TWI502633B - Method for forming metal gate - Google Patents

Method for forming metal gate Download PDF

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TWI502633B
TWI502633B TW100110306A TW100110306A TWI502633B TW I502633 B TWI502633 B TW I502633B TW 100110306 A TW100110306 A TW 100110306A TW 100110306 A TW100110306 A TW 100110306A TW I502633 B TWI502633 B TW I502633B
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metal gate
forming
gate
region
replacement
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TW100110306A
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TW201239960A (en
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chun yuan Wu
Chin Cheng Chien
Chiu Hsien Yeh
Yeng Peng Wang
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United Microelectronics Corp
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形成金屬閘極之方法Method of forming a metal gate

本發明係關於一種形成金屬閘極之方法。本發明特別是關於一種使用選擇性蝕刻,在實質上不影響經摻雜之替代材料之情況下,移除未經摻雜之替代材料,以便形成實質上無底切之凹穴,然後再將實質上無底切之凹穴建構成金屬閘極之方法,其可以避免凹穴在蝕刻時,橫向侵蝕造成底切之問題。This invention relates to a method of forming a metal gate. More particularly, the present invention relates to the use of selective etching to remove undoped replacement materials without substantially affecting the doped replacement material to form substantially undercut-free pockets, and then The method of forming a metal gate substantially without the undercut recess can avoid the problem of undercut caused by lateral erosion of the recess during etching.

在半導體元件的製作過程中,常常要使用蝕刻方法來定義所需元件的位置。例如,在製造靜態隨機存取記憶體(SRAM)的過程中,需要形成一組彼此鄰接的閘極結構。一般來說,如果要形成金屬閘極結構,通常會先後使用兩次蝕刻步驟來分別定義出第一金屬與第二金屬閘極結構的位置。In the fabrication of semiconductor components, etching methods are often used to define the location of the desired components. For example, in the manufacture of static random access memory (SRAM), it is necessary to form a set of gate structures adjacent to each other. In general, if a metal gate structure is to be formed, two etching steps are typically used in succession to define the locations of the first metal and second metal gate structures, respectively.

在第一次的蝕刻過程中,通常為濕蝕刻步驟,會使用遮罩來保護不需要蝕刻的區域,來限制蝕刻劑的作用範圍。實際上,儘管有著遮罩的保護,蝕刻劑除了會向下移除標的材料之外,也會無可避免地橫向侵蝕標的材料,特別是移除遮罩邊緣的標的材料。此等橫向侵蝕的結果,在蝕刻步驟完成後會在遮罩下方形成掏空的底切結構。掏空的底切結構一來會扭曲所欲形成凹穴的形狀,同時也會損害鄰接半導體元件的性能。During the first etching process, typically a wet etching step, a mask is used to protect areas that do not require etching to limit the range of action of the etchant. In fact, despite the protection of the mask, in addition to removing the target material downwards, the etchant inevitably erodes the target material laterally, particularly the target material that removes the edge of the mask. As a result of these lateral erosions, a hollow undercut structure is formed beneath the mask after the etching step is completed. The hollow undercut structure will distort the shape of the desired recess and also impair the performance of adjacent semiconductor components.

所以需要一種解決方法,可以在移除標的材料的過程中又實質上不影響週遭的材料,而可以形成實質上無底切之完美凹穴。Therefore, there is a need for a solution that can substantially eliminate the surrounding material during the removal of the target material, and can form a perfect recess that is substantially free of undercut.

本發明於是提出一種解決方案,可以在移除標的材料的過程中又實質上不影響週遭的材料。所以本發明方法可以用來形成實質上無底切之完美凹穴,特別是用來形成金屬閘極用之凹穴。The present invention thus proposes a solution that does not substantially affect the surrounding material during the removal of the target material. Therefore, the method of the present invention can be used to form a perfect recess that is substantially free of undercut, particularly for forming a recess for a metal gate.

本發明於是提出一種形成金屬閘極之方法。首先,提供一基材。其次,在基材上整體地沉積一替代(dummy)材料。之後,選擇性地在替代材料中植入一摻質,而形成一摻質區域。接著,移除部份的替代材料,而暴露出部分的基材並形成一替代閘極。替代閘極中包含介於第一區域與第二區域間之摻質區域。再來,於暴露之基材上形成圍繞替代閘極之一層間介電層。繼續,進行一選擇性蝕刻步驟,而移除替代閘極中之第一區域,以形成第一凹穴。蝕刻步驟實質上不移除第二區域與摻質區域,使得第一凹穴不延伸至摻質區域。然後,使用第一材料組填入第一凹穴中,以形成第一金屬閘極。The present invention thus proposes a method of forming a metal gate. First, a substrate is provided. Second, a dummy material is deposited integrally on the substrate. Thereafter, a dopant is selectively implanted in the replacement material to form a dopant region. Next, a portion of the replacement material is removed, and a portion of the substrate is exposed and an alternate gate is formed. The replacement gate includes a dopant region between the first region and the second region. Further, an interlayer dielectric layer surrounding one of the replacement gates is formed on the exposed substrate. Continuing, a selective etching step is performed to remove the first region of the replacement gate to form a first recess. The etching step does not substantially remove the second region from the dopant region such that the first recess does not extend to the dopant region. A first set of materials is then used to fill the first pocket to form a first metal gate.

在本發明一實施例中,摻質可以為三族(III)元素或是碳。在本發明另一實施例中,可以使用遮罩來覆蓋替代材料之第二區域,以便進行選擇性蝕刻步驟。在本發明又一實施例中,在完成第一金屬閘極後又繼續移除替代閘極中之第二區域與摻質區域,以形成一第二凹穴,更使用第二材料組填入第二凹穴中,以便形成與第一金屬閘極鄰接之第二金屬閘極。在本發明再一實施例中,可以同時或是前後移除替代閘極中之第二區域與摻質區域。在本發明又另一實施例中,第一金屬閘極可以為PMOS與NMOS其中之一者,而第二金屬閘極為另外一者。第一金屬閘極與第二金屬閘極可以位於一靜態隨機存取記憶體中(SRAM)。In an embodiment of the invention, the dopant may be a Group III (III) element or carbon. In another embodiment of the invention, a mask may be used to cover the second region of the replacement material for the selective etching step. In still another embodiment of the present invention, after the first metal gate is completed, the second region of the replacement gate and the dopant region are further removed to form a second recess, and the second material group is further filled. The second recess is formed to form a second metal gate adjacent to the first metal gate. In still another embodiment of the present invention, the second region and the dopant region of the replacement gate may be removed simultaneously or before and after. In still another embodiment of the present invention, the first metal gate may be one of a PMOS and an NMOS, and the second metal gate is the other one. The first metal gate and the second metal gate may be located in a static random access memory (SRAM).

