TWI515876B - Contact structure and forming method - Google Patents

Contact structure and forming method Download PDF

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TWI515876B
TWI515876B TW102138369A TW102138369A TWI515876B TW I515876 B TWI515876 B TW I515876B TW 102138369 A TW102138369 A TW 102138369A TW 102138369 A TW102138369 A TW 102138369A TW I515876 B TWI515876 B TW I515876B
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sub
stack
layers
layer
insulating
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TW102138369A
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TW201517248A (en
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陳士弘
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旺宏電子股份有限公司
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接觸窗結構與形成方法 Contact window structure and forming method

本發明是有關於高密度裝置,且特別是,在本發明的實施例中,提供一種形成三維高密度半導體裝置的方法,其以導體連接至半導體裝置(例如記憶體裝置)的主動層。 The present invention is directed to high density devices, and in particular, in embodiments of the present invention, a method of forming a three dimensional high density semiconductor device that is electrically connected to an active layer of a semiconductor device (e.g., a memory device).

三維半導體裝置是由多個主動層與多個絕緣層相互交替的堆疊所形成。在記憶體裝置中,每一層皆可包括一平面陣列的記憶胞,在現今的三維堆疊記憶體裝置中,主動層包括由主動層帶(active strip)建置而成的字元線與位元線,以供記憶胞使用,該些記憶胞交替堆疊形成了空隙相隔的脊狀結構(spaced-apart ridge-like structure)。該些主動層可由摻雜(p型或n型摻雜)半導體材料或無摻雜半導體材料製成。在此型的三維記憶裝置中,記憶胞可置放於層疊的位元線或層疊的字元線與交叉通過的字元線或交叉通過的位元線的交叉點上,以形成三維記憶體陣列。 The three-dimensional semiconductor device is formed by a stack in which a plurality of active layers and a plurality of insulating layers are alternately arranged. In a memory device, each layer can include a planar array of memory cells. In today's three-dimensional stacked memory devices, the active layer includes word lines and bits formed by active strips. Lines are used for memory cells that are alternately stacked to form a spaced-apart ridge-like structure. The active layers may be made of a doped (p-type or n-type doped) semiconductor material or an undoped semiconductor material. In the three-dimensional memory device of this type, the memory cells can be placed on the intersection of the stacked bit lines or the stacked word lines and the intersecting word lines or the intersecting bit lines to form a three-dimensional memory. Array.

其中一種連接層間導體至主動層的方式為多道微顯影蝕刻製程,其被揭露於美國專利號8,383,512中,名稱為Method for Making Connection Structure,其中揭露的內容在此引用做為參考。另一種方法則是美國專利申請號13/735,922,提交於2013/1/27,名稱為Method for Forming Interlayer Conductors to a Stack of Conductor Layers此揭露的內容在此引用作為參考。 One such method of connecting the interlayer conductor to the active layer is a multi-pass micro-developing etch process, which is disclosed in U.S. Patent No. 8,383,512, entitled For Making Connection Structure, the disclosure of which is hereby incorporated by reference. A further method is described in U.S. Patent Application Serial No. 13/735,922, filed on Dec.

在一範例中,提出一種階梯式接觸窗結構的形成方法。形成一由複數個主動層與複數個絕緣層交替的堆疊,如下所述。形成包括N個主動層的一第一子堆疊,該N個主動層被該些絕緣層分開,該N個主動層包括一上邊界主動層。形成一第二子堆疊於該第一子堆疊之上,該第二子堆疊包括M個主動層,該M個主動層被該些絕緣層分開,該M個主動層包括一上邊界主動層。形成一第一子堆疊絕緣層位於該第一子堆疊層與該第二子堆疊層之間,在一已知蝕刻步驟中該第一子堆疊絕緣層具有一不同於該第二子堆疊內的該些絕緣層的多個蝕刻時間的蝕刻時間。接通該些上邊界主動層。接續該些上邊界主動層之接通步驟,接通該第一子堆疊與該第二子堆疊的其餘該些主動層,並於該第一子堆疊與該第二子堆疊的該些主動層上產生一階梯式結構的著陸區(landing area)。形成延伸至該些著陸區的複數個層間導體,該些層間導體由絕緣材料各自分開。 In an example, a method of forming a stepped contact window structure is presented. A stack of alternating active layers and a plurality of insulating layers is formed as described below. Forming a first sub-stack comprising N active layers separated by the insulating layers, the N active layers including an upper boundary active layer. Forming a second sub-stack on the first sub-stack, the second sub-stack comprising M active layers, the M active layers being separated by the insulating layers, the M active layers comprising an upper boundary active layer. Forming a first sub-stack insulation layer between the first sub-stack layer and the second sub-stack layer, the first sub-stack insulation layer having a different one from the second sub-stack in a known etching step Etching time of the plurality of etching times of the insulating layers. Turn on the upper boundary active layers. And following the step of turning on the upper boundary active layer, turning on the remaining active layers of the first sub-stack and the second sub-stack, and stacking the active layers in the first sub-stack and the second sub-stack A landing area is created on a stepped structure. A plurality of interlayer conductors extending to the landing zones are formed, the interlayer conductors being separated by an insulating material.

在一範例中,提出一種階梯式接觸窗結構的形成方法。形成一由複數個主動層和複數個絕緣層交替的堆疊,如下所述。該堆疊包括具有上邊界主動層的複數個子堆疊,該些子堆疊 具有絕緣層和多個主動層對(active layer pair)在上邊界主動層之下,該絕緣層與該些主動層對構成多個第一層對(first layer pairs),該些第一層對在該已知蝕刻製程中有多個一致的第一子堆疊蝕刻時間。該堆疊也包括多個第二層對(second layer pairs),該些第二層對包括多個子堆疊絕緣層,該些子堆疊絕緣層位在該些子堆疊之間,該第二層對在該已知蝕刻製程中有多個第二子堆疊蝕刻時間,其相異於該些第一子堆疊蝕刻時間;在一個或多個蝕刻步驟中,經過蝕刻,使堆疊產生複數個開口,該些開口之蝕刻深度止於該些上邊界主動層。深度蝕刻被選定的該些開口以形成多個通孔,該些通孔顯露各該子堆疊內的多個主動層。形成多個層間導體於(1)該些通孔中以延伸至該些主動層,且(2)在該些開口未被進行深度蝕刻的過程中,形成該些層間導體以延伸至該些上邊界主動層。 In an example, a method of forming a stepped contact window structure is presented. A stack of alternating active layers and a plurality of insulating layers is formed as described below. The stack includes a plurality of sub-stacks having an active layer of an upper boundary, and the sub-stacks Having an insulating layer and a plurality of active layer pairs under the upper boundary active layer, the insulating layer and the active layer pairs forming a plurality of first layer pairs, the first layer pairs There are a plurality of consistent first sub-stack etch times in the known etch process. The stack also includes a plurality of second layer pairs, the second layer pairs including a plurality of sub-stack insulation layers, the sub-stack insulation layers being located between the sub-stacks, the second layer pair being The known etching process has a plurality of second sub-stack etch times that are different from the first sub-stack etch times; in one or more etch steps, the etch is performed to cause the stack to generate a plurality of openings, The etch depth of the opening stops at the upper boundary active layers. The openings are selected to be deeply etched to form a plurality of vias that expose a plurality of active layers within each of the sub-stacks. Forming a plurality of interlayer conductors in (1) the via holes to extend to the active layers, and (2) forming the interlayer conductors to extend to the openings when the openings are not deeply etched The active layer of the boundary.

在一範例中,一階梯式接觸窗結構包括一由主動層與絕緣層交替的堆疊,該堆疊為非簡單排列,使得下述之兩種狀況至少其一針對相同的蝕刻製程(1)主動層之間的蝕刻時間不同,或(2)絕緣層之間的蝕刻時間不同。一階梯式結構的著陸區位在該些主動層之上,該些層間導體延伸至該階梯式結構的著陸區,該些層間導體之間由絕緣材料所隔開。 In one example, a stepped contact window structure includes a stack of alternating active and insulating layers, the stack being non-simple, such that at least one of the following conditions is for the same etch process (1) active layer The etching time is different, or (2) the etching time between the insulating layers is different. A landing structure of a stepped structure is above the active layers, the interlayer conductors extending to a landing zone of the stepped structure, the interlayer conductors being separated by an insulating material.

為了對本發明之上述,優點及其他方面有更佳的瞭解,下文特舉較佳實施例,並配合所附圖式,作詳細說明如下: For a better understanding of the above, the advantages and other aspects of the present invention, the preferred embodiments are described below, and in the accompanying drawings,

ML1、ML2、ML3‧‧‧金屬層 ML1, ML2, ML3‧‧‧ metal layer

100‧‧‧半導體裝置 100‧‧‧Semiconductor device

102~105、112~115‧‧‧主動層帶 102~105, 112~115‧‧‧ active layer belt

102B、103B、104B、105B、112B、113B、114B、115B‧‧‧半導體墊 102B, 103B, 104B, 105B, 112B, 113B, 114B, 115B‧‧‧ semiconductor pads

102C1、102C2、102C3、103C1、103C2、104C1‧‧‧半導體板開口 102C1, 102C2, 102C3, 103C1, 103C2, 104C1‧‧‧ semiconductor board opening

119‧‧‧源極線終端 119‧‧‧Source line terminal

125-1~125-N‧‧‧層間導體 125-1~125-N‧‧‧Interlayer conductor

126‧‧‧接地選擇閘極 126‧‧‧ Grounding selection gate

127‧‧‧閘極選擇線 127‧‧‧ gate selection line

128、252‧‧‧源極線 128, 252‧‧‧ source line

152‧‧‧記憶材料層 152‧‧‧ memory material layer

154‧‧‧矽化金屬層 154‧‧‧Deuterated metal layer

200、330‧‧‧堆疊 200, 330‧‧‧ Stacking

202、202.2、202.3、202.4‧‧‧交替作用主動層 202, 202.2, 202.3, 202.4‧‧‧ alternating active layers

