US6153467A - Method of fabricating high density buried bit line flash EEPROM memory cell with a shallow trench floating gate - Google Patents
Method of fabricating high density buried bit line flash EEPROM memory cell with a shallow trench floating gate Download PDFInfo
- Publication number
- US6153467A US6153467A US09/271,736 US27173699A US6153467A US 6153467 A US6153467 A US 6153467A US 27173699 A US27173699 A US 27173699A US 6153467 A US6153467 A US 6153467A
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- oxide layer
- bit line
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 6
- 230000015654 memory Effects 0.000 title description 14
- 238000000034 method Methods 0.000 claims abstract description 57
- 230000008569 process Effects 0.000 claims abstract description 34
- 229910021420 polycrystalline silicon Inorganic materials 0.000 claims abstract description 32
- 229920005591 polysilicon Polymers 0.000 claims abstract description 30
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims abstract description 28
- 229910052710 silicon Inorganic materials 0.000 claims abstract description 28
- 239000010703 silicon Substances 0.000 claims abstract description 28
- 239000012535 impurity Substances 0.000 claims abstract description 16
- 150000004767 nitrides Chemical class 0.000 claims abstract description 12
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 12
- 239000000758 substrate Substances 0.000 claims abstract description 12
- 230000003647 oxidation Effects 0.000 claims abstract description 10
- 238000005530 etching Methods 0.000 claims abstract description 6
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims abstract description 5
- 229910052698 phosphorus Inorganic materials 0.000 claims abstract description 5
- 239000011574 phosphorus Substances 0.000 claims abstract description 5
- 239000011248 coating agent Substances 0.000 claims abstract description 3
- 238000000576 coating method Methods 0.000 claims abstract description 3
- 238000004518 low pressure chemical vapour deposition Methods 0.000 claims description 9
- 239000002019 doping agent Substances 0.000 claims description 4
- 238000011065 in-situ storage Methods 0.000 claims description 4
- 229910052785 arsenic Inorganic materials 0.000 claims description 3
- RQNWIZPPADIBDY-UHFFFAOYSA-N arsenic atom Chemical compound [As] RQNWIZPPADIBDY-UHFFFAOYSA-N 0.000 claims description 3
- 239000007943 implant Substances 0.000 claims description 3
- 229910021417 amorphous silicon Inorganic materials 0.000 claims description 2
- 238000001312 dry etching Methods 0.000 claims description 2
- 230000001590 oxidative effect Effects 0.000 claims 2
- 230000000694 effects Effects 0.000 abstract description 8
- 229920002120 photoresistant polymer Polymers 0.000 abstract description 3
- 229910052751 metal Inorganic materials 0.000 description 4
- 239000002184 metal Substances 0.000 description 4
- 230000008901 benefit Effects 0.000 description 3
- 238000001020 plasma etching Methods 0.000 description 3
- 238000005229 chemical vapour deposition Methods 0.000 description 2
- 238000000151 deposition Methods 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 230000036039 immunity Effects 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 239000004065 semiconductor Substances 0.000 description 2
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 description 2
- WKBOTKDWSSQWDR-UHFFFAOYSA-N Bromine atom Chemical compound [Br] WKBOTKDWSSQWDR-UHFFFAOYSA-N 0.000 description 1
- MYMOFIZGZYHOMD-UHFFFAOYSA-N Dioxygen Chemical compound O=O MYMOFIZGZYHOMD-UHFFFAOYSA-N 0.000 description 1
- JNCMHMUGTWEVOZ-UHFFFAOYSA-N F[CH]F Chemical compound F[CH]F JNCMHMUGTWEVOZ-UHFFFAOYSA-N 0.000 description 1
- XPDWGBQVDMORPB-UHFFFAOYSA-N Fluoroform Chemical compound FC(F)F XPDWGBQVDMORPB-UHFFFAOYSA-N 0.000 description 1
- 238000000342 Monte Carlo simulation Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- GDTBXPJZTBHREO-UHFFFAOYSA-N bromine Substances BrBr GDTBXPJZTBHREO-UHFFFAOYSA-N 0.000 description 1
- 229910052794 bromium Inorganic materials 0.000 description 1
- 239000003990 capacitor Substances 0.000 description 1
- 230000015556 catabolic process Effects 0.000 description 1
- 230000002860 competitive effect Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000008021 deposition Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 229910052760 oxygen Inorganic materials 0.000 description 1