本發明使用選擇性蝕刻,在實質上不影響經摻雜之替代材料之情況下,移除未經摻雜之替代材料,而形成實質上無底切之凹穴。然後,實質上無底切之凹穴即適合建構成良好之金屬閘極。使用本發明方法可以避免凹穴在蝕刻時附帶的橫向侵蝕,造成遮罩邊緣的下方底切之問題。The present invention uses selective etching to remove undoped replacement material without substantially affecting the doped replacement material to form a substantially undercut cavity. Then, a recess that is substantially free of undercut is suitable for constructing a good metal gate. The use of the method of the present invention avoids the lateral erosion associated with the pockets during etching, resulting in underlying undercutting of the edges of the mask.

請參考第1-10圖,例示本發明形成金屬閘極方法之例示性步驟。首先請參考第1圖,提供一基材101。基材101通常是一種半導體材料,例如矽晶圓或絕緣層上覆矽(Silicon-On Insulator,SOI)等。其次,在基材101上整體地依序形成一介電層以及一替代(dummy)材料110。介電層包含一般介電常數介電層102及/或高介電常數介電層103,而替代材料110目前用來暫時替代將來金屬閘極(圖未示)的位置,所以屬於一種犧牲性(sacrificial)材料,例如可以為未經摻雜的矽。可以使用習知之沉積方法,來全面性地(blanket)形成具有適當厚度之替代材料110。此外,基材101中可形成有所需之摻雜井、淺溝渠隔離(STI)104等之結構,在此不多加贅述。在替代材料110與高介電常數介電層103之間尚可形成一層視情況需要之阻障/蝕刻停止層。此層的材料可為TiN、SiN...等等。此層可以增加替代材料110與高介電常數介電層103材料之間的匹配性及/或在後續步驟中移除替代材料110時作為蝕刻停止層之用。Referring to Figures 1-10, exemplary steps of a method of forming a metal gate of the present invention are illustrated. Referring first to Figure 1, a substrate 101 is provided. The substrate 101 is typically a semiconductor material such as a germanium wafer or a Silicon-On Insulator (SOI). Next, a dielectric layer and a dummy material 110 are integrally formed on the substrate 101 in this order. The dielectric layer comprises a general dielectric constant dielectric layer 102 and/or a high-k dielectric layer 103, and the replacement material 110 is currently used to temporarily replace the position of a future metal gate (not shown), so it is a sacrifice. (sacrificial) material, for example, may be undoped germanium. The alternative material 110 having a suitable thickness can be blanketed using conventional deposition methods. In addition, a structure of a desired doping well, shallow trench isolation (STI) 104, and the like may be formed in the substrate 101, and will not be further described herein. A barrier/etch stop layer as desired may also be formed between the replacement material 110 and the high-k dielectric layer 103. The material of this layer may be TiN, SiN, etc. This layer can increase the matching between the alternative material 110 and the high-k dielectric layer 103 material and/or serve as an etch stop layer when the replacement material 110 is removed in a subsequent step.

之後,請參考第2圖,選擇性地在替代材料110中植入一適當之摻質121,例如硼、鋁等三族(III)元素或是碳,而形成一摻質區域120。摻質區域120的位置較佳會預先經過規劃,而位於將來電性不同又鄰接之金屬閘極,例如PMOS與NMOS(圖未示)之邊界區域上。例如,在植入前可以先使用一光阻等之遮罩131保護其他區域,而後在暴露出之區域中植入所需要之摻質121。隨後,再移除遮罩131。Thereafter, referring to FIG. 2, a suitable dopant 121, such as a group III (III) element such as boron or aluminum, or carbon is selectively implanted in the substitute material 110 to form a dopant region 120. The position of the dopant region 120 is preferably planned in advance, and is located on a boundary region of a metal gate that is different in incoming and adjacent, such as a PMOS and an NMOS (not shown). For example, a mask 131 such as a photoresist may be used to protect other regions prior to implantation, and then the desired dopant 121 is implanted in the exposed region. Subsequently, the mask 131 is removed.

接著,請參考第3圖,移除部份的替代材料110,而暴露出部分的基材101,使得替代材料110成為島狀之替代閘極110。替代閘極110包含第一區域111、第二區域112與位於第一區域111與第二區域112間之摻質區域120,也就是說摻質區域120不與第一區域111或第二區域重疊。第一區域111與第二區域112則用以形成預定之PMOS與NMOS。淺溝渠隔離104即為第一區域111與第二區域112部份的隔離結構。摻質區域120會位於絕緣的隔離結構,如淺溝渠隔離104上。例如,可以使用另一遮罩132保護替代閘極110,而經由蝕刻步驟移除替代材料110多餘的部份。蝕刻完成時,遮罩132可以暫時先保留住。遮罩132可以包含一金屬材料或介電材料,例如氮化鈦、氮化矽或碳化矽等。Next, referring to FIG. 3, a portion of the replacement material 110 is removed, and a portion of the substrate 101 is exposed, so that the replacement material 110 becomes an island-like replacement gate 110. The replacement gate 110 includes a first region 111, a second region 112, and a dopant region 120 between the first region 111 and the second region 112, that is, the dopant region 120 does not overlap with the first region 111 or the second region. . The first region 111 and the second region 112 are used to form predetermined PMOS and NMOS. The shallow trench isolation 104 is an isolation structure of the first region 111 and the second region 112 portion. The dopant region 120 will be located on an isolated isolation structure, such as shallow trench isolation 104. For example, the alternative gate 110 can be protected with another mask 132 while the excess portion of the replacement material 110 is removed via an etching step. When the etching is completed, the mask 132 can be temporarily retained. The mask 132 may comprise a metallic material or a dielectric material such as titanium nitride, tantalum nitride or tantalum carbide.

再來,請參考第4圖,在完成替代閘極110後,可以視情況需要進行所需之源極/汲極摻雜步驟,於是在替代閘極110兩旁暴露出之基材101中形成所需之源極/汲極140。較佳者為,在替代閘極110之第一區域111與第二區域112兩旁暴露出之基材101中分別形成一組不同導電型的源極/汲極140。此時,遮罩132即會在源極/汲極摻雜步驟中保護替代閘極110,而不參與摻雜步驟。此外,視產品規格與製程需要,本實施例另可形成有所需之側壁子結構、淺摻雜區、自對準金屬矽化物及/或嵌入式磊晶層(recessed epitaxial layer)等之結構,在此亦不多加贅述。Referring again to FIG. 4, after the replacement of the gate 110, the desired source/drain doping step can be performed as needed, thus forming a substrate 101 exposed on both sides of the replacement gate 110. Source/bungee 140 required. Preferably, a plurality of source/drain electrodes 140 of different conductivity types are respectively formed in the substrate 101 exposed on both sides of the first region 111 and the second region 112 of the replacement gate 110. At this time, the mask 132 protects the replacement gate 110 in the source/drain doping step without participating in the doping step. In addition, depending on the product specifications and process requirements, the present embodiment may further form a structure of a desired sidewall substructure, a shallow doped region, a self-aligned metal germanide, and/or a recessed epitaxial layer. I will not repeat them here.

