第一閘極溝渠150與第二閘極溝渠152。隨後,再形成前述之蝕刻停止層108。Referring to FIG. 2A, the present embodiment is integrated with a "high-k first process". That is, the first semiconductor element 110 and the second semiconductor element 112 also have a first gate trench 150 and a second gate trench 152, respectively. Each of the first semiconductor element 110 and the second semiconductor element 112 includes a gate dielectric layer 104, a lower barrier layer 106, and an etch stop layer 108, respectively. However, a high dielectric constant gate dielectric layer is formed prior to the formation of the dummy gate. In more detail, the process method is to form an interface layer 103 on the substrate 100, form a high dielectric constant gate dielectric layer 104 and a bottom barrier layer 106, and then form a dummy gate. Thereafter, the interface layer 103, the high dielectric constant gate dielectric layer 104, and the bottom barrier layer 106 are patterned into those shown in FIG. 1A. Thereafter, CESL 140 and ILD layer 142 are formed on substrate 100, and portions of CESL 140 and ILD layer 142 are removed by a planarization process until exposed dummy gates of first semiconductor component 110 and second semiconductor component 112 are exposed. pole. Then, the dummy gates of the first semiconductor component 110 and the second semiconductor component 112 are removed by using a suitable etching process, and the first gate trenches 150 and the second gates are respectively formed in the first semiconductor component 110 and the second semiconductor component 112. Gate ditches 152. Subsequently, the aforementioned etch stop layer 108 is formed again.

之後,請參照圖2B,依照上述對應圖1B至1K之步驟完成第一金屬閘極168a與第二金屬閘極168b之製造。Thereafter, referring to FIG. 2B, the fabrication of the first metal gate 168a and the second metal gate 168b is completed in accordance with the steps corresponding to FIGS. 1B through 1K.

在本發明上述實施例中,在移除第二閘極溝渠152之中的第一功函數金屬層160之前,第二閘極溝渠152的底部有第一遮蔽層169a覆蓋,而不是裸露出來,因此,在後續的電漿蝕刻過程中可以避免電漿穿過第一功函數金屬層160而破壞第一功函數金屬層160下方的蝕刻停止層108、底部阻障層106以及高k閘極介電層104(圖1D)。In the above embodiment of the present invention, before the first work function metal layer 160 in the second gate trench 152 is removed, the bottom of the second gate trench 152 is covered by the first shielding layer 169a instead of being exposed. Therefore, in the subsequent plasma etching process, the plasma can be prevented from passing through the first work function metal layer 160 to destroy the etch stop layer 108, the bottom barrier layer 106, and the high-k gate dielectric under the first work function metal layer 160. Electrical layer 104 (Fig. 1D).

再者,本發明上述實施例係藉由蝕刻製程同時移除第一閘極溝渠150與第二閘極溝渠152頂端處的以及接近溝渠頂端的側壁的第一功函數金屬層160、蝕刻停止層108與底部阻障層106,僅在於第一閘極溝渠150與第二閘極溝渠152內的底部以及接近溝渠底部的側壁分別形成具有特殊輪廓的第一功函數金屬層160a、U型蝕刻停止層108a與U型底部阻障層106a。由於第一功函數金屬層160a、U型蝕刻停止層108a與U型底部阻障層106a的最高點皆低於第一閘極溝渠150與第二閘極溝渠152的開口頂端,第一閘極溝渠150與第二閘極溝渠152的開口頂端處不會被第一功函數金屬層160a、U型蝕刻停止層108a與U型底部阻障層106a覆蓋,因此,此形狀特徵可維持第一閘極溝渠150與第二閘極溝渠152開口原來的大小(口徑),並有效降低第一閘極溝渠150與第二閘極溝渠152的深寬比(aspect ratio),故可以使後續的頂部阻障層163、第二功函數金屬層162以及填充金屬層168順利填入,以避免填補第一閘極溝渠150與第二閘極溝渠152時發生縫隙(seam),確保第一半導體元件110與第二半導體元件112的可靠度(圖1J)。Furthermore, the above embodiment of the present invention simultaneously removes the first work function metal layer 160 and the etch stop layer at the top end of the first gate trench 150 and the second gate trench 152 and near the top end of the trench by an etching process. 108 and the bottom barrier layer 106, only the bottom of the first gate trench 150 and the second gate trench 152 and the sidewall near the bottom of the trench respectively form a first work function metal layer 160a having a special profile, and a U-type etch stop Layer 108a and U-type bottom barrier layer 106a. Since the highest points of the first work function metal layer 160a, the U-type etch stop layer 108a and the U-type bottom barrier layer 106a are lower than the open tops of the first gate trench 150 and the second gate trench 152, the first gate The open top ends of the trenches 150 and the second gate trenches 152 are not covered by the first work function metal layer 160a, the U-type etch stop layer 108a and the U-type bottom barrier layer 106a, and therefore, the shape feature maintains the first gate The pole trench 150 and the second gate trench 152 are opened to the original size (caliber), and the aspect ratio of the first gate trench 150 and the second gate trench 152 is effectively reduced, so that the subsequent top resistance can be made. The barrier layer 163, the second work function metal layer 162, and the filling metal layer 168 are smoothly filled to avoid a gap when the first gate trench 150 and the second gate trench 152 are filled, and the first semiconductor device 110 is ensured. The reliability of the second semiconductor component 112 (Fig. 1J).