- 239000001301 oxygen Substances 0.000 description 1
- 238000000059 patterning Methods 0.000 description 1
- 238000000623 plasma-assisted chemical vapour deposition Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- WQJQOUPTWCFRMM-UHFFFAOYSA-N tungsten disilicide Chemical compound [Si]#[W]#[Si] WQJQOUPTWCFRMM-UHFFFAOYSA-N 0.000 description 1
- 229910021342 tungsten silicide Inorganic materials 0.000 description 1
- 238000007740 vapor deposition Methods 0.000 description 1
Images
Classifications
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B69/00—Erasable-and-programmable ROM [EPROM] devices not provided for in groups H10B41/00 - H10B63/00, e.g. ultraviolet erasable-and-programmable ROM [UVEPROM] devices
-
- H—ELECTRICITY
- H10—SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
- H10B—ELECTRONIC MEMORY DEVICES
- H10B41/00—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates
- H10B41/30—Electrically erasable-and-programmable ROM [EEPROM] devices comprising floating gates characterised by the memory core region
Definitions
- the present invention relates to a semiconductor memory process, and more specifically, to a structure of high-density buried bit line flash EEPROM memory cell with a shallow trench-floating gate.
- the ONO 15/poly-Si 10 is then patterned in elongated strips across each segment. Subsequently, a self-aligned arsenic implant is applied to form bit lines 20. An oxidation process combined with the CMOS gate oxidation process is done to form a gate oxide and grow a bit line oxide. The process continues with doped polysilicon 25 and tungsten silicide 35 deposition. A self-aligned stack gate etch process is employed to define word line 25 and floating gate cell 40. The advantages of this array are reduction of drain turn-on induced punchthrough and the allowance of scaling of effective channel length to as low as 0.25 ⁇ m.
- a method of fabricating a buried bit line flash EEROM using a recessed silicon trench floating gate for suppressing the short channel effect comprises following steps. Firstly, an ultra-thin pad oxide layer about 2-20 nm in thickness and a conductive impurity, such as phosphorus with concentrations of about 5 ⁇ 10 19 -5 ⁇ 10 21 /cm 3 , doped polysilicon layer is successively formed on the silicon substrate.
- a high temperature oxidation process is performed to oxidize the polysilicon layer so as to form an oxide layer and to drive the conductive impurities through the pad oxide layer into the silicon layer.
- a dry etch is used to etch the unmask regions until the silicon substrate is slightly recessed to form shallow trenches of about 50-600 nm in depth.
- the photoresist is stripped, and a gate dielectric layer formed of a gate nitride or oxynitride of about 3-25 nm in thickness is formed on the resultant surfaces.
- the buried bit line also formed where the bit line is a conductive layer beneath the remnant pad oxide layer.
- a planarization process such as CMP is done to form a plain surface using the gate dielectric layer as an etching stopped layer.
- a stacked ONO layer of about 5-30 nm is then deposited as an interpoly dielectric layer.
- another n+ doped polysilicon layer is formed and patterned to act as word lines.
- FIG. 1 is a synoptic layout of an EPROM array (FIG. 1a), and (FIG. 1b) is a cross-sectional view of an EPROM array, in accordance with the prior art;
- FIG. 2. is a cross-sectional view of forming a conductive impurity doped polysilicon layer on the pad oxide layer, in accordance with the present invention
- FIG. 3. is a cross-sectional view of an oxide layer and a conductive layer formed, respectively, on and beneath the pad oxide layer after a oxidation process is implemented, in accordance with the present invention
- FIG. 4. is a cross-sectional view of patterning the oxide layer and the pad oxide layer into the silicon substrate to define a plurality of floating regions, in accordance with the present invention
- FIG. 5. is a cross-sectional view of forming a gate oxide layer, in accordance with the present invention.
- FIG. 6 is a cross-sectional view of refilling all trenches with n+ doped polysilicon or ⁇ -Si (FIG. 6a), and then performing a planarization process by a CMP process (FIG. 6b), in accordance with the present invention
- FIG. 7 is a cross-sectional view of forming a thin stacked ONO layer as an interpoly dielectric layer, in accordance with the present invention.