202.1‧‧‧上邊界主動層 202.1‧‧‧Upper boundary active layer

204、204.1、204.2、312‧‧‧絕緣層 204, 204.1, 204.2, 312‧‧ insulation

204.3‧‧‧第三絕緣層 204.3‧‧‧The third insulation layer

206、278、328‧‧‧第一蝕刻屏蔽 206, 278, 328‧‧‧ first etch shield

212、284、336‧‧‧第二蝕刻屏蔽 212, 284, 336 ‧ ‧ second etch shield

220、290、352‧‧‧第三蝕刻屏蔽 220, 290, 352‧‧‧ third etching shield

298、364‧‧‧第四蝕刻屏蔽 298, 364‧‧‧ fourth etch shield

304、332‧‧‧第五蝕刻屏蔽 304, 332‧‧‧ fifth etching shield

208、280‧‧‧第一蝕刻屏蔽開口 208, 280‧‧‧ first etched shield opening

214、286‧‧‧第二蝕刻屏蔽開口 214, 286‧‧‧ second etched shield opening

222、292.1、292.2‧‧‧第三蝕刻屏蔽開口 222, 292.1, 292.2‧‧‧ third etched shield opening

299‧‧‧第四蝕刻屏蔽開口 299‧‧‧4th etched shield opening

306‧‧‧第五蝕刻屏蔽開口 306‧‧‧ fifth etched shield opening

224‧‧‧最上層主動層顯露區域 224‧‧‧The upper active layer reveals the area

228、234、334‧‧‧主動層202.1顯露區域 228, 234, 334‧‧‧ active layer 202.1 exposed area

226、230‧‧‧主動層202.2顯露區域 226, 230‧‧‧ active layer 202.2 revealed area

230、232‧‧‧主動層202.3顯露區域 230, 232‧‧‧ active layer 202.3 exposed area

236‧‧‧階梯式結構 236‧‧‧ stepped structure

238、310、358‧‧‧著陸區 238, 310, 358‧‧‧ landing zone

250、370‧‧‧接觸窗結構 250, 370‧‧‧Contact window structure

252‧‧‧子堆疊 252‧‧‧Sub-stacking

252.1‧‧‧第一子堆疊 252.1‧‧‧First sub-stacking

252.2‧‧‧第二子堆疊 252.2‧‧‧Second sub-stacking

252.3‧‧‧第三子堆疊 252.3‧‧‧ Third sub-stacking

252.4‧‧‧第四子堆疊 252.4‧‧‧ Fourth sub-stacking

254‧‧‧層對 254‧‧‧ layer pairs

262‧‧‧第二層對 262‧‧‧Second layer

264‧‧‧第三層對 264‧‧‧ third layer pair

266‧‧‧第四層對 266‧‧‧Fourth pair

256、258、260‧‧‧子堆疊絕緣層 256, 258, 260‧ ‧ sub-stack insulation

268‧‧‧上絕緣層 268‧‧‧Upper insulation

270‧‧‧下絕緣層 270‧‧‧lower insulation

272、372‧‧‧層間導體 272, 372‧‧ ‧ interlayer conductor

274‧‧‧側壁絕緣 274‧‧‧ Sidewall insulation

282‧‧‧第一蝕刻開口 282‧‧‧First etching opening

288‧‧‧第二蝕刻開口 288‧‧‧Second etching opening

294‧‧‧第三蝕刻開口 294‧‧‧ Third etching opening

296‧‧‧第四蝕刻開口 296‧‧‧fourth etching opening

300‧‧‧部分蝕刻結構 300‧‧‧ partially etched structure

302‧‧‧開口 302‧‧‧ openings

308、368‧‧‧通孔 308, 368‧‧‧through holes

314‧‧‧側牆絕緣層 314‧‧‧Side wall insulation

318‧‧‧上層開口 318‧‧‧Upper opening

331‧‧‧屏蔽部分 331‧‧‧Shielding section

338、340、342、344‧‧‧表面 338, 340, 342, 344‧‧‧ surface

348、349、350、351‧‧‧顯露表面區域 348, 349, 350, 351‧‧ ‧ exposed surface area

354、356‧‧‧剪切蝕刻屏蔽 354, 356‧ ‧ shear etching shield

360‧‧‧阻隔層 360‧‧‧Barrier

362‧‧‧絕緣材料 362‧‧‧Insulation materials

370‧‧‧接觸窗結構 370‧‧‧Contact window structure

975‧‧‧積體電路 975‧‧‧ integrated circuit

958‧‧‧平面解碼器 958‧‧‧ Planar Decoder

959‧‧‧位元線 959‧‧‧ bit line

960‧‧‧三維快閃記憶體陣列 960‧‧‧Three-dimensional flash memory array

961‧‧‧列解碼器 961‧‧‧ column decoder

962‧‧‧字元線 962‧‧‧ character line

963‧‧‧行解碼器 963‧‧‧ row decoder

964‧‧‧SSL線 964‧‧‧SSL line

965‧‧‧位址輸入線 965‧‧‧ address input line

966‧‧‧檢測放大器/資料輸入結構 966‧‧‧Sense amplifier/data input structure

968‧‧‧偏壓設置之供應電壓 968‧‧‧ bias voltage supply voltage

969‧‧‧狀態機 969‧‧‧ state machine

971‧‧‧資料輸入線 971‧‧‧ data input line

972‧‧‧資料輸出線 972‧‧‧ data output line

974‧‧‧積體電路 974‧‧‧Integrated circuit

第1圖繪示一半導體裝置的示意圖,其包括做為層間導體的半導體墊。 1 is a schematic diagram of a semiconductor device including a semiconductor pad as an interlayer conductor.

第2A、2B、2C、2D、2E與2F圖為一簡單側視圖,繪示了該堆疊為簡單排列時,多道微影蝕刻製程的一範例。 2A, 2B, 2C, 2D, 2E and 2F are a simple side view showing an example of a multi-pass lithography process when the stack is simply arranged.

第3A、3B、3C、3D與3E圖為一簡單側視圖,繪示了該堆疊為非簡單排列時,在微影蝕刻製程當中產生一蝕刻深度問題的範例。 3A, 3B, 3C, 3D, and 3E are a simplified side view showing an example of an etch depth problem in a lithography process when the stack is not simply arranged.

第4A、4B、4C、4D、4E、4F與4G圖為一簡單側視圖,係為一堆疊為簡單排列時,剪切蝕刻製程步驟之實施例。 4A, 4B, 4C, 4D, 4E, 4F and 4G are a simple side view, which is an embodiment of a shear etching process step when the stack is simply arranged.

第5A、5B、5C與5D圖為一簡單側視圖,係為一堆疊為非簡單排列時,剪切蝕刻製程步驟與製程中產生蝕刻深度問題之實施例。 5A, 5B, 5C, and 5D are a simple side view, which is an embodiment in which the etching etching process steps and the etching depth are generated in a process when the stack is a non-simple arrangement.

第6圖為一接觸窗結構的範例,其中由主動層與絕緣層交替的堆疊為非簡單排列。 Fig. 6 is an example of a contact window structure in which an alternating stack of active layers and insulating layers is a non-simple arrangement.

第7-25圖為第6圖接觸窗結構之形成步驟範例,該步驟為多道微影蝕刻製程。 Figures 7-25 are examples of the formation steps of the contact window structure of Figure 6, which is a multi-pass lithography process.

第7圖繪示一由主動層與絕緣層交替的堆疊。 Figure 7 illustrates a stack of alternating active and insulating layers.

第8圖繪示第7圖之結構加上蝕刻屏蔽之情況。 Figure 8 shows the structure of Figure 7 plus the etched shield.

第9圖繪示第8圖之結構經蝕刻步驟後之情況。 Figure 9 is a diagram showing the structure of Figure 8 after the etching step.

第10圖繪示第9圖之結構移除蝕刻屏蔽後之情況。 Figure 10 is a diagram showing the structure of Figure 9 after the etch mask is removed.

第11圖繪示第10圖之結構加上第二層蝕刻屏蔽之情況。 Figure 11 shows the structure of Figure 10 plus the second layer of etched shield.

第12圖繪示第11圖之結構經蝕刻步驟後之情況。 Fig. 12 is a view showing the state after the etching step of the structure of Fig. 11.

第13圖繪示第12圖之結構移除第二層蝕刻屏蔽後之情況。 Figure 13 is a diagram showing the structure of Figure 12 after the second layer of etch mask is removed.

第14圖繪示第13圖之結構加上第三層蝕刻屏蔽之情況。 Figure 14 shows the structure of Figure 13 plus the third layer of etched shield.

第15圖繪示第14圖之結構經蝕刻步驟後之情況。 Figure 15 is a diagram showing the structure of Figure 14 after the etching step.

第16圖繪示第15圖之結構移除第三層蝕刻屏蔽後之情況。 Figure 16 is a diagram showing the structure of Figure 15 after the third layer of etch mask is removed.

第17圖繪示第16圖之結構加上第四層蝕刻屏蔽之情況。 Figure 17 shows the structure of Figure 16 plus the fourth layer of etched shield.

第18圖繪示第17圖之結構經蝕刻步驟後之情況。 Figure 18 is a diagram showing the structure of Figure 17 after the etching step.

第19圖繪示第18圖之結構移除第四層蝕刻屏蔽後之情況。 Figure 19 is a diagram showing the structure of Figure 18 after the fourth layer of etch mask is removed.

第20圖繪示第19圖之結構加上第五層蝕刻屏蔽之情況。 Figure 20 illustrates the structure of Figure 19 plus a fifth layer of etched shield.

第21圖繪示第20圖之結構經蝕刻步驟後之情況。 Figure 21 is a diagram showing the structure of Figure 20 after the etching step.

第22圖繪示第21圖之結構移除第五層蝕刻屏蔽後,堆疊中通孔形成之情況。 Fig. 22 is a view showing the formation of the through holes in the stack after the fifth layer etching shield is removed from the structure of Fig. 21.

第23圖繪示第22圖之結構加入一絕緣層。 Figure 23 shows the structure of Figure 22 incorporating an insulating layer.

第24圖繪示第23圖之結構移除了一部分絕緣層,並於通孔中留下一側壁絕緣層。 Figure 24 illustrates that the structure of Figure 23 removes a portion of the insulating layer and leaves a sidewall insulating layer in the via.

第25圖繪示第24圖之結構加入層間導體之後產生如第6圖所繪示之接觸窗結構。 Figure 25 is a diagram showing the contact window structure as shown in Fig. 6 after the structure of Fig. 24 is added to the interlayer conductor.

第26-43圖為一藉剪切蝕刻步驟形成一接觸窗結構之範例。 Figures 26-43 show an example of a contact window structure formed by a shear etching step.

第26圖繪示一由主動層與絕緣層交替之堆疊,其上置第一蝕刻屏蔽。 Figure 26 illustrates a stack of alternating active and insulating layers with a first etch shield disposed thereon.

第27圖繪示第26圖之結構經蝕刻步驟後之情況。 Figure 27 is a diagram showing the structure of Figure 26 after the etching step.

第28圖繪示第27圖之結構移除第一蝕刻屏蔽,並以第二蝕刻屏蔽代替。 Figure 28 illustrates the structure of Figure 27 with the first etch mask removed and replaced with a second etch shield.

第29圖繪示第28圖之結構經蝕刻步驟後之情況。 Figure 29 is a diagram showing the structure of Figure 28 after the etching step.

第30圖繪示第29圖之結構移除第二蝕刻屏蔽。 Figure 30 illustrates the structure of Figure 29 with the second etch shield removed.

第31圖繪示第30圖之結構加上第三蝕刻屏蔽。 Figure 31 shows the structure of Figure 30 plus a third etch shield.

第32圖繪示第31圖之結構經蝕刻步驟後之情況。 Figure 32 is a diagram showing the structure of Fig. 31 after the etching step.

第33圖繪示第32圖進行第三蝕刻屏蔽之第一次修整。 Figure 33 shows the first trimming of the third etch mask in Figure 32.

第34圖繪示第33圖之結構經蝕刻步驟後之情況。 Figure 34 is a diagram showing the structure of Fig. 33 after the etching step.

第35圖繪示第34圖進行第三蝕刻屏蔽之第二次修整。 Figure 35 shows the second trimming of the third etch mask in Figure 34.

第36圖繪示第35圖之結構經蝕刻步驟後之情況。 Figure 36 shows the structure of Figure 35 after the etching step.

第37圖繪示第36圖移除修整後之第三蝕刻屏蔽。 Figure 37 illustrates the third etching shield after trimming is removed in Figure 36.

第38圖繪示第37圖之結構加入一絕緣/絕阻層後之情況。 Figure 38 illustrates the structure of Figure 37 after the addition of an insulating/extinction layer.

第39圖繪示第38圖之結構加入一絕緣材料後之情況。 Fig. 39 is a view showing the structure of Fig. 38 after the addition of an insulating material.

第40圖繪示第39圖之結構加上第四蝕刻屏蔽。 Figure 40 illustrates the structure of Figure 39 plus a fourth etch shield.

第41圖繪示第40圖之結構經蝕刻步驟後之情況。 Fig. 41 is a view showing the structure of Fig. 40 after the etching step.

第42圖繪示第41圖移除第二蝕刻屏蔽後與通孔形成之結構。 Figure 42 is a view showing the structure formed by the through hole after the second etching mask is removed.

第43圖繪示第42圖中之通孔內加入層間導體之結構。 Fig. 43 is a view showing the structure in which the interlayer conductor is added to the through hole in Fig. 42.

