TWI474784B - Filter for cigarette and cigarette - Google Patents
Filter for cigarette and cigarette Download PDFInfo
- Publication number
- TWI474784B TWI474784B TW100118954A TW100118954A TWI474784B TW I474784 B TWI474784 B TW I474784B TW 100118954 A TW100118954 A TW 100118954A TW 100118954 A TW100118954 A TW 100118954A TW I474784 B TWI474784 B TW I474784B
- Authority
- TW
- Taiwan
- Prior art keywords
- filter
- paper
- content liquid
- capsule
- cigarette
- Prior art date
Links
- 235000019504 cigarettes Nutrition 0.000 title claims description 43
- 239000007788 liquid Substances 0.000 claims description 80
- 239000002775 capsule Substances 0.000 claims description 64
- 239000003205 fragrance Substances 0.000 claims description 33
- 241000208125 Nicotiana Species 0.000 claims description 28
- 235000002637 Nicotiana tabacum Nutrition 0.000 claims description 28
- 239000000796 flavoring agent Substances 0.000 claims description 23
- 235000019634 flavors Nutrition 0.000 claims description 23
- 235000010983 sucrose acetate isobutyrate Nutrition 0.000 claims description 12
- UVGUPMLLGBCFEJ-SWTLDUCYSA-N sucrose acetate isobutyrate Chemical compound CC(C)C(=O)O[C@H]1[C@H](OC(=O)C(C)C)[C@@H](COC(=O)C(C)C)O[C@@]1(COC(C)=O)O[C@@H]1[C@H](OC(=O)C(C)C)[C@@H](OC(=O)C(C)C)[C@H](OC(=O)C(C)C)[C@@H](COC(C)=O)O1 UVGUPMLLGBCFEJ-SWTLDUCYSA-N 0.000 claims description 12
- 239000000463 material Substances 0.000 claims description 10
- 239000002304 perfume Substances 0.000 claims description 10
- 230000000149 penetrating effect Effects 0.000 claims description 9
- 239000002904 solvent Substances 0.000 claims description 8
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 238000004040 coloring Methods 0.000 claims description 4
- 239000003995 emulsifying agent Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 7
- 235000019198 oils Nutrition 0.000 description 7
- UFTFJSFQGQCHQW-UHFFFAOYSA-N triformin Chemical compound O=COCC(OC=O)COC=O UFTFJSFQGQCHQW-UHFFFAOYSA-N 0.000 description 7
- 235000019484 Rapeseed oil Nutrition 0.000 description 6
- 150000004667 medium chain fatty acids Chemical class 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 229920001353 Dextrin Polymers 0.000 description 5
- 239000004375 Dextrin Substances 0.000 description 5
- 229920002472 Starch Polymers 0.000 description 5
- 235000019425 dextrin Nutrition 0.000 description 5
- 150000004676 glycans Chemical class 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000000203 mixture Substances 0.000 description 5
- 229920001282 polysaccharide Polymers 0.000 description 5
- 239000005017 polysaccharide Substances 0.000 description 5
- 239000002994 raw material Substances 0.000 description 5
- 239000008107 starch Substances 0.000 description 5
- 235000019698 starch Nutrition 0.000 description 5
- NOOLISFMXDJSKH-UTLUCORTSA-N (+)-Neomenthol Chemical compound CC(C)[C@@H]1CC[C@@H](C)C[C@@H]1O NOOLISFMXDJSKH-UTLUCORTSA-N 0.000 description 4
- NOOLISFMXDJSKH-UHFFFAOYSA-N DL-menthol Natural products CC(C)C1CCC(C)CC1O NOOLISFMXDJSKH-UHFFFAOYSA-N 0.000 description 4
- 241000196324 Embryophyta Species 0.000 description 4
- 229940041616 menthol Drugs 0.000 description 4
- 230000000391 smoking effect Effects 0.000 description 4
- 235000013599 spices Nutrition 0.000 description 4
- 239000000341 volatile oil Substances 0.000 description 4
- 230000000740 bleeding effect Effects 0.000 description 3
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 2
- -1 cold weather Polymers 0.000 description 2
- 238000007599 discharging Methods 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000003925 fat Substances 0.000 description 2
- 239000000945 filler Substances 0.000 description 2
- 238000004816 paper chromatography Methods 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- QTBSBXVTEAMEQO-UHFFFAOYSA-M Acetate Chemical compound CC([O-])=O QTBSBXVTEAMEQO-UHFFFAOYSA-M 0.000 description 1
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 description 1
- 229920000298 Cellophane Polymers 0.000 description 1
- 108010010803 Gelatin Proteins 0.000 description 1
- 229920002148 Gellan gum Polymers 0.000 description 1
- 239000000654 additive Substances 0.000 description 1
- 230000002411 adverse Effects 0.000 description 1
- 239000001110 calcium chloride Substances 0.000 description 1
- 229910001628 calcium chloride Inorganic materials 0.000 description 1
- 230000001055 chewing effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 235000012343 cottonseed oil Nutrition 0.000 description 1
- 239000002385 cottonseed oil Substances 0.000 description 1
- GVJHHUAWPYXKBD-UHFFFAOYSA-N d-alpha-tocopherol Natural products OC1=C(C)C(C)=C2OC(CCCC(C)CCCC(C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-UHFFFAOYSA-N 0.000 description 1
- 235000014113 dietary fatty acids Nutrition 0.000 description 1
- 239000000194 fatty acid Substances 0.000 description 1
- 229930195729 fatty acid Natural products 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 229920000159 gelatin Polymers 0.000 description 1
- 239000008273 gelatin Substances 0.000 description 1
- 235000019322 gelatine Nutrition 0.000 description 1
- 235000011852 gelatine desserts Nutrition 0.000 description 1
- 235000010492 gellan gum Nutrition 0.000 description 1
- 239000000216 gellan gum Substances 0.000 description 1
- 239000003349 gelling agent Substances 0.000 description 1
- 235000011187 glycerol Nutrition 0.000 description 1
- 239000004519 grease Substances 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000004006 olive oil Substances 0.000 description 1
- 235000008390 olive oil Nutrition 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 235000010384 tocopherol Nutrition 0.000 description 1
- 229960001295 tocopherol Drugs 0.000 description 1
- 229930003799 tocopherol Natural products 0.000 description 1
- 239000011732 tocopherol Substances 0.000 description 1
- GVJHHUAWPYXKBD-IEOSBIPESA-N α-tocopherol Chemical compound OC1=C(C)C(C)=C2O[C@@](CCC[C@H](C)CCC[C@H](C)CCCC(C)C)(C)CCC2=C1C GVJHHUAWPYXKBD-IEOSBIPESA-N 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/061—Use of materials for tobacco smoke filters containing additives entrapped within capsules, sponge-like material or the like, for further release upon smoking
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/002—Cigars; Cigarettes with additives, e.g. for flavouring
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D1/00—Cigars; Cigarettes
- A24D1/02—Cigars; Cigarettes with special covers
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/04—Tobacco smoke filters characterised by their shape or structure
-
- A—HUMAN NECESSITIES
- A24—TOBACCO; CIGARS; CIGARETTES; SIMULATED SMOKING DEVICES; SMOKERS' REQUISITES
- A24D—CIGARS; CIGARETTES; TOBACCO SMOKE FILTERS; MOUTHPIECES FOR CIGARS OR CIGARETTES; MANUFACTURE OF TOBACCO SMOKE FILTERS OR MOUTHPIECES
- A24D3/00—Tobacco smoke filters, e.g. filter-tips, filtering inserts; Filters specially adapted for simulated smoking devices; Mouthpieces for cigars or cigarettes
- A24D3/06—Use of materials for tobacco smoke filters
- A24D3/14—Use of materials for tobacco smoke filters of organic materials as additive
Description
本發明係關於含有香料膠囊之香煙用過濾器以及香煙。The present invention relates to a filter for cigarettes containing a flavor capsule and a cigarette.
