TWI447025B - Method for manufacturing fiber reinforced products with bonding mechanism - Google Patents

Method for manufacturing fiber reinforced products with bonding mechanism Download PDF

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TWI447025B
TWI447025B TW101114127A TW101114127A TWI447025B TW I447025 B TWI447025 B TW I447025B TW 101114127 A TW101114127 A TW 101114127A TW 101114127 A TW101114127 A TW 101114127A TW I447025 B TWI447025 B TW I447025B
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fiber
reinforced
bonding mechanism
interposer
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TW201343401A (en
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Advanced Int Multitech Co Ltd
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Description

具結合機構之纖維強化產品的製造方法Method for manufacturing fiber reinforced product with bonding mechanism

本發明是有關於一種纖維強化產品的製造方法,特別是指一種具結合機構之纖維強化產品的製造方法。The present invention relates to a method for producing a fiber-reinforced product, and more particularly to a method for producing a fiber-reinforced product having a bonding mechanism.

隨著工業技術與生活水準的提升,人們對於各式產品的要求也愈來愈高,不僅要求價格便宜與實用性,還更進一步要求美觀、質輕,及使用壽命長...等功能。With the improvement of industrial technology and living standards, people's requirements for various products are getting higher and higher, not only requiring cheap and practical, but also further requiring beautiful, light weight, long service life and other functions.

因此,近年來,日常生活中以高強度且質輕之纖維強化材料所製成的產品愈來愈多,其中,又以碳纖維強化材料的產品最為常見,但是,眾所周知,碳纖維複合材料大多以熱壓方式成型,因此多用以製造如:板狀、管狀或柱狀...等斷面均一的產品,若要成型出具有較複雜之特徵結構的產品,往往需要分別成型後,再以人工方式利用機械力(例如:銷、鉚釘、螺絲...等)或黏合劑相互結合,如此,不但尺寸精度差且費時費工。Therefore, in recent years, there have been more and more products made of high-strength and light-weight fiber-reinforced materials in daily life, among which carbon fiber-reinforced materials are the most common, but it is well known that carbon fiber composites are mostly hot. It is formed by pressing, so it is often used to manufacture products with uniform cross-section such as plate, tube or column. If you want to form a product with more complicated features, it is often necessary to form separately and then manually. Mechanical forces (eg, pins, rivets, screws, etc.) or adhesives are combined with each other, which results in poor dimensional accuracy and time-consuming labor.

為改善上述缺點,相關業者研發出如日本第2010-046939號「一體成型成品的製造方法」,主要是將一含有熱塑性樹脂且端部成錐狀的纖維強化複合材料板置於一模具中,利用射包成型技術將附著件射出成型於該纖維強化複合材料板上。In order to improve the above-mentioned shortcomings, the related art has developed, as disclosed in Japanese Patent No. 2010-046939, "Manufacturing Method of One-Piece Finished Product", mainly by placing a fiber-reinforced composite material sheet containing a thermoplastic resin and having a tapered end portion in a mold. The attachment member is injection molded on the fiber reinforced composite material sheet by a shot forming technique.

但是,熱塑性樹脂的強度與剛性較差,造成該附著件與該纖維強化複合材料板的結合力不足,而容易因外力而發生斷裂或剝離。However, the thermoplastic resin is inferior in strength and rigidity, and the adhesion between the attachment member and the fiber-reinforced composite material sheet is insufficient, and it is liable to be broken or peeled due to an external force.

因此,本發明之目的,即在提供一種結合力較為穩定的具結合機構之纖維強化產品的製造方法。Accordingly, it is an object of the present invention to provide a method for producing a fiber-reinforced product having a bonding mechanism which has a relatively stable bonding force.

