TWI457380B - A method for producing a penetrating foam sheet and a product thereof - Google Patents

A method for producing a penetrating foam sheet and a product thereof Download PDF

Info

Publication number
TWI457380B
TWI457380B TW098103008A TW98103008A TWI457380B TW I457380 B TWI457380 B TW I457380B TW 098103008 A TW098103008 A TW 098103008A TW 98103008 A TW98103008 A TW 98103008A TW I457380 B TWI457380 B TW I457380B
Authority
TW
Taiwan
Prior art keywords
styrene
mesh
foamed
foaming
butadiene
Prior art date
Application number
TW098103008A
Other languages
Chinese (zh)
Other versions
TW201028439A (en
Original Assignee
Microcell Composite Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Microcell Composite Co Ltd filed Critical Microcell Composite Co Ltd
Priority to TW098103008A priority Critical patent/TWI457380B/en
Publication of TW201028439A publication Critical patent/TW201028439A/en
Application granted granted Critical
Publication of TWI457380B publication Critical patent/TWI457380B/en

Links

Landscapes

  • Laminated Bodies (AREA)

Description

穿透性發泡片體之製造方法及其產品 Method for manufacturing penetrating foamed sheet and product thereof

本發明係關於一種穿透性發泡片體之製造方法及其產品,尤其係指一種能避免有毒物質使用並能有效控制製品尺寸之穿透性發泡片體之製造方法及其產品。 The present invention relates to a method for producing a penetrating foamed sheet and a product thereof, and more particularly to a method for producing a penetrating foamed sheet which can avoid the use of toxic substances and can effectively control the size of the product and a product thereof.

伴隨著塑化產品發展的成熟,消費者對於塑化產品在加工製程、使用便利及後期回收處理的要求方面也越來越高,在加工過程中,要避免有毒物質的添加及製程中所產生的有毒氣體。產品於使用時,更希望能夠容易使用、美觀、且耐用,而後續回收處理則也須避免因塑料以燃燒法回收處理時所產生之戴奧辛(dioxin)等有毒氣體對人體所造成危害,故若不使用燃燒法,而採用大量堆疊的方式更會因多數塑料並不會自行分解,而造成對大自然環境的二次傷害。 With the maturity of the development of plasticized products, consumers are also getting higher and higher requirements for the processing, ease of use and post-harvest processing of plasticized products. In the process of processing, it is necessary to avoid the addition of toxic substances and the process. Toxic gas. When the product is used, it is more desirable to be easy to use, beautiful, and durable, and the subsequent recycling treatment must also avoid the harm caused to the human body by toxic gases such as dioxin which are generated when the plastic is recovered by the combustion method. Instead of using the combustion method, the use of a large number of stacking methods will cause secondary damage to the natural environment because most plastics do not decompose on their own.

目前被廣泛使用的塑化材料之一即為高分子發泡材料,該發泡材料依使用原料或特性之不同,大致可區分為塑膠發泡材料及橡膠發泡材料,或熱塑性材料及熱固性材料兩種。 One of the plasticizing materials currently widely used is a polymer foaming material, which can be roughly classified into a plastic foaming material and a rubber foaming material, or a thermoplastic material and a thermosetting material depending on the raw materials or characteristics used. Two.

既有的塑膠發泡材料,以乙烯-醋酸乙烯共聚物(ethylene vinyl acetate,EVA)為例,利用該材料進行發泡之發泡物可在加工後段程序輕易達到塑形之效果,且易於著色並進行回收利用;唯該材料之彈性及止滑效果皆較不理想;而橡膠發泡材料雖可彌補塑膠發泡材料之不足,但該橡膠發泡材料之加工製程較為複雜且塑形不易,另外亦容易產生對環境造成危害的污染物。 The existing plastic foaming material, taking ethylene vinyl acetate (EVA) as an example, the foamed foam by using the material can easily achieve the shaping effect in the post-processing section, and is easy to color. And recycling; only the elasticity and anti-slip effect of the material are less than ideal; while the rubber foaming material can make up for the deficiency of the plastic foaming material, the processing process of the rubber foaming material is complicated and difficult to shape. In addition, it is easy to produce pollutants that are harmful to the environment.

