TWI435775B - Production equipment for renewable energy released from waste plastics, tyres, and engine oil - Google Patents

Production equipment for renewable energy released from waste plastics, tyres, and engine oil Download PDF

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TWI435775B
TWI435775B TW99127014A TW99127014A TWI435775B TW I435775 B TWI435775 B TW I435775B TW 99127014 A TW99127014 A TW 99127014A TW 99127014 A TW99127014 A TW 99127014A TW I435775 B TWI435775 B TW I435775B
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gas
oil
water
waste
stage
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TW99127014A
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TW201206580A (en
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Kwok Sing Lee
Wenji Xu
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South China Reborn Resources Zhongshan Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W30/00Technologies for solid waste management
    • Y02W30/20Waste processing or separation

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  • Production Of Liquid Hydrocarbon Mixture For Refining Petroleum (AREA)
  • Separation, Recovery Or Treatment Of Waste Materials Containing Plastics (AREA)
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Description

廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備Recycling energy production equipment for waste plastics, tires and waste engine oil

本發明係關於一套廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,特別是該裝備在全程的生產過程中所產生的各類物質,直接通過設備的互聯系統將所有剩餘渣、氣、水等全部造成具較大經濟價值的產品。The invention relates to a comprehensive utilization production equipment for renewable energy of waste plastics, tires and waste engine oil, in particular, various substances generated in the whole process of the production process, and all remaining slag and gas are directly passed through the interconnection system of the equipment. Water, water, etc. all cause products with greater economic value.

隨著環保工業的持續發展,已將環保處理的實質應用日趨商業化方向,發展廢舊塑膠、輪胎、廢機油的再生資源利用也趨向成熟,但是這些項目現時大部分都是在單一利用和發展,在再生利用過程中的剩餘產物沒有進行循環利用的全面思考。例如:以單一廢舊塑膠、輪胎煉油設備為例,大多數的設備基本沒有考慮到真正的尾氣環保處理,也沒有考慮到熱氣回收再利用的課題,對於煉油的剩餘物粗雜黑的安全環保處理更是輕描淡說或根本置於不理。在廢舊塑膠、輪胎煉油所產生的可燃氣體(無毒氣體),只是回爐燃燒,但是在實在生產中,當產生氣體的時間與用於裂解爐的燃燒時間是兩個概念,根本在氣體回爐燃燒至裂解完成的這一時間內,氣體的回燒量只有三分之二,剩餘的可燃燒氣體就只能向天排放,從上述所指出的環保再生設備,其實還是不環保的,可能再次造成二次污染問題,同時把大量有經濟價值的可再利用資源白白浪費,的確是一種缺陷。本發明的再生能源綜合利用生產裝備,一般來說,包括有裂解催化爐,該裂解催化爐是臥式內置可順逆旋轉360度,並帶自動隨機刮壁式反應釜,如申請人在先申請的專利申請號為CN201010148298.2及CN201010147465.1的申請文件中所提到的反應釜刮壁器和與其配合的一種臥式廢舊塑膠、輪胎裂解爐;同時,該裂解爐體接有的尾氣環保裝置系統如申請人在先申請的專利申請號為CN201010168879.2的申請檔中提到的燃料裂解爐尾氣處理系統;以及為了確保燃氣安全運動而設置有附設雙重水封安全裝置的水洗器,具體結構在發明人在先申請且已授權的專利號為CN200510037543.1的申請文件中所提及;另外,該系統設備中用到的蒸餾催化塔的加熱方式採用可控矽中頻加熱方法,具體結構在發明人直屬子公司在先申請且已授權的專利號為CN200510101143.2的申請文件中所提及;該系統設備中用到的環保高能低硫煤系統具體使用方法在申請人在先申請的專利申請號為CN201010148172.5的申請文件中已經提及。With the continuous development of the environmental protection industry, the practical application of environmental protection has become more and more commercialized. The development of renewable resources for the development of waste plastics, tires and used motor oil has also matured. However, most of these projects are currently being used and developed in a single way. The remaining products in the recycling process are not fully considered for recycling. For example, taking a single waste plastic and tire refining equipment as an example, most of the equipment basically does not take into account the real environmental treatment of exhaust gas, nor does it take into account the subject of hot gas recovery and reuse, and the safe and environmentally friendly treatment of the residue of refining. It is even understated or simply ignored. The combustible gas (non-toxic gas) produced in waste plastics and tire refining is only burned back to the furnace, but in actual production, when the gas is generated and the burning time for the cracking furnace is two concepts, the gas is burned back to the furnace. During this period of cracking completion, the gas is only burned back to two-thirds, and the remaining combustible gas can only be discharged to the sky. From the above-mentioned environmentally-friendly recycling equipment, it is actually not environmentally friendly and may cause two again. The problem of secondary pollution, while wasting a lot of economically valuable reusable resources, is indeed a defect. The regenerative energy comprehensive utilization production equipment of the invention generally comprises a cracking catalytic furnace, which is horizontally built-in and can be rotated 360 degrees in reverse, and has an automatic random scraping wall reaction kettle, if the applicant applies in advance The patent application No. CN201010148298.2 and CN201010147465.1 mentioned in the application documents of the reactor scraper and a horizontal waste plastic and tire cracking furnace cooperated with it; at the same time, the cracking furnace body is connected with the exhaust gas environmental protection The fuel system furnace tail gas treatment system as mentioned in the application file of the applicant's prior application patent application No. CN201010168879.2; and a water washer equipped with a double water seal safety device for ensuring safe gas movement, The specific structure is mentioned in the application file of the inventor's prior application and authorized patent number CN200510037543.1; in addition, the heating method of the distillation catalytic tower used in the system equipment adopts a controllable medium frequency heating method. The specific structure is mentioned in the application file of the patent application number CN200510101143.2, which was previously filed by the inventor's direct subsidiary; Patent Application No. sulfur coal used in the system environment specific use high energy applicant previously filed application CN201010148172.5 of documents already mentioned.

本發明的目的在於解決現有再生環保設備的缺陷問題,而提供一整套廢舊塑膠、輪胎、廢機油的再生資源綜合利用的生產設備,該設備能夠較充分的利用再生能源,使渣、水、氣、熱能循環發展利用,形成具有可觀經濟價值的循環環保生產鏈,大大改變了現有裝備的單項功能。The object of the present invention is to solve the defects of the existing recycling environmental protection equipment, and provide a complete set of production equipment for comprehensive utilization of renewable resources of waste plastics, tires and waste engine oil, which can fully utilize renewable energy to make slag, water and gas. The development and utilization of thermal energy cycle has formed a circular environmental protection production chain with considerable economic value, which has greatly changed the individual functions of existing equipment.

為實現上述目的,本發明採用了下述技術方案:一種廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,包括相互配合的主體設備、第二級裝置、第三級裝置、裂解爐尾氣處理環保系統、可燃氣體發電的再利用系統、熱氣回收系統以及環保高能低硫煤系統。In order to achieve the above object, the present invention adopts the following technical solution: a recycling energy comprehensive utilization production equipment of waste plastics, tires and waste engine oil, including mutual cooperation main equipment, second-stage device, third-stage device, cracking furnace exhaust gas Handling environmental protection systems, recycling systems for combustible gas power generation, hot gas recovery systems, and environmentally friendly high-energy low-sulfur coal systems.