綜合以上所述,依據本發明所提供之具有金屬閘極之半導體元件之製造方法,係於移除閘極溝渠內的第一功函數金屬層之前,先在不保留第一功函數金屬層的閘極溝渠中先保留一部分的遮蔽層,可以避免第一功函數金屬層下方的蝕刻停止層、底部阻障層以及高k閘極介電層等在後續的蝕刻過程中遭到破壞。再者,本發明所提供之具有金屬閘極之半導體元件之製造方法中,第一功函數金屬層、蝕刻停止層與底部阻障層的僅會覆蓋在閘極溝渠底部及接近閘極溝渠底部的側壁之處,因此,閘極溝渠可以維持原來的大小(口徑),並有效降低閘極溝渠的深寬比故可以使後續的填充金屬層等順利填入,確保半導體元件的可靠度。In summary, the method for fabricating a semiconductor device having a metal gate according to the present invention is to remove the first work function metal layer before removing the first work function metal layer in the gate trench. A portion of the shielding layer is reserved in the gate trench to prevent the etch stop layer, the bottom barrier layer, and the high-k gate dielectric layer under the first work function metal layer from being damaged during the subsequent etching process. Furthermore, in the method for fabricating a semiconductor device having a metal gate provided by the present invention, the first work function metal layer, the etch stop layer and the bottom barrier layer only cover the bottom of the gate trench and the bottom of the gate trench Therefore, the gate trench can maintain the original size (caliber) and effectively reduce the aspect ratio of the gate trench, so that the subsequent filling metal layer can be smoothly filled in, and the reliability of the semiconductor component can be ensured.

雖然本發明已以實施例揭露如上,然其並非用以限定本發明,任何所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,故本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed in the above embodiments, it is not intended to limit the invention, and any one of ordinary skill in the art can make some modifications and refinements without departing from the spirit and scope of the invention. The scope of the invention is defined by the scope of the appended claims.

