TWI423477B - Light emitting diode apparatus and method for enhancing luminous efficiency thereof - Google Patents
Light emitting diode apparatus and method for enhancing luminous efficiency thereof Download PDFInfo
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Description
本發明係有關發光二極體裝置,尤指一種改變基板形狀使其與磷光質接觸面積增加的發光二極體裝置,以提高發光效率。The invention relates to a light-emitting diode device, in particular to a light-emitting diode device which changes the shape of a substrate to increase the contact area with the phosphorescent material, so as to improve luminous efficiency.
改善發光二極體的發光效率為近年研究的重心。當開啟發光二極體時,來自活性層(active layer)的光束向四周發散。部分光束可有效利用,部份光束則由基板吸收。如圖1所繪示。傳統發光二極體10由藍寶石基板102、LED晶粒104和封裝體106所組成。LED晶粒104磊晶生成於藍寶石基板102上並產生光束。晶粒104和藍寶石基板102經封裝保護於封裝體106內。圖中箭頭繪示發射自LED晶粒104之光束。顯然地,光束全方位地發散。實線箭頭顯示光束直接自提供有效光的發光二極體10發出。同時,點線箭頭和虛線箭頭顯示光束向藍寶石基板102發射。Improving the luminous efficiency of light-emitting diodes is the focus of recent research. When the light-emitting diode is turned on, the light beam from the active layer diverges around. Part of the beam can be used effectively, and part of the beam is absorbed by the substrate. As shown in Figure 1. The conventional light emitting diode 10 is composed of a sapphire substrate 102, an LED die 104, and a package 106. The LED die 104 is epitaxially formed on the sapphire substrate 102 and generates a light beam. The die 104 and the sapphire substrate 102 are encapsulated and protected within the package 106. The arrows in the figure show the beams emitted from the LED dies 104. Obviously, the beam diverges in all directions. The solid arrow indicates that the light beam is emitted directly from the light emitting diode 10 that provides effective light. At the same time, dotted and dashed arrows indicate that the light beam is emitted toward the sapphire substrate 102.
點線箭頭代表光束隔絕在藍寶石基板102內,無法助益發光二極體10的發光,主要因為藍寶石基板102的吸收造成全反射(total internal reflection)現象。另一方面,點線箭頭繪示光束有機會不被藍寶石基板102吸收而釋出。目前亟需一種改良的藍寶石基板102,以使困於藍寶石基板內的更多光束能獲得利用。The dotted arrow indicates that the light beam is isolated in the sapphire substrate 102, which does not contribute to the light emission of the light-emitting diode 10, mainly due to the phenomenon of total internal reflection caused by the absorption of the sapphire substrate 102. On the other hand, the dotted arrow indicates that the light beam has a chance to be released without being absorbed by the sapphire substrate 102. There is a need for an improved sapphire substrate 102 to enable more of the light beam trapped within the sapphire substrate.
為解決上述問題,美國第6,791,119號專利揭示一種改良的基板結構。如圖2所示,發光二極體包含基板(其具有第一和第二相對的面),預定的波長的光輻射(optical radiation)可由之透出。基板具有圖案化的剖面。複數個基座自基板的第一面向第二面延伸。將電壓施加於第二面上的二極體區時,二極體區發出預定波長範圍的光到基板。二極體區上的安裝支座(基板的對面)用來支承二極體區。因此,在二極體區施以電壓後,二極體區發射到基板的光會自第一面發出。基板的第一面可包含多個槽來界定基板中的多個三角形基座。槽可包含錐狀側壁(sidewalls)或斜底。基板第一面亦可包含通孔(via holes)陣列。通孔可包含錐狀側壁(sidewalls)或底。In order to solve the above problems, U.S. Patent No. 6,791,119 discloses an improved substrate structure. As shown in FIG. 2, the light emitting diode includes a substrate having first and second opposing faces through which optical radiation of a predetermined wavelength can be transmitted. The substrate has a patterned cross section. A plurality of pedestals extend from the first surface of the substrate toward the second side. When a voltage is applied to the diode region on the second side, the diode region emits light of a predetermined wavelength range to the substrate. The mounting support on the diode region (opposite the substrate) is used to support the diode region. Therefore, after the voltage is applied to the diode region, the light emitted from the diode region to the substrate is emitted from the first surface. The first side of the substrate can include a plurality of grooves to define a plurality of triangular pedestals in the substrate. The slots may include side walls or sloping bottoms. The first side of the substrate may also include an array of via holes. The through holes may include tapered sidewalls or a bottom.
