CN106114045A - Efficient stable imitates the processing method of metal wire-drawing decorating film - Google Patents

Efficient stable imitates the processing method of metal wire-drawing decorating film Download PDF

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Publication number
CN106114045A
CN106114045A CN201610461632.7A CN201610461632A CN106114045A CN 106114045 A CN106114045 A CN 106114045A CN 201610461632 A CN201610461632 A CN 201610461632A CN 106114045 A CN106114045 A CN 106114045A
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China
Prior art keywords
coating
parts
processing
raw
weight
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Pending
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CN201610461632.7A
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Chinese (zh)
Inventor
张宝平
张中宝
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WENZHOU CHENHUI PLASTIC PACKAGING CO Ltd
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WENZHOU CHENHUI PLASTIC PACKAGING CO Ltd
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Priority to CN201610461632.7A priority Critical patent/CN106114045A/en
Publication of CN106114045A publication Critical patent/CN106114045A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B44DECORATIVE ARTS
    • B44CPRODUCING DECORATIVE EFFECTS; MOSAICS; TARSIA WORK; PAPERHANGING
    • B44C5/00Processes for producing special ornamental bodies
    • B44C5/04Ornamental plaques, e.g. decorative panels, decorative veneers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D133/00Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D161/00Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
    • C09D161/02Condensation polymers of aldehydes or ketones only
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D177/00Coating compositions based on polyamides obtained by reactions forming a carboxylic amide link in the main chain; Coating compositions based on derivatives of such polymers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

Abstract

The present invention relates to the processing method that a kind of efficient stable imitates metal wire-drawing decorating film: the wire drawing pretreatment of (1) base material;(2) absciss layer: the film surface coating absciss layer processed in wire drawing, absciss layer coating is formed by the Raw material processing of following weight portion: polyamide wax 13 17 parts, butanone 11 15 parts, Ketohexamethylene 13 parts;(3) coloring: the coating that coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 8 12 parts, aldehyde ketone resin 8 12 parts, polyamide curing agent 46 parts, butanone 8 12 parts, butyl ester 0.5 1.5 parts;(4) solidification;(5) aluminize;(6) gluing: described glue-line coating is formed by the Raw material processing of following weight portion: acrylic resin 6 10 parts, polyamine polyamine acid ester resin 24 parts, toluene 24 parts, ethyl ester 68 parts;The metal drawbench film of the present invention has the machinability of excellence, dicoration, corrosion resistance, scoring resistance, heat-resisting quantity etc., and drawing film can be made to realize color variation, the various luster degree effect from dumb light to Gao Guang.

