TWI385850B - Combined type proton exchange device - Google Patents

Combined type proton exchange device Download PDF

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TWI385850B
TWI385850B TW099101539A TW99101539A TWI385850B TW I385850 B TWI385850 B TW I385850B TW 099101539 A TW099101539 A TW 099101539A TW 99101539 A TW99101539 A TW 99101539A TW I385850 B TWI385850 B TW I385850B
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switch
hydrogen
proton exchange
line
fuel cell
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TW099101539A
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Chinese (zh)
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TW201126803A (en
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Bang Jia Chen
Yao Ting Zhang
kuan yu Zhang
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Univ Kao Yuan
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

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  • Electrolytic Production Of Non-Metals, Compounds, Apparatuses Therefor (AREA)

Description

複合式質子交換裝置Composite proton exchange device

本發明係關於一種複合式質子交換裝置,特別是指一種將製氫及發電複合使用且透過開關切換的的複合式質子交換裝置。The present invention relates to a composite proton exchange device, and more particularly to a composite proton exchange device that combines hydrogen production and power generation and switches through a switch.

燃料電池於發電過程不會有二氧化碳的產生,燃料電池生成物只有水與熱並不造成污染;燃料電池直接將燃料中的化學能轉換成電能,藉此大大提升能量轉換效率;燃料電池發電發電時,不需其它機件配合,因此沒有噪音的產生;一般電池是將能量儲存於電池本體中,用完隨即捨棄或充電重複使用,燃料電池是由燃料透過化學能提供能源,因此只要持續不斷地供給燃料,燃料電池便可以不停地發電。There is no carbon dioxide generation in the fuel cell during the power generation process. The fuel cell produces only water and heat and does not cause pollution. The fuel cell directly converts the chemical energy in the fuel into electrical energy, thereby greatly improving the energy conversion efficiency; When there is no need for other parts to cooperate, there is no noise. Generally, the battery stores energy in the battery body. When it is used up, it is discarded or recharged. The fuel cell is powered by fuel through chemical energy, so as long as it continues By supplying fuel to the ground, the fuel cell can generate electricity continuously.

目前常見的燃料電池發電系統10係包含一接收電及水產生氫氣的電解器11及一與電解器11連接的燃料電池12,該燃料電池12接收電解器11產生的氫氣進而產生電,該電解器11透過一氫氣瓶13儲存氫氣,使該燃料電池12穩定的從該氫氣瓶13獲得氫氣;前述燃料電池發電系統10的電解器11及燃料電池12用久一定會有損壞的時候,一旦其中一台必須維修剩下的那一台也就無法正常運作。The conventional fuel cell power generation system 10 includes an electrolyzer 11 that receives electricity and water to generate hydrogen, and a fuel cell 12 that is connected to the electrolyzer 11. The fuel cell 12 receives hydrogen generated by the electrolyzer 11 to generate electricity. The device 11 stores hydrogen gas through a hydrogen cylinder 13 to stably obtain hydrogen from the hydrogen cylinder 13; when the electrolyzer 11 and the fuel cell 12 of the fuel cell power generation system 10 are permanently damaged, once The one that must be repaired will not function properly.

本發明係一種複合式質子交換裝置,其目的在於利用複合製氫及發電的效用且提供開關進行切換選擇。The present invention is a composite proton exchange device whose purpose is to utilize the utility of composite hydrogen production and power generation and to provide switching for switching selection.

