TWI495702B - The adhesive sheet transport means handrail - Google Patents

The adhesive sheet transport means handrail Download PDF

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Publication number
TWI495702B
TWI495702B TW098136455A TW98136455A TWI495702B TW I495702 B TWI495702 B TW I495702B TW 098136455 A TW098136455 A TW 098136455A TW 98136455 A TW98136455 A TW 98136455A TW I495702 B TWI495702 B TW I495702B
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Taiwan
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adhesive
handrail
adhesive layer
transport device
layer
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TW098136455A
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Chinese (zh)
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TW201026813A (en
Inventor
Mizuki Hasumi
Eitaro Fukutaka
Seiji Saita
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Denki Kagaku Kogyo Kk
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J133/00Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
    • C09J133/04Homopolymers or copolymers of esters
    • C09J133/06Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
    • C09J133/08Homopolymers or copolymers of acrylic acid esters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B66HOISTING; LIFTING; HAULING
    • B66BELEVATORS; ESCALATORS OR MOVING WALKWAYS
    • B66B31/00Accessories for escalators, or moving walkways, e.g. for sterilising or cleaning
    • B66B31/02Accessories for escalators, or moving walkways, e.g. for sterilising or cleaning for handrails
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J7/00Adhesives in the form of films or foils
    • C09J7/30Adhesives in the form of films or foils characterised by the adhesive composition
    • C09J7/38Pressure-sensitive adhesives [PSA]
    • C09J7/381Pressure-sensitive adhesives [PSA] based on macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C09J7/385Acrylic polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2301/00Additional features of adhesives in the form of films or foils
    • C09J2301/10Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet
    • C09J2301/12Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers
    • C09J2301/124Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape
    • C09J2301/1242Additional features of adhesives in the form of films or foils characterized by the structural features of the adhesive tape or sheet by the arrangement of layers the adhesive layer being present on both sides of the carrier, e.g. double-sided adhesive tape the opposite adhesive layers being different
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
    • C09J2433/00Presence of (meth)acrylic polymer

Description

運輸裝置之扶手黏著片Handrail adhesive sheet for transport device

本發明係有關於一種運輸裝置之扶手黏著片。更詳言之,係有關於一種作為運輸裝置之扶手及扶手之導輥之清掃用去雜物雙面黏著片使用的運輸裝置之扶手黏著片。The present invention relates to an armrest adhesive sheet for a transport device. More specifically, there is an armrest adhesive sheet for a transport device used as a cleaning double-sided adhesive sheet for a sweeping arm of an armrest and an armrest of a transport device.

被稱為電扶梯或電動走道之乘客運輸裝置之扶手,在謀求使用者之安全上,發揮了重要之作用。由於使用者觸摸,因此扶手會附著污垢或雜物,若將該污垢等置之不理則不衛生。又,在位於電扶梯內部之扶手的導輥,亦會附著污垢或雜物。因此,扶手係經常進行清掃以保持清潔。The handrails of passenger transport devices, known as escalators or electric walkways, play an important role in the safety of users. Since the user touches, the handrail adheres to dirt or debris, and if the dirt or the like is left untreated, it is unsanitary. Moreover, dirt or debris may also adhere to the guide rollers of the armrests located inside the escalator. Therefore, the armrests are often cleaned to keep them clean.

扶手,一般而言,係以橡膠皮帶或胺酯(urethane)製皮帶所形成,以使使用者觸摸亦不打滑。扶手之清掃方法,一般係使用中性洗劑或液態聚矽氧(liquid silicone)、有機溶劑(稀釋劑(thinner)、甲苯(toluene))來擦拭表面之污垢的方法。又,藉由擦拭清掃亦不脫落之頑強污垢,則使用刮刀等之器具來進行刮除。The armrests, in general, are formed by rubber belts or urethane belts so that the user does not slip when touched. The cleaning method of the handrail is generally a method of wiping the surface dirt using a neutral lotion or liquid silicone, an organic solvent (thinner, toluene). Further, by rubbing the stubborn dirt which is not removed by the wiping, the scraping is performed using an apparatus such as a scraper.

然而,在例如已附著於手之報紙油墨附著於扶手的情況下,以中性洗劑或液態聚矽氧等之擦抹清掃等係無法確實地去除。無法去除之油墨若置之不理,有時油墨則會徹底附著或浸漬於扶手。However, in the case where, for example, the newspaper ink adhered to the hand is attached to the handrail, the cleaning with a neutral lotion or liquid polyoxygen or the like cannot be reliably removed. If the ink that cannot be removed is left unattained, sometimes the ink will adhere completely or be immersed in the handrail.

又,扶手係呈無端狀,扶手在出現於上部之後,隨即進入地板下且通過驅動裝置附近,經過諸導輥而再次出現於地面。此時,有時會接觸到驅動裝置等之潤滑油等或受到潤滑油之飛濺,而使油污固化於扶手。或者,有時附著於扶手之油會觸及導輥,而固化於導輥之一部分。此種情況下,以抹布等來擦拭油污有時亦會不夠充分。再者,由於導輥之清掃係僅在運輸裝置保養時進行,因此即使以抹布等來擦拭扶手,有時馬上又會受到污染。Further, the armrest is endless, and the armrest, after appearing on the upper portion, then enters the floor and passes through the vicinity of the driving device and reappears on the ground through the guide rollers. At this time, the lubricating oil of the driving device or the like may be touched or splashed by the lubricating oil, and the oil may be solidified on the handrail. Alternatively, sometimes the oil attached to the armrest touches the guide roller and solidifies to one of the guide rollers. In this case, it is sometimes insufficient to wipe the oil with a rag or the like. Further, since the cleaning of the guide roller is performed only during the maintenance of the transport device, even if the handrail is wiped with a rag or the like, it may be contaminated immediately.

此種頑強之污垢,大多係藉由機械性刮除作業來清掃,不過扶手僅暫時變得乾淨而已,不久之後頑強之污垢便再次附著。其結果,必須定期實施既麻煩又耗時之刮除作業,而須在清掃作業耗費大量勞力。Most of this stubborn dirt is cleaned by mechanical scraping operations, but the handrails are only temporarily cleaned, and the stubborn dirt will soon adhere again. As a result, it is necessary to perform a troublesome and time-consuming scraping operation on a regular basis, and it takes a lot of labor in the cleaning operation.

又,由於會因頻繁地進行此種刮除作業造成扶手變形而損及美觀,因此必須更換扶手,導致維護費增高。Moreover, since the handrail is deformed due to frequent such scraping operations and the appearance is damaged, the handrail must be replaced, resulting in an increase in maintenance costs.