Description

Efficient stable imitates the processing method of metal wire-drawing decorating film
Technical field
The present invention relates to a kind of decorating film, imitate the processing side of metal wire-drawing decorating film more particularly to a kind of efficient stable Method.
Background technology
In the prior art, the application in industry and life of metallic plate particularly steel plate, aluminium is more and more extensive, vapour Car, refrigerator, washing machine, cooking apparatus, industry and civil buildings are required for using.General steel plate in use, metal Plate easily aoxidizes, perishable, accordingly, it would be desirable to first carry out antiseptic and rustproof process, such as spray paint, but antirust, anti-corrosive ability is not By force, and paint easy scratch and come off, causing the service life reduction of metallic plate, also can have a strong impact on the outward appearance of metallic plate.
In recent years, at a lot of products (as the double-colored plate of ABS, anti-wood block for printing, laser machine personality board, show and colour, family are shifted in thermoprint Electricity etc.) in gradually risen and be provided with overlay film on the surface of metallic plate, play protective action, Unfortunately obtaining more polychrome Also hidden metallic luster while coloured silk and pattern, lost the original texture of metal, reduce the decorative effect of overlay film.
Summary of the invention
It is an object of the invention to solve the deficiencies in the prior art, it is provided that a kind of efficient stable imitates metal wire-drawing decorating film Processing method.
The technical solution adopted for the present invention to solve the technical problems is:
Efficient stable imitates the processing method of metal wire-drawing decorating film, and described method is carried out as follows:
(1) base material wire drawing pretreatment: use PET as main film body material, an one side is carried out surface wire drawing process;
(2) absciss layer: the film surface coating absciss layer processed in wire drawing, absciss layer coating is by the Raw material processing of following weight portion Become: polyamide wax 13-17 part, butanone 11-15 part, Ketohexamethylene 1-3 part;
Absciss layer coating have the advantage that the pet sheet face being applicable to various anodized aluminium, production liquid stability is strong, levelling and Good luster, corrosion resistance, high temperature resistant, scratch resistance function admirable.
(3) coloring: the coating that coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 8-12 part, aldehyde Ketone resin 8-12 part, polyamide curing agent 4-6 part, butanone 8-12 part, butyl ester 0.5-1.5 part;
Pigmented finiss has the advantage that end properties is stable, and coating film gloss degree is good, and the thermoprint suitability is good, high temperature resistant, corrosion-resistant Property strong, good to dyestuff pardon, good with aluminium lamination fastness.
(4) solidification;
(5) aluminize;
(6) gluing: described glue-line coating is formed by the Raw material processing of following weight portion: acrylic resin 6-10 part, polyaspartic Resin 2-4 part, toluene 2-4 part, ethyl ester 6-8 part;
Glue-line coating has the advantage that has good tack to various quantity, pp, and plate double-colored to ABS has the strongest attachment Power, thermoprint performance is strong, has corrosion resistance high-temperature stability.
Preferably, in step (2), absciss layer coating is formed by the Raw material processing of following weight portion: polyamide wax 15 parts, butanone 13 parts, Ketohexamethylene 2 parts;First mixed solvent, is subsequently adding polyamide wax, is coated with by coating machine, coating after stirring more than 30min Net roller mesh number is 160-200 mesh, and coating temperature is 80,120,130,140,150,145,140,125 DEG C, and described temperature refers to The temperature of eight joint baking ovens, coating speed 70-80m/min, wet coating amount is 5-6g/.
Preferably, the coating that in step (3), coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 10 parts, aldehyde ketone resin 10 parts, polyamide curing agent 5 parts, butanone 10 parts, butyl ester 1 part;First mixed solvent, is then sequentially added into third Olefin(e) acid resin, aldehyde ketone resin and polyamide curing agent, be coated with by coating machine after stirring more than 30min, and coating net roller mesh number is 160-200 mesh, coating temperature is 80,120,140,150,165,165,150,140 DEG C, and described temperature refers to eight joint baking ovens Temperature, coating speed 70-90m/min, wet coating amount is 6-8g/.
Preferably, described glue-line coating is formed by the Raw material processing of following weight portion: acrylic resin 8 parts, polyaspartic Resin 3 parts, toluene 3 parts, ethyl ester 7 parts, first mixed solvent, then it is sequentially added into acrylic resin, polyaspartic resin, stirring Being coated with by coating machine after more than 30min, coating net roller mesh number is 80-120 mesh, coating temperature is 80,100,120,130, 135,135,130,120 DEG C, described temperature refers to the temperature of eight joint baking ovens, coating speed 70-90m/min, and wet coating amount is 9-11g/㎡。
The invention has the beneficial effects as follows: the metal drawbench film of the present invention has the machinability of excellence, dicoration, corrosion-resistant Property, scoring resistance, heat-resisting quantity etc., can make drawing film realize color variation, the various luster degree effect from dumb light to Gao Guang. Traditional drawing film technique typically uses Material cladding technology, and Technology is complicated, non-to the energy and raw-material consumption demand Chang great, limited in the progress of the aspect such as energy-conservation, to economize on resources, do not possess environment-friendly function.
Detailed description of the invention
Below by specific embodiment, technical scheme is described in further detail.
Industrial chemicals used by the embodiment of the present invention is all commercial convenient source, wire drawing used, aluminize equipment and coating apparatus Being all conventional equipment, solidification and aluminum plating process use the conventional fabrication process of drawing film.
