TWI430004B - Method for controlling light transmittance of electrochromic element - Google Patents

Method for controlling light transmittance of electrochromic element Download PDF

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TWI430004B
TWI430004B TW101133894A TW101133894A TWI430004B TW I430004 B TWI430004 B TW I430004B TW 101133894 A TW101133894 A TW 101133894A TW 101133894 A TW101133894 A TW 101133894A TW I430004 B TWI430004 B TW I430004B
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electrochromic element
transmittance
input
electrochromic
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TW201341926A (en
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Yi Wen Chung
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Tintable Smart Material Co Ltd
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電致變色元件透光度控制方法 Electrochromic element transmittance control method

本發明係有關於一種電致變色元件透光度控制方法,尤其是指一種不需反覆進行調整即快速、準確的令電致變色元件達到固定的透光度,並於經過時間老化現象後,不會有影響其透光度準確性的情況發生,而在其整體施行使用上更增實用功效特性之電致變色元件透光度控制方法創新設計者。 The invention relates to a method for controlling the transmittance of an electrochromic element, in particular to a method for quickly and accurately adjusting the transmittance of the electrochromic element without repeated adjustment, and after aging time, There is no innovative designer of the electro-chromic element transmittance control method that affects the accuracy of its transparency and is more practical and effective in its overall application.

按,隨著科技的日新月異,各種特殊的材料被大量的研發出來;其中,電致變色元件是指施加一電壓而呈現可逆式的顏色變化性質,將原本的透明無色狀態由通電後變成有色狀態,其結構上係為一種多層式電化學裝置,施加電壓於元件中,藉使元件內的物質產生氧化或還原之可逆反應而導致顏色變化的現象,該電致變色元件可供應用在日常生活之中,若外界陽光太強烈或是想令內部具有隱密性,即可應用此技術改變玻璃透光度。 According to the rapid development of science and technology, various special materials have been developed. Among them, electrochromic components refer to the application of a voltage to exhibit a reversible color change property, and the original transparent colorless state is turned into a colored state after being energized. The structure is a multi-layer electrochemical device that applies a voltage to the element, and causes a change in color due to a reversible reaction of oxidation or reduction of the substance in the element. The electrochromic element can be used in daily life. Among them, if the outside sun is too strong or wants to make the interior secret, this technology can be applied to change the glass transmittance.

其中,該類電致變色元件於操作使用上,其皆係對該電致變色元件輸入正向電源,令該電致變色元件透光度降低、吸光性增加、顏色越深〔請參閱第十圖電致變色元件之氧化反應示意圖所示〕,並對電致變色元件輸入反向電源,令該電致變色元件透光度提 高、吸光性減少、顏色越淺〔請參閱第十一圖電致變色元件之還原反應示意圖所示〕,利用反覆對電致變色元件輸入正向或反向電源,讓電致變色元件進行氧化或還原反應,而能達到將該電致變色元件調整至所需透光度之目的。 Wherein, the electrochromic element is used in operation, which inputs a forward power source to the electrochromic element, so that the electrochromic element has reduced transmittance, increased absorbance, and darker color (see the tenth Figure 2 shows the oxidation reaction of the electrochromic element, and inputs the reverse power to the electrochromic element to improve the transmittance of the electrochromic element. High, light absorption is reduced, and the color is lighter (please refer to the diagram of the reduction reaction of the electrochromic element in Fig. 11), and the electrochromic element is oxidized by inputting a forward or reverse power source to the electrochromic element. Or the reduction reaction can achieve the purpose of adjusting the electrochromic element to the desired transmittance.