美國第6,791,119號專利指出提高發光效率係由於第一和第二兩相對的面大小不同,促成斜坡的形成。然而,上述美國第6,791,119號專利的設計主要適用於未經磷光質封裝的發光二極體,因而不易施行。U.S. Patent No. 6,791,119 teaches that the improvement in luminous efficiency results in the formation of a slope due to the difference in the size of the first and second opposing faces. However, the design of the above-mentioned U.S. Patent No. 6,791,119 is mainly applicable to a light-emitting diode which is not encapsulated by a phosphorescent material, and thus is not easy to perform.
為克服上述習知之缺點同時提高發光二極體發光效率,本發明遂提出利用增加發光二極體基板與磷光質的接觸面積,以提高發光效率。相較於習知技藝,本發明顯得更易施行。In order to overcome the above disadvantages and improve the luminous efficiency of the light-emitting diode, the present invention proposes to increase the contact area between the light-emitting diode substrate and the phosphor to improve the luminous efficiency. The present invention appears to be easier to implement than conventional techniques.
本案之目的為提供一種具有提高發光效率的發光二極體裝置,包括用來提供第一光束的發光二極體晶粒;具有梯形剖面的基板,用來支承發光二極體晶粒,第一光束可由之透光;以及封裝體,含有磷光質並封裝發光二極體晶粒和基板,用來固定發光二極體晶粒和基板,在磷光質為第一光束所激發時來提供第二光束。The purpose of the present application is to provide a light emitting diode device having improved luminous efficiency, comprising a light emitting diode die for providing a first light beam; a substrate having a trapezoidal cross section for supporting a light emitting diode die, first The light beam is transparent to the light beam; and the package body containing phosphorescent material and encapsulating the light emitting diode die and the substrate for fixing the light emitting diode die and the substrate, and providing the second when the phosphorescent material is excited by the first light beam beam.
根據本案構想,基板在其梯形的坡面上具有槽。According to the present invention, the substrate has grooves on its trapezoidal slope.
根據本案構想,槽藉由電漿蝕刻(plasma etching)、濺射蝕刻(sputter etching)、離子光束蝕刻法(ion beam etching)、反應式離子蝕刻(reactive ion etching)、雷射切割(laser cutting)或機械切割(mechanical cutting)來形成。According to the present invention, the trench is subjected to plasma etching, sputter etching, ion beam etching, reactive ion etching, and laser cutting. Or mechanical cutting to form.
根據本案構想,基板為藍寶石基板。According to the present invention, the substrate is a sapphire substrate.
根據本案構想,基板由電子束蝕刻(electron beam lithography)、雷射光束直寫(laser beam direct writing)、灰階蝕刻(gray-scale lithography)、鑽石切割(diamond ruling)、聚焦離子束研磨(focus ion beam milling)或雷射濺鍍(laser ablation)所成形。According to the present concept, the substrate is subjected to electron beam lithography, laser beam direct writing, gray-scale lithography, diamond ruling, and focused ion beam polishing. Ion beam milling) or laser ablation.
根據本案構想,封裝體由環氧樹脂(epoxy resin)、矽膠(silicone)、聚醚醯亞胺(polyetherimide)、氟碳聚合物(fluorocarbon polymer)、聚甲基丙烯酸甲酯(polymethylmethacrylate,PMMA)、聚碳酸酯(polycarbonate,PC)、或環烯烴共聚物(Cyclo olefin copolymer,COC)所製成。According to the concept of the present invention, the package is made of epoxy resin, silicone, polyetherimide, fluorocarbon polymer, polymethylmethacrylate (PMMA), Polycarbonate (PC), or Cycloolefin copolymer (COC).
本案之另一目的為提供一種提高發光二極體裝置發光效率的方法,包括以下步驟:a)形成具有梯形剖面的基板;b)在基板上生成發光二極體晶粒;c)藉由發光二極體晶粒來提供第一光束;d)封裝基板、發光二極體晶粒和磷光質;以及e)藉由第一光束激發磷光質來提供第二光束。Another object of the present invention is to provide a method for improving the luminous efficiency of a light-emitting diode device, comprising the steps of: a) forming a substrate having a trapezoidal cross section; b) generating a light-emitting diode crystal on the substrate; c) by emitting light The diode die provides a first beam; d) the package substrate, the light emitting diode die and the phosphor; and e) the phosphor is provided by the first beam to provide a second beam.
