TWI400704B - Method of improving read stability of optical recording medium and optical recording medium manufactured using the method - Google Patents

Method of improving read stability of optical recording medium and optical recording medium manufactured using the method Download PDF

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TWI400704B
TWI400704B TW98107973A TW98107973A TWI400704B TW I400704 B TWI400704 B TW I400704B TW 98107973 A TW98107973 A TW 98107973A TW 98107973 A TW98107973 A TW 98107973A TW I400704 B TWI400704 B TW I400704B
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layer
recording medium
optical recording
substrate
recording
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TW201034012A (en
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Han Feng Chang
Yuh Rur Kuo
Yung Hui Hung
kun long Li
Shih Hsien Ma
Pang Chi Liu
Chin Yen Yeh
Kuan Lan Fang
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Cmc Magnetics Corp
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改善光記錄媒體讀寫訊號穩定性的方法及利用該方法製造之光記錄媒體Method for improving stability of read/write signals of optical recording medium and optical recording medium manufactured by the method

本發明是關於一種改善光記錄媒體讀寫訊號穩定性之方法,特別是一種不需大幅變換膜層結構及寫錄策略下,利用調整記錄層厚度與控制寫擦功率比值來改善光記錄媒體讀寫訊號穩定性的方法及利用該方法製造之光記錄媒體。The invention relates to a method for improving the stability of the read/write signal of an optical recording medium, in particular to improving the optical recording medium reading by adjusting the thickness of the recording layer and controlling the ratio of the writing power without significantly changing the structure of the film layer and the writing strategy. A method of writing signal stability and an optical recording medium manufactured by the method.

光資訊儲存是利用雷射光技術將資料記錄在光記錄媒體中,原理在於利用聚焦的雷射光來改變光碟記錄層材料的結構,使之在讀取時因結構差異而造成反射率有明顯的不同,以此作為0與1訊號的記錄與讀取。光記錄媒體的種類包含唯讀型光碟、可寫一次光碟以及可覆寫光碟,其中可覆寫光碟是利用相變化記錄層材料在不同強度的雷射光照射下會產生結晶相或非晶相的結構,藉由結晶相與非晶相之間的可逆相轉變來達到資料重複讀寫的功能。Optical information storage uses laser light technology to record data in an optical recording medium. The principle is to use the focused laser light to change the structure of the optical recording layer material, so that the reflectivity is significantly different due to structural differences during reading. This is used as a record and read of the 0 and 1 signals. The types of optical recording media include a read-only optical disc, a writable optical disc, and an rewritable optical disc, wherein the rewritable optical disc is formed by using a phase change recording layer material to generate a crystalline phase or an amorphous phase under irradiation of different intensity laser light. The structure realizes the function of repeated reading and writing of data by reversible phase transition between the crystalline phase and the amorphous phase.

對於相變化光碟的訊號儲存方法,記錄標記(recording mark)的寫入是使用一較高功率的短脈衝雷射(該短脈衝雷射之功率即為寫入功率Pw)照射於光碟片的記錄層,被照射的區域溫度急速上升至材料熔點以上,此時由於膜層散熱的設計及碟片快速旋轉,使得融熔區域急速冷卻,以致此區域的原子沒有時間移動到穩定之晶格位置,進而形成反射率較低之非晶相,此處非晶質區域與周圍結晶區域的光學特性不同,造成反射率對比。For the signal storage method of the phase change optical disc, the recording mark is written by using a higher power short pulse laser (the power of the short pulse laser is the write power Pw) to illuminate the record of the optical disc. In the layer, the temperature of the irradiated area rises rapidly above the melting point of the material. At this time, due to the heat dissipation design of the film layer and the rapid rotation of the disk, the melting region is rapidly cooled, so that the atoms in the region do not have time to move to the stable lattice position. Further, an amorphous phase having a low reflectance is formed, where the optical properties of the amorphous region and the surrounding crystalline region are different, resulting in a contrast ratio.

記錄標記的擦拭則是使用一略低功率之長脈衝雷射(該長脈衝雷射之功率即為抹除功率Pe)照射在記錄標記的區域,此區域的溫度將被加熱至結晶溫度以上、熔點以下,由於受到較長的雷射脈衝照射,原子有足夠的時間及能量移動到較穩定的狀態,此區域將形成反射率較高之結晶相,此為刪除記錄的動作。假如反射率較高的結晶相代表"0",而反射率較低的非晶相代表"1",如此便可將0與1之數位資料記錄於光碟片上。The wiping of the recording mark is performed by using a slightly low-power long-pulse laser (the power of the long-pulse laser is the erasing power Pe) to illuminate the area of the recording mark, and the temperature of this area will be heated to above the crystallization temperature. Below the melting point, due to the long laser pulse irradiation, the atom has sufficient time and energy to move to a more stable state, and this region will form a crystal phase with a higher reflectance, which is the action of deleting the record. If the crystal phase with a higher reflectance represents "0", and the amorphous phase with a lower reflectance represents "1", the digital data of 0 and 1 can be recorded on the disc.

讀取資料時,利用更低的讀取功率照射於光碟片的記錄層,由於結晶/非晶相的反射率不同,故可用一較低的雷射功率偵測其反射光之強弱變化,便可讀取所記錄之數位資料。When reading data, the recording layer of the optical disc is irradiated with a lower reading power. Since the reflectivity of the crystalline/amorphous phase is different, a weak laser power can be used to detect the change of the reflected light. The recorded digital data can be read.

因此當雷射光照射在記錄層時,調變不同的寫入功率Pw、抹除功率Pe與基底功率Pb的大小與照射時間,便能夠在記錄層上形成新的記錄標記,並同時消去已形成之舊記錄標記,達到直接覆寫(directover-write)的功能。Therefore, when the laser light is irradiated on the recording layer, the different writing power Pw, the erasing power Pe and the substrate power Pb are modulated and the irradiation time is formed, so that a new recording mark can be formed on the recording layer and simultaneously eliminated. The old record mark, to achieve direct overwrite (directover-write) function.

記錄標記的品質可以抖動值來評估,抖動值是指:當雷射照射記錄層上的記錄標記後,因為記錄標記與沒有記錄標記的區域反射率有明顯差異而形成0與1之數位資料。若於檢測記錄標記前頭與後端部位(由1改變為0以及由0改變為1)的邊界時間並設為邊緣信號時,此邊緣信號與再生信號的時脈T之時間偏差即為抖動值。在BD-RE的例子中,1倍速記錄線速度為4.92m/s,基準時脈T為15.15奈秒。The quality of the recorded mark can be evaluated by the jitter value. When the laser illuminates the recording mark on the recording layer, the digital data of 0 and 1 is formed because the reflectance of the area between the recorded mark and the area where the mark is not recorded is significantly different. If the boundary time between the front end and the back end portion (changed from 1 to 0 and from 0 to 1) is detected and set as the edge signal, the time deviation of the edge signal from the clock T of the reproduced signal is the jitter value. . In the example of BD-RE, the 1x speed recording linear velocity is 4.92 m/s, and the reference clock T is 15.15 nanoseconds.