請參考第5圖,然後,初步形成層間介電層150覆蓋暴露之基材101,並同時圍繞替代閘極110。但是,層間介電層150並不會覆蓋替代閘極110。例如,可以先形成層間介電層150來完全覆蓋暴露之基材101、遮罩132與替代閘極110。然後,再進行一平坦化製程,移除部份之層間介電層150,使得遮罩132暴露出來。所以,層間介電層150與遮罩132大約具有相同之高度。或是,移除部份之層間介電層150時一併移除遮罩132,所以層間介電層150與替代閘極110大約具有相同之高度,如第6圖所示。Referring to FIG. 5, then, an interlayer dielectric layer 150 is initially formed to cover the exposed substrate 101 while surrounding the replacement gate 110. However, the interlayer dielectric layer 150 does not cover the replacement gate 110. For example, the interlayer dielectric layer 150 can be formed to completely cover the exposed substrate 101, the mask 132, and the replacement gate 110. Then, a planarization process is performed to remove a portion of the interlayer dielectric layer 150, so that the mask 132 is exposed. Therefore, the interlayer dielectric layer 150 has approximately the same height as the mask 132. Alternatively, the mask 132 is removed when a portion of the interlayer dielectric layer 150 is removed, so the interlayer dielectric layer 150 has approximately the same height as the replacement gate 110, as shown in FIG.

繼續,請參考第6圖,進行一選擇性蝕刻步驟,而移除替代閘極110中之第一區域111,以形成第一凹穴113。例如,可以先使用一蝕刻遮罩133完全覆蓋第二區域112,甚至部份之摻質區域120,但是完全暴露出第一區域111。選擇性蝕刻步驟對未經摻雜處理之區域,即第一區域111具有相對較高的蝕刻率,所以實質上不會移除受到蝕刻遮罩133保護的第二區域112與蝕刻率相對較低的摻質區域120。因此,第一凹穴113不會延伸至摻質區域120,因此沒有橫向蝕刻(lateral etching)而於蝕刻遮罩133下方產生底切的缺點。此處所指之「實質上不會移除」蝕刻率相對較低的摻質區域120係意味著,在此選擇性蝕刻步驟下,第一區域111與摻質區域120的蝕刻率比會大於至少50。此等蝕刻率比會根據蝕刻劑的不同、蝕刻溫度的不同...而有所改變。Continuing, referring to FIG. 6, a selective etching step is performed to remove the first region 111 of the replacement gate 110 to form the first recess 113. For example, an etch mask 133 may be used to completely cover the second region 112, or even a portion of the dopant region 120, but completely expose the first region 111. The selective etching step has a relatively high etch rate for the undoped region, i.e., the first region 111, so that the second region 112 protected by the etch mask 133 is not substantially removed and the etch rate is relatively low. The dopant region 120. Therefore, the first recess 113 does not extend to the dopant region 120, so there is no disadvantage of lateral etching to create undercut under the etch mask 133. The term "substantially not removing" the dopant region 120 having a relatively low etching rate as used herein means that the etching ratio of the first region 111 to the dopant region 120 is greater than at least in this selective etching step. 50. These etching rate ratios vary depending on the etchant and the etching temperature.

在本實施例中,可以使用濕蝕刻方式,例如使用鹼性蝕刻劑,來執行選擇性移除替代閘極110中之第一區域111之蝕刻步驟。適合之蝕刻劑可以是稀釋氫氟酸(DHF)搭配氨水、或是氫氧化四甲基銨溶液(tetramethylammonium hydroxide,TMAH)。例如,先使用稀釋氫氟酸(DHF),在室溫下進行預蝕刻。之後,再使用鹼性蝕刻劑,選擇性完全移除第一區域111,以形成第一凹穴113。蝕刻完成後,即可移除蝕刻遮罩133。或者是,可以使用乾蝕刻與濕蝕刻混合的方式,例如先使用乾蝕刻、再進行濕蝕刻來執行選擇性移除替代閘極110中之第一區域111之蝕刻步驟。In the present embodiment, the etching step of selectively removing the first region 111 in the replacement gate 110 may be performed using a wet etching method, for example, using an alkaline etchant. Suitable etchants can be diluted hydrofluoric acid (DHF) with ammonia or tetramethylammonium hydroxide (TMAH). For example, pre-etching is performed at room temperature using diluted hydrofluoric acid (DHF). Thereafter, the first region 111 is selectively removed completely using an alkaline etchant to form the first recess 113. After the etching is completed, the etch mask 133 can be removed. Alternatively, an etching step of selectively removing the first region 111 in the replacement gate 110 may be performed by using dry etching and wet etching, for example, using dry etching and then wet etching.

然後,請參考第7圖,使用第一材料組161填入第一凹穴113中,以形成第一金屬閘極160。若有多餘之第一材料組161會覆蓋層間介電層150時,還可以進行一平坦化製程來移除多餘之第一材料組161而暴露出層間介電層150。第一材料組161可以包含功函數閘極金屬層163與低電阻金屬164。功函數閘極金屬層163可以為單一金屬層或是複合金屬層。經由第一材料組161中功函數閘極金屬163之適當組合,即可調整第一金屬閘極160具有適當之功函數。適當之高介電常數介電層103與功函數閘極金屬材料163為本技藝人士所知。Then, referring to FIG. 7, the first material group 161 is used to fill the first cavity 113 to form the first metal gate 160. If the excess first material group 161 covers the interlayer dielectric layer 150, a planarization process may be performed to remove the excess first material group 161 to expose the interlayer dielectric layer 150. The first material group 161 may include a work function gate metal layer 163 and a low resistance metal 164. The work function gate metal layer 163 may be a single metal layer or a composite metal layer. The first metal gate 160 can be adjusted to have an appropriate work function via a suitable combination of the work function gate metal 163 in the first material group 161. Suitable high-k dielectric layers 103 and work function gate metal materials 163 are known to those skilled in the art.

在另一個實施例中,請參考第7A圖,其例示一剖視圖。在移除替代閘極110中之第一區域111之後與使用第一材料組161填入第一凹穴113之前,可以先形成U形之高介電常數介電層103。然後才形成功函數閘極金屬層163與低電阻金屬164。在此情況下,原本形成在替代材料下方的高介電常數介電層便不用形成。In another embodiment, please refer to FIG. 7A, which illustrates a cross-sectional view. A U-shaped high-k dielectric layer 103 may be formed prior to removing the first region 111 in the replacement gate 110 and before filling the first recess 113 with the first material group 161. The function gate metal layer 163 and the low resistance metal 164 are then successfully formed. In this case, the high-k dielectric layer originally formed under the replacement material is not formed.

