TWI362721B - Dynamic random access memory and fabricating method thereof - Google Patents

Dynamic random access memory and fabricating method thereof Download PDF

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TWI362721B
TWI362721B TW96122308A TW96122308A TWI362721B TW I362721 B TWI362721 B TW I362721B TW 96122308 A TW96122308 A TW 96122308A TW 96122308 A TW96122308 A TW 96122308A TW I362721 B TWI362721 B TW I362721B
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layer
access memory
random access
substrate
dynamic random
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TW96122308A
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Chinese (zh)
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TW200901380A (en
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Kuo Chung Chen
Jen Jui Huang
Hong Wen Lee
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Nanya Technology Corp
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1362721 2005-0108 22658twf.doc/n 九、發明說明: * 【發明所屬之技術領域】 * 本發明是有關於一種記憶體元件及其製作方法,且特 • 別是有關於一種動態隨機存取記憶體(dynamic random access memory,DRAM)及其製作方法。 V 【先前技術】 • 隨著現今電腦微處理器的功能愈來愈強大,軟體所進 • 行的程式與運算也愈來愈複雜,因此記憶體的製作技術已 成為半導體產業中重要的技術之—。一般來說,記憶體可 依其儲存資料的型態而分為揮發性記憶體與非揮發性記憶 體。而動態隨機存取記憶體即屬於一種揮發性記憶體,^ 是由多個記憶胞(memory cell)所組成。每一個記憶胞主要 是由一個電晶體與一個電容器所構成’且每一個記憶胞之 間是藉由字元線(word line,WL)與位元線⑽丨B 此電性連接。 •圖1為習知一種動態隨機存取記憶體之剖面示意圖。 請參照圖1,習知的動態隨機存取記憶體包括基底1〇〇、電 • 谷益110以及橫向配置的電晶體120。基底100具有溝渠 102,而電容器11〇位於溝渠1〇2内。電容器11〇包括下電 • 極104、電容介電層腸以及上電極108。電晶體12〇配置 於基底100上。電晶體120包括閘極124、>及極區122b以 ^ 及源極區122a。汲極區122b以及源極區122a配置於閘極 I24二側之基底10〇中。電晶體120之汲極區122b透過形 成於基底100内的埋藏式導電帶13〇與電容器no之上電 6 上*362721 2005-0108 22658twf.doc/n 極108電性連接’源極區122a連接至配置於基底1〇〇上之 • 位元線接觸窗140。 .習知之動態隨機存取記憶體是將電容器110、橫向配 • 置的電晶體120以及位元線接觸窗140分別對應於基底 v 1〇〇表面上的不同位置,以水平的方式配置。也就是說, 電容益110、電晶體120和位元線接觸窗140分別會佔有 晶片表面上的部分面積,因此在每單位面積内所能配置的 > 汜憶體數目會受到限制。縱使藉由技術不斷地精進而使得 元件的線寬能夠逐漸縮小,但是受限於上述之配置方式, 元件積集度的提升仍被侷限。 因此,如何在有限的空間中製作出更多的元件且不影 響到元件的尺寸,以提高元件積集度與晶圓的使用率是目 前亟需解決的課題。 【發明内容】 本發明提供一種動態隨機存取記憶體,其記憶胞具有 一 同軸垂直配置的元件,能夠增加胞密度(ceU density)並提升 元件效能。 • 本發明提供一種動態隨機存取記憶體的製作方法,可 以改善每單位面積内所能製作出的記憶胞的數量,因此能 • 達到提高元件積集度的目的 本發明提出一種動態隨機存取記憶體,其包括半導體 基底、電谷益以及電晶體。半導體基底上配置有多個柱狀 釔構。各柱狀結構由半導體基底起由下而上包括絕緣層、 半導體層與半導體突出部。電容器包括下電極、上電極與 7 2〇〇5-〇i〇g 22658twf.d〇c/n ίΐΐΐί °下電極配置於柱狀域之_間隙,且連接 置於==:=::。電容介』 與第二摻雜區。閉極配置於半導體;出:辟第-摻雜區 區配置於閘極下方之半導體突出部中二以-摻雜 二摻雜區配置於閘極上方之半導體突出部=上電極°第 例如;=體=:上述之半導體突出部的尺寸 ^本發明之一實施例中,動態隨機存取記情 接觸^配置於電晶體之上方,且與第二摻雜區轉接。 在本發明之一實施例中,上述之接觸窗的材料例如是 在本發明之一實施例中,上述之閘極例如是 體突出部。 、兀T守 在本發明之一實施例中,上述之電晶體更包括閘極介 電層,配置於閘極與半導體突出部之間。 在本發明之一實施例中,動態隨機存取記憶體更包括 間隙壁,配置於半導體突出部側壁,且位於閘極之上、下 兩側。 在本發明之一實施例中,上述之電容介電層例如是複 合介電層。 在本發明之一實施例中’上述之複合介電層例如是氧 化物/氮化物層或氧化物/氮化物/氧化物(ΟΝΟ)層。 在本發明之一實施例中,上述之下電極的材料例如是 2005-0108 22658twf.doc/n 摻雜多晶矽。 在本發明之一實施例中,上述之上電極的材料例如是 換雜石夕。 鎢 在本發明之一實施例中 上述之閘極的材料例如是 本發明再提出一種動態隨機存取記憶體的製作方 法,此方法是先提供其中已形成有絕緣層之基底。然後, 移除部分基底與絕緣層,以於基底中形成多個溝渠,並暴 露出絕緣層下方之基底。接著,於溝渠側壁形成介電層: 之後’於鮮巾填人下電極,且下電極之上表面低於基底 之上表面。接著,移除部分基底,以於下電極之上方形成 開口。開口之寬度大於溝渠之寬度,且基底中之相鄰兩開 口之間包夹有-個突出部。隨之,進行離子植人製程,二 相鄰之溝渠之間、剩餘之絕緣層上的基底中形成上♦極、 然後,於突出部之下部形成第—摻雜,並與上電極^接。 接下來’於第-摻·上之開口㈣依序形成閘極介 以及閘極。之後,於開極上方之突出部中形成第二捧曰。 在本剌之-實施财,祕隨齡取記憶體 ^法^更包括於形成第二摻雜區之後,於基底 ^ 窗,其例如是與第二摻雜區耦接。 或接觸 在本發明之Μ施例中,上述之開口與突出部的 方法例如是先於基底上形成轉層。之後,再 4 J第-圖案化光阻層。第—圖案化光阻層形成於二^ 渠之間的基底之上方’且第—_化雜層之寬度例如^ 1362721 2005-0108 22658twf.doc/n 小於相鄰兩溝渠之間的基底寬度。之後,以第一圖案 2為罩幕:移除郷露出的罩幕層與基底,直到暴露= 电極。接著,移除第一圖案化光阻層。 氧化Ϊ本發明之—實施例中,上述之罩幕層的材料例如是 部。在本發明之-實施例中,上述之問極例如是環繞突出 後 在本發明之-實施例中,更包括於第一擦雜區 間極形成之前’㈣口之·形成下間隙壁。 "iff發明之—實施例中’上述之下間隙壁的形成方法 二疋^於基底上形成介電材料層。介電材料層例 Ϊ =著了介電材料層上形成第二圖案化光阻層 第―圖案化光阻層例如是形成於開口之上方,且第 2光阻層之寬度例如是小於開口之寬度。之後:巴 為罩幕’移除部份暴露出的介電材料層:: 寬度例:上述之第二圖案化光阻層之 在本發明之—實施例中,上述之 如是低於第-摻雜區之上表面。服土的上表面例 =明之一實施例中,上述之閘極的形成方法例如 上形成導體材料層。之後,移除部份導體材料 層’形成覆蓋下間隙壁之閘極。閘極之上表面㈣ 1362721 2005-OIog 22658tw-f.doc/n 突出部之上表面。 在本發明之一實施例中,更包括於間極形成之後、第 二摻雜區形成之前,於開口之側壁形成上間隙壁。上間隙 壁例如是覆蓋住閘極。 $㈣之—實施例中,更包括於形成介電層之後、 形珉下电極之前,於溝渠之側壁形成襯層。 如發Γ之—實施例中’上述之介電層的形成方法例 如疋熱氧化處理。 之離==之—實施射’上述之料植人製程所植入 之離子例如是Ν型離子。 在本發明之一實施例中,上述之下雷 摻雜多晶矽。 …電極的材料例如是 鶴。在本發明之—實施财,上述之閘極的材料例如是 減=月》,遺機存取記憶體的製作方法因採用先 == 接著於電容器上方形成垂直配置的 罨日日體,之後再於電晶體之第二摻 在製作出來的動態隨機存取記憶體中y 觸^ 及接觸窗的配置方式娜垂直的:置二== 之配置方式在晶片表面上具有更小乂 在曰Η由主-, 幻截•面積。也就是說, 中母枝面積内所能形成的動態隨機存取 數里會增加,因而可提升元件的積集度。 。心 此外,在本發明之動態隨機存取 是形成於基底中,幻目鄰電容器之下電贼透過 1362721 2005-0108 22658twf.doc/n 底耦接,也就是說數個動態隨機存取記憶胞共用一下電 極。因此’本發明可以大幅地提升電容器下電極的表面積, 使電容器的電容量有效地增加,因此更有利於小尺寸之記 憶體元件的製作,並提升元件效能。 為讓本發明之上述特徵和優點能更明顯易懂,下文特1362721 2005-0108 22658twf.doc/n IX. Description of the invention: * [Technical field to which the invention pertains] * The present invention relates to a memory element and a method of fabricating the same, and particularly to a dynamic random access memory Dynamic random access memory (DRAM) and its manufacturing method. V [Prior Art] • As the functions of today's computer microprocessors become more and more powerful, the programs and operations of software are becoming more and more complex, so the memory technology has become an important technology in the semiconductor industry. —. In general, memory can be classified into volatile memory and non-volatile memory depending on the type of data stored. The dynamic random access memory belongs to a kind of volatile memory, and ^ is composed of a plurality of memory cells. Each of the memory cells is mainly composed of a transistor and a capacitor, and each of the memory cells is electrically connected to the bit line (10) 丨B by a word line (WL). • Figure 1 is a schematic cross-sectional view of a conventional dynamic random access memory. Referring to FIG. 1, a conventional dynamic random access memory includes a substrate 1 , an electric grid 110 , and a laterally disposed transistor 120 . The substrate 100 has a trench 102 and the capacitor 11 is located within the trench 1〇2. The capacitor 11A includes a lower electrode 104, a capacitor dielectric layer, and an upper electrode 108. The transistor 12 is disposed on the substrate 100. The transistor 120 includes a gate 124, > and a polar region 122b with a source region 122a. The drain region 122b and the source region 122a are disposed in the substrate 10A on both sides of the gate I24. The drain region 122b of the transistor 120 is electrically connected to the source region 122a through the buried conductive strip 13〇 formed on the substrate 100 and the capacitor no. 6362721 2005-0108 22658twf.doc/n pole 108 is electrically connected. To the bit line contact window 140 disposed on the substrate 1 . The conventional dynamic random access memory is configured such that the capacitor 110, the laterally-arranged transistor 120, and the bit line contact window 140 correspond to different positions on the surface of the substrate v 1 , respectively, in a horizontal manner. That is, the capacitor 110, the transistor 120, and the bit line contact window 140 respectively occupy a portion of the area on the surface of the wafer, so the number of > memories that can be configured per unit area is limited. Even though the line width of the component can be gradually reduced by the technique, the increase in component integration is still limited by the above-mentioned configuration. Therefore, how to make more components in a limited space without affecting the size of the components to improve the component accumulation and the wafer usage rate is an urgent problem to be solved. SUMMARY OF THE INVENTION The present invention provides a dynamic random access memory having a memory cell having a coaxial vertical configuration capable of increasing cell density (ceU density) and improving component performance. The present invention provides a method for fabricating a dynamic random access memory, which can improve the number of memory cells that can be produced per unit area, and thus can achieve the purpose of improving component accumulation. The present invention proposes a dynamic random access method. A memory comprising