其中所述的主體設備包括:由輸送帶為起點,將石油產品廢棄物輸送到由路軌移動的氣壓式自動進料機,將原料推進熱裂解爐進行裂解催化得到油氣混合物,該熱裂解爐帶有一個自動隨機設置的帶有刮壁刀的反應釜,同時爐體接有裂解尾氣環保裝置系統,隨之後級設備順序為氣蠟油分離器作為由熱裂解爐所產生油氣裏蠟油首次分離工具,再依次連接有第一級冷凝器、水封式氣油分離器、水封安全裝置、水封式負壓裝置、重油承載容器,當油氣混合物經臥式冷凝器進入混合油承載容器,未能液化的可燃氣體隨之進入立式燃氣中和水洗器,該水洗器附設雙重水封安全裝置,可燃氣體經水洗器水洗後進入可燃氣體發電的再利用系統。The main equipment includes: a pneumatic automatic feeder fed by a conveyor belt to a petroleum product waste to be moved by a rail, and the raw material is pushed into a thermal cracking furnace for cracking and catalyzing to obtain an oil and gas mixture, the thermal cracking furnace belt There is a reactor with a scraping knife that is automatically and randomly set. At the same time, the furnace body is connected with a cracking tail gas environmental protection device system. The gas chromatographic oil separator is used as the first separation of the oil and gas in the oil and gas produced by the thermal cracking furnace. The tool is further connected with a first-stage condenser, a water-sealed gas oil separator, a water seal safety device, a water-sealed negative pressure device, and a heavy oil carrying container, and when the oil and gas mixture enters the mixed oil carrying container through the horizontal condenser, The combustible gas that has not been liquefied then enters the vertical gas neutralizing water scrubber, which is equipped with a double water seal safety device, and the combustible gas is washed by the water washer and then enters the recycling system of the combustible gas power generation.

所述的第二級裝置包括蒸餾催化塔,該設備的被蒸餾物來自於主體設備中的混合油承載容器中的混合油,蒸餾催化塔的加熱方式採用可控矽中頻加熱方法,有一中頻加熱裝置與蒸餾催化塔相連,當裂解後的廢舊塑膠油、輪胎油或者廢機油進入蒸餾塔處理後根據各種物料的不同氣化溫度的切線進入立式冷凝器再經水封安全器,進入柴、汽油承載容器。The second stage device comprises a distillation catalytic tower, the distillate of the device is derived from the mixed oil in the mixed oil carrying container in the main equipment, and the heating method of the distillation catalytic tower adopts a controllable medium frequency heating method, one medium The frequency heating device is connected to the distillation catalytic tower. When the cracked waste plastic oil, tire oil or waste engine oil enters the distillation tower, the tangential line of different gasification temperatures of various materials enters the vertical condenser and then passes through the water seal safety device. Firewood and gasoline carrying containers.

所述的第三級裝置是柴油精練機汽油脫膠設備,該設備由第一級化學脫碳除雜合成器為起點,經除碳漂白器、脫蠟除膠器,所述第二級裝置中的柴、汽油承載容器中的油品經輸入管道進入該脫蠟除膠器,該脫蠟除膠器為圓桶錐形攪拌器,攪器內設有立向擋板,底部設有鼓動沸騰裝置,攪拌流型以切流方式攪動;所需添加的化學劑裝置設置於添加劑容器內,並分為化學劑添加區及鹼性液體添加區,經處理後的有用物再輸送到渣液分離機,該機網目從200目至350目,經過濾過的流體輸送到精煉油合成罐,該罐的工作形式分開二級過濾,第一級為逆向加壓力過濾,第二級為順向過濾,此二級的過濾層均設置有過濾介質承載孔板,其過濾介質為固體粒狀物,被過濾物所要添加化學劑添加物置於添加劑容器內,經以上處理之後所得油品,經檢查合格後進入油庫儲存區,同時由各個精煉階段所產生的廢料由專用輸送裝置輸送至環保高能低硫煤系統再利用,經各個精煉階段所產生的廢氣、廢味經專用排氣管道通過水浴池及活性碳篩檢程式排出。The third-stage device is a diesel refining machine gasoline degumming device, which is started from a first-stage chemical decarburization and decontamination synthesizer, and is subjected to a carbon removal bleacher, a dewaxing degumming device, and the second-stage device. The oil in the diesel and gasoline carrying container enters the dewaxing and degreasing device through the input pipe. The dewaxing degumming device is a cone-shaped cone agitator, the vertical baffle is arranged in the stirrer, and the bottom is provided with agitating boiling. The device and the stirring flow type are agitated by a shear flow method; the chemical agent device to be added is disposed in the additive container, and is divided into a chemical agent addition zone and an alkaline liquid addition zone, and the processed useful matter is transported to the slag liquid separation. Machine, the machine mesh from 200 mesh to 350 mesh, the filtered fluid is transported to the refined oil synthesis tank, the working form of the tank is separated by secondary filtration, the first stage is reverse pressure filtration, the second stage is forward filtration, The filter layer of the second stage is provided with a filter medium bearing orifice plate, and the filter medium is a solid granular material, and the chemical additive added to the filtrate is placed in the additive container, and the oil obtained after the above treatment is tested. Enter the oil depot The storage area and the waste generated by each refining stage are transported by the special conveying device to the environmentally-friendly high-energy low-sulfur coal system for reuse. The exhaust gas and waste smell generated by each refining stage are passed through the special exhaust pipe through the water bath and the activated carbon sieve. The program is discharged.

所述的脫碳除雜合成器、除碳漂白器、脫蠟除膠器下端均連接廢渣排除管道並採用壓縮空氣壓送往環保高能低硫煤系統,在渣液分離機至精煉油合成罐之間同樣設置有添加劑容器。The decarburization and decontamination synthesizer, the carbon bleaching device, the dewaxing and degumming device are connected to the waste slag removal pipeline at the lower end and are sent to the environmentally-friendly high-energy low-sulfur coal system by using compressed air pressure, in the slag liquid separation machine to the refined oil synthesis tank. An additive container is also provided between them.

所述的裂解爐尾氣處理環保裝置系統與熱裂解爐的排煙口相連,該系統包括有帶多重水簾排氣管道,該多重水簾排氣管道的排氣口連接爐體燃燒室,中間裝有熱氣水緩衝室,緩衝室下部裝有雙重濕碳粒篩檢程式,另一端連接雙塔型濕式氣固分離器,氣固分離器尾端由管道連接引風器,下端由管道連接引風器的後部分水管,引水管利用引風器的壓力將水氣推入設備尾部的煙囪,煙囪由三部分組成,下部為圓桶罐狀體的水氣分離器,中為用於氣相分離的熱交換器,上部為排氣管道,該管道中部裝有鹼性水液噴淋器。The cracking furnace tail gas treatment environmental protection device system is connected to the exhaust port of the thermal cracking furnace, and the system comprises a multiple water curtain exhaust pipe, and the exhaust port of the multiple water curtain exhaust pipe is connected to the furnace body combustion chamber, the middle It is equipped with a hot gas water buffer chamber. The lower part of the buffer chamber is equipped with a double wet carbon particle screening program, and the other end is connected with a double tower type wet gas-solid separator. The tail end of the gas-solid separator is connected to the air inlet by a pipe, and the lower end is connected by a pipe. The water pipe in the rear part of the air deflector, the water pipe is used to push the water into the chimney at the tail of the equipment by the pressure of the air inlet. The chimney is composed of three parts, and the lower part is a water gas separator of the can body, and the middle is used for gas. The phase separated heat exchanger has an exhaust pipe at the upper part and an alkaline water sprayer in the middle of the pipe.

