TWI353672B - Non-volatile memory and fabricating method thereof - Google Patents

Non-volatile memory and fabricating method thereof Download PDF

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TWI353672B
TWI353672B TW96110328A TW96110328A TWI353672B TW I353672 B TWI353672 B TW I353672B TW 96110328 A TW96110328 A TW 96110328A TW 96110328 A TW96110328 A TW 96110328A TW I353672 B TWI353672 B TW I353672B
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gate
dielectric layer
volatile memory
source
layer
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TW96110328A
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TW200807725A (en
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Chrong Jung Lin
Hsin Ming Chen
Ya Chin King
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Ememory Technology Inc
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1353672 095006(1) 21483twf.doc/n 九、發明說明: 【發明所屬之技術領域】 本發明是有關於一種半導體元件,且特別是有關於一 種非揮發性記憶體及其製造方法。 【先前技術】 當半導體進入深次微米(Deep Sub-Micron)的製程時, 元件的尺寸逐漸縮小’對於記憶體元件而言,也就是代表 記憶胞尺寸愈來愈小。另一方面,隨著資訊電子產品(如電 腦、行動電話、數位相機或個人數位助理(personal Digital1353672 095006(1) 21483twf.doc/n IX. Description of the Invention: TECHNICAL FIELD The present invention relates to a semiconductor element, and more particularly to a non-volatile memory and a method of fabricating the same. [Prior Art] When the semiconductor enters the Deep Sub-Micron process, the size of the element is gradually reduced. For the memory element, the memory cell size is becoming smaller and smaller. On the other hand, with information electronics (such as computers, mobile phones, digital cameras or personal digital assistants (personal Digital)

Assistant,PDA))需要處理、儲存的資料曰益增加,在這些 資訊電子產品中所需的記憶體容量也就愈來愈大。對於這 種尺寸變小而記憶體容量卻需要增加的情形,如何製造尺 寸縮小、尚積集度,又能兼顧其品質的記憶體元件 的一致目標。 /' 非揮發性記憶體元件由於具有使存入之資料在斷電後 也不會消失之優點’所以已成油人電腦和電子設備所廣 泛採用的一種記憶體元件。 / 丨典f的發性記憶體元件係以摻雜的多晶矽 ysi icon衣作浮置閘極(刊加㈣伽。)與控制間極 :01 Gate)而構成堆疊結構 閘極與控制閘極之間則分別設置有-層介電層。子置 多芦發性記憶體需要形成多層多晶石夕層與 過程中’會經過多道光罩步驟,拉長 衣作抓私,且耗費較多的製造成本。 5 1353672 095006(1) 21483twf.doc/n _美國^利US 6678190揭露了一種非揮發性記憶體, 此種記憶n錢㈣乡❹晶韻’而是崎置於N井上 的兩串接的兩1>型金氧半導體電晶體作為選擇閘極愈浮置 二’二!:不ί要形成控制閘極,因此此種非揮發性記憶 體的衣程可υ赋金氧半導體電晶體的製程整合在一 起’而能夠減少製造成本。 σAssistant, PDA)) The amount of data that needs to be processed and stored increases, and the amount of memory required in these information electronics products is increasing. In the case where the size is small and the memory capacity needs to be increased, how to make the size reduction, the degree of integration, and the uniformity of the memory components of the quality can be achieved. /' Non-volatile memory components have the advantage of making the stored data not disappear after power-off, so it has become a memory component widely used in oil-based computers and electronic devices. / 丨典 f's hair memory component is made up of a doped polysilicon 矽si icon as a floating gate (published (four) gamma) and a control gate: 01 Gate) to form a stacked structure gate and control gate A dielectric layer is provided between the layers. The multi-reed hair memory needs to form a multi-layered polycrystalline stone layer and the process of going through multiple reticle steps, stretching the clothes for private use, and costing more manufacturing costs. 5 1353672 095006(1) 21483twf.doc/n _US^^ US 6678190 discloses a non-volatile memory, such memory n money (four) nostalgic crystal rhyme 'but two pieces of two connected in the N well 1> type MOS transistor as the selection gate is more floating two 'two! : The control gate is not formed, so the process of the non-volatile memory can integrate the process of the MOS transistor to reduce the manufacturing cost. σ

在對此類早層複晶石夕所形成之非揮發性記憶體程式化 或是讀取動偶不是_,但進行抹除操作時,通常是在 井區上施加電壓’餅區電餘合至浮置_,以於浮置 閉極與井區d形成足_差,岐電子經由穿随介 電層:導入純並移除之。由於在對此種非揮發性記憶體 進订程式化操作及抹除操作時,都是使電子穿越過穿隨介 電層而進人料閘極或從浮置排出,因此容易使得穿 隨介電層受到損害而導致漏電流,造成記憶體元件的可靠 度降低。料,隨著元件補度的提高,所產生的高漏電 流會越厫重,將大大地限制元件尺寸縮小的程度。另一個 使用井區電_合方式之缺點,由於#合效率可能不佳, 導致需要絲於井H電驗可能非常A,使得在此單層複 晶矽非揮發性記憶體需要高壓模組,這樣—來,製程複雜 度變高’成本亦不易降低。 【發明内容】 有鑑於此,本發明的目的就是在提供一種非揮發性記 憶體,於浮置閘極上之閘間介電層設置導電插塞作為抹除 閘極,而可以對此非揮發性記憶體重複地進行程式化及抹 095006(1) 21483twf.doc/n =:=動透過,層來 動二直接透過施於浮置閉極丄= 度塞,I效率甚佳,可以降低抹除電壓,減少製程負雜 本發明的另一目的是提供—接 方法,-Γ ν — 、種非揮發性記憶體的製造 製作出非揮# = 式錢半導體製程的情況下 。非揮發^憶體’並可以增加記憶體S件的集積度。 本發明提出-種非揮發性記憶體 隔離結構、浮置閉電晶體、特定 閘雷B /結構設置於基底巾,以定A出絲區。浮置 =;ΓΓ基广浮置間電晶體具有浮置閉極、穿 二電層、卜源極/祕區與第二祕/祕區。浮 門r置於基底上’並橫跨主動區。穿隨介電層設置於浮置 紅間。第—源極/祕區與第二源極/汲極區分 ς ^置·兩側的基底中。肢介電層作為設置於 / :圣上之閘間介電層。抹除閘極設置於特定介 上,抹除閘極為第一導電插塞。 層 依照本發明的較佳實施例所述之非揮發性記憶體, J之特定介電層覆蓋m閘極的-部份。 、、依照本發明的較佳實施例所述之非揮發性記憶體, 述之特定介電層覆蓋住整個浮 置閘極。 依照本發明的較佳實施例所述之非揮發性記憶體,上 比 3672 095006(1) 21483twf.doc;, 述之特定介電層之材質為氧化矽或是氮氧化矽。 依照本發明的較佳實施例所述之非揮發性記憶體,上 述之抹除卩雜,設置浮㈣極—端,且位於隔離結構上方。 依照本發明的較佳實施例所述之非揮發性記憶體,更 ^括第二^插塞與第三導電插塞’分別電性連接第-源 極/汲極區與第二源極/汲極區。 依照本發明的較佳實施例所述之非揮發性記憶體,更 ^選擇體,設置於基紅,並㈣連料置閘電 曰曰體,此選擇閘電晶體具有選擇閘極、閘介電層、第三源 、//及極區與第一源極/没極區。選擇閘極設置於基底上, 並橫跨主動區。閘介電較置於選擇·與基底I間。第 區與第二源極’沒極區分別設置於 選擇閘極兩 =本發明的較佳實施例所述之轉發性記憶體,上 处之特定介電層覆蓋住浮置閘極的一部份。 述之特定介電層覆蓋住整辦置篮上The non-volatile memory stylized or read kinetics formed on such early-layered ceramsite is not _, but when the erase operation is performed, the voltage is usually applied to the well area. To the floating _, so that the floating closed pole forms a foot_difference with the well d, and the germanium electrons pass through the dielectric layer: the pure and removed. Since the programming operation and the erasing operation of the non-volatile memory are performed, the electrons are traversed through the dielectric layer and are discharged into the gate or discharged from the floating gate, so that it is easy to wear the device. The electrical layer is damaged and causes leakage current, resulting in a decrease in the reliability of the memory component. As the component fill increases, the resulting high leakage current will be more severe, which will greatly limit the size of the component. Another disadvantage of using the well-area-electrical-combination method is that the efficiency may not be good, which may require the wire to be in the well H. The electricity may be very A, so that the single-layer polycrystalline non-volatile memory requires a high-voltage module. In this way, the process complexity becomes higher and the cost is not easy to reduce. SUMMARY OF THE INVENTION In view of the above, an object of the present invention is to provide a non-volatile memory in which a conductive plug is disposed as a erase gate on a dielectric layer between gates of a floating gate, which can be non-volatile. The memory is repeatedly programmed and wiped 095006(1) 21483twf.doc/n =:=moving through, layer 2 is directly applied to the floating closed-end 度=degree plug, I efficiency is very good, can reduce erase Voltage, Reducing Process Negative Miscellaneous Another object of the present invention is to provide a method of connection, - Γ ν, and the manufacture of a non-volatile memory to produce a non-volatile semiconductor process. Non-volatile memory can increase the accumulation of memory S. The present invention proposes a non-volatile memory isolation structure, a floating closed crystal, and a specific gate-brake B/structure disposed on the substrate towel to define the A-outlet region. Floating =; ΓΓ-based wide floating inter-electrode has a floating closed pole, a second electric layer, a source/secret area and a second secret/secret area. The floating gate r is placed on the substrate' and spans the active area. The wearing dielectric layer is placed in the floating red room. The first source/secret area is distinguished from the second source/drainage layer. The limb dielectric layer acts as a dielectric layer between the gates of / : St. The erase gate is placed on a specific dielectric, and the erase gate is the first conductive plug. Layer In accordance with a non-volatile memory of the preferred embodiment of the invention, the specific dielectric layer of J covers the portion of the m-gate. According to a non-volatile memory of the preferred embodiment of the present invention, the specific dielectric layer covers the entire floating gate. According to a preferred embodiment of the present invention, the non-volatile memory has a ratio of 3672 095006 (1) 21483 twf. doc; and the specific dielectric layer is made of yttrium oxide or yttrium oxynitride. In accordance with a non-volatile memory of the preferred embodiment of the present invention, the noisy is erased, the floating (tetra) pole-end is disposed, and is located above the isolation structure. The non-volatile memory according to the preferred embodiment of the present invention further includes a second plug and a third conductive plug respectively electrically connected to the first source/drain region and the second source/ Bungee area. According to a preferred embodiment of the present invention, the non-volatile memory is further provided in the base red, and (4) is connected to the gate electrode, and the selection gate has a gate and a gate. The electrical layer, the third source, the // and the polar regions and the first source/no-polar region. The selection gate is placed on the substrate and spans the active area. The gate dielectric is placed between the selection and the substrate I. The first region and the second source 'the non-polar region are respectively disposed on the selective gate two = the transmissive memory according to the preferred embodiment of the present invention, and the specific dielectric layer above covers a portion of the floating gate Share. The specific dielectric layer covers the whole basket