以往,於香煙用濾嘴裝入香料膠囊,而在使用時讓香料膠囊破碎以在吸煙時享受內容液的香味,且遮蔽(masking)熄火後的煙蒂之味道(專利文獻1至專利文獻5)。有關香料膠囊之細節係記載在例如專利文獻6。含有此等香料膠囊之香煙用過濾器存有各種問題。Conventionally, a flavor capsule is placed in a cigarette filter, and the flavor capsule is broken at the time of use to enjoy the flavor of the content liquid at the time of smoking, and the taste of the butt after the flameout is masked (Patent Documents 1 to 5) . Details of the flavor capsule are described, for example, in Patent Document 6. Filters for cigarettes containing such perfume capsules have various problems.
第1圖(a)表示一種香煙,其係以外層紙(chip paper)30連接煙草棒10與過濾器20,該煙草棒10為以捲紙12捲包煙草充填物11而成者,且該過濾器20為以捲繞紙23捲包埋入香料膠囊21之過濾器插塞(Filter Plug)22而成者。香料膠囊21具有以皮膜21a包入內容液21b之構造。此等香煙在吸煙時若壓碎香料膠囊21之皮膜21a,則如第1圖(b)所示,流出的內容液21b會被過濾器插塞22吸收,而不會滲出至外層紙30之表面。但壓碎埋入在過濾器插塞22之香料膠囊21時並無觸感,故使用感較差。Fig. 1(a) shows a cigarette which is a chip paper 30 which is connected to a tobacco rod 10 and a filter 20 which is formed by wrapping a tobacco filler 11 with a roll paper 12, and The filter 20 is a filter plug 22 in which a fragrance capsule 21 is wrapped in a wound paper 23 . The fragrance capsule 21 has a structure in which the content liquid 21b is wrapped in the film 21a. When the cigarettes crush the film 21a of the fragrance capsule 21 during smoking, as shown in Fig. 1(b), the discharged content liquid 21b is absorbed by the filter plug 22 without oozing out to the outer paper 30. surface. However, when the fragrance capsule 21 embedded in the filter plug 22 is crushed, there is no feeling of touch, so that the feeling of use is poor.
因此,使複數個過濾器插塞彼此分離而隔著中空部配置,並在該中空部設置香料膠囊,若為具有此構造之過濾器,則在壓碎香料膠囊時有觸感,故使用感較佳。Therefore, a plurality of filter plugs are separated from each other and disposed along the hollow portion, and a fragrance capsule is provided in the hollow portion. If the filter has such a configuration, the capsule is crushed when the capsule is crushed, so that the feeling of use is obtained. Preferably.
第2圖(a)表示一種香煙,其係以外層紙30連接煙草棒10與過濾器20,該煙草棒10為以捲紙12捲包香煙充填物11而成者,且該過濾器20具有在兩個過濾器插塞25間之中空部設置香料膠囊21之構造。在兩個過濾器插塞25之周圍捲有原料紙26,在兩者互相分離而隔著中空部配置之周圍捲有成形紙27。此外,亦存在有缺少原料紙與成形紙之任一者或兩者的過濾器插塞(第1圖的情形係僅為兼作原料紙與成形紙之捲繞紙)。因通常之成形紙係以穿透性高的原料所製作,故此等香煙在吸煙時若壓碎香料膠囊21之皮膜21a,則如第2圖(b)所示,流出的內容液21b會滲出至外層紙30之表面。Fig. 2(a) shows a cigarette in which the outer layer paper 30 is connected to the tobacco rod 10 and the filter 20, and the tobacco rod 10 is formed by wrapping the cigarette filling 11 with the roll paper 12, and the filter 20 has The configuration of the fragrance capsule 21 is provided in the hollow portion between the two filter plugs 25. The raw paper 26 is wound around the two filter plugs 25, and the forming paper 27 is wound around the hollow portion so as to be separated from each other. Further, there is also a filter plug which lacks either or both of the raw material paper and the formed paper (the case of Fig. 1 is only a winding paper which also serves as a raw material paper and a forming paper). Since the usual forming paper is made of a material having high penetrability, if the cigarette 21 is crushed by the film 21a of the fragrance capsule 21 during smoking, as shown in Fig. 2(b), the discharged content liquid 21b will seep out. To the surface of the outer paper 30.