所述的可燃氣體發電再利用系統連接於主體設備中的燃氣管道,經專用燃氣壓縮機將燃氣壓縮到0.5MPA同時起到第一級燃氣脫水作用時,再將氣體送到第二級專用燃氣壓縮機,此壓縮機再將燃氣壓縮至1MPA同時起到第二次燃氣脫水作用時,將可燃氣體送到燃氣儲存容器,儲存器設置有兩個出氣口,一個出氣口通往主體設備的熱裂解爐作為該爐的燃料,其氣體通過方法是經二次減壓送出,第一次減壓是經減壓設備減壓到0.4-0.5MPA,再經第二個減壓設備由0.4-0.5MPA減至0.1-0.2MPA送到爐膛燃燒;另一個出氣口通往氣體燃料發電機(42),其可燃氣體通過方法是經另一減壓設備減壓到0.1-0.5MPA後再進入氣體燃料發電機,發電機採用機械內混方式。The flammable gas power generation recycling system is connected to the gas pipeline in the main equipment, and when the gas is compressed to 0.5 MPA by a special gas compressor and simultaneously acts as a first-stage gas dehydration, the gas is sent to the first A two-stage special gas compressor, which compresses the gas to 1MPA and simultaneously acts as a second gas dehydration, and sends the combustible gas to the gas storage container. The reservoir is provided with two gas outlets, one The thermal cracking furnace leading to the main equipment of the air outlet is used as the fuel of the furnace, and the gas passing method is sent through the second pressure reduction. The first decompression is decompressed to 0.4-0.5 MPA by the decompression device, and then the second One decompression device is reduced from 0.4-0.5 MPA to 0.1-0.2 MPA for furnace combustion; the other outlet port leads to the gas fuel generator (42), and the flammable gas passing method is decompressed to 0.1 by another decompression device. After -0.5MPA, it enters the gas fuel generator, and the generator adopts mechanical internal mixing.

所述的熱氣回收系統由發電機工作運行所產生的熾熱氣體通過氣-水交換器對熱氣收集,該氣-水交換器採用導熱管導熱式,通過導熱管道以銅的傳熱系統1000倍以上導熱至循環水中,熱水經熱泵送到排煙櫃,再由排煙櫃通過熱空氣輸出管將120度以上的熱空氣送到環保高能低硫煤系統的烘乾設備利用,所經過熱交換的發電機熱空氣再經熱交換器降溫後,經煙氣道排出。The hot gas recovery system collects hot gas generated by the working operation of the generator through the gas-water exchanger, and the gas-water exchanger adopts a heat conduction type of a heat pipe, and the heat transfer system of the copper is 1000 times or more through the heat conduction pipe. The heat is transferred to the circulating water, and the hot water is pumped to the fume hood through the heat pump, and then the hot air of 120 degrees or more is sent to the drying equipment of the environmentally-friendly high-energy low-sulfur coal system through the hot air outlet pipe through the exhaust fume cabinet, and the heat exchange is performed. After the generator hot air is cooled by the heat exchanger, it is discharged through the flue gas passage.

所述的導熱管道是若干真空熱導管,在真空導熱管一端設置有金屬散熱輪,在相鄰真空熱導管之間設置有煙水隔層以及保溫層,所述的氣-水交換器一端設置有熱氣引入管以及消音器,底部設置有碳塵清潔口,並在設置熱氣引入管的一端設置有污水排放口,以及循環熱水管用以連接熱泵與氣-水交換器,所述的熱交換器設置於氣-水交換器的相對設置污水排放口另一端,該熱交換器上下端設置有循環冷水出口,上端設置有循環冷水入口,同時該端通過設置有循環熱水管與排煙櫃相連。The heat conducting pipe is a plurality of vacuum heat pipes, and a metal heat dissipating wheel is disposed at one end of the vacuum heat pipe, and a smoke water partition layer and a heat insulating layer are disposed between the adjacent vacuum heat pipes, and the gas-water exchanger is disposed at one end. There is a hot gas introduction pipe and a muffler, a carbon dust cleaning port is arranged at the bottom, a sewage discharge port is arranged at one end of the hot gas introduction pipe, and a circulating hot water pipe is connected to the heat pump and the gas-water exchanger, and the heat exchange is performed. The device is disposed at the other end of the oppositely disposed sewage discharge port of the gas-water exchanger, the upper and lower ends of the heat exchanger are provided with a circulating cold water outlet, the upper end is provided with a circulating cold water inlet, and the end is connected with the smoke exhausting cabinet through a circulating hot water pipe .

所述的環保高能低硫煤系統將廢塑膠、廢輪胎、煉油過程中所不能氣化的餘渣即粗黑碳再利用,包括有將粗碳黑進行陳化的人工陳化器,再經熱蒸氣處理器處理,再將處理過的粗炭黑作為主料,在其中添加配伍物料,配伍材料為原煤、二茂鐵、六次甲基四銨、氫氧化鈉、生石灰和黏結劑,形成煤基料,其中主料在煤基料中所占的重量百分比為45%-60%;然後將煤基料製成成品煤,所述的粗碳黑通過螺旋輸送機及碳黑輸入帶輸送。The environmentally-friendly high-energy low-sulfur coal system reuses the waste plastic, the waste tire, and the residual slag which cannot be vaporized during the refining process, that is, the crude black carbon, including the artificial aging device for aging the coarse carbon black, and then The steam treatment is carried out, and the treated crude carbon black is used as the main material, and the compatibility materials are added thereto, and the compatibility materials are raw coal, ferrocene, hexamethylene tetraammonium, sodium hydroxide, quicklime and binder, forming a coal base material, wherein the main material accounts for 45%-60% by weight of the coal base material; then the coal base material is made into a finished coal, and the crude carbon black is conveyed through a screw conveyor and a carbon black input belt. .

通過上述技術方案從而該發明具有下述有益效果:將現有設備的單項性進行整合,相對現有單項技術的單一環保生產概念來說,能夠有效杜絕環保生產後的剩餘物對土地及空氣環境造成的二次污染,或者是因為單一環保方式生產前的更具危害性的污染;本發明的系統裝備是一組循環環保生產及再利用設備,從第一次的環保生產到剩餘渣物及有害氣體、高溫氣體再作第二次的環保生產再利用,能夠起到真正廢棄物環保生產循環經濟鏈,可能達到或達到無污水排放、無煙塵排放、無室溫排放、無有害氣體排放、無惡臭、無刺激性氣味排放、噪音低、自產能源循環利用的良好的有益效果。Through the above technical solution, the invention has the following beneficial effects: the integration of the individual items of the existing equipment, and the single environmentally friendly production concept of the existing single technology can effectively prevent the residues of the environmentally friendly production from causing the land and the air environment. Secondary pollution, or because of a more environmentally friendly way to produce more hazardous pollution; the system equipment of the present invention is a set of environmentally friendly production and reuse equipment, from the first environmentally friendly production to residual slag and harmful gases The high-temperature gas will be reused for the second time in environmental protection production, which can play a recycling industry chain of real waste environmental protection production, and may achieve or achieve no sewage discharge, smokeless dust discharge, no room temperature discharge, no harmful gas emissions, no foul smell It has no irritating odor emission, low noise, and good beneficial effects of self-produced energy recycling.

下面結合附圖對本發明作出進一步的說明。The invention will now be further described with reference to the accompanying drawings.

如圖1至圖10所示,這種廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,包括相互配合的主體設備、第二級裝置、第三級裝置、裂解爐尾氣處理環保系統、可燃氣體發電的再利用系統、熱氣回收系統以及環保高能低硫煤系統。As shown in Figure 1 to Figure 10, the recycled energy comprehensive utilization production equipment of waste plastics, tires and waste engine oil includes the main equipment, the second-stage device, the third-stage device, the cracking furnace tail gas treatment and environmental protection system. Recycling system for combustible gas power generation, hot gas recovery system, and environmentally friendly high-energy low-sulfur coal system.