對此,業已提供一種方法,其係藉由將使用合成橡膠系黏著劑之雙面黏著帶黏著於扶手表面,再起動運輸裝置之扶手以清掃導輥(例如,參照專利文獻一、及專利文獻二)。In this regard, a method has been provided in which a double-sided adhesive tape using a synthetic rubber-based adhesive is adhered to the surface of a handrail, and the handrail of the transport device is restarted to clean the guide roller (for example, refer to Patent Document 1 and Patent Literature). two).

然而,專利文獻一、及專利文獻二之雙面膠帶,使用後在從扶手剝除雙面膠帶之際,曾經於扶手留下殘膠。再者,夏季之氣溫狀況下或在長時間黏著後予以剝除時,有時會留下殘膠。However, the double-sided tape of Patent Document 1 and Patent Document 2, after being used, removes the double-sided tape from the armrest, and has left residual glue on the handrail. In addition, when the temperature is removed in summer or after being peeled off for a long time, residual glue may be left.

此外,亦已提供一種將污垢吸附片黏貼於扶手表面之方法,該污垢吸附片係使將多孔質膜或無紡纖(spunless)不織布形成為帶狀之帶狀片浸漬於含有界面活性劑及洗淨劑之洗淨水而形成(例如,參照專利文獻三)。Further, there has been provided a method of adhering a dirt adsorbing sheet to a surface of a handrail, wherein the dirt adsorbing sheet is formed by immersing a porous film or a spunless nonwoven fabric in a strip shape in a strip-like sheet containing a surfactant and It is formed by washing water of a detergent (for example, refer to Patent Document 3).

然而,由於專利文獻三之污垢吸附片即使能吸附扶手表面之油,卻無法吸附內部之導輥之油,且亦無法除去附著於扶手或導輥之污垢或雜物、或已牢附於扶手或導輥之污垢或雜物,因此有時扶手立即又會受到污染。However, since the dirt adsorption sheet of Patent Document 3 can adsorb the oil of the inner guide roller even if it adsorbs the oil on the surface of the handrail, it is also impossible to remove the dirt or debris attached to the handrail or the guide roller, or is attached to the handrail. Or the dirt or debris of the guide roller, so sometimes the handrail is immediately contaminated.

專利文獻一:日本特開昭61-267682號公報Patent Document 1: Japanese Patent Laid-Open No. 61-267682

專利文獻二:日本特開昭62-161693號公報Patent Document 2: Japanese Patent Laid-Open No. 62-161693

專利文獻三:日本特開2006-89215號公報Patent Document 3: Japanese Patent Laid-Open Publication No. 2006-89215

本發明係以提供一種運輸裝置之扶手黏著片為目的,其可藉由黏著於運輸裝置之扶手,並移動運輸裝置之扶手,而除去扶手及導輥之污垢或雜物。The present invention is directed to providing an armrest adhesive sheet for a transport device which can remove dirt or debris from the armrest and the guide roller by adhering to the armrest of the transport device and moving the armrest of the transport device.

為了解決上述課題,本發明提供一種運輸裝置之扶手黏著片,作為運輸裝置之扶手及扶手之導輥之清掃用去雜物雙面黏著片使用,其包含:基材層;黏著層A,係積層於該基材層之一面,且黏著於運輸裝置之扶手表面;以及黏著層B,係積層於該基材層之另一面,且相對於黏著層A被賦予較小之黏著力。In order to solve the above problems, the present invention provides an armrest adhesive sheet for a transport device, which is used as a cleaning and decontamination double-sided adhesive sheet for a handrail of a transport device and a guide roller for an armrest, comprising: a base material layer; an adhesive layer A, Laminated on one side of the substrate layer and adhered to the surface of the armrest of the transport device; and the adhesive layer B is laminated on the other side of the substrate layer and is given a small adhesive force with respect to the adhesive layer A.

該運輸裝置之扶手黏著片中,較佳為該黏著層B之黏著力係0.1N/10mm以上,該黏著層A之黏著力則為10N/10mm以下。In the handrail adhesive sheet of the transport device, it is preferable that the adhesive layer B has an adhesive force of 0.1 N/10 mm or more, and the adhesive layer A has an adhesive force of 10 N/10 mm or less.

又,較佳為該黏著層A與該黏著層B係含有丙烯酸系黏著劑及/或界面活性劑。Further, it is preferable that the adhesive layer A and the adhesive layer B contain an acrylic adhesive and/or a surfactant.

此處,說明本發明之用語。本發明中,「運輸裝置(conveyer)」係意指如電扶梯或電動走道等般將乘客載置搬運於循環旋轉之帶上的帶狀搬運裝置。Here, the terminology of the present invention will be described. In the present invention, "conveyer" means a belt-shaped conveying device that carries passengers on a belt that is circulated and rotated, such as an escalator or an electric walkway.

又,「黏著力」係意指依照JIS Z0237所規定之「黏著帶/黏著片測試法」測量,於不鏽鋼(SUS)板之表面黏貼膜片後,朝180度方向剝離時之180度剝離黏著力(N/10mm)。In addition, "adhesion" means a 180-degree peeling adhesion when peeling toward a 180-degree direction after adhering a film to the surface of a stainless steel (SUS) board according to the "adhesive tape/adhesive sheet test method" prescribed in JIS Z0237. Force (N/10mm).

根據本發明,即能製得可藉由黏著於運輸裝置之扶手,並移動運輸裝置之扶手,而除去扶手及導輥之污垢、雜物的黏著片。According to the present invention, it is possible to obtain an adhesive sheet which can remove dirt and foreign matter of the handrail and the guide roller by adhering to the armrest of the transport device and moving the handrail of the transport device.

以下,針對用以實施本發明之較佳形態作說明。此外,以下所說明之實施形態係表示本發明代表性之實施形態之一例,並非藉此狹隘解釋本發明之範圍。Hereinafter, preferred embodiments for carrying out the invention will be described. In addition, the embodiment described below is an example of a representative embodiment of the present invention, and the scope of the present invention is not limited thereto.

本發明之運輸裝置之扶手黏著片,係一種黏著於運輸裝置之扶手的膜片,包含基材層1、積層於該基材層1之一面之黏著層A、以及積層於該基材層1之另一面之黏著層B(參照第一圖)。較佳為至少於黏著層A、B之一側表面,設置分隔層4。The handrail adhesive sheet of the transport device of the present invention is a film adhered to the handrail of the transport device, comprising a base material layer 1, an adhesive layer A laminated on one surface of the base material layer 1, and a laminated layer on the base material layer 1 The adhesive layer B on the other side (refer to the first figure). Preferably, at least one side surface of the adhesive layers A, B is provided with a separation layer 4.