- FIG. 8. is a cross-sectional view of depositing second n+ polysilicon as word lines, in accordance with present invention.
- FIG. 9. is a top view of high density contactless flash memory with buried bit lines and shallow trench floating gates, in accordance with the present invention.
- an ultra-thin pad oxide layer 110 is formed using a CVD method or thermal grown method on a silicon substrate 100.
- the pad oxide 110 thickness is about 2-20 nm.
- a high concentration conductive impurity doped polysilicon layer 115 is deposited on the pad oxide 110.
- the doped polysilicon layer 115 is formed by an in-situ doped LPCVD process at a temperature of about 400-620° C. to about 10-100 nm in thickness.
- the doping method can also be achieved by another method such as a pocl doped or by ion implant.
- a phosphorus contains liquid (POCl 3 ) is utilized as a source, the vapor from the liquid sources react with oxygen to form dopant oxides on the polysilicon layer,
- the equation is as follows:
- the doping concentration is about 5 ⁇ 10 19 -5 ⁇ 10 21 /cm 3
- the thickness of polysilicon layer 115 is about 10-100 nm.
- a high temperature thermal-oxidation process is performed at temperatures of about 700-1150°C. to oxidize the polysilicon layer 115.
- an oxide layer 120 is formed, in the meantime the conductive impurities are driven through the pad oxide layer 110 into the underlying silicon substrate 100 to form a thin conductive layer 170.
- a patterned photoresist 140 is masked on the oxide layer 120 to define the floating gate regions, and then etching steps are performed.
- CF 4 /O 2 , SF 6 , CHF 3 may be used as an etchant to etching oxide layer 120 firstly, followed by the application of bromine-based chemistries consisting of CF 3 Br and HBr/NF 3 to recess the silicon in an anisotropic way.
- the resulting recessed silicon trenches have a depth of about 50-600 nm.
- a comparison of suppressing short channel effect between the planar MOSFET and the recessed channel MOSFET was investigated using both drift-diffusion and Monte Carlo simulation.
- the threshold voltage roll-off (e.g., threshold voltage roll-off increases the off current level and power dissipation) is clearly presented for the planar device, however, the recessed structure nearly keeps the same threshold voltage for all simulated channel lengths and for any gate oxide thickness. In addition, for the device shorter than 50 nm, only a slow increase of the threshold swing is obtained in the recessed MOSFET's device.
- an ultra-thin conformal gate dielectric layer 160 deposited on all surfaces is carried out to about 3-20 nm in thickness.
- the ultra-thin conformal gate dielectric layer 160 is a nitride layer 160, which can be prepared by a low pressure CVD (LPCVD) or ajet vapor deposition (JVD).
- LPCVD low pressure CVD
- JVD jet vapor deposition
- the ultra-thin nitride layer is made at room temperature by JVD and then a post-thermal anneal at 800°C. in N 2 ambient.
- the ultra-thin JVD nitride serves as gate dielectric has been shown to exhibit excellent electrical properties, for instance, the transistor exhibits competitive transconductance and drivability against conventional MOSFETs.
- a thermal oxidation in N 2 O/O 2 ambient is followed to oxidize the nitride layer so as to form an oxynitride layer 160.
- the oxynitride 160 can be used to recover the etching damage. This was reported in the reference by S. Y. Ueng et al. titled “Superior Damage-Immunity of Thin Oxides Thermally Grown on Reactive-Ion-Etched Silicon Surface in N 2 O Ambient", IEEE Trans. Electro Devices, ED-41, p. 850, 1994.
- the N 2 O-grown oxides can remedy the RIE-induced defects, and exhibit significantly stronger immunity to RIE-induced damage.
- the MOS capacitor (MOSC) with oxynitride as a gate dielectric layer shows a great improvement over those of MOSC with pure oxygen ambient grown dielectric in the leakage currents and breakage fields.
- an in-situ n-type conductive impurity (n+ doped) doped polysilicon layer or a doped amorphous silicon ( ⁇ -Si) layer 175 is deposited to refill the shallow trenches 150.