其中所述的主體設備包括:由輸送帶2為起點,將石油產品廢棄物輸送到由路軌移動的氣壓式自動進料機1,將原料推進熱裂解爐3進行裂解催化得到油氣混合物,該熱裂解爐帶有一個自動隨機設置的帶有刮壁刀4的反應釜5,同時爐體接有裂解尾氣環保裝置系統,隨之後級設備順序為氣蠟油分離器6作為由熱裂解爐所產生油氣裏蠟油首次分離工具,再依次連接有第一級冷凝器7、水封式氣油分離器8、水封安全裝置9、水封式負壓裝置10、重油承載容器11,當油氣混合物經臥式冷凝器12進入混合油承載容器13,未能液化的可燃氣體隨之進入立式燃氣中和水洗器14,該水洗器附設雙重水封安全裝置15,可燃氣體經水洗器水洗後進入可燃氣體發電的再利用系統。The main equipment includes: the pneumatic product automatic waste feeder 1 is transported from the conveyor belt 2 as a starting point, and the raw material is pushed into the thermal cracking furnace 3 to carry out cracking and catalysis to obtain an oil and gas mixture. The cracking furnace is provided with an automatically randomly arranged reaction vessel 5 with a scraping knife 4, and the furnace body is connected with a cracking tail gas environmental protection device system, and the subsequent stage equipment is sequentially produced by the thermal cracking furnace as a gas wax oil separator 6 The first separation tool for the wax oil in the oil and gas, and then connected with the first stage condenser 7, the water-sealed gas oil separator 8, the water seal safety device 9, the water seal type negative pressure device 10, the heavy oil carrying container 11, when the oil and gas mixture After entering the mixed oil carrying container 13 through the horizontal condenser 12, the combustible gas that has not been liquefied enters the vertical gas neutralizing water washing device 14, and the water washing device is provided with a double water seal safety device 15, and the combustible gas is washed by the water washer. Enter the recycling system for combustible gas power generation.

所述的第二級裝置包括蒸餾催化塔16,該設備的被蒸餾物來自於主體設備中的混合油承載容器13中的混合油,蒸餾催化塔的加熱方式採用可控矽中頻加熱方法,有一中頻加熱裝置17與蒸餾催化塔相連,當裂解後的廢舊塑膠油、輪胎油或者廢機油進入蒸餾塔處理後根據各種物料的不同氣化溫度的切線進入立式冷凝器18再經水封安全器19,進入柴、汽油承載容器20。The second stage device comprises a distillation catalytic tower 16, the distillate of the device is derived from the mixed oil in the mixed oil carrying container 13 in the main equipment, and the heating method of the distillation catalytic tower adopts a controllable medium frequency heating method. An intermediate frequency heating device 17 is connected to the distillation catalytic tower. When the cracked waste plastic oil, tire oil or waste engine oil enters the distillation column, the tangential line of different gasification temperatures of various materials enters the vertical condenser 18 and then passes through the water seal. The safety device 19 enters the diesel and gasoline carrying container 20.

所述的第三級裝置是柴油精練機汽油脫膠設備,該設備由第一級化學脫碳除雜合成器21為起點,經除碳漂白器22、脫蠟除膠器23,所述第二級裝置中的柴、汽油承載容器20中的油品經輸入管道進入該脫蠟除膠器,該脫蠟除膠器為圓桶錐形攪拌器,攪器內設有立向擋板,底部設有鼓動沸騰裝置,攪拌流型以切流方式攪動;所需添加的化學劑裝置設置於添加劑容器24內,並分為化學劑添加區及鹼性液體添加區,經處理後的有用物再輸送到渣液分離機25,該機網目從200目至350目,經過濾過的流體輸送到精煉油合成罐26,該罐的工作形式分開二級過濾,第一級為逆向加壓力過濾,第二級為順向過濾,此二級的過濾層均設置有過濾介質承載孔板,其過濾介質為固體粒狀物,被過濾物所要添加化學劑添加物置於添加劑容器24內,經以上處理之後所得油品經檢查合格後進入油庫儲存區,同時由各個精煉階段所產生的廢料由專用輸送裝置輸送至環保高能低硫煤系統再利用,經各個精煉階段所產生的廢氣、廢味經專用排氣管道通過水浴池及活性碳篩檢程式排出。The third stage device is a diesel refining machine gasoline degumming device, which is started by a first-stage chemical decarburization and decontamination synthesizer 21, a decarburization bleacher 22, a dewaxing degumming device 23, and a second The oil in the diesel and gasoline carrying container 20 in the stage device enters the dewaxing and degreaser through an input pipe, and the dewaxing and degreaser is a cone-shaped agitator, and the baffle is provided with a vertical baffle and a bottom. An agitating boiling device is provided, and the stirring flow pattern is agitated by a shear flow method; the chemical agent device to be added is disposed in the additive container 24, and is divided into a chemical agent addition zone and an alkaline liquid addition zone, and the treated useful object is further It is sent to the slag liquid separator 25, the mesh of the machine is from 200 mesh to 350 mesh, and the filtered fluid is sent to the refined oil synthesis tank 26, the working form of the tank is separated by the secondary filtration, and the first stage is the reverse pressure filtration, the first stage The second stage is a forward filtration. The secondary filtration layers are provided with a filter medium bearing orifice plate, and the filter medium is a solid granular material, and the chemical additive added to the filtrate is placed in the additive container 24, after the above treatment After the obtained oil has passed the inspection Entering the oil depot storage area, the waste generated by each refining stage is transported by the special conveying device to the environmentally-friendly high-energy low-sulfur coal system for reuse. The exhaust gas and waste smell generated by each refining stage pass through the special bath and pass through the water bath and the activity. The carbon screening program is discharged.

所述的脫碳除雜合成器21、除碳漂白器22、脫蠟除膠器23下端均連接廢渣排除管道49並採用壓縮空氣50壓送往環保高能低硫煤系統,在渣液分離機至精煉油合成罐26之間同樣設置有添加劑容器24。The decarburization and decontamination synthesizer 21, the decarburization bleacher 22, the dewaxing and degumming device 23 are connected to the waste residue removal pipe 49 at the lower end, and are compressed by the compressed air 50 to the environmentally-friendly high-energy low-sulfur coal system, in the slag liquid separation machine. An additive container 24 is also provided between the refined oil synthesis tanks 26.

所述的裂解爐尾氣處理環保裝置系統與熱裂解爐的排煙口相連,該系統包括有帶多重水簾排氣管道27,該帶多重水簾排氣管道27的排氣口連接爐體燃燒室,中間裝有熱氣水緩衝室28,熱氣水緩衝室28下部裝有雙重濕碳粒篩檢程式29,另一端連接雙塔型濕式氣固分離器30,雙塔型濕式氣固分離器30尾端由管道連接引風器31,下端由管道連接引風器的後部分水管,引水管利用引風器的壓力將水氣推入設備尾部的煙囪32,煙囪由三部分組成,下部為圓桶罐狀體的水氣分離器33,中為用於氣相分離的熱交換器34,上部為排氣管道35,該管道中部裝有鹼性水液噴淋器36。The cracking furnace tail gas treatment environmental protection device system is connected to the exhaust port of the thermal cracking furnace, and the system comprises a multiple water curtain exhaust pipe 27, and the exhaust port with the multiple water curtain exhaust pipe 27 is connected to the furnace body for combustion. In the middle, there is a hot gas water buffer chamber 28 in the middle, a hot wet water buffer chamber 28 is equipped with a double wet carbon particle screening program 29, and the other end is connected to a double tower wet gas solid separator 30, and the double tower type wet gas solid separation The end of the device 30 is connected to the air blower 31 by a pipe, and the lower end is connected by a pipe to the water pipe at the rear part of the air blower. The water pipe pushes the water gas into the chimney 32 at the tail of the device by the pressure of the air blower. The chimney is composed of three parts, the lower part It is a water gas separator 33 of a can body, a heat exchanger 34 for gas phase separation, an exhaust pipe 35 at the upper portion, and an alkaline water sprayer 36 in the middle of the pipe.

