1331099 (1) 九、發明說明 【發明所屬之技術領域】 本發明係關於一種水壓轉印物品，其水溶性薄膜上之 印刷圖型具有水壓轉印形成的裝飾層，在該裝飾層上不施 加表面保護層，而可將該裝飾層做爲最表面層。 【先前技術】 水壓轉印方法，係將水溶性薄膜上塗有水溶性之印刷 圖型的轉印薄膜，飄浮在轉印槽內之水面上，將該轉印薄 膜中之水溶性薄膜以水潤濕之後，使物品（被轉印體）一 方面接觸於該轉印薄膜之印刷圖型上，一方面被壓入轉印 槽內之水中，利用水壓而將轉印薄膜之印刷圖型轉印到物 品之表面上而形成裝飾層的方法。然後，普通之轉印薄膜 ，係將印刷圖型事前印刷於水溶性薄膜上而形成之故，印 刷圖型之墨水係爲乾燥狀態，因此在轉印時，必須將活性 劑或稀釋劑類塗佈於轉印薄膜之印刷圖型上，而將印刷圖 型恢復到與剛印刷後同樣的潤濕狀態所顯現的附著性，此 通常係稱爲活性化。又，爲了在該物品之表面上形成的裝 飾層上賦予耐摩性、耐溶劑性、耐藥品性、耐候性等，而 必須在裝飾層上形成表面保護膜（頂被覆層）。 依此方式，在裝飾層上形成表面保護膜之時，可使全 體獲得表面光澤，因而在美觀設計上被賦予深度，因此視 水壓轉印物品之製品而定，被賦予如磨光般之一種高級感 ，因此具有美工表現上之効能。但是，其反面爲外觀表面 -5- (2) (2)1331099 之全體爲一樣的光澤感，例如在木紋圖案上，無法表現類 似侘、寂之雅緻的原木感、質感，因而成爲產生美工表現 之界限的原因。另一方面，即使未形成表面保護層而使裝 飾層露出之時，並非未必可表現類似該宅、寂之雅緻的原 木感、質感，但是在無表面保護層之狀態，而使耐摩性、 耐溶劑性、耐藥品性、耐候性等劣化，因而無法做成最終 製品，故而實際情況爲必須犧牲美工設計上的表現而施以 表面保護層。 並且，在裝飾層上形成表面保護層之時，會在表面觸 摸時產生滑溜之感覺或低級感，因而爲了防止該滑溜之感 覺並賦予高級感，雖然不施以表面保護層亦爲其中一個手 法，但是與上述之美工上表現的情形相同地，爲了獲得耐 摩性、耐溶劑性、耐藥品性、耐候性等之物理•化學的特 性，而做成裝飾層之表面觸摸感劣化且賦予低級感之犧牲 ，因而施以表面保護層。 因此，本申請人考慮在解決上述之美工表現或表面觸 感之問題上應係很困難之時，暫時將該美工表現或表面觸 感的問題擱置，如以下所述，而嘗試達成水壓轉印技術中 之種種課題之解決。 在第1之先前技術中，表面保護層係，在將印刷圖型 轉印而形成的裝飾層上以噴塗方式而塗佈氨基甲酸乙酯2 液型塗漆、壓克力透明型塗漆、紫外線硬化塗漆，在該紫 外線硬化塗漆上照射紫外線之時，使塗漆硬化而形成者。 但是，在該方法中，並非使裝飾層之耐溶劑性提高， -6- (3) (3)1331099 而係在被覆裝飾層之表面保護層（頂被覆層）上擔負耐摩 性、耐溶劑性等之角色者，並且，將印刷圖型轉印到物品 而後進行水洗、乾燥之後，才塗佈氨基甲酸乙酯2液型塗 漆’因而這些處理需要比較長的時間，而一般在乾燥方面 係暴露於熱風下進行，使裝飾層上容易附著灰塵，因而有 裝飾層的外觀降低之缺點。 在第2之先前技術中，提案有同時進行印刷圖型之水 壓轉印及表面保護層之方法（參照特許文獻1)。該方法 係，在水溶性薄膜上，除了施予非水溶性樹脂製之透明或 半透明之表面保護層之外，更在其上施予非水溶性之印刷 層而形成附有保護層之轉印薄膜，而後將該附有保護層之 轉印薄膜以水壓轉印到物品（被轉印物）上的方法。 該方法在水壓轉印時，利用水壓使物品之表面接觸轉 印薄膜之時，會使水溶性薄膜上之表面保護層及印刷層同 時被轉印到物品之表面，因此如上述第1之先前技術，不 需要轉印工程後之保護塗漆的塗佈工程及硬化工程，在裝 飾層與表面保護層之間不會附著灰塵。 依此方式，雖然該方法可在印刷層之轉印的同時，亦 形成表面保護層，而有作業工程簡易化、且裝飾層之外觀 並不差的優點，但是表面保護層係由丁基變性壓克力共聚 體 '乙基變性壓克力共聚體等之低耐溶劑性的保護劑所形 成，因此，雖然亦可賦予耐摩性等而機械地保護物品之印 刷層的表面，但是有與溶劑或藥品接觸時容易變質等之缺 乏化學上保護之缺點。 (4) (4)1331099 並且提案有類似於該第2之先前技術，而在第2之先 前技術之表面保護層上使用紫外線硬化樹脂之第3之先前 技術（參照特許文献2)。 在該第3之先前技術中，雖然表面保護層係使用紫外 線硬化樹脂之故，因而以機械或化學的方式保護裝飾層表 面有効，但是如後面所述，在轉印薄膜之最表面將印刷圖 型再現之時，會產生幾個較不受歡迎的缺點。 即，在上述之第1至第3之先前技術中所共同者，在 轉印之時，雖然係將活性劑或稀釋劑類塗佈於轉印薄膜之 印刷圖型上，而再現印刷圖型之附著性，但是該等活性劑 或稀釋劑類係使用有機溶劑之故，必須在工程條件上預留 該溶劑成分揮發到完了之時間或乾燥條件，若溶劑成分殘 留於印刷圖型之轉印後的裝飾層上之時，會對品質產生壞 的影響，又在作業中有機溶劑被放出到大氣中而被人體吸 入，因此在印刷圖型之活性化上使用有機溶劑之時，變成 有機大氣污染或勞動者之健康障礙的元凶，因而成爲非急 早對這些問題採取對策不可之問題。 因而，本申請人亦嘗試將環境對應型之塗漆做爲已經 在上述第1之先前技術中使用的紫外線硬化塗漆，而直接 塗佈到轉印薄膜之印刷圖型上而進行觀查，雖然印刷圖型 之墨水可暫時地再現附著性，但是使其在水壓轉印工程中 進行一貫作業之時，被判明在轉印時印刷圖型之附著性會 降低，因而造成轉印不良。又，使用相同紫外線硬化樹脂 組成物的紫外線硬化墨水且不混入著色顔料者，做同樣的 -8- (5) (5)1331099 試驗並進行觀查，發現可使印刷圖型之墨水再現其附著性 ，而且在轉印時印刷圖型之附著性不會降低，因而可進行 轉印。 在水壓轉印之時，並非僅印刷圖型之墨水恢復到潤濕 狀態而再現附著性即可，支持印刷圖型之水溶性薄膜亦被 轉印槽內的水潤濕，在物品被壓入水中之時，印刷圖型與 水溶性薄膜雙方必須固定於物品表面上。從而，在獲得兩 者之潤濕狀態的調和之時段，必須將物品壓入水中，並且 直到轉印完成爲止，必須使適應於物品之周圍的附著性再 現。 因此，這些嘗試之結果的不同，想來應係以相同的紫 外線硬化樹脂組成物，而做爲紫外線硬化塗漆及紫外線硬 化墨水之用途別製品之組成的不同所產生者，雖然在紫外 線硬化塗漆中含有低沸點溶劑，但是在紫外線硬化墨水中 則不含有溶劑係爲一般之情形，從而，將紫外線硬化塗漆 塗佈於印刷圖型之時，雖然由塗漆中之溶劑而使當初之附 著性再現，在轉印時點中，該溶劑會揮發完而使附著性降 低，另一方面，在紫外線硬化墨水中未含有溶劑成分之故 ，因而推測應可介由紫外線硬化墨水中之某些非溶劑成分 而使附著性再現，其後反覆地進行種種的試驗等，而將可 解決先前技術中種種問題的方法先提案。 該解決方法具備有：將無溶劑之紫外線硬化樹脂組成 物塗佈於轉印薄膜之印刷圖型上，介由該紫外線硬化樹脂 組成物中的非溶活性化成分而使印刷圖型之附著性再現的 (6) (6)1331099 工程、將物品之表面抵壓於含有紫外線硬化樹脂組成物之 印刷圖型上，而將物品與轉印薄膜一起壓入水中的工程、 將紫外線照射到介由上述工程而將含有紫外線硬化樹脂組 成物之印刷圖型轉印後的物品上，而使紫外線硬化樹脂組 成物與印刷圖型在渾然一體化之狀態被硬化，而形成裝飾 層的工程（未公開專利文獻3及4)。 本申請人在完成該發明之過程中，已確認，以該水壓 轉印方法獲得的水壓轉印物品之裝飾層本身，至少具備有 對物品表面的密著性及耐溶劑性，從而即使無表面保護層 之時，亦可進行製品化。 並且，本申請人已確認，以該水壓轉印方法獲得的水 壓轉印物品，不使用表面保護層亦可達成裝飾層美工設計 之變化的表現。 將說明關於裝飾層美工設計之變化的表現，例如，對 木紋圖案之印刷圖型實施水壓轉印形成的裝飾層進行觀査 之時，雖然表現其早材部分的層部分上可觀査到光澤感， 但是黑色墨水以高濃度印刷而表現其晚材部分的層部分上 則無觀查到光澤感，該光澤感之差異爲相鄰而存在之時， 恰好可感覺到似原木的立體感。 該光澤感之差異，推測應爲下列原因所發生者。即， 在水壓轉印時，爲了使印刷圖型之附著性再現而塗佈於轉 印薄膜之表面的紫外線硬化樹脂組成物，係由黑色墨水中 之著色顏料所吸收之故，因此在黑色墨水以高濃度轉印之 位置（層部分）上，顏料之粒子感被露出而被紫外線硬化 -10- (7) (7)1331099 ，因而光澤感降低，另一方面，在黑色墨水以外的墨水被 轉印的位置或黑色墨水以低濃度轉印之位置上，紫外線硬 化樹脂組成物並不太被吸油，因而被埋入於顏料間的方式 而進行紫外線硬化，故微細的凹凸維持少許的光澤，推測 這些應爲產生光澤感之差的原因。因而，根據該推測而從 美工設計觀點反覆地進行種種的確認試驗等。 【特許文獻1】日本特開平4-197699號公報 【特許文獻2】日本特開2003-305998號公報 【特許文獻3】日本特願2003-156439號說明書 【特許文獻4】日本特願2003-409874號說明書 本發明之第1基本目的，在提供一種水壓轉印方法， 使物品上之裝飾層本身具備有如密著性、耐溶劑性之機械 及化學的表面保護功能，並非形成表面保護層，而係可將 裝飾層做爲外觀最表面而使用，且能改良裝飾層表面的光 澤變化性。 本發明之其它目的，在提供一種水壓轉印方法，其在 裝飾層上形成具有光澤感之部分及光澤感減少的部分，利 用這些光澤感的差異，可將立體感賦予裝飾層。 本發明之又其它之目的，在提供一種水壓轉印方法， 根據光澤感的差異而將立體感賦予裝飾層上，該立體感係 感受到原木感、質感、實物感、嶄新感、奇異感、侘、寂 之雅緻等的工夫，因而賦予先前技術所未曾有之豐富的美 工設計表現。 本發明之更其它之目的，在提供一種水壓轉印物品， -11 - (8) (8)1331099 讓裝飾層主體具有表面保護功能，同時改良其光澤變化性 ，而提昇外觀性的表現。 【發明內容】 本發明的第〗特徵，要提供一種水壓轉印方法，在將 水溶性薄膜上的乾燥的印刷圖型弄濕之後，將上述印刷圖 型水壓轉印到物品的表面，在上述物品的表面形成裝飾層 ，之水壓轉印方法，其特徵爲：爲了弄濕上述印刷圖型， 而在上述印刷圖型，塗佈上含有光聚合性單體的無溶劑型 的紫外線硬化樹脂組成物，將上述含有光聚合性單體的無 溶劑型的紫外線硬化樹脂組成物浸透於上述印刷圖型，在 水壓轉印後，以紫外線來硬化上述紫外線硬化樹脂組成物 ，且因應於上述印刷圖型的墨水的顏料的吸油量、墨水的 濃度，對上述裝飾層的墨水印刷部分賦予高光澤圖案部及 低光澤圖案部鄰接的光澤變化性》 針對本發明的第1特徵，其中低光澤圖案部，係依據 曰本工業規格Z874 1 -1 997「方法3-60度鏡面光澤」而測 定爲具有20未滿的光澤度者；高光澤圖案部與低光澤圖 案部的光澤度之差異，係依據日本工業規格Z8741-1997「 方法3-60度鏡面光澤」而測定爲1〇以上者。 針對本發明的第1特徵，其中紫外線硬化樹脂組成物 中含有消豔成分’消豔成分其功能具有可賦予高光澤圖案 部及低光澤圖案部之消豔効果。 針對本發明的第1特徵，其中印刷圖型係具有木紋圖 -12- (9) (9)1331099 案，裝飾層之高光澤圖案部係對應於印刷圖型的木紋圖案 中之粗組織表現部，且裝飾層之低光澤圖案部係對應於印 刷圖型的木紋圖案中之緻密組織表現部；且粗組織表現部 係相當於早材部分，而緻密組織表現部係相當於晚材部分 ，最表面裝飾層係成爲不勻整紋理或正木紋之外觀。 本發明的第2特徵，要提供一種水壓轉印物品，具有 藉由上述第1特徵所形成的裝飾層。 在本發明，所謂的「墨水濃度」，代表「墨水的成分 也就是樹脂與顏料之中的顏料的含有比例」。 依此方式，裝飾層在水壓轉印時，塗佈於轉印薄膜上 之無溶劑型的紫外線硬化樹脂組成物，由轉印後之紫外線 照射，而與印刷圖型爲渾然一體化之狀態下被硬化而形成 ，因而具備耐摩性、耐溶劑性、耐藥品性、耐候性等之物 理·化學的表面保護功能，從而不會有如形成表面保護層 (頂被覆層）之先前技術一般，不會在形成表面保護層之 時產生的塵埃附著，而使良品率提高，並且由於爲露出狀 態而維持美工設計之表現的裝飾層，不會有如先前技術一 般，由於在其上施加的表面保護層（頂被覆層），而使美 工設計之表現減少，因而可提供可維持美工設計之表現之 製品（水壓轉印物品）。 並且，雖然裝飾層係與紫外線硬化樹脂組成物爲渾然 一體化之狀態下被硬化而形成者，但是該紫外線硬化樹脂 組成物，視印刷圖型之墨水中的顏料種類，而有容易吸收 、難以吸收者，例如，爲黑色墨水中之著色顔料的碳黑， -13- 1331099 do) 容易對紫外線硬化樹脂組成物吸油，因此這些顏料以高濃 度添加之墨水被轉印的位置（裝飾層部分=墨水印刷部分 )中，有微細凹凸產生於裝飾層上，因而觀察到光澤感降 低而顯現低光澤圖案部，而且，在吸收紫外線硬化樹脂組 成物之狀態下被硬化而形成凸領域。另一方面，在黑色墨 水以外的墨水被轉印的位置、或黑色墨水以低濃度被轉印 的位置（同樣裝飾層部分=墨水印刷部分）上，顯現出微細 凹凸之發生較少、而觀察到高光澤感之高光澤圖案，並且 紫外線硬化樹脂組成物之吸收少之狀態下被硬化，而形成 高度比該凸領域相對地低之凹領域。亦即，這些光澤感之 差異，係呼應於印刷圖型上而在裝飾層上必然鄰接產生者 ，因此由於該光澤感之差異之存在，可提供裝飾層被賦予 立體感之製品（水壓轉印物品）。 水壓轉印物品之相鄰的高光澤圖案部與低光澤圖案部 之光澤度的差異，雖然以1 0以上較佳，但是比該値更小 之時亦不會感覺到該差異很大。即，使用光澤度計之測定 數値與目視感覺不會有1 〇〇%—致之情形，目視感覺一般 在30至60的範圍內較遲鈍，排除此範圍之時，則變成較 銳利。例如，即使光澤度之測定數値的差異爲5之時，在 30至60的範圍內，不會感到對光澤度之差異爲5之光澤 感有太大變化，但是將該範圍在上方或下方排除之範圍內 ，光澤度之差異爲5，則感到有相當的差異。當然，光澤 度之差異越大的話，則感覺到越大，例如，低光澤圖案部 之光澤度爲未滿20之時’幾乎一眼即感覺到無光澤，從 -14- (11) (11)1331099 而，低光澤圖案部和與其相鄰的高光澤圖案部的光澤度之 差異爲10之時，低光澤圖案部與高光澤圖案部之差異並 未特別感到有差異。但是，並非高低之光澤圖案部的光澤 度爲進入30至60的範圍內者可以有例外。 並且，印刷圖型例如爲不勻整紋理或正木紋之時，在 表現早材部分的位置上，褐色或淡褐色之墨水係以低濃度 被轉印之故，紫外線硬化樹脂組成物在該位置上被吸收的 程度降低而成爲高光澤圖案部，在表現晚材部分的位置上 ，黑色墨水等係以高濃度被轉印之故，紫外線硬化樹脂組 成物在該位置上被吸收的程度提高而成爲低光澤圖案部， 利用這些光澤度之差異相鄰而存在之時，恰好可感受到如 原木之立體感，又，黑點所在之位置亦成爲低光澤圖案部 ，可觀察到如導管被近乎直角地切斷之時的切口處具有深 度之孔一樣，因此全體可被提供被賦予原木感、板接縫或 正木紋之質感的製品（水壓轉印物品）。當然，不僅不勻 整紋理或正木紋之一般的木紋，而且可感覺到將瘤或枝之 根本的部分或含有樹脂的部分等切斷的所謂高級杢之木質 感的製品，亦可以容易地獲得。 並且，含有消豔成分之紫外線硬化樹脂組成物，與印 刷圖型渾然一體化的狀態下被硬化之時，該消豔成分利用 高光澤圖案部而有効地作用，因此使高光澤圖案部與低光 澤圖案部之光澤度的差異有被縮小的傾向，而使全體的色 調失去，因而可提供侘、寂之雅緻的感覺之製品（水壓轉 印物品）。 -15- (12) (12)1331099 【實施方式】 將參照附圖而詳細地說明本發明之實施形態，第1圖 係槪略地顯示可獲得本發明之水壓轉印物品的一個水壓轉 印方法，該水壓轉印方法係，將由塗在印刷圖型12的水 溶性薄膜1 4所形成之轉印薄膜1 6，使印刷圖型1 2做爲上 面的方式而供給到未圖示之轉印槽內之水18上而飄浮， 使必須水壓轉印的物品1 〇介由該轉印薄膜1 6而被壓入水 1 8中之水壓轉印方法。 水溶性薄膜1 4，係由吸收水而潤濕軟化之例如聚乙烯 醇做爲主成分之水溶性材料所形成。該水溶性薄膜1 4，在 水壓轉印時，與轉印槽內的水18接觸而軟化，並固定圍 繞於必須加飾的物品上，而進行水壓轉印。印刷圖型1 2， 一般在水壓轉印之時，利用凹版印刷等而預先施加於水溶 性薄膜14上。 該水壓轉印方法之特徵，係將印刷圖型1 2以水壓轉 印到物品上之前，將紫外線硬化樹脂組成物、理想上爲無 溶劑型之紫外線硬化樹脂組成物塗佈到轉印薄膜1 6之印 刷圖型1 2上。 以下，將參照第2圖而說明實行轉印薄膜16之乾燥 後的印刷圖型12之附著性的恢復之水壓轉印方法具體工 程例，在該例中，預先將印刷圖型12印刷到水溶性薄膜 14上，使用該印刷圖型12被乾燥狀態的轉印薄膜16而將 作業開始（參照第2A圖）。雖然未圖示，實際上該轉印 -16- (13) (13)1331099 薄膜16,係從該薄膜滾筒連續地跑出或切斷成適當的長度 而被使用。 在進行水壓轉印之時，在轉印薄膜16之乾燥後的狀 態之印刷圖型12上，塗佈含有光聚合性單體的無溶劑型 之紫外線硬化樹脂組成物20 (參照第2B圖），介由該無 溶劑型之紫外線硬化樹脂組成物2 0而使印刷圖型1 2之附 著性再現的狀態下，將轉印薄膜16飄浮於轉印槽內之水 1 8中（參照第2C圖）’其次，將含有紫外線硬化樹脂組 成物20之印刷圖型12抵壓於物品1〇之表面i〇s上的方 式’而將物品與轉印薄膜16 —起被壓入水中（參照第 2D圖），然後將紫外線22照射到依此方式將含有紫外線 硬化樹脂組成物20之印刷圖型1 2轉印後之物品1 〇上， 而使紫外線硬化樹脂組成物20及印刷圖型12被硬化（參 照第2E圖）。而，雖然未圖示，實際上物品1〇係—面由 逆三角形之輸送帶而輸送、並由機器手臂支持，一面被壓 入水中’並且’視情況而定，亦可將無溶劑型之紫外線硬 化樹脂組成物20塗佈到印刷圖型12上之工程（參照第 2B圖），與飄浮於水上之工程（參照第2C圖）的工程順 序做成相反，而將無溶劑型之紫外線硬化樹脂組成物噴塗 到飄浮於水上的轉印薄膜之印刷圖型上，而進行印刷圖型 之附著性的再現。 紫外線硬化樹脂組成物，係利用紫外線的化學作用而 在較短時間內硬化之樹脂組成物，因應於用途，可採用紫 外線硬化型塗漆、紫外線硬化型墨水、紫外線硬化型黏著 -17- (14) (14)1331099 劑等之形態’該等形態在基本上係將（1)光聚合性預聚 體、（2)光聚合性單體、（3)光開始劑做爲必須成分而 製成者。