100...基底100. . . Base

102...淺溝隔離結構102. . . Shallow trench isolation structure

103...介面層103. . . Interface layer

104...閘極介電層104. . . Gate dielectric layer

106...底部阻障層106. . . Bottom barrier layer

106a...U型底部阻障層106a. . . U-shaped bottom barrier layer

108...蝕刻停止層108. . . Etch stop layer

108a...U型蝕刻停止層108a. . . U-shaped etch stop layer

110...第一半導體元件110. . . First semiconductor component

112...第二半導體元件112. . . Second semiconductor component

120...第一輕摻雜汲極120. . . First lightly doped bungee

122...第二輕摻雜汲極122. . . Second lightly doped bungee

124...間隙壁124. . . Clearance wall

130...第一源極/汲極130. . . First source/dip

132...第二源極/汲極132. . . Second source/dip

134...金屬矽化物134. . . Metal telluride

140...接觸窗蝕刻停止層140. . . Contact window etch stop layer

142...內層介電層142. . . Inner dielectric layer

150...第一閘極溝渠150. . . First gate ditches

152...第二閘極溝渠152. . . Second gate ditches

160、160a...第一功函數金屬層160, 160a. . . First work function metal layer

162、162a...第二功函數金屬層162, 162a. . . Second work function metal layer

163...頂部阻障層163. . . Top barrier

168...填充金屬層168. . . Filled metal layer

168a...第一金屬閘極168a. . . First metal gate

168b...第二金屬閘極168b. . . Second metal gate

169、169a、169b、169c...第一遮蔽層169, 169a, 169b, 169c. . . First shielding layer

170...罩幕層170. . . Mask layer

170a...圖案化的罩幕層170a. . . Patterned mask layer

174、174a、174b...第二遮蔽層174, 174a, 174b. . . Second shielding layer

圖1A至圖1K係為本發明第一實施例之一種具有金屬閘極之半導體元件之製造方法之剖面圖示意圖。1A to 1K are schematic cross-sectional views showing a method of fabricating a semiconductor device having a metal gate according to a first embodiment of the present invention.

圖2A至圖2B係為本發明第二實施例之一種具有金屬閘極之半導體元件之製造方法之剖面示意圖。2A to 2B are schematic cross-sectional views showing a method of fabricating a semiconductor device having a metal gate according to a second embodiment of the present invention.

100...基底100. . . Base

102...淺溝隔離結構102. . . Shallow trench isolation structure

103...介面層103. . . Interface layer

104...閘極介電層104. . . Gate dielectric layer

106...底部阻障層106. . . Bottom barrier layer

108...蝕刻停止層108. . . Etch stop layer

110...第一半導體元件110. . . First semiconductor component

112...第二半導體元件112. . . Second semiconductor component

120...第一輕摻雜汲極120. . . First lightly doped bungee

122...第二輕摻雜汲極122. . . Second lightly doped bungee

124...間隙壁124. . . Clearance wall

130...第一源極/汲極130. . . First source/dip

132...第二源極/汲極132. . . Second source/dip

134...金屬矽化物134. . . Metal telluride

140...接觸窗蝕刻停止層140. . . Contact window etch stop layer

142...內層介電層142. . . Inner dielectric layer

150...第一閘極溝渠150. . . First gate ditches

152...第二閘極溝渠152. . . Second gate ditches

160...第一功函數金屬層160. . . First work function metal layer

169a、169b...第一遮蔽層169a, 169b. . . First shielding layer

Claims (21)