用於製造多層體之習知塑性材料皆有其優缺點,雖可針對具有不同特性材料的混合方式進行研究以產生之新穎的材料並改善前述缺點,但相異性質的材料之結合,在配製及製程條件上往往有不易控制的缺點。另外,產品在製造後,其尺寸無法有效的加以控制,使得後續產品在加工上更為不易。 Conventional plastic materials used in the manufacture of multilayer bodies have their advantages and disadvantages. Although they can be studied for mixing materials with different characteristic materials to produce novel materials and improve the aforementioned disadvantages, the combination of materials of different properties is formulated. And process conditions often have shortcomings that are difficult to control. In addition, after the product is manufactured, its size cannot be effectively controlled, making subsequent products more difficult to process.

一般發泡塑化材料所製得之墊體在發泡過程中,其縱向發泡控制不易,使得材料發泡過程中皆係以不規則方向朝四面八方進行發泡,讓墊體的尺寸無法有效的控制,且發泡材料多係軟質塑化材料,故在製程上也較不易控制,而溢出的發泡材更會導致材料成本的增加。 Generally, in the foaming process, the cushion body made of the foaming plasticizing material is difficult to control the longitudinal foaming, so that the foaming process is foamed in an irregular direction in all directions, so that the size of the cushion body cannot be effectively effective. The control, and the foaming material is mostly soft plasticizing material, so it is also difficult to control in the process, and the overflowing foaming material will lead to an increase in material cost.

本發明人有鑑於上述一般發泡塑化材料所製得之墊體具有上述種種缺點,乃積極著手從事研究改良,以期能夠解決上述墊體於製造時所遇到的問題,經過不斷的試驗及努力,終於研發出本發明。 The present inventors have in view of the above-mentioned various disadvantages in view of the above-mentioned various disadvantages of the general foamed plasticized material, and are actively engaged in research and improvement in order to solve the problems encountered in the manufacture of the above-mentioned mat body, and have been continuously tested and Efforts have finally come to the present invention.

本發明之主要目的在提供一種能避免有毒物質使用並能有效控制製品尺寸之穿透性發泡片體之製造方法及其產品。 SUMMARY OF THE INVENTION The main object of the present invention is to provide a method for producing a penetrating foamed sheet which can avoid the use of toxic substances and which can effectively control the size of the product and products thereof.

為了達到上述發明目的,本發明係採取以下之技術手段予以達成,其中本發明係包括有下述步驟:提供一上發泡片體;提供一下發泡片體;提供一中間網布,該網布為不具延展性之耐熱材質,網布之網孔大小在0.1mm~10mm,各網孔之間的距離為0.5mm~5.0mm;夾合發泡,係將該中間網布置於該上、下發泡片體間,利用熱壓使上、下片體發泡,上、下片體發泡時,其相對於網布之一面會穿過網布之網孔而相互結合,進而形成一穿透性發泡片體。 In order to achieve the above object, the present invention is achieved by the following technical means, wherein the present invention comprises the steps of: providing an upper foamed sheet; providing a foamed sheet; providing an intermediate mesh, the net The cloth is a non-ductile heat-resistant material, the mesh size of the mesh is 0.1mm~10mm, and the distance between each mesh is 0.5mm~5.0mm; the sandwiching foaming is arranged on the upper mesh, Between the lower foamed sheets, the upper and lower sheets are foamed by hot pressing, and when the upper and lower sheets are foamed, one side of the mesh is passed through the mesh of the mesh to join each other to form a Penetrating foamed sheet.

本發明之穿透性發泡片體係包括有上發泡片體及下發泡片體,該上、下發泡片體之間設置有中間網布,該中間網布之網孔大小在0.1mm~10mm,各網孔之間的距離為0.5mm~5.0mm,而上、下發泡片體之厚度要比中間網布的厚度多0.1mm~1.0mm。 The penetrating foaming sheet system of the present invention comprises an upper foaming sheet body and a lower foaming sheet body, and an intermediate mesh cloth is disposed between the upper and lower foaming sheet bodies, and the mesh size of the intermediate mesh cloth is 0.1 Mm~10mm, the distance between each mesh is 0.5mm~5.0mm, and the thickness of the upper and lower foamed sheets is 0.1mm~1.0mm more than the thickness of the intermediate mesh.