為達成上述目的,本發明複合式質子交換裝置,包含:二質子交換膜燃料電池,各具有一陽極及一陰極,該陽極具有一電入口、一水入口及一氫入口,該陰極具有一電出口及一氫出口;該陽極的電入口連接一具有開關的第一線路用於導入電,且透過該開關啟閉;該陽極的水入口連接一具有開關的第一管路用於導入水,且透過該開關啟閉;該陽極的氫入口連接一具有開關的第二管路用於導入氫,且透過該開關啟閉;該陰極的的電出口連接一具有開關的第二線路用於傳送該質子交換膜燃料電池產生的電,且透過該開關啟閉;該陰極的的氫出口連接一具有開關的第三管路用於傳送該質子交換膜燃料電池產生的氫,且透過該開關啟閉,該二質子交換膜燃料電池的第三管路與第二管路分別連接一氫氣瓶用於儲存氫氣。To achieve the above object, the composite proton exchange device of the present invention comprises: a proton exchange membrane fuel cell each having an anode and a cathode, the anode having an electrical inlet, a water inlet and a hydrogen inlet, the cathode having an electricity An outlet and a hydrogen outlet; the electrical inlet of the anode is connected to a first line having a switch for introducing electricity, and is opened and closed by the switch; the water inlet of the anode is connected to a first line having a switch for introducing water, And opening and closing through the switch; the hydrogen inlet of the anode is connected to a second pipeline having a switch for introducing hydrogen, and is opened and closed through the switch; the electrical outlet of the cathode is connected to a second line having a switch for transmitting The electricity generated by the proton exchange membrane fuel cell is opened and closed by the switch; the hydrogen outlet of the cathode is connected to a third line having a switch for transmitting hydrogen generated by the proton exchange membrane fuel cell, and is The third pipeline and the second pipeline of the two-proton exchange membrane fuel cell are respectively connected with a hydrogen cylinder for storing hydrogen.

藉由前述進一步分析將可獲得下述功效:本發明透過開關的切換,使該質子交換膜燃料電池不僅能製造氫氣又能產生電力,且將二質子交換膜燃料電池複合在一起使用,讓使用者視需求選擇性切換使用。According to the foregoing further analysis, the following effects can be obtained: the switching of the switch enables the proton exchange membrane fuel cell to not only produce hydrogen but also generate electricity, and the two proton exchange membrane fuel cells are used together for use. The switch is selectively switched depending on the demand.

有關本發明為達成上述目的,所採用之技術、手段及其他功效,茲列舉實施例並配合圖式詳細說明如後,相信本發明之目的、特徵及其他優點,當可由之得一深入而具體之瞭解。The present invention has been described with reference to the embodiments and the detailed description of the present invention. The objects, features and other advantages of the present invention are believed to be Understand.

本發明實施例請參閱第2-5圖所示:本發明複合式質子交換裝置20(請參閱第2圖所示),包含:二質子交換膜燃料電池(Proton Exchange Membrane Fuel Cell,PEMFC)30,該質子交換膜燃料電池30具有一陽極31及一陰極32,該陽極31具有一電入口311、一水入口312及一氫入口313,該陰極32具有一電出口321及一氫出口322。For the embodiment of the present invention, please refer to FIG. 2-5. The composite proton exchange device 20 of the present invention (see FIG. 2) includes: Proton Exchange Membrane Fuel Cell (PEMFC) 30. The proton exchange membrane fuel cell 30 has an anode 31 and a cathode 32. The anode 31 has an electrical inlet 311, a water inlet 312, and a hydrogen inlet 313. The cathode 32 has an electrical outlet 321 and a hydrogen outlet 322.

該陽極31的電入口311連接一具有開關41的第一線路40,該第一線路40導入電傳送至該陽極31的電入口311,且該開關41用於啟閉電的傳輸,該第一線路40傳送的電是來自太陽能板或電力公司。The electrical inlet 311 of the anode 31 is connected to a first line 40 having a switch 41, the first line 40 is electrically connected to the electrical inlet 311 of the anode 31, and the switch 41 is used for the transmission of the opening and closing electricity, the first The electricity delivered by line 40 is from a solar panel or power company.

該陽極31的水入口312連接一具有開關51的第一管路50,該第一管路50導入水傳送至該陽極31的水入口312,且該開關51用於啟閉水的傳輸,該第一管路50輸送的水是來自於自來水公司,該第一管路50另連接一閥52用於限制水的流量。The water inlet 312 of the anode 31 is connected to a first line 50 having a switch 51 for introducing water to the water inlet 312 of the anode 31, and the switch 51 is used for opening and closing the transfer of water. The water delivered by the first line 50 is from a water company, and the first line 50 is further connected to a valve 52 for restricting the flow of water.