為了抑制內容液滲出至外層紙表面,可考慮使用非液體穿透性之外層紙及/或過濾器包材(Filter wrapper)(原料紙、成形紙、捲繞紙)。此等之原料並不限定為紙,亦可為玻璃紙(cellophane)、塑膠製包材(wrap)或該等之複合原料。將成形紙27設為非液體穿透性時,如第2圖(c)所示,流出的內容液21b會沿著非液體穿透性成形紙27的內側與過濾器插塞25之間隙,往煙草棒10與吸口端之方向移動。接著,最後經由煙草棒10之煙草充填物11而滲出至較外層紙30更靠近煙草棒10側之捲紙12。在吸口端的方向,會發生沿著成形紙27的內側與過濾器插塞25之間隙滲出至過濾器插塞25的端面之情形。In order to suppress the bleeding of the content liquid to the surface of the outer layer, it is conceivable to use a non-liquid penetrating outer layer paper and/or a filter wrapper (raw material paper, forming paper, wound paper). These raw materials are not limited to paper, and may be cellophane, plastic wrap or composite materials thereof. When the forming paper 27 is made non-liquid penetrating, as shown in FIG. 2(c), the outflowing content liquid 21b is along the gap between the inside of the non-liquid penetrating forming paper 27 and the filter plug 25. Move toward the tobacco rod 10 and the mouth end. Then, finally, the tobacco filler 11 of the tobacco rod 10 is exuded to the roll paper 12 closer to the tobacco rod 10 side than the outer paper 30. In the direction of the mouth end, a situation occurs in which the end face of the filter plug 25 is oozing out along the gap between the inside of the forming paper 27 and the filter plug 25.
此問題可藉由在非液體穿透性之成形紙27的內側塗覆蠟或糊,以將成形紙27的內側與過濾器插塞25之間隙塞滿,而可防止內容液21b沿著間隙流動。但因蠟或糊的垢附著於過濾器製造裝置,使量產化變得困難。This problem can be prevented by applying a wax or a paste on the inner side of the non-liquid penetrating forming paper 27 to fill the gap between the inner side of the forming paper 27 and the filter plug 25, thereby preventing the content liquid 21b from flowing along the gap. flow. However, since the wax or the paste scale adheres to the filter manufacturing apparatus, mass production becomes difficult.
[專利文獻1] 日本特開平7-250665號[Patent Document 1] Japanese Patent Laid-Open No. 7-250665
[專利文獻2] 日本特開平2003-304856號[Patent Document 2] Japanese Patent Laid-Open No. 2003-304856
[專利文獻3] 日本特開平2007-520204號[Patent Document 3] Japanese Patent Laid-Open No. 2007-520204
[專利文獻4] 日本特開平2008-528053號[Patent Document 4] Japanese Patent Laid-Open No. 2008-528053
[專利文獻5] 日本特開平2008-539717號[Patent Document 5] Japanese Patent Laid-Open No. 2008-539717
[專利文獻6] 日本特開平2008-546400號[Patent Document 6] Japanese Patent Laid-Open No. 2008-546400
本發明之目的係提供一種含有香料膠囊之香煙用過濾器以及具有此香煙用過濾器之香煙,該香煙用過濾器在製造過濾器中不會產生問題,使用時可防止內容液滲出至外層紙之表面、煙草棒之捲紙及過濾器吸口端面。An object of the present invention is to provide a filter for a cigarette containing a fragrance capsule, and a cigarette having the same, which does not cause a problem in the manufacture of a filter, and prevents the content liquid from oozing out to the outer layer when used. The surface, the tobacco rod roll paper and the filter suction end face.
根據本發明可提供一種香煙用過濾器,其具有:互相分離而隔著中空部所配置之複數個過濾器插塞;設置在前述複數個過濾器插塞間之中空部,且在皮膜內保持含有香料之內容液的香料膠囊;以及在前述過濾器插塞及香料膠囊周圍所捲之非液體穿透性外層紙及/或過濾器包材(原料紙、成形紙或捲繞紙)。前述內容液含有香料與增黏劑,且具有30mPa‧s以上的黏度。According to the present invention, there is provided a filter for a cigarette comprising: a plurality of filter plugs disposed apart from each other across a hollow portion; and a hollow portion disposed between the plurality of filter plugs and held in the film a fragrance capsule containing a fragrance-containing content liquid; and a non-liquid penetrating outer layer paper and/or a filter package (raw paper, formed paper or wound paper) wound around the filter plug and the fragrance capsule. The above liquid contains a fragrance and a tackifier, and has a viscosity of 30 mPa·s or more.
此外,根據本發明可提供一種香煙,其具有煙草棒與上述香煙用過濾器。Further, according to the present invention, there can be provided a cigarette having a tobacco rod and the above-described filter for cigarettes.
本發明之香煙用過濾器及香煙,係藉由在香料膠囊之內容液添加增黏劑使內容液的黏度在30mPa‧s以上,而可防止使用時內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面。In the filter for cigarettes and the cigarette of the present invention, by adding a tackifier to the content liquid of the flavor capsule, the viscosity of the content liquid is 30 mPa ‧ s or more, thereby preventing the content liquid from oozing out to the surface of the outer paper and the tobacco rod during use. Roll paper and filter suction end face.
本發明之香煙用過濾器中,設置在複數過濾器插塞間之中空部之香料膠囊的內容液含有香料與增黏劑,且具有30mPa‧s(25℃)以上之黏度。In the filter for cigarettes of the present invention, the content liquid of the flavor capsule provided in the hollow portion between the plurality of filter plugs contains a fragrance and a tackifier, and has a viscosity of 30 mPa ‧ (25 ° C) or more.
本發明中,內容液的黏度未達30mPa‧s(25℃),特別是未達18mPa‧s(25℃)時,在壓碎香料膠囊時,內容液會滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面。內容液的黏度較佳為在30mPa‧s(25℃)以上,更佳為在80mPa‧s(25℃)以上。In the present invention, the viscosity of the content liquid is less than 30 mPa ‧ (25 ° C), especially when it is less than 18 mPa ‧ (25 ° C), when the flavor capsule is crushed, the content liquid will ooze out to the surface of the outer paper, the tobacco rod Roll paper and filter suction end face. The viscosity of the content liquid is preferably 30 mPa ‧ (25 ° C) or more, more preferably 80 mPa ‧ (25 ° C) or more.
本發明中,香料可使用例如薄荷醇、植物精油等。In the present invention, for example, menthol, plant essential oil or the like can be used as the fragrance.
本發明中,添加在香料膠囊內容液的增黏劑可使用液體增黏劑或固體增黏劑。液體增黏劑係可使用油脂、例如生育酚(tocopherol)、菜籽油、橄欖油、棉籽油、或蔗糖二乙酸酯六異丁酸酯(SAIB)等。其中更佳為菜籽油或SAIB。In the present invention, a liquid tackifier or a solid tackifier may be used as the tackifier added to the perfume capsule content liquid. As the liquid tackifier, a fat or oil such as tocopherol, rapeseed oil, olive oil, cottonseed oil, or sucrose diacetate hexaisobutyrate (SAIB) or the like can be used. More preferably, it is rapeseed oil or SAIB.
