TWI480350B - Paint - Google Patents

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TWI480350B
TWI480350B TW101107327A TW101107327A TWI480350B TW I480350 B TWI480350 B TW I480350B TW 101107327 A TW101107327 A TW 101107327A TW 101107327 A TW101107327 A TW 101107327A TW I480350 B TWI480350 B TW I480350B
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lacquer
agent
resin
stabilizer
catalyst
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TW101107327A
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Chinese (zh)
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TW201336949A (en
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Chin Huang Ho
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Li In Der Entpr Ltd
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paint

本發明涉及塗料領域,具體涉及一種漆。 The invention relates to the field of coatings, and in particular to a lacquer.

室內裝飾用的金屬板材料使用較多的是鋁單板、鋁塑板表面塗上塗料,增加裝飾效果,其表面塗料一般採用銀色、珠光色或者透明色等素色,表面模樣多為平面,少數用皺紋漆、仿絨毛漆、仿沙粒漆、磁場紋漆來增加視覺以及觸覺效果;然而,這些塗料往往都比較單調,顏色暗淡,視覺效果不夠強烈。 The metal plate materials used for interior decoration are mostly coated with aluminum veneers and aluminum-plastic plates to increase the decorative effect. The surface coatings are generally silver, pearlescent or transparent, and the surface is mostly flat. A few use wrinkle paint, faux wool paint, imitation sand paint, magnetic field paint to increase the visual and tactile effects; however, these paints are often more monotonous, dim colors, and the visual effects are not strong enough.

為了解決上述問題,本發明的目的在於提供一種塗膜後表面形成特殊的多方向立體紋路,視覺效果更好的漆。 In order to solve the above problems, an object of the present invention is to provide a lacquer having a special multi-directional three-dimensional texture on the surface of a coating film and having a better visual effect.

為達到上述發明目的,本發明所運用之技術手段及藉由該技術手段所能達到之功效如下:一種漆,主要包括重量百分比之羥基丙烯酸樹脂69-78%、聚異氰酸酯樹脂4-6%、甲基化三聚氰胺甲醛樹脂9-13%、聚酯樹脂3-4%、催化劑2-3%、安定劑1-2%、矽烷偶聯劑0.5-1%及色漿1-2%。 In order to achieve the above object, the technical means utilized by the present invention and the efficiencies achieved by the technical means are as follows: a lacquer mainly comprising 69-78% of hydroxy acrylic resin by weight percentage, 4-6% of polyisocyanate resin, Methylated melamine formaldehyde resin 9-13%, polyester resin 3-4%, catalyst 2-3%, stabilizer 1-2%, decane coupling agent 0.5-1%, and color paste 1-2%.

所述漆,還包括重量百分比之消泡劑0.5-1%、分散劑0.5-1%及導電度增進劑0.5-1%。 The lacquer further comprises 0.5-1% by weight of the antifoaming agent, 0.5-1% of the dispersing agent, and 0.5-1% of the conductivity improving agent.

所述漆,其中該羥基丙烯酸樹脂為78%、聚異氰酸酯樹脂為4%、甲基化三聚氰胺甲醛樹脂為9%、聚酯樹脂為3%、催化劑為2%、安定劑為1%、矽烷偶聯劑為0.5% 及色漿為1%。 The lacquer, wherein the hydroxy acrylic resin is 78%, the polyisocyanate resin is 4%, the methylated melamine formaldehyde resin is 9%, the polyester resin is 3%, the catalyst is 2%, the stabilizer is 1%, and the decane couple The bonding agent is 0.5% And the color paste is 1%.

所述漆,其中該消泡劑為丙烯酸酯共聚物消泡劑0.5%,該分散劑為聚羧酸胺鹽分散劑0.5%,該導電度增進劑為胺鹽化合物導電度增進劑0.5%。 The lacquer, wherein the antifoaming agent is 0.5% of an acrylate copolymer antifoaming agent, the dispersing agent is 0.5% of a polycarboxylate amine salt dispersing agent, and the conductivity improving agent is 0.5% of an amine salt compound conductivity improving agent.

所述漆,其中該聚酯樹脂為無油醇酸樹脂。 The lacquer, wherein the polyester resin is an oil-free alkyd resin.