基於相變化光記錄媒體的記錄機制,為了能夠實現高倍速的記錄,記錄層材料必須具有高結晶速率,如此才可以在高轉速的情形下仍能完整的進行舊訊號的抹除,實現高速直接覆寫。結晶速率高低與記錄層材料的本質有關,但若為了提高記錄速度而一昧選擇高結晶速率的記錄層材料,容易使記錄媒體在高溫環境下進行長期保存時記錄標記隨著時間逐漸變形、甚至消失,或是非記錄標記的區域結晶型態改變,造成覆寫特性變差。這時便必須從記錄模層結構與寫錄策略的調整來控制雷射照射在光記錄媒體後產生的散熱問題,亦即,一方面必須讓足夠的雷射能量照射在記錄媒體以產生可順利讀取的訊號,一方面則必須讓雷射照射記錄層產生的熱能迅速排出,避免過多的熱量累積造成記錄層材料再次變質。此外,若記錄層材料在結晶速率快,當雷射寫入訊號時若記錄層熔融後未能急速冷卻而形成足夠長的標記,將難以控制記錄標記成為特定長度,也因此對應越短基準時脈T長度的記錄標記將越不容易正確的形成。Based on the recording mechanism of the phase-change optical recording medium, in order to enable high-speed recording, the recording layer material must have a high crystallization rate, so that the old signal can be completely erased under high-speed conditions, achieving high-speed direct Overwrite. The crystallization rate is related to the nature of the recording layer material. However, if a recording layer material having a high crystallization rate is selected in order to increase the recording speed, it is easy to cause the recording mark to gradually deform over time when the recording medium is stored for a long time in a high temperature environment, or even The disappearance, or the change in the crystalline form of the non-recorded mark, causes the overwrite characteristics to deteriorate. At this time, it is necessary to control the heat dissipation problem caused by the laser irradiation on the optical recording medium from the adjustment of the recording layer structure and the writing strategy, that is, on the one hand, sufficient laser energy must be irradiated on the recording medium to produce a smooth reading. On the one hand, the heat generated by the laser irradiation recording layer must be quickly discharged to avoid excessive heat accumulation and cause the recording layer material to deteriorate again. In addition, if the recording layer material has a high crystallization rate, when the recording layer is melted and the cooling of the recording layer is not rapidly cooled to form a sufficiently long mark, it is difficult to control the recording mark to a specific length, and thus the shorter reference time is required. The less the recording mark of the pulse length T will be formed correctly.

不同的記錄層材料形成非晶相的難易程度不同,結晶速率也不同,因此應用特定的記錄層材料時會有其最佳的記錄線速度與應用雷射功率的範圍,一般而言,記錄線速度提高時,為了能夠在更短的時間內形成記錄標記,必須採取更高能量的寫入功率,因此隨著記錄線速度增加,寫入功率與抹除功率往往也跟著提高,因此寫入功率與抹除功率的大小與比值對於能否形成完美的記錄標誌具有很重要的影響。Different recording layer materials have different degrees of difficulty in forming amorphous phase, and the crystallization rate is also different. Therefore, when a specific recording layer material is applied, there is an optimum recording line speed and a range of applied laser power. Generally, the recording line When the speed is increased, in order to form the recording mark in a shorter time, it is necessary to take a higher energy write power, so as the recording line speed increases, the write power and the erase power tend to increase, so the write power The magnitude and ratio of the erased power have a significant impact on the ability to form a perfect record mark.

中華民國專利證號第I289723號發明專利,揭示一種在相變記錄媒體的應用上,利用調整峰值功率、底值功率與抹除功率來控制照射功率,並改變抹除功率與峰值功率的比值等參數來找到最適合的特定記錄線速度之方法,以及利用特定的間隔改變記錄功率與抹除功率的比值來達到從內圈至外圈有一致良好特性的記錄方法。然而,上述專利中並未提到其對於資料讀取穩定性的影響,有時記錄媒體即使可以在初次寫入訊號時具有良好的記錄特性(例如低的抖動值),但是碟片膜層結構與記錄參數若沒有做出適當的設計,則碟片易因多次重複的讀取資料後,熱量累積在記錄層,使記錄標誌發生變化,進一步導致記錄的資料喪失。因此本發明之目的在於提供一種光記錄方法,可利用碟片吸收率與膜層結構的關係來控制適當的寫入功率與抹除功率,以及利用寫入功率與抹除功率的搭配來改善資料讀取穩定性的方法。如何適當地增加記錄層厚度與降低抹除功率和寫入功率之比值來提高資料讀取穩定性是本發明主要的解決手段。The invention patent of the Republic of China Patent No. I289723 discloses a method for controlling the illumination power by adjusting the peak power, the bottom power and the erasing power in the application of the phase change recording medium, and changing the ratio of the erasing power to the peak power, etc. The parameters are used to find the most suitable method for recording the line speed, and the ratio of the recording power to the erase power is changed by a specific interval to achieve a consistently good recording method from the inner ring to the outer ring. However, the above patent does not mention its influence on data reading stability. Sometimes the recording medium has good recording characteristics (for example, low jitter value) even when the signal is written for the first time, but the disc film structure If the recording parameters are not properly designed, the disc is easily accumulated in the recording layer due to repeated reading of the data, causing the recording mark to change, further causing the recorded data to be lost. Therefore, an object of the present invention is to provide an optical recording method which can control the appropriate write power and erase power by utilizing the relationship between the disc absorption rate and the film structure, and improve the data by using the combination of the write power and the erase power. The method of reading stability. How to appropriately increase the thickness of the recording layer and reduce the ratio of erasing power and writing power to improve data reading stability is the main solution of the present invention.

本發明提供一種改善光記錄媒體讀寫訊號穩定性的方法及利用該方法製造之光記錄媒體,係藉由改變光記錄媒體記錄層厚度來調整記錄媒體之光吸收率,並在預設之特定光吸收率下,設定抹除功率與寫入功率之比值(Pe/Pw)、寫入功率(Pw)、抹除功率(Pe)其中至少一項為可變動值。在不大幅改變初次寫入訊號之抖動值的前提下,於對應之吸收率逐步降低抹除功率與寫入功率之比值,或逐步增加記錄媒體(不包含反射層)之吸收率,再逐步降低抹除功率與寫入功率之比值,並以抖動值在經過連續1百萬次訊號讀取後是否急遽上升惡化來評估記錄訊號的讀寫穩定性之光記錄方法。The present invention provides a method for improving the stability of the read/write signal of an optical recording medium and an optical recording medium manufactured by the method, which adjusts the light absorption rate of the recording medium by changing the thickness of the recording layer of the optical recording medium, and is preset at a specific At the light absorption rate, at least one of the ratio of the erase power to the write power (Pe/Pw), the write power (Pw), and the erase power (Pe) is set to a variable value. Under the premise that the jitter value of the initial write signal is not greatly changed, the ratio of the erase power to the write power is gradually decreased at the corresponding absorption rate, or the absorption rate of the recording medium (excluding the reflective layer) is gradually increased, and then gradually decreased. The optical recording method of erasing the read/write stability of the recorded signal by erasing the ratio of the power to the write power and whether the jitter value deteriorates sharply after one million consecutive signal readings.

本發明提供之可寫錄光記錄媒體的記錄方法,可利用基板側入射之雷射光進行資料讀寫,若配合膜層結構的調整,也可利用與基板相反側入射之雷射光進行資料讀寫。鍍著於基板上的膜層包含反射層、記錄層、保護層與光穿透層。如第1圖所示,為一種膜層結構之表示,其建構於一基板、於基板之上的第一保護層、於第一保護層之上的記錄層、於記錄層之上的第二保護層、於第二保護層之上的第二介面層、於第二介面層之上的反射層、以及最上層的光穿透層。此結構之光記錄媒體可由投射於基板側之雷射光予以照射,進行資料讀寫。The recording method of the writable optical recording medium provided by the invention can read and write data by using the laser light incident on the substrate side, and if the film structure is adjusted, the laser light incident on the opposite side of the substrate can also be used for reading and writing data. . The film layer plated on the substrate includes a reflective layer, a recording layer, a protective layer, and a light penetrating layer. As shown in FIG. 1, a representation of a film structure is constructed on a substrate, a first protective layer over the substrate, a recording layer over the first protective layer, and a second over the recording layer. a protective layer, a second interface layer over the second protective layer, a reflective layer over the second interface layer, and a top light transmissive layer. The optical recording medium of this structure can be irradiated with laser light projected on the substrate side to perform reading and writing of data.