於是,本發明具結合機構之纖維強化產品的製造方法,包含下列步驟:(A)將多數含浸熱固性樹脂的纖維強化材料與一熱固性高分子膜片堆叠成為一複合基材,其中,該熱固性高分子膜片是選自聚醚類或聚醯胺類高分子材料所製成;(B)將該複合基材置於一熱壓模具中熱壓成為一半成品,該半成品包括一由該熱固性高分子膜片所形成的中介層,及一位在該中介層內且由所述纖維強化材料形成的本體;(C)在該中介層上塗覆黏著劑以形成一黏著層;(D)將該半成品置於一成型模具中,利用射出成型技術將熱塑性高分子材料充填於該成型模具中,以成型出與該黏著層相互結合的結合機構。Therefore, the method for manufacturing a fiber-reinforced product having a bonding mechanism of the present invention comprises the following steps: (A) stacking a plurality of fiber-reinforced materials impregnated with a thermosetting resin and a thermosetting polymer film into a composite substrate, wherein the thermosetting property is high. The molecular film is made of a polyether or polyamine polymer material; (B) the composite substrate is placed in a hot pressing mold to be hot pressed into a half finished product, and the semifinished product comprises a high thermosetting property. An interposer formed by a molecular film, and a body formed in the interposer and formed of the fiber-reinforced material; (C) applying an adhesive on the interposer to form an adhesive layer; (D) The semi-finished product is placed in a molding die, and a thermoplastic polymer material is filled in the molding die by an injection molding technique to form a bonding mechanism that is combined with the adhesive layer.

本發明的有益效果在於:利用由熱固性高分子膜片所形成的中介層,以確實包著由所述纖維強化材料形成的本體,而提供足夠的強度與剛性,配合黏著劑所形成的黏著層,不但能提升該半成品與該結合機構之間的結合力與穩定性,還能有效避免受外力作用而發生斷裂或剝離。The invention has the beneficial effects of: utilizing the interposer formed by the thermosetting polymer film to ensure the strength and rigidity of the body formed by the fiber reinforcing material, and the adhesive layer formed by the adhesive is provided. It not only improves the bonding force and stability between the semi-finished product and the bonding mechanism, but also effectively avoids the occurrence of cracking or peeling by external force.

有關本發明之前述及其他技術內容、特點與功效,在以下配合參考圖式之一個較佳實施例的詳細說明中,將可清楚的呈現。The above and other technical contents, features and advantages of the present invention will be apparent from the following detailed description of the preferred embodiments.

參閱圖1、2,本發明具結合機構之纖維強化產品的製造方法之一較佳實施例,首先,是如步驟21所示,將多數含浸熱固性樹脂的纖維強化材料31與一熱固性高分子膜片32堆叠成為一複合基材33,其中,該熱固性高分子膜片32是選自聚醚類(Polyethers)或聚醯胺類(polyamide)高分子材料所製成。Referring to Figures 1 and 2, a preferred embodiment of the method for producing a fiber-reinforced product having a bonding mechanism of the present invention, first, as shown in step 21, a plurality of fiber-reinforced materials 31 impregnated with a thermosetting resin and a thermosetting polymer film The sheets 32 are stacked to form a composite substrate 33, wherein the thermosetting polymer film 32 is made of a polymer material selected from the group consisting of polyethers or polyamides.

於本較佳實施例中,所述含浸熱固性樹脂的纖維強化材料31是含浸環氧樹脂的碳纖維預浸布,該熱固性高分子膜片32是聚氨基甲酸酯(polyurethane,PU)所製成。In the preferred embodiment, the fiber-reinforced material 31 impregnated with the thermosetting resin is a carbon fiber prepreg impregnated with an epoxy resin, and the thermosetting polymer film 32 is made of polyurethane (PU). .