而’市面販賣的紫外線硬化型塗漆方面，一般添 加有稀釋劑等之溶劑，在紫外線硬化型墨水之情形，雖然 係爲添加有乙醇等之溶劑者’但是一般紫外線硬化型墨水 不含有溶劑’而是以光聚合性單體做爲稀釋劑之功能而配 合者’在本發明，該水壓轉印方法中需要的「紫外線硬化 樹脂組成物」，係不論紫外線硬化樹脂之用途別的形態， 而將光聚合性預聚體、光聚合性單體、光開始劑做爲必須 成分而配合’且不添加溶劑’利用紫外線照射而硬化的性 質者之謂。 因而’使用在此說明的水壓轉印方法之「紫外線硬化 樹脂組成物」’係將含有溶劑的紫外線硬化樹脂組成物排 除，而僅限定不添加溶劑的無溶劑型之紫外線硬化樹脂組 成物。其理由爲’在該水壓轉印方法之中，使轉印薄膜之 印刷圖型的附著性再現，係由無溶劑型之紫外線硬化樹脂 組成物中之非溶劑活性化成分、典型地爲光聚合性單體所 形成者，因此係根據不含溶劑而獲得種種優點之想法。適 於做爲無溶劑型之紫外線硬化樹脂組成物的紫外線硬化樹 脂組成物，例如具有如下列組成之成分所形成者。 (1) 寡聚體（光聚合性預聚體） 30〜50重量％ (2) 多官能性壓克力樹脂（光聚合性單體） 10〜3 0重量 % (3) 單官能性壓克力樹脂（光聚合性單體） 10〜40重量 -18- (15) (15)1331099 % (4)光開始劑 0.5~5重量％ (5 )非反應添加物 1〜2 0重量％ 光聚合性預聚體，係利用光化學作用而獲得更硬化之 聚合物’其被稱爲光聚合性不飽和聚合物，或亦可稱爲基 材樹脂或光聚合性寡聚體。然後，其乃是影響做爲硬化後 之塗膜之基本的諸物性之基本成分，因應於所需要的特性 ’可將壓克力系寡聚體'聚酯系亭聚體'環氧壓克力系寡 聚體 '氨基甲酸乙酯壓克力系寡聚體等之任何一個，以單 獨或任意之組合而使用。而，光聚合性預聚體，雖然在最 終聚合物之程度聚合度並非很高，但是其亦非單體，而係 有某種程度聚合者，因此具有適當的黏度，考慮使用時之 作業性，被做成需要有稀釋劑。 光聚合性單體，係做爲光聚合性預聚體之稀釋劑的角 色’可確保樹脂組成物之實用上的作業性，且在照射紫外 線之時，其本身亦爲有關連到聚合者，官能基係爲具有一 個之單官能性單體 '及具有二個之多官能性單體。單官能 性單體，具有可提高與物品之密著性，且將柔軟性賦予硬 化後之塗膜之功能，並且多官能性單體具有使預聚體分子 間產生交聯的交聯劑之角色的功能。例如，聚丙烯酸甲基 等之聚丙烯酸酯，係介由交聯而將塗膜之收縮作用予以緩 和之目的而被使用。塗膜之收縮力變高之時，會降低塗膜 之附著性，因此聚丙烯酸酯，雖然係做爲紫外線硬化樹脂 組成物之黏度調整用的稀釋劑之功能，但是在該水壓轉印 -19- (16) (16)1331099 方法中，亦可做爲使乾燥狀態的印刷圖型之附著性再現的 功能成分而作用。 光開始劑，係吸收紫外線而開始聚合反應者，亦稱爲 光聚合開始劑，紫外線硬化反應爲自由基反應之時，可使 用乙酿苯（acetophenone )、苯醯苯（benzophenone )等 ，紫外線硬化反應爲離子反應之時，可使用噻唑（ thiazole)化合物等。 在紫外線硬化樹脂組成物中，亦可因應於需要而添加 其它之增感劑、充塡材、非活性有機聚合物、均化劑（ leveling agent)、觸變性（thixotropy)賦予劑、熱聚合 禁止劑、消豔成分等。尤其，如後面將詳述者，消豔成分 在促進藉由本發明所得到之水壓轉印物品的裝飾層之美工 設計的表現方面可有効地使用。 塗佈無溶劑型之紫外線硬化樹脂組成物20之工程， 以使用照相凹版滾筒塗佈方法、刮棒塗佈方法較佳。 將無溶劑型之紫外線硬化樹脂組成物20塗佈於印刷 圖型12上之時，無溶劑型之紫外線硬化樹脂組成物20中 之光聚合性單體浸入於印刷圖型12之乾燥後的墨水中， 並將其溶解，而在印刷圖型1 2上使與剛印刷後同樣的附 著性再現。從而，無溶劑型之紫外線硬化樹脂組成物20 可發揮與先前技術所常用的活性劑同等的功能，當然可以 省略活性劑或稀釋劑等之塗佈’做成將光聚合性單體啓動 之紫外線硬化樹脂組成物的各個成分’一般與溶劑等比較 ，其揮發性相當低，因此可使再現的附著性在爾後變動而 -20- (17) (17)1331099 降低的可能性很少，因而可達成對印刷圖型迄今爲止以上 之穩定的活性化。 並且，將該印刷圖型1 2轉印到物品1 0上，而照射紫 外線22之時，光聚合性單體等之紫外線硬化樹脂組成物 的各個成分，滲入於印刷圖型12之墨水中，使兩者成爲 渾然一體的狀態下被硬化，而使耐摩性等之機械特性被賦 予裝飾層上，並且被賦予耐溶劑性、耐藥品性等之化學的 表面保護功能。而，在第2B圖中，雖然未顯示印刷圖型 1 2之墨水成分與紫外線硬化樹脂組成物20成爲渾然一體 的狀態，但是必須理解，若在圖面上將此表現之時，使兩 者變成無法區別，因此方便上以層狀記載。並且，在紫外 線照射後，光聚合性單體其本身自己參加聚合，因此使其 遊離，其後亦不會產生任何不良情形。 水壓轉印方法方面，使用無溶劑型之紫外線硬化樹脂 組成物之時，有種種的優點，以下將予詳細說明。即使， 使用市販之如紫外線硬化型塗漆一般添加溶劑的紫外線硬 化樹脂組成物之時，亦不會對印刷圖型之活性化有任何的 不利，反而被理解爲更有利也說不定，紫外線硬化樹脂介 由紫外線照射而在短時間被硬化，因而添加的溶劑爲揮發 性高之低沸點溶劑之時，在物品被壓入水中之時會揮發完 ’因而使附著性不足而引起轉印不良，並且，反之，若添 加揮發性難之高沸點溶劑之時，雖然在物品被壓入水中之 時可以避免附著性不足的問題’但是紫外線照射作業，溶 劑完全揮發完畢必須等待一段時間，在溶劑之揮發不完全 -21 - (18) (18)1331099 之時照射紫外線，使溶劑產生被內包的狀態下，而將紫外 線硬化型樹脂硬化之時，隨後將產生缺陷。因而，不論低 沸點溶劑、或高沸點溶劑，使用添加溶劑的紫外線硬化樹 脂組成物之時，除了由於大氣污染或人體吸收而產生健康 危害以外，並產生工程處理上或品質上之種種問題，因此 較不採用。 相對於此，如已部分地敘述者，使用無溶劑型之紫外 線硬化樹脂組成物之時，光聚合性單體係以黏度調整爲目 的，而可做爲稀釋劑之功能，因此與溶劑含有型者比較， 可更多地調合之故，因而無溶劑型之紫外線硬化樹脂組成 物中之非溶劑活性化成分，典型上僅由光聚合性單體作用 之時，可使必要且充分的穩定附著性再現，又，紫外線硬 化樹脂組成物20與印刷圖型1 2渾然一體化而硬化之時， 具有相當於先前技術中所使用的溶劑的功能之光聚合性單 體本身亦參加聚合之故，其後該光聚合性單體做成遊離， 亦不會有任何不良。 但是，必須理解的，如已述者，本發明之水壓轉印物 品’並非利用塗佈無溶劑型之紫外線硬化樹脂組成物的水 壓轉印方法所獲得者，因此若無法享受上述優點中之數項 的話’亦可利用塗佈含有溶劑型之紫外線硬化樹脂組成物 的水壓轉印方法所獲得者。 紫外線22之照射，最好將轉印薄膜16之水溶性薄膜 14卷繞於含有紫外線硬化樹脂組成物20之印刷圖型12被 轉印後之物品1〇上之時進行較佳，從而，紫外線照射工 -22- (19) (19)1331099 程，最好在物品10尙未進入水中，或者物品10從水中出 來之後’爲了將水溶性薄膜14除去而實施水洗作業之前 實行較佳。而’紫外線22係由如含有低壓乃至高壓水銀 燈、金屬鹵素燈之光源燈及照射器（燈罩）之公知的紫外 線硬化裝置而照射。 依此方式，在水溶性薄膜1 4被卷繞於物品1 〇上而照 射紫外線之時’印刷圖型12在完全乾燥之前不會有灰塵 等附著固定，而在將水溶性薄膜14除去的時點上，將印 刷圖型12硬化之故’可降低灰塵等附著之可能性，因此 可容易地獲得外觀良好的裝飾層30。而，紫外線22之照 射，係在物品10於如綠色環境室般之隧道等沒有灰塵之 環境下進行之時，則當然可在水溶性薄膜1 4從物品1 〇被 洗滌而流掉之後進行◊ 其後，如第2 F圖所示，以沖水2 4噴射而使物品1 〇 被水洗，可將覆蓋於物品1 0上之狀態的轉印薄膜1 6之水 溶性薄膜14除去。其次，如第2G圖所示，將熱風26吹 在含有紫外線硬化樹脂組成物20之印刷圖型12被轉印的 物品10上，而將物品10表面乾燥，可完成具有裝飾層30 之製品10’。 依此方式獲得的水壓轉印物品之裝飾層3 0，丨系在水壓 轉印時使印刷圖型之附著性再現而塗佈於轉印薄膜上之紫 外線硬化樹脂組成物，利用紫外線照射而與印刷圖型渾然 一體化之狀態下被硬化而形成，而具備有耐摩性、耐溶劑 性、耐藥品性、耐候性等之機械及化學的表面保護功能， -23- (20) (20)1331099 由於該點而不必形成先前技術中爲必要的表面保護層（頂 被覆層），因而可提供以水壓轉印形成的裝飾層做爲物品 之外觀最表面之製品（水壓轉印物品）。依此方式，不需 形成表面保護層（頂被覆層）之時，則在形成頂被覆層之 時灰塵附著的機會消失，因而可獲得灰塵附著少、良品率 高之製品。 並且，藉由本發明所得到之水壓轉印物品之重要特徵 ，爲依此方式獲得的裝飾層，可避免由於表面保護層而減 少先前技術慣有的美工設計表現。又，如下面將詳述者， 依此方式獲得的裝飾層，可獲得先前技術所無法達成的美 工設計表現。 將以木紋圖案之印刷圖型水壓轉印後的製品爲例，而 參照第4圖詳細說明本發明之實施形態。該製品（水壓轉 印物品）100，爲裝小件東西用之蓋的形態之ABS樹脂成 型的基材（被轉印物品）102所製成，裝飾層130係在該 基材102周圍的垂直部及與該部連續的上面，介由第2圖 所示的水壓轉印方法而將不勻整紋理等之印刷圖型轉印而 形成。爲基材102原料之ABS樹脂本身，係已經一樣地 被施以淡褐色之著色，因而裝飾層130係具有將印刷圖型 之墨水之顏色重疊於淡褐色之底色上之不句整紋理圖案。 裝飾層130之圖案部分130A，係表現形成於不勻整 紋理圖案之內的春上比較粗的組織之早材部分的部分，將 淡褐色之墨水以極低濃度轉印到淡褐色之底色上，而顯現 以褐色爲背景而褐色的脈絡延伸到各個地點之外觀。並且 -24- (21) (21)1331099 ’裝飾層130之圖案部分130B，係表現形成於不勻整紋 理圖案之內的夏上比較緻密的組織之晚材部分的部分，主 要將黑色之墨水及焦褐色以極高濃度轉印到淡褐色之底色 上，因此底色之淡褐色幾乎隱蔽，而顯現焦褐色或幾乎近 於黑的色之外觀。並且，裝飾層130之圖案部分130C， 係在表現晚材部分的圖案部分130B與表現早材部分的圖 案部分13 0A的疆界接縫附近，如黑色點所在而顯示的圖 案部分，如第5圖放大而顯示者，導管以直角被切斷之時 的切口之被觀察部分。 依此方式之裝飾層130中，將表現晚材部分的圖案部 分130B與表現早材部分的圖案部分130A對比之時，晚材 部分的光澤度係極度地減少之感覺，相對於此，早材部分 則無此光澤度極度減少之感覺，因此在其等之間可辨別光 澤度的差異。 進行種種的試驗而判明，在水壓轉印時爲了使印刷圖 型之附著性再現而在轉印薄膜上塗佈的紫外線硬化樹脂組 成物，視印刷圖型之墨水中的顏料之種類而有容易被吸收 、難以被吸收者，例如，黑墨水中之碳黑等之高吸油性成 分，很容易將紫外線硬化樹脂組成物進行吸油，因此多量 地添加這些顔料的墨水被轉印的墨水印刷部分上，露出顏 料之粒子感（微細凹凸）之狀態下被硬化，因而顯示可看 出光澤感被減少的低光澤圖案部，另一方面，添加難以吸 收紫外線硬化樹脂組成物之顔料等的低吸油性成分之墨水 被轉印的墨水印刷部分，或以低濃度將墨水轉印的墨水印 -25- (22) (22)1331099 刷部分上，紫外線硬化樹脂組成物並未被吸油太多，而被 埋入顏料之粒子間硬化，因此保持光澤感而顯示出高光澤 圖案部。 依此方式，藉由本發明所得到之水壓轉印物品，晚材 部分係成爲低光澤圖案部，早材部分係成爲高光澤圖案部 ，利用這些光澤感的差異鄰接存在所造成的光澤變化性而 賦予立體感，並且黑色點存在的部分亦成爲低光澤圖案部 ，似導管以近乎直角被切斷之時的切口，可看出有深度的 孔一般，因此裝飾層130全體上被賦予原木感、年輪接板 接縫或正木紋之質感。當然，不僅可提供具有可感受到不 勻整紋理或正木紋之一般的木紋，而且可感受到將瘤或枝 之根本的部分或產生樹脂的部分等切斷之時所表現、特定 種類的樹木表現多者，例如玉木紋、泡木紋、葡萄木紋、 鳥眼木紋、如鱗木紋之高級木紋的質感木質感之裝飾層的 製品（水壓轉印物品）。 又，含有消豔成分的紫外線硬化樹脂組成物，與印刷 圖型成渾然一體化狀態而被硬化之時，該消豔成分介由高 光澤圖案部而有効地作用，因此可使高光澤圖案部與低光 澤圖案部之差異縮小，而使全體的色調消失，因而可提供 侘、寂等之雅緻之感覺的水壓轉印物品。 而，雖然紫外線硬化樹脂組成物’視印刷圖型之墨水 中的顏料種類，而有容易吸收、難以吸收者，容易對紫外 線硬化樹脂組成物吸油之高吸油成分，並非在紫外線硬化 樹脂組成物上實際測定而確認者，一般的吸油量方面，從 -26- (23)1331099 記載於技術文獻上的數値推 碳黒或松煙，碳黑的吸油量 60〜158，這些顔料的吸油量 係紫外線硬化樹脂組成物被 爲容易吸收紫外線硬化樹脂 ，有沉降性硫酸鋇等之體質 料的珪藻土、吸油量54之 色顏料、吸油量74之藍顏 、吸油量72之黃色顏料的 著色顏料，除了係考慮該吸 慮耐光性等之色的腿色對策 並且，使用先前技術之 圖型上而進行的水壓轉印所 或多或少會將活性劑或墨水 料中，介由墨水之顏料的種 使光澤差或多或少表現。但 之活性劑而製成的裝飾層之 做成以裝飾層做爲外觀最表 飾層上之表面保護層，而減 明，利用紫外線硬化樹脂組 轉印而獲得的裝飾層，其吸 顯著’所以較先前技術更有 依此方式，本發明之水 之水壓轉印物品的水壓轉印 定之時，被掲示有爲黑顏料的 指標係爲1〇〇~258，松煙則爲 ，相差一個位數之高，推想應 顯著地吸收。其它被認爲可做 組成物之高吸油成分的顏料中 顏料、或吸油量47之體質顏 紅色系顏料之用黃土製成的紅 料的紺青（ultramarine blue) 黃土。而，各色墨水中使用的 油量之大小而加入之外，尙考 而選定之時較佳》 活性劑，將附著性再現於印刷 獲得的先前技術之裝飾層，亦 成分一起吸收到裝飾層內之顏 類或墨水濃度造成的吸收差而 是，如已述者，使用先前技術 表面保護功能不足，因而無法 面之製品，因此介由施加於裝 少美工的表現，相對地如本發 成物而再現附著性的印刷圖型 收樹脂成分之容易度之影響很 利。 壓轉印物品及在製造該本發明 方法之中，雖然使用無溶劑型 -27- (24) (24)1331099 之紫外線硬化樹脂組成物可獲得種種的優點，但是所謂使 用於該水壓轉印方法中之無溶劑型之紫外線硬化樹脂組成 物中的「無溶劑型」，並非溶劑成分絕對爲零之意，只要 紫外線硬化樹脂組成物中之非活性化溶劑成分，可使典型 的光聚合性單體之印刷圖型的再附著化功能可必要且充分 地獲得的話即可，並非排除了基於其它理由而添加溶劑成 分’或排除殘留有製造單體或預聚體時使用的溶劑成分者 。並且同樣地，「無溶劑型」，並非光聚合性單體之揮發 性絕對爲零之意，而係如溶劑含量不那麼高之程度者，當 然亦可在實用上具有可忽略之程度的揮發性。 (實施例） 由將光澤差賦予物品之裝飾層上之本發明的實施例1 至4及比較例1至7說明如下。 (實施例1 ) 在本發明之具體的實施例1中，使用將轉印薄膜之墨 水的附著性再現所用之日本大橋化學工業株式會社製之商 品名稱爲「優比克S克利亞33-N2」的無溶劑型之紫外線 硬化樹脂組成物，使具有木紋圖案的轉印薄膜之墨水的附 著性以該紫外線硬化樹脂組成物而再現，在l〇crnx2〇Cmx 3mm之ABS樹脂製之平板上，以第2A圖至第2G圖所示 的工程順序，將轉印薄膜上之木紋圖案進行水壓轉印。轉 印薄膜，係將黑色或焦褐色之脈絡之晚材部分與其間之褐 -28- (25) (25)1331099 色的早材部分清楚地表現的方式，而以濃的墨水將木紋圖 案印刷而形成，使用丘比克株式會社對水壓轉印技術之技 術合作者授權販賣稱爲「ZEBRA LINE」之商品名的轉印 薄膜，並且上述之無溶劑型之紫外線硬化樹脂組成物，在 將轉印薄膜正要導入轉印槽內之前，以刮棒塗佈方法而塗 佈於轉印薄膜之印刷圖型上。依此方法將具有塗佈之無溶 劑型之紫外線硬化樹脂組成物的轉印薄膜，飄浮於轉印槽 之水面上，利用該紫外線硬化樹脂組成物使印刷圖型之附 著性再現之後，如第2D圖所示，介由轉印薄膜將物品壓 入水中，在轉印後，將物品從水中取出，並照射紫外線， 進行水洗 '乾燥而獲得（製品）水壓轉印物品。 (實施例2 ) 在本發明之具體的實施例2中，除了使用對「優比克 S克利亞33-N2」添加消豔成分而做成消豔規格之日本大 橋化學工業株式會社製之商品名稱爲「優比克S消豔克利 亞33-N2」的無溶劑型之紫外線硬化樹脂組成物以外，其 它與實施例1同樣地處理。 (實施例3 )BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to a hydraulic transfer article in which a printing pattern on a water-soluble film has a decorative layer formed by water pressure transfer, on which a decorative layer is formed. The surface protective layer is not applied, and the decorative layer can be used as the outermost layer. [Prior Art] The water pressure transfer method is a method in which a water-soluble film is coated with a water-soluble printing pattern, and a floating film is floated on the water surface in the transfer tank, and the water-soluble film in the transfer film is water. After wetting, the article (the transferred body) is contacted on the printing pattern of the transfer film on the one hand, and is pressed into the water in the transfer tank on the one hand, and the printing pattern of the transfer film is pressed by water pressure. A method of transferring a decorative layer onto a surface of an article. Then, the ordinary transfer film is formed by printing the printing pattern on the water-soluble film in advance, and the ink of the printing pattern is in a dry state, so the active agent or the diluent must be applied during the transfer. The printing pattern is applied to the printing pattern of the transfer film, and the printing pattern is restored to the adhesion exhibited by the same wet state immediately after printing, which is generally referred to as activation. Further, in order to impart abrasion resistance, solvent resistance, chemical resistance, weather resistance, and the like to the decorative layer formed on the surface of the article, it is necessary to form a surface protective film (top coating layer) on the decorative layer. In this way, when the surface protective film is formed on the decorative layer, the surface gloss can be obtained as a whole, and thus the depth is imparted to the aesthetic design, and therefore, depending on the product of the water-pressure transfer article, it is imparted as a polished finish. A sense of high quality, so it has the performance of the artist. However, the reverse side is the appearance of the surface -5 - (2) (2) 1331099, the whole gloss is the same, for example, on the wood grain pattern, it can not express the taste and texture of the wood, the texture, and the texture The reason for the limits of performance. On the other hand, even if the decorative layer is not formed when the surface protective layer is not formed, it does not necessarily mean that the taste and texture of the house and the elegant taste are not inferior, but in the state without the surface protective layer, the abrasion resistance and the resistance are improved. Since the solvent, chemical resistance, weather resistance, and the like are deteriorated, the final product cannot be formed. Therefore, it is necessary to apply a surface protective layer at the expense of the design of the art design. Further, when the surface protective layer is formed on the decorative layer, a slippery feeling or a low-level feeling is generated when the surface is touched, and therefore, in order to prevent the feeling of slipperiness and impart a high-grade feeling, it is one of the methods without applying a surface protective layer. However, in the same manner as in the above-described art, in order to obtain physical and chemical properties such as abrasion resistance, solvent resistance, chemical resistance, and weather resistance, the surface of the decorative layer is deteriorated in touch and imparts a low level of sensation. The sacrifice is thus applied to the surface protection layer. Therefore, the Applicant considers that the problem of the artist's performance or surface touch may be temporarily put on hold when it is difficult to solve the above-mentioned problem of the artistic performance or the surface touch, as described below, and try to achieve the water pressure transfer. The solution to various problems in printing technology. In the prior art of the first aspect, the surface protective layer is coated with a urethane 2 liquid type paint, an acrylic transparent type paint, and a spray coating method on a decorative layer formed by transferring a printing pattern. Ultraviolet-curing paint, when the ultraviolet-curable paint is irradiated with ultraviolet rays, the paint is cured and formed. However, in this method, the solvent resistance of the decorative layer is not improved, and -6-(3) (3) 1331099 is applied to the surface protective layer (top coating layer) of the decorative layer to withstand abrasion resistance and solvent resistance. And the role of the person, and, after transferring the printed pattern to the article and then washing and drying, the urethane 2 liquid type paint is applied. Therefore, these treatments take a relatively long time, and generally are in terms of drying. Exposed to the hot air, the decorative layer is liable to adhere to dust, and thus the appearance of the decorative layer is reduced. In the prior art of the second aspect, there has been proposed a method of simultaneously printing a water pressure transfer and a surface protective layer of a pattern (refer to Patent Document 1). In the method, on the water-soluble film, in addition to the transparent or translucent surface protective layer made of a water-insoluble resin, a water-insoluble printing layer is applied thereon to form a protective layer-attached layer. A film is printed, and then the transfer film with the protective layer is water-pressure-transferred onto the article (the object to be transferred). In the method of water pressure transfer, when the surface of the article is brought into contact with the transfer film by water pressure, the surface protective layer and the printed layer on the water-soluble film are simultaneously transferred to the surface of the article, so as described above. In the prior art, there is no need for a coating process and a hardening process for protecting the paint after the transfer process, and no dust adheres between the decorative layer and the surface protective layer. In this way, although the method can form a surface protective layer at the same time as the transfer of the printing layer, and the work engineering is simplified, and the appearance of the decorative layer is not bad, the surface protective layer is denatured by butyl. Since the acrylic copolymer is formed of a low solvent-resistant protective agent such as an ethyl-modified acrylic copolymer, the surface of the printed layer of the article can be mechanically protected by imparting abrasion resistance or the like, but it is compatible with the solvent. Or the lack of chemical protection, such as easy deterioration of the drug when it comes into contact. (4) (4) 1331099 A third prior art using ultraviolet curable resin on the surface protective layer of the second prior art is proposed (see Patent Document 2). In the prior art of the third aspect, although the surface protective layer is made of an ultraviolet curable resin, it is effective to mechanically or chemically protect the surface of the decorative layer, but as will be described later, the printed image is printed on the outermost surface of the transfer film. At the time of reproduction, there are several less popular disadvantages. That is, in the above-mentioned first to third prior art, at the time of transfer, although the active agent or the diluent is applied to the printing pattern of the transfer film, the printing pattern is reproduced. Adhesion, but the use of organic solvents in such active agents or diluents must be reserved in the engineering conditions for the evaporation of the solvent components to the end of the time or drying conditions, if the solvent components remain in the printing pattern transfer When it is on the decorative layer, it will have a bad influence on the quality. In the operation, the organic solvent is released into the atmosphere and is inhaled by the human body. Therefore, when the organic solvent is used for the activation of the printing pattern, it becomes an organic atmosphere. The culprit of pollution or the health disorder of workers has become a problem that cannot be taken early against these problems. Therefore, the applicant has also attempted to observe the environmentally-compatible paint as the ultraviolet-curable paint which has been used in the prior art of the above first, and directly apply it to the printing pattern