所述漆,其中該催化劑為二壬基萘磺酸催化劑0.7%、十二烷基磺酸催化劑0.7%及對甲苯磺酸催化劑0.6%之總合。 The lacquer wherein the catalyst is 0.7% of a dinonylnaphthalenesulfonic acid catalyst, 0.7% of a dodecylsulfonic acid catalyst, and 0.6% of a p-toluenesulfonic acid catalyst.

所述漆,其中該安定劑為二乙胺安定劑0.5%及三乙胺安定劑0.5%之總合。 The lacquer, wherein the stabilizer is a total of 0.5% diethylamine stabilizer and 0.5% triethylamine stabilizer.

所述漆,其中該矽烷偶聯劑為環氧基矽烷偶聯劑。 The lacquer, wherein the decane coupling agent is an epoxy decane coupling agent.

所述漆,其中該色漿為油性色漿。 The lacquer, wherein the color paste is an oily color paste.

本發明與現有技術的裝飾塗料相比,具有以下功效:塗料在金屬板上形成塗膜後,表面形成褶皺,從而具有特殊的多方向立體的紋路,凹凸曲折,顯現出不同形狀的圖案,並由於加有色漿,而呈現亮麗的顏色,配合金屬板底材的光澤,呈現不同的反射效果,視覺效果非常顯著,給人一種強烈的視覺享受,克服了現有技術裝飾板紋路單調、顏色暗淡的缺陷。 Compared with the decorative paint of the prior art, the invention has the following effects: after the paint forms a coating film on the metal plate, the surface is formed with wrinkles, thereby having a special multi-directional three-dimensional texture, and the concave and convex zigzag, showing a pattern of different shapes, and Due to the addition of color paste, it presents a bright color, with the luster of the metal plate substrate, showing different reflection effects, and the visual effect is very remarkable, giving a strong visual enjoyment, overcoming the monotonous and dim color of the decorative plate of the prior art. defect.

為讓本發明之上述及其他目的、特徵及優點能更明顯易懂,下文特舉本發明之較佳實施例,作詳細說明如下:下面將結合具體實施方法來詳細說明本發明,在本發明的示意性實施及說明用來解釋本發明,但並不作為對本 發明的限定。 The above and other objects, features and advantages of the present invention will become more <RTIgt; The schematic implementation and description are used to explain the present invention, but not as a Limitation of the invention.

本發明提供的漆,主要包括重量百分比之羥基丙烯酸樹脂69-78%、聚異氰酸酯樹脂4-6%、甲基化三聚氰胺甲醛樹脂9-13%、聚酯樹脂3-4%、催化劑2-3%、安定劑1-2%、矽烷偶聯劑0.5-1%及色漿1-2%。 The paint provided by the invention mainly comprises 69-78% of hydroxy acrylic resin by weight percentage, 4-6% of polyisocyanate resin, 9-13% of methylated melamine formaldehyde resin, 3-4% of polyester resin, catalyst 2-3 %, stabilizer 1-2%, decane coupling agent 0.5-1% and color paste 1-2%.

所述漆還包括重量百分比之消泡劑0.5-1%、分散劑0.5-1%及導電度增進劑0.5-1%。 The lacquer also includes 0.5 to 1% by weight of the antifoaming agent, 0.5 to 1% of the dispersing agent, and 0.5 to 1% of the conductivity improving agent.

以下為本發明提供的實施例,用來理解本發明的實施原理,並不作為對本發明的限制: The following is an embodiment of the present invention to understand the implementation of the present invention and is not intended to limit the invention:

實施例1 Example 1

本發明所述漆,主要包括重量百分比之羥基丙烯酸樹脂78%、聚異氰酸酯樹脂4%、甲基化三聚氰胺甲醛樹脂9%、無油醇酸樹脂3%、二壬基萘磺酸催化劑0.7%、十二烷基磺酸催化劑0.7%、對甲苯磺酸催化劑0.6%、二乙胺安定劑0.5%、三乙胺安定劑0.5%、丙烯酸酯共聚物消泡劑0.5%、環氧基矽烷偶聯劑0.5%、胺鹽化合物導電度增進劑0.5%、聚羧酸胺鹽分散劑0.5%及油性色漿1%。 The paint of the invention mainly comprises 78% by weight of hydroxy acrylic resin, 4% of polyisocyanate resin, 9% of methylated melamine formaldehyde resin, 3% of oil-free alkyd resin and 0.7% of dinonylnaphthalenesulfonic acid catalyst. Dodecylsulfonic acid catalyst 0.7%, p-toluenesulfonic acid catalyst 0.6%, diethylamine stabilizer 0.5%, triethylamine stabilizer 0.5%, acrylate copolymer defoamer 0.5%, epoxy decane coupling 0.5% of the agent, 0.5% of the amine salt compound conductivity enhancer, 0.5% of the polycarboxylate salt dispersant, and 1% of the oily color paste.