a semiconductor substrate, an electric grid, and a transistor. A plurality of columnar structures are disposed on the semiconductor substrate. Each of the columnar structures includes an insulating layer, a semiconductor layer, and a semiconductor protrusion from the semiconductor substrate from bottom to top. The capacitor includes a lower electrode, an upper electrode, and a lower electrode disposed in the columnar region, and the connection is placed at ==:=::. Capacitor medium and second doped region. a closed-pole disposed in the semiconductor; a semiconductor-embedded portion of the first-doped region disposed under the gate; a semiconductor protrusion disposed above the gate with a doped-doped region = upper electrode °, for example; Body =: Dimensions of the above-mentioned semiconductor protrusions. In one embodiment of the invention, the dynamic random access etch contact is disposed above the transistor and is switched with the second doped region. In an embodiment of the invention, the material of the contact window is, for example, in one embodiment of the invention, wherein the gate is, for example, a body protrusion. In one embodiment of the invention, the transistor further includes a gate dielectric layer disposed between the gate and the semiconductor protrusion. In an embodiment of the invention, the DRAM further includes a spacer disposed on the sidewall of the semiconductor protrusion and on the upper and lower sides of the gate. In one embodiment of the invention, the capacitor dielectric layer is, for example, a composite dielectric layer. In one embodiment of the invention, the composite dielectric layer described above is, for example, an oxide/nitride layer or an oxide/nitride/oxide (germanium) layer. In an embodiment of the invention, the material of the lower electrode is, for example, 2005-0108 22658 twf.doc/n doped polysilicon. In an embodiment of the invention, the material of the upper electrode is, for example, a replacement stone. Tungsten In one embodiment of the present invention, the material of the gate is, for example, a method of fabricating a dynamic random access memory, which first provides a substrate in which an insulating layer has been formed. Then, a portion of the substrate and the insulating layer are removed to form a plurality of trenches in the substrate and expose the substrate under the insulating layer. Next, a dielectric layer is formed on the sidewall of the trench: then the lower electrode is filled in the fresh towel, and the upper surface of the lower electrode is lower than the upper surface of the substrate. Next, a portion of the substrate is removed to form an opening above the lower electrode. The width of the opening is greater than the width of the trench, and a plurality of protrusions are sandwiched between adjacent openings in the substrate. Subsequently, an ion implantation process is performed, and an upper NMOS is formed in the substrate between the adjacent trenches and the remaining insulating layer, and then a first doping is formed under the protruding portion, and is connected to the upper electrode. Next, the opening (4) on the first doping layer sequentially forms a gate dielectric and a gate. Thereafter, a second holding is formed in the protrusion above the opening. In the present invention, the memory is further included in the memory after the second doped region is formed, for example, coupled to the second doped region. Or Contact In the embodiment of the present invention, the above-described method of opening and protruding is, for example, forming a layer of transition on the substrate. After that, the fourth J-patterned photoresist layer. The first patterned photoresist layer is formed over the substrate between the trenches and the width of the first-type hybrid layer is, for example, ^ 1362721 2005-0108 22658twf.doc/n is smaller than the substrate width between adjacent trenches. Thereafter, the first pattern 2 is used as a mask: the exposed mask layer and the substrate are removed until the exposed electrode is exposed. Next, the first patterned photoresist layer is removed. Cerium Oxide In the embodiment of the invention, the material of the above-mentioned mask layer is, for example, a portion. In the embodiment of the present invention, the above-mentioned problem pole is, for example, surrounded by protrusions. In the embodiment of the present invention, it is further included to form the lower spacer before the formation of the first erasing region. "iff Invention-In the embodiment, the method of forming the lower spacer described above is to form a dielectric material layer on the substrate. Example of a dielectric material layer Ϊ a second patterned photoresist layer is formed on the dielectric material layer. The patterned photoresist layer is formed over the opening, for example, and the width of the second photoresist layer is, for example, smaller than the opening. width. Thereafter: the mask is a mask to remove a portion of the exposed dielectric material layer:: Width example: the second patterned photoresist layer described above is in the present invention - in the embodiment, the above is lower than the first blend The surface above the miscellaneous area. Upper surface example of the soil 1. In the embodiment, the above-described method of forming the gate is formed, for example, on a conductor material layer. Thereafter, a portion of the conductor material layer is removed to form a gate covering the lower spacer. Upper surface of the gate (4) 1362721 2005-OIog 22658tw-f.doc/n Surface above the protrusion. In an embodiment of the invention, the upper spacer is formed on the sidewall of the opening after the formation of the interpole and before the formation of the second doped region. The upper gap wall covers, for example, the gate. $(四)—In the embodiment, the lining is formed on the sidewall of the trench after forming the dielectric layer and before forming the lower electrode. For example, in the embodiment, the method of forming the dielectric layer described above is, for example, a thermal oxidation treatment. The ion implanted by the implanting process described above is, for example, a sputum ion. In one embodiment of the invention, the above-described Ray-doped polysilicon is used. The material of the electrode is, for example, a crane. In the present invention, the material of the above-mentioned gate is, for example, minus = month, and the manufacturing method of the memory access memory is formed by first == then forming a vertical configuration of the next day on the capacitor, and then The second mode of the transistor is incorporated in the fabricated dynamic random access memory. The configuration of the y touch and the contact window is vertical: the configuration of the second == has a smaller size on the surface of the wafer. Main -, illusion cut · area. That is to say, the number of dynamic random accesses that can be formed in the area of the mother branch increases, so that the degree of integration of components can be improved. . In addition, the dynamic random access in the present invention is formed in the substrate, and the electric thief is coupled through the edge of the phantom capacitor, which is connected to the bottom, that is, several dynamic random access memory cells. Share the electrode. Therefore, the present invention can greatly increase the surface area of the lower electrode of the capacitor and effectively increase the capacitance of the capacitor, thereby facilitating the fabrication of a small-sized memory element and improving the performance of the element. In order to make the above features and advantages of the present invention more obvious, the following

