TWI468547B - Automatic nitroden humidifier controlling system in furance area - Google Patents
Automatic nitroden humidifier controlling system in furance area Download PDFInfo
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- TWI468547B TWI468547B TW99124654A TW99124654A TWI468547B TW I468547 B TWI468547 B TW I468547B TW 99124654 A TW99124654 A TW 99124654A TW 99124654 A TW99124654 A TW 99124654A TW I468547 B TWI468547 B TW I468547B
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Description
本發明係有關一種氮氣加濕自動控制系統,特別是使用於熱浸鍍鋅製程之氮氣加濕系統。The invention relates to a nitrogen humidification automatic control system, in particular to a nitrogen humidification system used in a hot dip galvanizing process.
鋅之電化學特性對於鋼材有犧牲保護之作用,熱浸鍍鋅具有價廉且耐腐蝕性好之特性,廣泛地用於各項工業用途,熱浸鍍鋅鋼片之抗蝕性,主要有兩大特徵:表面薄膜之保護作用與抗蝕作用,熱浸鍍鋅鋼片表面薄膜為緻密的氧化鋅與氫氧化鋅,此會保護底部鋼材使鏽蝕難以侵入破壞鋼材;另一特性是因為鋅的氧化電位較鐵高,所以較鐵易氧化,鋼材周圍之鋅會保護此鋼材,以抑制鋼材之腐蝕。The electrochemical properties of zinc have a sacrificial protective effect on steel. Hot dip galvanizing has the characteristics of low cost and good corrosion resistance. It is widely used in various industrial applications. The corrosion resistance of hot dip galvanized steel sheets is mainly Two major characteristics: the protective effect of the surface film and the anti-corrosion effect. The surface film of the hot dip galvanized steel sheet is dense zinc oxide and zinc hydroxide, which will protect the bottom steel material from rust and invade the steel; another characteristic is because zinc The oxidation potential is higher than that of iron, so it is easier to oxidize than iron. The zinc around the steel will protect the steel to inhibit corrosion of the steel.
參考第1圖,此是一種習知熱浸鍍鋅製程流程示意圖,從進料儲存塔(101)送入之鋼捲(102)進入清洗區(103),可將鋼板表面之油汙、碳化物和鐵粉清洗乾淨,以加強後續製程鋅的鍍覆性與避免汙染物進入鋅浴中,然後再進入連續退火區(104),此階段的溫度鋼材提高至鋼材之再結晶溫度以進行再結晶製程。經過連續退火區(104)之鋼板再以適當的角度與速度浸入鋅槽(105),鋼板表面的高溫會使鋅爐內一部份的鋅液蒸發,而此蒸發的鋅液產生的鋅灰會四處擴散,其中,一部分聚集在爐鼻(106)內,一部分會掉在鋼板上,結果就形成了不規則的細渣,此鋅灰會影響鍍鋅鋼板的品質,而當爐鼻內的濕度升高時,露點溫度會也會升高,露點溫度升高會使鋅槽內的表面鋅液不易蒸發,爐鼻(106)內的內壁就不易產生鋅灰堆積,但是露點溫度太高也會使鋼材表面氧化鋅薄膜厚度增加的太厚,此過厚的氧化鋅膜會造成條狀鋅渣且易造成刮傷缺陷,此最後經過鋅槽(105)之鋼板再進入均溫冷卻區(107)進行降溫冷卻,後續再經過調值整平區(108)與塗覆區(109)並進入出料儲存塔(110)。對於鋼板表面氧化鋅膜厚度加以控制,可以使具有良好的製程滑動性,更重要的是,適當控制鋼材表面厚度之氧化鋅薄膜也可以幫助後續鋼板沖壓製程時之沖壓成型性,所以如何控制爐鼻內之露點溫度就是重要的課題。Referring to Fig. 1, this is a schematic diagram of a conventional hot dip galvanizing process. The steel coil (102) fed from the feed storage tower (101) enters the cleaning zone (103), which can be used to deposit oil and carbide on the surface of the steel sheet. Cleaned with iron powder to enhance the plating of subsequent processes and avoid the entry of contaminants into the zinc bath, and then enter the continuous annealing zone (104). The temperature of the steel at this stage is increased to the recrystallization temperature of the steel for recrystallization. Process. The steel sheet passing through the continuous annealing zone (104) is immersed in the zinc tank (105) at an appropriate angle and speed. The high temperature on the surface of the steel sheet evaporates a part of the zinc liquid in the zinc furnace, and the zinc ash produced by the evaporated zinc liquid It will spread around, some of which will accumulate in the furnace nose (106), and some will fall on the steel plate. As a result, irregular fine slag will be formed. This zinc ash will affect the quality of the galvanized steel sheet. When the humidity rises, the dew point temperature will also increase. The increase