該陽極31的氫入口313連接一具有開關61的第二管路60,該第二管路60導入氫傳送至該陽極31的氫入口313,且該開關61用於啟閉氫的傳輸,該第二管路60(圖式並未予以繪出)另連接一閥用於限制水的流量。The hydrogen inlet 313 of the anode 31 is connected to a second line 60 having a switch 61 for introducing hydrogen to the hydrogen inlet 313 of the anode 31, and the switch 61 is for opening and closing the transfer of hydrogen. A second line 60 (not shown) is additionally connected to a valve for limiting the flow of water.

該陰極32的的電出口321連接一具有開關71的第二線路70,該第二線路70用於傳送該質子交換膜燃料電池30產生的電,且該開關71用於啟閉電的傳輸。The electrical outlet 321 of the cathode 32 is connected to a second line 70 having a switch 71 for transmitting electricity generated by the proton exchange membrane fuel cell 30, and the switch 71 is used for the opening and closing of electrical transmission.

該陰極32的的氫出口322連接一具有開關81的第三管路80,該第三管路80用於傳送該質子交換膜燃料電池30產生的氫,且該開關71用於啟閉電的傳輸,該第三管路80與該第二管路60連接,且該第三管路80與該第二管路60連接一氫氣瓶90用於儲存氫氣,使該質子交換膜燃料電池30能自行產生氫提供自己用,前提是提供該質子交換膜燃料電池30產生氫所需的電及水。The hydrogen outlet 322 of the cathode 32 is connected to a third line 80 having a switch 81 for transferring hydrogen generated by the proton exchange membrane fuel cell 30, and the switch 71 is used for opening and closing electricity. The third line 80 is connected to the second line 60, and the third line 80 and the second line 60 are connected to a hydrogen cylinder 90 for storing hydrogen to enable the proton exchange membrane fuel cell 30. Self-generating hydrogen is provided for its own use, provided that the proton exchange membrane fuel cell 30 supplies the electricity and water required to produce hydrogen.

本發明採用二台質子交換膜燃料電池20該各質子交換膜燃料電池20的第二管路60彼此作管路連接用於對該質子交換膜燃料電池20導入氫用,以及第三管路80彼此作管路連接用於從該質子交換膜燃料電池20導出氫用。The present invention employs two proton exchange membrane fuel cells 20. The second conduits 60 of the proton exchange membrane fuel cells 20 are connected to each other for introducing hydrogen to the proton exchange membrane fuel cell 20, and the third conduit 80. A pipe connection is made to each other for deriving hydrogen from the proton exchange membrane fuel cell 20.

該二質子交換膜燃料電池20透過開關的切換產生三種模式,如下說明:第一模式(請參閱第3圖所示):其一質子交換膜燃料電池20的第一線路40的開關41開啟導通輸入電、第一管路50的開關51開啟導通輸入水及第三管路80的開關81開啟導通輸出氫;另一質子交換膜燃料電池20的第二管路60的開關61開啟導通輸入氫及第二線路70的開關71開啟導通產出電;藉此該二質子交換膜燃料電池20分別進行製氫及發電。The two proton exchange membrane fuel cell 20 is switched by a switch to generate three modes, as explained below: the first mode (see FIG. 3): the switch 41 of the first line 40 of the proton exchange membrane fuel cell 20 is turned on. The input switch, the switch 51 of the first line 50 turns on the input water, and the switch 81 of the third line 80 turns on the output hydrogen; the switch 61 of the second line 60 of the other proton exchange membrane fuel cell 20 turns on the input hydrogen. And the switch 71 of the second line 70 is turned on to generate electricity; whereby the two-proton exchange membrane fuel cell 20 performs hydrogen production and power generation, respectively.