所述的可燃氣體發電再利用系統連接於主體設備中的燃氣管道37,經專用燃氣壓縮機將燃氣壓縮到0.5MPA同時起到第一級燃氣脫水作用時,再將氣體送到第二級專用燃氣壓縮機38,此壓縮機再將燃氣壓縮至1MPA同時起到第二次燃氣脫水作用時,將可燃氣體送到燃氣儲存容器39,燃氣儲存容器39設置有兩個出氣口,一個出氣口通往主體設備的熱裂解爐作為該爐的燃料,其氣體通過方法是經二次減壓送出,第一次減壓是經減壓設備40減壓到0.4-0.5MPA,再經第二個減壓設備41由0.4-0.5MPA減至0.1-0.2MPA送到爐膛燃燒;另一個出氣口通往氣體燃料發電機42,其可燃氣體通過方法是經另一減壓設備減壓到0.1-0.5MPA後再進入氣體燃料發電機42,氣體燃料發電機42採用機械內混方式。The combustible gas power generation reuse system is connected to the gas pipeline 37 in the main equipment, and the gas is compressed to 0.5MPA by a special gas compressor while the first stage gas dehydration is performed, and then the gas is sent to the gas. The second-stage dedicated gas compressor 38, which compresses the gas to 1MPA while performing the second gas dehydration, sends the combustible gas to the gas storage container 39, and the gas storage container 39 is provided with Two outlets, one outlet to the main equipment, the thermal cracking furnace as the fuel of the furnace, the gas passing method is sent through the second pressure reduction, the first decompression is decompressed by the pressure reducing device 40 to 0.4- 0.5MPA is further sent to the furnace by 0.4-0.5MPA to 0.1-0.2MPA through the second decompression device 41; the other outlet is connected to the gas fuel generator 42, and the flammable gas passing method is another reduction The pressure device is depressurized to 0.1-0.5 MPA before entering the gas fuel generator 42, and the gas fuel generator 42 is mechanically mixed.

所述的熱氣回收系統係將由氣體燃料發電機42工作運行所產生的熾熱氣體通過氣-水交換器43收集熱氣,該氣-水交換器43採用導熱管導熱式,通過導熱管道以銅的傳熱系統1000倍以上導熱至循環水中,熱水經熱泵44送到排煙櫃45,再由排煙櫃45通過熱空氣輸出管62將120度以上的熱空氣送到環保高能低硫煤系統的烘乾設備利用,所經過熱交換的發電機熱空氣再經熱交換器46降溫後,經煙氣道63排出。The hot gas recovery system collects hot gas from the hot gas generated by the operation of the gas fuel generator 42 through the gas-water exchanger 43. The gas-water exchanger 43 adopts a heat conduction type of a heat pipe, and transmits copper through a heat conduction pipe. The thermal system is more than 1000 times more thermally conductive to the circulating water, and the hot water is sent to the fume drying cabinet 45 via the heat pump 44, and then the hot air of 120 degrees or more is sent to the environmentally-friendly high-energy low-sulfur coal system by the fume hood 45 through the hot air output pipe 62. The drying device utilizes, and the hot air of the heat exchanger that has passed through the heat exchange is cooled by the heat exchanger 46, and then discharged through the flue gas passage 63.

所述的導熱管道是若干真空熱導管51,在真空熱導管51一端設置有金屬散熱輪54,在相鄰真空熱導管51之間設置有煙水隔層55以及保溫層64,所述的氣-水交換器43一端設置有熱氣引入管52以及消音器53,底部設置有碳塵清潔口56,並在設置熱氣引入管52的一端設置有污水排放口57,以及循環熱水管58,用以連接熱泵44與氣-水交換器43,所述的熱交換器46設置於氣-水交換器43的相對設置污水排放口另一端,該熱交換器46上下端設置有循環冷水出口59,上端設置有循環冷水入口60,同時該端通過設置有循環熱水管61與排煙櫃45相連。The heat conducting conduit is a plurality of vacuum heat pipes 51. At one end of the vacuum heat pipe 51, a metal heat dissipating wheel 54 is disposed, and between the adjacent vacuum heat pipes 51, a smoke water compartment 55 and an insulating layer 64 are disposed. The water exchanger 43 is provided with a hot gas introduction pipe 52 and a muffler 53 at one end, a carbon dust cleaning port 56 at the bottom, a sewage discharge port 57 at one end of the hot gas introduction pipe 52, and a circulating hot water pipe 58 for The heat pump 44 is connected to the gas-water exchanger 43, and the heat exchanger 46 is disposed at the other end of the oppositely disposed sewage discharge port of the gas-water exchanger 43. The upper and lower ends of the heat exchanger 46 are provided with a circulating cold water outlet 59, the upper end. A circulating cold water inlet 60 is provided, and the end is connected to the fume hood 45 through a circulating hot water pipe 61.

所述的環保高能低硫煤系統將廢塑膠、廢輪胎、煉油過程中所不能氣化的餘渣即粗黑碳再利用,包括有將粗碳黑進行陳化的人工陳化器47,再經熱蒸氣處理器48處理,再將處理過的粗炭黑作為主料,在其中添加配伍物料,配伍材料為原煤、二茂鐵、六次甲基四銨、氫氧化鈉、生石灰和黏結劑,形成煤基料,其中主料在煤基料中所占的重量百分比為45%-60%;然後將煤基料製成成品煤,所述的粗碳黑通過螺旋輸送機67及碳黑輸入帶65輸送。The environmentally-friendly high-energy low-sulfur coal system reuses the waste plastic, the waste tire, and the residual slag which cannot be vaporized in the refining process, that is, the crude black carbon, including the artificial aging device 47 for aging the coarse carbon black, and then After being treated by the hot steam processor 48, the treated crude carbon black is used as a main material, and the compatibility materials are added thereto, and the compatibility materials are raw coal, ferrocene, hexamethylene tetraammonium, sodium hydroxide, quicklime and binder. Forming a coal base in which the weight percentage of the main material in the coal base material is 45% to 60%; then the coal base material is made into a finished coal, and the crude carbon black is passed through a screw conveyor 67 and carbon black. The input belt 65 is transported.

在具體的生產利用過程中,第一階段,將含水量40%的廢舊塑膠經熱空氣烘乾設備烘乾後,含水量減少為20%,其熱空氣來源於圖8熱氣回收系統,具體收集工作由熱能收集器66進行處理,經烘乾後的廢舊塑膠經輸送帶源源不斷送入熱裂解爐3,送料量為14噸(以兩條爐計算),從加熱開始至裂解完成,所用燃油1100Kg,附加材料為鋁、鋅及氧化鈣等催化劑,其比例為所加入原料去水分後重量的平均1.5%,設備用電為336度,生產週期時間為28小時,生產氣、柴油混合油11.62噸,裂解剩餘物即粗炭黑為60Kg,此粗炭黑連同在熱裂解爐的尾氣環保處理系統所收的濕碳粉送至高能低硫煤生產系統作再利用處理,同時通過煉油過程中所產生的可燃氣體約872 m3 ,此可燃氣Co20-24%、二氧化碳Co2 1-3%、氫氣H2 8-12%、CmHn主要為甲烷3-4.2%等,該可燃氣經清潔除焦油及壓縮送入燃氣儲存容器39作為燃氣發電用途。In the specific production and utilization process, in the first stage, after the waste plastic with 40% water content is dried by the hot air drying equipment, the water content is reduced to 20%, and the hot air is derived from the hot gas recovery system of Figure 8. The work is processed by the heat energy collector 66, and the dried waste plastic is continuously sent to the thermal cracking furnace 3 through the conveyor belt, and the feeding amount is 14 tons (calculated by two furnaces), and the fuel is used from the start of heating to the completion of the cracking. 1100Kg, the additional materials are catalysts such as aluminum, zinc and calcium oxide. The ratio is 1.5% of the weight of the added raw materials after dehydration, the equipment power is 336 degrees, the production cycle time is 28 hours, and the production gas and diesel mixed oil is 11.62. Tons, the residue of cracking, that is, 60Kg of crude carbon black, is sent to the high-energy low-sulfur coal production system for reuse treatment together with the wet carbon powder collected in the exhaust gas environmental protection treatment system of the thermal cracking furnace, and at the same time through the refining process. The combustible gas produced is about 872 m 3 , the combustible gas is 20-20%, the carbon dioxide Co2 is 1-3%, the hydrogen gas is H2 8-12%, and the CmHn is mainly methane 3-4.2%, etc., the combustible gas is cleaned and detarated and Compressed into gas storage 39 as a gas generation purposes.