1、基材層1, the substrate layer

基材層1,並無特別限制,係由和紙、不織布、乙烯-乙酸乙烯共聚物、乙烯-甲基丙烯酸甲酯共聚物、乙烯-丙烯酸乙酯共聚物、乙烯-二烯共聚物、乙烯-丙烯-二烯三元共聚物、乙烯-辛烯共聚物、超低密度聚乙烯、低密度聚乙烯、直鏈狀低密度聚乙烯、高密度聚乙烯、聚丙烯、乙烯-丙烯共聚物、TPO(由硬鏈段為聚丙烯或聚乙烯,軟鏈段為乙烯與丙烯之橡膠狀共聚物、或乙烯與丙烯與二烯之橡膠狀共聚物、丙烯腈-丁二烯橡膠、天然橡膠所構成之熱可塑性彈性體)、聚苯乙烯、苯乙烯-異戊二烯共聚物、苯乙烯-丁二烯共聚物、氫化苯乙烯-丁二烯共聚物、苯乙烯-乙烯‧丁烯-乙烯嵌段共聚物、乙烯-乙烯‧丁烯-乙烯嵌段共聚物、苯乙烯-乙烯‧丁烯-苯乙烯嵌段共聚物、苯乙烯-乙烯‧丙烯-苯乙烯嵌段共聚物、苯乙烯-異戊二烯-苯乙烯嵌段共聚物、苯乙烯-乙烯-丙烯共聚物、苯乙烯-異丁烯-苯乙烯共聚物、苯乙烯-異丁烯共聚物、苯乙烯-乙烯-丁烯共聚物、聚酯胺酯(polyester urethane)、聚醚胺酯(polyether urethane)、離子聚合物(ionomer)、聚氯乙烯、乙烯與丙烯與二烯之橡膠狀共聚物、乙烯與丙烯之橡膠狀共聚物、氯磺化聚乙烯(chlorosulfonated polyethylene)、丙烯酸橡膠、氯平橡膠(chloroprene rubber)、具有聚甲烯型飽和主鏈之橡膠、於主鏈具有碳與氧之橡膠、於主鏈具有不飽和碳鍵之橡膠、於主鏈具有矽與氧之橡膠、以及於主鏈具有碳與氧及氮之橡膠等所構成。該等樹脂可單獨使用一種,亦可將兩種以上予以混合使用。於基材層1,由於膜片彼此之抗結塊性(antiblocking)良好,因此以使用乙烯-乙酸乙烯共聚物、乙烯-甲基丙烯酸甲酯共聚物、乙烯-丙烯酸乙酯共聚物、乙烯-辛烯共聚物、超低密度聚乙烯、低密度聚乙烯、直鏈狀低密度聚乙烯、聚丙烯、以及TPO等較佳。The substrate layer 1 is not particularly limited, and is made of paper, non-woven fabric, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene-diene copolymer, ethylene- Propylene-diene terpolymer, ethylene-octene copolymer, ultra low density polyethylene, low density polyethylene, linear low density polyethylene, high density polyethylene, polypropylene, ethylene-propylene copolymer, TPO (The hard segment is polypropylene or polyethylene, the soft segment is a rubbery copolymer of ethylene and propylene, or the rubbery copolymer of ethylene and propylene with diene, acrylonitrile-butadiene rubber, natural rubber Thermoplastic elastomer), polystyrene, styrene-isoprene copolymer, styrene-butadiene copolymer, hydrogenated styrene-butadiene copolymer, styrene-ethylene/butene-ethylene intercalation Segment copolymer, ethylene-ethylene/butylene-ethylene block copolymer, styrene-ethylene/butylene-styrene block copolymer, styrene-ethylene, propylene-styrene block copolymer, styrene-different Pentadiene-styrene block copolymer, styrene-ethylene-propylene Copolymer, styrene-isobutylene-styrene copolymer, styrene-isobutylene copolymer, styrene-ethylene-butene copolymer, polyester urethane, polyether urethane, ion polymerization (ionomer), polyvinyl chloride, rubbery copolymer of ethylene and propylene and diene, rubbery copolymer of ethylene and propylene, chlorosulfonated polyethylene, acrylic rubber, chloroprene rubber a rubber having a polymethylene-type saturated main chain, a rubber having carbon and oxygen in a main chain, a rubber having an unsaturated carbon bond in a main chain, a rubber having bismuth and oxygen in a main chain, and carbon having a main chain It is composed of oxygen and nitrogen rubber. These resins may be used alone or in combination of two or more. In the substrate layer 1, since the films are excellent in antiblocking property, ethylene-vinyl acetate copolymer, ethylene-methyl methacrylate copolymer, ethylene-ethyl acrylate copolymer, ethylene- An octene copolymer, an ultra low density polyethylene, a low density polyethylene, a linear low density polyethylene, a polypropylene, and a TPO are preferred.

基材層1係以拉伸強度為10~50MPa,硬度(蕭耳(shore)A)為30~100較佳。The base material layer 1 has a tensile strength of 10 to 50 MPa and a hardness (shore A) of preferably 30 to 100.

基材層1,在不損及其物性之範圍內,可含有各種添加劑。添加劑之具體例而言,例如可列舉抗菌劑、著色劑、抗氧化劑、填充劑、抗結塊劑、抗靜電劑、阻燃劑、紫外線吸收劑、潤滑劑、光穩定劑等、以及顏料。The base material layer 1 may contain various additives insofar as it does not impair its physical properties. Specific examples of the additive include an antibacterial agent, a colorant, an antioxidant, a filler, an anti-caking agent, an antistatic agent, a flame retardant, an ultraviolet absorber, a lubricant, a light stabilizer, and the like, and a pigment.

基材層1之製造方法,並無特別限制,可使用公知之方法。例如,在上述樹脂系膜片之情況下,可使用熔融拌合等或各種混合裝置(一軸或二軸擠製機、輥、班布里混合機(Banbury mixer)、以及各種捏合機(kneader)等),將各樹脂成分予以混和,再藉由膨脹法、T模法、以及壓延加工法等,將該混和物予以形成。The method for producing the base material layer 1 is not particularly limited, and a known method can be used. For example, in the case of the above resin-based film, melt mixing or the like or various mixing devices (one-axis or two-axis extruder, a roller, a Banbury mixer, and various kneaders) can be used. Then, the respective resin components are mixed, and the mixture is formed by an expansion method, a T-die method, a calendering method, or the like.

基材層1之厚度,並無特別限制,較佳為設置成20~300μm,更佳為設置成30~200μm。藉由將基材層1之厚度設置成20μm以上,即可獲得充分之強度。又,藉由將基材層1之厚度設置成300μm以下,有時可形成對扶手施工作業性優異之膜片。The thickness of the base material layer 1 is not particularly limited, but is preferably 20 to 300 μm, more preferably 30 to 200 μm. By setting the thickness of the base material layer 1 to 20 μm or more, sufficient strength can be obtained. Moreover, by setting the thickness of the base material layer 1 to 300 μm or less, it is possible to form a diaphragm excellent in handrail construction workability.