接著,如步驟22所示,將該複合基材33置於一熱壓模具200中熱壓成為一半成品34,該半成品34包括一由該熱固性高分子膜片32所形成的中介層341,及一位在該中介層341內且由所述纖維強化材料31形成的本體342。其中,該半成品34的本體342具有相反的一第一表面343與一第二表面344,及一環繞該第一表面343與該第二表面344周緣的環繞面345,該中介層341是包覆該第二表面344與該環繞面345。Then, as shown in step 22, the composite substrate 33 is placed in a hot press mold 200 and heat-pressed into a semi-finished product 34. The semi-finished product 34 includes an interposer 341 formed of the thermosetting polymer film 32, and A body 342 formed in the interposer 341 and formed of the fiber reinforcement 31. The body 342 of the semi-finished product 34 has an opposite first surface 343 and a second surface 344, and a surrounding surface 345 surrounding the first surface 343 and the second surface 344. The interposer 341 is coated. The second surface 344 is adjacent to the surrounding surface 345.

在此要特別說明的是,於本較佳實施例中,該中介層341是包覆該第二表面344與該環繞面345,在實際應用上,可以透過熱壓模具200的設計,或是改變該熱固性高分子膜片32與所述纖維強化材料31的堆叠方式,而使該中介層341僅包覆該環繞面345,依然可達成相同的功效。It should be particularly noted that, in the preferred embodiment, the interposer 341 covers the second surface 344 and the surrounding surface 345. In practical applications, the design of the hot stamping die 200 can be transmitted, or The stacking manner of the thermosetting polymer film 32 and the fiber reinforcing material 31 is changed, and the interposer 341 is only coated on the surrounding surface 345, and the same effect can be achieved.

然後,如步驟23所示,在該半成品34的中介層341上塗覆黏著劑以形成一黏著層346。最後,如步驟24所示,將該半成品34置於一成型模具201中,利用射出成型技術將熱塑性高分子材料充填於該成型模具201中,以成型出與該黏著層346相互結合的結合機構35,進而獲得一具結合機構35之纖維強化產品36。Then, as shown in step 23, an adhesive is applied to the interposer 341 of the semi-finished product 34 to form an adhesive layer 346. Finally, as shown in step 24, the semi-finished product 34 is placed in a molding die 201, and a thermoplastic polymer material is filled in the molding die 201 by an injection molding technique to form a bonding mechanism with the adhesive layer 346. 35, which in turn obtains a fiber reinforced product 36 having a bonding mechanism 35.

利用將該熱固性高分子膜片32與所述纖維強化材料31堆叠成為該複合基材33,並經熱壓成為該半成品34,使由該熱固性高分子膜片32所形成的中介層341,能確實包著該由所述纖維強化材料31形成的本體342,藉由強度與剛性較熱塑性樹脂佳的熱固性高分子膜片32所形成的中介層341,以及塗覆於中介層341上的黏著層346,來結合以熱塑性高分子材料射出成型之結合機構35,不但能夠提升該結合機構35與該半成品34之間的結合力與穩定性,還能提供足夠的強度與剛性,避免該半成品34與該結合機構35受外力而容易發生斷裂或剝離。The thermosetting polymer film 32 and the fiber-reinforced material 31 are stacked as the composite substrate 33, and the semi-finished product 34 is hot-pressed to form the interposer 341 formed of the thermosetting polymer film 32. The body 342 formed of the fiber-reinforced material 31, the interposer 341 formed of the thermosetting polymer film 32 having better strength and rigidity than the thermoplastic resin, and the adhesive layer coated on the interposer 341 are indeed included. 346, in combination with the bonding mechanism 35 for injection molding of a thermoplastic polymer material, not only can improve the bonding force and stability between the bonding mechanism 35 and the semi-finished product 34, but also provide sufficient strength and rigidity to avoid the semi-finished product 34 and The bonding mechanism 35 is easily broken or peeled by an external force.