本發明應用的光記錄媒體具有一基板,以及鍍著於基板上的膜層至少包含反射層、記錄層、保護層與光穿透層。其可利用基板側入射之雷射光進行資料讀寫,若配合膜層結構的調整,也可利用與基板相反側入射之雷射光進行資料讀寫。如第1圖為一種膜層結構之表示,其建構於一基板、於基板之上的反射層、於反射層之上的第一介面層、於第一介面層之上的第一保護層、於第一保護層之上的記錄層、於記錄層之上的第二保護層、於第二保護層之上的第二介面層、以及最上層的光穿透層。此結構之光記錄媒體可由投射於基板相反側之雷射光予以照射,進行資料讀寫。The optical recording medium to which the present invention is applied has a substrate, and the film layer plated on the substrate includes at least a reflective layer, a recording layer, a protective layer, and a light transmissive layer. The material can be read and written by using the laser light incident on the substrate side. If the film structure is adjusted, the laser light incident on the opposite side of the substrate can be used for reading and writing data. 1 is a representation of a film structure constructed on a substrate, a reflective layer over the substrate, a first interface layer over the reflective layer, a first protective layer over the first interface layer, a recording layer over the first protective layer, a second protective layer over the recording layer, a second interface layer over the second protective layer, and a light transmissive layer of the uppermost layer. The optical recording medium of this structure can be irradiated with laser light projected on the opposite side of the substrate to read and write data.

如第1圖所示,為本發明之光記錄媒體實施範例之一的膜層結構剖面圖,依此實施例之光記錄媒體包含一基板(1)、反射層(2)、第一介面層(3)、第一保護層(4)、記錄層(5)、第二保護層(6)、第二介面層(7)與光穿透層(8)。基板(1)選用具光學透明的材料,並能提供記錄媒體適當的機械強度,材質包括聚碳酸脂樹脂(polycarbonate resin)、聚甲基丙烯酸甲脂(polymethyl methacrylate)、聚苯乙烯樹脂(polystyrene resin)、聚乙烯樹脂(polyethylene resin)、聚丙烯樹脂(polypropylene resin)等,基板上預先刻有凹槽(grooves)與平地(land),當資料被記錄或讀取時,這些凹槽(grooves)與平地(land)可作為雷射光束導軌與資料記錄位置之用。As shown in FIG. 1 , a sectional view of a film structure of one embodiment of the optical recording medium of the present invention, the optical recording medium according to the embodiment includes a substrate (1), a reflective layer (2), and a first interface layer. (3) a first protective layer (4), a recording layer (5), a second protective layer (6), a second interface layer (7) and a light penetrating layer (8). The substrate (1) is provided with an optically transparent material and can provide appropriate mechanical strength of the recording medium, and the material includes a polycarbonate resin, a polymethyl methacrylate, and a polystyrene resin. ), polyethylene resin, polypropylene resin, etc., the substrate is pre-etched with grooves and land, when the data is recorded or read, these grooves (grooves) And land can be used as a laser beam guide and data recording position.

第一介面層(3)與第二介面層(7)選自金屬氮化物,例如氮化矽(Si3 N4 )、氮化鍺(GeN)、氮化鈦(TiN)、五氧化二鈮(Nb2 O5 )、氮氧化矽(Si-O-N),或金屬氧化物如二氧化矽(SiO2 )、三氧化二鋁(Al2 O3 )、二氧化鈦(TiO2 )。第一介面(3)層與第二介面層(7)之厚度分別介於0nm到50nm之間。The first interface layer (3) and the second interface layer (7) are selected from metal nitrides such as tantalum nitride (Si 3 N 4 ), germanium nitride (GeN), titanium nitride (TiN), tantalum pentoxide. (Nb 2 O 5 ), bismuth oxynitride (Si-ON), or metal oxides such as cerium oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), and titanium dioxide (TiO 2 ). The thickness of the first interface layer (3) and the second interface layer (7) are respectively between 0 nm and 50 nm.

第一保護層(4)與第二保護層(6)選自金屬氧化物或氮化物材料,例如硫化鋅一氧化矽(ZnS-SiO2 )、氮化矽(SiN或Si3 N4 )、氮化鍺(GeN)、碳化矽(SiC)、二氧化矽(SiO2 )、三氧化二鋁(Al2 O3 )、二氧化鈦(TiO2 )。第一保護層(4)與第二保護層(6)可以是上述介電材料其中一種,或是由上述介電材料中的兩種或兩種以上所組成,個別之厚度介於1nm到200nm之間。反射層(2)為銀(Ag)、金(Au)、鋁(Al)、鉬(Mo)、鉭(Ta)、鈦(Ti)與上述元素所組成之合金,厚度介於5nm到300nm之間。The first protective layer (4) and the second protective layer (6) are selected from metal oxide or nitride materials, such as zinc sulfide cerium oxide (ZnS-SiO 2 ), tantalum nitride (SiN or Si 3 N 4 ), Cerium nitride (GeN), tantalum carbide (SiC), cerium oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), titanium dioxide (TiO 2 ). The first protective layer (4) and the second protective layer (6) may be one of the above dielectric materials, or may be composed of two or more of the above dielectric materials, and the respective thicknesses are between 1 nm and 200 nm. between. The reflective layer (2) is an alloy of silver (Ag), gold (Au), aluminum (Al), molybdenum (Mo), tantalum (Ta), titanium (Ti) and the above elements, and has a thickness of 5 nm to 300 nm. between.

記錄層(5)為具高結晶速率之相變化材料,並可因應不同記錄線速度的使用需求而調整記錄層材料的組成,較理想的成分至少包含鍺(Ge)、錫(Sn)、銻(Sb)、碲(Te)、鎵(Ga)、銦(In)元素其中一種,具體的應用組成有Ge-In-Sb-Te、Ge-Sb-Sn、In-Sb-Te、Ag-In-Sb-Te、Ge-In-Sb-Sn、Ga-In-Sb-Te、Ga-In-Sb-Sn等。在BD2倍速的應用時,較理想的記錄層材料與組成範圍為:0<Ge<10、0<In<10、50<Sb<70、20<Te<30(原子百分比)。記錄層(5)之厚度介於3nm到30nm之間。光穿透層(8)為光硬化樹脂,用來保護光記錄媒體之膜層穩定性,避免膜層材料遭受磨損、受潮變質或暴露於空氣中氧化。The recording layer (5) is a phase change material having a high crystallization rate, and the composition of the recording layer material can be adjusted according to the use requirements of different recording line speeds. The ideal composition contains at least germanium (Ge), tin (Sn), and germanium. One of (Sb), tellurium (Te), gallium (Ga), and indium (In) elements, and the specific application composition is Ge-In-Sb-Te, Ge-Sb-Sn, In-Sb-Te, Ag-In -Sb-Te, Ge-In-Sb-Sn, Ga-In-Sb-Te, Ga-In-Sb-Sn, and the like. In the application of BD2 speed, the preferred recording layer material and composition range is: 0 < Ge < 10, 0 < In < 10, 50 < Sb < 70, 20 < Te < 30 (atomic percent). The thickness of the recording layer (5) is between 3 nm and 30 nm. The light penetrating layer (8) is a photohardening resin for protecting the film layer stability of the optical recording medium, and avoiding the film material being subjected to abrasion, moisture deterioration or exposure to oxidation in the air.