使用油脂作為增黏劑時,較佳為在內容液之19.1至57.4重量%的範圍內。使用SAIB作為增黏劑時,較佳為在內容液之40重量%以上,更佳為在60重量%以上。When fats and oils are used as the tackifier, it is preferably in the range of 19.1 to 57.4% by weight of the content liquid. When SAIB is used as the tackifier, it is preferably 40% by weight or more, more preferably 60% by weight or more based on the content liquid.
本發明中,內容液所含的香料及增黏劑之溶媒可使用例如中鏈脂肪酸三酸甘油酯(MCT)。In the present invention, for example, a medium chain fatty acid triglyceride (MCT) can be used as a solvent for the fragrance and the tackifier contained in the content liquid.
本發明中,內容液復可含有溶媒、色素、乳化劑等其他添加劑。In the present invention, the content liquid may contain other additives such as a solvent, a coloring matter, and an emulsifier.
本發明中,香料膠囊的皮膜可使用例如澱粉、糊精(dextrin)、多醣類、寒天、結冷膠(Gellan gum)、明膠、各種天然膠化劑、甘油、山梨糖醇(sorbito)、氯化鈣等,復可含有香料或著色料。In the present invention, the film of the flavor capsule may be, for example, starch, dextrin, polysaccharide, cold weather, gellan gum, gelatin, various natural gelling agents, glycerin, sorbito, Calcium chloride, etc., may contain a fragrance or a coloring material.
本發明中,外層紙及/或過濾器包材(原料紙、成形紙或捲繞紙)為非液體穿透性,係指此等材料亦具有耐油性。至少外層紙及/或過濾器包材中之與香料膠囊21直接接觸之例如成形紙27較佳為使用耐油紙。耐油性材料中,較佳為例如日本製紙PAPYLIA股份有限公司製之耐油紙,因其不使用薄膜及氟樹脂。將日本製紙PAPYLIA股份有限公司製之耐油紙的特性顯示於表1。In the present invention, the outer paper and/or the filter wrap (raw paper, formed paper or wound paper) are non-liquid penetrating, meaning that these materials also have oil resistance. Preferably, at least the forming paper 27 of the outer paper and/or filter package in direct contact with the perfume capsule 21 is a grease resistant paper. Among the oil-resistant materials, for example, an oil-resistant paper made by Nippon Paper PAPYLIA Co., Ltd. is used because it does not use a film or a fluororesin. The characteristics of the oil-resistant paper made by Nippon Paper PAPYLIA Co., Ltd. are shown in Table 1.
本發明中,香料膠囊除了設置在複數個過濾器插塞間之中空部以外,亦可如第1圖所示埋入在過濾器插塞中。In the present invention, the fragrance capsule may be embedded in the filter plug as shown in Fig. 1 except that it is provided in a hollow portion between the plurality of filter plugs.
此外,本發明之香料膠囊可適用在口嚼香煙、口含煙(SNUS)、國際出願PCT/JP2010/052835所記載之非燃燒香味吸引煙管等。Further, the perfume capsule of the present invention can be applied to a non-flammable flavor-sucking pipe or the like described in a chewing cigarette, a mouth-containing cigarette (SNUS), and an international pledge PCT/JP2010/052835.
以下說明本發明之實施例。Embodiments of the invention are described below.
第3圖為表示本實施例所製作之香煙用過濾器的尺寸之斜視圖。在醋酸鹽所構成之煙草棒側及吸口側的兩個過濾器棒25的周圍捲有原料紙(未圖示)。兩個過濾器棒25係互相分離而隔著中空部所配置,並在其周圍捲有非液體穿透性(耐油性)之成形紙27。在兩個過濾器棒25間的中空部配置有香料膠囊21。香料膠囊21具有以皮膜21a包入內容液21b之構造。煙草棒側之過濾器棒25之長度L1為11.0mm,吸口側之過濾器桿25之長度L2為10.0mm,中空部之長度S為6.0mm,全長TL為27.0mm,香料膠囊21之直徑D為4.5mm。本發明中,香料膠囊21之內容液21b具有30mPa‧s以上的黏度。Fig. 3 is a perspective view showing the size of the filter for cigarettes produced in the present embodiment. Raw material paper (not shown) is wound around the two filter rods 25 on the tobacco rod side and the suction side of the acetate. The two filter rods 25 are separated from each other and disposed along the hollow portion, and a non-liquid penetrating (oil-resistant) forming paper 27 is wound around the two. A fragrance capsule 21 is disposed in a hollow portion between the two filter rods 25. The fragrance capsule 21 has a structure in which the content liquid 21b is wrapped in the film 21a. The length L1 of the filter rod 25 on the tobacco rod side is 11.0 mm, the length L2 of the filter rod 25 on the suction side is 10.0 mm, the length S of the hollow portion is 6.0 mm, the total length TL is 27.0 mm, and the diameter D of the fragrance capsule 21 It is 4.5mm. In the present invention, the content liquid 21b of the fragrance capsule 21 has a viscosity of 30 mPa ‧ or more.
香料膠囊的製造方法並無特別限制,較佳為使用例如滴下法,即可製造具有無接縫皮膜之香料膠囊。此方法係使用雙重噴嘴,藉由從內側噴嘴吐出內容液同時從外側噴嘴吐出液狀之皮膜物質,皮膜液可無接縫地將內容液包入。The method for producing the flavor capsule is not particularly limited, and it is preferred to use a dropping method to produce a flavor capsule having a seamless film. In this method, a double nozzle is used, and by discharging the content liquid from the inner nozzle and discharging the liquid film material from the outer nozzle, the film liquid can be wrapped without a seam.
如第4圖所示,本實施例之香煙用過濾器中,因香料膠囊21的內容液21b之黏度在30mPa‧s(25℃)以上,故壓碎香料膠囊21的皮膜21a時,可抑制流出之內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面。此外,並不會對過濾器製造裝置造成不良影響。As shown in Fig. 4, in the filter for cigarettes of the present embodiment, since the viscosity of the content liquid 21b of the fragrance capsule 21 is 30 mPa ‧ (25 ° C) or more, when the film 21a of the fragrance capsule 21 is crushed, it can be suppressed. The discharged content liquid oozes out to the surface of the outer paper, the roll of the tobacco rod, and the end face of the filter suction port. In addition, it does not adversely affect the filter manufacturing apparatus.
