TWI507208B - Nontoxic and odorless fingernail paint and hair jel - Google Patents

Nontoxic and odorless fingernail paint and hair jel Download PDF

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Publication number
TWI507208B
TWI507208B TW103101383A TW103101383A TWI507208B TW I507208 B TWI507208 B TW I507208B TW 103101383 A TW103101383 A TW 103101383A TW 103101383 A TW103101383 A TW 103101383A TW I507208 B TWI507208 B TW I507208B
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Taiwan
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odorless
toxic
nail polish
nsio
hair
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TW103101383A
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Chinese (zh)
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TW201526917A (en
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Chin I Chen
Su Chin Hou
Jian Jun Liang
Jhih Kai Yang
Bo Ming Chiou
Jia Shien Wong
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Chin I Chen
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Description

無毒無臭指甲油及髮膠Non-toxic and odorless nail polish and hair spray

本發明係屬一種化學品配方,按此配方可以製造出一種完全無毒,無臭味之指甲油及髮膠,屬於一種化妝品。The invention belongs to a chemical formula, according to which a completely non-toxic, odorless nail polish and hair gel can be produced, belonging to a cosmetic.

目前市場上普遍販售之指甲油,是以硝酸纖維素、聚合丙烯酸酯(聚壓克力)、醇酸樹脂、、等有機高分子為粘著劑;以乙酸乙酯、三氯乙烷、乙酸丁酯、乙酸戊酯、甲苯、、為溶劑,以塑化劑為亮光劑,其中的色料含有鉻酸鉛,鎘黃、、等有毒物質。而且有機溶劑會揮發成臭氣。從媒體報導,有幾位指甲彩繪工作者,死於癌症,疑似與指甲油的化學成份有關。Nail polish, which is currently widely sold on the market, is an organic polymer such as nitrocellulose, polymeric acrylate (polyacrylic acid), alkyd resin, and the like; as ethyl acetate, trichloroethane, Butyl acetate, amyl acetate, toluene, as a solvent, plasticizer as a brightener, wherein the colorant contains lead chromate, cadmium yellow, and other toxic substances. Moreover, the organic solvent will volatilize into an odor. According to media reports, several nail painting workers, who died of cancer, are suspected to be related to the chemical composition of nail polish.

指甲油一旦塗刷在指甲上,如果要去除,必須使用「去光水」,其成份類似油漆業者使用的「松香水」才能溶解,造成二次傷害。Once the nail polish is applied to the nail, if it is to be removed, it is necessary to use "Glass Water", which is similar to the "pine perfume" used by the painter to dissolve, causing secondary damage.

本發明使用矽酸鈉,分子式Na2 O.nSiO2(aq) (其中n=2,俗稱2號水玻璃)當作粘著劑,用無毒色料,例如二氧化鈦、群青粉、黃色氧化鐵、紅色氧化鐵、黑色氧化鐵、食用黃色、食用紅色、食用綠色、食用紫色、、等為顯色劑。上述顯色劑分別與水玻璃混合研磨,成為紅橙黃綠藍紫白黑、、各色指甲油。用指甲專用細毛筆塗刷在指甲上,約2分鐘自然乾燥,若顧客看到圖樣後,感覺不滿意,可以立即用溫水洗掉,若顧客滿意, 就塗上食用油,就發生硬化反應。實際試用結果可行,而且過剩的食用油提供光澤效果。反應式如下:矽酸鈉+食用油→脂肪酸鈉+二氧化矽+甘油Na2 O.nSiO2(aq) +2RCOOR’(l) +H2 O → 2RCOONa(aq) +nSiO2(s) +2R’OH(l) 但是指甲油塗在指甲,乾燥後有細微裂紋,在商品化上,算是一個缺點。The invention uses sodium citrate, the molecular formula Na 2 O. nSiO 2 (aq) (where n = 2, commonly known as No. 2 water glass) as an adhesive, using non-toxic colorants, such as titanium dioxide, ultramarine blue powder, yellow iron oxide, red iron oxide, black iron oxide, edible yellow, edible Red, edible green, edible purple, and the like are coloring agents. The above-mentioned color developing agents are mixed and ground with water glass to form red orange yellow green blue purple white black and white nail polish. Apply nails to the nails and apply them to the nails for about 2 minutes. If the customer feels dissatisfied after seeing the pattern, they can immediately wash them off with warm water. If the customer is satisfied, apply the cooking oil and the hardening reaction will occur. . The actual trial results are feasible, and the excess cooking oil provides a glossy effect. The reaction formula is as follows: sodium citrate + edible oil → sodium fatty acid + cerium oxide + glycerol Na 2 O. nSiO 2(aq) +2RCOOR' (l) +H 2 O → 2RCOONa (aq) +nSiO 2(s) +2R'OH (l) But the nail polish is applied to the nail and has fine cracks after drying, which is commercialized. , is a disadvantage.