本發明之改善可寫錄光記錄媒體訊號讀取穩定性的方法,可提高光碟資料儲存的穩定性,使記錄之訊號不會因為多次重複的讀取便致使訊號強度衰弱或消失,可長期保存儲存的資料。The method for improving the reading stability of the recordable optical recording medium of the invention can improve the stability of the storage of the optical disc data, so that the recorded signal does not cause the signal strength to weaken or disappear due to repeated readings, and can be long-term. Save the stored data.

為了更進一步瞭解本發明之特點及技術內容,請參閱以下有關本發明之附圖及詳細說明,不過所附圖式僅提供參考與說明用,並非為用來對本發明加以限制者。For a better understanding of the features and technical aspects of the present invention, reference should be made to the accompanying drawings.

實施例一:Embodiment 1:

準備一刻有凹槽(grooves)與平地(land)之藍光可寫錄光碟(Blue-ray Disc-RE)基板(1),其軌距為74μm,厚度為1.1mm。利用磁控濺鍍的方式在基板(1)上鍍製一層厚100nm之銀(Ag)於反射層(2),接著在反射層(2)上鍍製厚8nm之氮化矽(SiN)於第一介面層(3),之後再於第一介面層(3)上鍍製厚8nm之硫化鋅-氧化矽(ZnS-SiO2 )於第一保護層(4),之後再於第一保護層(4)上分別形成厚11nm的記錄層(5),再於記錄層(5)上鍍製厚19nm之硫化鋅-氧化矽(ZnS-SiO2 )於第二保護層(6),以及在第二保護層(6)上鍍上厚30nm之氮化矽(SiN)於第二介面層(7),膜層結構圖如第1圖所示。最後,在保護層上旋鍍上一層厚0.1mm之光透射膜,作為光透射層(8),完成實驗範例一之碟片。A blue-ray disc-relay (1) having a groove and a land at a moment with a gauge of 74 μm and a thickness of 1.1 mm was prepared. A layer of 100 nm thick silver (Ag) is deposited on the substrate (1) by magnetron sputtering on the reflective layer (2), and then 8 nm thick tantalum nitride (SiN) is deposited on the reflective layer (2). a first interface layer (3), and then a thickness of 8 nm of zinc sulfide-yttria (ZnS-SiO 2 ) is deposited on the first interface layer (3) on the first protective layer (4), and then first protection a recording layer (5) having a thickness of 11 nm is formed on the layer (4), and a zinc oxide-yttria (ZnS-SiO 2 ) having a thickness of 19 nm is plated on the recording layer (5) on the second protective layer (6), and On the second protective layer (6), 30 nm thick tantalum nitride (SiN) is plated on the second interface layer (7), and the structure of the film layer is as shown in Fig. 1. Finally, a light transmission film having a thickness of 0.1 mm was spin-plated on the protective layer as a light transmitting layer (8), and the disc of the experimental example 1 was completed.

濺鍍之薄膜厚度是用原子力顯微鏡(AFM)與Eta Optik觀察;碟片之動態分析則是使用PULSTEC ODU-1000動態測試儀,量測碟片之動態性質。量測之寫入功率為5.5mW到5.9mW之間,讀取功率為0.35mW,雷射波長λ=405nm、數值孔鏡NA=0.85,寫入線速度分別有4.92m/s與9.84m/s,符合藍光可寫錄光碟(Blue-ray Disc-RE)1倍速與2倍速記錄速度之規格。The thickness of the sputtered film was observed by atomic force microscopy (AFM) and Eta Optik; the dynamic analysis of the disc was measured using the PULSTEC ODU-1000 dynamic tester to measure the dynamic properties of the disc. The measured write power is between 5.5mW and 5.9mW, the read power is 0.35mW, the laser wavelength is λ=405nm, the numerical aperture mirror is NA=0.85, and the write line speed is 4.92m/s and 9.84m/ respectively. s, in line with the Blu-ray Disc Recording Disc (Blue-ray Disc-RE) 1x speed and 2x speed recording speed specifications.

當雷射寫入訊號時,記錄層受到雷射光脈衝加熱而溫度上升,當寫入功率過小時,此時記錄層(5)溫度太低,無法使薄膜產生反射率變化,故無法量測出抖變值與調變值;反之,當寫入功率太大時,抖動值反而隨著寫入功率增加而上升,可能是因為過高的雷射功率,使得記錄層(5)溫度太高,造成碟片膜層結構產生變形,使得抖動值上升,因此一般光碟片的寫入功率有一適當範圍。When the laser writes the signal, the recording layer is heated by the laser light pulse and the temperature rises. When the writing power is too small, the temperature of the recording layer (5) is too low, and the reflectance of the film cannot be changed, so that the measurement cannot be measured. The jitter value and the modulation value; conversely, when the write power is too large, the jitter value increases as the write power increases, possibly because the laser power is too high, so that the temperature of the recording layer (5) is too high. The distortion of the disc film structure is caused, so that the jitter value is increased, so that the writing power of the optical disc generally has an appropriate range.

第2圖為實施例一之碟片分別以4.80mW到6.33mW之寫入功率、寫擦功率比值(Pe/Pw)維持在0.65下,進行連續直接覆寫10次後的動態測試結果。由結果可看出,當寫入功率在5.5mW時可以得到最低的抖動值(記錄標記前端抖動值為5.39;記錄標記後端抖動值為6.24),顯示5.5mW為較佳的寫入功率,當寫入功率大於或小於5.5mW,抖動值將逐漸上升。當寫入功率偏離最佳寫入功率±10%時,抖動值仍維持在7.0以下,符合藍光可寫錄光碟之規格。Fig. 2 is a dynamic test result after the disc of the first embodiment has a write power of 4.80 mW to 6.33 mW and a write power ratio (Pe/Pw) of 0.65, respectively, and is continuously overwritten 10 times. It can be seen from the results that the lowest jitter value can be obtained when the write power is 5.5 mW (the recording mark front-end jitter value is 5.39; the recording mark back-end jitter value is 6.24), indicating that 5.5 mW is the better write power. When the write power is greater than or less than 5.5 mW, the jitter value will gradually increase. When the write power deviates from the optimal write power by ±10%, the jitter value remains below 7.0, which is in accordance with the specifications of the Blu-ray recordable disc.