例1example 1
準備作為香料之薄荷醇及植物精油及作為溶媒之中鏈脂肪酸三酸甘油酯(MCT)(無增黏劑),以表2樣品A至C的比例混合,以調製香料膠囊之內容液。以迴轉式黏度計(東機產業(股)TVB-10M)測定內容液的黏度。It is prepared as a spice menthol and plant essential oil and as a solvent medium chain fatty acid triglyceride (MCT) (no tackifier), and mixed in the ratio of Samples A to C of Table 2 to prepare a content liquid of the flavor capsule. The viscosity of the content liquid was measured by a rotary viscometer (Tokyo Industry Co., Ltd. TVB-10M).
將作為皮膜物質之澱粉、糊精及多醣類混合物8重量%或20重量%、與上述內容液92重量%或80重量%予以混合,並以滴下法製作直徑4.5mm之香料膠囊。使用此香料膠囊來製造如第3圖所示之香煙用過濾器,復製造與第2圖(a)相同之香煙。The starch, dextrin, and polysaccharide mixture as a coating material was mixed with 8% by weight or 20% by weight, and 92% by weight or 80% by weight of the above-mentioned content liquid, and a perfume capsule having a diameter of 4.5 mm was produced by a dropping method. Using the fragrance capsule, a cigarette filter as shown in Fig. 3 was produced, and the same cigarette as in Fig. 2(a) was produced.
例2Example 2
準備作為香料之薄荷醇及植物精油、作為溶媒之中鏈脂肪酸三酸甘油酯(MCT)、及作為增黏劑之菜籽油,以表2樣品D至H的比例混合,以調製香料膠囊之內容液。以迴轉式黏度計(東機產業(股)TVB-10M)測定內容液的黏度。Prepared as a spice menthol and plant essential oil, as a solvent medium chain fatty acid triglyceride (MCT), and as a tackifier rapeseed oil, mixed in the ratio of Table 2 samples D to H to prepare a flavor capsule Content liquid. The viscosity of the content liquid was measured by a rotary viscometer (Tokyo Industry Co., Ltd. TVB-10M).
將作為皮膜物質之澱粉、糊精及多醣類混合物8重量%或20重量%、與上述內容液92重量%或80重量%予以混合,並以滴下法製作直徑4.5mm之香料膠囊。使用此香料膠囊來製造如第3圖所示之香煙用過濾器,復製造與第2圖(a)相同之香煙。The starch, dextrin, and polysaccharide mixture as a coating material was mixed with 8% by weight or 20% by weight, and 92% by weight or 80% by weight of the above-mentioned content liquid, and a perfume capsule having a diameter of 4.5 mm was produced by a dropping method. Using the fragrance capsule, a cigarette filter as shown in Fig. 3 was produced, and the same cigarette as in Fig. 2(a) was produced.
例3Example 3
準備作為香料之薄荷醇及植物精油、作為溶媒之中鏈脂肪酸三酸甘油酯(MCT)、及作為增黏劑之蔗糖二乙酸酯六異丁酸酯(SAIB),以表2樣品I至K的比例混合,以調製香料膠囊之內容液。以迴轉式黏度計(東機產業(股)TVB-10M)測定內容液的黏度。Prepared as a spice menthol and plant essential oil, as a solvent medium chain fatty acid triglyceride (MCT), and as a tackifier sucrose diacetate hexaisobutyrate (SAIB), as shown in Table 2, sample I The ratio of K is mixed to prepare the content liquid of the flavor capsule. The viscosity of the content liquid was measured by a rotary viscometer (Tokyo Industry Co., Ltd. TVB-10M).
將作為皮膜物質之澱粉、糊精及多醣類混合物20重量%、與上述內容液80重量%予以混合,並以滴下法製作直徑4.5mm之香料膠囊。使用此香料膠囊來製造如第3圖所示之香煙用過濾器,復製造與第2圖(a)相同之香煙。20% by weight of a mixture of a starch, a dextrin and a polysaccharide as a coating material, and 80% by weight of the above-mentioned content liquid, and a perfume capsule having a diameter of 4.5 mm was produced by a dropping method. Using the fragrance capsule, a cigarette filter as shown in Fig. 3 was produced, and the same cigarette as in Fig. 2(a) was produced.
針對上述樣品A至K之香煙,將其香料膠囊之皮膜壓碎10分鐘後,調查其內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面的情形。將其結果一併記於表2。With respect to the cigarettes of the above samples A to K, the film of the fragrance capsule was crushed for 10 minutes, and then the content liquid was infiltrated to the surface of the outer layer paper, the roll of the tobacco rod, and the end face of the filter suction port. The results are shown in Table 2.
從表2的結果得知,若香料膠囊之內容液的黏度在30mPa‧s(25℃)以上,則可抑制其內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面。此外,可知若香料膠囊之內容液的黏度在80mPa‧s(25℃)以上,則可更確實地抑制其內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面。As is apparent from the results of Table 2, when the viscosity of the content liquid of the flavor capsule is 30 mPa ‧ (25 ° C) or more, the content liquid can be prevented from oozing out to the surface of the outer layer paper, the roll of the tobacco rod, and the end face of the filter suction port. Further, it is understood that when the viscosity of the content liquid of the flavor capsule is 80 mPa ‧ (25 ° C) or more, it is possible to more reliably suppress the bleeding of the content liquid to the surface of the outer layer paper, the roll of the tobacco rod, and the end face of the filter nozzle.
例4Example 4
上述例1至3之實驗中,調查將香料膠囊之皮膜壓碎,在通常吸煙時間之10分鐘之內,其內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面的情形。但較佳為將香料膠囊之皮膜壓碎後,經過長時間其內容液亦不會滲出至煙草棒的捲紙。以如下之方式調查經過長時間後內容液滲出的情形。此外,以下實驗中膠囊之內容液未含有香料。In the experiments of the above Examples 1 to 3, it was investigated that the film of the perfume capsule was crushed, and within 10 minutes of the usual smoking time, the content liquid oozes out to the surface of the outer paper, the roll of the tobacco rod, and the end face of the filter suction port. . However, it is preferred that after the film of the flavor capsule is crushed, the content liquid does not ooze out to the roll of the tobacco rod after a long period of time. The case where the content liquid oozes after a long time is investigated in the following manner. Further, in the following experiment, the content liquid of the capsule did not contain a fragrance.
樣品LSample L
膠囊之內容液只使用作為溶媒之中鏈脂肪酸三酸甘油酯(MCT)。The content of the capsule is only used as a solvent medium chain fatty acid triglyceride (MCT).
樣品MSample M
將作為溶媒之中鏈脂肪酸三酸甘油酯(MCT)43重量%及作為增黏劑之菜籽油57重量%予以混合,以調製膠囊之內容液。The content of the capsule was prepared by mixing 43% by weight of a chain medium fatty acid triglyceride (MCT) and 57% by weight of rapeseed oil as a tackifier.