依 Α?、本發明的輕伟音姑也丨丨士、+ π 私.. 述之抹除閘極 方。According to the Α?, the light singer of the present invention is also a gentleman, + π private..

21發明的較佳實施例所述之非揮發性記憶體,更 第二導電插塞與第三導電插塞, 外伴货性记憶體,更 分別電性連接第一源 8 1353672 095006(1) 2l483twf.doc/n 極/沒極區與第三源極/汲極區。 人平ί發明之非揮發性記憶體’由於在浮置閘極上的閉間 二=上設置第-導電插塞,此第—導電插塞可以作為抹 ^閘極。而且’㈣特定介電層(自行鱗金屬魏物阻擔 層或抵抗保護氧化層)作為浮置間極與第一導電 ^ 間極)之間的閘間介電層,因此可以在不改變— (:: 軋半導體製韻情況下製作出非揮發性記,㈣。工、’ ’當施加電壓於第—導電插塞(抹除閘極)時’就 二:’並且在浮跡讀第—導電插塞(抹 使電子從浮置閘極穿過特定介電層 随效應 阻擋層或抵抗保護氧化層)而導出 導恭插== 極),而可以抹除此記憶體。藉由設置抹除問 本發體重複地進行程式化及抹對 此外,右弟一導電插塞(抹除閘極)設置 =使得第-輪塞(抹除閉極)與 : 面積可以縮小,亦即可以縮小穿隨窗口,輕〜的 在抹除此記憶體時,即可以加快抹除速度。/ 本發明提出-種非揮發性記憶體的製造 區子「間極、穿随介電層、第—源極/汲極 f多除部傾定介電層n下餘 1。之後’於特定介電層上形成第一導電插塞,其= 9 1353672 095006(1) 21483twf.doc/n 一導電插塞作為抹除閘極。 造方= ”施例所述之非揮發性記憶體的製 /、巾於移除部分特定介電層,只留下位 ,特定介電層之步驟如下。首先, ^ 二;浮=極。然後,以罩幕層為罩幕,移除部St ”电層。之後,移除罩幕層。 ,照本發明的較佳實施例所述之非揮發性記憶體的製 =法’於特定介電層上形成第―導電插塞之步驟前,更 〇括於基底上形成層間絕緣層。 依h本發_健實施綱狀非揮發性記憶體的製 ^法,上述之特定介電層覆蓋住浮置閘極的一部份。 ^依照本發明的較佳實施例所述之非揮發性記憶體的製 这方法,上述之特定介電層覆蓋住整個浮置閘極。 ^依知本發明的較佳實施例所述之非揮發性記憶體的製 造方法,於特定介電層上形成第一導電插塞之步驟中,更 ^括,成分別電性連接第一源極/汲極區與第二源極/汲極 區之第一導電插塞及第三導電插塞。 依照本發明的較佳實施例所述之非揮發性記憶體的製 造方法’上述之特定介電層之材質包括氧化矽或是氮氧化 石夕。 依照本發明的較佳實施例所述之非揮發性記憶體的製 邊方法’更包括於基底上形成選擇閘電晶體,選擇閘電晶 體串聯連接浮置閘電晶體,選擇閘電晶體具有選擇閘極、 問介電層以及第三源極/汲極區與第二源極/汲極區。 丄 095006(1) 21483twf.doc/n 造方:照揮發性記憶體的製 上的特定介電層之步驟如;^备只留下位於該浮置閑極 覆蓋浮置閑極。以罩幕m2先,於基底上形成罩幕層 之後移除轉層。a 4轉,雜部分蚊介電層。 ▲方體的製 包括於基底上形成層間絕緣$第、電插塞之步驟前,更 造方ί照實施例所述之非揮發性記憶體的製 Hi 介電層覆蓋住浮置開極的-部份。 造方法佳實施例所述之非揮發性記憶體的製 t依介ί層覆蓋住整個浮置開極。 ,止方:於二日的較佳貫施例所述之非揮發性記憶體的製 區之第二輪歧第==獅與第三辦及極 造方ί照ίΓ月Γ交佳實施例所述之非揮發性記憶體的製 ^法上4之特定介電層之㈣包括氧切或是氮氧化 在浮 介電層。第—導電插塞可 11 1353672 095006(1) 21483twf.doc/n 、第三導電插塞在同-個製程中製作出來。 Π以在不改變—般互補式金氧半導體製程的情況下製 作出非揮發性記憶體。而且,笛 接形成在浮置閑極上之間間介電第声―上導電插塞(抹除閉極)直 Μ ΜΜ 電層上’並不會增加額外的 二間’而可以增加半導體元件的集積度。 為讓本發明之上述和其他目的^ =下了文特舉較佳實施例’並配合所附圖t:;:說4 【實施方式】 首先,說明本發明之非揮發性記憶體。 ㈣會Ξ為本發明之—較佳實施例之非揮發性記 == 二1B所綠示為圖1A中沿A-A,線的剖面 圖圖c所、,.曰不為圖1A中沿B_B,線的剖面圖。 是設至圖1C ’本發明之非揮發性記憶體例如 〇X :土- 上。基底100例如是矽基底。在基底100 中例如是設置有井區102。而且, & 置有隔離結構104,以定義出主土 Λ “中例如是設 例如是淺溝渠隔離結構或者場氧化^。隔離-構1〇4 本發明之非揮發性記憶體例L是由浮置閘電曰f 108 120 〇 子置閘電晶體1G8例如是設置於基底⑽上。浮 電,權例如是由穿隧介電層11〇、浮置閘極ιΐ2、源二 =極區U6、源極/沒極區U8、特定介電層 電 塞124所構成。 等4播 12 1353672 095006(1) 21483twf.doc/n 動區==:==⑽上’並橫跨過主 上,閘㈣2之材;隔離結㈣ 穿随介電層110例如是 夕 1〇〇之間。穿随介電層UG之材112與基底 在浮置閘極112與穿隨介電;n 疋氧匕石夕。而且, 隙壁m。間隙壁114==,也可_有間The non-volatile memory of the preferred embodiment of the invention, the second conductive plug and the third conductive plug, the external companion memory are electrically connected to the first source 8 1353672 095006, respectively. 2l483twf.doc/n pole/nopole zone and third source/bungee zone. The non-volatile memory of the invention is made by the first conductive plug which is disposed on the floating gate. Moreover, '(4) a specific dielectric layer (self-scale metal-wet resistive layer or resistive protective oxide layer) acts as a dielectric layer between the inter-gate dielectric between the floating interpole and the first conductive interpole, so it can be left unchanged - (: : Producing non-volatile notes in the case of rolling semiconductors, (4). When the voltage is applied to the first conductive plug (wiping the gate), 'just two:' and read the first conductive plug in the floating track. The plug can be erased by smearing the electrons from the floating gate through the specific dielectric layer with the effect barrier or against the protective oxide layer. By setting the eraser to the body and repeating the stylization and wiping it, the right-handed conductive plug (wiping the gate) is set to make the first-wheel plug (erasing the closed pole) and: the area can be reduced, That is to say, it can be reduced to wear the window, and the lighter one can speed up the erasing when erasing the memory. / The present invention proposes a non-volatile memory manufacturing region "interelectrode, through dielectric layer, first-source/drainage f multi-divided portion of the dielectric layer n remaining 1 after. A first conductive plug is formed on the dielectric layer, which is 9 1353672 095006 (1) 21483 twf.doc / n a conductive plug as an erase gate. 造方 = "The non-volatile memory system described in the example /, towel to remove part of the specific dielectric layer, leaving only the bit, the specific dielectric layer steps are as follows. First, ^ two; float = pole. Then, with the mask layer as a mask, the portion St"" is removed. Thereafter, the mask layer is removed. The non-volatile memory method according to the preferred embodiment of the present invention is specific to Before the step of forming the first conductive plug on the dielectric layer, the interlayer insulating layer is further formed on the substrate. The specific dielectric layer is formed according to the method of non-volatile memory. Covering a portion of the floating gate. According to the method of non-volatile memory of the preferred embodiment of the present invention, the specific dielectric layer covers the entire floating gate. The method for manufacturing a non-volatile memory according to a preferred embodiment of the present invention, in the step of forming a first conductive plug on a specific dielectric layer, further comprising electrically connecting the first source/汲a first conductive plug and a third conductive plug of the polar region and the second source/drain region. A method for fabricating a non-volatile memory according to a preferred embodiment of the present invention The material comprises cerium oxide or oxynitride eve. According to a preferred embodiment of the invention The edge-making method of the hair memory further includes forming a selection gate transistor on the substrate, and selecting the gate transistor to connect the floating gate transistor in series, and selecting the gate transistor has a selection gate, a dielectric layer, and a third source /汲polar region and the second source/drain region. 丄095006(1) 21483twf.doc/n 造方: The steps of the specific dielectric layer on the basis of the volatile memory are as follows; The floating idler covers the floating idle pole. The mask m2 is first formed after the mask layer is formed on the substrate. A 4 turns, a part of the mosquito dielectric layer. ▲ The square body is formed on the substrate. Before the step of forming the interlayer insulation $ and the electrical plug, the Hi dielectric layer of the non-volatile memory described in the embodiment is covered to cover the portion of the floating open electrode. The non-volatile memory layer of the non-volatile memory covers the entire floating opening. The second side of the non-volatile memory is described in the preferred embodiment of the second day.轮之第== 狮与第三办和极造方 ί照 Γ Γ Γ Γ 佳 实施 实施 实施 实施 实施 实施 实施 实施 实施 非 非 非 非 非 非 非(4) of the dielectric layer includes oxygen cutting or oxynitridation in the floating dielectric layer. The first conductive plug can be 11 1353672 095006 (1) 21483 twf.doc/n, and the third conductive plug is fabricated in the same process.制作To make non-volatile memory without changing the complementary MOS process. Moreover, the flute is formed between the floating idler and the first acoustic-upper plug (wiping off) The above-mentioned and other objects of the present invention are added to the preferred embodiment of the present invention. Figure 4: Embodiments [Embodiment] First, the non-volatile memory of the present invention will be described. (4) The non-volatile memory of the present invention - the preferred embodiment is shown as 1A, along the line AA, the cross-sectional view of the line c, 曰 is not a cross-sectional view taken along line B_B in Fig. 1A. It is set to the non-volatile memory of the present invention such as 〇X:土-. The substrate 100 is, for example, a crucible substrate. A well region 102 is provided, for example, in the substrate 100. Moreover, the isolation structure 104 is provided to define the main soil "for example, for example, a shallow trench isolation structure or field oxidation ^. Isolation - structure 1 〇 4 The non-volatile memory of the invention is L The gate electrode 1G8 is, for example, disposed on the substrate (10). The floating power is, for example, a tunneling dielectric layer 11〇, a floating gate ιΐ2, a source second=polar region U6, Source/no-pole area U8, specific dielectric layer plug 124. Etc. 4 broadcast 12 1353672 095006(1) 21483twf.doc/n moving area ==:==(10) on 'and across the main gate (4) The material of 2; the isolation junction (4) The dielectric layer 110 is, for example, between the first and second layers. The material 112 and the substrate of the dielectric layer UG are in the floating gate 112 and the dielectric layer; n oxonite Even more. Moreover, the gap wall m. the gap wall 114 ==, also _ there is

源極區116與=::== m㈣1述「基底100中。而且’源極/沒極區 116與源極/及極區118是位於主動區觸中。 特定介電層m例如設置於浮置問極m上。特定介 電層120可以覆蓋住浮置閘極112的一部份也可以覆罢 住整個洋置閘極m。舉例來說,特定介電層m可以二 设置在導電插塞m與浮置閘極⑴之間。特定介電層⑽ 之材質例如是氧化矽或氮氧化矽。The source region 116 and the =::== m (four) are described in the "substrate 100." and the source/nopole region 116 and the source/polar region 118 are located in the active region. The specific dielectric layer m is, for example, floating. The specific dielectric layer 120 can cover a portion of the floating gate 112 or cover the entire ocean gate m. For example, the specific dielectric layer m can be disposed in the conductive plug Between the plug m and the floating gate (1), the material of the specific dielectric layer (10) is, for example, ruthenium oxide or ruthenium oxynitride.