雖然實施例一之碟片在連續10次直接覆寫後具有低的抖動值,進一步檢測其資料經長期讀取後的穩定性,結果如第3圖所示,係實施例一之碟片以寫入功率為5.5mW、抹除功率為3.6mW的條件(寫入功率與抹除功率的差值為Pw-Pe=1.9)寫入長度為2到8倍基準時脈T的記錄訊號後,訊號讀取次數與碟片抖動值(jitter)的動態測試結果,由第3圖結果可看出,當記錄媒體進行第一次記錄訊號後,記錄標記前端(jitter-L)與後端(jitter-T)的抖動值分別為5.39與6.24,但在室溫下連續以0.35mW的讀取功率讀出訊號後,碟片抖動值逐漸隨著讀取次數增加而上升。當連續讀取訊號760000次後,記錄標記前端(jitter-L)與後端(jitter-T)的抖動值分別上升為7.06與7.43,顯示記錄標記在經過多次低功率的讀取後明顯惡化,造成記錄之訊號無法長期穩定的保存。Although the disc of the first embodiment has a low jitter value after 10 consecutive overwrites, the stability of the data after long-term reading is further detected. As a result, as shown in FIG. 3, the disc of the first embodiment is The write power is 5.5mW and the erase power is 3.6mW (the difference between the write power and the erase power is Pw-Pe=1.9). After writing the recording signal with the length of 2 to 8 times the reference clock T, The dynamic test result of the number of signal readings and the jitter value of the jitter is shown in the result of Fig. 3. When the recording medium performs the first recording signal, the marker front end (jitter-L) and the back end (jitter) are recorded. The jitter values of -T) are 5.39 and 6.24, respectively. However, after reading the signal continuously at a reading power of 0.35 mW at room temperature, the jitter value of the disc gradually increases as the number of readings increases. When the signal is read continuously for 760000 times, the jitter values of the jitter front end (jitter-L) and the back end (jitter-T) rise to 7.06 and 7.43, respectively, and the display recording mark deteriorates significantly after repeated low-power reading. The signal that caused the recording cannot be stored stably for a long time.

為了改善記錄訊號惡化的情形,利用本發明之方法,藉由調整記錄層(5)厚度來控制記錄媒體對記錄雷射波長之吸收率,當記錄層(5)厚度被增加,搭配提高寫入功率與抹除功率的差值,便可以改善記錄訊號惡化的情形。In order to improve the deterioration of the recording signal, by using the method of the present invention, the absorption rate of the recording medium to the recording laser wavelength is controlled by adjusting the thickness of the recording layer (5), and when the thickness of the recording layer (5) is increased, the writing is improved. The difference between the power and the erase power can improve the deterioration of the recorded signal.

第4圖顯示採取實施例一之碟片膜層結構,但為避免反射訊號的影響,刪除其中的反射層(2)後,記錄層(5)厚度與記錄碟片吸收率之關係,由圖中可以看到,當記錄層(5)厚度為11nm時(實施例一),記錄媒體在藍光405nm波長之雷射照射下,吸收率約為52%(不包含反射層)。若記錄媒體在維持其他膜層結構不變的情形下,記錄層(5)厚度增為13nm時,記錄媒體在藍光405nm波長之雷射照射下,吸收率約為57%。當記錄層(5)厚度增為15nm時,記錄媒體在藍光405nm波長之雷射照射下,吸收率約為59%。當記錄層(5)厚度增為17nm時,記錄媒體在藍光405nm波長之雷射照射下,吸收率約為62%。當記錄層(5)厚度進一步增為20nm時,記錄媒體在藍光405nm波長之雷射照射下,吸收率約為68%。由上述結果可發現,碟片之吸收率隨著記錄層(5)厚度增加而上升,由於過低或過高的吸收率都會影響記錄層(5)薄膜對雷射能量的吸收情形,進而影響記錄層(5)的光學性質變化,吸收率過低或過高將會使碟片記錄靈敏度降低。因此在特定記錄條件下,記錄媒體必須具有一適當範圍的吸收率,而記錄層(5)厚度是影響記錄媒體吸收率的主要因素。Fig. 4 is a view showing the structure of the film layer of the first embodiment, but in order to avoid the influence of the reflection signal, the relationship between the thickness of the recording layer (5) and the absorption rate of the recording disk after the reflection layer (2) is deleted. It can be seen that when the recording layer (5) has a thickness of 11 nm (Example 1), the recording medium has an absorption rate of about 52% (excluding the reflective layer) under laser irradiation of a blue light of 405 nm. If the thickness of the recording layer (5) is increased to 13 nm while maintaining the structure of the other film layer, the recording medium has an absorption rate of about 57% under laser irradiation of a blue light of 405 nm. When the thickness of the recording layer (5) was increased to 15 nm, the recording medium had an absorption rate of about 59% under laser irradiation of a blue light of 405 nm. When the thickness of the recording layer (5) was increased to 17 nm, the recording medium had an absorption rate of about 62% under laser irradiation of a blue light of 405 nm. When the thickness of the recording layer (5) is further increased to 20 nm, the recording medium has an absorption rate of about 68% under laser irradiation of a blue light of 405 nm. From the above results, it can be found that the absorption rate of the disc increases as the thickness of the recording layer (5) increases, and the absorption rate of the recording layer (5) affects the laser energy due to the excessively low or too high absorption rate, thereby affecting The optical properties of the recording layer (5) vary, and the absorption rate is too low or too high, which will degrade the recording sensitivity of the disc. Therefore, under certain recording conditions, the recording medium must have an appropriate range of absorptivity, and the thickness of the recording layer (5) is a major factor affecting the absorptivity of the recording medium.

為證實不同記錄層(5)厚度與寫擦功率差值(Pw-Pe)的匹配對記錄訊號讀取穩定性的影響,採取改變記錄層(5)厚度與寫擦功率差值的應用如實施例二。In order to confirm the influence of the matching of the difference between the thickness of the recording layer (5) and the writing power difference (Pw-Pe) on the reading stability of the recording signal, an application for changing the difference between the thickness of the recording layer (5) and the power of the writing wipe is implemented. Example 2.

實施例二:Embodiment 2:

準備一刻有凹槽(grooves)與平地(land)之藍光可寫錄光碟(Blue-ray Disc-RE)基板,其軌距為74μm、厚度為1.1mm。利用磁控濺鍍的方式在基板上鍍製一層厚100nm之銀(Ag)反射層(2),接著在反射層(2)上鍍製厚8nm之氮化矽(SiN)於第一介面層(3),之後再於第一介面層(3)上鍍製厚8nm之硫化鋅-氧化矽(ZnS-SiO2 )於第一保護層(4),之後再於第一保護層(4)上分別形成厚13nm的記錄層(5),再於記錄層(5)上鍍製厚19nm之硫化鋅-氧化矽(ZnS-SiO2 )於第二保護層(6),以及在第二保護層(6)上鍍上厚30nm之氮化矽(SiN)於第二介面層(7)。最後,在第二保護層(6)上旋鍍上一層厚0.1mm之光透射膜,作為光透射層(8),完成實施例二之碟片。A blue-ray disc-RE substrate having grooves and land at a moment with a gauge of 74 μm and a thickness of 1.1 mm was prepared. A 100 nm thick silver (Ag) reflective layer (2) is deposited on the substrate by magnetron sputtering, and then 8 nm thick tantalum nitride (SiN) is deposited on the reflective layer (2) on the first interface layer. (3), then plating a thickness of 8 nm of zinc sulfide-yttria (ZnS-SiO 2 ) on the first protective layer (4) on the first interface layer (3), and then on the first protective layer (4) A recording layer (5) having a thickness of 13 nm is formed on the upper layer, and a 19 nm thick zinc sulfide-yttria (ZnS-SiO 2 ) is deposited on the recording layer (5) on the second protective layer (6), and in the second protection. The layer (6) is plated with 30 nm thick tantalum nitride (SiN) on the second interface layer (7). Finally, a light transmission film having a thickness of 0.1 mm was spin-plated on the second protective layer (6) to form a light transmitting layer (8), and the disk of the second embodiment was completed.