Embodiment 1:
Efficient stable imitates the processing method of metal wire-drawing decorating film, and described method is carried out as follows:
(1) base material wire drawing pretreatment: use PET as main film body material, an one side is carried out surface wire drawing process;
(2) absciss layer: the film surface coating absciss layer processed in wire drawing, absciss layer coating is by the Raw material processing of following weight portion Become: polyamide wax 13 parts, butanone 11 parts, Ketohexamethylene 1 part;First mixed solvent, is subsequently adding polyamide wax, stirs more than 30min Being coated with by coating machine afterwards, coating net roller mesh number is 160 mesh, and coating temperature is 80,120,130,140,150,145,140,125 DEG C, coating speed 70m/min, wet coating amount is 5g/.
(3) coloring: the coating that coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 8 parts, aldehyde ketone Resin 8 parts, polyamide curing agent 4 parts, butanone 8 parts, butyl ester 0.5 part;First mixed solvent, be then sequentially added into acrylic resin, Aldehyde ketone resin and polyamide curing agent, be coated with by coating machine after stirring more than 30min, and coating net roller mesh number is 160 mesh, coating Temperature is 80,120,140,150,165,165,150,140 DEG C, coating speed 70m/min, and wet coating amount is 6g/;
(4) solidification;
(5) aluminize;
(6) gluing: described glue-line coating is formed by the Raw material processing of following weight portion: acrylic resin 6 parts, polyaspartic resin 2 parts, toluene 2 parts, ethyl ester 6 parts;First mixed solvent, is then sequentially added into acrylic resin, polyaspartic resin, stirs 30min Below being coated with by coating machine afterwards, coating net roller mesh number is 80 mesh, coating temperature is 80,100,120,130,135,135,130, 120 DEG C, coating speed 70m/min, wet coating amount is 9g/.
Embodiment 2:
Efficient stable imitates the processing method of metal wire-drawing decorating film, and described method is carried out as follows:
(1) base material wire drawing pretreatment: use PET as main film body material, an one side is carried out surface wire drawing process;
(2) absciss layer: the film surface coating absciss layer processed in wire drawing, absciss layer coating is by the Raw material processing of following weight portion Become: polyamide wax 17 parts, butanone 15 parts, Ketohexamethylene 3 parts;First mixed solvent, is subsequently adding polyamide wax, stirs more than 30min Being coated with by coating machine afterwards, coating net roller mesh number is 160 mesh, and coating temperature is 80,120,130,140,150,145,140,125 DEG C, coating speed 70m/min, wet coating amount is 5g/.
(3) coloring: the coating that coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 12 parts, aldehyde ketone Resin 12 parts, polyamide curing agent 6 parts, butanone 12 parts, butyl ester 1.5 parts;First mixed solvent, is then sequentially added into acrylic acid tree Fat, aldehyde ketone resin and polyamide curing agent, be coated with by coating machine after stirring more than 30min, and coating net roller mesh number is 200 mesh, Coating temperature is 80,120,140,150,165,165,150,140 DEG C, coating speed 90m/min, and wet coating amount is 8g/;
(4) solidification;
(5) aluminize;
(6) gluing: described glue-line coating is formed by the Raw material processing of following weight portion: acrylic resin 10 parts, polyaspartic tree 4 parts of fat, toluene 4 parts, ethyl ester 8 parts;First mixed solvent, is then sequentially added into acrylic resin, polyaspartic resin, stirring Being coated with by coating machine after more than 30min, coating net roller mesh number is 120 mesh, coating temperature is 80,100,120,130,135, 135,130,120 DEG C, coating speed 90m/min, wet coating amount is 11g/.
Embodiment 3:
Efficient stable imitates the processing method of metal wire-drawing decorating film, and described method is carried out as follows:
(1) base material wire drawing pretreatment: use PET as main film body material, an one side is carried out surface wire drawing process;
(2) absciss layer: the film surface coating absciss layer processed in wire drawing, absciss layer coating is by the Raw material processing of following weight portion Become: polyamide wax 15 parts, butanone 13 parts, Ketohexamethylene 2 parts;First mixed solvent, is subsequently adding polyamide wax, stirs more than 30min Being coated with by coating machine afterwards, coating net roller mesh number is 180 mesh, and coating temperature is 80,120,130,140,150,145,140,125 DEG C, coating speed 70m/min, wet coating amount is 5g/.
(3) coloring: the coating that coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 10 parts, aldehyde ketone Resin 10 parts, polyamide curing agent 5 parts, butanone 10 parts, butyl ester 1 part;First mixed solvent, be then sequentially added into acrylic resin, Aldehyde ketone resin and polyamide curing agent, be coated with by coating machine after stirring more than 30min, and coating net roller mesh number is 180 mesh, coating Temperature is 80,120,140,150,165,165,150,140 DEG C, coating speed 80m/min, and wet coating amount is 7g/;
(4) solidification;
(5) aluminize;
(6) gluing: described glue-line coating is formed by the Raw material processing of following weight portion: acrylic resin 8 parts, polyaspartic resin 3 parts, toluene 3 parts, ethyl ester 7 parts;First mixed solvent, is then sequentially added into acrylic resin, polyaspartic resin, stirs 30min Below being coated with by coating machine afterwards, coating net roller mesh number is 100 mesh, coating temperature is 80,100,120,130,135,135, 130,120 DEG C, coating speed 80m/min, wet coating amount is 10g/.
The metal drawbench film of the present invention has the machinability of excellence, dicoration, corrosion resistance, scoring resistance, high temperature resistant Property etc., drawing film can be made to realize color variation, the various luster degree effect from dumb light to Gao Guang.
Embodiment described above is the one preferably scheme of the present invention, not makees the present invention any pro forma Limit, on the premise of without departing from the technical scheme described in claim, also have other variant and remodeling.