矽等 導電插塞124例如是設置於特定介電層12〇上。而且, 導電插塞12 4設置浮置閘極丨! 2 一端,且位於隔離結構刚 上方。在本發明中,導電插塞124是作為抹除閘極。導電 插塞124之材貝包括導體材料,例如是金屬材料、捧雜多 曰曰 此外,在源極/j:及極區116與源極/汲極區118上更設 置有導電插塞126與導電插塞128。導電插塞126與導電 插塞128分別電性連接源極/汲極區U6與源極/汲極區 Π8。導電插塞126與導電插塞128之材質包括導體材料, 13 1353672 095006(1) 21483twf.doc/n 例如是金屬材料、摻雜多晶矽等。導電插塞124、導電插 塞126與導電插塞128是在同一個製程中形成的。 而且,導電插塞124、導電插塞126與導電插塞128 例如是設置在層間絕緣層122中。層間絕緣層122之材質 例如是磷矽玻璃、硼磷矽玻璃等。 圖2A所繪示為本發明之另一較佳實施例之非揮發性 記憶體的上視圖。圖2B所繪示為圖2A中沿A_A,線的剖 面圖。圖2C所繪示為圖2A中沿B_B,線的剖面圖。。 Q請參照圖2Α至圖2C,本發明之非揮發性記憶體例如 疋设置於基底200上。基底200例如是矽基底。在基底2〇〇 中例如是設置有井區202。而且,在基底2〇〇中例如是設 置有隔離結構204,以定義出主動區2〇6。隔離結構2〇4 例如是淺溝渠隔離結構或者場氧化層。 非揮發性記憶體包括浮置閘電晶體208與選擇閘電晶 體210、特定介電層230、導電插塞232(抹除閘極)。浮置 閘電晶體208與選擇閘電晶體21〇例如是設置於基底2〇〇 上,且串聯連接串接在一起。 — 洋置閘電晶體208例如是由穿隧介電層212、浮置閘 極214、源極/汲極區218、源極/汲極區22〇所構成。 浮置閘極214例如是設置於基底2〇〇上,並橫跨過主 動區206,因此部分的浮置間極214會位於隔離結構2〇4 上。浮置閘極214之材質例如是掺雜多晶矽。 穿隧介電層212例如是設置於浮置閘極214與基底 2〇〇之間。穿隧介電層212之材質例如是氧化碎。而且, 1353672 095006(1) 21483twf.doc/n 在浮置閘極2H與穿随介電層m之側壁也可以設置有間 隙壁216。間隙壁216之材質例如是氧化珍或氮化石夕。 源極/汲極區218與源極/汲極區22〇例如是分別設置 於浮置閘極214兩側的基底2〇〇中。而且,源極/沒極區 218與源極/汲極區220是位於主動區2〇6中。 選擇閘電晶體210例如是由閘介電層222、選擇開極 224、源極/汲極區220、源極/汲極區228所構成。 選擇閘極224例如是設置於基底上,並橫跨過主 動區206。選擇閘極224之材質例如是推雜多晶石夕。 問介電層222例如是設置於選擇閘極η4與基底· 之間。閘介電層222之材質例如是氧化石夕。而且,在選擇 閘極224與閘介電層222之側壁也可以設置有間隙壁 226。間隙壁226之材質例如是氧化石夕或氮化矽。 源極/汲極區220與源極Λ及極區228例如是分別設置 於選擇閘極224兩側的基底中。而且,源極/汲極區 220與源極/没極區228是位於主動區206中。浮置閘電晶 體208與選擇閘電晶體21〇共用源極/沒極區—。 ,定介電層230例如是設置於浮置閘極214上。特定 二2 覆盍住洋置閘極214的一部份,並未覆蓋住 品206上之浮置閘極214。當然,特定介電層230 只設置在導電插塞232與浮置閘極214之間。特定 ”電層230之材質例如是氧切或是氮氧化石夕。 中明中’所謂的特定介電層23G是在邏輯製程 為自仃對準金屬魏物輯層(Sdf-Aligned Salicide 15 1353672 095006(]) 21483twf.doc/nThe conductive plug 124 is, for example, disposed on a specific dielectric layer 12A. Moreover, the conductive plug 12 4 sets the floating gate 丨! 2 One end and just above the isolation structure. In the present invention, the conductive plug 124 acts as an erase gate. The material of the conductive plug 124 includes a conductor material, such as a metal material, and a plurality of conductive plugs 126 are further disposed on the source/j: and the pole region 116 and the source/drain region 118. Conductive plug 128. The conductive plug 126 and the conductive plug 128 are electrically connected to the source/drain region U6 and the source/drain region Π8, respectively. The material of the conductive plug 126 and the conductive plug 128 includes a conductor material, and 13 1353672 095006(1) 21483 twf.doc/n is, for example, a metal material, a doped polysilicon or the like. Conductive plug 124, conductive plug 126 and conductive plug 128 are formed in the same process. Moreover, the conductive plug 124, the conductive plug 126, and the conductive plug 128 are disposed, for example, in the interlayer insulating layer 122. The material of the interlayer insulating layer 122 is, for example, phosphor bismuth glass, borophosphoquinone glass or the like. 2A is a top view of a non-volatile memory in accordance with another preferred embodiment of the present invention. Figure 2B is a cross-sectional view taken along line A-A of Figure 2A. 2C is a cross-sectional view taken along line B_B of FIG. 2A. . Q Referring to Fig. 2A to Fig. 2C, the non-volatile memory of the present invention, for example, is disposed on the substrate 200. The substrate 200 is, for example, a crucible substrate. A well region 202 is provided, for example, in the substrate 2A. Moreover, an isolation structure 204 is provided, for example, in the substrate 2 to define the active region 2〇6. The isolation structure 2〇4 is, for example, a shallow trench isolation structure or a field oxide layer. The non-volatile memory includes a floating gate transistor 208 and a selection gate transistor 210, a specific dielectric layer 230, and a conductive plug 232 (erasing gate). The floating gate transistor 208 and the selection gate transistor 21 are, for example, disposed on the substrate 2, and are connected in series in series. — The thyristor 208 is formed, for example, by a tunneling dielectric layer 212, a floating gate 214, a source/drain region 218, and a source/drain region 22 。. The floating gate 214 is disposed, for example, on the substrate 2 and over the active region 206 such that a portion of the floating interpole 214 is located on the isolation structure 2〇4. The material of the floating gate 214 is, for example, doped polysilicon. The tunneling dielectric layer 212 is disposed, for example, between the floating gate 214 and the substrate 2A. The material of the tunneling dielectric layer 212 is, for example, oxidized ash. Further, 1353672 095006(1) 21483twf.doc/n may also be provided with a gap wall 216 on the sidewalls of the floating gate 2H and the dielectric layer m. The material of the spacer 216 is, for example, oxidized or nitrided. The source/drain regions 218 and the source/drain regions 22 are, for example, disposed in the substrate 2's on both sides of the floating gate 214, respectively. Moreover, the source/nomogram region 218 and the source/drain region 220 are located in the active region 2〇6. The gate transistor 210 is formed, for example, by a gate dielectric layer 222, a selective opening 224, a source/drain region 220, and a source/drain region 228. The select gate 224 is, for example, disposed on the substrate and spans the active region 206. The material of the gate 224 is selected, for example, to push the polycrystalline spine. The dielectric layer 222 is disposed, for example, between the selection gate η4 and the substrate. The material of the gate dielectric layer 222 is, for example, oxidized oxide. Further, a spacer 226 may be provided in the sidewalls of the gate 224 and the gate dielectric layer 222. The material of the spacer 226 is, for example, oxidized oxide or tantalum nitride. The source/drain regions 220 and the source and drain regions 228 are, for example, disposed in the substrates on both sides of the select gate 224, respectively. Moreover, source/drain regions 220 and source/no-polar regions 228 are located in active region 206. The floating gate transistor 208 shares the source/no-polar region with the selection gate transistor 21〇. The dielectric layer 230 is disposed, for example, on the floating gate 214. The specific portion 2 covers a portion of the ocean gate 214 and does not cover the floating gate 214 of the product 206. Of course, the specific dielectric layer 230 is disposed only between the conductive plug 232 and the floating gate 214. The material of the specific "electric layer 230" is, for example, oxygen cutting or arsenic oxynitride. The so-called specific dielectric layer 23G in the middle of the logic is a self-aligned metal wafer layer in the logic process (Sdf-Aligned Salicide 15 1353672). 095006(]) 21483twf.doc/n