第二階段,經過裂解後的混合油進入第二級裝置,該系統日處理量為14噸,該裝置的加熱工具為可控矽中頻加熱設備110KW,將生產的氣、柴油混合油切線後所需用電750度。In the second stage, the mixed oil after cracking enters the second-stage device. The daily processing capacity of the system is 14 tons. The heating tool of the device is 110KW of the controllable medium-frequency heating device, and the produced gas and diesel mixed oil is tangentially cut. The required electricity is 750 degrees.

第三階段,經第二級裝置處理後,將餾分中的柴、汽油送入精煉裝置處理,經清潔、除味、脫色、脫膠、脫蠟等工序,所得柴、汽油的總量為10.67噸,柴油經處理合成後可到達中國國Ⅱ標準,汽油為93#汽油,在處理過程中的剩餘物經鹼化處理,利用全密封的輸送工具一般為管道送入高能低硫煤生產系統作再利用處理。In the third stage, after treatment by the second-stage device, the diesel and gasoline in the fraction are sent to the refining device for treatment, and after cleaning, deodorization, decolorization, degumming, dewaxing, etc., the total amount of diesel and gasoline obtained is 10.67 tons. After the diesel oil is processed and synthesized, it can reach the Chinese national standard II. The gasoline is 93# gasoline. The residue in the treatment process is alkalized. The fully sealed conveying tool is generally used to feed the high-energy low-sulfur coal production system. Use processing.

第四階段,由燃氣儲存容器輸出的可燃氣體經減壓後進入內混式燃氣發電機,具體可採用濟南柴油發電機廠500KW/h產品,上述經所述的第二階段處理後的872m3 可燃氣可發電3925度,在發電過程中產生的熱氣經熱回收再利用系統換成熱空氣,連同熱裂解爐的尾氣處理剩餘熱水熱換成熱空氣聯合送入第一階段中起始的熱空氣烘乾設備再用。In the fourth stage, the combustible gas outputted from the gas storage container is decompressed and then enters the internal mixed gas generator. Specifically, the 500KW/h product of the Jinan Diesel Generator Factory can be used, and the above-mentioned second stage treatment is performed. 872m 3 combustible gas can generate 3925 degrees of heat, the hot gas generated in the power generation process is replaced by hot air by the heat recovery and reuse system, together with the exhaust gas treatment of the hot cracking furnace, the hot water is replaced by hot air and sent to the first stage. The hot air drying equipment is used again.

本實施以廢舊塑膠煉油為例,凡有與之原理和基本結構與本實施例相同或近似的,均在本發明保護範圍之內。In this embodiment, the waste plastic refining is taken as an example, and all the principles and basic structures are the same as or similar to those of the embodiment, and are within the protection scope of the present invention.

與現有技術相比,將現有設備的單項性進行整合,相對現有單項技術的單一環保生產概念來說,能夠有效杜絕環保生產後的剩餘物對土地及空氣環境造成的二次污染,或者是因為單一環保方式生產前的更具危害性的污染;本發明的系統裝備是一組循環環保生產及再利用設備,從第一次的環保生產到剩餘渣物及有害氣體、高溫氣體再作第二次的環保生產再利用,能夠起到真正廢棄物環保生產循環經濟鏈,可能達到或達到無污水排放、無煙塵排放、無室溫排放、無有害氣體排放、無惡臭、無刺激性氣味排放、噪音低、自產能源循環利用的良好的有益效果。Compared with the prior art, the integration of the individual items of the existing equipment can effectively eliminate the secondary pollution caused by the residues of the environmentally friendly production to the land and the air environment, compared with the single environmentally friendly production concept of the existing single technology, or because A single environmentally friendly way to produce more harmful pollution before production; the system equipment of the invention is a set of environmentally friendly production and recycling equipment, from the first environmentally friendly production to the remaining slag and harmful gases, high temperature gas and then second The second environmental protection production reuse can play a circular industrial chain of real waste environmental protection production, which may reach or achieve no sewage discharge, smokeless dust emission, no room temperature emission, no harmful gas emissions, no odor, no irritating odor emission, Good noise with low noise and self-produced energy recycling.

1...氣壓式自動進料機1. . . Pneumatic automatic feeder

2...輸送帶2. . . conveyor

3...熱裂解爐3. . . Thermal cracking furnace

4...刮壁刀4. . . Scraper

5...反應釜5. . . Reactor

6...氣蠟油分離器6. . . Gas wax oil separator

7...第一級冷凝器7. . . First stage condenser

8...水封式氣油分離器8. . . Water-sealed gas oil separator

9...水封安全裝置9. . . Water seal safety device

10...水封式負壓裝置10. . . Water seal type negative pressure device

11...重油承載容器11. . . Heavy oil carrying container

12...臥式冷凝器12. . . Horizontal condenser

13...混合油承載容器13. . . Mixed oil carrying container

14...立式燃氣中和水洗器14. . . Vertical gas neutral water washer

15...雙重水封安全裝置15. . . Double water seal safety device

16...蒸餾催化塔16. . . Distillation catalytic tower

17...中頻加熱裝置17. . . Intermediate frequency heating device

18...立式冷凝器18. . . Vertical condenser

19...水封安全器19. . . Water seal safety device

20...柴、汽油承載容器20. . . Firewood, gasoline carrying container

21...脫碳除雜合成器twenty one. . . Decarburization and decontamination synthesizer

22...除碳漂白器twenty two. . . Carbon bleacher

23...脫蠟除膠器twenty three. . . Dewaxing remover

24...添加劑容器twenty four. . . Additive container

25...渣液分離機25. . . Slag liquid separator

26...精煉油合成罐26. . . Refined oil synthetic tank

27...帶多重水簾排氣管道27. . . Multiple water curtain exhaust pipe

28...熱氣水緩衝室28. . . Hot air water buffer

29...雙重濕碳粒篩檢程式29. . . Double wet carbon screening program

30...雙塔型濕式氣固分離器30. . . Double tower type wet gas-solid separator

31...引風器31. . . Inductor

32...煙囪32. . . chimney

33...水氣分離器33. . . Water gas separator

34...熱交換器34. . . Heat exchanger

35...排氣管道35. . . Exhaust pipe

36...鹼性水液噴淋器36. . . Alkaline water sprayer

37...燃氣管道37. . . Gas pipeline

38...第二級專用燃氣壓縮機38. . . Second-stage dedicated gas compressor

39...燃氣儲存容器39. . . Gas storage container

40、41...減壓設備40, 41. . . Pressure reducing equipment

42...氣體燃料發電機42. . . Gas fuel generator

43...氣水交換器43. . . Gas water exchanger

44...熱泵44. . . Heat pump

45...排煙櫃45. . . Fume hood

46...熱交換器46. . . Heat exchanger

47...人工陳化器47. . . Artificial aging device

48...熱蒸氣處理器48. . . Hot steam processor

49...廢渣排除管道49. . . Waste residue removal pipeline

50...壓縮空氣50. . . Compressed air

51...真空熱導管51. . . Vacuum heat pipe

52...熱氣引入管52. . . Hot gas introduction tube

53...消音器53. . . silencer

54...金屬散熱輪54. . . Metal heat sink

55...煙水隔層55. . . Smoke water compartment

56...碳塵清潔口56. . . Carbon dust cleaning port

57...污水排放口57. . . Sewage discharge

58...循環熱水管58. . . Circulating hot water pipe

59...循環冷水出口59. . . Circulating cold water outlet

60...循環冷水入口60. . . Circulating cold water inlet

61...循環熱水管61. . . Circulating hot water pipe

62...熱空氣輸出管62. . . Hot air outlet tube

63...煙氣道63. . . Smoke path

64...保溫層64. . . Insulation

65...碳黑輸入帶65. . . Carbon black input belt

66...熱能收集器66. . . Thermal collector

67...螺旋輸送機67. . . Screw conveyor

圖1為本發明之廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備整體圖。1 is an overall view of a comprehensive utilization production equipment for renewable energy of waste plastics, tires and used motor oil of the present invention.