of the dew point temperature will make the surface zinc liquid in the zinc tank not easily evaporate. The inner wall of the furnace nose (106) will not easily produce zinc ash accumulation, but the dew point temperature is too high. It will also increase the thickness of the zinc oxide film on the surface of the steel too thick. This excessively thick zinc oxide film will cause strip-shaped zinc slag and easily cause scratch defects. Finally, the steel plate passing through the zinc tank (105) enters the uniform temperature cooling zone. (107) Performing cooling cooling, and then passing through the adjustment leveling zone (108) and the coating zone (109) and entering the discharge storage tower (110). Controlling the thickness of the zinc oxide film on the surface of the steel sheet can make it have good process slidability. More importantly, the zinc oxide film which appropriately controls the thickness of the steel surface can also help the stamping formability of the subsequent steel stamping process, so how to control the furnace The dew point temperature in the nose is an important issue.
圖2為習知之氮氣加濕系統示意圖,一乾氮氣(201)由入口送入到加濕水槽(202)中以形成一濕氮氣,此加濕水槽(202)具有一水量補充管路(203a)與一水量流出管路(203b),此濕氮氣流出加濕水槽(202)後通過一流量計(204)並進入一流量控制管路(205),此流量控制管路(205)是用多個關斷閥(206)與調整閥(207)來進行流量控制,後續濕氮氣則可導入爐鼻內。此種加濕器系統的缺點是只能提供濕氮氣而無法同時提供乾氮氣,所以隨著鋼板尺寸與厚度的不同,爐鼻內都會是相同的露點溫度,並且加濕器內也無控制溫度以改變濕氮氣濕度之裝置,加濕氮氣也無法確知所包含之相對濕度或露點資料,其無法符合實際需求,加濕水槽(202)內之水位不足時也無法確實得知補充之水量,並且,此加濕水槽(202)內因水分揮發後會留下水垢或雜質,其易累積在此加濕水槽(202)內並且無法移除。2 is a schematic view of a conventional nitrogen humidification system. A dry nitrogen gas (201) is fed from an inlet to a humidification water tank (202) to form a wet nitrogen gas. The humidification water tank (202) has a water supply supplement line (203a). And a water flow outflow line (203b), the wet nitrogen flows out of the humidification water tank (202), passes through a flow meter (204) and enters a flow control line (205), which is used by the flow control line (205) A shut-off valve (206) and a regulating valve (207) are used for flow control, and subsequent wet nitrogen gas can be introduced into the furnace nose. The disadvantage of this type of humidifier system is that it can only supply wet nitrogen and cannot provide dry nitrogen at the same time. Therefore, with the difference in size and thickness of the steel plate, the same dew point temperature will be in the furnace nose, and there is no control temperature in the humidifier. In order to change the humidity of the wet nitrogen gas, it is impossible to ascertain the relative humidity or dew point data contained in the humidified nitrogen gas, which cannot meet the actual demand, and the water amount in the humidification water tank (202) cannot be surely known. The humidification water tank (202) will leave scale or impurities due to evaporation of water, which is easily accumulated in the humidification water tank (202) and cannot be removed.
此習知之加濕系統需人工監看露點並調整濕氮氣流量,無法自動化控制,無法及時、迅速因應爐區內露點的變化與需求,如此可能在露點過高時有鋅渣產生,露點過低時產生鋅灰,所以影響品質甚大。The conventional humidification system needs to manually monitor the dew point and adjust the flow rate of wet nitrogen, which cannot be automatically controlled, and cannot timely and quickly respond to the change and demand of the dew point in the furnace zone. Therefore, zinc slag may be generated when the dew point is too high, and the dew point is too low. When the zinc ash is produced, the quality is very high.