舉較佳實施例,並配合所附圖式,作詳細說明如下。 【實施方式】 主圖2A至圖20A為依照本發明—實施例所繪示之動態 機存取s己憶體的製作流程上視圖。圖2B至圖是沿 著圖2A至圖20A中剖面線1-1,之剖面示意圖。DETAILED DESCRIPTION OF THE PREFERRED EMBODIMENTS The preferred embodiments, together with the drawings, are described in detail below. [Embodiment] FIG. 2A to FIG. 20A are top views of a manufacturing process of a dynamic machine access s memory in accordance with an embodiment of the present invention. Fig. 2B is a schematic cross-sectional view taken along line 1-1 of Fig. 2A to Fig. 20A.

首先,請同時參照圖2A與圖2B,提供基底200,基 底200例如是絕緣層上覆矽(silicon on insulator,SOI)之基 底。基底200的材料例如是p型半導體。也就是說,基底 2〇〇例如是由半導體基底2〇〇a、絕緣層2〇肋以及半導體主 體200C所構成。絕緣層2〇〇b例如是配置於半導體基底 2〇〇a與半導體主體200c之間,以隔開半導體基底200a以 及用以製作元件的半導體主體細e,因此能夠減少耗電、 降低元件錯誤,並提高元件效能。半導體基底200a以及半 導體主,200c的材料例#是!>型+導體,其例如是在石夕中 加入v里的硼或是其他合適之三價原子。絕緣層2〇〇b的 料例如是氧化矽。 接著,於基底200上依序形成墊氧化(pad 〇xide)層 202、墊氮化(pad nitride)層204以及罩幕層206。墊氧化層 2〇2例如是氧化矽層或其他合適之氧化物層。墊氮化層2糾 12 v 1362721 2005-0108 22658twfd〇c/n 例=是氮化矽層或其他合適之氮化物層。罩幕層206則例 如疋硼矽玻璃(b〇r〇sincate giass,BSG)層。當然,罩幕層2〇6 也可以是硼矽破璃以外的材質,只要選擇具有適當^刻選 擇比的材質即可。墊氧化層202的形成方法例如是化學氣 相沈積法或是熱氧化法。墊氮化層2〇4以及罩幕層的 形成方法皆例如是化學氣相沈積法。之後,於罩幕層2〇6 上形成圖案化光阻層208。 之後,請同時參照圖3A與圖3B,以圖案化光阻層2〇8 為罩幕,進行蝕刻製程,移除暴露出的罩幕層2〇6、墊氮 化^ 204以及墊氧化層2〇2。隨之,移除圖案化光阻層2〇8。 接著,再以剩餘的罩幕層206為罩幕,移除暴露出的半導 體主體2GGe絲露出絕緣層雇,以於絕緣層細b上方 形成溝渠21〇m剩餘的半導社體職例如是 形成行列排列之柱狀結構200c,。而使用上述之罩幕層2〇6 為罩幕’能夠避免在進行餘刻製程之後於塾氮化層2〇4的 邊角產生圓化(rounding)的問題。 _特別注意的是,在本實施例的上視示意圖中(如圖3A 所不)’罩幕層2〇6的每一個區塊上視之形狀為圓形。然而 在其他實施财,罩幕層2G6的每—個區塊上視之形狀可 以例如是_形、㈣、正方形或其他雜,於此技術領 域具有通常知識者可視其需求進行調整。當然,柱狀結構 2〇〇c上視之形狀則對應於罩幕層鹰上視之形狀,柱狀 結構20Ge,可以是圓柱狀、_柱狀或對應之多邊形的柱 13 ubirn 2005-0108 22658twf.doc/n 盆參照圖M與圖4B,移除罩幕層206, 例如疋乾式_法或是濕式峨。之後,於 ^ :之側壁形成介電層212。介電層212例如是氧化 t適之介電膜層。介電層212的形以法例如 疋對私210之側壁表面進行熱氧化處理,以於溝渠21〇 層缚的氧化石夕層。然後,於溝渠210表面以First, referring to Figures 2A and 2B, a substrate 200 is provided. The substrate 200 is, for example, a silicon on insulator (SOI) substrate. The material of the substrate 200 is, for example, a p-type semiconductor. That is, the substrate 2 is composed of, for example, a semiconductor substrate 2A, an insulating layer 2 rib, and a semiconductor body 200C. The insulating layer 2B is disposed between the semiconductor substrate 2A and the semiconductor body 200c, for example, to separate the semiconductor substrate 200a and the semiconductor body thin e for fabricating the device, thereby reducing power consumption and reducing component errors. And improve component performance. The semiconductor substrate 200a and the semiconductor main body, the material example of the 200c is #! > Type + conductor, which is, for example, boron added to V in Shi Xi or other suitable trivalent atom. The material of the insulating layer 2〇〇b is, for example, cerium oxide. Next, a pad idexide layer 202, a pad nitride layer 204, and a mask layer 206 are sequentially formed on the substrate 200. The pad oxide layer 2〇2 is, for example, a hafnium oxide layer or other suitable oxide layer. Pad nitride layer 2 Correction 12 v 1362721 2005-0108 22658twfd〇c/n Example = is a tantalum nitride layer or other suitable nitride layer. The mask layer 206 is, for example, a layer of b〇r〇sincate giass (BSG). Of course, the mask layer 2〇6 may be made of a material other than boron enamel, as long as a material having an appropriate selection ratio is selected. The formation method of the pad oxide layer 202 is, for example, a chemical vapor deposition method or a thermal oxidation method. The pad nitride layer 2〇4 and the mask layer are formed by, for example, chemical vapor deposition. Thereafter, a patterned photoresist layer 208 is formed on the mask layer 2〇6. After that, referring to FIG. 3A and FIG. 3B simultaneously, the photoresist layer 2〇8 is patterned as a mask, and an etching process is performed to remove the exposed mask layer 2〇6, pad nitride 204, and pad oxide layer 2. 〇 2. Accordingly, the patterned photoresist layer 2〇8 is removed. Then, the remaining mask layer 206 is used as a mask to remove the exposed semiconductor body 2GGe wire to expose the insulating layer, so as to form a trench 21 〇m over the insulating layer b, for example, the remaining semiconductor body is formed. The columnar structure 200c arranged in rows and columns. The use of the above-mentioned mask layer 2〇6 as a mask' can avoid the problem of rounding at the corners of the tantalum nitride layer 2?4 after the finish process. It is to be noted that in the top view of the present embodiment (as shown in Fig. 3A), each of the blocks of the mask layer 2〇6 has a circular shape. However, in other implementations, the shape of each mask of the mask layer 2G6 may be, for example, a _ shape, a (four), a square, or other miscellaneous, and the technical person skilled in the art may adjust it according to his needs. Of course, the shape of the columnar structure 2〇〇c corresponds to the shape of the mask layer eagle view, the columnar structure 20Ge, which may be a columnar, _ columnar or corresponding polygonal column 13 ubirn 2005-0108 22658twf .doc/n Basin Referring to Figure M and Figure 4B, the mask layer 206 is removed, such as a dry or wet type. Thereafter, a dielectric layer 212 is formed on the sidewall of the ^:. Dielectric layer 212 is, for example, a dielectric film layer that is oxidized. The dielectric layer 212 is formed by, for example, thermally oxidizing the sidewall surface of the private 210 to the oxidized stone layer of the trench 21 层. Then, on the surface of the trench 210

成觀層214。概層214例如是氮化石夕層 之介電膜層’其形成方法例如是化學氣相沈積 法。s然,襯層214也可以是選擇氮化物以外的材質,例 如碳化物、氮碳化物缝氧化轉,與縣層鳩具有不 同蝕刻選擇比的材質。Forming layer 214. The layer 214 is, for example, a dielectric film layer of a nitride layer, which is formed by, for example, a chemical vapor deposition method. Alternatively, the lining layer 214 may be made of a material other than a nitride, such as a carbide or a nitrogen carbide seam, which has a different etching selectivity than the county layer.

七繼之,於溝渠210中填入罩幕層216。罩幕層叫 路出柱狀結構赢,之上部以及位於溝渠21G上部之部份 襯層214。罩幕層216的材料例如是光阻。罩幕層216的 形成方法例如是糾賤轉塗佈法毯覆性地於基底上 形成罩幕㈣層(未料),罩幕_蓋柱狀結構 200c’ 立、入溝渠21G卜之後’例如是以臭氧回射彳方式,移 除柱狀結構施,上方之罩幕材料層以及部份位於溝準 210中之罩幕材料層。 〃 然後,請同時參照圖5A與圖5B,以罩幕層216為罩 幕,移除暴露出的襯層214及介電層2U。移除襯層214 及介電層212的方法例如是渥式钱刻&。經過移除後的襯 層214之頂部表面及介電層212之頂部表面例如是約相等 於罩幕層216之上表面。接著,將罩幕層216移除,其移 14 -L JUZ /Z1 2005-0108 22658twf.doc/n 除方法例如是乾式蝕刻法。 之後,請同時參照圖6A與圖6B,進行 渠2K)底部之襯層214,以於柱狀結構;側^ =成壤狀的襯層214。接著,再以剩餘的襯層214為罩幕, 以暴露出的絕緣層200b。移除底部襯層214 以及絶緣層200b的方法例如是乾式蝕刻法。Seventh, the mask layer 216 is filled in the trench 210. The mask layer is called the exit column structure to win, the upper portion and a portion of the lining 214 located in the upper portion of the trench 21G. The material of the mask layer 216 is, for example, a photoresist. The mask layer 216 is formed by, for example, a ruthenium-transfer coating method to form a mask (four) layer on the substrate (unknown), and the mask-cap column structure 200c' is placed after the trench 21G. In the ozone retroreflective manner, the column structure is removed, the upper mask material layer and a portion of the mask material layer located in the trench 210. 〃 Then, referring to FIG. 5A and FIG. 5B simultaneously, the exposed lining layer 214 and the dielectric layer 2U are removed by using the mask layer 216 as a mask. The method of removing the liner layer 214 and the dielectric layer 212 is, for example, a 钱 type of money engraving & The top surface of the removed liner 214 and the top surface of the dielectric layer 212 are, for example, approximately equal to the upper surface of the mask layer 216. Next, the mask layer 216 is removed, which is shifted by 14 - L JUZ / Z1 2005-0108 22658twf.doc / n. The method is, for example, a dry etching method. Thereafter, referring to Fig. 6A and Fig. 6B, the lining 214 at the bottom of the channel 2K) is applied to the columnar structure; the side is a lining 214 which is formed into a soil. Next, the remaining liner 214 is used as a mask to expose the insulating layer 200b. The method of removing the underlying liner layer 214 and the insulating layer 200b is, for example, a dry etching method.