綜上所述,本發明具結合機構之纖維強化產品的製造方法,將該熱固性高分子膜片32與所述纖維強化材料31堆叠成為該複合基材33,並經熱壓成為該半成品34,使由該熱固性高分子膜片32所形成的中介層341,能確實包著該由所述纖維強化材料31形成的本體342,以提供足夠的強度與剛性,配合黏著劑所形成的黏著層346,不但能提升該半成品34與該結合機構35之間的結合力與穩定性,還能有效避免受外力作用而發生斷裂或剝離,故確實能達成本發明之目的。In summary, in the method for manufacturing a fiber-reinforced product having a bonding mechanism, the thermosetting polymer film 32 and the fiber-reinforced material 31 are stacked into the composite substrate 33, and hot-pressed into the semi-finished product 34. The interposer 341 formed of the thermosetting polymer film 32 can surely enclose the body 342 formed of the fiber-reinforced material 31 to provide sufficient strength and rigidity to form an adhesive layer 346 formed by an adhesive. Moreover, not only can the bonding force and stability between the semi-finished product 34 and the bonding mechanism 35 be improved, but also the fracture or peeling can be effectively prevented by the external force, so the object of the present invention can be achieved.

惟以上所述者,僅為本發明之較佳實施例而已,當不能以此限定本發明實施之範圍,即大凡依本發明申請專利範圍及發明說明內容所作之簡單的等效變化與修飾,皆仍屬本發明專利涵蓋之範圍內。The above is only the preferred embodiment of the present invention, and the scope of the invention is not limited thereto, that is, the simple equivalent changes and modifications made by the scope of the invention and the description of the invention are All remain within the scope of the invention patent.

21...將多數含浸熱固性樹脂的纖維強化材料與一熱固性高分子膜片堆叠成為一複合基材twenty one. . . Stacking a majority of fiber-reinforced materials impregnated with thermosetting resin and a thermosetting polymer film into a composite substrate

22...將該複合基材置於一熱壓模具中熱壓成為一半成品,該半成品包括一由該熱固性高分子膜片所形成的中介層,及一位在該中介層內且由所述纖維強化材料形成的本體twenty two. . . The composite substrate is hot pressed into a semi-finished product in a hot pressing mold, the semi-finished product comprises an interposer formed by the thermosetting polymer film, and one bit in the interposer and composed of the fiber reinforcing material Formed ontology

23...在該半成品的中介層上塗覆黏著劑以形成一黏著層twenty three. . . Applying an adhesive to the interposer of the semi-finished product to form an adhesive layer

24...將該半成品置於一成型模具中,利用射出成型技術將熱塑性高分子材料充填於該成型模具中,以成型出與該黏著層相互結合的結合機構twenty four. . . The semi-finished product is placed in a molding die, and a thermoplastic polymer material is filled in the molding die by an injection molding technique to form a bonding mechanism combined with the adhesive layer.

200...熱壓模具200. . . Hot pressing mold

201...成型模具201. . . Molding mold

31...纖維強化材料31. . . Fiber reinforced material

32...熱固性高分子膜片32. . . Thermosetting polymer membrane

33...複合基材33. . . Composite substrate

34...半成品34. . . Semi finished product

341...中介層341. . . Intermediary layer

342...本體342. . . Ontology

343...第一表面343. . . First surface

344...第二表面344. . . Second surface

345...環繞面345. . . Surrounding surface

346...黏著層346. . . Adhesive layer

35...結合機構35. . . Combined mechanism

36...纖維強化產品36. . . Fiber reinforced products

圖1是一流程圖,說明本發明具結合機構之纖維強化產品的製造方法的較佳實施例;及1 is a flow chart showing a preferred embodiment of a method of manufacturing a fiber reinforced product having a bonding mechanism of the present invention;

圖2是一示意圖,輔助說明圖1。Figure 2 is a schematic view of the assistance of Figure 1.