一種具有金屬閘極之半導體元件之製造方法,包括:提供一基底,該基底表面形成有一第一半導體元件與一第二半導體元件,且該第一半導體元件與該第二半導體元件中分別形成有一第一閘極溝渠與一第二閘極溝渠;於該第一閘極溝渠與該第二閘極溝渠中形成一第一功函數金屬層;於該基底上形成一第一遮蔽層;進行第一次移除部分該第一遮蔽層之步驟,使留下的該第一遮蔽層位於該第二閘極溝渠的底部並且填滿該第一閘極溝渠;進行第二次移除部分該第一遮蔽層之步驟,留下位於該第一閘極溝渠底部的該第一遮蔽層,使該第二閘極溝渠以及該第一閘極溝渠側壁的該第一功函數金屬層裸露出來;以該第一遮蔽層為罩幕,移除未被該第一遮蔽層覆蓋的該第一功函數金屬層,只留下該第一閘極溝渠底部的該第一功函數金屬層;以及移除該第一遮蔽層。A method of fabricating a semiconductor device having a metal gate includes: providing a substrate, a surface of the substrate is formed with a first semiconductor component and a second semiconductor component, and a first semiconductor component and the second semiconductor component are respectively formed a first gate trench and a second gate trench; forming a first work function metal layer in the first gate trench and the second gate trench; forming a first shielding layer on the substrate; Removing a portion of the first shielding layer at a time, leaving the first shielding layer at the bottom of the second gate trench and filling the first gate trench; performing a second removal portion a step of shielding the first shielding layer at the bottom of the first gate trench to expose the first work function metal layer of the second gate trench and the sidewall of the first gate trench; The first shielding layer is a mask to remove the first work function metal layer not covered by the first shielding layer, leaving only the first work function metal layer at the bottom of the first gate trench; and removing The first shielding layer. 如申請專利範圍第1項所述之具有金屬閘極之半導體元件之製造方法,更包括:移除部分該第一遮蔽層之前,於該第一遮蔽層上形成一圖案化的罩幕層,該圖案化的罩幕層覆蓋該第一半導體元件,裸露出該第二半導體元件;以該圖案化的罩幕層為罩幕,進行該第一次移除部分該第一遮蔽層步驟,移除該第二半導體元件上的部分該第一遮蔽層;以及移除該圖案化的罩幕層。The method for manufacturing a semiconductor device having a metal gate according to claim 1, further comprising: forming a patterned mask layer on the first shielding layer before removing a portion of the first shielding layer, The patterned mask layer covers the first semiconductor component to expose the second semiconductor component; and the patterned mask layer is used as a mask to perform the first removing portion of the first shielding layer step Removing the first masking layer from the portion of the second semiconductor component; and removing the patterned mask layer. 如申請專利範圍第2項所述之具有金屬閘極之半導體元件之製造方法,其中進行該第一次移除部分該第一遮蔽層之步驟的方法包括蝕刻法。The method of manufacturing a semiconductor device having a metal gate according to claim 2, wherein the method of performing the step of removing a portion of the first shielding layer for the first time comprises an etching method. 如申請專利範圍第2項所述之具有金屬閘極之半導體元件之製造方法,其中進行該第二次移除部分該第一遮蔽層步驟的方法包括蝕刻法。A method of fabricating a semiconductor device having a metal gate according to claim 2, wherein the method of performing the second removing of the first masking step comprises etching. 如申請專利範圍第1項所述之具有金屬閘極之半導體元件之製造方法,其中該第一遮蔽層包括介電抗反射塗層(dielectric anti-reflection coating,DARC)、光吸收氧化(light absorbing oxide,DUO)層、底部抗反射塗層(bottom anti-reflective coating,BARC)或犧牲吸光材料(sacrificial light absorbing material,SLAM)層。The method for fabricating a semiconductor device having a metal gate according to claim 1, wherein the first shielding layer comprises a dielectric anti-reflection coating (DARC) and a light absorbing oxide (light absorbing) Oxide, DUO) layer, bottom anti-reflective coating (BARC) or sacrificial light absorbing material (SLAM) layer. 如申請專利範圍第1項所述之具有金屬閘極之半導體元件之製造方法,其中該第一功函數金屬層的材料包括氮化鈦、碳化鈦、氮化鉭、碳化鉭、碳化鎢或氮化鋁鈦。The method for manufacturing a semiconductor device having a metal gate according to claim 1, wherein the material of the first work function metal layer comprises titanium nitride, titanium carbide, tantalum nitride, tantalum carbide, tungsten carbide or nitrogen. Aluminum titanium. 如申請專利範圍第1項所述之具有金屬閘極之半導體元件之製造方法,更包括於該第一閘極溝渠與該第二閘極溝渠中形成一第二功函數金屬層。The method for fabricating a semiconductor device having a metal gate according to claim 1, further comprising forming a second work function metal layer in the first gate trench and the second gate trench. 如申請專利範圍第7項所述之具有金屬閘極之半導體元件之製造方法,其中該第二功函數金屬層包括鋁化鈦層、鋁化鋯層、鋁化鎢層、鋁化鉭層或鋁化鉿層。The method for manufacturing a semiconductor device having a metal gate according to claim 7, wherein the second work function metal layer comprises a titanium aluminide layer, a zirconium aluminide layer, a tungsten aluminide layer, a tantalum layer or Aluminized ruthenium layer. 