本發明之目的是提供一可自動控制爐鼻內氮氣露點之氮氣加濕系統,其包含:一加濕器,用來增加氮氣之濕度;一乾氮氣分流管路,其具有一入口與二出口,其中該入口為乾氮氣管,其一出口為導入上述加濕器內之乾氮氣管,另一出口為與出加濕器之濕氮氣結合以導入至上述爐鼻內之濕氮氣管;一露點感測器,設於與爐鼻連接之濕氮氣管路間以偵測爐鼻內之露點溫度;一加熱器,設於此加濕器內,其用以使加濕器內之水溫改變;一複數個關斷閥,設在此氮氣加濕自動控制系統管路內以作為切斷關路與流通用;及一供水裝置連接至此加濕器,其用來提供此加濕器之水量補充。The object of the present invention is to provide a nitrogen humidification system capable of automatically controlling the nitrogen dew point in the furnace nose, comprising: a humidifier for increasing the humidity of the nitrogen; and a dry nitrogen bypass line having an inlet and a second outlet. Wherein the inlet is a dry nitrogen tube, one outlet is a dry nitrogen tube introduced into the humidifier, and the other outlet is a wet nitrogen tube combined with the humid nitrogen of the humidifier to be introduced into the furnace nose; a dew point a sensor disposed between the wet nitrogen line connected to the nose of the furnace to detect the dew point temperature in the furnace nose; a heater disposed in the humidifier for changing the temperature of the water in the humidifier a plurality of shut-off valves are provided in the pipeline of the nitrogen humidification automatic control system for shutting off the flow and flow; and a water supply device is connected to the humidifier for providing the humidifier supplement.
藉由本發明可於熔融鍍鋅鋼板表面在無損於表面外觀下安定且確實地形成氧化鋅膜,其將濕氮氣吹進爐鼻內之手段可以改變爐鼻內之露點溫度,並且測定其中之相對濕度與露點溫度。By the present invention, a zinc oxide film can be stably and surely formed on the surface of the hot-dip galvanized steel sheet without impairing the surface appearance, and the means for blowing wet nitrogen into the furnace nose can change the dew point temperature in the furnace nose, and determine the relative Humidity and dew point temperature.
參考圖3,為本發明之氮氣加濕系統(300)示意圖,其包括:一乾濕氮氣分流管(301)、一裝設於濕氮氣出口之露點感測器(302)、一加濕器(303)、一裝置於加濕器(303)內之加熱器(304)、一複數個控制閥(305a,305b,305c,305d)與一連接至加濕器之供水通道(306),其中此露點感測器(302)裝置於與爐鼻連接之濕氮氣管路間以偵測爐鼻內之露點溫度,此供水通道(306)用來提供此加濕器(303)之水量補充。3 is a schematic view of a nitrogen humidification system (300) according to the present invention, comprising: a dry and wet nitrogen shunt tube (301), a dew point sensor (302) installed at a wet nitrogen outlet, and a humidifier (303), a heater (304) installed in the humidifier (303), a plurality of control valves (305a, 305b, 305c, 305d) and a water supply passage (306) connected to the humidifier, wherein The dew point sensor (302) is arranged between the wet nitrogen line connected to the nose to detect the dew point temperature in the furnace nose. The water supply channel (306) is used to provide the water quantity supplement of the humidifier (303).
乾濕氮氣分流管(301)具有一入口與二出口,其入口為乾氮氣管路,其一出口導入至加濕器內,另一出口為與出加濕器(303)之濕氮氣結合以導入至上述爐鼻內之濕氮氣管。另具有一加熱冷卻單元(307)連接至此加濕器(303)內,其用以加熱或冷卻此加濕器(303)內之水溫,當加濕器內水溫過高或過低時可作為冷卻或與加熱用,以提高此加濕器之效能,其可作為上述加熱器之備用加熱冷卻單元。The dry and wet nitrogen shunt tube (301) has an inlet and a second outlet, the inlet of which is a dry nitrogen line, one of which is introduced into the humidifier, and the other outlet is combined with the wet nitrogen of the humidifier (303). Introduced into the wet nitrogen tube in the above furnace nose. Another heating and cooling unit (307) is connected to the humidifier (303) for heating or cooling the water temperature in the humidifier (303) when the water temperature in the humidifier is too high or too low. It can be used for cooling or heating to improve the performance of the humidifier, which can be used as a backup heating and cooling unit for the above heater.