of the transfer film. Although the printing pattern ink can temporarily reproduce the adhesion, when it is consistently operated in the hydraulic transfer engineering, it is found that the adhesion of the printing pattern at the time of transfer is lowered, resulting in poor transfer. Further, when the ultraviolet curable ink of the same ultraviolet curable resin composition was used and the coloring pigment was not mixed, the same -8-(5) (5) 1331099 test was carried out and observed, and it was found that the ink of the printed pattern can be reproduced. The adhesion of the printed pattern at the time of transfer is not lowered, so that transfer can be performed. At the time of water pressure transfer, not only the ink of the printing pattern is restored to the wet state but the adhesion is reproduced, and the water-soluble film supporting the printing pattern is also wetted by the water in the transfer tank, and is pressed in the article. When entering the water, both the printed pattern and the water-soluble film must be fixed to the surface of the article. Thus, during the period of the reconciliation of the wet state of the two, the article must be pressed into the water, and the adhesion adapted to the surroundings of the article must be reproduced until the transfer is completed. Therefore, the result of these attempts differs from the fact that the same ultraviolet curable resin composition is used, and the composition of the ultraviolet curable paint and the ultraviolet curable ink is different, although the ultraviolet hardening paint is applied. It contains a low-boiling solvent, but it does not contain a solvent in the ultraviolet-curable ink. Therefore, when the ultraviolet-curable paint is applied to a printing pattern, the solvent is added to the original coating. Sexual reproduction, in the point of transfer, the solvent is volatilized to reduce the adhesion, and on the other hand, the ultraviolet curable ink does not contain a solvent component, so it is presumed that some of the non-violet-curable ink should be The solvent component is used to reproduce the adhesion, and various tests and the like are repeatedly performed, and a method for solving various problems in the prior art is proposed. The solution includes applying a solvent-free ultraviolet curable resin composition to a printing pattern of a transfer film, and adhering the printing pattern through the non-dissolved active component in the ultraviolet curable resin composition. Reproduced (6) (6) 1331099 works, the surface of the article is pressed against the printing pattern containing the ultraviolet curable resin composition, and the article is pressed into the water together with the transfer film, and the ultraviolet rays are irradiated to the substrate. In the above-mentioned work, the article in which the printing pattern of the ultraviolet curable resin composition is transferred, and the ultraviolet curable resin composition and the printing pattern are hardened in a state of being integrated, and the decorative layer is formed (unpublished) Patent Documents 3 and 4). In the process of completing the invention, the applicant has confirmed that the decorative layer of the hydraulically-transferred article obtained by the hydraulic transfer method has at least the adhesion to the surface of the article and solvent resistance, so that even When there is no surface protective layer, it can also be made into a product. Further, the applicant has confirmed that the water pressure transfer article obtained by the hydraulic transfer method can achieve a change in the decorative design of the decorative layer without using the surface protective layer. The performance of the change in the design of the decorative layer will be explained. For example, when the decorative layer formed by the water-pressure transfer is observed on the printed pattern of the wood grain pattern, although the layer portion of the early wood portion is observable Glossy, but the black ink is printed at a high concentration and the layer portion of the late wood portion is not observed to have a glossy feeling. When the difference in gloss is adjacent, the three-dimensionality of the log can be felt. . The difference in gloss is supposed to occur for the following reasons. In other words, at the time of water pressure transfer, the ultraviolet curable resin composition applied to the surface of the transfer film in order to reproduce the adhesion of the printing pattern is absorbed by the coloring pigment in the black ink, so that it is black. When the ink is transferred at a high concentration (layer portion), the particle sensation of the pigment is exposed and is cured by ultraviolet rays-10-(7) (7) 1331099, so that the gloss is lowered, and on the other hand, the ink other than the black ink is used. At the position where the transfer position or the black ink is transferred at a low concentration, the ultraviolet curable resin composition is not attracted to oil, and thus is embedded in the pigment to be ultraviolet-cured, so that the fine unevenness maintains a slight gloss. It is speculated that these should be the cause of the difference in gloss. Therefore, various confirmation tests and the like are repeatedly performed from the viewpoint of the art design based on the estimation. [Patent Document 1] Japanese Patent Application Laid-Open No. Hei. No. Hei. No. 2003-305998 [Patent Document 3] Japanese Patent Application No. 2003-156439 [Patent Document 4] Japanese Patent Application No. 2003-409874 The first basic object of the present invention is to provide a hydraulic transfer method in which the decorative layer itself on the article has a mechanical and chemical surface protection function such as adhesion and solvent resistance, and does not form a surface protective layer. The decorative layer can be used as the outermost surface of the appearance, and the gloss variability of the surface of the decorative layer can be improved. Another object of the present invention is to provide a water pressure transfer method which forms a portion having a glossy feeling and a reduced gloss on a decorative layer, and a difference in glossiness can be imparted to the decorative layer. Still another object of the present invention is to provide a water pressure transfer method for imparting a three-dimensional feeling to a decorative layer according to a difference in glossiness, which senses a sense of wood, texture, physical sense, freshness, and sensation. The work of 侘, 之, elegance, and so on, thus giving the rich design of the art that the prior art has never had. A still further object of the present invention is to provide a hydraulically-transferred article, -11 - (8) (8) 1331099 which allows the decorative layer body to have a surface protection function while improving its gloss variability and enhancing the appearance of the appearance. SUMMARY OF THE INVENTION A feature of the present invention is to provide a water pressure transfer method for transferring a print pattern of a water-soluble film onto a surface of an article after the wet print pattern is wetted. A water pressure transfer method for forming a decorative layer on the surface of the article, characterized in that in order to wet the printing pattern, a solvent-free ultraviolet ray containing a photopolymerizable monomer is applied to the printing pattern. In the cured resin composition, the solvent-free ultraviolet curable resin composition containing the photopolymerizable monomer is impregnated into the above-described printing pattern, and after the water pressure transfer, the ultraviolet curable resin composition is cured by ultraviolet rays, and the reaction is carried out. The amount