圖2為圖1中主體設備的主體視圖。Figure 2 is a perspective view of the main body of Figure 1.

圖3為圖2中主體設備的另一視圖。Figure 3 is another view of the main unit of Figure 2.

圖4A是圖1中反應釜的截面圖。4A is a cross-sectional view of the reaction vessel of FIG. 1.

圖4B是與圖4A配合的熱裂解爐表示圖。Figure 4B is a representation of a thermal cracking furnace in conjunction with Figure 4A.

圖5為第三級裝置之柴油精練機汽油脫膠設備表示圖。Figure 5 is a representation of a diesel refiner gasoline degumming apparatus for a third stage apparatus.

圖6為裂解爐尾氣處理環保裝置系統表示圖。Fig. 6 is a diagram showing the system of the environmental protection device for the cracking furnace tail gas treatment.

圖7為圖6中煙囪表示圖。Figure 7 is a diagram showing the chimney of Figure 6.

圖8為熱氣回收系統表示圖。Figure 8 is a representation of a hot gas recovery system.

圖9為可燃氣體發電再利用系統表示圖。Fig. 9 is a view showing a system for recovering a combustible gas power generation system.

圖10為環保高能低硫煤系統表示圖。Figure 10 is a representation of an environmentally friendly high energy low sulfur coal system.

3...熱裂解爐3. . . Thermal cracking furnace

6...氣蠟油分離器6. . . Gas wax oil separator

7...第一級冷凝器7. . . First stage condenser

8...水封式氣油分離器8. . . Water-sealed gas oil separator

9...水封安全裝置9. . . Water seal safety device

10...水封式負壓裝置10. . . Water seal type negative pressure device

11...重油承載容器11. . . Heavy oil carrying container

12...臥式冷凝器12. . . Horizontal condenser

13...混合油承載容器13. . . Mixed oil carrying container

14...立式燃氣中和水洗器14. . . Vertical gas neutral water washer

15...雙重水封安全裝置15. . . Double water seal safety device

16...蒸餾催化塔16. . . Distillation catalytic tower

17...中頻加熱裝置17. . . Intermediate frequency heating device

18...立式冷凝器18. . . Vertical condenser

19...水封安全器19. . . Water seal safety device

20...柴、汽油承載容器20. . . Firewood, gasoline carrying container

27...帶多重水簾排氣管道27. . . Multiple water curtain exhaust pipe

37...燃氣管道37. . . Gas pipeline

47...人工陳化器47. . . Artificial aging device

65...碳黑輸入帶65. . . Carbon black input belt

67...螺旋輸送機67. . . Screw conveyor

Claims (7)