2、黏著層2, adhesive layer

本發明之運輸裝置之扶手黏著片的黏著層A、B,係形成為用以使膜片密接於扶手,以及使其吸附污垢或雜物。The adhesive layers A, B of the handrail adhesive sheet of the transport device of the present invention are formed to adhere the membrane to the handrail and to adsorb dirt or debris.

其中,黏著層A係黏著於運輸裝置之扶手表面,以吸附/除去附著於扶手表面之污垢或雜物。又,黏著層B係吸附/除去附著於導輥之污垢或雜物。Among them, the adhesive layer A adheres to the surface of the handrail of the transport device to adsorb/remove dirt or debris attached to the surface of the handrail. Further, the adhesive layer B adsorbs/removes dirt or foreign matter adhering to the guide roller.

導輥側之黏著層B的黏著力,係設定成小於運輸裝置之扶手側之黏著層A的黏著力。若黏著層B之黏著力大於黏著層A之黏著力,則在將膜片黏著於運輸裝置之扶手且移動運輸裝置之扶手,以除去扶手及導輥之污垢等時,有時膜片會從扶手浮起。The adhesive force of the adhesive layer B on the guide roller side is set to be smaller than the adhesive force of the adhesive layer A on the armrest side of the transport device. If the adhesive force of the adhesive layer B is greater than the adhesive force of the adhesive layer A, sometimes the film will be removed from the handrail of the transport device and the handrail of the transport device to remove the dirt of the handrail and the guide roller. The armrests floated.

黏著層A之黏著力,較佳為設置成10N/10mm以下,更佳為設置成2~5N/10mm。又,黏著層B之接著力,較佳為設置成0.1N/10mm以上,更佳為設置成0.3~1N/10mm。若黏著層A之黏著力大於10N/10mm,則在剝離膜片時,有時會在扶手留下殘膠。又,若黏著層B之黏著力小於0.1N/10mm,有時則無法吸附雜物等。The adhesive force of the adhesive layer A is preferably set to 10 N/10 mm or less, more preferably 2 to 5 N/10 mm. Further, the adhesive force of the adhesive layer B is preferably set to 0.1 N/10 mm or more, and more preferably set to 0.3 to 1 N/10 mm. If the adhesion of the adhesive layer A is greater than 10 N/10 mm, the residual glue may be left on the handrail when the film is peeled off. Further, when the adhesive force of the adhesive layer B is less than 0.1 N/10 mm, it is sometimes impossible to adsorb foreign matter or the like.

黏著層A、B,只要可使運輸裝置之扶手黏著片密接於扶手,且可使其吸附雜物等即可,則無特別限制,例如可為含有橡膠系黏著劑、丙烯酸系黏著劑、丁基系黏著劑等者。其中,丙烯酸系黏著劑係黏著性及再剝離性之設計容易。又,於黏著層A、B,視需要亦可摻合賦黏劑、抗老化劑、以及硬化劑等各種添加劑。The adhesive layers A and B are not particularly limited as long as the hand-held adhesive sheet of the transport device can be adhered to the handrail, and the foreign matter can be adsorbed, for example, a rubber-based adhesive, an acrylic adhesive, or a D-containing adhesive can be used. Base adhesives, etc. Among them, the acrylic adhesive is easy to be designed for adhesion and removability. Further, various additives such as an adhesive, an anti-aging agent, and a curing agent may be blended in the adhesive layers A and B as needed.

丙烯酸系黏著劑之具體例而言,可列舉(甲基)丙烯酸酯之均聚物或與共聚性單體之共聚物。(甲基)丙烯酸酯之具體例而言,可列舉甲酯(methyl ester)、乙酯(ethyl ester)、丁酯(butyl ester)、2-乙基己酯(2-ethylhexyl ester)、及辛酯(octyl ester)等之(甲基)丙烯酸烷基酯(methacrylic acid alkyl ester)、甲基丙烯酸二甲胺乙酯(dimethylaminoethyl methacrylate)、及甲基丙烯酸第三丁胺乙酯(t-butylaminoethyl methacrylate)等之(甲基)丙烯酸烷基胺基烷基酯(methacrylicacid alkyl amino alkylester)、(甲基)丙烯酸縮水甘油酯(methacrylic acid glycidylester)、(甲基)丙烯酸酯(methacrylic acid)、亞甲基丁二酸(itaconic acid)、順丁烯二酸酐(maleicanhydride)、(甲基)丙烯酸醯胺酯(amide methacrylate)以及(甲基)丙烯酸N-羥醯胺酯(N-hydroxyamide methacrylate)等。共聚性單體之具體例而言,可列舉乙酸乙烯(vinyl acetate)、苯乙烯、以及丙烯腈(acrylonitrile)等。Specific examples of the acrylic pressure-sensitive adhesive include a homopolymer of (meth) acrylate or a copolymer with a copolymerizable monomer. Specific examples of the (meth) acrylate include methyl ester, ethyl ester, butyl ester, 2-ethylhexyl ester, and octane. Methacrylic acid alkyl ester, dimethylaminoethyl methacrylate, and t-butylaminoethyl methacrylate Methacrylic acid alkyl amino alkylester, methacrylic acid glycidylester, methacrylic acid, methylene Itaconic acid, maleicanhydride, amide methacrylate, and N-hydroxyamide methacrylate. Specific examples of the copolymerizable monomer include vinyl acetate, styrene, and acrylonitrile.

此等之中,黏著層A所使用之黏著劑A,主單體係2-乙基己酯(2-ethylhexylester),其聚合物之玻璃轉移溫度係-70~-30℃,再者以分子量為五十萬以上,較佳為一百萬以上之乳化系黏著劑較佳。另一方面,黏著層B所使用之黏著劑B,主單體係丁酯(butylester),其聚合物之玻璃轉移溫度係-50~-10℃,再者以使分子量為五十萬以上,較佳為一百萬以上之乳化系黏著劑與硬化劑反應、交聯的黏著劑較佳。Among them, the adhesive A used in the adhesive layer A, the main single system 2-ethylhexylester, the glass transition temperature of the polymer is -70 to -30 ° C, and the molecular weight is further More than 500,000, preferably more than one million, of an emulsified adhesive is preferred. On the other hand, the adhesive B used in the adhesive layer B, the main single system butylester, the glass transition temperature of the polymer is -50 to -10 ° C, and the molecular weight is more than 500,000. Preferably, an adhesive having more than one million emulsifying adhesives and a curing agent is crosslinked.