Claims (4)

1. the processing method that efficient stable imitates metal wire-drawing decorating film, it is characterised in that: described method is carried out as follows:
(1) base material wire drawing pretreatment: use PET as main film body material, an one side is carried out surface wire drawing process;
(2) absciss layer: the film surface coating absciss layer processed in wire drawing, absciss layer coating is by the Raw material processing of following weight portion Become: polyamide wax 13-17 part, butanone 11-15 part, Ketohexamethylene 1-3 part;
(3) coloring: the coating that coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 8-12 part, aldehyde ketone tree Fat 8-12 part, polyamide curing agent 4-6 part, butanone 8-12 part, butyl ester 0.5-1.5 part;
(4) solidification;
(5) aluminize;
(6) gluing: described glue-line coating is formed by the Raw material processing of following weight portion: acrylic resin 6-10 part, polyaspartic Resin 2-4 part, toluene 2-4 part, ethyl ester 6-8 part.
Efficient stable the most according to claim 1 imitates the processing method of metal wire-drawing decorating film, it is characterised in that: step (2) in, absciss layer coating is formed by the Raw material processing of following weight portion: polyamide wax 15 parts, butanone 13 parts, Ketohexamethylene 2 parts;First mix Bonding solvent, is subsequently adding polyamide wax, is coated with by coating machine after stirring more than 30min, and coating net roller mesh number is 160-200 Mesh, coating temperature is 80,120,130,140,150,145,140,125 DEG C, coating speed 70-80m/min, and wet coating amount is 5- 6g/㎡。
Efficient stable the most according to claim 1 imitates the processing method of metal wire-drawing decorating film, it is characterised in that: step (3) coating that in, coloring uses is formed by the Raw material processing of following weight portion: acrylic resin 10 parts, aldehyde ketone resin 10 parts, poly- Amide hardener 5 parts, butanone 10 parts, butyl ester 1 part;First mixed solvent, is then sequentially added into acrylic resin, aldehyde ketone resin and gathers Amide hardener, is coated with by coating machine after stirring more than 30min, and coating net roller mesh number is 160-200 mesh, and coating temperature is 80,120,140,150,165,165,150,140 DEG C, coating speed 70-90m/min, wet coating amount is 6-8g/.
Efficient stable the most according to claim 1 imitates the processing method of metal wire-drawing decorating film, it is characterised in that: described glue Coating is formed by the Raw material processing of following weight portion: acrylic resin 8 parts, polyaspartic resin 3 parts, toluene 3 parts, ethyl ester 7 Part, first mixed solvent, then it is sequentially added into acrylic resin, polyaspartic resin, is coated with by coating machine after stirring more than 30min Cloth, coating net roller mesh number is 80-120 mesh, and coating temperature is 80,100,120,130,135,135,130,120 DEG C, coating speed 70-90m/min, wet coating amount is 9-11g/.
CN201610461632.7A 2016-06-23 2016-06-23 Efficient stable imitates the processing method of metal wire-drawing decorating film Pending CN106114045A (en)

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CN201610461632.7A CN106114045A (en) 2016-06-23 2016-06-23 Efficient stable imitates the processing method of metal wire-drawing decorating film

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109367175A (en) * 2018-10-10 2019-02-22 重庆科欣塑料有限公司 A kind of wire drawing film composite material and packaging material and packaging product comprising it

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746203A (en) * 2009-11-25 2010-06-23 中国乐凯胶片集团公司 Preparation method of wire drawing decorative film
CN102642439A (en) * 2011-12-22 2012-08-22 东莞市国鼎光电膜材科技有限公司 Manufacture process of imitation stainless steel metal drawbench film
CN104393217A (en) * 2014-10-20 2015-03-04 佛山荷韵特种材料有限公司 Composite stacked and coated lithium ion battery diaphragm and preparation method thereof
CN205220102U (en) * 2015-12-13 2016-05-11 温州晨辉包装材料有限公司 Novel PVC transfer membrane

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101746203A (en) * 2009-11-25 2010-06-23 中国乐凯胶片集团公司 Preparation method of wire drawing decorative film
CN102642439A (en) * 2011-12-22 2012-08-22 东莞市国鼎光电膜材科技有限公司 Manufacture process of imitation stainless steel metal drawbench film
CN104393217A (en) * 2014-10-20 2015-03-04 佛山荷韵特种材料有限公司 Composite stacked and coated lithium ion battery diaphragm and preparation method thereof
CN205220102U (en) * 2015-12-13 2016-05-11 温州晨辉包装材料有限公司 Novel PVC transfer membrane

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109367175A (en) * 2018-10-10 2019-02-22 重庆科欣塑料有限公司 A kind of wire drawing film composite material and packaging material and packaging product comprising it

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Application publication date: 20161116