接下來,請參考例示另一方向側視圖之第8圖,再一次進行蝕刻步驟,而移除替代閘極110中之第二區域112與摻質區域120,以形成第二凹穴115。可以使用乾蝕刻與濕蝕刻混合的方式,或者是直接使用濕蝕刻方式,例如使用鹼性蝕刻劑,在沒有遮罩之情形下來移除替代閘極110中之第二區域112與摻質區域120。適合之蝕刻劑可以是較高溫度與較高濃度(相對於第一區域111之選擇性蝕刻)之氫氧化四甲基銨溶液(tetramethylammonium hydroxide,TMAH),或是其他氫氧化四烷基銨溶液。Next, referring to FIG. 8 which illustrates the side view of the other direction, the etching step is performed again, and the second region 112 and the dopant region 120 in the replacement gate 110 are removed to form the second recess 115. The second region 112 and the dopant region 120 in the replacement gate 110 may be removed using a dry etch and wet etch, or directly using a wet etch, such as an alkaline etchant, without masking. . Suitable etchants may be tetramethylammonium hydroxide (TMAH) or other tetraalkylammonium hydroxide solution at a higher temperature and a higher concentration (selective etching with respect to the first region 111). .

然後,請參考第9圖,再使用第二材料組166填入第二凹穴115中,以形成第二金屬閘極165。若有多餘之第二材料組166會覆蓋層間介電層150時,也可以進行一平坦化製程來移除多餘之第二材料組166而暴露出層間介電層150。第二材料組166可以包含功函數閘極金屬層167與低電阻金屬168。功函數閘極金屬層167可以為單一金屬層或是複合金屬層。經由第二材料組166中功函數閘極金屬167之適當組合,即可調整第二材料組166具有適當之功函數。Then, referring to FIG. 9, the second material set 166 is used to fill the second recess 115 to form the second metal gate 165. If the excess second material set 166 covers the interlayer dielectric layer 150, a planarization process can also be performed to remove the excess second material set 166 to expose the interlayer dielectric layer 150. The second material set 166 can include a work function gate metal layer 167 and a low resistance metal 168. The work function gate metal layer 167 can be a single metal layer or a composite metal layer. The second material set 166 can be adjusted to have an appropriate work function via a suitable combination of work function gate metals 167 in the second material set 166.

如果第一金屬閘極160為PMOS與NMOS其中之一者,而第二金屬閘極165即為另外一者,相對應地,第一金屬閘極160與第二金屬閘極165兩旁的源極/汲極140則分別具有相對應的P型或N型導電性。於是第一金屬閘極160與第二金屬閘極165即可以為靜態隨機存取記憶體中(SRAM)鄰接之閘極,且第一金屬閘極160與第二金屬閘極165係直接接觸並以功函數閘極金屬彼此電連接。適當之高介電常數介電層103與功函數閘極金屬材料163/167為本技藝人士所知,例如高介電常數介電層103是選自矽酸鉿氧化合物(HfSiO)、矽酸鉿氮氧化合物(HfSiON)、氧化鉿(HfO)、氧化鑭(LaO)、鋁酸鑭(LaAlO)、氧化鋯(ZrO)、矽酸鋯氧化合物(ZrSiO)、鋯酸鉿(HfZrO)或其組合,N型功函數閘極金屬材料較佳選自氮化鈦(TiN)、碳化鉭(TaC)、氮化鉭(TaN)、氮化矽鉭(TaSiN)及鋁等所構成的群組,P型功函數閘極金屬材料較佳選自由氮化鈦(TiN)、鎢(W)、氮化鎢(WN)、鉑(Pt)、鎳(Ni)、釕(Ru)、碳氮化鉭(TaCN)或碳氮氧化鉭(TaCNO)所構成的群組。If the first metal gate 160 is one of the PMOS and the NMOS, and the second metal gate 165 is the other one, correspondingly, the source of the first metal gate 160 and the second metal gate 165 The /poles 140 have corresponding P-type or N-type conductivity, respectively. Thus, the first metal gate 160 and the second metal gate 165 may be gates adjacent to the SRAM, and the first metal gate 160 is in direct contact with the second metal gate 165. The work function gate metals are electrically connected to each other. Suitable high-k dielectric layer 103 and work function gate metal material 163/167 are known to those skilled in the art. For example, high-k dielectric layer 103 is selected from the group consisting of bismuth citrate (HfSiO) and citric acid. Niobium oxynitride (HfSiON), hafnium oxide (HfO), lanthanum oxide (LaO), lanthanum aluminate (LaAlO), zirconia (ZrO), zirconium oxynitride (ZrSiO), hafnium zirconate (HfZrO) or In combination, the N-type work function gate metal material is preferably selected from the group consisting of titanium nitride (TiN), tantalum carbide (TaC), tantalum nitride (TaN), tantalum nitride (TaSiN), and aluminum. The P-type work function gate metal material is preferably selected from the group consisting of titanium nitride (TiN), tungsten (W), tungsten nitride (WN), platinum (Pt), nickel (Ni), ruthenium (Ru), and tantalum carbonitride. (TaCN) or a group of tantalum oxynitride (TaCNO).

當第一金屬閘極160與第二金屬閘極165皆已完成後,就可以繼續形成用於電連接第一金屬閘極160與第二金屬閘極165之源極/汲極140之接觸插塞170。例如,請參考第10圖,先形成層間介電層150完全覆蓋第一金屬閘極160與第二金屬閘極165,接下來形成暴露源極/汲極140之接觸洞(圖未示)。然後,在接觸洞填入適當之導電材料,完成接觸插塞170。視情況需要,接觸插塞170與源極/汲極140之間還可以預先形成金屬矽化物(圖未示)。After the first metal gate 160 and the second metal gate 165 have been completed, the contact plugging for electrically connecting the source/drain 140 of the first metal gate 160 and the second metal gate 165 can be continued. Plug 170. For example, referring to FIG. 10, an interlayer dielectric layer 150 is formed to completely cover the first metal gate 160 and the second metal gate 165, and then a contact hole (not shown) exposing the source/drain 140 is formed. Contact plug 170 is then completed by filling the contact hole with a suitable conductive material. A metal halide (not shown) may be formed in advance between the contact plug 170 and the source/drain 140 as occasion demands.

