TWI455876B - 奈米金屬碳管複合材、奈米金屬碳管複合材製備方法及奈米碳管導電基板 - Google Patents

奈米金屬碳管複合材、奈米金屬碳管複合材製備方法及奈米碳管導電基板 Download PDF

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TWI455876B
TWI455876B TW101117777A TW101117777A TWI455876B TW I455876 B TWI455876 B TW I455876B TW 101117777 A TW101117777 A TW 101117777A TW 101117777 A TW101117777 A TW 101117777A TW I455876 B TWI455876 B TW I455876B
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Taiwan
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nano metal
carbon tube
tube composite
nano
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TW101117777A
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TW201348126A (zh
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Chih Yung Chen
Yaching Lee
Szu Wen Chen
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Chi Mei Corp
Ncku Res & Dev Foundation
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Priority to TW101117777A priority Critical patent/TWI455876B/zh
Priority to CN2013101775826A priority patent/CN103420357A/zh
Publication of TW201348126A publication Critical patent/TW201348126A/zh
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Publication of TWI455876B publication Critical patent/TWI455876B/zh

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Claims (15)

  1. 一種奈米金屬碳管複合材，包含：複數個經改質奈米碳管，每一個經改質奈米碳管含有複數個官能基團；及複數個奈米金屬團，每一個奈米金屬團是連結於每一個經改質奈米碳管中之至少一官能基團上，且兩相鄰的經改質奈米碳管透過至少一個奈米金屬團而彼此相互連結。
  2. 依據申請專利範圍第1項所述之奈米金屬碳管複合材，其中，該等官能基團為一可提供電子的基團。
  3. 依據申請專利範圍第2項所述之奈米金屬碳管複合材，其中，該等官能基團包含至少一種由下列所構成群組的基團：酸酐基、羧基、羥基、醯基及胺基。
  4. 依據申請專利範圍第1項所述之奈米金屬碳管複合材，其中，該奈米金屬團包含至少一種由下列所構成群組的金屬：銀、錫及鎘。
  5. 一種奈米金屬碳管複合材製備方法，包含以下步驟：步驟(a)：提供複數個的經改質奈米碳管，每一個經改質奈米碳管含有複數個官能基團；步驟(b)：提供複數個金屬離子，與該等經改質奈米碳管上的官能基團連結並獲得一混合物；步驟(c)：將該混合物加入一還原劑中以使該等金屬離子進行還原反應，形成複數個具有奈米金屬粒子的奈米碳管； 步驟(d)：將該等具有奈米金屬粒子的奈米碳管施予一加熱處理，即可獲得奈米金屬碳管複合材。
  6. 依據申請專利範圍第5項所述之奈米金屬碳管複合材製備方法，還包含一於步驟(c)前進行的清洗處理步驟。
  7. 依據申請專利範圍第5項所述之奈米金屬碳管複合材製備方法，其中，該等官能基團為一可提供電子的基團。
  8. 依據申請專利範圍第7項所述之奈米金屬碳管複合材製備方法，其中，該等官能基團包含至少一種由下列所構成群組的基團：酸酐基、羧基、羥基、醯基及胺基。
  9. 依據申請專利範圍第5項所述之奈米金屬碳管複合材製備方法，其中，該金屬離子包含至少一種由下列所構成群組的化合物：銀離子、錫離子及鎘離子。
  10. 依據申請專利範圍第5項所述之奈米金屬碳管複合材製備方法，其中，該還原劑包含至少一種由下列所構成群組的化合物：硼氫化鈉、次磷酸鈉、二鹽酸肼及水合肼。
  11. 依據申請專利範圍第5項所述之奈米金屬碳管複合材製備方法，其中，該加熱處理的操作溫度範圍120℃~200℃。
  12. 一種奈米碳管導電基板，包含：一基材；及一奈米金屬碳管複合材，形成於該基材上；其中，該奈米金屬碳管複合材包含複數個經改質奈米碳管，每一個經改質奈米碳管含有複數個官能基團； 及複數個奈米金屬團，每一個奈米金屬團是連結於每一個經改質奈米碳管中之至少一官能基團上，且兩相鄰的經改質奈米碳管透過至少一個金屬團而彼此相互連結。
  13. 依據申請專利範圍第12項所述之奈米碳管導電基板，其中，該等官能基團為一可提供電子的基團。
  14. 依據申請專利範圍第13項所述之奈米碳管導電基板，其中，該等官能基團包含至少一種由下列所構成群組的基團：酸酐基、羧基、羥基、醯基及胺基。
  15. 依據申請專利範圍第12項所述之奈米碳管導電基板，其中，該基材的材質為玻璃、塑膠或矽。
TW101117777A 2012-05-18 2012-05-18 奈米金屬碳管複合材、奈米金屬碳管複合材製備方法及奈米碳管導電基板 TWI455876B (zh)

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TW101117777A TWI455876B (zh) 2012-05-18 2012-05-18 奈米金屬碳管複合材、奈米金屬碳管複合材製備方法及奈米碳管導電基板
CN2013101775826A CN103420357A (zh) 2012-05-18 2013-05-14 纳米金属碳管复合材、纳米金属碳管复合材制备方法及纳米碳管导电基板

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TW101117777A TWI455876B (zh) 2012-05-18 2012-05-18 奈米金屬碳管複合材、奈米金屬碳管複合材製備方法及奈米碳管導電基板

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TWI455876B true TWI455876B (zh) 2014-10-11

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KR101929623B1 (ko) * 2016-10-28 2018-12-14 고려대학교 산학협력단 플렉시블 전극 및 이의 제조방법

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CN1775818A (zh) * 2005-12-15 2006-05-24 上海交通大学 碳纳米管/聚合物纳米复合材料制备的方法
WO2007139244A1 (en) * 2006-05-30 2007-12-06 Korea Basic Science Institute A carbon nanotube of which surface is modified by transition metal coordination, and a method for modifying the same
US20080213487A1 (en) * 2006-10-13 2008-09-04 Samsung Electronics Company, Ltd. Multicomponent carbon nanotube-polymer complex, composition for forming the same, and preparation method thereof
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CN1263677C (zh) * 2004-04-22 2006-07-12 华中师范大学 纳米金属或金属氧化物均布于碳纳米管表面的复合材料制备
US20060057290A1 (en) * 2004-05-07 2006-03-16 Glatkowski Paul J Patterning carbon nanotube coatings by selective chemical modification
US8859048B2 (en) * 2006-01-03 2014-10-14 International Business Machines Corporation Selective placement of carbon nanotubes through functionalization
KR101202405B1 (ko) * 2008-05-28 2012-11-23 (주)바이오니아 탄소나노튜브 및 금속으로 이루어진 나노복합체 및 이의제조방법

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1775818A (zh) * 2005-12-15 2006-05-24 上海交通大学 碳纳米管/聚合物纳米复合材料制备的方法
WO2007139244A1 (en) * 2006-05-30 2007-12-06 Korea Basic Science Institute A carbon nanotube of which surface is modified by transition metal coordination, and a method for modifying the same
US20080213487A1 (en) * 2006-10-13 2008-09-04 Samsung Electronics Company, Ltd. Multicomponent carbon nanotube-polymer complex, composition for forming the same, and preparation method thereof
TW201024350A (en) * 2008-12-30 2010-07-01 Chi Mei Optoelectronics Corp Surface modification method of carbon nanotube, liquid crystal display panel and method of manufacturing thereof
US20100255290A1 (en) * 2009-04-07 2010-10-07 Tsinghua University Carbon nanotube metal nanoparticle composite and method for making the same

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CN103420357A (zh) 2013-12-04

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