Block Oxide’SAB)的膜層。㈣’在半導體元件 晶圓通常可區分為主元件區與周邊電路區,其中位於主 L中之开.杜你丨念紅士 n' 件區中之元件例如包括有記憶體元件、靜電放; (mectro-S她Discharge,ESD)保護電路等而位於周 路區中之兀件例如是邏輯元件等。由於仇於主元件區中= 兀件與周邊電路d巾之元件的電性需財同。因此在元 形成之後通常會進行石夕化(驗ide)製程,以於閉極層 極/沒極區上形成-層金屬魏物,從而降低元件之阻值。 然而,在進行上述之魏製程時,需藉由—膜層(特定介電 層23〇)將不需形成金屬石夕化物的部分覆蓋起來以避免石夕 化反應之發生。由於本·接將—般邏輯製程巾所使用的 特定介電層230(自行鱗金財化物吨層(Seif Aii㈣ Salidde Bbclc Oxide ’ SAB)或抵抗保護氧化層)作為浮置閘 極與導電插塞(抹除閘極)之間的閘間介電層。因此本發明 的非揮發性記憶體可以在不改變—般互補式金氧半導體製 程的情況下f作出來’且不會增加額外的空間,而可以辦 加記憶體元件的集積度。 導電插塞232例如是設置於特定介電層230上。而且, 導電插塞232設置浮置閘極214 一端,且位於隔離結構2〇4 上方。在本發明中,導電插塞232是作為抹除問極。 此外,在源極/汲極區218與源極/汲極區228上更設 置有導電插塞234與導電插塞236。導電插塞234與導電 插塞236分別電性連接源極/汲極區218與源極/汲極區 228。導電插塞234與導電插塞236之材質包括導體材料, 16 丄^3672 095006(1) 21483twf.d〇c/n 例如疋金屬材料、摻雜多晶石夕等。導電插塞232、導電插 塞234與導電插塞236是在同一個製程_形成的。 而且,導電插塞232、導電插塞234與導電插塞236 例如是設置在層間絕緣層238中。層間絕緣層238之材質 例如是填石夕玻璃、硼填石夕玻璃等。 此外,如圖2A所示,在基底200中也可以設置井區 拉出區240。此井區拉出區24〇連接井區2〇2。在井區拉出 區240上例如設置有導電插塞242。此導電插塞242電性 連接井區202。 圖3A所繪示為本發明之又一較佳實施例之非揮發性 記憶體的上視圖。圖3B所繪示為圖3A中沿A_A,線的剖 面圖。圖3C所繪示為圖3A中沿B-B,線的剖面圖。在圖 3A至圖3C中’構件與圖2A至圖2C相同者給予相同的標 號,並省略其詳細說明。 請參照圖3A至圖3C,本發明之非揮發性記憶體例如 疋ό又置於基底200上。基底200例如是^夕基底。在基底2〇〇 中例如是設置有井區202。而且,在基底2〇〇中例如是設 置有隔離結構204,以定義出主動區206。 非揮發性記憶體包括浮置閘電晶體2〇8與選擇閘電晶 體210、特定介電層230a'導電插塞232(抹除閘極)。浮置 閘電晶體208與選擇閘電晶體21〇例如是設置於基底2〇〇 上,且串聯連接串接在一起。 浮置閘電晶體208例如是由穿隧介電層212、浮置閘 極214、源極/汲極區218、源極/汲極區22〇所構成。在浮 17 1353672 095006(1) 2l483twf.doc/n 置閘極214與穿隧介電岸 -1$. ^ Θ ^ 之側土例如設置有間隙壁 216。選擇間電晶體21〇例如 224、源極/汲極區22〇 / 222選擇間極 艰極及極區228所構成。Α嘴搭 閘極224與閘介電層22 厅構底在選擇 Β 2之側壁也可以設置有間隙壁 226。/予置閘電晶體2〇8虚 極區22〇。 /〜擇閘$日日體210共用源極/汲 八币介電層邊例如是設置於浮置間極214上。特定The film layer of Block Oxide'SAB). (4) 'In the semiconductor component wafer, the main component area and the peripheral circuit area are generally distinguishable, and the element in the main L is opened. The components in the 丨 红 红 ' ' ' ' 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 、 (mectro-S her Discharge, ESD) The protection circuit and the like are located in the road area, for example, logic elements and the like. Because the elements in the main component area are the same as the electrical components of the peripheral circuit. Therefore, after the formation of the element, the eve process is usually performed to form a layer of metal material on the closed/pole region, thereby reducing the resistance of the element. However, in the above-mentioned Wei process, it is necessary to cover the portion which does not need to form the metal ruthenium by the film layer (specific dielectric layer 23 〇) to avoid the occurrence of the lithospheric reaction. The specific dielectric layer 230 (Seif Aii (S) Salidde Bbclc Oxide ' SAB) or the protective oxide layer used as the floating gate and the conductive plug is used as the general logic processing towel. The dielectric layer between the gates (wiping the gate). Therefore, the non-volatile memory of the present invention can be made without changing the complementary MOS process without adding extra space, and the degree of accumulation of the memory elements can be increased. The conductive plug 232 is disposed, for example, on a specific dielectric layer 230. Moreover, the conductive plug 232 is disposed at one end of the floating gate 214 and above the isolation structure 2〇4. In the present invention, the conductive plug 232 is used as an eraser. In addition, a conductive plug 234 and a conductive plug 236 are further disposed on the source/drain region 218 and the source/drain region 228. The conductive plug 234 and the conductive plug 236 are electrically connected to the source/drain region 218 and the source/drain region 228, respectively. The material of the conductive plug 234 and the conductive plug 236 includes a conductor material, 16 丄 ^ 3672 095006 (1) 21483 twf.d 〇 c / n such as a bismuth metal material, doped polycrystalline stone, and the like. The conductive plug 232, the conductive plug 234 and the conductive plug 236 are formed in the same process. Moreover, the conductive plug 232, the conductive plug 234, and the conductive plug 236 are disposed, for example, in the interlayer insulating layer 238. The material of the interlayer insulating layer 238 is, for example, a stone-filled glass or a boron-filled glass. Further, as shown in Fig. 2A, a well zone pull-out zone 240 may also be provided in the substrate 200. The well area pull-out area 24〇 connects the well area 2〇2. A conductive plug 242 is provided, for example, on the well draw-out area 240. The conductive plug 242 is electrically connected to the well region 202. 3A is a top view of a non-volatile memory in accordance with still another preferred embodiment of the present invention. Figure 3B is a cross-sectional view taken along line A-A of Figure 3A. 3C is a cross-sectional view taken along line B-B of FIG. 3A. The same components as those in Figs. 2A to 2C are given the same reference numerals in Figs. 3A to 3C, and detailed description thereof will be omitted. Referring to Figures 3A through 3C, the non-volatile memory of the present invention, e.g., tantalum, is placed on substrate 200. The substrate 200 is, for example, a base substrate. A well region 202 is provided, for example, in the substrate 2A. Moreover, an isolation structure 204 is provided, for example, in the substrate 2 to define the active region 206. The non-volatile memory includes a floating gate transistor 2〇8 and a selection gate transistor 210, and a specific dielectric layer 230a' conductive plug 232 (erasing gate). The floating gate transistor 208 and the selection gate transistor 21 are, for example, disposed on the substrate 2, and are connected in series in series. The floating gate transistor 208 is formed, for example, by a tunneling dielectric layer 212, a floating gate 214, a source/drain region 218, and a source/drain region 22A. In the floating 17 1353672 095006 (1) 2l483twf.doc / n the gate 214 and the tunnel dielectric wall -1$. ^ Θ ^ side soil, for example, is provided with a spacer 216. The inter-connector transistor 21, for example, 224, and the source/drain region 22 〇 / 222 are selected to select the interpolar pole and the pole region 228. The gate 224 and the gate dielectric layer 22 may also be provided with a spacer 226 on the side wall of the selection Β 2 . / Pre-gate transistor 2〇8 virtual region 22〇. /~ Selecting the gate $Japanese body 210 sharing source / 汲 The eight-coin dielectric layer side is, for example, disposed on the floating interpole 214. specific

” Ί隱覆蓋住整個浮置閘極214。特定介電層潘 之材質例如是氧化矽或氮氧化矽等。 曰 導電插塞232a例如是設置於特定介電層23〇a上。而 且,導電插塞加設置浮置閘極叫的末端,且位於隔離 結構2〇4上方。在本發明中,導電插塞232是作為抹除閉 極。由於導電插塞232a是設置於浮置閘極214的末端,因 此洋置閘極214與導電插塞现之間所央的面積可以縮 小,亦即可以縮小穿隧窗口。在抹除此記憶體時,即可以The cover layer covers the entire floating gate 214. The material of the specific dielectric layer is, for example, tantalum oxide or tantalum oxynitride, etc. The conductive plug 232a is disposed, for example, on a specific dielectric layer 23〇a. The plug is provided with the end of the floating gate and is located above the isolation structure 2〇4. In the present invention, the conductive plug 232 is used as the erased closed pole. Since the conductive plug 232a is disposed on the floating gate 214 Therefore, the area between the central gate 214 and the conductive plug can be reduced, that is, the tunneling window can be reduced. When the memory is erased,