請參考第11-17圖,例示本發明形成金屬閘極方法之另一種例示性步驟,其特點在於使用光阻界定硬遮罩之圖案與使用一低電阻金屬同時填滿原先替代材料所佔據之區域,以形成第一金屬閘極與第二金屬閘極。首先請同時參考第11圖與第12圖,第11圖中之切線A-A’展開後即呈現第12圖之剖視圖。提供一基材101。基材101通常是一種半導體材料,例如矽晶圓或絕緣層上覆矽(Silicon-On Insulator,SOI)等。基材101被層間介電層150所覆蓋。基材101中包含源極/汲極140與淺溝渠隔離104。基材101上已經形成有相鄰之替代材料110,基材101上另外還有主動區域105。替代材料110與主動區域105交會之處,即為日後金氧半導體閘極所在之處。Referring to Figures 11-17, another exemplary step of forming a metal gate of the present invention is illustrated, which is characterized by the use of a photoresist to define a pattern of a hard mask that is filled with a low-resistance metal while filling the original replacement material. a region to form a first metal gate and a second metal gate. First, please refer to Fig. 11 and Fig. 12 at the same time. The tangential line A-A' in Fig. 11 is expanded to show a cross-sectional view of Fig. 12. A substrate 101 is provided. The substrate 101 is typically a semiconductor material such as a germanium wafer or a Silicon-On Insulator (SOI). The substrate 101 is covered by an interlayer dielectric layer 150. The substrate 101 includes a source/drain 140 and a shallow trench isolation 104. An adjacent replacement material 110 has been formed on the substrate 101, and an active region 105 is additionally provided on the substrate 101. Where the alternative material 110 meets the active region 105 is where the MOS gate is located.

替代閘極1110中包含替代材料110、包含氮化矽之密封層116、側壁子117、蝕刻停止層118與視情況需要之一般介電常數介電層102或是高介電常數介電層103。替代閘極2110中亦包含有替代材料、包含氮化矽之密封層、側壁子、蝕刻停止層與視情況需要之介電層,但因簡化之故而未繪出。側壁子117可以為單一或是複合結構。The replacement gate 1110 includes an alternative material 110, a sealing layer 116 including tantalum nitride, a sidewall spacer 117, an etch stop layer 118, and a general dielectric constant dielectric layer 102 or a high-k dielectric layer 103 as occasion demands. . The replacement gate 2110 also includes an alternative material, a sealing layer comprising tantalum nitride, a sidewall spacer, an etch stop layer, and a dielectric layer as desired, but is not shown for simplicity. The side wall sub-117 can be a single or composite structure.

基材101已經預先進行過化學機械研磨,使得替代閘極1110/2110與層間介電層150之頂面同平面,同時替代閘極1110/2110部分的頂面還會暴露出來。替代材料110目前用來暫時替代將來金屬閘極(圖未示)的位置,所以屬於一種犧牲性(sacrificial)材料,例如可以為未經摻雜的矽。基材101中另外還可形成有所需之摻雜井等之結構,在此不多加贅述。The substrate 101 has been previously subjected to chemical mechanical polishing such that the replacement gate 1110/2110 is flush with the top surface of the interlayer dielectric layer 150, and the top surface of the portion of the gate 1110/2110 is exposed. The alternative material 110 is currently used to temporarily replace the location of future metal gates (not shown) and is therefore a sacrificial material, such as may be undoped germanium. A structure in which a desired doping well or the like is additionally formed in the substrate 101 will not be described herein.

在替代材料110與高介電常數介電層103之間尚可形成一層視情況需要之阻障/蝕刻停止層。此層的材料可為TiN、SiN...等等。此層可以增加替代材料110與高介電常數介電層103材料之間的匹配性及/或在後續步驟中移除替代材料110時作為蝕刻停止層之用。替代閘極1110可以為NMOS或PMOS其中一者,而替代閘極2110即為另一者。A barrier/etch stop layer as desired may also be formed between the replacement material 110 and the high-k dielectric layer 103. The material of this layer may be TiN, SiN, etc. This layer can increase the matching between the alternative material 110 and the high-k dielectric layer 103 material and/or serve as an etch stop layer when the replacement material 110 is removed in a subsequent step. The alternate gate 1110 can be one of an NMOS or a PMOS, and the alternate gate 2110 is the other.

第12A圖繪示第11圖中之切線B-B’之剖視圖。請參考第12A圖,選擇性地在替代材料110中植入一適當之摻質121,例如硼、鋁等三族(III)元素或是碳,而形成一摻質區域120。摻質區域120的位置較佳會預先經過規劃,而位於將來電性不同又鄰接之金屬閘極,例如PMOS與NMOS(圖未示)之邊界區域上,例如位於淺溝渠隔離104之上。例如,在植入前可以先使用一光阻等之遮罩(圖未示)保護其他區域,而後在暴露出之區域中植入所需要之摻質121。隨後,再移除遮罩。Fig. 12A is a cross-sectional view showing a tangent B-B' in Fig. 11. Referring to FIG. 12A, a suitable dopant 121, such as a group III (III) element such as boron or aluminum, or carbon is selectively implanted in the replacement material 110 to form a dopant region 120. The location of the dopant region 120 is preferably pre-programmed to be located on a boundary region of a metal gate that is different in incoming and adjacent, such as a PMOS and an NMOS (not shown), such as over the shallow trench isolation 104. For example, a mask such as a photoresist (not shown) may be used to protect other areas prior to implantation, and then the desired dopant 121 is implanted in the exposed area. Then, remove the mask.

之後,請參考第13圖,先在層間介電層150上全面性地沉積遮罩131,例如氮化鈦硬遮罩,再全面性地沉積氧化物134,例如二氧化矽。還要使用圖案化之光阻135來選擇性地覆蓋替代閘極1110/2110(NMOS或PMOS)其中一者。第13圖繪示圖案化之光阻135覆蓋替代閘極2110。接下來就可以使用圖案化之光阻135來圖案化遮罩131,例如使用蝕刻步驟,將光阻135之圖案轉移至遮罩131上,隨後即可移除光阻135。Thereafter, referring to FIG. 13, a mask 131, such as a titanium nitride hard mask, is deposited on the interlayer dielectric layer 150 in a comprehensive manner, and then an oxide 134 such as cerium oxide is deposited in a comprehensive manner. A patterned photoresist 135 is also used to selectively cover one of the alternate gates 1110/2110 (NMOS or PMOS). FIG. 13 illustrates the patterned photoresist 135 covering the replacement gate 2110. Next, the patterned photoresist 135 can be used to pattern the mask 131, for example, using an etching step to transfer the pattern of the photoresist 135 onto the mask 131, and then the photoresist 135 can be removed.

接著,請參考第14圖,經由遮罩131之保護,以蝕刻步驟移除暴露之替代閘極1110或2110其中一者之替代材料110。由於遮罩131的保護,祇有替代閘極1110與2110其中一者之替代材料110才會被移除。第14圖例示祇有替代閘極1110中之替代材料110被移除而形成第一凹穴113,而替代閘極2110中之替代材料110被保留。Next, referring to FIG. 14, the replacement material 110 of one of the exposed replacement gates 1110 or 2110 is removed by an etching step via the protection of the mask 131. Due to the protection of the mask 131, only the replacement material 110 of one of the alternative gates 1110 and 2110 will be removed. Figure 14 illustrates that only the replacement material 110 in the replacement gate 1110 is removed to form the first pocket 113, while the replacement material 110 in the replacement gate 2110 is retained.