第44圖為一簡化流程示意圖,繪示第7-25圖所述之接觸窗結構形成步驟。 Figure 44 is a simplified flow diagram showing the steps of forming the contact window structure described in Figures 7-25.

第45圖為一簡化流程示意圖,繪示第26-43圖之接觸窗結構形成步驟。 Figure 45 is a simplified flow diagram showing the formation of the contact window structure of Figures 26-43.

第46圖為一簡化流程示意圖,繪示第26-43圖接觸窗結構形成之步驟。 Figure 46 is a simplified flow diagram showing the steps of forming the contact window structure of Figures 26-43.

第47圖為一積體電路之簡化方塊圖。 Figure 47 is a simplified block diagram of an integrated circuit.

以下為多個實施例參照附圖的詳細說明。以下的說明將會參照特定的實施例和形成方法,本意並非為了對本發明作任何不必要的限制,或是揭露任何實施例與方法。以下所有實施例皆係用於示範本發明,而非限制其範圍,以本專利之申請範圍所界定為準。那些在本技術領域具有通常知識的入員可以瞭解在接下來說明中的各種等效的變化。除非另有說明外,在本申請中規定的關係,例如,平行、對齊,具有均勻的特性,或在同一平面上,作為指定的關係表示於製造過程的限制,並在生產上的變化。當元件被描述為連結,連接,接觸或相互接觸,皆不必在物理上彼此直接接觸,除非特別如此描述。在各個實施例中相同的元件通常是具有相同的附圖標記。 The following is a detailed description of various embodiments with reference to the accompanying drawings. The following description is intended to be illustrative of specific embodiments and methods, and is not intended to All of the following examples are intended to illustrate the invention and not to limit its scope, which is defined by the scope of the application of this patent. Those skilled in the art having ordinary knowledge will be able to understand various equivalent changes in the following description. Unless otherwise stated, the relationships specified in this application, for example, parallel, aligned, have uniform characteristics, or on the same plane, as a specified relationship, are indicative of limitations in the manufacturing process and variations in production. When the elements are described as being connected, connected, contacted or in contact with one another, they are not necessarily in physical contact with each other unless specifically described. The same elements in the various embodiments are generally given the same reference numerals.

第1圖為一三維半導體裝置100之示意圖(例如記憶體裝置),該半導體裝置描述於美國專利公開號2012/0182806,2011年4月1日提交,名稱為Memory Architecture of 3D Array With Alternating Memory String Orientation and String Select Structures。為了使主動層表現明顯,圖中許多絕緣材料未明確繪出,包括了半導體層和連接到層間導體的半導體墊以及其他部件。三維半導體裝置100於一基板(圖未繪示)上形成,基板上具有一絕緣層(圖未繪示)。該基板包括了至少一積體電路或其他結構。四個半導體墊102B、103B、104B與105B位於該堆疊的主動層的近端,而另外四個半導體墊112B、113B、114B與115B則位於該堆疊的主動層的末端。如圖所示,但該些相應主動層之數量與該些半導體墊之數量可以延伸至任何層數N,N為比1大之數字。如圖所示,此三維半導體裝置包括了主動層帶的堆疊(如102、103、104與105),該些主動層帶之間由絕緣材料所隔開,半導體墊(如102B、103B、104B與105B)隔開了對應主動層中的主動層帶。如圖繪示,該半導體墊102B、103B、104B與105B以電耦合方式與該些主動層連接,再連接解碼電路至陣列內的選擇層。半導體墊102B、103B、104B與105B與主動層可同時性地產生圖案化,只要用於層間導體的通孔發生例外的可能。在上述實施例中,每一條主動層帶包括適於由半導體材料製作之一通道區間。如圖所示,該些主動層帶沿Y軸呈脊狀分布,所以主動層帶102、103、104與105可配置為快閃記憶胞串之主體,也包括了通道區間於主體中。以下舉例,在水平NAND串狀配置中,如圖所示,一層記憶材料152表面鍍上複數層堆疊的主動層帶,且在其他範例中至少會位在主動層帶的側壁之上。在其他實施範例中,該些主動層帶可被配置為垂直NAND串狀配置之字元線。參見發明人共有之美國專利號8,363,476,名稱為Memory Device,Manufacturing Method and Operating Method of the Same。 1 is a schematic diagram of a three-dimensional semiconductor device 100 (eg, a memory device), which is described in US Patent Publication No. 2012/0182806, filed on April 1, 2011, entitled Memory Architecture of 3D Array With Alternating Memory String Orientation and String Select Structures. In order to make the active layer behave significantly, many of the insulating materials in the figure are not explicitly depicted, including semiconductor layers and semiconductor pads and other components connected to the interlayer conductors. The three-dimensional semiconductor device 100 is formed on a substrate (not shown) having an insulating layer (not shown). The substrate includes at least one integrated circuit or other structure. Four semiconductor pads 102B, 103B, 104B, and 105B are located at the proximal end of the active layer of the stack, while the other four semiconductor pads 112B, 113B, 114B, and 115B are located at the ends of the active layer of the stack. As shown, the number of corresponding active layers and the number of semiconductor pads can be extended to any number of layers N, N being a number greater than one. As shown, the three-dimensional semiconductor device includes a stack of active layers (eg, 102, 103, 104, and 105) separated by an insulating material between the active layers, such as 102B, 103B, 104B. The active layer strip in the corresponding active layer is separated from 105B). As shown, the semiconductor pads 102B, 103B, 104B, and 105B are electrically coupled to the active layers, and the decoding circuit is coupled to the selected layer within the array. The semiconductor pads 102B, 103B, 104B, and 105B and the active layer can be simultaneously patterned, as long as the vias for the interlayer conductors are exceptional. In the above embodiments, each active layer strip includes a channel section adapted to be fabricated from a semiconductor material. As shown, the active layer strips are ridged along the Y-axis, so the active layer strips 102, 103, 104, and 105 can be configured as the body of the flash memory cell string, and also include the channel sections in the body. In the following example, in a horizontal NAND string configuration, as shown, a layer of memory material 152 is plated with a plurality of layers of active layer strips, and in other examples at least over the sidewalls of the active layer strip. In other embodiments, the active layer strips can be configured as word lines in a vertical NAND string configuration. See U.S. Patent No. 8,363,476, the disclosure of which is incorporated herein by reference.

每一主動層帶之堆疊其中一端皆為半導體墊,而另外一端則 為源極線。因此,主動層帶102,103,104,105的終端為近端的半導體墊102B、103B、104B與105B而另一末端為源極線終端119,該源極線終端119通過一閘極選擇線127,主動層帶112、113、114與115的終端為遠端的半導體墊112B,113B,114B與115B且另一近端為源極線終端(例如源極線128),該源極線終端通過一閘極選擇線126。 One end of each active layer stack is a semiconductor pad, and the other end is It is the source line. Therefore, the terminals of the active layer strips 102, 103, 104, 105 are the proximal semiconductor pads 102B, 103B, 104B and 105B and the other end is the source line terminal 119. The source line terminal 119 passes through a gate select line 127, and the active layer strip 112 The terminals of 113, 114 and 115 are remote semiconductor pads 112B, 113B, 114B and 115B and the other proximal end is a source line terminal (for example, source line 128), and the source line terminal passes through a gate selection line. 126.

在第1圖的實施例中,複數個導體125-1到125-N正交排列於複數個主動層帶的堆疊上,該些導體125-1到125-N與該些主動層帶形成之堆疊具有一共形表面,該些導體組成的複數個堆疊之間有溝槽被界定,且在主動層帶102,103,104,105側表面的交界處之間界定複數層陣列之介面區間(interface region),該些陣列位在堆疊及導體125-1到125-N之上(例如:字元線或源極選擇線)。因此,一矽化層(例如:矽化鎢、矽化鈷,矽化鈦或鎳矽化物)154可在該些導體上方表面形成(例如:字元線或源極選擇線)。 In the embodiment of FIG. 1, a plurality of conductors 125-1 to 125-N are orthogonally arranged on a stack of a plurality of active layer strips, and the conductors 125-1 to 125-N are formed with the active layer strips. The stack has a conformal surface, a plurality of stacks of conductors are defined between the trenches, and an interface between the plurality of layers is defined between the intersections of the active layer strips 102, 103, 104, 105 side surfaces (interface Region), the arrays are above the stack and conductors 125-1 through 125-N (eg, word line or source select line). Thus, a germanium layer (eg, tungsten telluride, cobalt telluride, titanium telluride or nickel germanide) 154 may be formed on the upper surface of the conductors (eg, word line or source select line).

根據於離子植入程序,由記憶體材料製成的層152可包括複數層介電質電能儲存結構(dielectric charge storage structure)。舉例,一複數層介電質電能儲存結構包括一穿隧層,該穿隧層包括了一氧化矽材料、一由氮化矽製成之電荷儲存層以及一由氧化矽製成之阻隔層。在一些例子中,介電質電能儲存層中的穿隧層可包括一厚度小於2奈米的第一氧化矽層,一厚度小於3奈米的氮化矽層,以及一厚度小於3奈米的第二氧化矽層。在其他離子植入程序中,由記憶體材料製成的層152只包括電荷儲存層,而不包括穿隧層以及阻隔層。 Depending on the ion implantation procedure, layer 152 made of memory material can include a plurality of dielectric charge storage structures. For example, a plurality of layers of dielectric energy storage structures include a tunneling layer comprising a tantalum oxide material, a charge storage layer made of tantalum nitride, and a barrier layer made of tantalum oxide. In some examples, the tunneling layer in the dielectric energy storage layer can include a first tantalum oxide layer having a thickness of less than 2 nanometers, a tantalum nitride layer having a thickness of less than 3 nanometers, and a thickness of less than 3 nanometers. The second layer of ruthenium oxide. In other ion implantation procedures, layer 152 made of memory material includes only the charge storage layer, and does not include the tunneling layer and the barrier layer.

在其他替代方案中,反熔絲材料(anti-fuse materials)如二氧 化矽,氮氧化矽或是其他種類的氧化矽,該些材料的厚度等級約在1到5奈米之間,係為可以利用之等級。其他反熔絲材料,例如氮化矽也為可以利用的材料。在一反熔絲實施例中,主動層帶102、103、104與105可為一第一導電型(例如p型)的半導體材料,導體(例如字元線或源極選擇線)125-N可為一第二導電型(例如n型)半導體材料。當導體125-N係用較高摻雜率的n+-型多晶矽,則該些主動層帶102、103、104與105可使用p型多晶矽形成。在反熔絲實施例中,主動層帶之寬度必須有足夠空間提供給一空乏區以支援二極體操作,因此,記憶胞內部包括一由可程式化的反熔絲層形成p-n接面的整流電路,該整流電路於陽極與陰極之間,也就是在多晶矽層帶與導體線之間的三維陣列交叉點中。 In other alternatives, anti-fuse materials such as dioxins Plutonium, bismuth oxynitride or other types of cerium oxide, these materials have a thickness rating of between about 1 and 5 nanometers, which is a grade that can be utilized. Other antifuse materials, such as tantalum nitride, are also available materials. In an anti-fuse embodiment, the active layer strips 102, 103, 104, and 105 can be a first conductivity type (eg, p-type) semiconductor material, conductor (eg, word line or source select line) 125-N It can be a second conductivity type (eg, n-type) semiconductor material. When the conductors 125-N are made of a higher doping ratio of n+-type polysilicon, the active layer strips 102, 103, 104, and 105 may be formed using p-type polysilicon. In the anti-fuse embodiment, the width of the active layer must have sufficient space to provide a depletion region to support diode operation. Therefore, the internal memory cell includes a pn junction formed by a programmable antifuse layer. A rectifying circuit between the anode and the cathode, that is, in a three-dimensional array intersection between the polysilicon layer strip and the conductor line.