加快抹除速度。當然,導電插塞232a也可以設置於特定介 電層230a上的任意位置。 此外,在源極/汲極區218與源極/汲極區228上更設 置有導電插塞234與導電插塞236。導電插塞234與導電 插塞236分別電性連接源極/汲極區218與源極/汲極區 228。而且,導電插塞232、導電插塞234與導電插塞236 例如是設置在層間絕緣層238中。 此外,如圖3A所示’在基底200中也可以設置井區 拉出區240。此井區拉出區240連接井區202。在井區拉出 1353672 095006(1) 21483twf.doc/n 區24〇上例如。又置有導電插塞sc。此導電插塞⑽電性 連接連接井區202。 本發明之非揮發性記憶體,由於在浮置間極上之閑間 介電層上設置導電插塞’此導電插塞可以作為抹除問極。 〃使用特疋;i電層(自行對準金屬_化物阻擋層或抵抗 保護氧化層)作為浮置閘極與導電插塞(抹除間極)之間的 閘間”電層’因此可以在不改變一般互補式金氧半導體製 • 程的情況下製作出非揮發性記憶體。 而且,當施加電壓於導電插塞(抹除閘極)時,就能夠 齡至浮置閑極’並且在浮置與導電插塞(抹除間極 之間形成足夠大的電壓差,而產生F_N穿隨效應,使電子 從浮置f雜㈣特定介電層(自行料金屬魏物阻擒層 或抵抗保護氧化層)而導出至導電插塞(抹除閘極),而可以 抹除此記憶體。藉由設置抹除閘極’即可以對本發明之非 揮發性記憶體重複地進行程式化及抹除操作。 此外,若導電插塞(抹除閘極)設置浮置閘極一末端, • 使得導電插塞(抹除閘極)與浮置閘極之間所夾的面積可以 縮小,亦即可以縮小穿隧窗口。在抹除此記憶體時,、即可 以加快抹除速度。 接著,說明本發明之非揮發性記憶體的製造方法。 圖4A至圖4D所繪示為本發明之非揮發性記憶體的製 造流程剖面圖。圖5A至圖5D所繪示為本發明之非捏二 記憶體的製造流程剖面圖。圖4A至圖4〇為對應圖= A-A’線的剖面;圖5A至圖5D為對應圖3A中B_B,線的剖 1353672 095006(1) 2l483twf.doc/n 面。 凊同時參照圖4A及圖5A,首先提供基底3〇〇。基底 3〇〇例如是矽基底。於此基底3〇〇中形成井區3〇2。井區 302之形成方法例如是離子植入法。接著,於 中 形成隔,結構綱。隔離結構綱例如是淺溝^隔離結構。Speed up the erasure. Of course, the conductive plug 232a can also be disposed at any position on the specific dielectric layer 230a. In addition, a conductive plug 234 and a conductive plug 236 are further disposed on the source/drain region 218 and the source/drain region 228. The conductive plug 234 and the conductive plug 236 are electrically connected to the source/drain region 218 and the source/drain region 228, respectively. Moreover, the conductive plug 232, the conductive plug 234, and the conductive plug 236 are disposed, for example, in the interlayer insulating layer 238. Further, a well zone pull-out zone 240 may also be provided in the substrate 200 as shown in Fig. 3A. This well zone pull-out zone 240 connects the well zone 202. Pull out in the well area 1353672 095006 (1) 21483twf.doc / n area 24 〇 for example. A conductive plug sc is also placed. The conductive plug (10) is electrically connected to the well region 202. In the non-volatile memory of the present invention, a conductive plug is provided on the free dielectric layer on the floating interpole. This conductive plug can serve as an eraser. 〃Using special features; the i-electrode layer (self-aligning the metal-block barrier or resisting the protective oxide layer) acts as the "electrical layer" between the floating gate and the conductive plug (wiping the interpole). Non-volatile memory is produced without changing the general complementary MOS process. Moreover, when a voltage is applied to the conductive plug (erasing the gate), it can reach the floating idler' and The floating and conductive plugs (the voltage difference formed between the erased electrodes is formed, and the F_N wear-through effect is generated, so that the electrons are discharged from the floating (f) specific dielectric layer (the metal-containing material barrier layer or the protective oxidation resistance) The layer is exported to the conductive plug (erasing the gate), and the memory can be erased. By setting the erase gate, the non-volatile memory of the present invention can be repeatedly programmed and erased. In addition, if the conductive plug (wiping gate) is provided with one end of the floating gate, • the area between the conductive plug (wiping gate) and the floating gate can be reduced, that is, it can be reduced Tunneling window. When erasing this memory, you can add Next, the manufacturing method of the non-volatile memory of the present invention will be described. Figure 4A to Figure 4D are cross-sectional views showing the manufacturing process of the non-volatile memory of the present invention, which is illustrated in Figures 5A to 5D. A cross-sectional view of the manufacturing process of the non-pinched memory of the present invention. Fig. 4A to Fig. 4A are cross sections corresponding to the line A-A'; Fig. 5A to Fig. 5D are corresponding to B_B in Fig. 3A, and the line is divided into 1353672 095006 (1) 2l483twf.doc/n face. Referring to Figures 4A and 5A simultaneously, a substrate 3 is first provided. The substrate 3 is, for example, a germanium substrate. A well region 3〇2 is formed in the substrate 3〇〇. The formation method of the region 302 is, for example, an ion implantation method. Next, a spacer is formed in the structure, and the isolation structure is, for example, a shallow trench isolation structure.

接著,於基底300上形成閘極結構3〇6a與閘極結構 〇6b閘極結構3〇如是由穿隨介電層3〇ga與浮置閘極31〇a 斤構成閘極結構306b是由閘介電層3〇8b與選擇閘極 =斤構成。閘極結構3〇6a與閘極結構3〇6b的形成方法 =如疋依序基底3GG上形成—層介電層與—層導體材料層 後’進行微影_製程,圖案化導體㈣ 成的。穿财電層施與·電層遍之材f = Z 化矽。當然,穿隧介電層3〇8a與閘介電層3〇扑之材質與 厚^可為相同也可為不同。浮置閘極31〇a與選擇閘極3i〇b 2質例如是摻雜多糾’其形成方法例如是化學氣象沈Next, a gate structure 3〇6a and a gate structure 〇6b gate structure 3 are formed on the substrate 300. For example, the gate structure 306b is formed by the dielectric layer 3〇ga and the floating gate 31〇. The gate dielectric layer 3〇8b and the selected gate=jin are formed. The method for forming the gate structure 3〇6a and the gate structure 3〇6b=such as the formation of a dielectric layer and a layer of a conductor material layer on the substrate 3GG, followed by a lithography process, a patterned conductor (4) . Wear the financial layer and the electric layer of the material f = Z 矽. Of course, the material and thickness of the tunneling dielectric layer 3〇8a and the gate dielectric layer 3 may be the same or different. The floating gate 31〇a and the selective gate 3i〇b 2 are, for example, doped and multi-corrected, and the formation method thereof is, for example, chemical meteorology