第14A圖繪示第11圖中之切線B-B’之剖視圖。由於遮罩131與摻質區域120之保護,所以此次之蝕刻步驟實質上不會移除受到蝕刻遮罩131與摻質區域120保護的替代閘極2110與蝕刻率相對較低的摻質區域120。因此,第一凹穴113不會延伸至摻質區域120,因此沒有橫向蝕刻(lateral etching)而於蝕刻遮罩131下方產生底切的缺點。Fig. 14A is a cross-sectional view showing a tangent B-B' in Fig. 11. Due to the protection of the mask 131 and the dopant region 120, the etching step of this time does not substantially remove the replacement gate 2110 protected by the etch mask 131 and the dopant region 120 and the dopant region having a relatively low etching rate. 120. Therefore, the first recess 113 does not extend to the dopant region 120, so there is no disadvantage of lateral etching to create undercut under the etch mask 131.

此處所指之「實質上不會移除」蝕刻率相對較低的摻質區域120係意味著,在此選擇性蝕刻步驟下,第一區域111與摻質區域120的蝕刻率比會大於至少50。此等蝕刻率比會根據蝕刻劑的不同、蝕刻溫度的不同...而有所改變。The term "substantially not removing" the dopant region 120 having a relatively low etching rate as used herein means that the etching ratio of the first region 111 to the dopant region 120 is greater than at least in this selective etching step. 50. These etching rate ratios vary depending on the etchant and the etching temperature.

在本實施例中,可以使用濕蝕刻方式,例如使用鹼性蝕刻劑,來執行選擇性移除替代閘極1110之蝕刻步驟。適合之蝕刻劑可以是稀釋氫氟酸(DHF)搭配氨水、或是氫氧化四甲基銨溶液(tetramethylammonium hydroxide,TMAH)。例如,先使用稀釋氫氟酸(DHF),在室溫下進行預蝕刻。之後,再使用鹼性蝕刻劑,選擇性完全移除替代閘極1110,以形成第一凹穴113。或者是,可以使用乾蝕刻與濕蝕刻混合的方式,例如先使用乾蝕刻、再進行濕蝕刻來執行選擇性形成替代閘極1110中第一凹穴113之蝕刻步驟。In the present embodiment, the etching step of selectively removing the replacement gate 1110 may be performed using a wet etching method, for example, using an alkaline etchant. Suitable etchants can be diluted hydrofluoric acid (DHF) with ammonia or tetramethylammonium hydroxide (TMAH). For example, pre-etching is performed at room temperature using diluted hydrofluoric acid (DHF). Thereafter, the replacement gate 1110 is selectively removed completely using an alkaline etchant to form the first recess 113. Alternatively, an etching step of selectively forming the first recess 113 in the gate 1110 may be performed by dry etching and wet etching, for example, using dry etching and then wet etching.

再來,請參考第15圖,在蝕刻遮罩131之保護下,就可以在第一凹穴113中填入所需之第一功函數閘極金屬層163。第15A圖繪示第11圖中之切線B-B’之剖視圖。如果使用全面性地沉積方式(blank deposition),第一功函數閘極金屬層163還會覆蓋遮罩131。視情況需要,此時可以依據建立PMOS或是NMOS之計畫,填入對應之適當第一功函數閘極金屬層163。所以第一功函數閘極金屬層163可以是N型功函數閘極金屬材料,或是P型功函數閘極金屬材料,N型功函數閘極金屬材料較佳選自氮化鈦(TiN)、碳化鉭(TaC)、氮化鉭(TaN)、氮化矽鉭(TaSiN)及鋁等所構成的群組,P型功函數閘極金屬材料較佳選自由氮化鈦(TiN)、鎢(W)、氮化鎢(WN)、鉑(Pt)、鎳(Ni)、釕(Ru)、碳氮化鉭(TaCN)或碳氮氧化鉭(TaCNO)所構成的群組。Then, referring to Fig. 15, under the protection of the etching mask 131, the first work function gate metal layer 163 can be filled in the first cavity 113. Fig. 15A is a cross-sectional view showing a tangent B-B' in Fig. 11. The first work function gate metal layer 163 also covers the mask 131 if a comprehensive deposition is used. Depending on the situation, at this time, according to the plan for establishing PMOS or NMOS, the corresponding first work function gate metal layer 163 may be filled. Therefore, the first work function gate metal layer 163 may be an N-type work function gate metal material or a P-type work function gate metal material, and the N-type work function gate metal material is preferably selected from titanium nitride (TiN). a group consisting of tantalum carbide (TaC), tantalum nitride (TaN), tantalum nitride (TaSiN), and aluminum. The P-type work function gate metal material is preferably selected from titanium nitride (TiN), tungsten. (W), a group consisting of tungsten nitride (WN), platinum (Pt), nickel (Ni), ruthenium (Ru), tantalum carbonitride (TaCN) or tantalum oxynitride (TaCNO).

請參考第16圖,然後,使用另一只圖案化光阻135來覆蓋未被遮罩131所保護的部分,所以圖案化光阻135會覆蓋第一凹穴113與部份之第一功函數閘極金屬層163。第16A圖繪示第11圖中之切線B-B’之剖視圖。視情況需要,圖案化光阻135中可能包含底部抗反射層(BARC)。Referring to FIG. 16, then, another patterned photoresist 135 is used to cover the portion not protected by the mask 131, so the patterned photoresist 135 covers the first recess 113 and a portion of the first work function. Gate metal layer 163. Fig. 16A is a cross-sectional view showing a tangent B-B' in Fig. 11. A patterned anti-reflective layer (BARC) may be included in the patterned photoresist 135 as needed.

繼續,隨即利用圖案化光阻135作為遮罩,剝除暴露之第一功函數閘極金屬層163與與遮罩131。於是,另一個替代閘極(圖中例示替代閘極2110)以及其中之替代材料110便會暴露出來。隨後。圖案化光阻135便可以加以移除。Continuing, the patterned photoresist 135 is used as a mask to strip the exposed first work function gate metal layer 163 and the mask 131. Thus, another alternative gate (illustrated as an alternate gate 2110 in the figure) and the replacement material 110 therein are exposed. Subsequently. The patterned photoresist 135 can be removed.

然後,請參考第17圖,完全移除暴露出來之替代材料110與摻質區域120而形成第二凹穴115。接下來,使用第二功函數閘極金屬167層填入第二凹穴115中,同時也會順便填入第一凹穴113中。然後,再使用一低電阻金屬164同時填滿原先替代閘極1110與2110所佔據之區域,即第一凹穴113與第二凹穴115中,以分別形成第一金屬閘極160與第二金屬閘極165。Then, referring to FIG. 17, the exposed substitute material 110 and the dopant region 120 are completely removed to form the second recess 115. Next, a second work function gate metal 167 layer is used to fill the second cavity 115, and at the same time, it is also filled into the first cavity 113. Then, a low-resistance metal 164 is used to simultaneously fill the regions occupied by the original replacement gates 1110 and 2110, that is, the first recess 113 and the second recess 115, to form the first metal gate 160 and the second, respectively. Metal gate 165.