如第5圖所示,係實施例二之碟片以寫入功率為5.7mW、抹除功率為3.6mW的條件(寫入功率與抹除功率的差值為Pw-Pe=2.1)寫入長度為2到8倍基準時脈T的記錄訊號後,訊號讀取次數與碟片抖動值的動態測試結果,由第5圖結果可看出,當記錄媒體進行第一次記錄訊號後,記錄標記前端(jitter-L)與後端(jitter-T)的抖動值分別為5.26與6.10,但在室溫下連續以0.35mW的讀取功率讀出訊號後,碟片抖動值逐漸隨著讀取次數增加而上升。當連續讀取訊號1006000次後,記錄標記前端(jitter-L)與後端(jitter-T)的抖動值分別上升為6.13與6.71,顯示記錄標記在經過多次低功率的讀取後有惡化情形,但抖動值仍維持在低於7.0,顯示增加記錄層厚度並調整提高寫入功率與抹除功率之差值後,記錄標記經多次訊號讀取後惡化情形已有所改善。若持續以本發明之方法,再增加記錄層(5)厚度至對應吸收率,其應用情形如實施例三。As shown in FIG. 5, the disc of the second embodiment is written with a write power of 5.7 mW and an erase power of 3.6 mW (the difference between the write power and the erase power is Pw-Pe=2.1). After the recording signal of the reference clock T of 2 to 8 times, the dynamic test result of the number of signal readings and the jitter value of the disc, as can be seen from the result of FIG. 5, when the recording medium performs the first recording signal, the recording is performed. The jitter values of the marker front end (jitter-L) and the back end (jitter-T) are 5.26 and 6.10, respectively, but after reading the signal continuously at a reading power of 0.35 mW at room temperature, the disc jitter value gradually follows the reading. The number of fetches increases and increases. After continuously reading the signal for 1006,000 times, the jitter values of the jitter front end (jitter-L) and the back end (jitter-T) rise to 6.13 and 6.71, respectively, and the display recording mark deteriorates after multiple low-power readings. In the case, but the jitter value is still maintained below 7.0, indicating that the thickness of the recording layer is increased and the difference between the writing power and the erasing power is adjusted, the deterioration of the recording mark after reading the signal multiple times has been improved. If the thickness of the recording layer (5) is increased to the corresponding absorption rate by the method of the present invention, the application is as in the third embodiment.

實施例三:Embodiment 3:

準備一刻有凹槽(grooves)與平地(land)之藍光可寫錄光碟(Blue-ray Disc-RE)基板,其軌距為74μm、厚度為1.1mm。利用磁控濺鍍的方式在基板上鍍製一層厚100nm之銀(Ag)於反射層(2),接著在反射層(2)上鍍製厚8nm之氮化矽(SiN)於第一介面層(3),之後再於第一介面層(3)上鍍製厚8nm之硫化鋅-氧化矽(ZnS-SiO2 )於第一保護層(4),之後再於第一保護層(4)上形成厚15nm的記錄層(5),再於記錄層(5)上鍍製厚19nm之硫化鋅-氧化矽(ZnS-SiO2 )於第二保護層(6),以及在第二保護層(6)上鍍上厚30nm之氮化矽(SiN)於第二介面層(7)。最後,在第二保護層(6)上旋鍍上一層厚0.1mm之光透射膜,作為光透射層(8),完成實施例三之碟片。A blue-ray disc-RE substrate having grooves and land at a moment with a gauge of 74 μm and a thickness of 1.1 mm was prepared. A layer of 100 nm thick silver (Ag) is deposited on the substrate by magnetron sputtering on the reflective layer (2), and then a thickness of 8 nm of tantalum nitride (SiN) is deposited on the reflective layer (2) on the first interface. Layer (3), and then plating a thickness of 8 nm of zinc sulfide-yttria (ZnS-SiO 2 ) on the first protective layer (4) on the first interface layer (3), and then on the first protective layer (4) a recording layer (5) having a thickness of 15 nm is formed thereon, and a 19 nm thick zinc sulfide-yttria (ZnS-SiO 2 ) is deposited on the recording layer (5) on the second protective layer (6), and in the second protection. The layer (6) is plated with 30 nm thick tantalum nitride (SiN) on the second interface layer (7). Finally, a light transmission film having a thickness of 0.1 mm was spin-plated on the second protective layer (6) to form a light transmitting layer (8), and the disk of the third embodiment was completed.

如第6圖所示,係實施例三之碟片以寫入功率為5.9mW、抹除功率為3.4mW的條件(寫入功率與抹除功率的比值為Pw-Pe=2.5)寫入長度為2到8倍基準時脈T的記錄訊號後,訊號讀取次數與碟片抖動值的動態測試結果,由第六圖結果可看出,當記錄媒體進行第一次記錄訊號後,記錄標記前端(jitter-L)與後端(jitter-T)的抖動值分別為5.27與6.29,但在室溫下連續以0.35mW的讀取功率讀出訊號後,碟片抖動值逐漸隨著讀取次數增加而上升。當連續讀取訊號1061000次後,記錄標記前端(jitter-L)與後端(jitter-T)的抖動值分別為5.51與6.46,顯示記錄標記在經過多次低功率的讀取後抖動值只有很輕微地上升,抖動值仍維持在低於6.5,顯示增加記錄層厚度並調整提高寫入功率與抹除功率之差值後,記錄標記經多次訊號讀取後惡化情形已獲明顯改善,記錄訊號並不會因為多次以讀取功率讀出訊號後發生惡化變質的情形。As shown in FIG. 6, the disc of the third embodiment has a write power of 5.9 mW and an erase power of 3.4 mW (the ratio of the write power to the erase power is Pw-Pe=2.5). After 2 to 8 times the recording signal of the reference clock T, the dynamic test result of the number of signal readings and the jitter value of the disc, as can be seen from the result of the sixth figure, when the recording medium performs the first recording signal, the recording mark is recorded. The jitter values of the front end (jitter-L) and the back end (jitter-T) are 5.27 and 6.29, respectively, but after reading the signal continuously at a reading power of 0.35 mW at room temperature, the disc jitter value is gradually read. The number of times increases and rises. After continuously reading the signal 1061000 times, the jitter values of the jitter front end (jitter-L) and the back end (jitter-T) are 5.51 and 6.46, respectively, and the jitter value of the recording mark after reading the low-power reading is only Very slight rise, the jitter value is still maintained below 6.5, showing that increasing the thickness of the recording layer and adjusting the difference between the write power and the erase power, the deterioration of the recorded mark after a number of signal readings has been significantly improved. The recording signal does not deteriorate due to the deterioration of the signal after reading the power for a plurality of times.

若進一步再將記錄媒體之記錄層(5)厚度增加到20nm,則對應的吸收率為68%,在這個膜層結構下因為吸收率太高,導致記錄層(5)對雷射光敏感性改變,如此便無法在既有的膜層結構下順利地以雷射光寫入記錄標記。If the thickness of the recording layer (5) of the recording medium is further increased to 20 nm, the corresponding absorption rate is 68%, and the sensitivity of the recording layer (5) to the laser light is changed because the absorption rate is too high under this film layer structure. Therefore, it is impossible to smoothly write the recording mark with laser light under the existing film structure.