1 繼而’請同時參照圖7A與圖7β,於溝渠21〇中殖入 下電極218上表面的高度例如是與襯層… 的而度约略相等,其材料例如是摻雜钟的多晶石夕。 成方法例如是利用化學氣相沈積法先於基 200,日枯形成^體層(未緣示)’其順應性地覆蓋柱狀結構 c八入溝渠21〇中。之後,再進行回钱刻製程,將導 體層回蝕至暴露出溝渠210之上部。 下古值得提的是’由於溝渠21G的底部與絕緣層200b 之半導體基底2〇〇a相連接,因此形成於相鄰溝渠21〇1 Then, please refer to FIG. 7A and FIG. 7β simultaneously, and the height of the upper surface of the lower electrode 218 in the trench 21〇 is, for example, approximately equal to the degree of the lining layer, and the material thereof is, for example, a polycrystalline spine doped with a clock. . The method is formed by, for example, chemical vapor deposition prior to the base 200, forming a bulk layer (not shown) which conforms to the columnar structure c into the trench 21〇. Thereafter, a process of returning the ink is performed to etch back the conductor layer to expose the upper portion of the trench 210. It is worth mentioning that the bottom of the trench 21G is connected to the semiconductor substrate 2〇〇a of the insulating layer 200b, and thus is formed in the adjacent trench 21〇.

的下,,218彼此之間可以藉由半導體基底電性連 也就疋》兒,在後續形成於基底2〇〇中的多個電容界丑 用一個下電極。 σ /、 接著,請同時參照圖8Α與圖8Β,於基底2〇〇上形成 另一層罩幕f 22G。罩幕層220順應性地覆蓋柱狀結構 2〇〇C 3’且填入溝渠210中。罩幕層220的材料例如是氧化 矽或疋其他合適之材料。於罩幕層220形成之後,還可選 擇f也進行化學機械研磨(chemical mechanical polish, CMP)法,使罩幕層22〇的表面平坦化。之後,於罩幕層 15 1362721 2005-0108 22658twf.d〇c/n 220上形成圖案化光阻層222。圖案化光阻層222的投影位 置例如是對應於柱狀結構200c’之中央上方,且圖案化光 阻層222的寬度例如是小於柱狀結構200c,之寬度。 然後,請同時參照圖9A與圖9B,以圖案化光阻層222 為罩幕’移除暴露出的罩幕層220、墊氮化層204、墊氧化 層202與部分柱狀結構200c,,以形成開口 224。開口 224 之底部例如是暴露出襯層214以及下電極218之頂部。開 口 224例如是形成於溝渠21〇上,且開口 224之寬度例如 於溝渠210之寬度。也就是說,開口 224的底部例如 是還暴露出部分柱狀結構200c,。此外,開口 224形成之 後,柱狀結構2〇〇c’的上部例如是形成了突出部225,由相 鄰的開口 224所包夾。 請繼續參照圖9A與圖9B,將圖案化光阻層222移 ,。之後,於開口 224之部分表面形成襯氧化層226。襯 氧化層226例如疋暴露出襯層214之頂部表面與介電層 212之頂部表面。概氧化層226的材料例如是氧化㈣^ ,、他s適之氧化物,其形成方法例如是熱氧化法。 請同時參照目10Α與圖1〇Β,進行離子植入製程,於 :口 224下方之柱狀結構職,形成植入區域。離子植入 j所植人離子例如是Ν贿子,如钟_。離子植入製 是採多:嫌人,判料_植人能量來使植入離 種°上述離子植人製程中所使用的離子 通常知以量’於此技術領域具有 1362721 2005-0108 22658twf.doc/n 承上述,完成離子植入製程之後,更可以選擇性地進 ' 订後離子,入(P〇St 10n imPlantation)的回火(annealing)製 程,以恢復表面原子的結構及電性,並使離子適當地分饰 . 於柱狀結構200c’中。由於柱狀結構200c,的材料例如是半 導體石夕,經過離子植人製程後的柱狀結構職,會因而形 ’ 成導體材料’可以作為電容器之上電極。而位於柱狀社構Underneath, 218 can be electrically connected to each other by a semiconductor substrate, and a lower electrode is used in a plurality of capacitors formed in the substrate 2A. σ /, Next, please refer to FIG. 8A and FIG. 8A simultaneously to form another mask f 22G on the substrate 2〇〇. The mask layer 220 conformally covers the columnar structure 2〇〇C 3' and is filled into the trench 210. The material of the mask layer 220 is, for example, yttrium oxide or other suitable material. After the formation of the mask layer 220, a chemical mechanical polish (CMP) method is also selected to planarize the surface of the mask layer 22A. Thereafter, a patterned photoresist layer 222 is formed over the mask layer 15 1362721 2005-0108 22658twf.d〇c/n 220. The projected position of the patterned photoresist layer 222 is, for example, corresponding to the center of the columnar structure 200c', and the width of the patterned photoresist layer 222 is, for example, smaller than the width of the columnar structure 200c. Then, referring to FIG. 9A and FIG. 9B, the exposed photoresist layer 222 is used as a mask to remove the exposed mask layer 220, the pad nitride layer 204, the pad oxide layer 202 and the partial columnar structure 200c, To form an opening 224. The bottom of the opening 224 is, for example, exposed to the top of the liner 214 and the lower electrode 218. The opening 224 is formed, for example, on the trench 21, and the width of the opening 224 is, for example, the width of the trench 210. That is, the bottom of the opening 224, for example, also exposes a portion of the columnar structure 200c. Further, after the opening 224 is formed, the upper portion of the columnar structure 2〇〇c' is formed, for example, by a projection 225 which is sandwiched by the adjacent opening 224. Referring to FIG. 9A and FIG. 9B, the patterned photoresist layer 222 is moved. Thereafter, a liner oxide layer 226 is formed on a portion of the surface of the opening 224. A liner oxide layer 226, such as germanium, exposes the top surface of liner layer 214 and the top surface of dielectric layer 212. The material of the oxide layer 226 is, for example, an oxide (tetra), and an oxide thereof, which is formed by, for example, a thermal oxidation method. Please refer to item 10Α and Figure 1〇Β for the ion implantation process. The columnar structure below the port 224 forms the implanted area. Ion implantation j implanted human ions, for example, a bribe, such as the clock. The ion implantation system is more than suspicion: it is suspected that the implanted energy is used to make the ions used in the ion implantation process. The amount of ions used in the above-mentioned ion implantation process is generally known as 1362721, 2005-0108, 22658 twf. Doc/n According to the above, after the ion implantation process is completed, the ionic tempering process can be selectively performed to restore the structure and electrical properties of the surface atoms. The ions are appropriately decorated in the columnar structure 200c'. Since the material of the columnar structure 200c is, for example, a semiconductor stone, the columnar structure after the ion implantation process can form a conductor material as the upper electrode of the capacitor. Columnar community