在其他實施例中,不同的可程式化電阻式記憶體材料同樣也可用做記憶體材料,包括金屬氧化物如氧化鎢或離子摻雜的金屬氧化物,或是其他材料,一些這般的材料可製成藉由多種電壓或電流編程或抹除的裝置,且可實現每一記憶胞儲存多位元組之操作。 In other embodiments, different programmable resistive memory materials can also be used as memory materials, including metal oxides such as tungsten oxide or ion doped metal oxides, or other materials, some such materials. A device that is programmed or erased by a variety of voltages or currents can be fabricated, and the operation of storing multiple bytes per memory cell can be achieved.

由第1圖可看出,該些半導體墊102B、103B、104B與105B配置於該裝置之相對應層中且連結一側的該些主動層帶,該些半導體墊為連續圖案化方式形成。在一些實施例中,該些位於相對應層中之半導體墊連結兩側的該些主動層帶。在其他實施例中,該些半導體墊可藉由其他材料或是結構連結該些主動層帶,此可產生電性連接而使裝置操作所需的電壓或電流通過。而且,一覆蓋於上的絕緣層(未繪示於圖中)與半導體墊102B、103B、104B與105B,最下方的半導體墊除外,包括了開口102C1、102C2、102C3、103C1、103C2與104C1,在其下方的半導體墊之上顯露出 多個著陸區而形成一階梯式結構。 As can be seen from FIG. 1, the semiconductor pads 102B, 103B, 104B and 105B are disposed in corresponding layers of the device and are connected to the active layer strips on one side, and the semiconductor pads are formed in a continuous patterning manner. In some embodiments, the semiconductor pads in the corresponding layers are connected to the active layer strips on both sides. In other embodiments, the semiconductor pads may be connected to the active layer strips by other materials or structures, which may result in electrical connections to pass voltages or currents required for operation of the device. Moreover, an overlying insulating layer (not shown) and semiconductor pads 102B, 103B, 104B and 105B, except for the lowermost semiconductor pad, include openings 102C1, 102C2, 102C3, 103C1, 103C2 and 104C1, Exposed on the underlying semiconductor pad A plurality of landing zones form a stepped structure.

一種連接層間導體與堆疊內之主動層的方式為多道顯影蝕刻製程,揭露於發明人共有之美國專利號8,383,512,名稱為Method for Making Multilayer Connection Structure,此揭露在此引用作為參考。另一種相同的應用方法,稱作剪切蝕刻製程(trim-etch process),揭露於發明人共有之美國專利申請號13/735,922,於2013年1月7日提交,名稱為Method for Forming Interlayer Conductors to a Stack of Conductor Layers,此揭露在此引用作為參考。 One way of connecting the interlayer conductors to the active layers in the stack is a multi-pass development etch process, which is disclosed in U.S. Patent No. 8,383,512, the entire disclosure of which is incorporated herein by reference. A similar application method, called a trim-etch process, is disclosed in the inventor's U.S. Patent Application Serial No. 13/735,922, filed on Jan. 7, 2013, entitled Method for Forming Interlayer Conductors To a Stack of Conductor Layers, the disclosure of which is incorporated herein by reference.

第2A-2F圖繪示一用於形成接觸窗結構的多道顯影蝕刻製程,第2A圖繪示了一堆疊200,該堆疊200內有交替的多個主動層202與多個絕緣層204,最上方的主動層202.1覆蓋有一第一蝕刻屏蔽206。第一蝕刻屏蔽206有多個第一蝕刻屏蔽開口208。第2B圖繪示了第2A圖之結構經第一階蝕刻後的情形,也就是一主動層202和一絕緣層204,該第一蝕刻於蝕刻屏蔽開口208中產生第一蝕刻開口210。第一蝕刻屏蔽206經移除後,見第2C圖,一第二蝕刻屏蔽212形成並覆蓋於堆疊200之上。見第2D圖,第二蝕刻屏蔽有多個第二蝕刻屏蔽開口214,該些蝕刻屏蔽開口214之一對齊第一蝕刻開口208,其餘則否。接下來,如第2E圖所示,第二階段進行第二次蝕刻,形成多個通孔並延伸至該第二、第三及第四主動層202.2,202.3與204.4與第一主動層202.1在第二層蝕刻屏蔽移除後被顯露出來,如第2F圖所示。 2A-2F illustrates a multi-pass development etching process for forming a contact window structure, and FIG. 2A illustrates a stack 200 having alternating active layers 202 and a plurality of insulating layers 204 therein. The uppermost active layer 202.1 is covered with a first etched shield 206. The first etch mask 206 has a plurality of first etch shield openings 208. FIG. 2B illustrates a second etching process of the structure of FIG. 2A, that is, an active layer 202 and an insulating layer 204. The first etching creates a first etching opening 210 in the etch shielding opening 208. After the first etch mask 206 is removed, see FIG. 2C, a second etch mask 212 is formed overlying the stack 200. Referring to FIG. 2D, the second etch mask has a plurality of second etched shield openings 214, one of the etched shield openings 214 being aligned with the first etched opening 208, and the rest is not. Next, as shown in FIG. 2E, the second stage performs a second etching to form a plurality of via holes and extend to the second, third, and fourth active layers 202.2, 202.3 and 204.4 and the first active layer 202.1. The second layer of etch mask is removed after removal, as shown in Figure 2F.

堆疊200由主動層202與絕緣層204所製成,該些主動層202與絕緣層204各自有相同的蝕刻性質。在此例中,主動層202由相同導 電材料所製成且具有相同厚度。同樣的,絕緣層204由相同絕緣材料所製成且具有相同厚度。因此,每一對主動層與絕緣層在一已知蝕刻製程中會有一相同的蝕刻時間,此種主動層與絕緣層成對的配置可視為具有簡單排列之堆疊層。 The stack 200 is made of an active layer 202 and an insulating layer 204, each of which has the same etching properties as the insulating layer 204. In this example, the active layer 202 is the same guide Made of electrical materials and of the same thickness. Likewise, the insulating layer 204 is made of the same insulating material and has the same thickness. Therefore, each pair of active layers and the insulating layer have the same etching time in a known etching process, and the configuration in which the active layer and the insulating layer are paired can be regarded as a stacked layer having a simple arrangement.

第3A-3D圖繪示了一不具有簡單排列之堆疊層,與第2A-2F圖相似的堆疊層。在此例中,第三絕緣層204.3之厚度比起上方的絕緣層204.2與204.1更厚,因此,該第三絕緣層204.3所花之蝕刻時間比絕緣層204.1更多。第一上邊界主動層202.1,第一絕緣層204.1,第二主動層202.4以及第二絕緣層204.2在第二蝕刻屏蔽開口214.1進行蝕刻時,相對於第三絕緣層204.3在第二蝕刻屏蔽開口214.2進行蝕刻時則可以完整完成。 Figures 3A-3D illustrate a stacked layer that is similar to the 2A-2F diagram without a simple arrangement of stacked layers. In this example, the thickness of the third insulating layer 204.3 is thicker than the insulating layers 204.2 and 204.1 above, and therefore, the etching time of the third insulating layer 204.3 is more than that of the insulating layer 204.1. The first upper boundary active layer 202.1, the first insulating layer 204.1, the second active layer 202.4, and the second insulating layer 204.2 are etched in the second etched shield opening 214.1, and the second etched shield opening 214.2 is opposite to the third insulating layer 204.3. It can be completed completely when etching.

如同此處所敘述,該些結構提供了一非簡單排列,主動層與/或絕緣層有相異的蝕刻時間,主動層與/或絕緣層之間由不同材料製程和不同的蝕刻性質,甚至是不同的厚度,或為一包括主動層與/或絕緣層之間的不同材料和不同厚度的組合。 As described herein, the structures provide a non-simple arrangement in which the active layer and/or the insulating layer have different etching times, the active layer and/or the insulating layer are formed of different materials and different etching properties, or even Different thicknesses, or a combination of different materials and different thicknesses between the active layer and/or the insulating layer.

第4A-4G圖繪示了一剪切蝕刻製程的簡易範例。一蝕刻屏蔽220形成於最上邊界主動層202.1之上,該蝕刻屏蔽220有一蝕刻屏蔽開口222其顯露出最上邊界主動層之一部份224。如第4B圖所示,第一蝕刻步驟為:蝕刻穿越主動層202.1與絕緣層204.1使主動層202.2顯露出一部分226。經過一第一剪切步驟後,一部份的蝕刻屏蔽220經移除並顯露出最上邊界主動層202.1之另一部分228。下一蝕刻步驟如第4D圖所示,蝕刻穿越主動層202和一絕緣層204使該主動層202.2之部分230,以及該主動層 202.3之部分232皆顯露出來。經過第二剪切步驟後,見第4E圖,一部份的蝕刻屏蔽220經移除並顯露出最上邊界主動層202.1之部分234。接續另一蝕刻步驟,見第4F圖,在開口234、230與232之部分穿越一主動層與一絕緣層後產生出如第4F圖所示之結構,經移除蝕刻屏蔽220後,第4G圖繪示出一階梯式結構236有一數量之著陸區238,分別對應至主動層202.1-202.4,藉此連接主動層與層間導體。 4A-4G illustrate a simplified example of a shear etch process. An etch mask 220 is formed over the uppermost boundary active layer 202.1. The etch mask 220 has an etched shield opening 222 that exposes a portion 224 of the uppermost active layer. As shown in FIG. 4B, the first etching step is: etching through the active layer 202.1 and the insulating layer 204.1 to expose the active layer 202.2 to a portion 226. After a first shearing step, a portion of the etch mask 220 is removed and reveals another portion 228 of the uppermost active layer 202.1. The next etching step, as shown in FIG. 4D, etches through the active layer 202 and an insulating layer 204 to form a portion 230 of the active layer 202.2, and the active layer Part 232 of 202.3 is revealed. After the second shearing step, see Figure 4E, a portion of the etch mask 220 is removed and reveals a portion 234 of the uppermost active layer 202.1. Following another etching step, see FIG. 4F, after a portion of the openings 234, 230, and 232 traverses an active layer and an insulating layer, a structure as shown in FIG. 4F is produced. After the etching shield 220 is removed, the 4G is removed. The figure illustrates a stepped structure 236 having a number of landing zones 238 corresponding to the active layers 202.1-202.4, respectively, thereby connecting the active layer to the interlayer conductor.

第5A-5D圖繪示一例,該例與第4A-4G圖所示範之相近。兩例之堆疊皆為非簡單排列。在此例中,第二絕緣層204.2比起上方或下方之絕緣層厚更多,經過如第5D圖之蝕刻步驟後,該步驟可對應至第4D圖,該蝕刻步驟已足夠蝕刻主動層202.1的部分228與位於下方之絕緣層204.1之部分,以使主動層232.2的部分230顯露出來。儘管如此,見第5D圖所繪示,該蝕刻步驟只能使部分的絕緣層204.2完成蝕刻,因為該絕緣層204.2之厚度較大,同時也須更長的蝕刻時間。因此,與第4D圖不同的是,該第三主動層202.3不會在第二蝕刻步驟時顯露出來。儘管如此,使第二蝕刻步驟繼續進行,穿過第二絕緣層204.2直到第三主動層202.3被顯露出來,可能損毀或破壞主動層202.2之顯露部分230。 An example is shown in Figures 5A-5D, which is similar to that illustrated in Figures 4A-4G. The stacking of the two cases is a non-simple arrangement. In this example, the second insulating layer 204.2 is thicker than the insulating layer above or below. After the etching step as in FIG. 5D, the step may correspond to the 4D drawing, which is sufficient to etch the active layer 202.1. Portion 228 is portion of insulating layer 204.1 located below to expose portion 230 of active layer 232.2. Nonetheless, as seen in Fig. 5D, the etching step can only complete etching of a portion of the insulating layer 204.2 because the thickness of the insulating layer 204.2 is large and a longer etching time is required. Therefore, unlike FIG. 4D, the third active layer 202.3 is not exposed at the second etching step. Nonetheless, the second etching step is continued through the second insulating layer 204.2 until the third active layer 202.3 is exposed, possibly exposing or destroying the exposed portion 230 of the active layer 202.2.