賦黏劑可考量軟化點、及與各成分之相溶性等再予以選擇,例如可列舉萜烯樹脂(terpene resin)、松香樹脂(rosin resin)、氫化松香樹脂(hydrogenated rosin resin)、苯并呋喃-茚樹脂(coumarone-indene resin)、苯乙烯系樹脂、脂肪族系石油樹脂、脂環族系石油樹脂、萜烯-酚樹脂(terpene-phenol resin)、茬系樹脂(xylene resin)、其他脂肪族烴樹脂或芳香族烴樹脂等。賦黏劑之軟化點較佳為65~130℃,更佳為軟化點為65~130℃之石油樹脂的脂環族飽和烴樹脂、軟化點為80~130℃之聚萜烯樹脂(polyterpene resin)、以及軟化點為80~130℃之氫化松香的甘油酯(glycerin ester)等。The tackifier can be selected in consideration of the softening point and the compatibility with each component, and examples thereof include terpene resin, rosin resin, hydrogenated rosin resin, and benzofuran. - coumarone-indene resin, styrene resin, aliphatic petroleum resin, alicyclic petroleum resin, terpene-phenol resin, xylene resin, other fat A hydrocarbon resin, an aromatic hydrocarbon resin or the like. The softening point of the tackifier is preferably 65 to 130 ° C, more preferably an alicyclic saturated hydrocarbon resin of a petroleum resin having a softening point of 65 to 130 ° C, and a polyterpene resin having a softening point of 80 to 130 ° C. And a glycerin ester of a hydrogenated rosin having a softening point of 80 to 130 °C.

硬化劑例如可列舉異氰酸酯(isocyanate)系硬化劑、環氧(epoxy)系硬化劑、以及胺(amine)系硬化劑等。此等可單獨使用,亦可將兩種以上予以混合使用。Examples of the curing agent include an isocyanate-based curing agent, an epoxy-based curing agent, and an amine-based curing agent. These may be used singly or in combination of two or more.

異氰酸酯(isocyanate)系硬化劑之具體例而言,可列舉2,4-甲苯二異氰酸酯(2,4-tolylene diisocyanate)、2,6-二異氰酸甲苯酯(2,6-tolylene diisocyanate)、1,3-苯二甲基二異氰酸酯(1,3-xylylene diisocyanate)、1,4-苯二甲基二異氰酸酯(1,4-xylylene diis ocyanate)、二苯甲烷-4,4’-二異氰酸酯(diphenylmethane-4,4’-diisocyanate)、二苯甲烷-2,4’-二異氰酸酯(diphenylmethane-2,4’-diisocyanate)、3-甲二苯甲烷二異氰酸酯(3-methyldiphenylmethane diisocyanate)、六亞甲二異氰酸酯(hexamethylene diisocyanate)、異佛酮二異氰酸酯(isophorone diisocyanate)、二環己基甲烷-4,4’-二異氰酸酯(dicyclohexylmethane-4,4’-diisocyanate)、二環己基甲烷-2,4’-二異氰酸酯(dicycl ohexylmethane-2,4’-diisocyanate)、以及離胺酸異氰酸酯(lysine isocyanate)等多價異氰酸酯化合物。Specific examples of the isocyanate-based curing agent include 2,4-tolylene diisocyanate and 2,6-tolylene diisocyanate. 1,3-xylylene diisocyanate, 1,4-xylylene diis ocyanate, diphenylmethane-4,4'-diisocyanate (diphenylmethane-4,4'-diisocyanate), diphenylmethane-2,4'-diisocyanate, 3-methyldiphenylmethane diisocyanate, Liuya Hexaethylene diisocyanate, isophorone diisocyanate, dicyclohexylmethane-4,4'-diisocyanate, dicyclohexylmethane-2,4' a divalent ohexylmethane-2, 4'-diisocyanate, and a polyvalent isocyanate compound such as lysine isocyanate.

將黏著層A、B形成於基材層1上之方法,並無特別限制,例如可列舉將由黏著劑、賦黏劑及抗老化劑等所構成之黏著劑溶液塗佈於基材層1之一面,再予以乾燥的方法、或將黏著劑溶液預先塗佈於分隔件之一面,再預先予以乾燥,然後與基材層1貼合的方法等。The method of forming the adhesive layers A and B on the base material layer 1 is not particularly limited, and for example, an adhesive solution composed of an adhesive, an adhesive, an anti-aging agent, or the like is applied to the base material layer 1 . On the one hand, a method of drying, or a method in which an adhesive solution is applied to one surface of a separator in advance, and then dried, and then bonded to the substrate layer 1 is used.

黏著層A、B之厚度,可在不損及黏著性及處理性之範圍內,予以適當設定,不過以設定成5~100μm,更佳為設定成10~40μm。The thickness of the adhesive layers A and B can be appropriately set within a range that does not impair adhesion and handleability, but is set to 5 to 100 μm, more preferably 10 to 40 μm.

可添加於黏著層A、B之界面活性劑,並無特別限制,可使用一般之陰離子型界面活性劑、陽離子型界面活性劑、非離子型界面活性劑、兩性界面活性劑、高分子界面活性劑、氰系界面活性劑、以及反應性界面活性劑等各種界面活性劑。此等界面活性劑不僅可單獨,亦可將複數種予以併用。The surfactant which can be added to the adhesive layers A and B is not particularly limited, and a general anionic surfactant, a cationic surfactant, a nonionic surfactant, an amphoteric surfactant, and a polymer interface activity can be used. Various surfactants such as a surfactant, a cyanide surfactant, and a reactive surfactant. These surfactants may be used alone or in combination of plural kinds.

此等界面活性劑之中,較佳為不會與乳化黏著劑引起酸鹼反應(acid-base reaction)之陰離子型界面活性劑、以及非離子型界面活性劑。陽離子型界面活性劑,由於有可能使設備之金屬部分腐蝕,因此並不佳。陰離子型界面活性劑而言,係有脂肪酸型、烷基苯型、硫酸酯型、以及高級醇型等,例如有高級脂肪酸鈉、烷磺酸鈉、烷苯磺酸鈉、以及烷二苯醚二磺酸鈉等。Among these surfactants, an anionic surfactant which does not cause an acid-base reaction with an emulsified adhesive, and a nonionic surfactant are preferable. Cationic surfactants are not preferred because they may corrode metal parts of the equipment. The anionic surfactant is a fatty acid type, an alkylbenzene type, a sulfate type, and a higher alcohol type, and the like, for example, a higher fatty acid sodium, a sodium alkane sulfonate, a sodium alkylbenzene sulfonate, and an alkyl diphenyl ether. Sodium disulfonate and the like.