• 施,以。料體層218之間介電層犯以及襯層214則S • $電容器之電容介電層。當然,介電層212的厚度以及襯 層214的厚度可視其需求以進行調整。 之後,請同時參照圖11A與圖UB,於突出部2乃之 下部形成摻雜區250。摻雜區250的形成方法例如是進行 植入$程。而植入離子例如是N型離子,其濃度例如 疋”於10 cm-3至l〇2〇cnf3之間。離子植入製程例如是夢 由,制植入能量及植入角度,使得N型離子可以植入於^ 出部225之中。完成上述離子植入製程之後,更可以選 性地進行後離子植入的回火製程,以恢復表面原子的結構 及電性,也可使離子適當地分佈於突出部225下部。 . 在本實施例中,突出部225的材料例如是p型半導 體,因此摻雜區250所植入離子例如是N型離子。當然, •.在其他實施例中,突出部225的材料也可以是N J半、導 •體,而摻雜區250所植入離子則可以對應是p型離子,於 此技彳=領域具有通常知識者可視製程需求進行調整。' 明同時參照圖12A與圖12B,進行回钱刻製程,以將 形成於開口 224底部之襯氧化層226移除。之後,於基底 17 1362721 2005-0108 22658twf.doc/n 200 ^形成介電材料層228,且介電材料層挪填 。介電材料層228的材科例如是氧化石夕或是其他合 =雷2 ’其形成方法例如是化學氣相沈積法。此外,於 1電材料層228形成之後,還可選擇 =以使介電材料層狗表面平坦化。:後 23〇 =位置例如疋位於溝渠21〇以及開口 2 =ίι::Γ:的寬度例如是小於開σ 224之寬度且方大: 接著’請同時參照圖13Α與圖13Β, ^為罩幕,將暴露出之部份介電材料層228與 =么:::中,罩幕層22。_例如是與= :主^的β ^用乾式烟树可將之—併移除。值得 底ΐ二層228並非移除至暴露出開口 224的 _ 疋;圖案化光阻層230與突出部225之間留下一 小七刀的介電材料層228,作為下間隙壁 施的上表面例如是低於摻雜區25Q之上表面 ^„化光阻層23〇移除。之後,將部份襯氧“ 層二後例如是濕_^°在移除部“氧化 壁一之上表面具襯二層高:之上㈣ 壁二Ϊ =參照圖MA與圖14B’於突出咖 . ,以作為閘極介電層。介電層232的材 /’疋 矽,其形成方法例如是化學氣相沈積法或熱氧 18 1362721 2005-0108 22658twf.doc/n 化法三然後,於基底200上形成導體材料層234,順應性 地覆盆墊氮化層204、介電材料層228以及介電層232。導 體材料層234的材料例如是才參雜多晶石夕、金屬如鎢、銅、 含銅合金或含鎢合金,或者是金屬矽化物等,其形成方法 例如^物理氣相沈積法。此外,於導體材料層234形成之 後’還可選雜地進行化學機械研磨法,以使導體芦 234的表面平坦化。 9 凊同時參照圖15A與圖15B,進行回蝕刻製程,將部 分導體材料層234移除,以形成閘極234a。移除部份導體 材料層234的方法例如是乾式蝕刻法。閘極234a例如是形 成於下間隙壁228a之上方。而閘極234a例如是位於介電 層232與介電層228之間,且環繞在突出部225的周圍。 閘極234a之上表面例如是低於突出部225之上表面,閘極 234a之下表面例如是低於摻雜區250之上表面。 4寸別注思的是,請參照圖15A所示之上視圖,閘極 234a例如是長條狀結構環繞在突出部225的周圍,使位於 縱白上各個穴出部225側壁之閘極234a可以相互輕接,而 構成後續形成之動態隨機存取記憶體中的字元線。 接著’請同時參照圖16A與圖16B,於基底2〇〇上形 隙壁材料層236。間隙壁材料層236例如是順應性^ 覆蓋住墊氮化層204、介電層232、閘極234a以及^電材 料層228。間隙壁材料層236的材料例如是氧化矽或是其 他合適的介電材料,其形成方法例如是化學氣相沈積 此外,於間隙壁材料層236形成之後,還可進一步^擇性 19 1362721 2005-0108 22658twf.d〇c/n 地進行化學機械研磨法,使得間隙壁材料層236的表面平 坦化。• Shi, to. The dielectric layer between the body layers 218 and the liner layer 214 are the capacitive dielectric layers of the S•$ capacitor. Of course, the thickness of the dielectric layer 212 and the thickness of the liner 214 can be adjusted as needed. Thereafter, referring to Fig. 11A and Fig. UB, a doping region 250 is formed on the lower portion of the protruding portion 2. The method of forming the doped region 250 is, for example, performing implantation. The implanted ions are, for example, N-type ions, and the concentration thereof is, for example, between 10 cm-3 and 10〇2〇cnf3. The ion implantation process is, for example, a dream, an implantation energy, and an implantation angle, so that the N-type The ions can be implanted in the output portion 225. After the ion implantation process is completed, the post-ion implantation tempering process can be selectively performed to restore the structure and electrical properties of the surface atoms, and the ions can be appropriately selected. The ground is distributed in the lower portion of the protrusion 225. In the present embodiment, the material of the protrusion 225 is, for example, a p-type semiconductor, and thus the implanted ions of the doped region 250 are, for example, N-type ions. Of course, in other embodiments The material of the protrusion 225 may also be an NJ half, a conductor, and the implanted ions of the doped region 250 may correspond to a p-type ion, and the technical field is adjusted by the general knowledge to the process requirements. Referring to FIG. 12A and FIG. 12B simultaneously, a re-etching process is performed to remove the liner oxide layer 226 formed at the bottom of the opening 224. Thereafter, a dielectric material is formed on the substrate 17 1362721 2005-0108 22658twf.doc/n 200 . Layer 228, and the dielectric material layer is filled. The material of the material layer 228 is, for example, oxidized stone or other composites. The forming method thereof is, for example, chemical vapor deposition. Further, after the formation of the electric material layer 228, the dielectric material can also be selected = The surface of the layer dog is flattened.: The rear 23〇= position, for example, the width of the channel 21〇 and the opening 2 = ίι::Γ: is, for example, smaller than the width of the opening σ 224 and the square is large: then 'Please refer to FIG. 13 and FIG. 13Β, ^ is the mask, which will expose part of the dielectric material layer 228 and =?:::, the mask layer 22. _ For example with =: the main ^ β ^ with a dry type of smoke tree can be - And removing. It is worthwhile that the second layer 228 is not removed to expose the opening 224; a small layer of dielectric material layer 228 is left between the patterned photoresist layer 230 and the protrusion 225 as a lower gap. The upper surface of the wall is, for example, removed from the upper surface of the doped region 25Q. After that, part of the lining oxygen "after the second layer is, for example, wet _^° in the removal portion", the upper surface of the oxidized wall is lined with two layers high: above (four) wall two Ϊ = with reference to Figure MA and Figure 14B' Coffee. As a gate dielectric layer. The material of the dielectric layer 232 is formed by a chemical vapor deposition method or a thermal oxygen method, and then a conductive material layer 234 is formed on the substrate 200, and is compliant. The padded pad nitride layer 204, the dielectric material layer 228, and the dielectric layer 232 are formed. The material of the conductor material layer 234 is, for example, a doped polycrystalline stone, a metal such as tungsten, copper, a copper-containing alloy or a tungsten-containing alloy, or a metal halide or the like, which is formed by, for example, physical vapor deposition. Further, after the formation of the conductor material layer 234, a chemical mechanical polishing method may be optionally performed to planarize the surface of the conductor reed 234. 9A Referring to FIGS. 15A and 15B, an etch back process is performed to remove a portion of the conductor material layer 234 to form the gate 234a. A method of removing a portion of the conductor material layer 234 is, for example, a dry etching method. The gate 234a is formed, for example, above the lower spacer 228a. The gate 234a is, for example, located between the dielectric layer 232 and the dielectric layer 228 and surrounds the protrusion 225. The upper surface of the gate 234a is, for example, lower than the upper surface of the protrusion 225, and the lower surface of the gate 234a is, for example, lower than the upper surface of the doped region 250. 4 inch, please refer to the top view shown in FIG. 15A. The gate 234a is, for example, an elongated structure surrounding the protrusion 225, so that the gate 234a of the sidewall of each of the holes 225 in the longitudinal direction can be Lightly connected to each other to form a word line in a subsequently formed dynamic random access memory. Next, please refer to Figs. 16A and 16B simultaneously to form a layer of material 236 on the substrate 2 . The spacer material layer 236 is, for example, compliant to cover the pad nitride layer 204, the dielectric layer 232, the gate 234a, and the electrical material layer 228. The material of the spacer material layer 236 is, for example, ruthenium oxide or other suitable dielectric material, and the formation method thereof is, for example, chemical vapor deposition. Further, after the formation of the spacer material layer 236, further improvement can be made 19 1362721 2005- A chemical mechanical polishing method is performed at 0108 22658 twf.d〇c/n to planarize the surface of the spacer material layer 236.

請同時參關17A與圖17B,進行回關製程,將部 分間隙壁材料層236移除,形成上間隙壁⑽,而上間隙 壁236a覆蓋閘極234a。在一實施例中,由於介電材料層 228以及間隙壁材料層236的材料例如是同為氧化石夕,因 此在移除部份間隙壁材料層挪時,暴露出的介電材料層 228及部份介電層232亦會同時被移除,使得介電層加 之上表面、介電材料層228之上表面及上間隙壁23如之上 表面約相等但均低於突出部225之上表面。 然後 。月同日寸,妝圖18A與圖18B,將塾氮化芦204 移除’移除方法例如是乾絲駭或赋磁彳法。之後, 於突出部225之上部形成摻雜區252。摻雜區252的形成 方法例如枝雜子植人製程。植人軒勤是n型離 子’其濃度例如是介於l〇I8Cm-3至1〇2〇cm-3之間。離子植Please simultaneously refer to 17A and FIG. 17B to perform a return process to remove a portion of the spacer material layer 236 to form an upper spacer (10), and the upper spacer 236a covers the gate 234a. In an embodiment, since the material of the dielectric material layer 228 and the spacer material layer 236 is, for example, the same as the oxidized stone, the exposed dielectric material layer 228 and the removed portion of the spacer material layer are removed. Part of the dielectric layer 232 is also removed at the same time, so that the upper surface of the dielectric layer, the upper surface of the dielectric material layer 228, and the upper spacer 23 are equal to the upper surface but lower than the upper surface of the protrusion 225. . Then. At the same time of the month, the makeup picture 18A and FIG. 18B, the removal method of the yttrium nitride 204 is, for example, a dry wire or a magnetic enthalpy method. Thereafter, a doping region 252 is formed on the upper portion of the protrusion 225. The method of forming the doped region 252 is, for example, a hybrid process.植人轩勤 is an n-type ion' whose concentration is, for example, between l〇I8Cm-3 and 1〇2〇cm-3. Ion implantation

^製^例如是藉由不同的植人能量及植人角度來使N型離 ^刀,到突出部225之上部。此外,進行離子植入製程之 f更可以選擇性地進行後離子植入的回火製程,以恢復 表面原子構及電性H在其 225的材料也可以大出口P 子則可以是p型離ΐ!+導體,而摻雜區252所植入離 配置的:吉完成上述步驟所形成的結構即為垂直 日曰_ 配置的電晶體具有垂直配置的環繞閘 閘極234a例如是輕接縱向上的各個的電晶體, 20 1362721 2005-0108 22658twf.doc/n 作為後續預形成之動態隨機存取記憶體之字元線,用以連 接記憶胞。For example, the N-type knife is removed from the upper portion of the protrusion 225 by different implanting energy and implanting angle. In addition, the ion implantation process can selectively perform a post-ion implantation tempering process to restore the surface atomic structure and electrical H. The material of the 225 can also be large. The exit P can be p-type.导体!+conductor, and the doped region 252 is implanted away from the configuration: the structure formed by the above steps is a vertical corona. The configured transistor has a vertically arranged surrounding gate 234a, for example, in a lightly connected longitudinal direction. Each of the transistors, 20 1362721 2005-0108 22658twf.doc / n as a subsequent pre-formed dynamic random access memory word line for connecting the memory cells.