of oil absorbed by the pigment of the ink of the printing pattern and the concentration of the ink, the gloss of the high gloss pattern portion and the low gloss pattern portion are applied to the ink printed portion of the decorative layer, and the first feature of the present invention is as follows. The low-gloss pattern portion is determined to have a gloss of 20 or less according to the industrial specification Z874 1 - 997 "method 3-60 degree specular gloss"; The difference in gloss between the pattern portion and the low-gloss pattern portion is one or more in accordance with Japanese Industrial Standard Z8741-1997 "Method 3-60 degree specular gloss". According to a first aspect of the invention, the ultraviolet curable resin composition contains a deodorant component. The deodorant component has a function of imparting a glazing effect to the high gloss pattern portion and the low gloss pattern portion. With respect to the first feature of the present invention, wherein the printed pattern has the wood grain pattern -12-(9) (9) 1331099, the high-gloss pattern portion of the decorative layer corresponds to the coarse structure in the wood grain pattern of the printed pattern. The expression portion, and the low-gloss pattern portion of the decorative layer corresponds to the dense tissue representation portion of the wood pattern of the printed pattern; and the coarse tissue representation portion corresponds to the early material portion, and the dense tissue representation portion corresponds to the late material In part, the outermost decorative layer is the appearance of uneven texture or positive grain. According to a second aspect of the invention, there is provided a hydraulic pressure transfer article comprising the decorative layer formed by the first feature. In the present invention, the "ink concentration" means "the composition of the ink, that is, the content ratio of the pigment in the resin to the pigment". In this manner, the solvent-free ultraviolet curable resin composition applied to the transfer film during the water-pressure transfer is irradiated by the ultraviolet rays after the transfer, and the printing pattern is in an integrated state. Since it is hardened and formed, it has physical and chemical surface protection functions such as abrasion resistance, solvent resistance, chemical resistance, and weather resistance, so that it does not have the prior art as a surface protective layer (top coating layer). The dust which is generated at the time of forming the surface protective layer is adhered, and the yield is improved, and the decorative layer which maintains the performance of the design for the exposed state does not have the surface protective layer applied thereto as in the prior art. (Top coating), which reduces the performance of the art design, and thus provides a product (hydraulic transfer article) that can maintain the performance of the art design. In addition, although the decorative layer and the ultraviolet curable resin composition are cured in a state of being integrated, the ultraviolet curable resin composition is easily absorbed and difficult depending on the type of the pigment in the ink of the printing pattern. The absorber, for example, carbon black which is a color pigment in black ink, -13- 1331099 do) is easy to absorb oil from the ultraviolet curable resin composition, and therefore the position at which these pigments are transferred at a high concentration is transferred (decorative layer portion = In the ink-printed portion, fine concavities and convexities are generated on the decorative layer. Therefore, the low-gloss pattern portion is observed to be lowered in glossiness, and the ultraviolet-curable resin composition is cured to form a convex region. On the other hand, in the position where the ink other than the black ink is transferred or the position where the black ink is transferred at a low concentration (the same decorative layer portion = ink printed portion), the occurrence of fine unevenness is less observed. It is hardened in a state in which the high-glossy high gloss pattern is absorbed, and the ultraviolet curable resin composition is less absorbed, and a concave field having a height lower than that of the convex field is formed. That is to say, the difference in the glossiness echoes the printed pattern and is inevitably adjacent to the producer on the decorative layer. Therefore, due to the difference in the gloss, the decorative layer can be provided with a three-dimensional effect (water pressure transfer) Printed items). The difference in gloss between the adjacent high-gloss pattern portion and the low-gloss pattern portion of the water-pressure-transferred article is preferably 10 or more, but the difference is not large even when it is smaller than the crucible. That is, the measurement using the gloss meter does not cause a visual sensation of 1 〇〇%, and the visual sensation is generally slow in the range of 30 to 60, and when the range is excluded, it becomes sharp. For example, even if the difference in the measured number of gloss is 5, in the range of 30 to 60, the glossiness of the gloss difference of 5 is not greatly changed, but the range is above or below. Within the exclusion range, the difference in gloss is 5, and there is a considerable difference. Of course, the greater the difference in gloss, the greater the feeling. For example, when the gloss of the low-gloss pattern portion is less than 20, it feels dull at almost one eye, from -14- (11) (11) 1331099 However, when the difference between the glossiness of the low-gloss pattern portion and the high-gloss pattern portion adjacent thereto is 10, the difference between the low-gloss pattern portion and the high-gloss pattern portion is not particularly different. However, there is an exception to the fact that the gloss of the high-low gloss pattern portion is in the range of 30 to 60. Further, when the printing pattern is, for example, uneven texture or positive grain, the brown or light brown ink is transferred at a low concentration at the position where the early material portion is expressed, and the ultraviolet curing resin composition is at the position. The degree of absorption is lowered to become a high-gloss pattern portion, and at a position where the late material portion is expressed, black ink or the like is transferred at a high concentration, and the ultraviolet curable resin composition is absorbed at the position to be improved. In the low-gloss pattern portion, when the difference in glossiness is adjacent to each other, the three-dimensional feeling such as the log can be felt, and the position where the black dot is located also becomes a low-gloss pattern portion, and it can be observed that the catheter is nearly right angled. The cut at the time of the ground cut has the same depth as the hole, and therefore the whole can be provided with a product (hydraulic transfer article) which is given a texture of a log, a seam or a positive grain. Of course, not only the uneven grain of the texture or the grain of the wood grain, but also the so-called high-grade woody article which cuts the essential part of the tumor or the branch or the resin-containing portion, etc., can be easily obtained. . Further, when the ultraviolet curable resin composition containing the glazing component is cured in a state in which it is integrated with the printing pattern, the glazing component is effectively acted by the high gloss pattern portion, so that the high gloss pattern portion is low. The difference in glossiness of the glossy pattern portion tends to be reduced, and the entire color tone is lost, so that a product of a feeling of sorrow and silence (hydraulic transfer article) can be provided. -15- (12) (12) 1331099 [Embodiment] Embodiments of the present invention will be described in detail with reference to the accompanying drawings, in which Fig. 1 shows a water pressure of a hydraulically-transformed article of the present invention. In the transfer method, the transfer film 16 formed of the water-soluble film 14 coated on the printing pattern 12 is supplied to the printing pattern 1 2 as the above method. The water-pressure transfer method in which the water-transfer-transferred article 1 is pressed into the water 18 through the transfer film 16 is floated on the water 18 in the transfer tank. The water-soluble film 14 is formed of a water-soluble material containing, for example, polyvinyl alcohol as a main component by water absorption and softening. The water-soluble film 14 is softened by contact with water 18 in the transfer tank at the time of water pressure transfer, and is fixed around an article to be decorated, and is subjected to water pressure transfer. The printing pattern 12 is generally applied to the water-soluble film 14 by gravure printing or the like at the time of water pressure transfer. The water pressure transfer method is characterized in that the ultraviolet curable resin composition, preferably a solventless ultraviolet curable resin composition, is applied to the transfer before the printing pattern 12 is transferred onto the article by water pressure. The printed pattern of film 16 is on top. Hereinafter, a specific example of a hydraulic transfer method for recovering the adhesion of the print pattern 12 after drying of the transfer film 16 will be described with reference to Fig. 2, in which the print pattern 12 is printed in advance in this example. On the water-soluble film 14, the transfer film 16 in which the printing pattern 12 is dried is used to start the operation (see FIG. 2A). Although not shown, the transfer film -16-(13)(13)1331099 film 16 is actually used to continuously run or cut from the film roll to an appropriate length. At the time of the water-pressure transfer, a solvent-free ultraviolet curable resin composition 20 containing a photopolymerizable monomer is applied to the printed pattern 12 in a state after the transfer of the transfer film 16 (see FIG. 2B). In the state in which the adhesion of the printing pattern 12 is reproduced by the solvent-free ultraviolet curable resin composition 20, the transfer film 16 is floated in the water in the transfer tank (refer to 2C)) Next, the article 12 is pressed against the surface i〇s of the article 1 by the printing pattern 12 containing the ultraviolet curable resin composition 20, and the article is pressed into the water together with the transfer film 16 (refer to 2D), the ultraviolet rays 22 are irradiated onto the article 1 on which the printing pattern 12 containing the ultraviolet curable resin composition 20 is transferred, and the ultraviolet curable resin composition 20 and the printed pattern 12 are applied. It is hardened (refer to Figure 2E). However, although not shown, the article 1 is actually transported by a conveyor belt of an inverse triangle and supported by a robot arm, and is pressed into the water 'and' depending on the case, and may be solvent-free. The ultraviolet curable resin composition 20 is applied to the printing pattern 12 (see Fig. 2B), and is reversed from the engineering sequence of the project floating on the water (see Fig. 2C), and the solventless ultraviolet curing is performed. The resin composition is sprayed onto the printed pattern of the transfer film floating on the water to reproduce the adhesion of the printed pattern. The ultraviolet curable resin composition is a resin composition which is hardened by a chemical action of ultraviolet rays in a short period of time, and may be used in an ultraviolet curing type, an ultraviolet curing type ink, or an ultraviolet curing type adhesion depending on the application. (14) 1331099 Forms of agents, etc. These forms are basically made of (1) photopolymerizable prepolymer, (2) photopolymerizable monomer, and (3) photoinitiator as essential components. By. In the case of the ultraviolet curable paint which is sold in the market, a solvent such as a diluent is generally added. In the case of the ultraviolet curable ink, the solvent is added with ethanol or the like, but the ultraviolet curable ink generally does not contain a solvent. In the present invention, the "ultraviolet-curing resin composition" required for the water-pressure transfer method is not limited to the use of the ultraviolet curable resin. In addition, a photopolymerizable prepolymer, a photopolymerizable monomer, and a photoinitiator are used as an essential component, and the property of 'curing without using a solvent' is hardened by ultraviolet irradiation. Therefore, the "ultraviolet-curing resin composition" using the water-pressure transfer method described herein is a solvent-free ultraviolet curable resin composition, and only the solvent-free ultraviolet curable resin composition to which no solvent is added is limited. The reason for this is that in the hydraulic pressure transfer method, the adhesion of the printing pattern of the transfer film is reproduced, and the non-solvent-activated component in the solvent-free ultraviolet curable resin composition is typically light. Since the polymerizable monomer is formed, it is based on the idea that various advantages are obtained without a solvent. An ultraviolet curable resin composition suitable for use as a solventless ultraviolet curable resin composition, for example, a composition having the following composition. (1) Oligomer (photopolymerizable prepolymer) 30 to 50% by weight (2) Polyfunctional acrylic resin (photopolymerizable monomer) 10 to 30% by weight (3) Monofunctional pressure Force resin (photopolymerizable monomer) 10~40 weight -18- (15) (15) 1331099 % (4) Light start agent 0. 5 to 5% by weight (5) Non-reactive additive 1 to 2% by weight Photopolymerizable prepolymer, which is photochemically used to obtain a more hardened polymer, which is called a photopolymerizable unsaturated polymer. Or it may be called a base resin or a photopolymerizable oligomer. Then, it is the basic component that affects the basic properties of the film as a hardened film. According to the required characteristics, the acrylic oligomer can be made into a polyester polyester pavilion. Any one of the oligomers 'urethane acryl oligomers and the like can be used singly or in any combination. On the other hand, the photopolymerizable prepolymer has a degree of polymerization which is not very high in the degree of the final polymer, but it is not a monomer, but is a certain degree of polymerization, and therefore has an appropriate viscosity, and the workability at the time of use is considered. It is made to have a thinner. The photopolymerizable monomer, which functions as a diluent for the photopolymerizable prepolymer, ensures the practical workability of the resin composition, and when irradiated with ultraviolet rays, it is itself connected to the aggregator. The functional group is a monofunctional monomer having one and a polyfunctional monomer having two. The monofunctional monomer has a function of improving the adhesion to the article and imparting flexibility to the cured coating film, and the polyfunctional monomer has a crosslinking agent which causes cross-linking between the prepolymer molecules. The function of the character. For example, polyacrylate such as polyacrylic acid methyl group is used for the purpose of alleviating the shrinkage action of the coating film by crosslinking. When the shrinkage force of the coating film becomes high, the