凊同時參照圖4B及圖SB,進行摻質植入步驟,而於 土氏300中形成淡摻雜區312&、31沘、3i2c。摻牛 驟例如是採用離子植入法將掺質植入基底細中 ( =極結構306a與閘極結構3_的側壁形間、 間隙壁314a、314b之材質例如是氧化石夕ί 氮氧化石夕等。間隙壁314a、314b之形成方如是 以化學氣相沈積法形成—層絕緣材料層後,利 '钱刻移除部分絕緣材料層㈣成之。 、° 20 1353672 095006(1) 2l483twf.doc/n 然後’以具有間隙壁314a、314b的閘極結構3〇6a、 306b為罩幕,進行摻質植入步驟,而於基底3〇〇申形成濃 摻雜區316a、316b、316c。摻質植入步驟例如是採用離子 植入法將摻質植入基底300中。淡摻雜區312a與濃摻雜區 316a構成源極/汲極區318a;淡摻雜區312b與濃摻雜區 316b構成源極/汲極區318b ;淡摻雜區312c與濃摻雜區 316c構成源極/汲極區318(^閘極結構3〇如、源極/汲極區 318a與源極/汲極區318b構成浮置閘電晶體。閘極姓構 3〇6b、源極/及極區318b與源極/沒極區3脱構成選擇閉 電晶體。 —入Ϊ Γ參照圖4C及圖5C,於基底遍上形成一層特 ^電層320。此特定介電層32〇例如是一般的邏 =乍為自行對準金屬魏物阻擋層阶譲卿d触娜 xide,SAB)或抵抗保護氧化層的膜 電層320是在自行對準石夕化製程中,用^ =Referring to Fig. 4B and Fig. SB, a dopant implantation step is performed to form lightly doped regions 312 & 31, 3i2c in the T. For example, the doping is implanted into the base of the substrate by ion implantation (the material of the sidewall structure of the gate structure 306a and the gate structure 3_, and the material of the spacers 314a, 314b is, for example, oxidized stone. Etc. The formation of the spacers 314a, 314b is formed by chemical vapor deposition, after the layer of insulating material is removed, and the portion of the insulating material is removed (4). ° 20 1353672 095006 (1) 2l483twf. Doc/n then 'with the gate structures 3〇6a, 306b having the spacers 314a, 314b as masks, the dopant implantation step is performed, and the heavily doped regions 316a, 316b, 316c are formed on the substrate 3. The dopant implantation step is, for example, implanting a dopant into the substrate 300 by ion implantation. The lightly doped region 312a and the heavily doped region 316a constitute a source/drain region 318a; the lightly doped region 312b is heavily doped The region 316b constitutes the source/drain region 318b; the lightly doped region 312c and the heavily doped region 316c constitute the source/drain region 318 (^ gate structure 3, source/drain region 318a and source/ The bungee region 318b constitutes a floating gate transistor. The gate electrode structure 3〇6b, the source/polar region 318b and the source/drain region 3 are decoupled to form a closed cell. Referring to FIG. 4C and FIG. 5C, a layer of electrical layer 320 is formed on the substrate. The specific dielectric layer 32 is, for example, a general logic layer 自行 self-aligned metal barrier layer. The crystal layer 320 of the anti-oxidation layer is in the self-alignment process, using ^ =

=:分的!層,以避切化反應之;生= ^ ί “二5與避輯製程中的自行對準金屬碎化物阻擋 的情況下製作出本發明之非揮呈 32。之材質例如是氧化石鳩=就體。特-介電層 然後於基底300上形成—屏罢莖 覆蓋住閘極結構3G6a上的介電;罩幕層322 例如是光阻材料s 0。罩幕層322之材質 材抖罩幕層322之形成方法例如是先於基底 21 1353672 095006(1) 21483twf.doc/n 300上以旋轉塗佈法塗佈一層光阻材料然後進行微^制 程而形成之。當然’罩幕層322之材質也可以是其他材 清參照圖4D及圖5D,以罩幕層322為罩幕,移 分介電層320’而只留下位於閘極結構3嶋上的介 320二移除部分介電層32。之方法包括濕式钱刻法,例二 以氫氟酸作為蝕刻劑。然後,移除罩幕層322。 然後,於基底300上形成一層層間絕緣層324。層間 絕緣層324之材質例如是磷矽玻璃、硼磷矽玻璃等。 於層間絕緣層324中形成導電插塞326、328、33〇。 =電插塞328解電插塞33〇分別電性連接源極/汲極區 318a與源極/及極區通。導電插塞326位於浮置問極施 ^方’並連接介電層32〇a。導電插塞326是作為抹除問極。 導電插塞326、328、330的形成步驟如下。首先,圖案化 層間絕緣層324而形成插塞開σ,插塞開口會暴露出介電 層320a、源極/汲極區318a與源極/汲極區318匕。之後,於 插塞開口中填入導電材料而形成之。 在本發明之非揮發性記憶體的製造方法中,由於在浮 ^閘極上形成導電錄’赠為驗陳。,以特定 ”電層(自行對準金屬石夕化物阻擔層或抵抗保護氧化層)作 為浮置閘極與導電插塞(抹除閘極)之間關間介電層,因 此可以在不改變—般互補式錢半導難程的情況下製作 出軍發性記㈣^且,導電插塞(抹除閘極)直接設置 在浮置閘極上之閘間介電層上,並不會增加額外的空間, 而可以增加半導體元件的集積度。 22 1353672 095006(1) 21483twf.doc/n 綜上所述,在本制之转雜記 由於在浮置閘極上之閉間介電層上^ 方法 導電插塞可以作騎除_,且 導_塞’此 對準金屬石夕化物阻擔層或抵抗保護氧化Hi電層番(自行 :,曰曰體的源崎極區之插塞在同一 出來。因此可以在不改變—般互補式金氧衣主 況下製作出鱗發性記憶體,且不會增加額=的^ 可以增加記憶體元件的集積度。 上間,而 雖然本發明已以較佳實施例揭露如上,铁 發明丄任何熟習此技藝者’在不脫離本發明之精二 =乾圍内’當可作些許之更動與潤飾,因此本發明之 範圍當視後附之申請專利範圍所界定者為 ,、* 【圖式簡單說明】 圖1A所繪示為本發明之一較 憶體的上視圖。 开俾1性5己 圖1Β所繪示為1Α中沿Α Α,線的剖面圖。 圖ic所繪示為圖1Α中沿Β_Β,線的剖面圖。 記憶為本發明之另—較佳實施例之非揮發性 圖2Β所繪示為圖2Α中沿Α_Α,線的剖面圖。 圖2C所繪示為圖2Α中沿Β_Β,線的剖面圖。 γ ^ t所繪7為本發明之又—較佳實關之非揮發性 έ己憶體的上視圖。 23 1353672 095006(1) 21483twf.doc/n 圖3B所繪示為圖3A中沿A_A,線的剖面圖。 圖3C所繪示為圖3A中沿B_B,線的剖面圖。 圖4A至圖4D所綠示為本發明之—較佳實施例之非揮 發性記憶體的製造流程剖面圖。 圖5A至圖5D所繪示為本發明之一較佳實施例之非揮 發性記憶體的製造流程剖面圖。 【主要元件符號說明】 100、200、300 :基底 102、202、302 :井區 104、204、304 :隔離結構 106、206 :主動區 108、208 :浮置閘電晶體 110、212、308a :穿隧介電層 112、214、310a :浮置閘極 114、216、226、314a、314b :間隙壁 116、118、218、220、228、318a、318b、318c :源極 / >及極區 120、230、230a、320、320a :特定介電層 122、238、324 :層間絕緣層 124、126、128、232、234、236、242、326、328、330 : 導電插塞 210:選擇閘電晶體 222、308b :閘介電層 224、310b :選擇閘極 24 1353672 095006(1) 21483twf.doc/n 240 :井區拉出區 306a、306b :閘極結構 312a、312b、312c :淡摻雜區 316a、316b、316c ··濃摻雜區 322 :罩幕層=: sub-! layer to avoid the shearing reaction; raw = ^ ί "2 5 and the self-aligned metal fragmentation in the avoidance process to make the non-volatile material of the present invention, for example It is an oxide stone 鸠 = in-body. The special-dielectric layer is then formed on the substrate 300 - the stem plate covers the dielectric on the gate structure 3G6a; the mask layer 322 is, for example, a photoresist material s 0. The mask layer 322 The method for forming the material shattering mask layer 322 is formed, for example, by applying a layer of photoresist material by spin coating on the substrate 21 1353672 095006 (1) 21483 twf.doc/n 300 and then performing a micro-process. The material of the mask layer 322 may also be other materials. Referring to FIG. 4D and FIG. 5D, the mask layer 322 is used as a mask to remove the dielectric layer 320' and leave only the dielectric 320 on the gate structure 3. A portion of the dielectric layer 32 is removed. The method includes wet etching, and hydrofluoric acid is used as an etchant. Then, the mask layer 322 is removed. Then, an interlayer insulating layer 324 is formed on the substrate 300. The material of the interlayer insulating layer 324 is, for example, phosphor bismuth glass, borophosphon glass or the like. Conductive is formed in the interlayer insulating layer 324. Plugs 326, 328, 33〇. = Electrical plug 328 The power plugs 33 are electrically connected to the source/drain regions 318a and the source/pole regions. The conductive plugs 326 are located at the floating poles. The dielectric layer 32a is connected to the dielectric layer 32A. The conductive plug 326 is used as a eraser. The steps of forming the conductive plugs 326, 328, 330 are as follows. First, the interlayer insulating layer 324 is patterned to form a plug opening σ. The plug opening exposes the dielectric layer 320a, the source/drain region 318a and the source/drain region 318A. Thereafter, the plug opening is filled with a conductive material to form it. In the method of manufacturing the memory, since the conductive recording is formed on the floating gate, the specific electrical layer (self-aligning the metallization resisting layer or resisting the protective oxide layer) is used as the floating gate. The dielectric layer is closed between the conductive plug (wiping the gate), so that the military can be made without changing the complementary sub-conductance (four) ^, and the conductive plug (wipe In addition to the gate) directly placed on the dielectric layer of the gate on the floating gate, does not add extra space, but can increase by half The degree of accumulation of conductor elements. 22 1353672 095006(1) 21483twf.doc/n In summary, in the case of the conversion of the system, due to the conductive plug on the closed dielectric layer on the floating gate, the method can be used for riding _, and 'This is aligned with the metal-shield resistive layer or resists the protection of the oxidized Hi-electric layer (self: the plug of the source-salt region of the corpus callosum is in the same out. Therefore, it can be changed without changing - the complementary galvanic coat The scaly memory is produced under the condition of the main condition, and the increase of the amount of the memory element can be increased without increasing the amount of the memory element. Although the present invention has been disclosed in the preferred embodiment as above, the iron invention is familiar with any of the above. The skilled artisan can make some changes and refinements without departing from the essence of the present invention. Therefore, the scope of the present invention is defined by the scope of the appended claims, and * [simplified description of the drawings 1A is a top view of a memory of the present invention. The opening 1 is shown in FIG. 1A as a cross-sectional view of the line along the line 。 。. Figure ic is shown in Figure 1 A cross-sectional view along the line Β Β 。. Memory is another non-volatile diagram of the preferred embodiment of the invention Β 2C is a cross-sectional view along the line Α_Α, Figure 2C is a cross-sectional view along the line Β_Β in Figure 2Α. Figure 7 is a further example of the invention. Figure 1B is a cross-sectional view taken along line A_A in Figure 3A. Figure 3C is taken along line B_B in Figure 3A. Figure 1B is a cross-sectional view taken along line A_A in Figure 3A. 4A to 4D are cross-sectional views showing a manufacturing process of a non-volatile memory according to a preferred embodiment of the present invention. Figs. 5A to 5D are diagrams showing a preferred embodiment of the present invention. Cross-sectional view of the manufacturing process of the non-volatile memory. [Main component symbol description] 100, 200, 300: substrate 102, 202, 302: well region 104, 204, 304: isolation structure 106, 206: active region 108, 208 : floating gate transistors 110, 212, 308a: tunneling dielectric layers 112, 214, 310a: floating gates 114, 216, 226, 314a, 314b: spacers 116, 118, 218, 220, 228, 318a , 318b, 318c: source / > and polar regions 120, 230, 230a, 320, 320a: specific dielectric layers 122, 238, 324: interlayer insulating layers 124, 126, 128, 232, 234, 2 36, 242, 326, 328, 330: conductive plug 210: select gate transistor 222, 308b: gate dielectric layer 224, 310b: select gate 24 1353672 095006 (1) 21483twf.doc / n 240: well area pull Outlet regions 306a, 306b: gate structures 312a, 312b, 312c: lightly doped regions 316a, 316b, 316c · concentrated doped regions 322: mask layer