上述實施例一至實施例三中,係用以說明本發明之改善訊號讀取穩定性的方法,其藉由控制碟片吸收率為52%到59%,提高寫擦功率差值從1.9到2.5,可以在不改變或不需大幅改變記錄媒體膜層結構與寫擦策略下,改善光記錄媒體之訊號讀取穩定性。進一步的說明本發明之改善訊號讀取穩定性的方法,係利用調整寫入功率與抹除功率的差值來與碟片吸收率做適當的搭配,較大的碟片吸收率應搭配較大的寫入功率與抹除功率差值,如表一所示。在BD-1X的寫入速度下,當碟片吸收率為52%時,寫入功率與抹除功率的差值須於2.1到2.6之間的範圍;當碟片吸收率為57%時,寫入功率與抹除功率的差值須於2.2到2.7之間的範圍;當碟片吸收率為59%時,寫入功率與抹除功率的差值須於2.3到2.8之間的範圍;當碟片吸收率為62%時,寫入功率與抹除功率的差值須於2.5到3.0之間的範圍。In the above-mentioned Embodiments 1 to 3, the method for improving the signal reading stability of the present invention is described, which improves the write power difference from 1.9 to 2.5 by controlling the disc absorption rate from 52% to 59%. The signal reading stability of the optical recording medium can be improved without changing or changing the recording medium film structure and the writing erasing strategy. Further, the method for improving the signal reading stability of the present invention is to adjust the difference between the write power and the erase power to properly match the disc absorption rate, and the larger disc absorption rate should be matched with a larger one. The difference between the write power and the erase power is shown in Table 1. At the write speed of BD-1X, when the disc absorption rate is 52%, the difference between the write power and the erase power must be in the range between 2.1 and 2.6; when the disc absorption rate is 57%, The difference between the write power and the erase power shall be in the range between 2.2 and 2.7; when the disc absorbance is 59%, the difference between the write power and the erase power shall be in the range between 2.3 and 2.8; When the disc absorption rate is 62%, the difference between the write power and the erase power must be in the range between 2.5 and 3.0.

上述之實施例僅係用以詳細說明本發明之技術特徵及功效,並非用以限制本發明之專利權範圍,凡熟悉此類技藝之人仕根據上述說明,及依以下申請專利範圍所載之特徵及在功效上所作等效性之變換或修改,本質上未脫離本發明技藝精神之範疇者,均應包含在本發明之專利權範圍。The above-mentioned embodiments are only intended to illustrate the technical features and effects of the present invention, and are not intended to limit the scope of the patents of the present invention, and those skilled in the art are entitled to the above description and the scope of the following claims. Variations or modifications of the features and equivalents in terms of their efficiencies are intended to be included within the scope of the present invention.

(1)...基板(1). . . Substrate

(2)...反射層(2). . . Reflective layer

(3)...第一介面層(3). . . First interface layer

(4)...第一保護層(4). . . First protective layer

(5)...記錄層(5). . . Recording layer

(6)...第二保護層(6). . . Second protective layer

(7)...第二介面層(7). . . Second interface layer

(8)...光穿透層(8). . . Light penetrating layer

第1圖:係本發明之光記錄媒體的一種膜層結構剖面圖。Fig. 1 is a sectional view showing a structure of a film layer of an optical recording medium of the present invention.

第2圖:係本發明實施例一之碟片以4.80mW到6.33mW之寫入功率、寫擦功率比值(Pe/Pw)維持在0.65下,進行連續直接覆寫10次後的動態測試結果。Fig. 2 is a dynamic test result after the disc is continuously overwritten 10 times with a write power of 4.80 mW to 6.33 mW and a write power ratio (Pe/Pw) maintained at 0.65 for the disc of the first embodiment of the present invention. .

第3圖:係本發明實施例一之碟片以寫入功率為5.5mW、抹除功率為3.6mW的條件(寫入功率與抹除功率的差值為Pw-Pe=1.9)寫入長度為2到8倍基準時脈T的記錄訊號後,訊號讀取次數與碟片抖動值的動態測試結果。Figure 3 is a drawing of the disc of the first embodiment of the present invention with a write power of 5.5 mW and an erase power of 3.6 mW (the difference between the write power and the erase power is Pw-Pe = 1.9). After 2 to 8 times the reference signal of the reference clock T, the dynamic test result of the number of signal readings and the jitter value of the disc.

第4圖:為本發明採取實施例一之碟片膜層結構,並刪除其中反射層後,不同記錄層厚度下碟片吸收率的變化。Fig. 4 is a view showing the structure of the disc film layer of the first embodiment taken in the present invention, and the change in the absorptivity of the disc under the thickness of the different recording layer after the reflective layer is removed.

第5圖:係本發明實施例二之碟片以寫入功率為5.7mW、抹除功率為3.6mW的條件(寫入功率與抹除功率的差值為Pw-Pe=2.1)寫入長度為2到8倍基準時脈T的記錄訊號後,訊號讀取次數與碟片抖動值的動態測試結果。Figure 5: The disc of the second embodiment of the present invention has a write power of 5.7 mW and an erase power of 3.6 mW (the difference between the write power and the erase power is Pw-Pe = 2.1). After 2 to 8 times the reference signal of the reference clock T, the dynamic test result of the number of signal readings and the jitter value of the disc.

第6圖:係本發明實施例三之碟片以寫入功率為5.9mW、抹除功率為3.4mW的條件(寫入功率與抹除功率的比值為Pw-Pe=2.5)寫入長度為2到8倍基準時脈T的記錄訊號後,訊號讀取次數與碟片抖動值的動態測試結果。Figure 6 is a condition in which the disc of the third embodiment of the present invention has a write power of 5.9 mW and an erase power of 3.4 mW (the ratio of the write power to the erase power is Pw-Pe = 2.5). 2 to 8 times the reference signal of the reference clock T, the dynamic test result of the number of signal readings and the jitter value of the disc.

(1)...基板(1). . . Substrate

(2)...反射層(2). . . Reflective layer

(3)...第一介面層(3). . . First interface layer

(4)...第一保護層(4). . . First protective layer

(5)...記錄層(5). . . Recording layer

(6)...第二保護層(6). . . Second protective layer

(7)...第二介面層(7). . . Second interface layer

(8)...光穿透層(8). . . Light penetrating layer

Claims (16)