adhesion of the coating film is lowered. Therefore, although the polyacrylate is used as a diluent for adjusting the viscosity of the ultraviolet curable resin composition, in the water pressure transfer- 19-(16) (16) 1331099 In the method, it can also function as a functional component for reproducing the adhesion of the printed pattern in a dry state. The photoinitiator is a photopolymerization initiator which absorbs ultraviolet rays and starts to polymerize. When the ultraviolet curing reaction is a radical reaction, acetophenone, benzophenone, etc. can be used. When the reaction is an ionic reaction, a thiazole compound or the like can be used. In the ultraviolet curable resin composition, other sensitizers, sputum materials, inactive organic polymers, leveling agents, thixotropy-imparting agents, and thermal polymerization prohibition may be added as needed. Agent, Xiaoyan ingredients, etc. In particular, as will be described later in detail, the glazing component can be effectively used in promoting the performance of the decorative design of the decorative layer of the water-pressure-transferred article obtained by the present invention. The coating of the solventless type ultraviolet curable resin composition 20 is preferably carried out using a gravure cylinder coating method or a bar coating method. When the solventless ultraviolet curable resin composition 20 is applied onto the printing pattern 12, the photopolymerizable monomer in the solventless ultraviolet curable resin composition 20 is immersed in the dried ink of the printing pattern 12. In the middle, it is dissolved, and the same adhesion as that immediately after printing is reproduced on the printing pattern 12. Therefore, the solvent-free ultraviolet curable resin composition 20 can exhibit the same function as the active agent commonly used in the prior art, and of course, the coating of the active agent or the diluent can be omitted. The respective components of the cured resin composition are generally relatively low in volatility compared with a solvent, etc., so that the adhesion of the reproduction can be changed afterwards, and -20-(17) (17) 1331099 is less likely to be lowered, so that Achieving stable activation of the above printing patterns for the above. Further, when the printing pattern 12 is transferred onto the article 10, and the ultraviolet ray 22 is irradiated, each component of the ultraviolet curable resin composition such as a photopolymerizable monomer penetrates into the ink of the printing pattern 12, The two are cured in a state of being integrated, and mechanical properties such as abrasion resistance are imparted to the decorative layer, and a chemical surface protection function such as solvent resistance and chemical resistance is imparted. In addition, in FIG. 2B, although the ink component of the printing pattern 12 and the ultraviolet curable resin composition 20 are not shown in a state of being integrated, it is understood that if this is expressed on the drawing, both It becomes indistinguishable, so it is convenient to describe it in layers. Further, after the ultraviolet ray irradiation, the photopolymerizable monomer itself participates in the polymerization, so that it is freed, and thereafter, no problem occurs. In the case of the water pressure transfer method, when a solventless ultraviolet curable resin composition is used, various advantages are obtained, which will be described in detail below. Even when using a UV-curable resin composition which is generally added with a solvent such as an ultraviolet curing paint, there is no disadvantage to the activation of the printing pattern, but it is understood to be more advantageous or not. Since the resin is hardened by ultraviolet irradiation for a short period of time, when the added solvent is a solvent having a high volatility and a low boiling point, it will volatilize when the article is pressed into water, and thus the adhesion is insufficient to cause transfer failure. On the other hand, when a volatile high-boiling solvent is added, the problem of insufficient adhesion can be avoided when the article is pressed into water. However, in the ultraviolet irradiation operation, the solvent must be completely volatilized for a certain period of time, in the solvent. Volatile incomplete-21 - (18) (18) 1331099 When ultraviolet rays are irradiated to cause the solvent to be encapsulated, and the ultraviolet curable resin is hardened, defects are subsequently generated. Therefore, regardless of the low boiling point solvent or the high boiling point solvent, when the ultraviolet curable resin composition containing the solvent is added, in addition to the health hazard due to atmospheric pollution or human absorption, various problems in engineering processing or quality are caused. Less used. On the other hand, when a solventless ultraviolet curable resin composition is used as a part of the description, the photopolymerizable single system is used for the purpose of adjusting the viscosity, and can function as a diluent, so that it is compatible with the solvent. In comparison, it is possible to blend more, and thus the non-solvent-activated component in the solvent-free ultraviolet curable resin composition, which is typically only acted upon by the photopolymerizable monomer, can provide necessary and sufficient stable adhesion. In the case where the ultraviolet curable resin composition 20 is integrated with the printing pattern 12 and hardened, the photopolymerizable monomer having a function equivalent to the solvent used in the prior art itself participates in the polymerization. Thereafter, the photopolymerizable monomer is made free and does not have any defects. However, it must be understood that, as described above, the hydraulically-transferred article 'of the present invention is not obtained by a hydraulic transfer method of applying a solvent-free ultraviolet curable resin composition, and therefore, if the above advantages are not obtained, In the case of the number, it is also possible to obtain a method of applying a water pressure transfer method containing a solvent-type ultraviolet curable resin composition. Preferably, when the ultraviolet ray 22 is irradiated, the water-soluble film 14 of the transfer film 16 is wound around the article 1 on which the printing pattern 12 of the ultraviolet ray-curable resin composition 20 is transferred, so that ultraviolet rays are formed. Irradiation -22-(19) (19) 1331099, preferably after the article 10 has not entered the water, or after the article 10 has emerged from the water, it is preferred to perform the water washing operation in order to remove the water-soluble film 14. The ultraviolet light 22 is irradiated by a known ultraviolet curing device such as a light source lamp containing a low-pressure or high-pressure mercury lamp, a metal halide lamp, and an illuminator (light cover). In this manner, when the water-soluble film 14 is wound on the article 1 and irradiated with ultraviolet rays, the printing pattern 12 is not adhered and fixed before being completely dried, and the water-soluble film 14 is removed. In the above, the printing pattern 12 is hardened to reduce the possibility of adhesion of dust or the like, so that the decorative layer 30 having a good appearance can be easily obtained. On the other hand, when the ultraviolet ray 22 is irradiated in an environment where there is no dust such as a tunnel in a green environment room, it is of course possible to carry out ◊ after the water-soluble film 14 is washed and discharged from the article 1 〇. Thereafter, as shown in Fig. 2F, the article 1 is sprayed with the flushing water 24, and the water-soluble film 14 of the transfer