實施例2 Example 2

本發明所述漆,主要包括重量百分比之羥基丙烯酸樹脂74%、聚異氰酸酯樹脂4.5%、甲基化三聚氰胺甲醛樹脂11%、無油醇酸樹脂3.4%、二壬基萘磺酸催化劑0.8%、十二烷基磺酸催化劑0.8%、對甲苯磺酸催化劑0.7%、二乙胺安定劑0.6%、三乙胺安定劑0.6%、丙烯酸酯共聚物消泡劑0.6%、環氧基矽烷偶聯劑0.6%、胺鹽化合物導電度增進劑0.6%、聚羧酸胺鹽分散劑0.6%及油性色漿1.2 %。 The paint of the invention mainly comprises 74% by weight of hydroxy acrylic resin, 4.5% of polyisocyanate resin, 11% of methylated melamine formaldehyde resin, 3.4% of oil-free alkyd resin and 0.8% of dinonylnaphthalenesulfonic acid catalyst. Dodecylsulfonic acid catalyst 0.8%, p-toluenesulfonic acid catalyst 0.7%, diethylamine stabilizer 0.6%, triethylamine stabilizer 0.6%, acrylate copolymer defoamer 0.6%, epoxy decane coupling Agent 0.6%, amine salt compound conductivity improver 0.6%, polycarboxylate amine salt dispersant 0.6% and oily color paste 1.2 %.

實施例3 Example 3

本發明所述漆,主要包括重量百分比之羥基丙烯酸樹脂70%、聚異氰酸酯樹脂5%、甲基化三聚氰胺甲醛樹脂12.5%、無油醇酸樹脂3.5%、二壬基萘磺酸催化劑0.9%、十二烷基磺酸催化劑0.9%、對甲苯磺酸催化劑0.8%、二乙胺安定劑0.8%、三乙胺安定劑0.8%、丙烯酸酯共聚物消泡劑0.8%、環氧基矽烷偶聯劑0.8%、胺鹽化合物導電度增進劑0.8%、聚羧酸胺鹽分散劑0.8%及油性色漿1.6%。 The paint of the invention mainly comprises 70% by weight of hydroxy acrylic resin, 5% of polyisocyanate resin, 12.5% of methylated melamine formaldehyde resin, 3.5% of oil-free alkyd resin and 0.9% of dinonylnaphthalenesulfonic acid catalyst. Dodecylsulfonic acid catalyst 0.9%, p-toluenesulfonic acid catalyst 0.8%, diethylamine stabilizer 0.8%, triethylamine stabilizer 0.8%, acrylate copolymer defoamer 0.8%, epoxy decane coupling The agent was 0.8%, the amine salt compound conductivity enhancer was 0.8%, the polycarboxylate amine salt dispersant was 0.8%, and the oily colorant was 1.6%.

實施例4 Example 4

本發明所述漆,主要包括重量百分比之羥基丙烯酸樹脂69%、聚異氰酸酯樹脂5%、甲基化三聚氰胺甲醛樹脂11%、無油醇酸樹脂4%、二壬基萘磺酸催化劑1%、十二烷基磺酸催化劑1%、對甲苯磺酸催化劑1%、二乙胺安定劑1%、三乙胺安定劑1%、丙烯酸酯共聚物消泡劑1%、環氧基矽烷偶聯劑1%、胺鹽化合物導電度增進劑1%、聚羧酸胺鹽分散劑1%及油性色漿2%。 The paint of the invention mainly comprises 69% by weight of hydroxy acrylic resin, 5% of polyisocyanate resin, 11% of methylated melamine formaldehyde resin, 4% of oil-free alkyd resin, 1% of dinonylnaphthalenesulfonic acid catalyst, Dodecanesulfonic acid catalyst 1%, p-toluenesulfonic acid catalyst 1%, diethylamine stabilizer 1%, triethylamine stabilizer 1%, acrylate copolymer defoamer 1%, epoxy decane coupling The agent 1%, the amine salt compound conductivity improver 1%, the polycarboxylate amine salt dispersant 1%, and the oily paste 2%.