一種廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,其特徵在於:包括相互配合的主體設備、第二級裝置、第三級裝置、裂解爐尾氣處理環保系統、可燃氣體發電的再利用系統、熱氣回收系統以及環保高能低硫煤系統;其中所述的主體設備包括:由輸送帶為起點,將石油產品廢棄物輸送到由路軌移動的氣壓式自動進料機,將原料推進熱裂解爐進行裂解催化得到油氣混合物,該熱裂解爐帶有一個自動隨機刮壁刀的反應釜,同時爐體接有裂解尾氣環保裝置系統,隨之後級設備順序為氣蠟油分離器作為由熱裂解爐所產生油氣裏蠟油首次分離工具,再依次連接有第一級冷凝器、水封式氣油分離器,水封安全裝置、水封式負壓裝置、重油承載容器,當油氣混合物經臥式冷凝器進入混合油承載容器,未能液化的可燃氣體隨之進入立式燃氣中和水洗器,該水洗器附設雙重水封安全裝置,可燃氣體經水洗器水洗後進入可燃氣體發電的再利用系統。 The invention relates to a comprehensive utilization production equipment for waste plastics, tires and waste engine oil, which is characterized in that: the main equipment, the second-stage device, the third-stage device, the cracking furnace tail gas treatment and environmental protection system, and the reuse of the combustible gas power generation are included. The system, the hot gas recovery system and the environmentally-friendly high-energy low-sulfur coal system; wherein the main equipment comprises: a conveyor belt as a starting point, conveying the petroleum product waste to a pneumatic automatic feeder driven by the rail, and propelling the raw material into the thermal cracking The furnace is subjected to pyrolysis catalysis to obtain an oil and gas mixture. The thermal cracking furnace is provided with a reaction vessel of an automatic random scraping blade, and the furnace body is connected with a cracking tail gas environmental protection device system, and the subsequent stage equipment is a gas wax oil separator as a thermal cracking. The first separation tool for the wax oil in the oil and gas produced by the furnace is connected with a first-stage condenser, a water-sealed gas oil separator, a water seal safety device, a water-sealed negative pressure device, and a heavy oil carrying container. The condenser enters the mixed oil carrying container, and the flammable gas that has not been liquefied enters the vertical gas neutralizing water washer. Double water seal is attached to the safety device, the combustible gas into the water after washing is recycled combustible gas generation system. 如申請專利範圍第1項所述之廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,其特徵在於:所述的第二級裝置包括蒸餾催化塔,該設備的被蒸餾物來自於主體設備中的混合油承載容器中的混合油,蒸餾催化塔的加熱方式採用可控矽中頻加熱方法,有一中頻加熱裝置與蒸餾催化塔相連,當裂解後的廢舊塑膠油、輪胎油或者廢機油進入蒸餾塔處理後根據各種物料的不同氣化溫度的切線進入立式冷凝器再經水封安全器進入柴、汽油承載容 器。 The regenerative energy comprehensive utilization production equipment for waste plastics, tires and waste engine oil according to claim 1 is characterized in that: the second-stage device comprises a distillation catalytic tower, and the distillate of the device is from the main body. The mixed oil in the equipment carries the mixed oil in the container, and the heating method of the distillation catalytic tower adopts a controllable medium frequency heating method, and an intermediate frequency heating device is connected with the distillation catalytic tower, when the cracked waste plastic oil, tire oil or waste After the oil enters the distillation tower, it enters the vertical condenser according to the tangential line of different gasification temperatures of various materials and then enters the diesel and gasoline bearing capacity through the water seal safety device. Device. 如申請專利範圍第第1項所述之廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,其特徵在於:所述的第三級裝置是柴油精練及汽油脫膠設備,該設備由第一級化學脫碳除雜合成器為起點,經除碳漂白器、脫蠟除膠器,所述第二級裝置中的柴、汽油承載容器中的油品經輸入管道進入該脫蠟除膠器,該脫蠟除膠器為圓桶錐形攪拌器,攪器內設有立向擋板,底部設有鼓動沸騰裝置,攪拌流型以切流方式攪動;所需添加的化學劑裝置設置於添加劑容器內,並分為化學劑添加區及鹼性液體添加區,經處理後的有用物再輸送到渣液分離機,該機網目從200目至350目,經過濾過的流體輸送到精煉油合成罐,該罐的工作形式分開二級過濾,第一級為逆向加壓力過濾,第二級為順向過濾,此二級的過濾層均設置有過濾介質承載孔板,其過濾介質為固體粒狀物,被過濾物所要添加化學劑添加物置於添加劑容器內,經以上處理之後所得油品經檢查合格後進入油庫儲存區,同時由各個精煉階段所產生的廢料由專用輸送裝置輸送至環保高能低硫煤系統再利用,經各個精煉階段所產生的廢氣、廢味經專用排氣管道通過水浴池及活性碳篩檢程式排出。 The regenerative energy comprehensive utilization production equipment of waste plastics, tires and waste engine oils as claimed in claim 1 is characterized in that: the third-stage device is a diesel refining and gasoline degumming device, and the device is first The chemical decarburization and decontamination synthesizer is used as a starting point. After decarburization bleaching and dewaxing degumming, the oil in the diesel and gasoline carrying containers in the second-stage device enters the dewaxing and degreasing device through the input pipeline. The dewaxing degumming device is a cone conical agitator, the vertical baffle is arranged in the stirrer, the agitating boiling device is arranged at the bottom, and the stirring flow type is agitated by the cutting flow; the chemical device to be added is set in The additive container is divided into a chemical agent addition zone and an alkaline liquid addition zone, and the treated utility is transported to the slag liquid separator, the mesh of the machine is from 200 mesh to 350 mesh, and the filtered fluid is transported to the refined oil. Synthetic tank, the working form of the tank is separated by two-stage filtration, the first stage is reverse pressure filtration, the second stage is forward filtration, and the second stage filtration layer is provided with a filter medium bearing orifice plate, and the filter medium is solid Granular The chemical additive to be added to the filter is placed in the additive container. After the above treatment, the obtained oil is inspected and then enters the oil storage area, and the waste generated by each refining stage is transported by the special conveying device to the environmentally-friendly high-energy low-sulfur coal system. After reuse, the exhaust gas and waste generated by each refining stage are discharged through a water bath and an activated carbon screening program through a dedicated exhaust pipe. 如申請專利範圍第3項所述之廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,其特徵在於:所述的脫碳除雜合成器、除碳漂白器、脫蠟除膠器下端均連接廢渣排除管道並採用壓縮空氣壓送往環保高能低硫煤系統,在渣液分離機至精煉油合成罐之間 同樣設置有添加劑容器。 The recyclable energy comprehensive utilization production equipment of waste plastics, tires and waste engine oils as claimed in claim 3, characterized in that: the decarburization and decontamination synthesizer, the carbon bleaching device, the dewaxing and degumming device lower end They are connected to the waste residue removal pipeline and sent to the environmentally-friendly high-energy low-sulfur coal system by compressed air pressure, between the slag liquid separation machine and the refined oil synthesis tank. An additive container is also provided. 如申請專利範圍第1項所述之廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,其特徵在於:所述的裂解爐尾氣處理環保裝置系統與熱裂解爐的排煙口相連,該系統包括有帶多重水簾排氣管道,該多重水簾排氣管道的排氣口連接爐體燃燒室,中間裝有熱氣水緩衝室,緩衝室下部裝有雙重濕碳粒篩檢程式,另一端連接雙塔型濕式氣固分離器,氣固分離器尾端由管道連接引風器,下端由管道連接引風器的後部分水管,引水管利用引風器的壓力將水氣推入設備尾部的煙囪,煙囪由三部分組成,下部為圓桶罐狀體的水氣分離器,中為用於氣相分離的熱交換器,上部為排氣管道,該管道中部裝有鹼性水液噴淋器。 The recyclable energy comprehensive utilization production equipment of waste plastics, tires and waste engine oils as claimed in claim 1 is characterized in that: the cracking furnace exhaust gas treatment environmental protection device system is connected with the exhaust port of the thermal cracking furnace, The system includes a multiple water curtain exhaust pipe, the exhaust port of the multiple water curtain exhaust pipe is connected to the combustion chamber of the furnace body, and a hot gas water buffer chamber is arranged in the middle, and a double wet carbon particle screening program is installed in the lower part of the buffer chamber, and another One end is connected with a double-tower wet gas-solid separator. The tail end of the gas-solid separator is connected to the air blower by a pipe, and the lower end is connected by a pipe to the rear part of the air blower. The water pipe pushes the water gas by the pressure of the air blower. The chimney at the end of the equipment, the chimney consists of three parts, the lower part is a water-gas separator of the drum-shaped tank, the heat exchanger for gas phase separation, the upper part is the exhaust pipe, and the middle part of the pipe is filled with alkaline water. Liquid shower. 如申請專利範圍第1項所述之廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,其特徵在於:所述的可燃氣體發電再利用系統連接於主體設備中的燃氣管道,經專用燃氣壓縮機將燃氣壓縮到0.5MPA同時起到第一級燃氣脫水作用時,再將氣體送到第二級專用燃氣壓縮機,此壓縮機再將燃氣壓縮至1MPA同時起到第二次燃氣脫水作用時,將可燃氣體送到燃氣儲存容器,儲存器設置有兩個出氣口,一個出氣口通往主體設備的熱裂解爐作為該爐的燃料,其氣體通過方法是經二次減壓送出,第一次減壓是經減壓設備減壓到0.4-0.5MPA,再經第二個減壓設備由0.4-0.5MPA減至0.1-0.2MPA送到爐膛燃燒;另一個出氣口通往氣體燃料發電機,其可燃氣體通過方法是經另一減壓設備減壓到 0.1-0.5MPA後再進入氣體燃料發電機。 For example, the regenerative energy comprehensive utilization production equipment of waste plastics, tires and waste engine oils as claimed in claim 1 is characterized in that: the flammable gas power generation reuse system is connected to a gas pipeline in the main equipment, and is dedicated When the gas compressor compresses the gas to 0.5MPA and simultaneously acts as the first-stage gas dehydration, the gas is sent to the second-stage dedicated gas compressor, which then compresses the gas to 1MPA. In the second gas dehydration, the combustible gas is sent to the gas storage container. The storage device is provided with two gas outlets, and one gas outlet is connected to the thermal cracking furnace of the main equipment as the fuel of the furnace, and the gas passing method is After the second pressure reduction, the first decompression is decompressed to 0.4-0.5MPA by the decompression device, and then transferred to the furnace by 0.4-0.5MPA to 0.1-0.2MPA through the second decompression device; An air outlet leads to the gas fuel generator, and the flammable gas passing method is decompressed by another pressure reducing device After entering 0.1-0.5MPA, enter the gas fuel generator. 如申請專利範圍第1項所述之廢舊塑膠、輪胎、廢機油的再生能源綜合利用生產裝備,其特徵在於:所述的環保高能低硫煤系統將廢塑膠、廢輪胎、煉油過程中所不能氣化的餘渣即粗黑碳再利用,包括有將粗碳黑進行陳化的人工陳化器,再經熱蒸氣處理器處理,再將處理過的粗炭黑作為主料,在其中添加配伍物料,配伍材料為原煤、二茂鐵、六次甲基四銨、氫氧化鈉、生石灰和黏結劑,形成煤基料,其中主料在煤基料中所占的重量百分比為45%-60%;然後將煤基料製成成品煤。 For example, the recyclable energy comprehensive utilization production equipment of waste plastics, tires and waste engine oil mentioned in the first paragraph of the patent application is characterized in that the environmentally-friendly high-energy low-sulfur coal system cannot be used in waste plastics, waste tires and refining processes. The remaining residue of gasification, that is, the crude black carbon is reused, including a manual aging device for aging the crude carbon black, and then treated by a steam steam processor, and the treated crude carbon black is used as a main material, and is added thereto. Compatible materials, compatible materials are raw coal, ferrocene, hexamethylene tetraammonium, sodium hydroxide, quicklime and binder to form a coal base, of which the main material accounts for 45% by weight of the coal base - 60%; then the coal base is made into finished coal.
TW99127014A 2010-08-12 2010-08-12 Production equipment for renewable energy released from waste plastics, tyres, and engine oil TWI435775B (en)

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TW201437565A (en) * 2013-03-27 2014-10-01 Choosetop Technology Industry Co Ltd Cracking furnace exhaust gas recycling method
CN114165314A (en) * 2021-12-07 2022-03-11 威海泓创企业管理咨询有限公司 Waste tire cracking non-condensable gas generator tail gas treatment device and method

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