如申請專利範圍第1項所述之具有金屬閘極之半導體元件之製造方法,更包括形成一填充金屬層,以填滿該第一閘極溝渠與該第二閘極溝渠。The method for fabricating a semiconductor device having a metal gate according to claim 1, further comprising forming a filling metal layer to fill the first gate trench and the second gate trench. 如申請專利範圍第9項所述之具有金屬閘極之半導體元件之製造方法,其中該填充金屬層包括鋁、鋁化鈦或氧化鋁鈦。The method of manufacturing a semiconductor device having a metal gate according to claim 9, wherein the filler metal layer comprises aluminum, titanium aluminide or titanium oxide. 如申請專利範圍第1項所述之具有金屬閘極之半導體元件之製造方法,更包括:於該第一閘極溝渠與該第二閘極溝渠中形成一頂部阻障層,覆蓋該第一功函數金屬層。The method for manufacturing a semiconductor device having a metal gate according to claim 1, further comprising: forming a top barrier layer in the first gate trench and the second gate trench, covering the first Work function metal layer. 如申請專利範圍第11項所述之具有金屬閘極之半導體元件之製造方法,其中該頂部阻障層的材料包括氮化鈦。The method of manufacturing a semiconductor device having a metal gate according to claim 11, wherein the material of the top barrier layer comprises titanium nitride. 如申請專利範圍第11項所述之具有金屬閘極之半導體元件之製造方法,於形成該頂部阻障層之前,更包括於該第一閘極溝渠與該第二閘極溝渠中形成一第二功函數金屬層。The method for manufacturing a semiconductor device having a metal gate according to claim 11, wherein before forming the top barrier layer, forming a first portion in the first gate trench and the second gate trench Two work function metal layer. 如申請專利範圍第11項所述之具有金屬閘極之半導體元件之製造方法,更包括形成一填充金屬層,以填滿該第一閘極溝渠與該第二閘極溝渠。The method for fabricating a semiconductor device having a metal gate according to claim 11, further comprising forming a filling metal layer to fill the first gate trench and the second gate trench. 如申請專利範圍第11項所述之具有金屬閘極之半導體元件之製造方法,於形成該第一功函數金屬層之前,更包括於該第一閘極溝渠與該第二閘極溝渠內形成一底部阻障層。The method for fabricating a semiconductor device having a metal gate according to claim 11 is further included in the first gate trench and the second gate trench before forming the first work function metal layer. A bottom barrier layer. 如申請專利範圍第15項所述之具有金屬閘極之半導體元件之製造方法,其中該底部阻障層的材料包括氮化鈦。The method of manufacturing a semiconductor device having a metal gate according to claim 15, wherein the material of the bottom barrier layer comprises titanium nitride. 如申請專利範圍第15項所述之具有金屬閘極之半導體元件之製造方法,於形成該第一功函數金屬層之前,更包括於該底部阻障層上形成一蝕刻停止層。The method for fabricating a semiconductor device having a metal gate according to claim 15 further comprises forming an etch stop layer on the bottom barrier layer before forming the first work function metal layer. 如申請專利範圍第17項所述之具有金屬閘極之半導體元件之製造方法,其中該蝕刻停止層的材料包括氮化鉭。The method of manufacturing a semiconductor device having a metal gate according to claim 17, wherein the material of the etch stop layer comprises tantalum nitride. 如申請專利範圍第17項所述之具有金屬閘極之半導體元件之製造方法,在形成該頂部阻障層之前更包括:於該基底上形成一第二遮蔽層,覆蓋該第一半導體元件與該第二半導體元件;部分移除該第二遮蔽層,裸露出該第一閘極溝渠與該第二閘極溝渠側壁的該蝕刻停止層;以留下的該第二遮蔽層為罩幕,移除裸露出的部分該蝕刻停止層以及部分該底部阻障層;以及移除該第二遮蔽層。The method for fabricating a semiconductor device having a metal gate according to claim 17, further comprising: forming a second shielding layer on the substrate to cover the first semiconductor device and before forming the top barrier layer The second semiconductor component partially removes the second shielding layer, exposing the etch stop layer of the first gate trench and the sidewall of the second gate trench; and leaving the second shielding layer as a mask Removing the exposed portion of the etch stop layer and a portion of the bottom barrier layer; and removing the second mask layer. 如申請專利範圍19項所述之具有金屬閘極之半導體元件之製造方法,其中以留下的該第二遮蔽層為罩幕,移除部分該蝕刻停止層以及部分該底部阻障層之後,留下的該蝕刻停止層以及該底部阻障層的頂部低於該第一閘極溝渠頂部以及該第二閘極溝渠頂部。The method for fabricating a semiconductor device having a metal gate according to claim 19, wherein after the second shielding layer is left as a mask, after the portion of the etch stop layer and a portion of the bottom barrier layer are removed, The etch stop layer and the top of the bottom barrier layer are lower than the top of the first gate trench and the second gate trench. 如申請專利範圍第19項所述之具有金屬閘極之半導體元件之製造方法,其中該第二遮蔽層包括介電抗反射塗層、光吸收氧化層、底部抗反射塗層層或犧牲吸光材料層。The method for fabricating a semiconductor device having a metal gate according to claim 19, wherein the second shielding layer comprises a dielectric anti-reflective coating, a light absorbing oxide layer, a bottom anti-reflective coating layer or a sacrificial light absorbing material. 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