將上述矽酸鈉改成矽酸鉀,且分子式K2 O.nSiO2(aq) 式中n,俗稱「模數」,盡量找市面上能買得到的最高的,得到n=3.5~4.0,重做上述實驗,塗在指甲上,乾燥後裂紋變成很細,很少。反應式如下:矽酸鉀+食用油→脂肪酸鉀+二氧化矽+甘油K2 O.nSiO2(aq) +2RCOOR’(l) +H2 O → 2 RCOOK(aq) +nSiO2(s) +2 R’OH(l) The above sodium citrate is changed to potassium citrate, and the molecular formula K 2 O. nSiO 2 (aq) type n, commonly known as "modulo", try to find the highest available on the market, get n = 3.5 ~ 4.0, redo the above experiment, painted on the nail, the crack becomes very fine after drying, Very few. The reaction formula is as follows: potassium citrate + edible oil → fatty acid potassium + cerium oxide + glycerol K 2 O. nSiO 2(aq) +2RCOOR' (l) +H 2 O → 2 RCOOK (aq) +nSiO 2(s) +2 R'OH (l)

將將上述矽酸鉀改成矽酸膠,其分子式H2 O.nSiO2(aq) 重做上述實驗,則裂紋完全消失。反應式如下:矽酸膠+食用油→脂肪酸+二氧化矽+甘油H2 O.nSiO2(aq) +RCOOR’(l) → RCOOH(l) +nSiO2(s) +R’OH(l) The above potassium citrate will be changed to citric acid gum, and its molecular formula H 2 O. When nSiO 2 (aq) was redoed for the above experiment, the crack completely disappeared. The reaction formula is as follows: citric acid gel + edible oil → fatty acid + cerium oxide + glycerol H 2 O. nSiO 2(aq) +RCOOR' (l) → RCOOH (l) +nSiO 2(s) +R'OH (l)

將上述實驗中,添加澎潤土,使其黏稠度提高,可以提高每次塗刷之厚度。In the above experiment, the ruthenium soil was added to increase the viscosity, and the thickness of each application was increased.

將頭髮捲在造型器材上,刷上指甲油,待其乾燥後,刷上硬化劑再取下造型器材,則髮型固定。Roll the hair on the styling equipment, brush the nail polish, and after drying it, brush the hardener and remove the styling equipment, then fix the hair.

(本發明屬化學配方,故無圖式)(The invention is a chemical formula, so there is no pattern)

將國內廠商榮祥化工公司生產之RS-30矽酸膠(為 H2 Si2 O5 ,H2 Si3 O7 ,H2 Si2 O5 ,H2 Si4 O9 之混合物,業界簡化其分子式為H2 O.nsiO2 其中n的平均值約3~4)98公克和澎潤土2公克預先研磨,再和20公克二氧化鈦(俗稱鈦白粉)混合研磨,成為白色指甲油,其他顏色指甲油支配方如下表: The RS-30 bismuth gel produced by the domestic manufacturer Rongxiang Chemical Co., Ltd. (a mixture of H 2 Si 2 O 5 , H 2 Si 3 O 7 , H 2 Si 2 O 5 , H 2 Si 4 O 9 The molecular formula is H 2 O.nsiO 2 , wherein the average value of n is about 3 to 4) 98 g and 2 g of bentonite are pre-ground, and then mixed with 20 g of titanium dioxide (commonly known as titanium dioxide) to become white nail polish, other color nails. The oil formula is as follows:

取上述各色指甲油,按照顧客選定之圖樣,在顧客的指甲上繪圖,靜置2分鐘則塗膜乾燥,(若遇到濕冷天氣,則需用吹風機吹乾)再給顧客觀賞,若顧客不滿意,可用溫水洗掉,若顧客滿意,則再讓顧客從下列食用油:沙拉油,花生油,胡麻油,橄欖油,葵花油,豬油,、、中任選一瓶,將食用油塗在指甲上,則食用油和矽酸膠慢慢發生反應,約30分鐘後,水玻璃硬化成不溶於水的二氧化矽薄膜。指甲上的圖樣遇水不溶,交易完成。顧客回去後,圖樣約可維持兩個星期。Take the above-mentioned nail polishes, draw on the customer's nails according to the pattern selected by the customer, and let the film dry after standing for 2 minutes. (If you encounter wet and cold weather, blow it with a hair dryer) and then show it to the customer. If the customer does not Satisfied, wash off with warm water, if the customer is satisfied, then let the customer choose the following cooking oil: salad oil, peanut oil, flax oil, olive oil, sunflower oil, lard, and On the nail, the edible oil and the citric acid gel react slowly, and after about 30 minutes, the water glass hardens into a water-insoluble cerium oxide film. The pattern on the nail is insoluble in water and the transaction is completed. After the customer returns, the pattern can last for about two weeks.

將頭髮用客戶指定顏色之矽酸膠濡濕,而後捲在造型器材上,待其乾燥後,刷上食用油做硬化劑使髮型固定。最後取下造型器材,頭髮呈現客戶所需之形狀及圖樣。The hair is moistened with a customer-specified color of citric acid, and then wound on a styling equipment. After it is dried, the edible oil is used as a hardening agent to fix the hair. Finally, the styling equipment is removed, and the hair presents the shape and pattern desired by the customer.

在客戶指定的皮膚上,用指甲油彩繪客戶指定的圖樣,待其乾燥後,刷上食用油做硬化劑,則皮膚上顯現客戶所需的圖樣。On the skin specified by the customer, paint the customer-designed pattern with nail polish. After drying, apply the cooking oil as a hardening agent, and the pattern required by the customer will appear on the skin.

Claims (6)

一種無毒無臭指甲油,包括:一粘著劑,由水玻璃構成;一呈色粉,由無毒礦石粉或食用色素構成;一硬化劑,由食用油構成;一增稠劑,由澎潤土構成。 A non-toxic and odorless nail polish comprising: an adhesive consisting of water glass; a coloring powder consisting of non-toxic ore powder or food coloring; a hardening agent consisting of edible oil; and a thickening agent Composition. 根據申請專利範圍第1項之一種無毒無臭指甲油,其中之粘著劑係指水玻璃,其中水玻璃係指下列三種物質之總稱:矽酸鈉水溶液:Na2 O.nSiO2(aq) ;矽酸鉀水溶液:K2 O.nSiO2(aq 、矽酸膠水溶液:H2 O.nSiO2(aq) 尤其是指H2 O.nSiO2(aq)According to claim 1, the non-toxic and odorless nail polish, wherein the adhesive refers to water glass, wherein the water glass refers to the general name of the following three substances: sodium citrate aqueous solution: Na 2 O. nSiO 2 (aq) ; potassium citrate aqueous solution: K 2 O. nSiO 2 (aq , aqueous solution of citric acid: H 2 O.nSiO 2 (aq) especially refers to H 2 O.nSiO 2 (aq) . 根據申請專利範圍第2項之一種無毒無臭指甲油,其中水玻璃,式中的n=1~10,其平均值為2~6,尤其是指3~5。 According to the second aspect of the patent application, a non-toxic and odorless nail polish, wherein the water glass, wherein n=1~10, has an average value of 2-6, especially 3~5. 根據申請專利範圍第1項之一種無毒無臭指甲油,其中之硬化劑係指食用植物油與動物油及脂肪酸。 A non-toxic and odorless nail polish according to item 1 of the patent application, wherein the hardener refers to edible vegetable oil and animal oil and fatty acid. 根據申請專利範圍第1項之一種無毒無臭指甲油,可以用做髮膠,呈現客戶所指定之頭髮之形狀及顏色。 A non-toxic and odorless nail polish according to item 1 of the patent application can be used as a hair spray to present the shape and color of the hair specified by the customer. 根據申請專利範圍第1項之一種無毒無臭指甲油,可以用做皮膚彩繪,呈現客戶所指定之皮膚之形狀及顏色。According to the non-toxic and odorless nail polish of item 1 of the patent application, it can be used as a skin painting to present the shape and color of the skin specified by the customer.
TW103101383A 2014-01-14 2014-01-14 Nontoxic and odorless fingernail paint and hair jel TWI507208B (en)

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Non-Patent Citations (2)

* Cited by examiner, † Cited by third party
Title
【www.cosdna.com/cht/cosmetic e95778615.html】 *
CosDNA, mini BOURJOIS指甲油56,2012-05-13 *

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