以上述為背景,第6圖繪示一接觸窗結構250同樣由主動層與絕緣層交替之堆疊為非簡單排列。接觸窗結構250包括了一由主動層202與絕緣層204交替之堆疊200,堆疊200包 括多個子堆疊252,該些子堆疊252有上邊界主動層202.1。該些子堆疊252同時也有第一層對(first layer pairs)254,該第一層對254由主動層202與絕緣層204交替而成,位於各個上邊界主動層202.1之下。在第6圖的實施例中,有四個子堆疊分別標號為252.1到252.4。該第一層對254由主動層202與絕緣層204交替且在一已知的蝕刻製程中有相同的第一蝕刻時間。堆疊200也包括在子堆疊252之間的子堆疊絕緣層256、258與260。在此實施例中,子堆疊絕緣層256與260之組成成分相同,同樣由二氧化矽SiO2製成,而子堆疊絕緣層258則由氮化矽SiN製成。子堆疊絕緣層256與260的厚度和組成實質上完全相同,因此具有實質上相同的蝕刻性質。儘管如此,子堆疊絕緣層256與260的厚度遠大於絕緣層204,因此在已知的蝕刻製程中,穿透子堆疊絕緣層256與260所需的時間大於穿透絕緣層204所需之時間。 Against the background of the above, FIG. 6 illustrates that a contact window structure 250 is also a non-simple arrangement of alternating stacks of active layers and insulating layers. Contact window structure 250 includes a stack 200 of alternating active layer 202 and insulating layer 204, stacking 200 packages A plurality of sub-stacks 252 are included, the sub-stacks 252 having an upper boundary active layer 202.1. The sub-stacks 252 also have a first layer pair 254 which is formed by alternating the active layer 202 and the insulating layer 204 under each of the upper boundary active layers 202.1. In the embodiment of Figure 6, there are four sub-stacks labeled 252.1 to 252.4, respectively. The first layer pair 254 is alternated between the active layer 202 and the insulating layer 204 and has the same first etch time in a known etch process. Stack 200 also includes sub-stack insulating layers 256, 258, and 260 between sub-stacks 252. In this embodiment, the sub-stack insulating layers 256 and 260 have the same composition, and are also made of cerium oxide SiO2, and the sub-stack insulating layer 258 is made of tantalum nitride SiN. Sub-stack insulation layers 256 and 260 are substantially identical in thickness and composition and thus have substantially the same etch properties. Nonetheless, the thickness of the sub-stack insulating layers 256 and 260 is much greater than the insulating layer 204, so the time required to penetrate the sub-stack insulating layers 256 and 260 is greater than the time required to penetrate the insulating layer 204 in a known etching process. .

子堆疊絕緣層256與位於其下的相鄰主動層202.1構成了一第二層對262,該第二層對262在已知蝕刻製程中有一第二蝕刻時間。子堆疊絕緣層260與位於其下的相鄰主動層202.1構成了一第三層對264,該第三層對264在已知的蝕刻製程中有一同樣的第二蝕刻時間。子堆疊絕緣層258與位於其下的相鄰主動層202.1構成了一第四層對266,該第四層對266在已知的蝕刻製程中有一異於第一到第三蝕刻時間的第四蝕刻時間。針對不同層對254、262、264與266之蝕刻時間,可由一廣範圍的,相同或相異的材料性質、蝕刻率或是相同/相異的主動層及絕緣層的 厚度來決定。 The sub-stack insulating layer 256 and the adjacent active layer 202.1 located thereunder form a second layer pair 262 having a second etch time in a known etching process. The sub-stack insulation layer 260 and the adjacent active layer 202.1 located thereunder form a third layer pair 264 having the same second etch time in a known etch process. The sub-stack insulating layer 258 and the adjacent active layer 202.1 located thereunder form a fourth layer pair 266 having a fourth different from the first to third etching times in a known etching process. Etching time. The etching time for the different layer pairs 254, 262, 264 and 266 can be varied from a wide range of the same or different material properties, etching rates or the same/different active and insulating layers. The thickness is determined.

接觸窗結構250包括一上絕緣層268,該上絕緣層268位於子堆疊252.1之主動層202.1之上。一下絕緣層270位於子堆疊252.4中的主動層202.4之下方。上絕緣層268與下絕緣層270皆由二氧化矽所製成。一組層間導體272延伸穿過上絕緣層268以階梯方式與每一子堆疊252中的每一主動層202連結。每一層間導體272由側壁絕緣274包圍,該側壁絕緣274由氮化矽製成。 Contact window structure 250 includes an upper insulating layer 268 that is over active layer 202.1 of sub-stack 252.1. The lower insulating layer 270 is located below the active layer 202.4 in the sub-stack 252.4. Both the upper insulating layer 268 and the lower insulating layer 270 are made of hafnium oxide. A set of interlayer conductors 272 extend through upper insulating layer 268 in a stepped manner with each active layer 202 in each sub-stack 252. Each interlayer conductor 272 is surrounded by a sidewall insulation 274 made of tantalum nitride.

第7-25圖為第6圖中接觸窗結構250的多道微影蝕刻製程步驟的實施例,與第2A-2F圖一併參考討論。 Figures 7-25 illustrate an embodiment of a multi-pass lithography process step of the contact window structure 250 of Figure 6, which is discussed in conjunction with Figures 2A-2F.

第7圖繪示該堆疊200包括子堆疊252.1-252.4,該堆疊200位於上絕緣層268與下絕緣層270之間,該些子堆疊之間由子堆疊絕緣層256,258,260所分隔。第8圖繪示了堆疊200(如第7圖所示)上覆蓋一第一蝕刻屏蔽278,該第一蝕刻屏蔽278有第一蝕刻屏蔽開口280。第9圖繪示經蝕刻後第一蝕刻屏蔽開口280穿越絕緣層268,往下蝕刻至下邊界主動層202.1形成第一蝕刻開口282。第10圖則繪示第一蝕刻屏蔽278被移除後之結構。 FIG. 7 illustrates that the stack 200 includes sub-stacks 252.1-252.4 between the upper insulating layer 268 and the lower insulating layer 270, which are separated by sub-stack insulating layers 256, 258, 260. FIG. 8 illustrates that the stack 200 (shown in FIG. 7) is overlaid with a first etch mask 278 having a first etch shield opening 280. FIG. 9 illustrates that the first etched shield opening 280 passes through the insulating layer 268 after etching, and is etched down to the lower boundary active layer 202.1 to form a first etched opening 282. FIG. 10 illustrates the structure after the first etch mask 278 is removed.

第11圖繪示堆疊重新覆上一第二蝕刻屏蔽284,該第二蝕刻屏蔽284覆蓋了第一蝕刻開口282的一半,第二蝕刻屏蔽284上有第二蝕刻屏蔽開口286與其餘一半的第一蝕刻開口282相對齊。在第12圖中,經蝕刻後第二蝕刻屏蔽開口286往下蝕刻至下邊界主動層202.1形成蝕刻開口288。第13圖則繪示第 二蝕刻屏蔽284被移除以顯露出第一蝕刻開口282之情形。 11 illustrates that the stack is overlaid with a second etch mask 284 covering half of the first etch opening 282, and the second etch mask 284 has a second etch shield opening 286 and the remaining half of the An etched opening 282 is aligned. In FIG. 12, the second etched shield opening 286 is etched down to the lower boundary active layer 202.1 to form an etch opening 288. Figure 13 shows the first The second etch mask 284 is removed to reveal the first etched opening 282.

第14圖繪示第13圖之堆疊200重新覆上一第三蝕刻屏蔽290,該第三蝕刻屏蔽290有一第三蝕刻屏蔽開口292.1顯露出第二蝕刻開口282的一半,該第三蝕刻屏蔽290之第三蝕刻屏蔽開口292.2覆蓋了第二蝕刻開口288的一半。第15圖繪示了第14圖中,堆疊200經第三蝕刻開口292.1蝕刻穿過第一子堆疊252.1與子堆疊絕緣層256,第15圖同時繪示了經第三蝕刻開口292.2蝕刻穿過第三子堆疊252.3與子堆疊絕緣層260的結果,以上過程形成了第三蝕刻開口294與第四蝕刻開口296。第16圖則繪示第三蝕刻屏蔽290移除之情形。 14 shows that the stack 200 of FIG. 13 is overlaid with a third etch mask 290 having a third etch shield opening 292.1 exposing half of the second etch opening 282, the third etch mask 290 The third etch shield opening 292.2 covers half of the second etch opening 288. 15 illustrates that in FIG. 14, the stack 200 is etched through the first sub-stack 252.1 and the sub-stack insulating layer 256 via the third etch opening 292.1, and FIG. 15 simultaneously illustrates etching through the third etch opening 292.2. As a result of the third sub-stack 252.3 and the sub-stacked insulating layer 260, the above process forms a third etch opening 294 and a fourth etch opening 296. Figure 16 illustrates the removal of the third etched shield 290.

第17圖繪示了一第四蝕刻屏蔽298,其有第四蝕刻屏蔽開口299,該第四蝕刻屏蔽開口299顯露了前述所有第一到第四蝕刻開口282、288、294與296。第18圖繪示一蝕刻步驟在每一子堆疊252.1、252.2、252.3與252.4中,穿越了上邊界主動層202.1及下方的絕緣層204.1。此步驟形成了一部分蝕刻結構300,該部分蝕刻結構300移除第四蝕刻屏蔽298如第19圖所繪示。該部分蝕刻結構300有開口302延伸至堆疊200內的不同層階。第20圖繪示了一第五蝕刻屏蔽304覆蓋及顯露兩開口302,第五蝕刻屏蔽有蝕刻屏蔽開口306,位於第19圖中顯露的蝕刻開口302之上。第21圖則繪示了蝕刻屏蔽開口306穿越了兩主動層202與兩絕緣層204。 FIG. 17 illustrates a fourth etch mask 298 having a fourth etch shield opening 299 that exposes all of the first through fourth etch openings 282, 288, 294, and 296. Figure 18 illustrates an etch step in each of the sub-stacks 252.1, 252.2, 252.3, and 252.4, traversing the upper boundary active layer 202.1 and the underlying insulating layer 204.1. This step forms a portion of the etched structure 300 that removes the fourth etched mask 298 as depicted in FIG. The partially etched structure 300 has openings 302 that extend to different levels within the stack 200. Figure 20 illustrates a fifth etch mask 304 covering and exposing the two openings 302. The fifth etch shield has an etch shield opening 306 over the exposed etch opening 302 shown in FIG. Figure 21 illustrates the etched shield opening 306 traversing the two active layers 202 and the two insulating layers 204.

第22圖為第21圖移除了第五蝕刻屏蔽304的示意 圖,通孔308往下延伸至主動層302的著陸區310,第22圖之結構有階梯式排列之著陸區310。第23圖繪示一絕緣層312,該絕緣層312例如由氮化矽所製成,置放在結構內的每一通孔308,以形成一側壁絕緣314。在第24圖中,絕緣層312位於絕緣層268之上,且將在該些通孔308底部之絕緣層312移除,使著陸區310可顯露出來。在第25圖繪示了該些通孔308內以一導體填充,如鎢W,以生出層間導體272,該些層間導體從上絕緣層268延伸至每一主動層202的著陸區310。此可生出如第6圖的接觸窗結構。 Figure 22 is a schematic view of the second etching shield 304 removed from Figure 21 The through hole 308 extends downward to the landing zone 310 of the active layer 302. The structure of Fig. 22 has a landing zone 310 arranged in a stepped manner. FIG. 23 illustrates an insulating layer 312, such as tantalum nitride, disposed in each via 308 in the structure to form a sidewall insulating 314. In FIG. 24, the insulating layer 312 is over the insulating layer 268, and the insulating layer 312 at the bottom of the vias 308 is removed, so that the landing zone 310 can be exposed. In FIG. 25, the vias 308 are filled with a conductor, such as tungsten W, to produce interlayer conductors 272 extending from the upper insulating layer 268 to the landing zone 310 of each active layer 202. This produces a contact window structure as shown in FIG.