此加濕器(303)另具有一過濾水循環系統(308),其具有一過濾器(308a)、一循環幫浦(308b)與一循環管路(308c),其中,此循環管路之一端接至此加濕器(303)底部,另一端將已過濾水由此加濕器(303)之濕氮氣出口處之管路導進此加濕器(303)內,此水過濾循環系統(308)可作為去除加濕器內水垢用,避免加濕器(303)內之水垢累積。此加濕系統(300)另具有一液面感測器(309a)與液面顯示器(309b),其用來感測此加濕器(303)內之液面高度,並提供一訊號給供水裝置以補充並維持加濕器內之水量。The humidifier (303) further has a filtered water circulation system (308) having a filter (308a), a circulation pump (308b) and a circulation line (308c), wherein one end of the circulation line Connected to the bottom of the humidifier (303), the other end introduces the filtered water into the humidifier (303) through the pipeline at the wet nitrogen outlet of the humidifier (303), and the water filtration circulation system (308) It can be used as a scale to remove scale in the humidifier to avoid scale accumulation in the humidifier (303). The humidification system (300) further has a liquid level sensor (309a) and a liquid level display (309b) for sensing the liquid level in the humidifier (303) and providing a signal to the water supply. The device supplements and maintains the amount of water in the humidifier.
其中在此乾濕氮氣分流管(301)前另裝設有一減壓閥(313)、一關斷閥(305d)與一壓力計(312a),用以監測控制進入乾濕氮氣分流管(301)之氮氣壓力,另外在濕氮氣分流管(301)之兩出口設有兩個氮氣流量控制器(310a,310b),可分別控制流入乾氮氣管路與濕氮氣管路之氮氣流量,而在加濕器之濕氮氣出口與乾氮氣管路會合處也有一總氮氣流量控制閥(310c)以控制進入爐鼻之氮氣流量,在進入爐鼻前另設有關斷閥(305b,305c)以控制露點偵測器(302)之開啟與否,此關斷閥作為關斷與流通之用。A pressure reducing valve (313), a shut-off valve (305d) and a pressure gauge (312a) are additionally installed in front of the dry and wet nitrogen shunt pipe (301) for monitoring and controlling the flow into the dry and wet nitrogen shunt pipe (301). Nitrogen pressure, and two nitrogen flow controllers (310a, 310b) at the two outlets of the wet nitrogen shunt tube (301), respectively, can control the flow of nitrogen into the dry nitrogen line and the wet nitrogen line, respectively. The wet nitrogen outlet of the humidifier and the dry nitrogen line also have a total nitrogen flow control valve (310c) to control the flow of nitrogen into the furnace nose, and a shut-off valve (305b, 305c) is provided to control before entering the furnace nose. Whether the dew point detector (302) is turned on or off, the shut-off valve is used for shutdown and circulation.
在供水裝置(306)設有一電磁控制閥(311)來控制入水流量。另外此乾濕氮氣分流管(301)前端另裝置有一減壓閥(313)、一壓力計(312a)與一關斷閥(305)。此加濕器裝置有一壓力計(312b),用以監控加濕器內之氣體壓力,此加熱器裝置有一水溫計(312c),用以監控此加濕器內之水溫。An electromagnetic control valve (311) is provided at the water supply device (306) to control the flow of incoming water. In addition, the front end of the dry and wet nitrogen shunt tube (301) is further provided with a pressure reducing valve (313), a pressure gauge (312a) and a shut-off valve (305). The humidifier device has a pressure gauge (312b) for monitoring the pressure of the gas in the humidifier. The heater device has a water temperature gauge (312c) for monitoring the temperature of the water in the humidifier.
雖然本發明已以前述較佳實施例揭示,然其並非用以限定本發明,任何熟習此技藝者,在不脫離本發明之精神和範圍內,當可作各種之更動與修改。因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。While the present invention has been described in its preferred embodiments, it is not intended to limit the scope of the invention, and various modifications and changes can be made without departing from the spirit and scope of the invention. Therefore, the scope of the invention is defined by the scope of the appended claims.