第二模式(請參閱第4圖所示):該二質子交換膜燃料電池20的第一線路40的開關41開啟導通輸入電、第一管路50的開關51開啟導通輸入水及第三管路80的開關81開啟導通輸出氫;藉此該二質子交換膜燃料電池20同時進行製氫增加供氫量。The second mode (refer to FIG. 4): the switch 41 of the first line 40 of the two-proton exchange membrane fuel cell 20 is turned on to turn on the input power, the switch 51 of the first line 50 is turned on to turn on the input water, and the third tube The switch 81 of the path 80 turns on the conduction of hydrogen; whereby the two-proton exchange membrane fuel cell 20 simultaneously performs hydrogen production to increase the amount of hydrogen supplied.

第三模式(請參閱第5圖所示):該二質子交換膜燃料電池20的第二管路60的開關61開啟導通輸入氫及第二線路70的開關71開啟導通產出電;藉此該二質子交換膜燃料電池20同時進行發電增加供電量。The third mode (refer to FIG. 5): the switch 61 of the second line 60 of the two-proton exchange membrane fuel cell 20 turns on the switch 71 for turning on the input hydrogen and the second line 70 to turn on and output electricity; The two-proton exchange membrane fuel cell 20 simultaneously generates electricity to increase the amount of power supplied.

該二質子交換膜燃料電池20複合製氫及發電的效用且透過開關切換,進而提供使用者視需求任意切換。The two-proton exchange membrane fuel cell 20 combines the effects of hydrogen production and power generation and is switched by a switch, thereby providing the user with arbitrary switching as needed.

10...燃料電池發電系統10. . . Fuel cell power generation system

11...電解器11. . . Electrolyzer

12...燃料電池12. . . The fuel cell

13...氫氣瓶13. . . Hydrogen bottle

20...複合式質子交換裝置20. . . Composite proton exchange device

30...質子交換膜燃料電池30. . . Proton exchange membrane fuel cell

31...陽極31. . . anode

311...電入口311. . . Electric entrance

312...水入口312. . . Water inlet

313...氫入口313. . . Hydrogen inlet

32...陰極32. . . cathode

321...電出口321. . . Electric outlet

322...氫出口322. . . Hydrogen outlet

40...第一線路40. . . First line

41...開關41. . . switch

50...第一管路50. . . First line

51...開關51. . . switch

52...閥52. . . valve

60...第二管路60. . . Second pipeline

61...開關61. . . switch

70...第二線路70. . . Second line

71...開關71. . . switch

80...第三管路80. . . Third pipeline

81...開關81. . . switch

90...氫氣瓶90. . . Hydrogen bottle

第1圖 習用燃料電池發電系統之示意圖。Figure 1 Schematic diagram of a conventional fuel cell power generation system.

第2圖 本發明複合式質子交換裝置之示意圖。Figure 2 is a schematic view of a composite proton exchange apparatus of the present invention.

第3圖 本發明複合式質子交換裝置之動作示意圖一。Fig. 3 is a schematic view showing the operation of the composite proton exchange device of the present invention.

第4圖 本發明複合式質子交換裝置之動作示意圖二。Fig. 4 is a schematic view showing the operation of the composite proton exchange device of the present invention.

第5圖 本發明複合式質子交換裝置之動作示意圖三。Fig. 5 is a schematic view showing the operation of the composite proton exchange device of the present invention.

20...複合式質子交換裝置20. . . Composite proton exchange device

30...質子交換膜燃料電池30. . . Proton exchange membrane fuel cell

31...陽極31. . . anode

311...電入口311. . . Electric entrance

312...水入口312. . . Water inlet

313...氫入口313. . . Hydrogen inlet

32...陰極32. . . cathode

321...電出口321. . . Electric outlet

322...氫出口322. . . Hydrogen outlet

40...第一線路40. . . First line

41...開關41. . . switch

50...第一管路50. . . First line

51...開關51. . . switch

52...閥52. . . valve

60...第二管路60. . . Second pipeline

61...開關61. . . switch

70...第二線路70. . . Second line

71...開關71. . . switch

80...第三管路80. . . Third pipeline

81...開關81. . . switch

90...氫氣瓶90. . . Hydrogen bottle

Claims (4)