根據本案構想,本發明進一步包括在梯形的坡面上形成數個槽的步驟。According to the present invention, the invention further includes the step of forming a plurality of grooves on the slope of the trapezoid.
根據本案構想,其中槽由電漿蝕刻、濺射蝕刻、離子光束蝕刻法、反應式離子蝕刻、雷射切割或機械切割所形成。According to the present invention, the grooves are formed by plasma etching, sputter etching, ion beam etching, reactive ion etching, laser cutting or mechanical cutting.
根據本案構想,其中形成步驟藉由電子束蝕刻、雷射光束直寫、灰階蝕刻、鑽石切割、聚焦離子束研磨或雷射濺鍍所施行。According to the present invention, the forming step is performed by electron beam etching, laser beam direct writing, gray scale etching, diamond cutting, focused ion beam milling or laser sputtering.
根據本案構想,其中基板為藍寶石基板。According to the present invention, the substrate is a sapphire substrate.
根據本案構想,其中封裝步驟由環氧樹脂(epoxy resin)、矽膠(silicone)、聚醚醯亞胺(polyetherimide)、氟碳聚合物(fluorocarbon polymer)、聚甲基丙烯酸甲酯(PMMA)、聚碳酸酯(PC)、或環烯烴共聚物(COC)所施行。According to the concept of the present invention, the encapsulation step consists of epoxy resin, silicone, polyetherimide, fluorocarbon polymer, polymethyl methacrylate (PMMA), poly Carbonate (PC) or cyclic olefin copolymer (COC) is used.
本案之另一目的為提供一種提高發光二極體裝置發光效率的方法,包括以下步驟:a)在基板上生成發光二極體晶粒;b)形成具有梯形剖面的基板;c)藉由發光二極體晶粒來提供第一光束;d)封裝基板、發光二極體晶粒和磷光質;以及e)藉由第一光束來激發磷光質,以提供第二光束。Another object of the present invention is to provide a method for improving the luminous efficiency of a light-emitting diode device, comprising the steps of: a) generating a light-emitting diode crystal on a substrate; b) forming a substrate having a trapezoidal cross section; c) emitting light The diode die provides a first beam; d) the package substrate, the light emitting diode die and the phosphor; and e) the phosphor is excited by the first beam to provide a second beam.
根據本案構想,本發明進一步包括在梯形坡面上形成數個槽的步驟。According to the present concept, the invention further includes the step of forming a plurality of grooves on the trapezoidal slope.
根據本案構想,其中槽由電漿蝕刻、濺射蝕刻、離子光束蝕刻法、反應式離子蝕刻、雷射切割或機械切割所形成。According to the present invention, the grooves are formed by plasma etching, sputter etching, ion beam etching, reactive ion etching, laser cutting or mechanical cutting.
根據本案構想,其中形成步驟由電子束蝕刻、雷射光束直寫、灰階蝕刻、鑽石切割、聚焦離子束研磨或雷射濺鍍來施行。According to the present invention, the forming step is performed by electron beam etching, laser beam direct writing, gray scale etching, diamond cutting, focused ion beam milling or laser sputtering.
根據本案構想,其中基板為藍寶石基板。According to the present invention, the substrate is a sapphire substrate.
根據本案構想,其中封裝步驟由環氧樹脂(epoxy resin)、矽膠(silicone)、聚醚醯亞胺(polyetherimide)、氟碳聚合物(fluorocarbon polymer)、聚甲基丙烯酸甲酯(PMMA)、聚碳酸酯(PC)、或環烯烴共聚物(COC)所施行。According to the concept of the present invention, the encapsulation step consists of epoxy resin, silicone, polyetherimide, fluorocarbon polymer, polymethyl methacrylate (PMMA), poly Carbonate (PC) or cyclic olefin copolymer (COC) is used.
體現本發明特徵與優點的兩個實施例將在後段的說明中詳細敘述。本發明能夠在不同的態樣上具有各種的變化,皆不脫離本發明的範圍,且其中的說明及圖式在本質上當作說明之用,而非用以限制本發明。Two embodiments embodying the features and advantages of the present invention are described in detail in the following description. The present invention is capable of various modifications in the various aspects of the invention and the invention is not intended to limit the invention.