第26-43圖為一剪切蝕刻製程步驟實施例,前述之第4A-4G圖所討論之剪切蝕刻製程為此處的簡化實施例。 Figures 26-43 illustrate an embodiment of a shear etch process step, and the shear etch process discussed in Figures 4A-4G above is a simplified embodiment herein.

第26圖繪示了一與堆疊200(第7圖)相同的堆疊330,唯獨缺少了上絕緣層268。一第一蝕刻屏蔽332形成於堆疊330之上,該第一蝕刻屏蔽332覆蓋於子堆疊252.1之主動層202.1的部分331,且顯露出約一半的主動層。經過第一蝕刻步驟後,該結果於第27圖表示,經由顯露部分,子堆疊252.1,子堆疊絕緣256,第二子堆疊252.2以及子堆疊絕緣層258皆有一半部分蝕刻完成。顯露出第三子堆疊252.3之上邊界主動層202.1之部分334。 Figure 26 depicts the same stack 330 as stack 200 (Fig. 7), except that the upper insulating layer 268 is missing. A first etch mask 332 is formed over the stack 330, the first etch mask 332 overlying the portion 331 of the active layer 202.1 of the sub-stack 252.1 and revealing approximately half of the active layer. After the first etching step, the result is shown in Fig. 27, via the exposed portion, the sub-stack 252.1, the sub-stack insulation 256, the second sub-stack 252.2, and the sub-stack insulating layer 258 are all partially etched. A portion 334 of the boundary active layer 202.1 above the third sub-stack 252.3 is exposed.

第28圖繪示第27圖之結構,其覆蓋一第二蝕刻屏蔽336於上,該第二蝕刻屏蔽覆蓋並顯露出一半的部分334與大約一半的部分331,在顯露部分331,蝕刻穿透子堆疊252.1與子 堆疊絕緣層256。而在顯露部分334,蝕刻穿透子堆疊252.3與子堆疊絕緣層260。此步驟生出了如第29圖所示之結構,該結構有表面區域338、340、342與344。在第30圖,第二蝕刻屏蔽被移除於第29圖所示之結構。 Figure 28 is a diagram showing the structure of Figure 27, which covers a second etch mask 336 which covers and reveals a half of the portion 334 and about half of the portion 331 at the exposed portion 331, etching through Sub-stacking 252.1 and sub-sub The insulating layer 256 is stacked. In the exposed portion 334, the penetration sub-stack 252.3 and the sub-stack insulating layer 260 are etched. This step produces a structure as shown in Fig. 29 having surface areas 338, 340, 342 and 344. In Fig. 30, the second etch mask is removed from the structure shown in Fig. 29.

第31圖繪示第三蝕刻屏蔽346覆蓋於表面338-344,且顯露出該些表面338-344之一部份,然後蝕刻穿透一主動層202與一絕緣層204,以生出如第32圖所繪示的結構。該結構有顯露的表面區域348-351。在此之後,第33圖繪示一第三蝕刻屏蔽352經修整後產生一剪切蝕刻屏蔽354,該剪切蝕刻屏蔽354顯露出每一子堆疊252.1-252.4的主動層202.1之多餘部分。皆下來為另一蝕刻步驟,穿透一主動層202與絕緣層204,結果於第34圖所示。第35圖繪示了該剪切蝕刻屏蔽354經修整後產生的剪切蝕刻屏蔽356,再一次顯露使一主動層202與下方的絕緣層204受到蝕刻處理,結果如第36圖所示。 FIG. 31 illustrates that the third etch mask 346 covers the surface 338-344 and exposes a portion of the surfaces 338-344, and then etches through an active layer 202 and an insulating layer 204 to produce a 32. The structure shown in the figure. The structure has exposed surface areas 348-351. Thereafter, FIG. 33 illustrates that a third etch mask 352 is trimmed to produce a shear etch mask 354 that reveals excess portions of the active layer 202.1 of each sub-stack 252.1-252.4. All of them are another etching step, which penetrates an active layer 202 and an insulating layer 204. The result is shown in Fig. 34. Figure 35 illustrates the shear etch mask 356 produced by the trim etch mask 354 after being trimmed, again exposing an active layer 202 and the underlying insulating layer 204 to an etch process, as shown in Figure 36.

第37圖繪示了第36圖移除了剪切蝕刻屏蔽356之結果,該結構顯示出以一階梯式排列的著陸區358。如第38圖所示,在階梯式結構上覆以一絕緣層360,或稱作阻隔層360,可由如氮化矽SiN所製成。接下來,如第39圖所示,整個結構上方被一絕緣材料362所覆蓋,可由如二氧化矽所製作。接下來,一第四蝕刻屏蔽364具有與著陸區358對齊之開口366,該第四蝕刻屏蔽形成於絕緣材料362之上。蝕刻後,通孔368穿越絕緣材料362與絕緣層360到達著陸區358。此結果繪示於第41圖。 第42圖繪示第41圖之結構經移除第四蝕刻屏蔽364。第43圖表示出層間導體272,該層間導體可由鎢W所製作,形成於通孔368內且產生出接觸窗結構370。 Figure 37 illustrates the result of the removal of the shear etch mask 356 in Figure 36, which shows the landing zone 358 in a stepped arrangement. As shown in Fig. 38, the stepped structure is covered with an insulating layer 360, or a barrier layer 360, which may be made of, for example, tantalum nitride SiN. Next, as shown in Fig. 39, the entire structure is covered by an insulating material 362, which can be made of, for example, cerium oxide. Next, a fourth etch mask 364 has an opening 366 aligned with the landing zone 358 formed over the insulating material 362. After etching, the vias 368 pass through the insulating material 362 and the insulating layer 360 to reach the landing zone 358. This result is shown in Figure 41. Figure 42 illustrates the structure of Figure 41 with the fourth etch mask 364 removed. The 43rd diagram shows the interlayer conductor 272, which may be fabricated from tungsten W, formed in the via 368 and creates a contact structure 370.

第44圖為一簡化流程圖,該流程圖繪示第7-25圖所示之接觸窗結構形成方法的步驟。在步驟380中形成一由主動層202與絕緣層204交替之堆疊200。步驟382中複數個開口294,288與296蝕刻至該堆疊中,該些開口深入至邊界主動層202.1。在步驟384,特定的開口294,288與296更深入蝕刻以產生通孔308。在步驟366與388中,絕緣層314形成於通孔308之中以及尚未被蝕刻的開口294、288與296之中。接續步驟390中層間導體272之形成,層間導體272連接至主動區域202的著陸區310。 Figure 44 is a simplified flow chart showing the steps of the method of forming the contact window structure shown in Figures 7-25. A stack 200 of alternating active layer 202 and insulating layer 204 is formed in step 380. In step 382, a plurality of openings 294, 288 and 296 are etched into the stack, the openings deep into the boundary active layer 202.1. At step 384, the particular openings 294, 288 and 296 are etched deeper to create vias 308. In steps 366 and 388, an insulating layer 314 is formed in vias 308 and openings 294, 288, and 296 that have not been etched. Following the formation of the interlayer conductor 272 in step 390, the interlayer conductor 272 is connected to the landing zone 310 of the active region 202.

第45圖為一簡化流程圖,該流程圖繪示了第26-43圖所示之接觸窗結構形成方法的基本步驟。在步驟392,形成一由主動層202與絕緣層204交替之堆疊330。在步驟394中堆疊330經一蝕刻處理以顯露出區域338、342與344,該些區域位於子堆疊252之上邊界主動層202.1。區域338、342與344同時也可稱作表面區域338、342與344。在步驟396中,該些區域經蝕刻至顯露出主動層202.2、202.3與202.4,該些主動層位於上邊界主動層202.1之下,藉此形成一階梯式結構。步驟398中一絕緣層360形成於該階梯式結構。步驟400,該絕緣層360上覆蓋一絕緣材料362。在步驟402中,形成通孔368穿透絕緣材料362 與絕緣層400。在步驟404中,層間導體372置於通孔368之內,以產生一接觸窗結構370。 Figure 45 is a simplified flow chart showing the basic steps of the method of forming the contact window structure shown in Figures 26-43. At step 392, a stack 330 of alternating active layer 202 and insulating layer 204 is formed. In step 394, stack 330 is etched to expose regions 338, 342, and 344 that are located above boundary active layer 202.1 of sub-stack 252. Regions 338, 342, and 344 may also be referred to as surface regions 338, 342, and 344 at the same time. In step 396, the regions are etched to reveal active layers 202.2, 202.3, and 202.4, the active layers being under the upper boundary active layer 202.1, thereby forming a stepped structure. In step 398, an insulating layer 360 is formed in the stepped structure. In step 400, the insulating layer 360 is covered with an insulating material 362. In step 402, a via hole 368 is formed to penetrate the insulating material 362. And insulating layer 400. In step 404, the interlayer conductor 372 is placed within the via 368 to create a contact structure 370.

第46圖為一簡化流程圖,該流程圖繪示了第7-25圖與第26-43圖所示之接觸窗結構形成方法的基本步驟。在步驟410中,形成由主動層202與絕緣層204交替之堆疊220、380,由第一、第二、第三與第四子堆疊252所組成,每一子堆疊252中有多層主動層202,該些主動層之間由絕緣層204所隔開。每一子堆疊中的該些主動層202包括一上邊界主動層202.1。在步驟412中,第一、第二、第三子堆疊絕緣層256、258、260形成並設置於子堆疊252之間。在第一、第二以及第三子堆疊絕緣層中,至少兩層子堆疊絕緣層與子堆疊的絕緣層204在已知的蝕刻製程中有不同的蝕刻時間。在步驟414中,上邊界主動層202.1被接通,接下來其他主動層202.2-202.4在步驟416中被接通,構成如第22與42圖的階梯式結構。在步驟418,層間導體272形成並延伸至著陸區310、318。該些層間導體之間由絕緣材料所隔開。 Figure 46 is a simplified flow chart showing the basic steps of the method of forming the contact window structure shown in Figures 7-25 and 26-43. In step 410, a stack 220, 380 of alternating active layer 202 and insulating layer 204 is formed, consisting of first, second, third, and fourth sub-stacks 252, each having multiple layers of active layers 202 The active layers are separated by an insulating layer 204. The active layers 202 in each sub-stack include an upper boundary active layer 202.1. In step 412, the first, second, and third sub-stack insulating layers 256, 258, 260 are formed and disposed between the sub-stacks 252. In the first, second, and third sub-stack insulation layers, at least two sub-stack insulation layers and sub-stack insulation layers 204 have different etching times in known etching processes. In step 414, the upper boundary active layer 202.1 is turned "on", and then the other active layers 202.2-202.4 are turned "on" in step 416 to form a stepped structure as shown in Figures 22 and 42. At step 418, the interlayer conductors 272 are formed and extend to the landing zones 310, 318. The interlayer conductors are separated by an insulating material.