根據以上實施例所述配方,將原料按品質份混合,攪拌均勻,得到本發明所述的漆,將本發明的漆塗裝於鋁光板或者其他金屬板,塗於金屬板表面,成為一層濕膜,濕膜厚度100-110微米(μm),加熱170-180℃對塗膜進行3-5分鐘烘烤,形成一層乾膜,乾膜形成後會收縮起皺,形成如結晶礦石的形狀,視覺效果非常好,得到的乾膜形成有凹凸不平的褶皺,厚度為20-160微米(μm),該乾 膜還可形成多種不同形狀的圖案,再配合金屬板的光澤反射,簡直就是一種視覺享受。 According to the formulation described in the above embodiment, the raw materials are mixed according to the quality parts, and the mixture is uniformly stirred to obtain the lacquer according to the present invention. The lacquer of the present invention is coated on an aluminum light plate or other metal plate and applied to the surface of the metal plate to form a wet layer. The film has a wet film thickness of 100-110 micrometers (μm), and is heated at 170-180 ° C for 3-5 minutes to form a dry film. After the dry film is formed, it shrinks and wrinkles to form a shape such as crystalline ore. The visual effect is very good, and the obtained dry film is formed with uneven wrinkles, and the thickness is 20-160 micrometers (μm), the dry The film can also be formed into a variety of different shapes of patterns, combined with the glossy reflection of the metal plate, is simply a visual enjoyment.

分析這種塗膜形成的原因,係採用兩種上不同的羥基(-OH)丙烯酸樹脂,配合兩種含有異氰酸(-NCO)基團的聚異氰酸酯樹脂,及兩種含有羥基(-OH)、醚基(-OR)的甲基化三聚氰胺甲醛樹脂,與少量的聚酯樹脂,並加入幾種催化劑,在塗裝後加熱乾燥時,因樹脂含有羥基(-OH)、羧基(-COOH)、醯胺基(-CONH2),其官能基團固化反應階段不同,造成塗膜內層及表面乾燥收縮時間不同,使塗膜起皺形成不規則紋路的圖案。 The reason for the formation of the coating film was analyzed by using two different hydroxyl (-OH) acrylic resins, two polyisocyanate resins containing isocyanate (-NCO) groups, and two hydroxyl groups (-OH). ), ether-based (-OR) methylated melamine formaldehyde resin, with a small amount of polyester resin, and several catalysts added, after heating and drying after coating, the resin contains hydroxyl (-OH), carboxyl (-COOH) ), amidino group (-CONH 2 ), the functional group curing reaction phase is different, resulting in different drying and shrinking time of the inner layer and surface of the coating film, causing the coating film to wrinkle to form an irregular pattern.

綜上所述,本發明與現有技術的裝飾塗料相比,具有以下功效:塗料在金屬板上形成塗膜後,表面形成褶皺,從而具有特殊的多方向立體的紋路,凹凸曲折,顯現出不同形狀的圖案,並由於加有色漿,而呈現亮麗的顏色,配合金屬板底材的光澤,呈現不同的反射效果,視覺效果非常顯著,給人一種強烈的視覺享受,克服了現有技術裝飾板紋路單調、顏色暗淡的缺陷。 In summary, the present invention has the following effects as compared with the prior art decorative coatings: after the coating forms a coating film on the metal plate, the surface is formed with wrinkles, thereby having a special multi-directional three-dimensional texture, which is unevenly curved and appears different. The shape of the pattern, and the addition of color paste, the bright color, with the luster of the metal plate substrate, showing different reflection effects, the visual effect is very significant, giving a strong visual enjoyment, overcoming the existing decorative plate texture Monotonous, dim color defects.

以上對本發明實施例所提供的技術方案進行了詳細介紹,本文中應用了具體個例對本發明實施例的原理以及實施方式進行了闡述,以上實施例的說明只適用於幫助理解本發明實施例的原理;同時,對於本領域的一般技術人員,依據本發明實施例,在具體實施方式以及應用範圍上均會有改變之處,綜上所述,本說明書內容不應理解為對本發明的限制。 The technical solutions provided by the embodiments of the present invention are described in detail above. The principles and implementation manners of the embodiments of the present invention are described in the following. The description of the foregoing embodiments is only applicable to help understand the embodiments of the present invention. The present invention is not limited by the scope of the present invention, and the description of the present invention is not limited to the details of the present invention.