接下來,例如使用化學機械研磨法來移除多餘之第一功函數閘極金屬163、第二功函數閘極金屬層167層與低電阻金屬164後,即完成了所需之第一金屬閘極160與第二金屬閘極165。如果第一金屬閘極160為PMOS與NMOS其中之一者,則第二金屬閘極165即為另外一者,相對應地,第一金屬閘極160與第二金屬閘極165兩旁的源極/汲極140則分別具有相對應的P型或N型導電性。於是第一金屬閘極160與第二金屬閘極165即可以為靜態隨機存取記憶體中(SRAM)鄰接之閘極。Next, after removing the excess first work function gate metal 163, the second work function gate metal layer 167 layer and the low resistance metal 164, for example, using a chemical mechanical polishing method, the required first metal gate is completed. The pole 160 and the second metal gate 165. If the first metal gate 160 is one of the PMOS and the NMOS, the second metal gate 165 is the other one, and correspondingly, the source of the first metal gate 160 and the second metal gate 165 The /poles 140 have corresponding P-type or N-type conductivity, respectively. Thus, the first metal gate 160 and the second metal gate 165 can be gates adjacent to the SRAM.

適當之高介電常數介電層103與功函數閘極金屬材料163/167為本技藝人士所知,例如高介電常數介電層103是選自矽酸鉿氧化合物(HfSiO)、矽酸鉿氮氧化合物(HfSiON)、氧化鉿(HfO)、氧化鑭(LaO)、鋁酸鑭(LaAlO)、氧化鋯(ZrO)、矽酸鋯氧化合物(ZrSiO)、鋯酸鉿(HfZrO)或其組合,N型功函數閘極金屬材料較佳選自氮化鈦(TiN)、碳化鉭(TaC)、氮化鉭(TaN)、氮化矽鉭(TaSiN)及鋁等所構成的群組,P型功函數閘極金屬材料較佳選自由氮化鈦(TiN)、鎢(W)、氮化鎢(WN)、鉑(Pt)、鎳(Ni)、釕(Ru)、碳氮化鉭(TaCN)或碳氮氧化鉭(TaCNO)所構成的群組。Suitable high-k dielectric layer 103 and work function gate metal material 163/167 are known to those skilled in the art. For example, high-k dielectric layer 103 is selected from the group consisting of bismuth citrate (HfSiO) and citric acid. Niobium oxynitride (HfSiON), hafnium oxide (HfO), lanthanum oxide (LaO), lanthanum aluminate (LaAlO), zirconia (ZrO), zirconium oxynitride (ZrSiO), hafnium zirconate (HfZrO) or In combination, the N-type work function gate metal material is preferably selected from the group consisting of titanium nitride (TiN), tantalum carbide (TaC), tantalum nitride (TaN), tantalum nitride (TaSiN), and aluminum. The P-type work function gate metal material is preferably selected from the group consisting of titanium nitride (TiN), tungsten (W), tungsten nitride (WN), platinum (Pt), nickel (Ni), ruthenium (Ru), and tantalum carbonitride. (TaCN) or a group of tantalum oxynitride (TaCNO).

當第一金屬閘極160與第二金屬閘極165皆已完成後,就可以繼續形成用於電連接第一金屬閘極160與第二金屬閘極165之源極/汲極140之接觸插塞170。例如,請參考第10圖所示。After the first metal gate 160 and the second metal gate 165 have been completed, the contact plugging for electrically connecting the source/drain 140 of the first metal gate 160 and the second metal gate 165 can be continued. Plug 170. For example, please refer to Figure 10.

以上所述僅為本發明之較佳實施例,凡依本發明申請專利範圍所做之均等變化與修飾,皆應屬本發明之涵蓋範圍。The above are only the preferred embodiments of the present invention, and all changes and modifications made to the scope of the present invention should be within the scope of the present invention.

101...基材101. . . Substrate

102...一般介電常數介電層102. . . General dielectric constant dielectric layer

103...高介電常數介電層103. . . High dielectric constant dielectric layer

104...淺溝渠隔離104. . . Shallow trench isolation

105...主動區域105. . . Active area

110...替代材料110. . . Alternative material

110...替代閘極110. . . Alternative gate

1110...替代閘極1110. . . Alternative gate

2110...替代閘極2110. . . Alternative gate

111...第一區域111. . . First area

112...第二區域112. . . Second area

113...第一凹穴113. . . First pocket

115...第二凹穴115. . . Second pocket

116...密封層116. . . Sealing layer

117...側壁子117. . . Side wall

118...蝕刻停止層118. . . Etch stop layer

120...摻質區域120. . . Doping region

121...摻質121. . . Doping

131...遮罩131. . . Mask

132...遮罩132. . . Mask

133...蝕刻遮罩133. . . Etched mask

134...氧化物134. . . Oxide

135...光阻135. . . Photoresist

140...源極/汲極140. . . Source/bungee

150...層間介電層150. . . Interlayer dielectric layer

160...第一金屬閘極160. . . First metal gate

161...第一材料組161. . . First material group

163‧‧‧功函數閘極金屬層163‧‧‧Work function gate metal layer

164‧‧‧低電阻金屬164‧‧‧Low-resistance metal

165‧‧‧第二金屬閘極165‧‧‧Second metal gate

166‧‧‧第二材料組166‧‧‧Second material group

167‧‧‧功函數閘極金屬層167‧‧‧Work function gate metal layer

168‧‧‧低電阻金屬168‧‧‧Low-resistance metal

170‧‧‧接觸插塞170‧‧‧Contact plug

第1-10圖例示本發明形成金屬閘極方法之例示性步驟。1-10 illustrate exemplary steps of a method of forming a metal gate of the present invention.

第11-17圖例示本發明形成金屬閘極方法之例示性步驟。Figures 11-17 illustrate exemplary steps of a method of forming a metal gate of the present invention.