- the method such as a LPCVD or a PECVD can be used (operating at temperature about 400-550°C. or 250-400°C., respectively).
- a higher temperature process operating at temperatures of about 580-650°C.
- a LPCVD is required.
- the material can be poly-Si or ⁇ -Si).
- in-situ phosphorus doped or arsenic doped Si is preferred, and the concentration is come up to about 5 ⁇ 10 19 -5 ⁇ 10 21 /cm 3 .
- a planarization process such as a chemical/mechanical polish (CMP) process using the gate dielectric layer 160 as a CMP stopping layer is achieved to form a flat surface.
- CMP chemical/mechanical polish
- a thin stacked ONO 180 is formed as the interpoly dielectric 180.
- the "ONO" layer refers the nitride layer formed using LPCVD on a thermal oxidation firstly, and then re-oxidation again to grow an oxide layer.
- the ONO layer having the properties of extremely dielectric integrity and long life time in breakdown characteristics.
- the thickness of upper oxide/nitride/ lower oxide of ONO 180 is, respectively, about 1-5 nm, 4-20 nm, and 1-5 nm.
- n+ polysilicon layer 190 is deposited on all areas, and patterned to defined word lines.
- a CVD method such as LPCVD is performed at a temperature of about 450-650°C., and the doping concentration is about 5 ⁇ 10 19 -5 ⁇ 10 21 /cm 3 .
- FIG. 9 is a top-view diagram illustrating the high-density contactless nonvolatile memory with buried bit line and floating gate in the silicon trench region, wherein the source/drain regions are bit lines 170, and the polysilicon gate 190 are word lines.
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- Non-Volatile Memory (AREA)
Abstract
Description
4POCl.sub.3 +3O.sub.2 →2P.sub.2 O.sub.5 +6Cl.sub.2
Claims (14)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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US09/271,736 US6153467A (en) | 1998-06-03 | 1999-03-18 | Method of fabricating high density buried bit line flash EEPROM memory cell with a shallow trench floating gate |
Applications Claiming Priority (2)
Application Number | Priority Date | Filing Date | Title |
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US09/089,897 US6048765A (en) | 1998-06-03 | 1998-06-03 | Method of forming high density buried bit line flash EEPROM memory cell with a shallow trench floating gate |
US09/271,736 US6153467A (en) | 1998-06-03 | 1999-03-18 | Method of fabricating high density buried bit line flash EEPROM memory cell with a shallow trench floating gate |
Related Parent Applications (1)
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US09/089,897 Continuation-In-Part US6048765A (en) | 1998-06-03 | 1998-06-03 | Method of forming high density buried bit line flash EEPROM memory cell with a shallow trench floating gate |
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US6153467A true US6153467A (en) | 2000-11-28 |
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US09/271,736 Expired - Lifetime US6153467A (en) | 1998-06-03 | 1999-03-18 | Method of fabricating high density buried bit line flash EEPROM memory cell with a shallow trench floating gate |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US20010012664A1 (en) * | 1999-09-01 | 2001-08-09 | Tran Luan C. | Semiconductor processing methods of forming transistors, semiconductor processing methods of forming dynamic random access memory circuitry, and related integrated circuitry |
US6326264B1 (en) * | 1998-07-10 | 2001-12-04 | Nec Corporation | Semiconductor device and method for manufacturing same |
US6417048B1 (en) * | 2001-11-19 | 2002-07-09 | Vanguard International Semiconductor Corporation | Method for fabricating flash memory with recessed floating gates |
US6489193B1 (en) * | 2002-01-09 | 2002-12-03 | Silicon Integrated Systems Corp. | Process for device isolation |
US6566194B1 (en) | 2001-10-01 | 2003-05-20 | Advanced Micro Devices, Inc. | Salicided gate for virtual ground arrays |
US6642107B2 (en) * | 2001-08-11 | 2003-11-04 | Samsung Electronics Co., Ltd. | Non-volatile memory device having self-aligned gate structure and method of manufacturing same |
US6645801B1 (en) | 2001-10-01 | 2003-11-11 | Advanced Micro Devices, Inc. | Salicided gate for virtual ground arrays |