21...將多數含浸熱固性樹脂的纖維強化材料與一熱固性高分子膜片堆叠成為一複合基材twenty one. . . Stacking a majority of fiber-reinforced materials impregnated with thermosetting resin and a thermosetting polymer film into a composite substrate

22...將該複合基材置於一熱壓模具中熱壓成為一半成品,該半成品包括一由該熱固性高分子膜片所形成的中介層,及一位在該中介層內且由所述纖維強化材料形成的本體twenty two. . . The composite substrate is hot pressed into a semi-finished product in a hot pressing mold, the semi-finished product comprises an interposer formed by the thermosetting polymer film, and one bit in the interposer and composed of the fiber reinforcing material Formed ontology

23...在該半成品的中介層上塗覆黏著劑以形成一黏著層twenty three. . . Applying an adhesive to the interposer of the semi-finished product to form an adhesive layer

24...將該半成品置於一成型模具中,利用射出成型技術將熱塑性高分子材料充填於該成型模具中,以成型出與該黏著層相互結合的結合機構twenty four. . . The semi-finished product is placed in a molding die, and a thermoplastic polymer material is filled in the molding die by an injection molding technique to form a bonding mechanism combined with the adhesive layer.

Claims (4)

一種具結合機構之纖維強化產品的製造方法,包含:(A)將多數含浸熱固性樹脂的纖維強化材料與一熱固性高分子膜片堆叠成為一複合基材,其中,該熱固性高分子膜片是選自聚醚類或聚醯胺高分子材料所製成;(B)將該複合基材置於一熱壓模具中熱壓成為一半成品,該半成品包括一由該熱固性高分子膜片所形成的中介層,及一位在該中介層內且由所述纖維強化材料形成的本體;(C)在該中介層上塗覆黏著劑以形成一黏著層;及(D)將該半成品置於一成型模具中,利用射出成型技術將熱塑性高分子材料充填於該成型模具中,以成型出一與該黏著層相互結合的結合機構,進而獲得一具結合機構之纖維強化產品。A method for manufacturing a fiber-reinforced product having a bonding mechanism, comprising: (A) stacking a plurality of fiber-reinforced materials impregnated with a thermosetting resin and a thermosetting polymer film into a composite substrate, wherein the thermosetting polymer film is selected (B) the composite substrate is placed in a hot pressing mold and heat-pressed into a semi-finished product comprising a thermosetting polymer film formed by the thermosetting polymer film. An interposer, and a body formed in the interposer and formed of the fiber-reinforced material; (C) applying an adhesive on the interposer to form an adhesive layer; and (D) placing the semi-finished product in a molding In the mold, a thermoplastic polymer material is filled in the molding die by an injection molding technique to form a bonding mechanism that is bonded to the adhesive layer, thereby obtaining a fiber-reinforced product having a bonding mechanism. 根據申請專利範圍第1項所述之具結合機構之纖維強化產品的製造方法,其中,該步驟(B)之半成品的本體具有相反的一第一表面與一第二表面,及一環繞該第一表面與該第二表面周緣的環繞面,該中介層是包覆該第二表面與該環繞面。The method for manufacturing a fiber-reinforced product having a bonding mechanism according to the first aspect of the invention, wherein the body of the semi-finished product of the step (B) has an opposite first surface and a second surface, and a surrounding a surrounding surface of the surface and the periphery of the second surface, the interposer is covering the second surface and the surrounding surface. 根據申請專利範圍第1項所述之具結合機構之纖維強化產品的製造方法,其中,該步驟(B)之半成品的本體具有相反的一第一表面與一第二表面,及一環繞該第一表面與該第二表面周緣的環繞面,該中介層是環繞該環繞面。The method for manufacturing a fiber-reinforced product having a bonding mechanism according to the first aspect of the invention, wherein the body of the semi-finished product of the step (B) has an opposite first surface and a second surface, and a surrounding A surrounding surface of the surface and the periphery of the second surface, the interposer surrounding the surrounding surface. 根據申請專利範圍第1至3項中任一項所述之具結合機構之纖維強化產品的製造方法,其中,該步驟(A)中所述含浸熱固性樹脂的纖維強化材料是含浸環氧樹脂的碳纖維預浸布,該熱固性高分子膜片是聚氨基甲酸酯所製成。The method for producing a fiber-reinforced product having a bonding mechanism according to any one of claims 1 to 3, wherein the fiber-reinforced material impregnated with the thermosetting resin in the step (A) is impregnated with an epoxy resin. A carbon fiber prepreg, which is made of polyurethane.
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