由於本發明係直接利用兩上、下發泡片體受熱發泡來進行結合,因此不需要使用任何有毒性之膠體,且發泡過程中,材質的縱向發泡會受到網布材質之拉扯而受到限制,讓上、下發泡片體僅會朝縱向進行發泡而不會有材料溢出的問題。 Since the invention directly uses the two upper and lower foamed sheets to be thermally foamed for bonding, it is not necessary to use any toxic colloid, and during the foaming process, the longitudinal foaming of the material is pulled by the mesh material. Restricted, the upper and lower foamed sheets are only foamed in the longitudinal direction without the problem of material overflow.

本發明穿透性發泡片體之製造方法係包括有下述步驟:提供一上發泡片體,其為TPE材質,選自下述聚合物或共聚物之組群:苯乙烯-丁二烯-苯乙烯嵌共聚物(Styrene-Butadiene-Styrene,SBS)、苯乙烯-異戊二烯-苯乙烯(Styrene-Isoprene-Styrene,SIS)、苯乙烯-乙烯-丁烯-苯乙烯彈性體(Styrene-Ethylene-Butylene-Styrene Elastomer,SEBS)、苯乙烯-丁二烯橡膠(Styrene-butadiene rubber,SBR)、聚苯乙烯(polystyrene,PS)、丙烯腈-丁二烯-苯乙烯共聚物(Acrylonitrile-Butadiene-Styrene,ABS)、聚乙烯(polyethylene,PE)、高密度聚乙烯(high-density polyethylene,HDPE)、聚丙烯(polypropylene,PP)、丙烯腈-苯乙烯共聚物(Acrylonitrile-styrene copolymer,AS),或前述聚合物及/或共聚物之混合物;提供一下發泡片體,其為TPE材質,選自下述聚合物或共聚物之組群:苯乙烯-丁二烯-苯乙烯嵌共聚物(Styrene-Butadiene-Styrene,SBS)、苯乙烯-異戊二烯-苯乙烯(Styrene-Isoprene-Styrene,SIS)、苯乙烯-乙烯-丁烯-苯乙烯彈性體(Styrene-Ethylene-Butylene-Styrene Elastomer,SEBS)、苯乙烯-丁二烯橡膠(Styrene-butadiene rubber,SBR)、聚苯乙烯(polystyrene,PS)、丙烯腈-丁二烯-苯乙烯共聚物(Acrylonitrile-Butadiene-Styrene,ABS)、聚乙烯(polyethylene,PE)、高密度聚乙烯(high-density polyethylene,HDPE)、聚丙烯(polypropylene,PP)、丙烯腈-苯乙烯共聚物(Acrylonitrile-styrene copolymer,AS),或前述聚合物及/或共聚物之混合物;提供一中間網布,該網布為不具延展性之耐熱材質,網布之網孔大小在0.1mm~10mm,各網孔之間的距離為0.5mm~5.0mm;夾合發泡,係將該中間網布置於該上、下發泡片體間,利用熱壓使上、下片體發泡,上、下片體發泡時,其相對於網布之一面會穿過網布之網孔而相互結合,進而形成一穿透性發泡片體。 The manufacturing method of the penetrating foamed sheet of the present invention comprises the steps of: providing an upper foamed sheet material which is a TPE material selected from the group consisting of the following polymers or copolymers: styrene-butyl Styrene-Butadiene-Styrene (SBS), Styrene-Isoprene-Styrene (SIS), Styrene-Ethylene-Butylene-Styrene Elastomer ( Styrene-Ethylene-Butylene-Styrene Elastomer (SEBS), Styrene-butadiene rubber (SBR), polystyrene (PS), acrylonitrile-butadiene-styrene copolymer (Acrylonitrile) -Butadiene-Styrene, ABS), polyethylene (PE), high-density polyethylene (HDPE), polypropylene (PP), acrylonitrile-styrene copolymer (Acrylonitrile-styrene copolymer, AS), or a mixture of the foregoing polymers and/or copolymers; providing a foamed sheet of TPE material selected from the group consisting of styrene-butadiene-styrene embedded Copolymer (Styrene-Butadiene-Styrene, SBS), styrene-isoprene - Styrene-Isoprene-Styrene (SIS), Styrene-Ethylene-Butylene-Styrene Elastomer (SEBS), Styrene-butadiene rubber , SBR), polystyrene (PS), Acrylonitrile-Butadiene-Styrene (ABS), polyethylene (PE), high density polyethylene (high-density) Polyethylene (PPPE), polypropylene (PP), acrylonitrile-styrene copolymer (AS), or a mixture of the foregoing polymers and/or copolymers; providing an intermediate mesh, the mesh For the non-ductile heat-resistant material, the mesh size of the mesh is 0.1mm~10mm, and the distance between the meshes is 0.5mm~5.0mm; the sandwiching foaming is to arrange the intermediate net on the upper and lower sides. Between the foamed sheets, the upper and lower sheets are foamed by hot pressing, and when the upper and lower sheets are foamed, they are combined with one side of the mesh through the mesh of the mesh to form a wear. Permeable foamed sheet.