然而,上述電致變色元件雖可利用輸入正向或反向電源之改變,達到調整其透光度之預期功效,但也在其整體實際施行使用上發現,由於輸入電源之電壓及電流大小會影響到電致變色元件的變化速度及使用壽命,使得利用反覆對電致變色元件輸入正向或反向電源,讓電致變色元件進行氧化或還原反應改變其透光度之方式,不僅造成欲將電致變色元件調整至所需透光度之過程需反覆調整、較為緩慢,且反覆電壓及電流的變化亦會導致該電致變色元件之使用壽命降低,致令其在整體操作施行上仍存有改進之空間。 However, although the above electrochromic element can utilize the change of the input forward or reverse power source to achieve the expected effect of adjusting the transmittance, it is also found in the overall practical use of the input power source due to the voltage and current of the input power source. Affecting the changing speed and service life of the electrochromic element, so that the method of inputting the forward or reverse power source to the electrochromic element and causing the electrochromic element to undergo oxidation or reduction reaction to change its transmittance is not only caused by the desire The process of adjusting the electrochromic element to the required transmittance needs to be adjusted repeatedly, and the change of the voltage and current repeatedly causes the life of the electrochromic element to be reduced, so that the overall operation is still performed. There is room for improvement.

緣是,發明人有鑑於此,秉持多年該相關行業之豐富設計開發及實際製作經驗,針對現有之缺失再予以研究改良,提供一種電致變色元件透光度控制方法,以期達到更佳實用價值性之目的者。 In view of this, the inventor has been in the process of many years of rich experience in design and development of the relevant industries, and has made research and improvement on the existing defects, and provided a method for controlling the transmittance of electrochromic elements in order to achieve better practical value. The purpose of sex.

本發明之主要目的在於提供一種電致變色元件透光度控制方法,其主要係利用對電致變色元件輸入固定的總電量值即能達到所需的固定透光度,使得其不需反覆進行調整即快速、準確的令電致變色元件達到固定的透光度,並於經過時間老化現象後,不會有影響其透光度準確性的情況發生,而在其整體施行使用上更增實用功效特性者。 The main object of the present invention is to provide a method for controlling the transmittance of an electrochromic element, which is mainly capable of achieving a desired fixed transmittance by inputting a fixed total amount of electricity to the electrochromic element, so that it does not need to be repeated. The adjustment is fast and accurate, so that the electrochromic element achieves a fixed transmittance, and after the aging of the time, there is no influence on the accuracy of the transmittance, and the utility model is more practical in its application. Efficacy characteristics.

本發明電致變色元件透光度控制方法之主要目的與功效,係由以下具體技術手段所達成: The main purpose and efficacy of the method for controlling the transmittance of the electrochromic element of the present invention are achieved by the following specific technical means:

其主要係先由電致變色元件在相同透光度、不同輸入電壓時,所產生之不同電流值與不同變化速度間的關係,將每秒電流值相加得知其所需輸入之總電量值,使得於使用該電致變色元件即可對其輸入固定透光度之總電量值,而能達到固定的透光度。 The main difference is the relationship between the different current values generated by the electrochromic elements at the same transmittance and different input voltages and the different change speeds, and the current values per second are added to know the total amount of input required. The value is such that the total electric quantity of the fixed transmittance can be input to the electrochromic element to achieve a fixed transmittance.

本發明之電致變色元件透光度控制方法的較佳實施例,其中,由電致變色元件得知其隨著切換次數增加所輸入之電量會減少,再將總電量值扣掉電量減少差值即可獲得固定透光度之停止電量值。 A preferred embodiment of the method for controlling transmittance of an electrochromic element according to the present invention, wherein the electrochromic element knows that the amount of electricity input as the number of switching increases is reduced, and the total amount of electricity is deducted from the amount of electricity. The value can be used to obtain the value of the stop power of the fixed transmittance.