樣品N、O、PSample N, O, P
將作為溶媒之中鏈脂肪酸三酸甘油酯(MCT)60重量%、50重量%或40重量%、與作為增黏劑之SAIB 40重量%、50重量%或60重量%予以混合,以調製膠囊之內容液。60% by weight, 50% by weight or 40% by weight of the medium chain fatty acid triglyceride (MCT) as a solvent, and 40% by weight, 50% by weight or 60% by weight of SAIB as a tackifier to prepare a capsule The content of the liquid.
以迴轉式黏度計(東機產業(股)TVB-10M)測定此等內容液的黏度。將膠囊內容液的組成及黏度表示於表3。The viscosity of these contents was measured by a rotary viscometer (Dongji Industry Co., Ltd. TVB-10M). The composition and viscosity of the capsule content liquid are shown in Table 3.
將作為皮膜物質之澱粉、糊精及多醣類混合物以20重量%、與上述內容液80重量%予以混合,並以滴下法製作直徑4.5mm之香料膠囊。使用此香料膠囊來製造如第3圖所示之香煙用過濾器,復製造與第2圖(a)相同之香煙。The starch, dextrin, and polysaccharide mixture as a coating material was mixed at 20% by weight with 80% by weight of the above-mentioned content liquid, and a perfume capsule having a diameter of 4.5 mm was produced by a dropping method. Using the fragrance capsule, a cigarette filter as shown in Fig. 3 was produced, and the same cigarette as in Fig. 2(a) was produced.
針對上述樣品L至P之香煙,將其香料膠囊之皮膜壓碎一星期後,調查其內容液滲出至煙草棒的捲紙的情形。此時,內容液滲出的長度係指測定由連接於一方的過濾器插塞25之煙草棒10的末端至內容液滲出至捲紙所達之位置為止之長度。將其結果一併記於表3。With respect to the cigarettes of the above samples L to P, the film of the flavor capsule was crushed for one week, and then the content liquid was oozing out to the roll of the tobacco rod. At this time, the length of the content liquid oozing refers to the length measured from the end of the tobacco rod 10 connected to one of the filter plugs 25 to the position at which the content liquid oozes to the roll paper. The results are shown in Table 3.
此外,第5圖為表示樣品M至P之內容液的黏度與內容液滲出長度之關係的曲線圖。Further, Fig. 5 is a graph showing the relationship between the viscosity of the content liquid of the samples M to P and the bleeding length of the content liquid.
如表3所示,未含增黏劑之樣品L之情形,所調查之10支全部在一星期後之內容液滲出長度係達57mm,內容液則達煙草棒前端的捲紙。對此,使用菜籽油或SAIB作為增黏劑之情形,即使在一星期後,其內容液亦不會達煙草棒前端的捲紙。此外,由表3及第5圖得知,即使內容液之黏度相同,SAIB之內容液的滲出長度較菜籽油為短。As shown in Table 3, in the case of the sample L containing no tackifier, all of the 10 samples investigated had a leaching length of 57 mm after one week, and the content liquid reached the roll paper at the front end of the tobacco rod. In this case, when rapeseed oil or SAIB is used as the tackifier, even after one week, the content liquid does not reach the roll paper at the front end of the tobacco rod. Further, as is apparent from Tables 3 and 5, even if the viscosity of the content liquid is the same, the exudation length of the SAIB content liquid is shorter than that of the rapeseed oil.
當內容液之滲出長度長時,會有浸透於捲紙之內容液的成分會因紙層析(paper chromatography)現象而分離之問體。對此,作為增黏劑之含有SAIB的內容液,因其一星期後滲出長度短,故可抑制因紙層析現象所造成之內容液成分之分離。When the exudation length of the content liquid is long, the components which are soaked in the contents of the roll paper are separated by a paper chromatography phenomenon. On the other hand, since the SAIB-containing content liquid as the tackifier has a short exudation length after one week, separation of the content liquid component due to the paper chromatography phenomenon can be suppressed.
10...煙草棒10. . . Tobacco stick
11...充填物11. . . Filling
12...捲紙12. . . Roll paper
20...過濾器20. . . filter
21...香料膠囊twenty one. . . Spice capsule
21a...皮膜21a. . . Film
21b...內容液21b. . . Content liquid
22、25...過濾器插塞22, 25. . . Filter plug
23...捲繞紙twenty three. . . Winding paper
26...原料紙26. . . Raw paper
27...成形27. . . Forming
30...外層紙30. . . Outer paper
D...直徑D. . . diameter
L1、L2...長度L1, L2. . . length
S...中空部之長度S. . . Length of hollow
TL...全長TL. . . full length
第1圖為埋入在習知之香煙用過濾器之香料膠囊的內容液被過濾器插塞吸收之說明圖。Fig. 1 is an explanatory view showing that the content liquid of the flavor capsule embedded in the conventional cigarette filter is absorbed by the filter plug.
第2圖為習知其他的香煙用過濾器中之香料膠囊的內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面之說明圖。Fig. 2 is an explanatory view showing the contents of the flavor capsule of the conventional cigarette filter oozing out to the surface of the outer layer paper, the roll of the tobacco rod, and the end face of the filter nozzle.
第3圖為本發明實施例之香煙用過濾器之分解斜視圖。Fig. 3 is an exploded perspective view showing the filter for cigarettes according to the embodiment of the present invention.
第4圖為本發明實施例之香煙用過濾器中,可抑制香料膠囊之內容液滲出至外層紙的表面、煙草棒的捲紙及過濾器吸口端面的情形之說明圖。Fig. 4 is an explanatory view showing a state in which the content of the fragrance capsule oozes out to the surface of the outer layer paper, the roll of the tobacco rod, and the end face of the filter suction port in the filter for cigarettes according to the embodiment of the present invention.
第5圖為本發明實施例之香煙用過濾器中之香料膠囊之內容液的黏度、與將香料膠囊之皮膜壓碎一星期後其內容液滲出至捲紙的長度之關係曲線圖。Fig. 5 is a graph showing the relationship between the viscosity of the content liquid of the flavor capsule in the filter for cigarettes of the embodiment of the present invention and the length of the content liquid permeating to the roll paper after crushing the film of the flavor capsule for one week.