101...基材101. . . Substrate

102...一般介電常數介電層102. . . General dielectric constant dielectric layer

103...高介電常數介電層103. . . High dielectric constant dielectric layer

110...替代閘極110. . . Alternative gate

113...第一凹穴113. . . First pocket

120...摻質區域120. . . Doping region

133...蝕刻遮罩133. . . Etched mask

140...源極/汲極140. . . Source/bungee

150...層間介電層150. . . Interlayer dielectric layer

Claims (22)

一種形成金屬閘極之方法,包含:提供一基材;在該基材上整體地沉積一替代(dummy)材料;選擇性地在該替代材料中植入一摻質,而形成一摻質區域;在形成該摻質區域之後,移除部份該替代材料以暴露部分之該基材並形成一替代閘極,該替代閘極包含一第一區域、一第二區域與該摻質區域;於暴露之該基材上形成圍繞該替代閘極之一層間介電層;進行一選擇性蝕刻步驟,在實質上不移除該摻質區域與該第二區域下而移除該替代閘極中之該第一區域,以形成一第一凹穴,使得該第一凹穴實質上不延伸至該摻質區域;以及使用一第一材料組填入該第一凹穴中,以形成一第一金屬閘極。 A method of forming a metal gate, comprising: providing a substrate; depositing a dummy material integrally on the substrate; selectively implanting a dopant in the replacement material to form a dopant region After forming the dopant region, removing a portion of the replacement material to expose a portion of the substrate and forming an alternate gate, the replacement gate including a first region, a second region, and the dopant region; Forming an interlayer dielectric layer around the replacement gate on the exposed substrate; performing a selective etching step to remove the replacement gate without substantially removing the dopant region and the second region The first region is formed to form a first recess such that the first recess does not extend substantially to the dopant region; and the first recess is filled into the first recess to form a The first metal gate. 如請求項1形成金屬閘極之方法,其中該替代材料包含矽。 A method of forming a metal gate as claimed in claim 1, wherein the substitute material comprises germanium. 如請求項1形成金屬閘極之方法,其中該摻質選自由三族元素與碳所形成之群組。 A method of forming a metal gate as claimed in claim 1, wherein the dopant is selected from the group consisting of a tri-family element and carbon. 如請求項1形成金屬閘極之方法,其中使用一第一遮罩以定義該摻質區域。 A method of forming a metal gate as claimed in claim 1, wherein a first mask is used to define the dopant region. 如請求項1形成金屬閘極之方法,其中於移除部份該替代材料中,使用一第二遮罩覆蓋該替代材料,以輔助形成該替代閘極。 A method of forming a metal gate as claimed in claim 1, wherein in the removing portion of the replacement material, a second mask is used to cover the replacement material to assist in forming the replacement gate. 如請求項5形成金屬閘極之方法,其中於該移除步驟之後,更包含:進行一源極/汲極摻雜步驟,而在該替代閘極旁暴露出之該基材中形成一組源極/汲極,其中該第二遮罩在該源極/汲極摻雜步驟中覆蓋該替代閘極。 A method of forming a metal gate according to claim 5, wherein after the removing step, further comprising: performing a source/drain doping step, and forming a group in the substrate exposed by the replacement gate a source/drain, wherein the second mask covers the replacement gate in the source/drain doping step. 如請求項1形成金屬閘極之方法,其中使用一濕蝕刻進行該選擇性蝕刻步驟。 A method of forming a metal gate as claimed in claim 1, wherein the selective etching step is performed using a wet etch. 如請求項7形成金屬閘極之方法,其中該濕蝕刻使用一鹼性蝕刻劑。 A method of forming a metal gate as in claim 7, wherein the wet etching uses an alkaline etchant. 如請求項1形成金屬閘極之方法,其中該第一凹穴實質上無底切。 A method of forming a metal gate as claimed in claim 1, wherein the first recess is substantially free of undercut. 如請求項1形成金屬閘極之方法,其中該第一材料組包含一低電阻金屬與一第一功函數材料。 A method of forming a metal gate according to claim 1, wherein the first material group comprises a low resistance metal and a first work function material. 如請求項1形成金屬閘極之方法,更包含:移除該替代閘極中之該第二區域與該摻質區域,以形成一第二凹穴;以及 使用一第二材料組填入該第二凹穴中,以形成一第二金屬閘極。 The method of claim 1, wherein the method further comprises: removing the second region of the replacement gate and the dopant region to form a second recess; A second set of materials is used to fill the second recess to form a second metal gate. 如請求項11形成金屬閘極之方法,同時移除該替代閘極中之該第二區域與該摻質區域。 A method of forming a metal gate as claimed in claim 11 while removing the second region of the replacement gate from the dopant region. 如請求項11形成金屬閘極之方法,分段移除該替代閘極中之該第二區域與該摻質區域。 As claimed in claim 11, the method of forming a metal gate periodically removes the second region of the replacement gate from the dopant region. 如請求項11形成金屬閘極之方法,更包含:加厚該層間介電層以覆蓋該第一金屬閘極與該第二金屬閘極;以及形成一接觸插塞以穿過該層間介電層並電連接該基材。 The method of claim 11, wherein the method further comprises: thickening the interlayer dielectric layer to cover the first metal gate and the second metal gate; and forming a contact plug to pass through the interlayer dielectric The layers are electrically connected to the substrate. 如請求項11形成金屬閘極之方法,其中該第二材料組包含一第二高介電常數材料與一第二功函數材料。 A method of forming a metal gate according to claim 11, wherein the second material group comprises a second high dielectric constant material and a second work function material. 如請求項11形成金屬閘極之方法,其中該第一金屬閘極為一PMOS與一NMOS其中之一者,而該第二金屬閘極為另外一者。 A method of forming a metal gate according to claim 11, wherein the first metal gate is one of a PMOS and an NMOS, and the second metal gate is the other one. 如請求項16形成金屬閘極之方法,其中該第一金屬閘極與該第二金屬閘極位於一靜態隨機存取記憶體中(SRAM)。 A method of forming a metal gate according to claim 16, wherein the first metal gate and the second metal gate are in a static random access memory (SRAM). 如請求項5形成金屬閘極之方法,其中該第二遮罩包含一金屬 材料。 A method of forming a metal gate according to claim 5, wherein the second mask comprises a metal material. 如請求項1形成金屬閘極之方法,其中使用一蝕刻遮罩保護該第二區域以進行該選擇性蝕刻步驟。 A method of forming a metal gate as claimed in claim 1, wherein the second region is protected using an etch mask to perform the selective etching step. 如請求項19形成金屬閘極之方法,其中使用一光阻來圖案化一硬遮罩材料而形成該蝕刻遮罩,該硬遮罩材料包含一氮化物與一氧化物。 A method of forming a metal gate as claimed in claim 19, wherein the etch mask is formed using a photoresist to pattern a hard mask material comprising a nitride and an oxide. 如請求項11形成金屬閘極之方法,其中使用一低電阻材料同時填入該第一凹穴與該第二凹穴中,以形成該第一金屬閘極與該第二金屬閘極。 A method of forming a metal gate as claimed in claim 11, wherein a low resistance material is simultaneously filled into the first recess and the second recess to form the first metal gate and the second metal gate. 如請求項1形成金屬閘極之方法,其中該摻質區域不與該第一區域或該第二區域重疊。A method of forming a metal gate as claimed in claim 1, wherein the dopant region does not overlap the first region or the second region.
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