本發明電致變色元件透光度控制方法之主要目的與功效,係由以下具體技術手段所達成: The main purpose and efficacy of the method for controlling the transmittance of the electrochromic element of the present invention are achieved by the following specific technical means:

其主要係先由電致變色元件在相同透光度、不同輸入電壓時,所產生之不同電流值與不同變化速度間的關係,將每秒電流值相加得知其所需輸入之總電量值,且將該總電量值除上該電致變色元件之尺寸面積,而獲得該電致變色元件單位面積達到固定透光度之單位面積電量值,於使用時則依所需不同尺寸面積的電致變色元件與該單位面積電量值之乘積,即能獲得在該所需尺寸面積之電致變色元件達到固定透光度的總電量值,使得於使用該電致變色元件即可對其輸入固定透光度之總電量值,而能達到固定的透光度。 The main difference is the relationship between the different current values generated by the electrochromic elements at the same transmittance and different input voltages and the different change speeds, and the current values per second are added to know the total amount of input required. And dividing the total electric quantity value by the size area of the electrochromic element to obtain a unit area electric quantity value of the electrochromic element per unit area reaching a fixed transmittance, and depending on the required size area when used The product of the electrochromic element and the unit area electric quantity value, that is, the total electric quantity value of the electrochromic element in the required size area to achieve a fixed transmittance can be obtained, so that the electrochromic element can be input thereto by using the electrochromic element. Fix the total power value of the transmittance, and achieve a fixed transmittance.

本發明之電致變色元件透光度控制方法的較佳實施例,其中,由電致變色元件得知其隨著切換次數增加所輸入之電量會減少,再 將總電量值扣掉電量減少差值即可獲得該所需尺寸面積之電致變色元件的固定透光度之停止電量值。 A preferred embodiment of the method for controlling transmittance of an electrochromic element according to the present invention, wherein the electrochromic element knows that the amount of electricity input as the number of switching increases is reduced, and then The value of the stop value of the fixed transmittance of the electrochromic element of the required size area can be obtained by deducting the difference between the total amount of electricity and the amount of decrease in the amount of electricity.

第一圖:電致變色元件輸入不同電壓之特性示意圖 First: Schematic diagram of the characteristics of different voltages input to electrochromic elements

第二圖:電致變色元件輸入2.5V時總電流面積示意圖 Figure 2: Schematic diagram of the total current area when the electrochromic element is input at 2.5V

第三圖:電致變色元件輸入2.0V時總電流面積示意圖 Third figure: Schematic diagram of the total current area when the electrochromic element is input at 2.0V

第四圖:電致變色元件輸入1.5V時總電流面積示意圖 Figure 4: Schematic diagram of the total current area when the electrochromic element is input at 1.5V

第五圖:電致變色元件老化現象示意圖 Figure 5: Schematic diagram of aging phenomenon of electrochromic components

第六圖:本發明之控制步驟示意圖 Figure 6: Schematic diagram of the control steps of the present invention

第七圖:不同尺寸電致變色元件輸入1.5V時之特性示意圖 Figure 7: Schematic diagram of the characteristics of different size electrochromic elements when inputting 1.5V

第八圖:不同尺寸電致變色元件輸入2.0V時之特性示意圖 Figure 8: Schematic diagram of the characteristics of different size electrochromic elements when inputting 2.0V

第九圖:本發明之另一實施例控制步驟示意圖 Ninth diagram: Schematic diagram of control steps of another embodiment of the present invention

第十圖:電致變色元件之氧化反應示意圖 Figure 10: Schematic diagram of oxidation reaction of electrochromic elements

第十一圖:電致變色元件之還原反應示意圖 Figure 11: Schematic diagram of the reduction reaction of electrochromic elements

為令本發明所運用之技術內容、發明目的及其達成之功效有更完整且清楚的揭露,茲於下詳細說明之,並請一併參閱所揭之圖式及圖號: For a more complete and clear disclosure of the technical content, the purpose of the invention and the effects thereof achieved by the present invention, it is explained in detail below, and please refer to the drawings and drawings:

首先,請參閱第一圖電致變色元件輸入不同電壓之特性示意圖所示,當外部電源輸入電致變色元件,令電致變色元件透光度降低、吸光性增加、顏色越深、進行氧化反應時,由於電致變色元件 於相同透光度之條件限定下,其若輸入不同電壓即會產生不同的電流值及不同的變化速度,使得即可由不同輸入電壓達到相同透光度之電流值與變化速度間的關係得知,不論輸入電壓高低,其每秒的電流值變化相加會形成相同的總電量值〔請再一併參閱第二圖電致變色元件輸入2.5V時總電流面積示意圖、第三圖電致變色元件輸入2.0V時總電流面積示意圖、第四圖電致變色元件輸入1.5V時總電流面積示意圖所示〕,如:第1秒得到電流值50mA+第2秒電流值45mA+第3秒電流值30mA+…+第n秒〔透光度到達〕之電流值即為總電量值。 First, please refer to the first diagram of the characteristics of the input voltage of the electrochromic element. When the external power source is input to the electrochromic element, the transmittance of the electrochromic element is reduced, the absorbance is increased, the color is deeper, and the oxidation reaction is performed. Electrochromic element Under the condition of the same transmittance, if different voltages are input, different current values and different speeds of change will be generated, so that the relationship between the current value and the change speed of the same transmittance can be obtained from different input voltages. Regardless of the input voltage level, the change of the current value per second will form the same total power value. Please refer to the second figure for the total current area of the electrochromic element input 2.5V, and the third figure electrochromic. Schematic diagram of the total current area when the component is input at 2.0V, and the total current area shown in the fourth figure when the electrochromic element is input at 1.5V], for example, the current value is 50mA in the first second, the current value is 45mA in the second second, and the current value is 30mA in the third second. ... + the current value of the nth second [transmission arrival] is the total electricity value.

請再一併參閱第五圖電致變色元件老化現象示意圖所示,且由於電致變色元件於使用一段時間後,其會有老化現象,即輸入相同的電壓、在相同電流量與相同透光度的情況下,其透光度之變化速度會產生變化,如:第1次、第4000次、第6000次間之透光度變化速度即會越來越快,造成若仍以第1次之透光度變化速度時間進行計算,其透光度則並非為所需透光度。 Please refer to the fifth diagram for the aging phenomenon of electrochromic components, and because the electrochromic components will age after using them for a period of time, that is, input the same voltage, the same amount of current and the same light. In the case of degree, the speed of change of transmittance will change. For example, the speed of change of transmittance between the first, the 4,000th and the 6,000th will become faster and faster, resulting in the first time. The transmittance change speed time is calculated, and the transmittance is not the required transmittance.

如此一來,請再一併參閱第六圖本發明之控制步驟示意圖所示,其係先由電致變色元件在相同透光度、不同輸入電壓時,所產生之不同電流值與不同變化速度間的關係,將每秒電流值相加得知其所需輸入之總電量值,且由電致變色元件之老化現象得知其隨著切換次數增加所輸入之電量會減少,再將總電量值扣掉電量減少差值即可獲得固定透光度之停止電量值,使得於使用該電致變色元件即可對其輸入固定透光度之停止電量值,而能不需反覆進行調整即快速、準確的令電致變色元件達到固定的透光度,並於經過時間老化現象後,不會有影響其透光度準確性的情況發生。 In this way, please refer to the sixth figure, which is shown in the schematic diagram of the control steps of the present invention, which are different current values and different change speeds generated by the electrochromic elements at the same transmittance and different input voltages. The relationship between the current values per second is added to the total amount of electricity required for the input, and it is known from the aging phenomenon of the electrochromic element that the amount of electricity input as the number of switching increases will decrease, and the total amount of electricity will be reduced. The deduction of the difference in the amount of power reduction can obtain the value of the stop power of the fixed transmittance, so that the value of the stop power of the fixed transmittance can be input by using the electrochromic element, and the adjustment can be performed without repeated adjustment. Accurately make the electrochromic element achieve a fixed transmittance, and after the aging of the time, there will be no impact on the accuracy of the transmittance.