21a...皮膜21a. . . Film
21b...內容液21b. . . Content liquid
25...過濾器插塞25. . . Filter plug
27...成形27. . . Forming
D...直徑D. . . diameter
L1、L2...長度L1, L2. . . length
S...中空部之長度S. . . Length of hollow
TL...全長TL. . . full length
Claims (4)
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
JP2010125222 | 2010-05-31 |
Publications (2)
Publication Number | Publication Date |
---|---|
TW201204275A TW201204275A (en) | 2012-02-01 |
TWI474784B true TWI474784B (en) | 2015-03-01 |
Family
ID=45066683
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
TW100118954A TWI474784B (en) | 2010-05-31 | 2011-05-31 | Filter for cigarette and cigarette |
Country Status (12)
Country | Link |
---|---|
US (1) | US20130081644A1 (en) |
EP (1) | EP2578093B1 (en) |
JP (1) | JP5487300B2 (en) |
KR (1) | KR101450424B1 (en) |
CN (2) | CN102933104A (en) |
CA (1) | CA2801198C (en) |
HK (1) | HK1216592A1 (en) |
MY (1) | MY158242A (en) |
RU (1) | RU2550333C2 (en) |
TW (1) | TWI474784B (en) |
UA (1) | UA103859C2 (en) |
WO (1) | WO2011152316A1 (en) |
Families Citing this family (31)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
KR101589390B1 (en) * | 2011-08-05 | 2016-01-27 | 니뽄 다바코 산교 가부시키가이샤 | Cigarette |
KR20140116531A (en) * | 2012-01-25 | 2014-10-02 | 니뽄 다바코 산교 가부시키가이샤 | Fragrance composition for improving breath having smell of cigarettes |
MY171787A (en) * | 2012-02-21 | 2019-10-29 | Jt Int Sa | Smoking article filter |
WO2013179428A1 (en) * | 2012-05-30 | 2013-12-05 | 日本たばこ産業株式会社 | Cigarette and packaging members |
ES2821430T3 (en) * | 2012-05-30 | 2021-04-26 | Japan Tobacco Inc | Cigarette |
MX363927B (en) * | 2012-08-06 | 2019-04-08 | Philip Morris Products Sa | Method of forming smoking articles with mouth end cavities. |
SG11201500860VA (en) * | 2012-08-06 | 2015-03-30 | Philip Morris Products Sa | Smoking article with mouth end cavity |
PL2978327T3 (en) | 2013-03-28 | 2019-06-28 | Philip Morris Products S.A. | Smoking article including a flavour delivery member |
TWI654942B (en) * | 2013-05-14 | 2019-04-01 | 瑞士商菲利浦莫里斯製品股份有限公司 | Tobacco containing liquid transfer member and cladding material |
WO2015035137A1 (en) * | 2013-09-05 | 2015-03-12 | Schweitzer-Mauduit International, Inc. | Coated plug wrap for a smoking article |
WO2015075804A1 (en) * | 2013-11-21 | 2015-05-28 | 日本たばこ産業株式会社 | Cigarette |
KR102504427B1 (en) | 2013-12-20 | 2023-03-02 | 필립모리스 프로덕츠 에스.에이. | Smoking article having a filter including a capsule |
JP6629294B2 (en) * | 2014-07-31 | 2020-01-15 | ジェイティー インターナショナル エス.エイ. | Filter elements for smoking articles |
GB201503388D0 (en) | 2015-02-27 | 2015-04-15 | British American Tobacco Co | A smoking article and filter unit thereof |
GB201503389D0 (en) * | 2015-02-27 | 2015-04-15 | British American Tobacco Co | A smoking article and filter unit therefor |
JP6236408B2 (en) * | 2015-03-04 | 2017-11-22 | 日本たばこ産業株式会社 | cigarette |
TW201701779A (en) * | 2015-07-01 | 2017-01-16 | 菲利浦莫里斯製品股份有限公司 | Hydrophobic smoking article tube |
TW201711575A (en) * | 2015-08-13 | 2017-04-01 | 菲利浦莫里斯製品股份有限公司 | Flavor capsules for smoking articles |
WO2017036586A1 (en) | 2015-08-28 | 2017-03-09 | Jt International S.A. | Smoking article |
EP3340816B1 (en) * | 2015-08-28 | 2020-04-15 | JT International S.A. | Smoking article |
CN107772530B (en) * | 2016-08-24 | 2022-06-21 | 贵州中烟工业有限责任公司 | Composite cigarette filter tip for improving cigarette taste and application |
CN110392533B (en) * | 2017-04-03 | 2022-04-08 | 菲利普莫里斯生产公司 | Smoking article mouthpiece configured to receive an insertion unit |
GB201715924D0 (en) * | 2017-09-29 | 2017-11-15 | British American Tobacco Investments Ltd | A filter unit for a smoking article |
EA039292B1 (en) * | 2017-10-03 | 2021-12-29 | Джапан Тобакко Инк. | Filtered smoking article |
GB201717569D0 (en) * | 2017-10-25 | 2017-12-06 | British American Tobacco Investments Ltd | A filter for a smoking article or an aerosol generating product |
KR102190097B1 (en) * | 2018-04-04 | 2020-12-11 | 이정수 | Manufacturing method of flavor filter |
CN108652078A (en) * | 2018-06-29 | 2018-10-16 | 中国烟草总公司郑州烟草研究院 | A kind of quick-fried pearl cigarette with hollow cavity |
KR102022909B1 (en) * | 2019-06-19 | 2019-09-19 | 주식회사 케이티앤지 | A smoking article with technology modifying sidestream and a smoking article case including the same |
CN110552248A (en) * | 2019-06-25 | 2019-12-10 | 浙江友丰包装材料有限公司 | Antibacterial breathable tipping paper and production process thereof |
CN114245712A (en) * | 2019-09-06 | 2022-03-25 | 菲利普莫里斯生产公司 | Aerosol-generating device with sealing element in cavity |
EP4223506A1 (en) * | 2020-10-02 | 2023-08-09 | Japan Tobacco Inc. | Tip paper for tobacco products with capsule filters and tobacco products |
Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008539717A (en) * | 2005-05-03 | 2008-11-20 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Cigarette with filterable flavor capsule, filter subassembly and manufacturing method |
JP2008546400A (en) * | 2005-06-21 | 2008-12-25 | ヴェ. マヌ フィル | Smoking device incorporating a collapsible capsule, collapsible capsule, and method of manufacturing the capsule |
WO2009094859A1 (en) * | 2008-01-25 | 2009-08-06 | Rj Reynolds Tobacco Company | Process for manufacturing breakable capsules useful in tobacco products |
Family Cites Families (15)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US3635226A (en) * | 1969-06-16 | 1972-01-18 | British American Tobacco Co | Tobacco-smoke filters |