上述上、下發泡片體夾置中間網布進行發泡後,各發泡片體之厚度要 比網布的厚度多0.1mm~1.0mm,由於上、下發泡片體在發泡時,其縱向之發泡行為會受到中間網布的拉扯,因此不會有激烈的發泡反應發生,而發泡反應便會轉為縱向之發泡上,讓上、下發泡片體之發泡朝穿透性發泡片體的厚度方向進行,配合熱壓作業能夠有效的控制穿透性發泡片體的厚度,又,中間網布之網孔排列形狀可以依需求呈現出不同之文字、圖樣或花紋,讓發泡後經熱壓的穿透性發泡片體上可以自然的行程出所欲的文字、圖樣或花紋,如此一來,加熱的熱壓模具便不需要設置文字圖樣或花紋,不僅可以降低製造設備的成本,更可以輕易的達成在穿透性發泡片體形成所欲文字、圖樣或花紋之功效。 After the upper and lower foam sheets are interposed with the intermediate mesh cloth for foaming, the thickness of each foamed sheet body is required to be It is 0.1mm~1.0mm thicker than the thickness of the mesh. Since the foaming behavior of the upper and lower foamed sheets is foamed by the intermediate mesh, there is no intense foaming reaction. The foaming reaction is converted into longitudinal foaming, so that the foaming of the upper and lower foamed sheets is carried out in the thickness direction of the penetrating foamed sheet, and the heat-pressing operation can effectively control the penetrating hair. The thickness of the foam body, and the mesh arrangement shape of the intermediate mesh cloth can present different characters, patterns or patterns according to requirements, so that the heat-transmissive penetrating foamed sheet can be naturally taken out after foaming. The desired text, pattern or pattern, so that the heated hot pressing mold does not need to set the text pattern or pattern, which can not only reduce the cost of the manufacturing equipment, but also easily achieve the formation of the penetrating foam sheet. The effect of words, patterns or patterns.

又,本發明之穿透性發泡片體係包括有上發泡片體及下發泡片體,該上、下發泡片體之間設置有中間網布,該中間網布之網孔大小在0.1mm~10mm,各網孔之間的距離為0.5mm~5.0mm,而上、下發泡片體之厚度要比中間網布的厚度多0.1mm~1.0mm,且該中間網布之網孔排列形狀呈現出不同之文字、圖樣或花紋。 Moreover, the penetrating foam sheet system of the present invention comprises an upper foamed sheet body and a lower foamed sheet body, and an intermediate mesh cloth is disposed between the upper and lower foamed sheet bodies, and the mesh size of the intermediate mesh cloth In 0.1mm~10mm, the distance between each mesh is 0.5mm~5.0mm, and the thickness of the upper and lower foamed sheets is 0.1mm~1.0mm more than the thickness of the intermediate mesh, and the intermediate mesh is The mesh arrangement shape presents different text, patterns or patterns.

經由本發明所製造之穿透性發泡片體,可應用於瑜珈墊、止滑墊、隔熱墊方面,因此應用範圍上十分的廣泛,且由於發泡過程中,尺寸得以有效的加以控制,因此不會產生材料耗損的問題,更能節省墊體在製造上的成本。 The penetrating foamed sheet body manufactured by the invention can be applied to the yoga mat, the anti-slip mat and the heat insulating mat, so the application range is very wide, and the size can be effectively controlled due to the foaming process. Therefore, there is no problem of material loss, and the cost of manufacturing the pad body can be saved.