另,請再一併參閱第七圖不同尺寸電致變色元件輸入1.5V時之特性示意圖及第八圖不同尺寸電致變色元件輸入2.0V時之特性示意圖所示,在不同尺寸的電致變色元件其在相同透光度、不同輸入電壓時,由不同電流值與不同變化速度間的關係所獲得之總電流面積容量值係呈正比;使得請再一併參閱第九圖本發明之另一實施例控制步驟示意圖所示,本發明亦可先由電致變色元件在相同透光度、不同輸入電壓時,所產生之不同電流值與不同變化速度間的關係,將每秒電流值相加得知其所需輸入之總電量值,且將該總電量值除上該電致變色元件之尺寸面積,而獲得該電致變色元件單位面積達到固定透光度之單位面積電量值,於使用時則依所需不同尺寸面積的電致變色元件與該單位面積電量值之乘積,即能獲得在該所需尺寸面積之電致變色元件達到固定透光度的總電量值,另由電致變色元件之老化現象得知其隨著切換次數增加所輸入之電量會減少,再將總電量值扣掉電量減少差值即可獲得該所需尺寸面積之電致變色元件的固定透光度之停止電量值,使得於使用該電致變色元件即可對其輸入固定透光度之停止電量值,而能不需反覆進行調整即快速、準確的令電致變色元件達到固定的透光度,並於經過時間老化現象後,不會有影響其透光度準確性的情況發生。 In addition, please refer to the seventh diagram for the characteristics of different sizes of electrochromic components when inputting 1.5V and the eighth diagram for the characteristics of different sizes of electrochromic components when inputting 2.0V. When the component has the same transmittance and different input voltages, the total current area capacity value obtained by the relationship between different current values and different change speeds is proportional; so please refer to the ninth figure for another aspect of the present invention. The schematic diagram of the control steps of the embodiment shows that the current value of each second can be added by the relationship between the different current values generated by the electrochromic element at the same transmittance and different input voltages and the different speeds of change. Knowing the total electric quantity value of the input required, and dividing the total electric quantity value by the size area of the electrochromic element, obtaining the electric quantity per unit area of the unit area of the electrochromic element reaching a fixed transmittance, When the electrochromic element of different size areas is multiplied by the electric quantity per unit area, the electrochromic element in the required size area can be obtained to achieve a fixed transmittance. The total amount of electricity, and the aging phenomenon of the electrochromic element, it is known that the amount of electricity input will decrease as the number of switching times increases, and the total amount of electricity is deducted from the difference in the amount of electricity to obtain the required size. The value of the stop power of the fixed transmittance of the color changing element enables the input of the fixed light transmittance to be used for the use of the electrochromic element, and the electrochromic can be quickly and accurately adjusted without repeated adjustments. The component achieves a fixed transmittance and does not affect the accuracy of its transparency after the aging of time.

藉由以上所述,本發明結構之組成與使用實施說明可知,本發明與現有結構相較之下,本發明主要係利用對電致變色元件輸入固定的總電量值即能達到所需的固定透光度,使得其不需反覆進行調整即快速、準確的令電致變色元件達到固定的透光度,並於經過時間老化現象後,不會有影響其透光度準確性的情況發生,而 在其整體施行使用上更增實用功效特性者。 From the above, the composition and use of the structure of the present invention show that, compared with the prior art, the present invention mainly utilizes the total amount of electricity input to the electrochromic element to achieve the desired fixation. The transmittance is such that it does not need to be adjusted repeatedly, that is, the electrochromic element achieves a fixed transmittance quickly and accurately, and after the aging phenomenon, there is no possibility of affecting the transparency of the transmittance. and Those who have increased utility characteristics in their overall implementation.

然而前述之實施例或圖式並非限定本發明之產品結構或使用方式,任何所屬技術領域中具有通常知識者之適當變化或修飾,皆應視為不脫離本發明之專利範疇。 However, the above-described embodiments or drawings are not intended to limit the structure or the use of the present invention, and any suitable variations or modifications of the invention will be apparent to those skilled in the art.