又,在黏著劑溶液係以高溫乾燥之情況下、或黏著片使用環境係高溫之情況下,較佳係使用在高溫不易分解之非離子型界面活性劑。非離子型界面活性劑而言,係有聚氧乙烯烷基醚(polyoxyethylene alkyl ether)、聚氧乙烯十四基醚(polyoxyethylene myristyl ether)、聚氧乙烯伸烷基烷基醚(polyoxyethylene alkylene alkyl ether)、聚氧乙烯(polyoxylethylene)衍生物、聚氧乙烯聚氧丙烯(polyoxyethylenepolyoxypropylene)嵌段聚合物、去水山梨醇脂肪酸酯(sorbitan fatty acid ester)、聚氧乙烯去水山梨醇脂肪酸酯(polyoxyethylene sorbitan fatty acid ester)、聚氧乙烯山梨糖醇脂肪酸酯(polyoxyethylene sorbitol fatty acid ester)、脂肪酸甘油酯(glycerin fatty acid ester)、聚氧乙烯脂肪酸酯(polyoxyethylene fattyacid ester)、聚氧乙烯油酸酯(polyoxyethylene oleic acid ester)、聚氧乙烯烷基胺(polyoxyethylene alkylamine)、烷基烷醇醯胺(alkyl alkanol amide)、以及聚氧乙烯壬基苯基醚(polyoxyethylene nonyl phenylether)等。Further, in the case where the adhesive solution is dried at a high temperature or when the adhesive sheet is used in a high temperature environment, it is preferred to use a nonionic surfactant which is not easily decomposed at a high temperature. The nonionic surfactant is a polyoxyethylene alkyl ether, a polyoxyethylene myristyl ether, or a polyoxyethylene alkylene alkyl ether. ), polyoxylethylene derivative, polyoxyethylene polyoxypropylene block polymer, sorbitan fatty acid ester, polyoxyethylene sorbitan fatty acid ester ( Polyoxyethylene sorbitan fatty acid ester, polyoxyethylene sorbitol fatty acid ester, glycerin fatty acid ester, polyoxyethylene fatty acid ester, polyoxyethylene oil Polyoxyethylene oleic acid ester, polyoxyethylene alkylamine, alkyl alkanol amide, and polyoxyethylene nonyl phenylether.

界面活性劑之添加量,相對於上述黏著劑100質量百分率,係0.1~20質量百分率,較佳為0.5~10質量百分率。若界面活性劑之添加量未滿0.1質量百分率時,對附著於扶手及導輥之污垢等,有時無法獲得充分之洗淨效果。另一方面,若界面活性劑之添加量超過20質量百分率,則會對黏著劑賦予可塑化效果,而在剝離膜片之際,有時會在扶手表面留下殘膠。The amount of the surfactant added is 0.1 to 20% by mass, preferably 0.5 to 10% by mass, based on 100% by mass of the above-mentioned adhesive. When the amount of the surfactant added is less than 0.1% by mass, a sufficient cleaning effect may not be obtained for the dirt adhering to the handrail or the guide roller. On the other hand, when the amount of the surfactant added exceeds 20% by mass, the adhesive can be imparted with a plasticizing effect, and when the film is peeled off, the residual glue may be left on the surface of the handrail.

3、運輸裝置之扶手黏著片的使用方法3. How to use the handrail adhesive sheet of the transport device

將本發明之運輸裝置之扶手黏著片黏著於運輸裝置之扶手的方法,並無特別限制,例如可藉由一邊剝離設於黏著層A表面之分隔層4,一邊以橡膠滾輪、擠壓輥等使用於用以壓著扶手之簡易黏貼治具等來黏著。又,黏著片係在使用前剝離設於黏著層B表面之分隔層4然後使用。The method of adhering the armrest adhesive sheet of the transport device of the present invention to the armrest of the transport device is not particularly limited. For example, the rubber layer, the squeeze roller, etc. can be removed by peeling off the partition layer 4 provided on the surface of the adhesive layer A. It is used for sticking with a simple adhesive jig for pressing the armrest. Further, the adhesive sheet is peeled off from the separator layer 4 provided on the surface of the adhesive layer B before use, and then used.

其次,說明對扶手完成膜片黏著後之清掃步驟。膜片之扶手黏著寬度及長度,雖亦取決於扶手之大小,不過以可覆蓋扶手表面之程度,較佳為60~150mm左右,且長度較佳為20~40m,較短時則為1~5m。將此種寬度及長度之膜片黏著於扶手表面後,使運輸裝置起動以使膜片黏著部分轉動二至五周,然後在膜片非停留在運輸裝置內部之位置使其停止。若在膜片停留在運輸裝置內部之狀態下再起動運輸裝置,則有膜片會在運輸裝置內部剝落之虞,而有導致運輸裝置產生異常之虞。上述步驟後,即從扶手表面剝離膜片而完成清掃。以一次上述步驟尚無法完全除去雜物時,則重複進行二至三次上述步驟。Next, the cleaning step after the handrail completes the adhesion of the film will be described. The width and length of the armrest of the diaphragm are also determined by the size of the armrest, but it is preferably about 60 to 150 mm, and the length is preferably 20 to 40 m, and the length is 1 to 1 in the case of covering the surface of the armrest. 5m. After the film of this width and length is adhered to the surface of the handrail, the transport device is activated to rotate the adhesive portion of the film for two to five weeks, and then stopped at a position where the film does not stay inside the transport device. If the transport device is restarted while the diaphragm stays inside the transport device, there is a flaw in the diaphragm which may peel off inside the transport device, which may cause an abnormality in the transport device. After the above steps, the film is peeled off from the surface of the armrest to complete the cleaning. When the impurities are not completely removed in one of the above steps, the above steps are repeated two to three times.

【實施例】[Examples]

<實施例1><Example 1>

藉由以下步驟(a)~(c)製作本發明之運輸裝置之扶手黏著片,並針對「黏著力」、「殘膠」、「浮起」、及「雜物吸附性」之各特性進行評估。The handrail adhesive sheet of the transport device of the present invention is produced by the following steps (a) to (c), and the characteristics of "adhesion force", "residual glue", "floating", and "waste adsorption property" are performed. Evaluation.

(a)使用具有螺桿徑為100mm之層合設備的單軸T模擠製機,將屬芳香族乙烯彈性體樹脂之苯乙烯-丁二烯隨機共聚物之全氫添加物(旭化成CHEMICALS公司製、S.O.E SS9000:苯乙烯含量為70wt%、氫化率為100%)100質量百分率,形成厚度為80μm之基材層1。(a) A uniaxial T-die extruder having a laminating apparatus having a screw diameter of 100 mm, and a hydrogen-rich additive of a styrene-butadiene random copolymer of an aromatic vinyl elastomer resin (Asahi Kasei Chemical Co., Ltd. SOE SS9000: a styrene content of 70% by weight and a hydrogenation rate of 100% by weight of 100% by mass to form a substrate layer 1 having a thickness of 80 μm.