第47圖為一積體電路的簡化方塊圖,該積體電路975包含了一三維NAND快閃記憶體陣列960,結構如第1圖所示,以此為例,在一半導體基板上佈有高密度,窄線寬的全域字元線,一列解碼器(row decoder)961與複數條字元線連結,且排列於記憶體陣列960的橫列方向。一行解碼器(column decoder)963與複數條SSL線964連結且沿直行方向排列,用於讀取和編程資 料,該些資料來自於堆疊內的記憶陣列960內的該些記憶胞。一平面解碼器(plane decoder)958通過字元線959與記憶陣列960內的複數個平面連結。位址由總線(bus)965所供應並連結至行解碼器965,列解碼器961與平面解碼器958。位於區塊966中的檢測放大器(sense amplifier)與資料輸入結構則與行解碼器963連接。在此例中,透過總線967,資料供應透過資料輸入線路(data-in line)971,該資料從積體電路971上之輸入/輸出埠供應,或是透過其他位於積體電路975上之內部/外部資料源來供應,送至位於區塊966的資料輸入結構。在上述實施例中,另一線路974包含至積體電路975中,用於做為一通用處理器或一特殊用途應用處理線路,或是一模組之集合以提供一由NAND快閃記憶體陣列支援的系統單晶片。資料透過檢測放大器上的資料輸出線(data-out line)972傳送至輸入/輸出埠,或是其他位於積體電路975內部/外部的資料目的地。 Figure 47 is a simplified block diagram of an integrated circuit 975 comprising a three-dimensional NAND flash memory array 960 having the structure shown in Figure 1, for example, on a semiconductor substrate. A high density, narrow linewidth global word line, a row decoder 961 is coupled to a plurality of word lines and arranged in the course direction of the memory array 960. A row decoder 963 is connected to a plurality of SSL lines 964 and arranged in a straight direction for reading and programming. The data is derived from the memory cells within the memory array 960 within the stack. A plane decoder 958 is coupled to a plurality of planes within memory array 960 by word line 959. The address is supplied by bus 965 and coupled to row decoder 965, column decoder 961 and plane decoder 958. A sense amplifier and data input structure located in block 966 is coupled to row decoder 963. In this example, through the bus 967, the data is supplied through a data-in line 971 which is supplied from the input/output port on the integrated circuit 971 or through other internals located on the integrated circuit 975. / External data source to supply, to the data entry structure located in block 966. In the above embodiment, another line 974 is included in the integrated circuit 975 for use as a general purpose processor or a special purpose application processing circuit, or a collection of modules to provide a NAND flash memory. System single chip supported by the array. The data is transmitted to the input/output port through a data-out line 972 on the sense amplifier, or other data destinations located inside/outside of the integrated circuit 975.

以一控制單元實現,在此例中,運用一偏壓設置狀態機(bias arrangement state machine)969,透過位於區域968的電壓供應器或電源供應器產生或供應電壓,控制偏壓設置的電壓的應用,進行如讀取,消除,程式化或是清除驗證與程式化驗證所需的電壓。就已知的習知技術,該控制單元可藉由特殊用途邏輯回路實現。在其他實施例中,該控制單元包含了一通用處理器,其可能會被實現於同一積體電路用於執行一控制之電腦程式。在另外的實施例中,一特殊用途邏輯回路與通用處理器的結合可利 用於控制單元的實現。 Implemented by a control unit, in this example, a bias arrangement state machine 969 is used to generate or supply a voltage through a voltage supply or power supply located in region 968 to control the bias voltage setting. Application, such as reading, erasing, stylizing or clearing the voltage required for verification and stylization verification. With known prior art techniques, the control unit can be implemented by a special purpose logic loop. In other embodiments, the control unit includes a general purpose processor that may be implemented in the same integrated circuit for executing a controlled computer program. In another embodiment, a special purpose logic loop is combined with a general purpose processor Used for the implementation of the control unit.

在許多實施例中,一三維陣列裝置如記憶體裝置,該三維陣列裝置包括了一複數層圖案化的半導體材料,每一圖案化層包括了複數條由半導體材料形成之平行線,該些平行線一端連接至一半導體墊的第一側,該些半導體墊連接至在一堆疊內設置的複數層圖案化層,每一半導體墊皆包括了一連接層間導體的著陸區,該些層間導體連接至一內連接覆蓋導體(overlying inter-connect conductor),該內連接覆蓋導體沿著半導體材料之平行線方向排列。由上方俯視,該些層間導體沿橫列方向排列且位於一被絕緣層包覆的通孔結構內,每一列皆沿著X方向排列且平行於第一側。在其他實施例中,該層間導體可沿Y方向部分偏置,其垂直於X方向。在其他實施例中,該些著陸區可形成多種階梯式排列,如第6圖與第43圖所繪示。 In many embodiments, a three-dimensional array device, such as a memory device, includes a plurality of patterned semiconductor materials, each patterned layer including a plurality of parallel lines formed of a semiconductor material, the parallel One end of the wire is connected to the first side of a semiconductor pad, and the semiconductor pads are connected to a plurality of patterned layers disposed in a stack, each of the semiconductor pads including a landing zone connecting the interlayer conductors, the interlayer conductors are connected The overlying inter-connect conductors are arranged to be aligned along the parallel lines of the semiconductor material. Viewed from above, the interlayer conductors are arranged in the course direction and are located in a via structure covered by an insulating layer, each column being aligned along the X direction and parallel to the first side. In other embodiments, the interlayer conductor may be partially offset in the Y direction, which is perpendicular to the X direction. In other embodiments, the landing zones may be formed in a plurality of stepped arrangements, as depicted in Figures 6 and 43.

綜上所述,雖然本發明已以較佳實施例揭露如上,然其並非用以限定本發明。本發明所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作各種之更動與潤飾。因此,本發明之保護範圍當視後附之申請專利範圍所界定者為準。 In conclusion, the present invention has been disclosed in the above preferred embodiments, and is not intended to limit the present invention. A person skilled in the art can make various changes and modifications without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.

200‧‧‧堆疊 200‧‧‧Stacking

202.1‧‧‧主動層 202.1‧‧‧ active layer

204.1‧‧‧絕緣層 204.1‧‧‧Insulation

202.4‧‧‧第二主動層 202.4‧‧‧Second active layer

204.3‧‧‧第三絕緣層 204.3‧‧‧The third insulation layer

252.1‧‧‧第一子堆疊 252.1‧‧‧First sub-stacking

252.2‧‧‧第二子堆疊 252.2‧‧‧Second sub-stacking

252.3‧‧‧第三子堆疊 252.3‧‧‧ Third sub-stacking

252.4‧‧‧第四子堆疊 252.4‧‧‧ Fourth sub-stacking

254‧‧‧層對 254‧‧‧ layer pairs

262‧‧‧第二層對 262‧‧‧Second layer

264‧‧‧第三層對 264‧‧‧ third layer pair

266‧‧‧第四層對 266‧‧‧Fourth pair

256、258、260‧‧‧子堆疊絕緣層 256, 258, 260‧ ‧ sub-stack insulation

268‧‧‧上絕緣層 268‧‧‧Upper insulation

270‧‧‧下絕緣層 270‧‧‧lower insulation

272‧‧‧層間導體 272‧‧‧Interlayer conductor

314‧‧‧側壁絕緣層 314‧‧‧ sidewall insulation

Claims (20)