上述的熱壓條件為一般的塑化墊熱壓條件,其溫度、壓力屬於具有本案通常技藝人士所可瞭解者,且並非本案的重點,因此在此便省略其說明。 The above-mentioned hot pressing conditions are general plasticizing pad hot pressing conditions, and the temperature and pressure thereof are known to those skilled in the art, and are not the focus of the present invention, and thus the description thereof will be omitted herein.

綜上所述,本發明利用中間網布的設置,使得上、下發泡片體在發泡過程中,能夠有效的控制發泡的方向性,讓墊體的製造成本上能夠加以控制,且由於尺寸的變異性被加以控制,因此能夠依需求製造出具有市場競爭力的塑化墊體,故本發明極具產業的利用性無疑。 In summary, the present invention utilizes the arrangement of the intermediate mesh cloth, so that the upper and lower foamed sheets can effectively control the directionality of foaming during the foaming process, so that the manufacturing cost of the cushion body can be controlled, and Since the variability of the size is controlled, it is possible to manufacture a plasticized mat body which is competitive in the market according to the demand, so that the present invention is highly industrially usable.

Claims (2)

一種穿透性發泡片體之製造方法,係包括有下述步驟:提供一上發泡片體;提供一下發泡片體;提供一中間網布,該網布為不具延展性之耐熱材質,網布之網孔大小在0.1mm~10mm,各網孔之間的距離為0.5mm~5.0mm;以及夾合發泡,係將該中間網布置於該上、下發泡片體間,利用熱壓使上、下片體發泡,上、下片體發泡時,其相對於網布之一面會穿過網布之網孔而相互結合,進而形成一穿透性發泡片體;其中,該上、下發泡片體為TPE材質,而該TPE材質選自下述聚合物或共聚物之組群:苯乙烯-丁二烯-苯乙烯嵌共聚物(Styrene-Butadiene-Styrene,SBS)、苯乙烯-異戊二烯-苯乙烯(Styrene-Isoprene-Styrene,SIS)、苯乙烯-乙烯-丁烯-苯乙烯彈性體(Styrene-Ethylene-Butylene-Styrene Elastomer,SEBS)、苯乙烯-丁二烯橡膠(Styrene-butadiene rubber,SBR)、聚苯乙烯(polystyrene,PS)、丙烯腈-丁二烯-苯乙烯共聚物(Acrylonitrile-Butadiene-Styrene,ABS)、聚乙烯(polyethylene,PE)、高密度聚乙烯(high-density polyethylene,HDPE)、聚丙烯(polypropylene,PP)、丙烯腈-苯乙烯共聚物(Acrylonitrile-styrene copolymer,AS),或前述聚合物及/或共聚物之混合物。 A method for manufacturing a penetrating foamed sheet comprises the steps of: providing an upper foamed sheet; providing a foamed sheet; and providing an intermediate mesh cloth which is a non-ductile heat resistant material The mesh size of the mesh cloth is 0.1mm~10mm, and the distance between each mesh hole is 0.5mm~5.0mm; and the sandwiching foaming is arranged between the upper and lower foaming sheets. The upper and lower sheets are foamed by hot pressing, and when the upper and lower sheets are foamed, they are combined with one side of the mesh through the mesh of the mesh to form a penetrating foam sheet. Wherein the upper and lower foamed sheets are made of TPE, and the TPE material is selected from the group consisting of styrene-butadiene-styrene-embedded copolymers (Styrene-Butadiene-Styrene) , SBS), Styrene-Isoprene-Styrene (SIS), Styrene-Ethylene-Butylene-Styrene Elastomer (SEBS), Benzene Styrene-butadiene rubber (SBR), polystyrene (PS), acrylonitrile-butadiene-styrene Acrylonitrile-Butadiene-Styrene (ABS), polyethylene (PE), high-density polyethylene (HDPE), polypropylene (PP), acrylonitrile-styrene copolymer (Acrylonitrile- Styrene copolymer, AS), or a mixture of the foregoing polymers and/or copolymers. 如申請專利範圍第1項所述之穿透性發泡片體之製造方法,其中該中間網布之網孔排列形狀呈現出不同之文字、圖樣或花紋。 The method for manufacturing a penetrating foamed sheet according to the first aspect of the invention, wherein the mesh arrangement shape of the intermediate mesh exhibits different characters, patterns or patterns.
TW098103008A 2009-01-23 2009-01-23 A method for producing a penetrating foam sheet and a product thereof TWI457380B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
TW098103008A TWI457380B (en) 2009-01-23 2009-01-23 A method for producing a penetrating foam sheet and a product thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
TW098103008A TWI457380B (en) 2009-01-23 2009-01-23 A method for producing a penetrating foam sheet and a product thereof