綜上所述,本發明實施例確能達到所預期之使用功效,又其所揭露之具體構造,不僅未曾見諸於同類產品中,亦未曾公開於申請前,誠已完全符合專利法之規定與要求,爰依法提出發明專利之申請,懇請惠予審查,並賜准專利,則實感德便。 In summary, the embodiments of the present invention can achieve the expected use efficiency, and the specific structure disclosed therein has not been seen in similar products, nor has it been disclosed before the application, and has completely complied with the provisions of the Patent Law. And the request, the application for the invention of a patent in accordance with the law, please forgive the review, and grant the patent, it is really sensible.

Claims (4)

一種電致變色元件透光度控制方法,其主要係先由電致變色元件在相同透光度、不同輸入電壓時,所產生之不同電流值與不同變化速度間的關係,將每秒電流值相加得知其所需輸入之總電量值,使得於使用該電致變色元件即可對其輸入固定透光度之總電量值,而能達到固定的透光度。 A method for controlling transmittance of an electrochromic element, which is mainly a relationship between different current values generated by electrochromic elements at different transmittances and different input voltages and different speeds of change, and current values per second Adding the total charge value of the input required is such that the total charge value of the fixed transmittance can be input to the electrochromic element, and a fixed transmittance can be achieved. 如申請專利範圍第1項所述電致變色元件透光度控制方法,其中,由電致變色元件得知其隨著切換次數增加所輸入之電量會減少,再將總電量值扣掉電量減少差值即可獲得固定透光度之停止電量值。 The method for controlling transmittance of an electrochromic element according to claim 1, wherein the electrochromic element knows that the amount of electricity input as the number of switching increases is reduced, and the total amount of electricity is deducted. The difference can be used to obtain the value of the stop power of the fixed transmittance. 一種電致變色元件透光度控制方法,其主要係先由電致變色元件在相同透光度、不同輸入電壓時,所產生之不同電流值與不同變化速度間的關係,將每秒電流值相加得知其所需輸入之總電量值,且將該總電量值除上該電致變色元件之尺寸面積,而獲得該電致變色元件單位面積達到固定透光度之單位面積電量值,於使用時則依所需不同尺寸面積的電致變色元件與該單位面積電量值之乘積,即能獲得在該所需尺寸面積之電致變色元件達到固定透光度的總電量值,使得於使用該電致變色元件即可對其輸入固定透光度之總電量值,而能達到固定的透光度。 A method for controlling transmittance of an electrochromic element, which is mainly a relationship between different current values generated by electrochromic elements at different transmittances and different input voltages and different speeds of change, and current values per second Adding the total electric quantity value of the input required, and dividing the total electric quantity value by the size area of the electrochromic element, obtaining the electric quantity per unit area of the unit area of the electrochromic element reaching a fixed transmittance, When used, the product of the electrochromic element of different size and the unit area electric quantity value is obtained, that is, the total electric quantity value of the electrochromic element of the required size area to achieve a fixed transmittance can be obtained, so that By using the electrochromic element, the total amount of electric power of the fixed transmittance can be input thereto, and a fixed transmittance can be achieved. 如申請專利範圍第3項所述電致變色元件透光度控制方法,其中,由電致變色元件得知其隨著切換次數增加所輸入之電量會減少,再將總電量值扣掉電量減少差值即可獲得該所需尺寸面積之電 致變色元件的固定透光度之停止電量值。 The method for controlling transmittance of an electrochromic element according to claim 3, wherein the electrochromic element knows that the amount of electric power input decreases as the number of switching times increases, and the total electric quantity value is deducted from the electric quantity. The difference can be obtained for the required size area The value of the stop power of the fixed transmittance of the color-changing element.
TW101133894A 2012-09-14 2012-09-14 Method for controlling light transmittance of electrochromic element TWI430004B (en)

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