(b)於基材層1之一面,以使黏著層A預先乾燥後之厚度成為20μm的方式,塗佈丙烯酸水系黏著劑(日本觸媒公司製:SKE-4851、主成分:2-乙基己酯(2-ethylhexyl ester)、玻璃轉移溫度為-30℃)及環氧系交聯劑(三菱瓦斯化學公司製:TETRAD-C),再貼合乾燥後之紙分隔件110μm(住化加工紙公司製、SL-80KCD7)。(b) An acrylic water-based adhesive (SKE-4851, main component: 2-ethyl group) was applied to one surface of the base material layer 1 so that the thickness of the adhesive layer A was 20 μm before drying. 2-ethylhexyl ester, glass transition temperature: -30 ° C) and epoxy-based cross-linking agent (TETRAD-C, manufactured by Mitsubishi Gas Chemical Co., Ltd.), and then attached to a dried paper separator of 110 μm (living processing) Paper company, SL-80KCD7).

(c)於貼合有黏著層A之基材層1的反面,以使黏著層B預先乾燥後之厚度成為20μm的方式,塗佈丙烯酸水系黏著劑(E-TEC公司製:N-730A、主成分:丁酯(butyl ester)、玻璃轉移溫度為-50℃)及環氧系交聯劑(三菱瓦斯化學公司製:TETRAD-C),再貼合乾燥後之紙分隔件110μm(住化加工紙公司製、SL-80KCD7),而製得運輸裝置之扶手黏著片。(c) Applying an acrylic water-based adhesive (N-730A, manufactured by E-TEC Co., Ltd.) to the reverse side of the base material layer 1 to which the adhesive layer A is bonded, so that the thickness of the adhesive layer B is 20 μm in advance. Main component: butyl ester, glass transition temperature -50 ° C) and epoxy crosslinking agent (TETRAD-C, manufactured by Mitsubishi Gas Chemical Co., Ltd.), and then laminated with a paper separator of 110 μm after drying (living Process paper company, SL-80KCD7), and made the handrail adhesive sheet of the transport device.

(1)黏著力之測量(1) Measurement of adhesion

依照JIS Z0237所規定之「黏著帶/黏著片測試法」,測量黏著層A,B之黏著力(180度剝離黏著力)。The adhesion of the adhesive layers A and B (180 degree peeling adhesion force) was measured in accordance with the "adhesive tape/adhesive sheet test method" prescribed in JIS Z0237.

(2)殘膠之評估(2) Evaluation of residual glue

在23±2℃、65±5%RH之條件下,將厚度為1mm之氯磺化橡膠片透過雙面膠帶黏著於SUS板以作為被黏體,於該氯磺化橡膠片黏著寬度為25mm、長度為100mm之膜片的黏著層A。黏著係藉由以重量為2kg之橡膠滾輪使其於膜片上來回一次來進行。在黏著後經過20分鐘後,藉由以膜片之黏著面積之2500mm2 為100%之殘膠部分的面積率,來評估(目視評估)使膜片之一端朝180度方向以速度為300mm/分從被黏體剝離時殘留於被黏體之殘膠。Under the condition of 23±2°C and 65±5% RH, a chlorosulfonated rubber sheet having a thickness of 1 mm was adhered to the SUS plate through a double-sided tape as an adherend, and the adhesion of the chlorosulfonated rubber sheet was 25 mm. Adhesive layer A of a film having a length of 100 mm. Adhesion was carried out by pulling back and forth on the membrane with a rubber roller weighing 2 kg. After 20 minutes after the adhesion, it was evaluated (visual evaluation) by taking the area ratio of the residue portion of the adhesive sheet of 2500 mm 2 to 100%, and the end of the film was oriented at 180 degrees at a speed of 300 mm/ Residue remaining in the adherend when peeling off from the adherend.

(3)浮起之評估(3) Evaluation of floating

在23±2℃、65±5%RH之條件下,將厚度為1mm之氯磺化橡膠片透過雙面膠帶黏著於SUS板以作為被黏體,於該氯磺化橡膠片黏著25mm寬之膜片的黏著層A。此外,於反面之黏著層B亦黏著厚度為1mm之氯磺化橡膠片。黏著係藉由以重量為2kg之橡膠滾輪使其於黏著於黏著層B之氯磺化橡膠片上來回一次來進行。在黏著後經過20分鐘後,以下述評估基準評估使黏著於黏著層B之氯磺化橡膠片之一端朝180度方向以速度為300mm/分從黏著層B剝離時之剝離位置。Under the condition of 23±2°C and 65±5% RH, a chlorosulfonated rubber sheet having a thickness of 1 mm was adhered to the SUS plate through a double-sided tape to be an adherend, and the chlorosulfonated rubber sheet was adhered to a width of 25 mm. Adhesive layer A of the diaphragm. Further, a chlorosulfonated rubber sheet having a thickness of 1 mm was adhered to the adhesive layer B on the reverse side. The adhesion was carried out by rubbing it back and forth on the chlorosulfonated rubber sheet adhered to the adhesive layer B by a rubber roller having a weight of 2 kg. After the lapse of 20 minutes after the adhesion, the peeling position at which one end of the chlorosulfonated rubber sheet adhered to the adhesive layer B was peeled off from the adhesive layer B at a speed of 300 mm/min was evaluated on the basis of the following evaluation criteria.

「良」:剝離位置係黏著於黏著層B之氯磺化橡膠片與黏著層B之界面的情況者。"Good": The peeling position is adhered to the interface between the chlorosulfonated rubber sheet of the adhesive layer B and the adhesive layer B.

「不良」:剝離位置係黏著於黏著層A之氯磺化橡膠片與黏著層A之界面的情況者。"Poor": The peeling position is adhered to the interface between the chlorosulfonated rubber sheet of the adhesive layer A and the adhesive layer A.

(4)雜物吸附性之評估(4) Evaluation of adsorption of impurities

於膜片之黏著層B之上,置放厚度為150μm之纖維素系纖維不織布,從該不織布之上,以重量為2kg之橡膠滾輪使其來回二十次。於二十次來回中,以目視判定纖維素系纖維不織布從黏著片之黏著層B浮起的狀態,再以下述評估基準評估。On the adhesive layer B of the film, a cellulose-based fiber nonwoven fabric having a thickness of 150 μm was placed, and from the nonwoven fabric, a rubber roller having a weight of 2 kg was used to make it 20 times. The state in which the cellulose-based fiber nonwoven fabric floated from the adhesive layer B of the adhesive sheet was visually judged in twenty round trips, and evaluated based on the following evaluation criteria.