圖3與圖4繪示本發明之第一實施例。在圖3中,發光二極體裝置20包括基板202、發光二極體晶粒204和封裝體206。發光二極體晶粒204可提供第一光束。基板202的剖面呈梯形。基板202用來支承發光二極體晶粒204,可使第一光束自發光二極體晶粒204穿透之。本實施例中,基板202係藍寶石基板。封裝體206含有磷光質2062,並封裝有發光二極體晶粒204和基板202,以俾固定發光二極體晶粒20和基板202,當磷光質2062經第一光束激發時提供第二光束。實際上,第一光束和第二光束的結合可激發出肉眼可見的白光。3 and 4 illustrate a first embodiment of the present invention. In FIG. 3, the light emitting diode device 20 includes a substrate 202, a light emitting diode die 204, and a package 206. The light emitting diode die 204 can provide a first beam of light. The cross section of the substrate 202 is trapezoidal. The substrate 202 is used to support the light emitting diode die 204, so that the first light beam can penetrate the light emitting diode die 204. In this embodiment, the substrate 202 is a sapphire substrate. The package 206 contains a phosphor 2062 and is packaged with a light-emitting diode die 204 and a substrate 202 to fix the LED die 20 and the substrate 202 to provide a second beam when the phosphor 2062 is excited by the first beam. . In fact, the combination of the first beam and the second beam excites white light that is visible to the naked eye.
與圖1中的習知技藝相較之下,基板202的剖面呈梯形,並非三角形。假設基板102和202兩者的高度與上表面尺寸均相同,則基板202與封裝體206中磷光質2062的接觸面積大於圖1中的基板102的接觸面積。基板202的結構可改善發光效率。In contrast to the conventional technique of FIG. 1, the substrate 202 has a trapezoidal cross section and is not triangular. Assuming that both the heights of the substrates 102 and 202 are the same as the upper surface dimensions, the contact area of the substrate 202 with the phosphor 2062 in the package 206 is greater than the contact area of the substrate 102 in FIG. The structure of the substrate 202 can improve luminous efficiency.
形成發光二極體裝置20及結合光的方法包含以下步驟。首先,形成具有梯形剖面的基板202,接著在基板202上生成發光二極體晶粒204。其中形成與生成的步驟順序可對調。換言之,發光二極體晶粒204先生成於基板202上,之後形成梯形剖面的基板202。The method of forming the light-emitting diode device 20 and combining light includes the following steps. First, a substrate 202 having a trapezoidal cross section is formed, and then a light emitting diode die 204 is formed on the substrate 202. The order in which the steps are formed and generated can be reversed. In other words, the light-emitting diode die 204 is formed on the substrate 202, and then the substrate 202 having a trapezoidal cross-section is formed.
藉由發光二極體晶粒204來提供第一光束,並封裝基板202、發光二極體晶粒204和磷光質2062。最後,藉由第一光束來激發磷光質2062,以提供第二光束。第一和第二光束的結合可產生白光。The first light beam is provided by the light emitting diode die 204, and the substrate 202, the light emitting diode die 204, and the phosphor 2062 are packaged. Finally, the phosphor 6206 is excited by the first beam to provide a second beam. The combination of the first and second beams produces white light.
在本實施例中,基板202的坡面由電子束蝕刻(electron beam lithography)所成形,亦可採用雷射光束直寫(laser beam direct writing)、灰階蝕刻(gray-scale lithography)、鑽石切割(diamond ruling)、聚焦離子束研磨(focus ion beam milling)、雷射濺鍍(laser ablation)等。封裝體206由環氧樹脂(epoxy resin)所製成,然並不限於環氧樹脂(epoxy resin)。封裝體206亦可由矽膠(silicone)、聚醚醯亞胺(polyetherimide、氟碳聚合物(fluorocarbon polymer)、聚甲基丙烯酸甲酯(PMMA)、聚碳酸酯(PC)、或環烯烴共聚物(COC)來製成。In this embodiment, the slope of the substrate 202 is formed by electron beam lithography, and laser beam direct writing, gray-scale lithography, and diamond cutting may also be used. (diamond ruling), focused ion beam milling, laser ablation, and the like. The package 206 is made of an epoxy resin, but is not limited to an epoxy resin. The package 206 may also be a silicone, a polyetherimide, a fluorocarbon polymer, a polymethyl methacrylate (PMMA), a polycarbonate (PC), or a cyclic olefin copolymer ( COC) to make.