之後,請同時參照圖19A與圖19B,將墊氧化層2〇2 移除。隨之,於基底200上形成導體層238,導體層238 順應性地覆蓋柱狀結構20〇c,、介電層232以及間^壁材 料層236。導體層238的材料例如是金屬材料,如鎢、銅、 含銅合金或含鎢合金等,其形成方法例如是_氣相沈積 法。此外’於導體層238形成之後,可以選擇性地進行化 學機械研磨法,以使導體層238的表面平坦化。 隨之,請同時參照圖20A與圖20B,將導體層238圖 案化,以於突出部225上方形成接觸窗238a。 的形成方法例如是先於導體層238上方形成圖案^光阻層Thereafter, please simultaneously remove the pad oxide layer 2〇2 with reference to FIGS. 19A and 19B. Accordingly, a conductor layer 238 is formed on the substrate 200, and the conductor layer 238 conformally covers the columnar structure 20〇c, the dielectric layer 232, and the interlayer material layer 236. The material of the conductor layer 238 is, for example, a metal material such as tungsten, copper, a copper-containing alloy or a tungsten-containing alloy, and the like is formed by, for example, a vapor deposition method. Further, after the conductor layer 238 is formed, a chemical mechanical polishing method can be selectively performed to planarize the surface of the conductor layer 238. Accordingly, referring to Figs. 20A and 20B, the conductor layer 238 is patterned to form a contact window 238a over the protrusion 225. The formation method is, for example, forming a pattern photoresist layer before the conductor layer 238.

(未繪不)’且_化光阻層覆蓋住位於突出部225上方的 導體層2%。之後,以圖案化光阻層為罩幕,並以介電材 = 228為終止層,進行钱刻製程,移除暴露出的導體層 。剩餘的導體層238例如是位於突出部225之上方,且 區252耦接,以作為接觸窗篇。接觸窗驗之 二=TAT如會形成間隙,於間隙中填入 門二、书a 。内層,丨電層240使相鄰兩接觸窗238a之 離,而避免短路的發生。内層介電層24〇的材 質例2卿玻璃,其形成料例如是化學氣相沈積法。 获明上述纽例鱗用職定本伽,其僅作為本 =月之動態隨機存取記憶體的多種製造方法中的其中一 種0 21 1362721 2005-0108 22658twf.doc/n f 21A :、依照本發明一實施例所繪示動態隨機存取 記憶體之結構上現示意圖。圖21B是沿著圖21 Ι-Γ之剖面示意圖。 彳阳银 請同時參照圖21A與圖21B,本發明之動態隨機存取 記憶體3G0包括半導體基底搬、垂直配置的電晶體训 與電容器32〇。電容器32〇配置於半導體基底3〇2上。恭 晶體31〇配置於電容器32〇的上方,且與電容器3(not shown) and the photoresist layer covers 2% of the conductor layer above the protrusions 225. After that, the patterned photoresist layer is used as a mask, and the dielectric layer = 228 is used as a termination layer, and the exposed conductive layer is removed. The remaining conductor layer 238 is, for example, above the protrusion 225, and the region 252 is coupled to serve as a contact window. Contact window test 2 = TAT will form a gap, fill the door 2, book a in the gap. The inner layer, the tantalum layer 240, separates the adjacent two contact windows 238a to avoid the occurrence of a short circuit. The material of the inner dielectric layer 24 is a chemical glass, and the forming material thereof is, for example, a chemical vapor deposition method. It is known that the above-mentioned New Zealand example is used as one of various manufacturing methods of the dynamic random access memory of this month. 0 21 1362721 2005-0108 22658twf.doc/nf 21A : According to the present invention The schematic diagram of the structure of the dynamic random access memory is shown in the embodiment. Figure 21B is a schematic cross-sectional view taken along line 图-Γ of Figure 21.彳阳银 Please also refer to Figs. 21A and 21B, the dynamic random access memory 3G0 of the present invention includes a semiconductor substrate-mounted, vertically-disposed transistor training capacitor 32 〇. The capacitor 32 is disposed on the semiconductor substrate 3〇2. Christine 31〇 is placed above the capacitor 32〇 and with the capacitor 3

電晶體310的上方更配置有接觸窗33〇,且與電晶體训 麵接。 半導體基底302上配置有柱狀結構3〇4。柱狀結構3〇4 由下而上包括絕緣層304a、半導體層3〇4b以及半導體 出部304c。羊導體突出部3〇4c的尺寸例如是小於半導體 層304b的尺寸。半導體基底3〇2、半導體層麟以及半 導體突出部施的㈣例如是p型半導體。在本實施例之 圖21A的上視圖中,柱狀結構3〇4的上視之形狀例如是圓Above the transistor 310, a contact window 33 is further disposed and connected to the transistor. A columnar structure 3〇4 is disposed on the semiconductor substrate 302. The columnar structure 3〇4 includes an insulating layer 304a, a semiconductor layer 3〇4b, and a semiconductor output portion 304c from bottom to top. The size of the sheep conductor projections 3〇4c is, for example, smaller than the size of the semiconductor layer 304b. The semiconductor substrate 3, 2, the semiconductor layer, and the semiconductor protrusions are, for example, p-type semiconductors. In the upper view of Fig. 21A of the present embodiment, the shape of the upper view of the columnar structure 3〇4 is, for example, a circle.

形’亦即柱狀結構304例如是除狀。然而在其他實施例 中,柱狀結構304也可以是橢圓柱狀、矩形桎狀或其他多 邊形柱狀,於此技術領域具有通常知識者可視其需求進行 調整。 、 ·'. 電容器320包括下電極322、上電極324與電容介電 層326。下電極322配置於相鄰兩柱狀結構3〇4之間的間 隙二且連接半導體基底3〇2。下電極32;2❸材料例如是播 雜多晶矽。上電極324配置於半導體層3〇仙中。上電極 324的材料例如是摻雜矽。電容介電層326則配置於下電 22 4 1362721 2005-0108 22658twf.doc/n 極322與上電極324之間。電容介電層從例如是複合介 電層,由氮化物層326a與氧化物層3施所組成,並中氧 化物層326b例如是配置於半導體層遍側壁,而氮化物 層施例如是配置於下電極322與氧化物層遍之間。 ft他實施例中,電容介電層326更可以例如是氧化石夕 二^化韻或疋—般常見的氧化梦/氮化氧化碎(ΟΝΟ)The shape 'i.e., the columnar structure 304 is, for example, a shape. In other embodiments, however, the columnar structure 304 can also be an elliptical cylinder, a rectangular dome, or other polygonal column, which can be adjusted by one of ordinary skill in the art to meet its needs. The capacitor 320 includes a lower electrode 322, an upper electrode 324, and a capacitor dielectric layer 326. The lower electrode 322 is disposed in the gap 2 between the adjacent two columnar structures 3〇4 and is connected to the semiconductor substrate 3〇2. The lower electrode 32; 2 ❸ material is, for example, a polycrystalline germanium. The upper electrode 324 is disposed in the semiconductor layer 3 . The material of the upper electrode 324 is, for example, doped germanium. The capacitor dielectric layer 326 is disposed between the power source 22 4 1362721 2005-0108 22658 twf.doc/n pole 322 and the upper electrode 324. The capacitor dielectric layer is composed of, for example, a composite dielectric layer, and is composed of a nitride layer 326a and an oxide layer 3, and the intermediate oxide layer 326b is disposed, for example, on the sidewall of the semiconductor layer, and the nitride layer is disposed, for example. The lower electrode 322 is overlapped with the oxide layer. In the embodiment of the ft, the capacitor dielectric layer 326 can be, for example, an oxidized dream/nitriding oxide (ΟΝΟ) which is commonly used in oxidized stone.

’電容介電層326的材料及厚度並不揭限於本實 2=:,,於此技術領域具有通常知識者,可視其需求 隸f直配置的電晶體31G包括閉極312、摻雜區31如以 辟,乡且312配置於半導體突出部304c的側The material and thickness of the capacitor dielectric layer 326 are not limited to the present invention. The transistor 31G, which is generally configured in the art, includes a closed electrode 312 and a doped region 31. As shown in the figure, the township 312 is disposed on the side of the semiconductor protrusion 304c.