2525

Claims (1)

100-9-27 十、申請專利範圍·· —— 1曰-種非揮發性記憶體㈣造方法,包括·· 浮置’ ΐ基底上已形成有—浮置閘電晶體,該 ,及極1置閉極、—穿隨介電層、—第一源極/ 及極E與一第二源極/汲極區; 於該基底上形成一特定介電層; 該特該=介電層,只留下位於該浮置閘極上的 導電==成-第-導電插塞,其中該第- 造方i如ϋ專利範料1項所述之非揮發性記憶體的製 置門極1~^於&除部分該特定介電層,只留下位於該浮 置閘極上的該狀介電層之步驟包括: 士形成一罩幕層覆蓋該浮置閘極; 移:該罩單幕,移除部分該特定介電層;以及 造方3法如申二:=第介i;:述:非揮發性議^ 驟前’更包括於該基底二導電插塞之步 造方==圍41,之非揮發性記憶體的製 5如申妹直^,丨-’丨電層復蓋住该洋置閘極的一部份。 造方法,二二:1項所述之非揮發性記憶體的製 L由、:ί,介電層覆蓋住整個該浮置問極。 °月利祀圍第1項所述之非揮發性記憶體的製 1353672 100-9-27 包括於該基底上形成-選擇閘電晶體,該選擇 閑電晶體串聯連接該浮置閘電晶體,該 = 一選擇閘極、一閘介電芦以乃一筐_、心评J电曰日篮包括 源極/沒極區。 “及L源極/祕區與該第二 造方法Λ 項舰之轉發性記憶體的製 〃中於移除部分該特定介電層, 置閘極上的該特定介電層之步驟包括:下位於i予 =ίίΐ开ί成一罩幕層覆蓋該浮置閘極; 乂忒罩幕層絲幕,歸部分 移除該罩幕層。 層,以及 8.如申請專利範圍第6 驟前,更=於該基底上形成—層間絕緣層w插基之步 造方法,非揮發性記憶體的製 10. 如申請專利範圍第予置間極的一部份。 製造方法,其中該特定八。項所述之非揮發性記憶體的 11. 如申W利範圍第電6層=整個該浮置閘極。 步驟中,Μ㈣成;场辆第—料插塞之 第三源極/汲極區之—第_連接衫—源極/沒極區與該 12·如申請專利範圍第T塞及"第三導電插塞。 製造方法,其中該特定介發性記憶體的 化矽等。 電層之材貝包括氧化矽或是氮氧 27100-9-27 X. Patent application scope · · —— 1曰- kinds of non-volatile memory (4) manufacturing methods, including · · Floating ' ΐ ΐ has formed on the substrate - floating gate transistor, the pole 1 a closed-pole, a dielectric layer, a first source/and a pole E and a second source/drain region; forming a specific dielectric layer on the substrate; the dielectric layer , leaving only the conductive == into-first conductive plug on the floating gate, wherein the first manufacturing side is a non-volatile memory forming gate 1 as described in Patent Item 1 The step of leaving the dielectric layer on the floating gate except for a portion of the specific dielectric layer includes: forming a mask layer covering the floating gate; shifting: the mask Curtain, remove part of the specific dielectric layer; and the method of making 3, such as Shen 2: = 介介 i;: said: before the non-volatile discussion, the step is further included in the step of the base two conductive plugs = = circumference 41, the non-volatile memory system 5 such as Shen Mei straight ^, 丨 - '丨 electric layer covers part of the ocean gate. Method 2, 2: The non-volatile memory of the item 1 is made up of: ί, and the dielectric layer covers the entire floating questioner. The non-volatile memory system 1353672 100-9-27 described in Item 1 of the above-mentioned item is included in the substrate to form a selective gate transistor, and the selective idle transistor is connected in series to the floating gate transistor. The = one choice gate, one gate dielectric reed is a basket _, heart evaluation J electric 曰 day basket including source / no pole area. "and the L source/secret area and the second method of manufacturing the transfer memory of the ship" to remove a portion of the specific dielectric layer, the step of placing the specific dielectric layer on the gate includes: Located at i y = ί ΐ ί 成 成 成 成 成 成 成 成 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 罩 ; ; 罩 ; Forming a method of forming an interlayer insulating layer w on the substrate, a method of forming a non-volatile memory, and a part of the intermediate portion of the patent application range. The manufacturing method, wherein the specific eight item 11. The non-volatile memory 11. If the W-range range is the sixth layer = the entire floating gate. In the step, the Μ(4) is formed; the third source/drain region of the field-first plug - _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ _ The material of the layer includes yttrium oxide or nitrogen oxide 27
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