根據本發明,基板202的剖面呈梯形。因此,基板202的下表面不需要大於上表面。請參照圖4。基板202的剖面仍呈梯形,然其上表面大於下表面。基板202與封裝體206中磷光質2062的接觸面積因而增加,發光效率隨之改善。According to the present invention, the cross section of the substrate 202 is trapezoidal. Therefore, the lower surface of the substrate 202 need not be larger than the upper surface. Please refer to Figure 4. The cross section of the substrate 202 is still trapezoidal, but its upper surface is larger than the lower surface. The contact area between the substrate 202 and the phosphor 6206 in the package 206 is thus increased, and the luminous efficiency is improved.
圖5至圖7繪示本發明之第二實施例。如圖5所示,發光二極體裝置30包括基板302、發光二極體晶粒304和封裝體306。發光二極體晶粒304可提供第一光束。基板302的剖面呈梯形,用來支承發光二極體晶粒304,可使第一光束自發光二極體晶粒304穿透之。本實施例中,基板302係藍寶石基板,同第一實施例。封裝體306含有磷光質3062並封裝有發光二極體晶粒304和基板302,以固定發光二極體晶粒304與基板302,當第一光束激發磷光質3062時提供第二光束。5 to 7 illustrate a second embodiment of the present invention. As shown in FIG. 5, the light emitting diode device 30 includes a substrate 302, a light emitting diode die 304, and a package 306. The light emitting diode die 304 can provide a first beam of light. The substrate 302 has a trapezoidal cross section for supporting the light emitting diode die 304, so that the first light beam can penetrate the light emitting diode die 304. In the present embodiment, the substrate 302 is a sapphire substrate, which is the same as the first embodiment. The package 306 contains a phosphor 3062 and is packaged with a light emitting diode die 304 and a substrate 302 to fix the LED die 304 and the substrate 302 to provide a second beam when the first beam excites the phosphor 3062.
不同於第一實施例,基板302在梯形坡面3024上具有槽3022。槽3022藉由電漿蝕刻(plasma etching)形成。實施上亦可使用濺射蝕刻(sputter etching)、離子光束蝕刻法(ion beam etching)、反應式離子蝕刻(reactive ion etching)、雷射切割(laser cutting)或機械切割(mechanical cutting),其效果相同。槽3022可增加基板302與磷光質3062的接觸面積。Unlike the first embodiment, the substrate 302 has a slot 3022 on the trapezoidal ramp 3024. The trench 3022 is formed by plasma etching. In practice, sputter etching, ion beam etching, reactive ion etching, laser cutting, or mechanical cutting may also be used. the same. The groove 3022 can increase the contact area of the substrate 302 with the phosphor 3062.
同樣地,假如基板102和302的高度與上表面尺寸與均相同,則基板302與封裝體306中磷光質3062的接觸面積大於圖1中的基板102的接觸面積。基板302的結構可改善發光效率。Similarly, if the heights of the substrates 102 and 302 are the same as the upper surface, the contact area of the substrate 302 with the phosphor 3062 in the package 306 is larger than the contact area of the substrate 102 in FIG. The structure of the substrate 302 can improve luminous efficiency.
在本實施例,基板302的坡面3024由電子束蝕刻(electron beam lithography)所成形,同樣亦可採用雷射光束直寫(laser beam direct writing)、灰階蝕刻(gray-scale lithography)、鑽石切割(diamond ruling)、聚焦離子束研磨(focus ion beam milling)或雷射濺鍍(laser ablation)。封裝體306是由環氧樹脂(epoxy resin)所製成。如同第一實施例,封裝體306不限由環氧樹脂來製成,亦可由矽膠(silicone)、聚醚醯亞胺(polyetherimide)、氟碳聚合物(fluorocarbon polymer)、聚甲基丙烯酸甲酯(PMMA)、聚碳酸酯(PC)、或環烯烴共聚物(COC)來製成。In the present embodiment, the slope surface 3024 of the substrate 302 is formed by electron beam lithography, and laser beam direct writing, gray-scale lithography, and diamond can also be used. Diamond ruling, focus ion beam milling or laser ablation. The package 306 is made of an epoxy resin. As with the first embodiment, the package 306 is not limited to epoxy resin, but may also be silicone, polyetherimide, fluorocarbon polymer, polymethyl methacrylate. (PMMA), polycarbonate (PC), or cyclic olefin copolymer (COC).