US6730564B1 (en) | 2002-08-12 | 2004-05-04 | Fasl, Llc | Salicided gate for virtual ground arrays |
US20040131979A1 (en) * | 2003-01-07 | 2004-07-08 | International Business Machines Corporation | Apparatus and method to improve resist line roughness in semiconductor wafer processing |
US20050077566A1 (en) * | 2003-10-10 | 2005-04-14 | Wei Zheng | Recess channel flash architecture for reduced short channel effect |
CN100390998C (en) * | 2004-03-25 | 2008-05-28 | 夏普株式会社 | Semiconductor memory device, and fabrication method thereof |
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US6048765A (en) * | 1998-06-03 | 2000-04-11 | Texas Instruments - Acer Incorporated | Method of forming high density buried bit line flash EEPROM memory cell with a shallow trench floating gate |
US6084264A (en) * | 1998-11-25 | 2000-07-04 | Siliconix Incorporated | Trench MOSFET having improved breakdown and on-resistance characteristics |
-
1999
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Cited By (23)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
US6326264B1 (en) * | 1998-07-10 | 2001-12-04 | Nec Corporation | Semiconductor device and method for manufacturing same |
US20060008977A1 (en) * | 1999-09-01 | 2006-01-12 | Tran Luan C | Semiconductor processing methods of forming transistors, semiconductor processing methods of forming dynamic random access memory circuitry, and related integrated circuitry |
US7253047B2 (en) | 1999-09-01 | 2007-08-07 | Micron Technology, Inc. | Semiconductor processing methods of forming transistors, semiconductor processing methods of forming dynamic random access memory circuitry, and related integrated circuitry |
US6914287B2 (en) | 1999-09-01 | 2005-07-05 | Micron Technology, Inc | Semiconductor processing methods of forming transistors, semiconductor processing methods of forming dynamic random access memory circuitry, and related integrated circuitry |
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US20010012664A1 (en) * | 1999-09-01 | 2001-08-09 | Tran Luan C. | Semiconductor processing methods of forming transistors, semiconductor processing methods of forming dynamic random access memory circuitry, and related integrated circuitry |
US7294903B2 (en) | 1999-09-01 | 2007-11-13 | Micron Technology, Inc. | Transistor assemblies |
US7291880B2 (en) | 1999-09-01 | 2007-11-06 | Micron Technology, Inc. | Transistor assembly |
US6642107B2 (en) * | 2001-08-11 | 2003-11-04 | Samsung Electronics Co., Ltd. | Non-volatile memory device having self-aligned gate structure and method of manufacturing same |
US6645801B1 (en) | 2001-10-01 | 2003-11-11 | Advanced Micro Devices, Inc. | Salicided gate for virtual ground arrays |
US6566194B1 (en) | 2001-10-01 | 2003-05-20 | Advanced Micro Devices, Inc. | Salicided gate for virtual ground arrays |
US6417048B1 (en) * | 2001-11-19 | 2002-07-09 | Vanguard International Semiconductor Corporation | Method for fabricating flash memory with recessed floating gates |
US6489193B1 (en) * | 2002-01-09 | 2002-12-03 | Silicon Integrated Systems Corp. | Process for device isolation |
US6730564B1 (en) | 2002-08-12 | 2004-05-04 | Fasl, Llc | Salicided gate for virtual ground arrays |
US7018779B2 (en) * | 2003-01-07 | 2006-03-28 | International Business Machines Corporation | Apparatus and method to improve resist line roughness in semiconductor wafer processing |
US20060110685A1 (en) * | 2003-01-07 | 2006-05-25 | Ibm Corporation | Apparatus and method to improve resist line roughness in semiconductor wafer processing |
US20040131979A1 (en) * | 2003-01-07 | 2004-07-08 | International Business Machines Corporation | Apparatus and method to improve resist line roughness in semiconductor wafer processing |
US6965143B2 (en) * | 2003-10-10 | 2005-11-15 | Advanced Micro Devices, Inc. | Recess channel flash architecture for reduced short channel effect |
US20050077566A1 (en) * | 2003-10-10 | 2005-04-14 | Wei Zheng | Recess channel flash architecture for reduced short channel effect |
CN100390998C (en) * | 2004-03-25 | 2008-05-28 | 夏普株式会社 | Semiconductor memory device, and fabrication method thereof |
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