出部304c周圍。閘極312之上表面 t=於摻雜區314b之上表面,閘極312之下表面例如 2广雜區314a之上表面相等,或是位於換雜區314a 連接附近。問極312例如是長條狀結構,以電性 中的Ϊ — ?之電曰曰體310 ’構成動態隨機存取記憶體300 狀ίΐ 在本實施例中,閘極312例如是縱向的長條 鋼=1極312的材料例如是擦雜多晶石夕、金屬如轉、 金或含鎢合金,或者是金屬耗物等。此外, 更包括閘極介電層316,配置於閘極312 —體大出部施之間,且環繞半導體突出部3〇4c。 雜區3=與摻雜區314b分別配置於半導體突出部 導體突出部304c中極配3f4H極312下方之半 1興上電極324耦接;摻雜區314b則 23 1362721 2005-0108 22658twf.doc/n 配置於閘極312上方之半導赞*山加, + 導體犬出4 3〇4c中,與接觸窗 病接。另一方面’閘極312下方可以配置有 3⑽,以隔絕閘極312與上電極似接觸;而間極312上方 則配置有上間隙壁通’以隔絕閘極犯與接觸窗33〇之 3 Γ Ϊ接。此外’相鄰兩半導體突出部3 G 4 C之間例如 有Μ層3Π’以避免相鄰兩半導體突出部3〇和側 土上的閘極312彼此接觸。 ,觸窗330例如疋柱狀結構配置於半導體突出部綱。 全屬材^雜區賤_。接觸窗謂的材料例如是 鎢、銅、含銅合金或含鶴合金等。而相鄰接 的_窗。内》_ "電層332,以分隔相鄰 他適當之介電:料C料例如是硼矽玻璃或是其 位元Cl 還可於接觸窗330之上方配置 如是it 與接觸窗33g _接。上述之位元線例 如^縱^^的方向垂直。在本實施例中’閉極312例 動態^ J,而位兀線則例如是橫向的配置。因此, 字;記憶體300令的每個記憶胞之間,可以藉由 予兀線以及位元線相連接。 是於本發明之動態隨機存取記憶體的製作方法 置4ΐΓ=器,接著於電容器之上方形成垂直配 以構成再於電晶體之摻雜區上方形成接觸窗, 將電Si取記憶胞。上述之動態隨機存取記憶胞 知:C體以及接觸窗採同轴垂直配置,可以較習 式具有更小的截面積’使得在晶片中每單位面 24 1362721 2005-0108 22658twf.doc/n 積内所能形糾__存取記錄 能達到提高元件積集度的效果。 里㈢增加,因而 另一方面,在本發明之動態隨機存 容器是形成於基底巾,且相鄰電容器:’讀中,其電 麵接’也就紐數鋪態隨機存取 电,透過基底 極,因此可以大幅度提升電容器下電极^^用―個下電Around the exit 304c. The upper surface of the gate 312 is at the upper surface of the doped region 314b, and the lower surface of the gate 312 is equal to the upper surface of the wide region 314a, or is located near the junction of the impurity-changing region 314a. The question electrode 312 is, for example, a strip-like structure, and constitutes a dynamic random access memory 300 in the electrical body 310'. In the present embodiment, the gate 312 is, for example, a longitudinal strip. The material of the steel=1 pole 312 is, for example, a rubbed polycrystalline stone, a metal such as a spin, a gold or a tungsten-containing alloy, or a metal consumable. In addition, a gate dielectric layer 316 is further disposed between the gate 312 and the semiconductor protrusions 3〇4c. The impurity region 3 is coupled to the doped region 314b, which is disposed in the semiconductor protrusion portion conductor portion 304c, respectively, and is connected to the half-up electrode 324 below the pole 3f4H pole 312; the doped region 314b is 23 1362721 2005-0108 22658twf.doc/ n The semi-conductor is placed above the gate 312, and the conductor is out of the 4 3〇4c, which is connected to the contact window. On the other hand, '3' (10) may be disposed under the gate 312 to isolate the gate 312 from contacting the upper electrode; and the upper gap 312 is provided with an upper gap through to isolate the gate from the contact window 33. Connected. Further, there is, for example, a tantalum layer 3' between the adjacent two semiconductor protrusions 3 G 4 C to prevent the adjacent two semiconductor protrusions 3 and the gates 312 on the side soil from coming into contact with each other. The contact window 330 is disposed, for example, in a columnar structure on the semiconductor protruding portion. All genus and miscellaneous areas 贱 _. The material of the contact window is, for example, tungsten, copper, a copper-containing alloy or a crane-containing alloy. And the adjacent _ window. The inner layer _ " electrical layer 332 to separate adjacent appropriate dielectric: material C material such as borosilicate glass or its bit Cl can also be placed above the contact window 330, such as it and the contact window 33g _ . The above bit line is, for example, perpendicular to the direction of the ^^^. In the present embodiment, 'closed 312 cases are dynamic, and the horizontal line is, for example, a lateral arrangement. Therefore, each of the memory cells of the memory 300 can be connected by a predetermined line and a bit line. In the method of fabricating the dynamic random access memory of the present invention, a vertical alignment is formed over the capacitor to form a contact window over the doped region of the transistor, and the Si is taken as a memory cell. The above-mentioned dynamic random access memory cell knows that the C body and the contact window adopt a coaxial vertical configuration, which can have a smaller cross-sectional area than the conventional one, so that the unit per unit surface 24 1362721 2005-0108 22658 twf.doc/n product in the wafer The internal tangible __ access record can achieve the effect of improving the component accumulation. In the third (three) increase, on the other hand, the dynamic random storage container of the present invention is formed on the base towel, and the adjacent capacitor: 'reading, its electrical connection' is also a random number of random access electric power, through the substrate Extremely, so it can greatly improve the lower electrode of the capacitor

效地增加電容器的電容量,因此更有利:積’能夠有 元件的製作。 寸之記憶體 雖然本發明已以較佳實施例揭露如上,鈇 限f本發明,任何所屬技術領域中具有通常者非,以 脫離本發明之精神和範圍内,當可作些許之更^潤^不 =本發明之保護範圍#視後附之巾請專利範圍^定者 【圖式簡單說明】Effectively increasing the capacitance of the capacitor is therefore more advantageous: the product can be fabricated. The present invention has been disclosed in the above preferred embodiments, and is not intended to be exhaustive or otherwise ^Not = the scope of protection of the present invention # 视 附 附 附 附 须 须 须 须 须 须 须 须 须 须 须 须 须 须 须

圖1為習知一種動態隨機存取記憶胞之剖面示意圖。 圖2A至圖20A為依照本發明一實施例所繪示之動態 隨機存取記憶體的製作流程上視圖。 圖2B至圖20B是沿著圖2A至圖20A中剖面線Ι-Γ 之剖面示意圖。 圖21A為依照本發明一實施例所繪示動態隨機存取 記憶體之結構上視示意圖。 圖21B是沿著圖21A中剖面線I-Ι,之剖面示意圖。 【主要元件符號說明】 100、200 :基底 25 1362721 2005-0108 22658twf.doc/n 102、210 :溝渠 • 104、218、322 :下電極 106、326 :電容介電層 108、324 :上電極 • 110、320 :電容器 - 120、310 :電晶體 122a :源極區 122b .没極區 124、234a、312 :閘極 130 :埋藏式導電帶 140 :位元線接觸窗 200a、302 :半導體基底 200b、304a :絕緣層 200c :半導體主體 200c’、304 :柱狀結構 202 :墊氧化層 籲 204:墊氮化層 206、216、220 :罩幕層 • 208、222、230 :圖案化光阻層 • 212、232、317 :介電層 . 214 :槪層 . 224 :開口 225 :突出部 226 :襯氧化層 26 1362721 2005-0108 22658twf.doc/n 228 :介電材料層 228a、318a :下間隙壁 234 :導體材料層 236 :間隙壁材料層 236a、318b :上間隙壁 238 :導體層 238a、330 :接觸窗 240、332 :内層介電層 250、252、314a、314b :摻雜區 300 :動態隨機存取記憶體 304b :半導體層 304c :半導體突出部 316 :閘極介電層 326a : lu化物層 326b :氧化物層1 is a schematic cross-sectional view of a conventional dynamic random access memory cell. 2A to 20A are top views of a process of manufacturing a dynamic random access memory according to an embodiment of the invention. 2B to 20B are schematic cross-sectional views taken along line Ι-Γ in Figs. 2A to 20A. FIG. 21A is a schematic top view showing the structure of a dynamic random access memory according to an embodiment of the invention. Figure 21B is a cross-sectional view taken along line I-Ι of Figure 21A. [Main component symbol description] 100, 200: substrate 25 1362721 2005-0108 22658twf.doc/n 102, 210: trench • 104, 218, 322: lower electrode 106, 326: capacitor dielectric layer 108, 324: upper electrode • 110, 320: capacitor - 120, 310: transistor 122a: source region 122b. gate region 124, 234a, 312: gate 130: buried conductive strip 140: bit line contact window 200a, 302: semiconductor substrate 200b 304a: insulating layer 200c: semiconductor body 200c', 304: columnar structure 202: pad oxide layer 204: pad nitride layer 206, 216, 220: mask layer • 208, 222, 230: patterned photoresist layer • 212, 232, 317: dielectric layer. 214: germanium layer. 224: opening 225: protrusion 226: lining oxide layer 26 1362721 2005-0108 22658twf.doc/n 228: dielectric material layer 228a, 318a: lower gap Wall 234: conductor material layer 236: spacer material layer 236a, 318b: upper spacer 238: conductor layer 238a, 330: contact window 240, 332: inner dielectric layer 250, 252, 314a, 314b: doped region 300: Dynamic random access memory 304b: semiconductor layer 304c: semiconductor protrusion 316: gate dielectric layer 326a: lu compound Layer 326b: oxide layer

2727

Claims (1)