一種階梯式接觸窗結構的形成方法,包括:形成一由複數個主動層與複數個絕緣層交替的堆疊,包括:形成包括N個主動層的一第一子堆疊,該N個主動層被該些絕緣層分開,該N個主動層包括一上邊界主動層;形成一第二子堆疊於該第一子堆疊之上,該第二子堆疊包括M個主動層,該M個主動層被該些絕緣層分開,該M個主動層包括一上邊界主動層;且形成一第一子堆疊絕緣層位於該第一子堆疊層與該第二子堆疊層之間,在一已知蝕刻步驟中該第一子堆疊絕緣層具有一不同於該第二子堆疊內的該些絕緣層的多個蝕刻時間的蝕刻時間;接通該些上邊界主動層;接續該些上邊界主動層之接通步驟,接通該第一子堆疊與該第二子堆疊的其餘該些主動層,並於該第一子堆疊與該第二子堆疊的該些主動層上產生階梯式結構的複數個著陸區(landing area);以及形成延伸至該些著陸區的複數個層間導體,該些層間導體由絕緣材料各自分開。 A method for forming a stepped contact window structure includes: forming a stack consisting of a plurality of active layers and a plurality of insulating layers, comprising: forming a first sub-stack comprising N active layers, wherein the N active layers are Separating the insulating layers, the N active layers include an upper boundary active layer; forming a second sub-stack on the first sub-stack, the second sub-stack comprising M active layers, the M active layers being Separating the insulating layers, the M active layers include an upper boundary active layer; and forming a first sub-stack insulating layer between the first sub-stack layer and the second sub-stack layer, in a known etching step The first sub-stack insulation layer has an etching time different from a plurality of etching times of the insulating layers in the second sub-stack; turning on the upper boundary active layers; and connecting the upper boundary active layers Step: turning on the first sub-stack and the remaining active layers of the second sub-stack, and generating a plurality of landing areas of the stepped structure on the active layers of the first sub-stack and the second sub-stack (landing area); and forming an extension A plurality of conductor layers between the plurality of landing zone, between the plurality of conductive layers are each separated by an insulating material. 如申請專利範圍第1項所述之形成方法,其中該堆疊形成步驟包括:形成一包括第一子堆疊、第二子堆疊、第三子堆疊及第四子堆疊的堆疊;形成一第二子堆疊絕緣層於該第二子堆疊與該第三子堆疊 之間;以及形成一第三子堆疊絕緣層於該第三子堆疊與該第四子堆疊之間。 The method of forming the method of claim 1, wherein the stacking step comprises: forming a stack comprising a first sub-stack, a second sub-stack, a third sub-stack, and a fourth sub-stack; forming a second sub- Stacking an insulating layer on the second sub-stack and the third sub-stack And forming a third sub-stack insulation layer between the third sub-stack and the fourth sub-stack. 如申請專利範圍第2項所述之形成方法,其中各該第一、第二、第三以及第四子堆疊包括相同數量的主動層。 The method of forming of claim 2, wherein each of the first, second, third, and fourth sub-stacks comprises the same number of active layers. 如申請專利範圍第3項所述之形成方法,其中該第一、第二、第三以及第四子堆疊的該些絕緣層,皆有實質上相同的厚度並以一第一絕緣材料所製成;該第一、第二以及第三子堆疊絕緣層分別由一第二絕緣材料、一第三絕緣材料以及一第四絕緣材料所製成;且該第二、第三以及第四絕緣材料中之至少兩者,為不同絕緣材料且具有不同蝕刻性質。 The method of forming the third aspect of the invention, wherein the insulating layers of the first, second, third, and fourth sub-stacks have substantially the same thickness and are made of a first insulating material. The first, second, and third sub-stack insulation layers are respectively made of a second insulating material, a third insulating material, and a fourth insulating material; and the second, third, and fourth insulating materials are formed At least two of them are different insulating materials and have different etching properties. 如申請專利範圍第3項所述之形成方法,其中:在各該第一、第二、第三以及第四子堆疊之中的該些絕緣層,在一已知蝕刻製程中有實質上相同的蝕刻時間;且在該已知蝕刻製程中,在各該第一、第二與第三子堆疊絕緣層,有不同於該第一、第二、第三以及第四子堆疊之中的該些絕緣層的蝕刻時間。 The forming method of claim 3, wherein the insulating layers in each of the first, second, third, and fourth sub-stacks are substantially the same in a known etching process. Etching time; and in the known etching process, in each of the first, second, and third sub-stack insulating layers, different from the first, second, third, and fourth sub-stacks Etching time of some insulating layers. 如申請專利範圍第5項所述之形成方法,其中在該已知蝕刻製程中,該第一和第三子堆疊絕緣層有實質上相同的蝕刻時間。 The method of forming of claim 5, wherein the first and third sub-stack insulating layers have substantially the same etching time in the known etching process. 如申請專利範圍第1項所述之形成方法,其中:該些上邊界主動層的接通步驟,包括:在一個或多個蝕刻步驟中,選擇其中一子堆疊層的該些上邊界主動層的一區域,並顯露該區域;;且其餘該些主動層的接通步驟包括: 對該些上邊界主動層被顯露的該區域進行蝕刻步驟,使被選擇的該子堆疊層的該些上邊界主動層之下的複數個主動層顯露出來;使用一材料覆蓋被顯露的該些主動層,且包括覆蓋該些上邊界主動層;以及對該材料蝕刻成孔,以使被選擇的該子堆疊層的該些主動層被顯露出來。 The method of forming the method of claim 1, wherein the step of turning on the upper boundary active layer comprises: selecting one of the upper boundary active layers of one of the sub-stack layers in one or more etching steps An area and revealing the area; and the remaining steps of the active layers include: Performing an etching step on the exposed regions of the upper boundary active layer to expose a plurality of active layers under the active layer of the upper boundary layer of the selected sub-stack layer; using a material to cover the exposed portions An active layer, comprising: covering the upper boundary active layers; and etching the material into holes such that the active layers of the selected sub-stack layer are exposed. 如申請專利範圍第7項所述之形成方法,其中:該一個或多個蝕刻步驟中,該些上邊界主動層被顯露的區域產生了一階梯式結構的該些區域;且執行被顯露的該些區域的蝕刻步驟,以產生一階梯式結構的層間導體接觸窗區域於該些主動層上。 The method of forming the method of claim 7, wherein: in the one or more etching steps, the exposed regions of the upper boundary active layer generate the regions of a stepped structure; and the execution is revealed The etching steps of the regions are performed to create a stepped structure of interlayer conductor contact window regions on the active layers. 一種接觸窗結構的形成方法,包括:形成一由複數個主動層和複數個絕緣層交替的堆疊,該堆疊包括具有上邊界主動層的複數個子堆疊,該些子堆疊具有絕緣層和多個主動層對在上邊界主動層之下,該絕緣層與該些主動層對構成多個第一層對(first layer pairs),該些第一層對在該已知蝕刻製程中有多個一致的第一子堆疊蝕刻時間,該堆疊也包括多個第二層對,該些第二層對包括多個子堆疊絕緣層,該些子堆疊絕緣層位在該些子堆疊之間,該第二層對在該已知蝕刻製程中有多個第二子堆疊蝕刻時間,其相異於該些第一子堆疊蝕刻時間;在一個或多個蝕刻步驟中,經過蝕刻,使堆疊產生複數個開口,該些開口之蝕刻深度止於該些上邊界主動層;深度蝕刻被選定的該些開口以形成多個通孔,該些通孔顯露各該子堆疊內的多個主動層;且 形成多個層間導體:在該些通孔中,該些層間導體延伸至該些主動層;且在該些開口未被進行深度蝕刻的過程中,該些層間導體延伸至該些上邊界主動層。 A method for forming a contact window structure includes: forming a stack consisting of a plurality of active layers and a plurality of insulating layers, the stack comprising a plurality of sub-stacks having an active layer of an upper boundary, the sub-stack having an insulating layer and a plurality of active layers The pair of layers below the active layer of the upper boundary, the insulating layer and the pair of active layers form a plurality of first layer pairs, the first layer pairs having a plurality of uniformities in the known etching process a first sub-stack etch time, the stack also includes a plurality of second layer pairs, the second layer pairs including a plurality of sub-stack insulating layers, the sub-stack insulating layers being located between the sub-stacks, the second layer There are a plurality of second sub-stack etch times in the known etch process, which are different from the first sub-stack etch times; in one or more etch steps, the etch is performed to cause the stack to generate a plurality of openings, Etching depths of the openings terminate at the upper boundary active layers; the openings are selected to form a plurality of vias, the vias exposing a plurality of active layers in each of the sub-stacks; Forming a plurality of interlayer conductors, wherein the interlayer conductors extend to the active layers; and the interlayer conductors extend to the upper boundary active layers during the deep etching of the openings . 如申請專利範圍第9項所述之形成方法,其中該堆疊形成步驟包括形成一包含第一子堆疊、第二子堆疊以及第三子堆疊的堆疊。 The forming method of claim 9, wherein the stack forming step comprises forming a stack comprising the first sub-stack, the second sub-stack, and the third sub-stack. 如申請專利範圍第10項所述之形成方法,其中各該第一、第二以及第三子堆疊包括了相同數量的多個第一層對。 The method of forming of claim 10, wherein each of the first, second, and third sub-stacks comprises the same number of the plurality of first layer pairs. 如申請專利範圍第10項所述之形成方法,其中該第一、第二以及第三子堆疊中的該些絕緣層,由一第一絕緣材料所製成;在該第一以及第二子堆疊之間的該子堆疊絕緣層由一第二絕緣材料所製成;且在該第二以及第三子堆疊之間的該子堆疊絕緣層由一第三絕緣材料所製成;在該第一、第二以及第三絕緣材料中至少兩種為不同材料且具有不同的蝕刻性質。 The forming method of claim 10, wherein the insulating layers in the first, second and third sub-stacks are made of a first insulating material; in the first and second sub- The sub-stack insulation layer between the stacks is made of a second insulating material; and the sub-stack insulation layer between the second and third sub-stacks is made of a third insulating material; At least two of the first, second and third insulating materials are different materials and have different etching properties. 如申請專利範圍第9項所述之形成方法,其中每一子堆疊包括至少三組第一層對。 The method of forming of claim 9, wherein each sub-stack comprises at least three sets of first layer pairs. 如申請專利範圍第9項所述之形成方法,進一步包括:形成側壁絕緣層於該些通孔中;且在該些開口未被進行深度蝕刻的過程中,形成側壁絕緣層於該些開口中。 The method of forming the method of claim 9, further comprising: forming a sidewall insulating layer in the via holes; and forming sidewall insulating layers in the openings during the deep etching of the openings . 如申請專利範圍第14項所述之形成方法,其中在該些通孔及未被進行深度蝕刻的該些開口內形成層間導 體的步驟,實質上同時進行。 The method of forming the method of claim 14, wherein the vias are formed in the vias and the openings that are not deeply etched. The steps of the body are performed substantially simultaneously. 一種階梯式接觸窗結構,包括:一由複數個主動層與複數個絕緣層交替之堆疊,該堆疊為非簡單排列;一位在該些主動層上的階梯式結構的複數個著陸區;且複數個層間導體延伸至該些著陸區,該些層間導體之間被絕緣材料分開,其中該些主動層與該些絕緣層交替之該堆疊包括:一第一子堆疊,包括N個主動層,該些主動層由多個絕緣層分開,該N個主動層包括一上邊界主動層;一第二子堆疊位於該第一子堆疊之上,該第二子堆疊包括M個主動層,該M個主動層由多個絕緣層分開,該M個主動層包括一上邊界主動層;以及一第一子堆疊絕緣層位於該第一與第二子堆疊之間,該第一子堆疊絕緣層在一已知蝕刻步驟中,有不同於該第二子堆疊中的該些絕緣層的多個蝕刻時間的一蝕刻時間。 A stepped contact window structure comprising: a stack of alternating active layers and a plurality of insulating layers, the stack being a non-simple arrangement; a plurality of landing zones of a stepped structure on the active layers; a plurality of interlayer conductors extending to the landing areas, the interlayer conductors being separated by an insulating material, wherein the stack of the active layers and the insulating layers comprises: a first sub-stack comprising N active layers The active layers are separated by a plurality of insulating layers, the N active layers including an upper boundary active layer; a second sub-stack being located above the first sub-stack, the second sub-stack comprising M active layers, the M The active layers are separated by a plurality of insulating layers, the M active layers including an upper boundary active layer; and a first sub-stack insulating layer between the first and second sub-stacks, the first sub-stack insulating layer is In a known etching step, there is an etching time different from the plurality of etching times of the insulating layers in the second sub-stack. 如申請專利範圍第16項所述之階梯式接觸窗結構,其中該堆疊包括:一第三與第四子堆疊;一第二子堆疊絕緣層位在該第二與第三子堆疊之間;一第三子堆疊絕緣層位在該第三與第四子堆疊之間;且在該第一、第二、第三與第四子堆疊中的該些絕緣層有實質上相同的厚度且由一第一絕緣材料所製成;該第一、第二與第三子堆疊絕緣層由一第二絕緣材料、一第三絕緣材料及一第四絕緣材料所製成;且 在該第一、第二、第三以及第四絕緣材料中的至少兩種為不同材料且具有不同的蝕刻性質。 The stepped contact window structure of claim 16, wherein the stack comprises: a third and fourth sub-stack; a second sub-stack insulating layer is located between the second and third sub-stacks; a third sub-stack insulating layer is positioned between the third and fourth sub-stacks; and the insulating layers in the first, second, third, and fourth sub-stacks have substantially the same thickness and a first insulating material; the first, second and third sub-stack insulating layers are made of a second insulating material, a third insulating material and a fourth insulating material; At least two of the first, second, third, and fourth insulating materials are different materials and have different etching properties. 如申請專利範圍第17項所述之階梯式接觸窗結構,其中:在該第一、第二、第三與第四子堆疊中的該些絕緣層在一已知蝕刻製程中有一實質上相同的蝕刻時間;且在該已知蝕刻製程中,各該第一、第二與第三子堆疊絕緣層,有不同於該第一、第二、第三以及第四子堆疊中的該些絕緣層的蝕刻時間。 The stepped contact window structure of claim 17, wherein the insulating layers in the first, second, third and fourth sub-stacks are substantially identical in a known etching process Etching time; and in the known etching process, each of the first, second, and third sub-stack insulating layers is different from the insulating layers in the first, second, third, and fourth sub-stacks The etching time of the layer. 如申請專利範圍第18項所述之階梯式接觸窗結構,其中該第一與第三子堆疊絕緣層在該已知蝕刻製程中的蝕刻時間實質上相同。 The stepped contact window structure of claim 18, wherein the etching time of the first and third sub-stack insulating layers in the known etching process is substantially the same. 如申請專利範圍第16項所述之階梯式接觸窗結構,其中(1)該些主動層之間的蝕刻時間不同,或(2)該些絕緣層之間的蝕刻時間不同,至少其中之一經過相同的蝕刻製程。 The stepped contact window structure according to claim 16, wherein (1) the etching time between the active layers is different, or (2) the etching time between the insulating layers is different, at least one of After the same etching process.
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US11462560B2 (en) 2020-05-27 2022-10-04 Yangtze Memory Technologies Co., Ltd. Methods for forming three-dimensional memory devices
US11557570B2 (en) 2020-05-27 2023-01-17 Yangtze Memory Technologies Co., Ltd. Methods for forming three-dimensional memory devices
US11557601B2 (en) 2020-05-27 2023-01-17 Yangtze Memory Technologies Co., Ltd. Three-dimensional memory devices
US11574922B2 (en) 2020-05-27 2023-02-07 Yangtze Memory Technologies Co., Ltd. Three-dimensional memory devices

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US11462560B2 (en) 2020-05-27 2022-10-04 Yangtze Memory Technologies Co., Ltd. Methods for forming three-dimensional memory devices
US11557570B2 (en) 2020-05-27 2023-01-17 Yangtze Memory Technologies Co., Ltd. Methods for forming three-dimensional memory devices
US11557601B2 (en) 2020-05-27 2023-01-17 Yangtze Memory Technologies Co., Ltd. Three-dimensional memory devices
US11574922B2 (en) 2020-05-27 2023-02-07 Yangtze Memory Technologies Co., Ltd. Three-dimensional memory devices
TWI793427B (en) * 2020-05-27 2023-02-21 大陸商長江存儲科技有限責任公司 Three-dimensional memory device and method for forming the same

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