一種複合式質子交換裝置,包含:二質子交換膜燃料電池,各具有一陽極及一陰極,該陽極具有一電入口、一水入口及一氫入口,該陰極具有一電出口及一氫出口;該陽極的電入口連接一具有開關的第一線路,該第一線路導入電傳送至該陽極的電入口,且該開關用於啟閉電的傳輸;該陽極的水入口連接一具有開關的第一管路,該第一管路導入水傳送至該陽極的水入口,且該開關用於啟閉水的傳輸;該陽極的氫入口連接一具有開關的第二管路,該第二管路導入氫傳送至該陽極的氫入口,且該開關用於啟閉氫的傳輸;該陰極的的電出口連接一具有開關的第二線路,該第二線路用於傳送該質子交換膜燃料電池產生的電,且該開關用於啟閉電的傳輸;該陰極的的氫出口連接一具有開關的第三管路,該第三管路用於傳送該質子交換膜燃料電池產生的氫,且該開關用於啟閉電的傳輸,該二質子交換膜燃料電池的第三管路與第二管路分別連接一氫氣瓶用於儲存氫氣。A composite proton exchange device comprising: a two-proton exchange membrane fuel cell, each having an anode and a cathode, the anode having an electrical inlet, a water inlet and a hydrogen inlet, the cathode having an electrical outlet and a hydrogen outlet; The electrical inlet of the anode is connected to a first line having a switch, the first line is electrically connected to an electrical inlet of the anode, and the switch is used for opening and closing electrical transmission; the water inlet of the anode is connected to a switch having a switch a pipeline, the first pipeline introduces water to the water inlet of the anode, and the switch is used for opening and closing water transfer; the hydrogen inlet of the anode is connected to a second pipeline having a switch, the second pipeline Introducing hydrogen to the hydrogen inlet of the anode, and the switch is for opening and closing the transfer of hydrogen; the electrical outlet of the cathode is connected to a second line having a switch for transmitting the proton exchange membrane fuel cell And the switch is used for the transmission of the opening and closing electricity; the hydrogen outlet of the cathode is connected to a third line having a switch for transferring hydrogen generated by the proton exchange membrane fuel cell, and For opening and closing off the transmission power, the two proton exchange membrane fuel cell of the third line and the second line are connected to a hydrogen tank for storing hydrogen. 如申請專利範圍第1項所述複合式質子交換裝置,其中,其一質子交換膜燃料電池的該第一線路的開關開啟導通輸入電、該第一管路的開關開啟導通輸入水及該第三管路的開關開啟導通輸出氫;另一質子交換膜燃料電池的該第二管路的開關開啟導通輸入氫及該第二線路的開關開啟導通產出電。 The composite proton exchange device of claim 1, wherein the switch of the first line of the proton exchange membrane fuel cell is turned on, the input of the switch of the first line is turned on, and the first The switch of the three pipelines is turned on to output hydrogen; the switch of the second pipeline of the other proton exchange membrane fuel cell is turned on to turn on the input hydrogen and the switch of the second line is turned on to output electricity. 如申請專利範圍第1項所述複合式質子交換裝置,其中,該二質子交換膜燃料電池的第一線路的開關開啟導通輸入電、第一管路的開關開啟導通輸入水及第三管路的開關開啟導通輸出氫。 The composite proton exchange device according to claim 1, wherein the switch of the first line of the two-proton exchange membrane fuel cell is turned on to turn on the input power, the switch of the first pipeline is turned on to turn on the input water, and the third line is The switch turns on and turns on the output hydrogen. 如申請專利範圍第1項所述複合式質子交換裝置,其中,該二質子交換膜燃料電池的第二管路的開關開啟導通輸入氫及第二線路的開關開啟導通產出電。 The composite proton exchange device according to claim 1, wherein the switch of the second line of the two-proton exchange membrane fuel cell is turned on to turn on the input hydrogen and the switch of the second line is turned on to output electricity.
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Citations (8)

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