根據本發明,基板302的剖面呈梯形。因此,基板302的下表面不需要大於上表面。請參照圖6。基板302的上表面大於其下表面,然其剖面仍呈梯形。基板302與封裝體2306中磷光質3062的接觸面積因而增加,發光效率亦隨之改善According to the present invention, the cross section of the substrate 302 is trapezoidal. Therefore, the lower surface of the substrate 302 need not be larger than the upper surface. Please refer to Figure 6. The upper surface of the substrate 302 is larger than the lower surface thereof, but its cross section is still trapezoidal. The contact area between the substrate 302 and the phosphor 3062 in the package 2306 is thus increased, and the luminous efficiency is also improved.
應注意的是,任何非垂直的坡面3024均可使用於本發明,不侷限兩坡面3024均有槽3022。如圖7所示,在單一坡面3024上具有槽3022的不對稱梯形亦適用於本發明。It should be noted that any non-vertical ramp 3024 can be used with the present invention, and it is not limited that both ramps 3024 have slots 3022. As shown in Figure 7, an asymmetric trapezoid having a groove 3022 on a single ramp 3024 is also suitable for use in the present invention.
雖然本發明已以實施例揭露如上,然其並非用以限定本發明。反之,任何所屬技術領域中具有通常知識者,在不脫離本發明之精神和範圍內,當可作些許之更動與潤飾,因此本發明之保護範圍當視後附之申請專利範圍所界定者為準。Although the present invention has been disclosed above by way of example, it is not intended to limit the invention. To the contrary, the scope of the invention is defined by the scope of the appended claims. quasi.
10...發光二極體10. . . Light-emitting diode
102...藍寶石基板102. . . Sapphire substrate
104...LED晶粒104. . . LED die
106...封裝體106. . . Package
20...發光二極體裝置20. . . Light-emitting diode device
202...基板202. . . Substrate
204...發光二極體晶粒204. . . Light-emitting diode grain
206...封裝體206. . . Package
2062...磷光質2062. . . Phosphorescence
30...發光二極體裝置30. . . Light-emitting diode device
302...基板302. . . Substrate
3022...槽3022. . . groove
3024...坡面3024. . . Slope
304...發光二極體晶粒304. . . Light-emitting diode grain
306...封裝體306. . . Package
3062...磷光質3062. . . Phosphorescence
圖1繪示習知技藝之傳統發光二極體。FIG. 1 illustrates a conventional light emitting diode of the prior art.
圖2繪示習知技藝中另一經改良的發光二極體。2 illustrates another modified light emitting diode in the prior art.
圖3繪示本發明之第一實施例。Figure 3 illustrates a first embodiment of the present invention.
圖4繪示第一實施例之另一樣態。Figure 4 illustrates another aspect of the first embodiment.
圖5繪示本發明之第二實施例。Figure 5 illustrates a second embodiment of the present invention.
圖6繪示第二實施例之另一樣態。Figure 6 illustrates another aspect of the second embodiment.
圖7繪示第一與第二實施例之綜合樣態。Figure 7 illustrates a combination of the first and second embodiments.
20...發光二極體裝置20. . . Light-emitting diode device
202...基板202. . . Substrate
204...發光二極體晶粒204. . . Light-emitting diode grain
206...封裝體206. . . Package
2062...磷光質2062. . . Phosphorescence
Claims (15)
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TW200623444A (en) * | 2004-12-22 | 2006-07-01 | Advanced Optoelectronic Tech | LED device emitting neutral color light and manufacture method thereof |
US20070069231A1 (en) * | 2005-09-29 | 2007-03-29 | Kaori Namioka | Semiconductor light-emitting device and method |
US7667224B2 (en) * | 2005-03-09 | 2010-02-23 | Kabushiki Kaisha Toshiba | Semiconductor light emitting device and semiconductor light emitting apparatus |
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TW200623444A (en) * | 2004-12-22 | 2006-07-01 | Advanced Optoelectronic Tech | LED device emitting neutral color light and manufacture method thereof |
US7667224B2 (en) * | 2005-03-09 | 2010-02-23 | Kabushiki Kaisha Toshiba | Semiconductor light emitting device and semiconductor light emitting apparatus |
US20070069231A1 (en) * | 2005-09-29 | 2007-03-29 | Kaori Namioka | Semiconductor light-emitting device and method |
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