101...進料儲存塔101. . . Feed storage tower
102...鋼捲102. . . Steel coil
103...清洗區103. . . Cleaning area
104...連續退火區104. . . Continuous annealing zone
105...鋅槽105. . . Zinc tank
106...爐鼻106. . . Furnace
107...均溫冷卻區107. . . Average temperature cooling zone
108...調值整平區108. . . Adjusted leveling area
109...塗覆區109. . . Coating area
110...出料儲存塔110. . . Discharge storage tower
201...乾氮氣201. . . Dry nitrogen
202...加濕水槽202. . . Humidifying sink
203a...水量補充管路203a. . . Water supply line
203b...水量流出管路203b. . . Water flow outflow line
204...流量計204. . . Flow meter
205...流量控制管路205. . . Flow control line
206...關斷閥206. . . Shut off valve
207...調整閥207. . . Adjustment valve
300...氮氣加濕系統300. . . Nitrogen humidification system
301...乾濕氮氣分流管301. . . Dry and wet nitrogen shunt
302...露點偵測器302. . . Dew point detector
303...加濕器303. . . humidifier
304...加熱器304. . . Heater
305a...關斷閥305a. . . Shut off valve
305b...關斷閥305b. . . Shut off valve
305c...關斷閥305c. . . Shut off valve
305d...關斷閥305d. . . Shut off valve
306...供水裝置306. . . Water supply unit
307...加熱冷卻單元307. . . Heating and cooling unit
308...過濾水循環系統308. . . Filter water circulation system
308a...過濾器308a. . . filter
308b...循環幫浦308b. . . Cyclic pump
309a...液面感測器309a. . . Liquid level sensor
309b...液面顯示器309b. . . Liquid level display
310a...氮氣流量控制器310a. . . Nitrogen flow controller
310b...氮氣流量控制器310b. . . Nitrogen flow controller
310c...總氮氣流量控制閥310c. . . Total nitrogen flow control valve
311...電磁控制閥311. . . Electromagnetic control valve
312a...壓力計312a. . . pressure gauge
312b...壓力計312b. . . pressure gauge
312c...水溫計312c. . . Water temperature meter
313...減壓閥313. . . Pressure reducing valve
圖1為習知之熱浸鍍鋅流程示意圖。FIG. 1 is a schematic view of a conventional hot dip galvanizing process.
圖2為習知之氮氣加濕系統示意圖。2 is a schematic view of a conventional nitrogen humidification system.
圖3為本發明之氮氣加濕系統示意圖。Figure 3 is a schematic view of a nitrogen humidification system of the present invention.
301...乾濕氮氣分流管301. . . Dry and wet nitrogen shunt
302...露點偵測器302. . . Dew point detector
303...加濕器303. . . humidifier
304...加熱器304. . . Heater
305a...關斷閥305a. . . Shut off valve
305b...關斷閥305b. . . Shut off valve
305c...關斷閥305c. . . Shut off valve
305d...關斷閥305d. . . Shut off valve
306...供水裝置306. . . Water supply device
307...加熱冷卻單元307. . . Heating and cooling unit
308...過濾水循環系統308. . . Filter water circulation system
308a...過濾器308a. . . filter
308b...循環幫浦308b. . . Cyclic pump
309a...液面感測器309a. . . Liquid level sensor
309b...液面顯示器309b. . . Liquid level display
310a...氮氣流量控制器310a. . . Nitrogen flow controller
310b...氮氣流量控制器310b. . . Nitrogen flow controller
310c...總氮氣流量控制閥310c. . . Total nitrogen flow control valve
311...電磁控制閥311. . . Electromagnetic control valve
312a...壓力計312a. . . pressure gauge
312b...壓力計312b. . . pressure gauge
312c...水溫計312c. . . Water temperature meter
313...減壓閥313. . . Pressure reducing valve
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CN106480388A (en) * | 2015-09-02 | 2017-03-08 | 上海东新冶金技术工程有限公司 | Suppress dry and wet gas humidification by mixing of gas device and its using method of zinc gray for galvanizing |
CN110042336B (en) * | 2018-01-17 | 2021-02-19 | 宝山钢铁股份有限公司 | Nose nitrogen humidifying device of hot galvanizing furnace |
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TW200932642A (en) * | 2008-01-17 | 2009-08-01 | Asia Ic Mic Process Inc | Keeping device for the atmosphere in the chemical tank and the method thereof |
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TW200932642A (en) * | 2008-01-17 | 2009-08-01 | Asia Ic Mic Process Inc | Keeping device for the atmosphere in the chemical tank and the method thereof |
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