「良」:纖維素系纖維不織布不浮起者。"Good": Cellulose fiber non-woven fabric does not float.

「不良」:纖維素系纖維不織布浮起者。"Poor": Cellulose fiber is not woven.

將所製作之運輸裝置之扶手黏著片的評估結果表示於「表一」。所有特性值均評估為良好,製得目標之膜片。The evaluation result of the handrail adhesive sheet of the manufactured transport device is shown in "Table 1". All characteristic values were evaluated as good, and the target membrane was produced.

<實施例2/3><Example 2/3>

除了變更黏著層A及黏著層B之黏著力以外,係設置成與實施例1同樣之構成。所有特性值均評估為良好,製得目標之膜片。The configuration was the same as that of the first embodiment except that the adhesion of the adhesive layer A and the adhesive layer B was changed. All characteristic values were evaluated as good, and the target membrane was produced.

<實施例4><Example 4>

除了使用乙烯-乙酸乙烯共聚物膜片(林一二公司製、E003:乙酸乙烯含量為17wt%)作為基材層1,且塗佈丙烯酸水系黏著劑(昭和高分子公司製:SE-4500、主成分:丁酯(butyl ester)、玻璃轉移溫度為-25℃)及環氧系交聯劑(三菱瓦斯化學公司製:TETRAD-C)作為黏著層B以外,係以與實施例1同樣之步驟製作膜片。黏著層A之黏著力係設置成1N/10mm,黏著層B之黏著力則設置成0.3N/10mm。所有特性值均評估為良好,製得目標之膜片。An ethylene-vinyl acetate copolymer film (manufactured by Lin Yi Er Co., Ltd., E003: vinyl acetate content: 17% by weight) was used as the substrate layer 1, and an acrylic water-based adhesive (SE-4500, manufactured by Showa Polymer Co., Ltd.) was applied. The main component: butyl ester (glass transition temperature: -25 ° C) and epoxy-based crosslinking agent (TETRAD-C, manufactured by Mitsubishi Gas Chemical Co., Ltd.) were the same as in Example 1 except for the adhesive layer B. Steps to make a diaphragm. The adhesive force of the adhesive layer A was set to 1 N/10 mm, and the adhesive force of the adhesive layer B was set to 0.3 N/10 mm. All characteristic values were evaluated as good, and the target membrane was produced.

<比較例1~3><Comparative Examples 1 to 3>

將實施例1~3中黏著層A及黏著層B所使用之黏著劑予以對調以製作膜片。比較例1~3中,由於黏著層A之黏著力低於黏著層B之黏著力,因此產生浮起。The adhesives used in the adhesive layer A and the adhesive layer B in Examples 1 to 3 were reversed to prepare a film. In Comparative Examples 1 to 3, since the adhesive force of the adhesive layer A was lower than the adhesive force of the adhesive layer B, floating occurred.

<比較例4><Comparative Example 4>

將實施例1之黏著層A的黏著力變更成12N/10mm的比較例4中,由於黏著力過強,因此留下殘膠。In Comparative Example 4 in which the adhesive force of the adhesive layer A of Example 1 was changed to 12 N/10 mm, since the adhesive force was too strong, residual adhesive remained.

<比較例5><Comparative Example 5>

將實施例1之黏著層B的黏著力變更成0.01N/10mm的比較例5中,由於黏著力過低,因此雜物吸附性惡化。In Comparative Example 5 in which the adhesive force of the adhesive layer B of Example 1 was changed to 0.01 N/10 mm, the adhesion of the foreign matter was deteriorated because the adhesive force was too low.

從「表一」可知,根據本發明,藉由使黏著片黏著於運輸裝置之扶手,即可確實地進行扶手及導輥之清掃。As can be seen from "Table 1", according to the present invention, the handrail and the guide roller can be reliably cleaned by adhering the adhesive sheet to the armrest of the transport device.

本發明之運輸裝置之扶手黏著片,適合使用作為電扶梯或電動走道等之扶手及導輥之清掃用去雜物雙面黏著片。The handrail adhesive sheet of the transport device of the present invention is suitable for use as a double-sided adhesive sheet for cleaning the handrail and the guide roller of an escalator or an electric walkway.

1...基材層1. . . Substrate layer

4...分隔件4. . . Separator

A...黏著層AA. . . Adhesive layer A

B...黏著層BB. . . Adhesive layer B

第一圖係用以說明本發明之運輸裝置之扶手黏著片之構成的截面示意圖。The first figure is a schematic cross-sectional view for explaining the constitution of the handrail adhesive sheet of the transport device of the present invention.

1...基材層1. . . Substrate layer

4...分隔件4. . . Separator

A...黏著層AA. . . Adhesive layer A

B...黏著層BB. . . Adhesive layer B

Claims (5)

一種運輸裝置之扶手黏著片,其包含:基材層;黏著層A,係積層於該基材層之一面,以黏著於運輸裝置之扶手表面;以及黏著層B,係積層於該基材層之另一面,且相對於黏著層A被賦予較小之黏著力。 An armrest adhesive sheet for a transport device, comprising: a substrate layer; an adhesive layer A laminated on one side of the substrate layer to adhere to a handrail surface of the transport device; and an adhesive layer B laminated on the substrate layer The other side is given a small adhesion to the adhesive layer A. 如申請專利範圍第1項所述之運輸裝置之扶手黏著片,其中該黏著層B之黏著力係0.1N/10mm以上,該黏著層A之黏著力則為10N/10mm以下。 The handrail adhesive sheet of the transport device according to claim 1, wherein the adhesive layer B has an adhesive force of 0.1 N/10 mm or more, and the adhesive layer A has an adhesive force of 10 N/10 mm or less. 如申請專利範圍第1項或第2項所述之運輸裝置之扶手黏著片,其中該黏著層A與該黏著層B係含有丙烯酸系黏著劑。 The handrail adhesive sheet of the transport device according to claim 1 or 2, wherein the adhesive layer A and the adhesive layer B contain an acrylic adhesive. 如申請專利範圍第1項或第2項所述之運輸裝置之扶手黏著片,其中該黏著層A與該黏著層B係含有界面活性劑。 The handrail adhesive sheet of the transport device according to claim 1 or 2, wherein the adhesive layer A and the adhesive layer B contain a surfactant. 如申請專利範圍第1項或第2項所述之運輸裝置之扶手黏著片,其係運輸裝置之扶手及扶手之導輥的清掃用去雜物雙面黏著片。The handrail adhesive sheet of the transport device according to the first or second aspect of the patent application, which is a double-sided adhesive sheet for cleaning the handrail of the transport device and the guide roller of the handrail.
TW098136455A 2008-11-04 2009-10-28 The adhesive sheet transport means handrail TWI495702B (en)

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