一種光記錄媒體,包含有基板、反射層、至少一保護層、記錄層、至少一介面層及光穿透層;其特徵在於:保護層可防止記錄層與反射層之間在加熱過程中發生熱能擴散,提供適當的絕熱效果,並具有光學補償之用;反射層與介面層接觸,可提供優良的光學反射效果以及導熱功能;介面層用以控制記錄媒體整體膜層在寫入訊號時的適當散熱性、整體吸收率與光學補償,且該光記錄媒體不包含反射層之光吸收率介於52%到70%時,對應之寫入功率與抹除功率的差值(Pw-Pe)介於2.1到3.0之間者。 An optical recording medium comprising a substrate, a reflective layer, at least one protective layer, a recording layer, at least one interface layer and a light transmissive layer; wherein the protective layer prevents the recording layer and the reflective layer from occurring during heating Thermal energy diffusion provides proper thermal insulation and optical compensation; the reflective layer is in contact with the interface layer to provide excellent optical reflection and thermal conductivity; and the interface layer is used to control the overall recording layer of the recording medium when writing signals. Appropriate heat dissipation, overall absorption rate and optical compensation, and the optical recording medium does not include the reflective layer, the light absorption rate is between 52% and 70%, corresponding to the difference between the write power and the erase power (Pw-Pe) Between 2.1 and 3.0. 如申請專利範圍第1項所述之光記錄媒體,其可由投射於基板相反側之雷射光予以照射,進行資料讀寫;配合膜層結構的調整,也可利用與基板側入射之雷射光進行資料讀寫。 The optical recording medium according to claim 1, wherein the optical recording medium can be irradiated by laser light projected on the opposite side of the substrate to perform reading and writing of the data; and the adjustment of the structure of the film layer can also be performed by using the laser light incident on the substrate side. Data reading and writing. 如申請專利範圍第1項所述之光記錄媒體,其中記錄層之厚度為3nm到30nm之間者。 The optical recording medium according to claim 1, wherein the recording layer has a thickness of between 3 nm and 30 nm. 如申請專利範圍第1項所述之光記錄媒體,其中記錄層材料含有至少選自鍺(Ge)、銦(In)、銻(Sb)、錫(Sn)、鎵(Ga)及碲(Te)之一種者。 The optical recording medium according to claim 1, wherein the recording layer material contains at least selected from the group consisting of germanium (Ge), indium (In), antimony (Sb), tin (Sn), gallium (Ga), and antimony (Te). One of them. 如申請專利範圍第1項所述之光記錄媒體,其中,該第一保護層與第二保護層之厚度介於1nm到200nm之間,其材質可為硫化鋅-氧化矽(ZnS-SiO2 )、氮化矽(SiN或Si3 N4 )、氮化鍺(GeN)、碳化矽(SiC)、 二氧化矽(SiO2 )、三氧化二鋁(Al2 O3 )、二氧化鈦(TiO2 )等介電材質其中之一者,或是由前述介電材質中的兩種或兩種以上所組成者。The optical recording medium of claim 1, wherein the first protective layer and the second protective layer have a thickness of between 1 nm and 200 nm, and the material thereof may be zinc sulfide-yttria (ZnS-SiO 2 ). ), tantalum nitride (SiN or Si 3 N 4 ), tantalum nitride (GeN), tantalum carbide (SiC), cerium oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), titanium dioxide (TiO 2 ) One of the dielectric materials, or one or more of the foregoing dielectric materials. 如申請專利範圍第1項所述之光記錄媒體,其中,該反射層材質可為金(Au)、銀(Ag)、鉬(Mo)、鋁(Al)、鈦(Ti)、鉭(Ta)等元素其中之一者,或以其為主成分之合金者。 The optical recording medium according to claim 1, wherein the reflective layer material is gold (Au), silver (Ag), molybdenum (Mo), aluminum (Al), titanium (Ti), tantalum (Ta). One of the elements, or an alloy based on it. 如申請專利範圍第1項所述之光記錄媒體,其中,該光穿透層為光硬化樹脂者。 The optical recording medium according to claim 1, wherein the light penetrating layer is a photohardenable resin. 如申請專利範圍第1項所述之光記錄媒體,其中,該基板可為矽基板或具光學透明特性的材料,且能提供適當的機械強度,包括聚碳酸脂樹脂(polycarbonate resin)、聚甲基丙烯酸甲脂(polymethyl methacrylate)、聚苯乙烯樹脂(polystyrene resin)、聚乙烯樹脂(polyethylene resin)、聚丙烯樹脂(polypropylene resin)等。 The optical recording medium according to claim 1, wherein the substrate can be a ruthenium substrate or a material having optical transparency, and can provide appropriate mechanical strength, including polycarbonate resin, polymethylation. Polymethyl methacrylate, polystyrene resin, polyethylene resin, polypropylene resin, and the like. 一種光記錄媒體,包含有基板、反射層、保護層、記錄層及光穿透層;其特徵在於:保護層可防止記錄層與反射層之間在加熱過程中發熱能生擴散,提供適當的絕熱效果,以及具有光學補償之用;反射層與介面層接觸,可提供優良的光學反射效果以及導熱功能;其中,反射層位於基板上方,保護層位於反射層上方、記錄層位於保護層上方、光穿透層位於記錄層上方,且該光記錄媒體不包含反射層之光吸收率介於52%到70%時,對應之寫入功率與抹除功率的差值(Pw-Pe) 介於2.1到3.0之間者。 An optical recording medium comprising a substrate, a reflective layer, a protective layer, a recording layer and a light transmissive layer; wherein the protective layer prevents heat generation between the recording layer and the reflective layer during heating, and provides appropriate heat insulation The effect is as well as optical compensation; the reflective layer is in contact with the interface layer to provide excellent optical reflection and thermal conductivity; wherein the reflective layer is above the substrate, the protective layer is above the reflective layer, the recording layer is above the protective layer, and the light is When the penetrating layer is located above the recording layer, and the optical recording medium does not include the reflective layer, the light absorption rate is between 52% and 70%, corresponding to the difference between the writing power and the erasing power (Pw-Pe) Between 2.1 and 3.0. 如申請專利範圍第9項所述之光記錄媒體,其可由投射於基板相反側之雷射光予以照射,進行資料讀寫;配合膜層結構的調整,也可利用與基板側入射之雷射光進行資料讀寫。 The optical recording medium of claim 9, which can be irradiated by laser light projected on the opposite side of the substrate to perform reading and writing of data; and the adjustment of the structure of the film layer can also be performed by using laser light incident on the substrate side. Data reading and writing. 如申請專利範圍第9項所述之光記錄媒體,其中記錄層之厚度為3nm到30nm之間者。 The optical recording medium according to claim 9, wherein the recording layer has a thickness of between 3 nm and 30 nm. 如申請專利範圍第9項所述之光記錄媒體,其中記錄層材料含有至少選自鍺(Ge)、銦(In)、銻(Sb)、錫(Sn)、鎵(Ga)及碲(Te)之一種者。 The optical recording medium of claim 9, wherein the recording layer material contains at least selected from the group consisting of germanium (Ge), indium (In), antimony (Sb), tin (Sn), gallium (Ga), and antimony (Te). One of them. 如申請專利範圍第9項所述之光記錄媒體,其中,該保護層之厚度介於1nm到200nm之間,其材質可為硫化鋅-氧化矽(ZnS-SiO2 )、氮化矽(SiN或Si3 N4 )、氮化鍺(GeN)、碳化矽(SiC)、二氧化矽(SiO2 )、三氧化二鋁(Al2 O3 )、二氧化鈦(TiO2 )等介電材質其中之一者,或是由前述介電材質中的兩種或兩種以上所組成者。The optical recording medium according to claim 9, wherein the protective layer has a thickness of between 1 nm and 200 nm, and the material thereof may be zinc sulfide-yttria (ZnS-SiO 2 ) or tantalum nitride (SiN). Or a dielectric material such as Si 3 N 4 ), tantalum nitride (GeN), tantalum carbide (SiC), cerium oxide (SiO 2 ), aluminum oxide (Al 2 O 3 ), or titanium dioxide (TiO 2 ). One of them is composed of two or more of the aforementioned dielectric materials. 如申請專利範圍第9項所述之光記錄媒體,其中,該反射層材質可為金(Au)、銀(Ag)、鉬(Mo)、鋁(Al)、鈦(Ti)、鉭(Ta)等元素其中之一者,或以其為主成分之合金者。 The optical recording medium according to claim 9, wherein the reflective layer material is gold (Au), silver (Ag), molybdenum (Mo), aluminum (Al), titanium (Ti), tantalum (Ta). One of the elements, or an alloy based on it. 如申請專利範圍第9項所述之光記錄媒體,其中,該光穿透層為光硬化樹脂者。 The optical recording medium according to claim 9, wherein the light penetrating layer is a photohardenable resin. 如申請專利範圍第9項所述之光記錄媒體,其中,該基板可為矽基板或具光學透明特性的材料,且能提供適當的機械強度,包括聚碳酸脂樹脂(polycarbonate resin)、聚甲基丙烯酸甲脂(polymethyl methacrylate)、聚苯乙烯樹脂(polystyrene resin)、聚乙烯樹脂(polyethylene resin)、聚丙烯樹脂(polypropylene resin)等。The optical recording medium of claim 9, wherein the substrate can be a ruthenium substrate or a material having optically transparent properties, and can provide appropriate mechanical strength, including polycarbonate resin, polymethylation Polymethyl methacrylate, polystyrene resin, polyethylene resin, polypropylene resin, and the like.
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