雖然本發明已利用上述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者在不脫離本發明之精神和範圍之內,相對上述實施例進行各種更動與修改仍屬本發明所保護之技術範疇,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。 While the invention has been described in connection with the preferred embodiments described above, it is not intended to limit the scope of the invention. The technical scope of the invention is protected, and therefore the scope of the invention is defined by the scope of the appended claims.

Claims (9)

一種漆,主要包括重量百分比之羥基丙烯酸樹脂69-78%、聚異氰酸酯樹脂4-6%、甲基化三聚氰胺甲醛樹脂9-13%、聚酯樹脂3-4%、催化劑2-3%、安定劑1-2%、矽烷偶聯劑0.5-1%及色漿1-2%。 A lacquer mainly comprising 69-78% by weight of hydroxy acrylic resin, 4-6% polyisocyanate resin, 9-13% methylated melamine formaldehyde resin, 3-4% polyester resin, 2-3% catalyst, stability The agent is 1-2%, the decane coupling agent is 0.5-1%, and the color paste is 1-2%. 如申請專利範圍第1項所述的漆,還包括重量百分比之消泡劑0.5-1%、分散劑0.5-1%及導電度增進劑0.5-1%。 The lacquer according to claim 1, further comprising 0.5 to 1% by weight of the antifoaming agent, 0.5 to 1% of the dispersing agent, and 0.5 to 1% of the conductivity improving agent. 如申請專利範圍第1項所述的漆,其中該羥基丙烯酸樹脂為78%、聚異氰酸酯樹脂為4%、甲基化三聚氰胺甲醛樹脂為9%、聚酯樹脂為3%、催化劑為2%、安定劑為1%、矽烷偶聯劑為0.5%及色漿為1%。 The lacquer according to claim 1, wherein the hydroxy acrylic resin is 78%, the polyisocyanate resin is 4%, the methylated melamine formaldehyde resin is 9%, the polyester resin is 3%, and the catalyst is 2%. The stabilizer was 1%, the decane coupling agent was 0.5%, and the colorant was 1%. 如申請專利範圍第2項所述的漆,其中該消泡劑為丙烯酸酯共聚物消泡劑0.5%,該分散劑為聚羧酸胺鹽分散劑0.5%,該導電度增進劑為胺鹽化合物導電度增進劑0.5%。 The lacquer according to claim 2, wherein the antifoaming agent is 0.5% of an acrylate copolymer antifoaming agent, the dispersing agent is 0.5% of a polycarboxylate amine salt dispersing agent, and the conductivity improving agent is an amine salt compound. Conductivity improver 0.5%. 如申請專利範圍第3項所述的漆,其中該聚酯樹脂為無油醇酸樹脂。 The lacquer of claim 3, wherein the polyester resin is an oil-free alkyd resin. 如申請專利範圍第3項所述的漆,其中該催化劑為二壬基萘磺酸催化劑0.7%、十二烷基磺酸催化劑0.7%及對甲苯磺酸催化劑0.6%之總合。 The lacquer of claim 3, wherein the catalyst is 0.7% of a dinonylnaphthalenesulfonic acid catalyst, 0.7% of a dodecylsulfonic acid catalyst, and 0.6% of a p-toluenesulfonic acid catalyst. 如申請專利範圍第3項所述的漆,其中該安定劑為二乙胺安定劑0.5%及三乙胺安定劑0.5%之總合。 The lacquer of claim 3, wherein the stabilizer is a total of 0.5% diethylamine stabilizer and 0.5% triethylamine stabilizer. 如申請專利範圍第3項所述的漆,其中該矽烷偶聯劑為 環氧基矽烷偶聯劑。 The lacquer of claim 3, wherein the decane coupling agent is Epoxy decane coupling agent. 如申請專利範圍第3項所述的漆,其中該色漿為油性色漿。 The lacquer of claim 3, wherein the color paste is an oily color paste.
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200506013A (en) * 2003-03-21 2005-02-16 Du Pont Polytrimethylene ether diol containing coating compositions
TW200944564A (en) * 2008-04-16 2009-11-01 Eternal Chemical Co Ltd Coating composition and purpose thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
TW200506013A (en) * 2003-03-21 2005-02-16 Du Pont Polytrimethylene ether diol containing coating compositions
TW200944564A (en) * 2008-04-16 2009-11-01 Eternal Chemical Co Ltd Coating composition and purpose thereof

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