GB1528657A (en) * | 1975-03-13 | 1978-10-18 | Riso Kagaku Corp | Stencil paper assembly |
US5746231A (en) * | 1993-01-11 | 1998-05-05 | Craig Lesser | Tobacco smoke filter for removing toxic compounds |
AU675573B2 (en) | 1993-09-30 | 1997-02-06 | British-American Tobacco Company Limited | Improvements relating to tobacco smoke filter elements |
US7833543B2 (en) * | 1995-06-07 | 2010-11-16 | Durect Corporation | High viscosity liquid controlled delivery system and medical or surgical device |
JP2003204865A (en) * | 2002-01-15 | 2003-07-22 | Ushiwaka Kozo | Container for heaping up food such as confectionery |
BR0313254B1 (en) * | 2002-08-09 | 2012-05-15 | Filter cigarette and methods of reducing the cost of filter cigarette manufacturing and producing filter tip cigarettes. | |
US7836895B2 (en) | 2003-06-23 | 2010-11-23 | R. J. Reynolds Tobacco Company | Filtered cigarette incorporating a breakable capsule |
US20050186261A1 (en) * | 2004-01-30 | 2005-08-25 | Angiotech International Ag | Compositions and methods for treating contracture |
US10285431B2 (en) * | 2004-12-30 | 2019-05-14 | Philip Morris Usa Inc. | Encapsulated flavorant designed for thermal release and cigarette bearing the same |
US7578298B2 (en) | 2005-02-04 | 2009-08-25 | Philip Morris Usa Inc. | Flavor capsule for enhanced flavor delivery in cigarettes |
ATE465650T1 (en) * | 2006-03-10 | 2010-05-15 | British American Tobacco Co | SMOKING ARTICLE FILTER |
GB0804273D0 (en) * | 2008-03-07 | 2008-04-16 | British American Tobacco Co | Plug wrap or tipping papaer for smoking articles |
US8262550B2 (en) * | 2009-03-19 | 2012-09-11 | R. J. Reynolds Tobacco Company | Apparatus for inserting objects into a filter component of a smoking article |
CN202232976U (en) * | 2011-08-26 | 2012-05-30 | 武汉黄鹤楼新材料科技开发有限公司 | Visual filter tip |
-
2011
- 2011-05-27 JP JP2012518366A patent/JP5487300B2/en active Active
- 2011-05-27 CN CN2011800270151A patent/CN102933104A/en active Pending
- 2011-05-27 WO PCT/JP2011/062251 patent/WO2011152316A1/en active Application Filing
- 2011-05-27 CN CN201510333971.2A patent/CN105167184B/en active Active
- 2011-05-27 UA UAA201215131A patent/UA103859C2/en unknown
- 2011-05-27 KR KR1020127030193A patent/KR101450424B1/en active IP Right Grant
- 2011-05-27 CA CA2801198A patent/CA2801198C/en active Active
- 2011-05-27 RU RU2012156836/12A patent/RU2550333C2/en active
- 2011-05-27 MY MYPI2012005170A patent/MY158242A/en unknown
- 2011-05-27 EP EP11789719.9A patent/EP2578093B1/en active Active
- 2011-05-31 TW TW100118954A patent/TWI474784B/en active
-
2012
- 2012-11-29 US US13/689,147 patent/US20130081644A1/en not_active Abandoned
-
2013
- 2013-04-26 HK HK16104380.2A patent/HK1216592A1/en unknown
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2008539717A (en) * | 2005-05-03 | 2008-11-20 | フィリップ・モーリス・プロダクツ・ソシエテ・アノニム | Cigarette with filterable flavor capsule, filter subassembly and manufacturing method |
JP2008546400A (en) * | 2005-06-21 | 2008-12-25 | ヴェ. マヌ フィル | Smoking device incorporating a collapsible capsule, collapsible capsule, and method of manufacturing the capsule |
WO2009094859A1 (en) * | 2008-01-25 | 2009-08-06 | Rj Reynolds Tobacco Company | Process for manufacturing breakable capsules useful in tobacco products |
Also Published As
Publication number | Publication date |
---|---|
CN102933104A (en) | 2013-02-13 |
HK1216592A1 (en) | 2016-11-25 |
KR20130012585A (en) | 2013-02-04 |
JPWO2011152316A1 (en) | 2013-08-01 |
CA2801198A1 (en) | 2011-12-08 |
TW201204275A (en) | 2012-02-01 |
MY158242A (en) | 2016-09-30 |
RU2012156836A (en) | 2014-07-27 |
EP2578093A4 (en) | 2014-05-28 |
CA2801198C (en) | 2016-04-19 |
CN105167184B (en) | 2019-08-23 |
CN105167184A (en) | 2015-12-23 |
WO2011152316A1 (en) | 2011-12-08 |
JP5487300B2 (en) | 2014-05-07 |
US20130081644A1 (en) | 2013-04-04 |
EP2578093B1 (en) | 2018-10-03 |
UA103859C2 (en) | 2013-11-25 |
KR101450424B1 (en) | 2014-10-13 |
RU2550333C2 (en) | 2015-05-10 |
EP2578093A1 (en) | 2013-04-10 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
TWI474784B (en) | Filter for cigarette and cigarette | |
EP3299084B1 (en) | Process for manufacturing capsules useful in tobacco products | |
AU2012334263B2 (en) | Smoking article with liquid delivery material | |
EP2552255B1 (en) | Methods of manufacturing cigarettes and filter subassemblies with squeezable flavor capsule | |
US8424541B2 (en) | Tobacco-free oral flavor delivery pouch product | |
CN105813486B (en) | Smoking product with liquid release component | |
CN103361173B (en) | Preparation method of controllable-releasing and warm-wet-environment-resistance vegetable glue compound cigarette capsule, product obtained and applications thereof | |
CN108024572A (en) | Aerosol generation product with dispersed spices | |
KR20180040568A (en) | Flavor capsules for smoking articles | |
KR20080022127A (en) | Smoking device incorporating a breakable capsule, breakable capsule and process for manufacturing said capsule | |
KR20160105394A (en) | Smoking article with liquid delivery material | |
TW201402025A (en) | Cigarette | |
TWI508671B (en) | "cigarette | |
JP6012291B2 (en) | Cigarette filter and cigarette using the same | |
CN208480600U (en) | A kind of discoloration Three-element composite filter core | |
CN102573812A (en) | Scented capsules | |
KR20170041667A (en) | Moisturized activated carbon for smoking articles |