U02/21 2005-0108 22658twf.doc/n 十、申請專利範固: 包括 L種動態隨機存取記憶體_一 έ士 構,縣底上配置有多個— 半導體層與導體基底起包括-絕緣層、 一電容器,包括: 下 間 下電極 該練狀結狀_間隙1 一上電極 以及 ♦六,配置於該半導體層中;以及 電層’配置於該下電極與該上 電極之 —電晶體,包括: 一 酉己置於該半導體突出部側壁; 出部中配=該閘極下方之該半導體突 出部中。— 區配置於該閘極上方之該半導體突 士如申請專利範圍第j 體,其巾該半導妓 ^ 11之動滅機存取記憶 3.如申請專利寸小於該半導體層的尺寸。 體’更包括-麵窗,^述之動態_存取記憶 且與該第二摻雜區_^接觸_配置於該電晶體之上方, 4·如申請專利範圍笛 體,其中該接觸窗的材料包括鶴所述之動態隨機存取記憶 28 丄丄 2005-0108 22658twf.doc/n 5 ·如申睛專利範園第1 體’其中該閘極環繞讀半導 6.如申請專利範圍第丄 體’更包括一閘極介電;, 部之間。U02/21 2005-0108 22658twf.doc/n X. Application for patents: including L kinds of dynamic random access memory _ a gentleman structure, a plurality of configurations on the bottom of the county - the semiconductor layer and the conductor substrate are included - insulated a layer, a capacitor, comprising: a lower lower electrode, the drilled junction, a gap 1 , an upper electrode, and a sixth electrode, disposed in the semiconductor layer; and an electrical layer disposed on the lower electrode and the upper electrode — a transistor The method includes: a sidewall disposed on the sidewall of the semiconductor protrusion; and an output portion in the semiconductor protrusion under the gate. - the semiconductor tuner disposed above the gate is in the form of a j-th body of the patent application, and the semiconductor memory of the semi-conductor is accessed. 3. If the patent application size is smaller than the size of the semiconductor layer. The body 'more includes a face window, the dynamic _ access memory and the second doped region _ ^ contact _ disposed above the transistor, 4 · as claimed in the scope of the flute, wherein the contact window The material includes the dynamic random access memory described by the crane. 28 丄丄2005-0108 22658twf.doc/n 5 · For example, the application of the patented Fan Park 1st body' where the gate surrounds the read semi-guide 6. If the scope of patent application is 丄The body 'includes a gate dielectric; between the ministries. 7·如申凊專利範圍第 體,更包括一間隙壁,配 於該閘極之上、下兩侧。 8. 如申請專利範旧楚, ^ + + ^ 弟1項所述之動態隨機存取記憶 體’其中該電容介電層包括—複合介電層。 9. 如申請專利範圍箆 ^ # ^ .. 弟8項所述之動態隨機存取記憶 ==介電層包括氧化物/氣綱 體1中1項所述之動態隨機存取記憶 體其中該下電極的材料包括摻雜多晶石夕。7. For example, the scope of the patent scope includes a spacer wall on the upper and lower sides of the gate. 8. As claimed in the patent application, ^ + + ^ 。 1 of the dynamic random access memory 'where the capacitive dielectric layer comprises - a composite dielectric layer. 9. The scope of the patent application 箆^ # ^ .. The dynamic random access memory of the 8th item == The dielectric layer includes the dynamic random access memory of the item 1 of the oxide/gas body 1 The material of the lower electrode includes doped polycrystalline stone. 項所述之動態隨機存取記憶 體突出部。 項所述之動態隨機存取記憶 配置於該閘極與該半導體突出 1項所述之動態隨機存取記憶 置於該半導體突出部側壁,且位 f 利範圍第1項所述之動態隨機存取記憶 體,其中該上電極的材料包括摻雜石夕。 ^如申請專利範圍第i項所述之動態㈣存取記憶 體,其中該閘極的材料包括鶴。 一種動態隨機存取記憶體的製作方法,包括: 提供-基底,該基底中已形成有一絕緣層; 移除部分該基底與該絕緣層,於該基底中形成多個溝 渠’以暴露出該絕緣層下方之該基底; 於該些溝渠側壁形成一介電層; 29 1362721 2005-0108 22658twf.doc/n 孩卜冤極之上表面低於 於該些溝渠中填入一下電極 該基底之上表面; 私除部分該基底’於該下電極之上方形成多數個開 口 :該些開口之寬度大於該些溝渠之寬度,且該基底中之 相綽兩該些開口之間包夾有一突出部; 行—離子植人製程,於相鄰之該輯渠之間、剩餘 之該、,巴緣層上的該基底令形成一上電極; 與該部形成一第—捧雜區,該第一摻雜區 介電之該些心側壁依序形成一問極 =該閘極上方之该突出部中形成—第二摻雜區。 體的制作如方專审利範圍第13項所述之動態隨機存取記憶 底上包括於形成該第二摻雜區之後,於該基 _’該接觸窗與該第二摻雜區叙接。 體的制作方帛13項所叙祕隨機存取記憶 =广該些開口與該突出部的形成方法包括: 於该基底上形成—罩幕層; 匕任 於該基底上形成—第—圖 案化光阻層形成於相鄰兩該些溝渠之間^ 一圖 且該第一圖案化光阻芦 ^ 方, 該基底寬度,· 叙寬度小於相鄰兩該些溝渠之間的 幕層=底圖為罩幕’移除被暴露出的該罩 直到暴露出該下電極;以及 30 1362721 2005-0108 22658twf.doc/n 移除該第一圖案化光阻層β 心Γί f ^專利範11 f 1 5項所述之動紐機存取記憶 體的衣作方法,其中該罩幕層的材料包括氧化矽。 13項㈣之動紐機存取記憶 篮的裏作方去,其中該閘極環繞該突出部。 料概㈣13項所叙祕賴存取記憶 :土'衣义法S包括於該第一摻雜區形成之後、該閘極 形成之刖,於該些開口之側壁形成—下間隙壁。 體的專利範圍第18項所述之祕隨機存取記憶 -的製作方法’其中該下間隙壁的形成方法包括: 些開=基底上形成—介電材料層,該介電材料層填入該 圖幸ΓΓ介紐料層上軸—第二圖案化光阻層,該第二 於該些開口之上方,該第二圖案化光阻 層之X度小於該些開口之寬度; 以該第二圖案化光阻層為罩幕份 介電材料層,以剩餘之聂人示ρ伤暴路出的該 隙壁;以及刃餘之暴路出的該介電材料層作為該下間 移除該弟二圖案化光阻層。 體的製作^^r述之動態隨機存取記憶 溝渠之寬度。 “―目案化光阻層之寬度大於該些 21·如申請專利範圍第丨 體的製作方法,1拷下心所这之動悲隨機存取記憶 八中該下間隙壁的上表面低於該第一 31The dynamic random access memory cell of the item. The dynamic random access memory of the item is disposed on the sidewall of the semiconductor protrusion and the dynamic random access memory of the semiconductor protrusion 1 is placed in a dynamic random memory as described in item 1 of the range The memory is taken, wherein the material of the upper electrode comprises doped stone. ^ The dynamic (four) access memory as described in claim i, wherein the material of the gate comprises a crane. A method for fabricating a dynamic random access memory, comprising: providing a substrate, an insulating layer is formed in the substrate; removing a portion of the substrate and the insulating layer, forming a plurality of trenches in the substrate to expose the insulating a substrate under the layer; forming a dielectric layer on the sidewalls of the trenches; 29 1362721 2005-0108 22658twf.doc/n The surface above the surface of the pupil is lower than the surface of the trench filled with the lower electrode a private portion of the substrate forming a plurality of openings above the lower electrode: the width of the openings is greater than the width of the trenches, and a plurality of the openings in the substrate are sandwiched between the openings; An ion implantation process, the substrate on the margin layer between adjacent ones of the adjacent channels, forming an upper electrode; forming a first-doping region with the portion, the first doping The sidewalls of the dielectric regions of the region are sequentially formed with a question mark = a second doped region is formed in the protrusion above the gate. The dynamic random access memory of the method described in claim 13 is included after forming the second doped region, and the contact window is connected to the second doped region. . The method for forming a random access memory is as follows: a method for forming the opening and the protruding portion includes: forming a mask layer on the substrate; forming a pattern on the substrate - forming a pattern The photoresist layer is formed between the adjacent two trenches and the first patterned photoresist reed, the width of the substrate is less than the thickness of the adjacent two trenches=basemap Removing the exposed cover for the mask to expose the lower electrode; and removing the first patterned photoresist layer β Γ f f f 专利 11 11 11 f 1 The method for manufacturing a memory device according to the item 5, wherein the material of the mask layer comprises ruthenium oxide. The movement of the 13th (4) moving machine accesses the memory of the basket, wherein the gate surrounds the protrusion. (4) The secret memory access memory of the item (4) includes: after the formation of the first doped region, the gate is formed, and the lower spacer is formed on the sidewall of the opening. The method for fabricating the secret random access memory described in claim 18, wherein the method for forming the lower spacer comprises: forming a layer of a dielectric material on the substrate, the dielectric material layer filling the layer The second patterned upper photoresist layer, the second patterned photoresist layer, the second patterned photoresist layer has an X degree smaller than the width of the openings; The patterned photoresist layer is a layer of dielectric material of the mask portion, and the remaining wall is covered by the remaining Nie; and the layer of dielectric material from the edge of the storm is removed as the lower portion. Brother II patterned photoresist layer. The volume of the dynamic random access memory of the volume is described. "The width of the meshed photoresist layer is greater than that of the 21st. For example, the manufacturing method of the corpuscle of the patent application scope, the upper surface of the lower spacer is lower than the sorrow random access memory. First 31
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