Publications (2)

Publication Number Publication Date
TW201028439A TW201028439A (en) 2010-08-01
TWI457380B true TWI457380B (en) 2014-10-21

Family

ID=44853577

Family Applications (1)

Application Number Title Priority Date Filing Date
TW098103008A TWI457380B (en) 2009-01-23 2009-01-23 A method for producing a penetrating foam sheet and a product thereof

Country Status (1)

Country Link
TW (1) TWI457380B (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3951717A (en) * 1973-09-13 1976-04-20 Bayer Aktiengesellschaft Process for making a laminate having a foam core
TW200508001A (en) * 2003-08-27 2005-03-01 Microcell Composite Company Continuous blowing manufacturing method for thermoplastic elastomer composite material containing sandwich mezzanine structure
TW200819293A (en) * 2006-10-31 2008-05-01 Microcell Composite Company Manufacturing method of yoga pad
TWM333415U (en) * 2007-03-23 2008-06-01 Chang Wong Ind Co Ltd Foam structure with embossed surface and shaping design

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3951717A (en) * 1973-09-13 1976-04-20 Bayer Aktiengesellschaft Process for making a laminate having a foam core
TW200508001A (en) * 2003-08-27 2005-03-01 Microcell Composite Company Continuous blowing manufacturing method for thermoplastic elastomer composite material containing sandwich mezzanine structure
TW200819293A (en) * 2006-10-31 2008-05-01 Microcell Composite Company Manufacturing method of yoga pad
TWM333415U (en) * 2007-03-23 2008-06-01 Chang Wong Ind Co Ltd Foam structure with embossed surface and shaping design

Also Published As

Publication number Publication date
TW201028439A (en) 2010-08-01

Similar Documents

Publication Publication Date Title
CN105908946B (en) Coextru-lamination stone moulds PVC floor
JP5762418B2 (en) Cushion molding method
JP4594445B1 (en) Foam and production method thereof
JP2014508055A5 (en) Laminated plate having bending rigidity, molded product from the laminated plate, and manufacturing method thereof
JP2017503889A5 (en)
JP2009145694A (en) Sound absorbing substrate for vehicle and method for manufacturing same
US20130150518A1 (en) Floor covering and method for producing the same
TWI457380B (en) A method for producing a penetrating foam sheet and a product thereof
JP4621804B1 (en) Insulation
TWI321097B (en)
TW200505973A (en) Foaming process for producing thermoplastic elastomer composite material
TW200819293A (en) Manufacturing method of yoga pad
CN102873950A (en) High-surface-energy double-direction stretching polypropylene thin film and manufacturing method thereof
US20050275127A1 (en) Method for manufacturing slippery-proof foam materials having protruded threads
JP2008303593A (en) Tatami mat forming member and thin tatami mat using the same
JP2016190400A (en) Method for producing resin laminated board for outside plate
JP2009166365A5 (en)
KR101729086B1 (en) Method for manufacturing tpo foam sheet for car interior
CN101786369A (en) Method for manufacturing transparent foaming sheet and product thereof
US20190161593A1 (en) Complex structure material, resin component, method of producing resin component
CN101433442A (en) Composite bathtub
TW200918316A (en) Method for manufacturing multi-layered structure of glueless thermoplastic foam elastic body
JP2003310395A (en) Bed composed of spring structure resin molding, production process therefor and bed cushion composed of spring structure resin molding
TWI526291B (en) Continuous system of air cushion elastomer and production equipment
RU2813278C2 (en) Multilayer composite board from bulk materials and plastic

Legal Events

Date Code Title Description
GD4A Issue of patent certificate for granted invention patent