film 16 covered in the state of the article 10 can be removed. Next, as shown in Fig. 2G, the hot air 26 is blown onto the article 10 on which the printing pattern 12 containing the ultraviolet curable resin composition 20 is transferred, and the surface of the article 10 is dried to complete the article 10 having the decorative layer 30. '. The decorative layer 30 of the water-pressure-transferred article obtained in this manner is an ultraviolet-curable resin composition which is applied to the transfer film by reproducing the adhesion of the printing pattern during water-pressure transfer, and is irradiated with ultraviolet rays. It is formed by hardening in a state of being integrated with a printed pattern, and has mechanical and chemical surface protection functions such as abrasion resistance, solvent resistance, chemical resistance, and weather resistance, -23- (20) (20 1331099 Since it is not necessary to form a surface protective layer (top coating layer) which is necessary in the prior art, it is possible to provide a decorative layer formed by water pressure transfer as the outermost surface of the article (hydraulic transfer article) ). In this manner, when the surface protective layer (top coating layer) is not required to be formed, the chance of dust adhesion disappears when the top coating layer is formed, so that a product having less dust adhesion and a high yield can be obtained. Further, the important features of the water-pressure-transferred article obtained by the present invention are the decorative layers obtained in this manner, thereby avoiding the reduction of the prior art design performance due to the surface protective layer. Further, as will be described in detail below, the decorative layer obtained in this manner can obtain an artistic design performance that cannot be achieved by the prior art. An embodiment of the present invention will be described in detail with reference to Fig. 4, taking a product of a water pattern transfer of a wood grain pattern as an example. The product (hydraulic transfer article) 100 is made of a base material (transferred article) 102 molded in a form of a cover for a small item, and a decorative layer 130 is provided around the substrate 102. The vertical portion and the upper surface continuous with the portion are formed by transferring a printing pattern such as uneven texture to the water pressure transfer method shown in Fig. 2 . The ABS resin itself, which is the raw material of the substrate 102, has been subjected to the same pale brown color, and thus the decorative layer 130 has a texture pattern in which the color of the ink of the printing pattern is superimposed on the base color of the light brown color. . The pattern portion 130A of the decorative layer 130 is a portion of the early wood portion of the relatively thick tissue formed in the uneven texture pattern, and the light brown ink is transferred to the base of the light brown at a very low concentration. And the appearance of a brownish background with a brown background extends to the appearance of each location. And -24-(21) (21) 1331099 'the pattern portion 130B of the decorative layer 130 is a portion of the late-maturing portion of the relatively dense tissue formed in the uneven texture pattern, mainly black ink and The brownish brown color is transferred to the base of the light brown at a very high concentration, so that the light brown color of the base color is almost concealed, and the appearance of a brownish-brown or almost black color appears. Further, the pattern portion 130C of the decorative layer 130 is in the vicinity of the boundary portion between the pattern portion 130B representing the late wood portion and the pattern portion 130A representing the early material portion, such as the pattern portion displayed as the black dot, as shown in FIG. Enlarged to show the observed portion of the incision when the catheter is severed at a right angle. In the decorative layer 130 in this manner, when the pattern portion 130B representing the late wood portion is compared with the pattern portion 130A representing the early material portion, the gloss of the late wood portion is extremely reduced, and in contrast, the early material is In some cases, there is no such feeling that the gloss is extremely reduced, so the difference in gloss can be discerned between them. In the various tests, it was found that the ultraviolet curable resin composition applied to the transfer film in order to reproduce the adhesion of the printing pattern during the water pressure transfer depends on the type of the pigment in the ink of the printing pattern. It is easy to be absorbed and is difficult to be absorbed. For example, a highly oil-absorbing component such as carbon black in black ink, it is easy to absorb the ultraviolet curable resin composition, so that a large amount of ink to which these pigments are added is transferred to the ink printing portion. In the state in which the particle sensation (fine concavities and convexities) of the pigment is exposed, the low-gloss pattern portion in which the glossiness is reduced is displayed, and the low oil absorption such as the pigment which is difficult to absorb the ultraviolet curable resin composition is added. The ink of the sexual component is transferred to the ink printing portion, or the ink is transferred at a low concentration to the ink portion of the -25(22)(22)1331099 brush portion, and the ultraviolet curable resin composition is not sucked too much, and Since the particles embedded in the pigment harden, the gloss is maintained and a high-gloss pattern portion is exhibited. According to this aspect, in the water-pressure-transferred article obtained by the present invention, the late-light portion is a low-gloss pattern portion, and the early-material portion is a high-gloss pattern portion, and the gloss variability caused by the difference in the glossiness is adjacent thereto. The portion which gives a three-dimensional effect and the presence of the black dots also becomes a low-gloss pattern portion, and the slits at the time when the catheter is cut at a nearly right angle can be seen, and the depth of the holes is generally observed, so that the decorative layer 130 is given a log feeling as a whole. The texture of the annual ring joints or the positive wood grain. Of course, it is possible to provide not only a general wood grain which can feel an uneven texture or a positive grain, but also a specific type of tree which is expressed when a part of a tumor or a branch or a resin-generating part is cut off. A product that has many performances, such as jade wood grain, wood grain grain, grape wood grain, bird eye wood grain, decorative wood layer of high-grade wood grain such as scale wood grain (water pressure transfer article). In addition, when the ultraviolet curable resin composition containing the deodorant component is cured in a state of being integrated with the printing pattern, the deodorant component acts effectively through the high gloss pattern portion, so that the high gloss pattern portion can be obtained. The difference from the low-gloss pattern portion is reduced, and the entire color tone is lost, so that the water pressure transfer article which provides an elegant feeling such as squatting and silence can be provided. In addition, although the ultraviolet curable resin composition 'is easily absorbed and difficult to absorb depending on the type of the pigment in the ink of the printing pattern, the high oil absorption component which is easy to absorb the ultraviolet curable resin composition is not on the ultraviolet curable resin composition. For the actual measurement, the general oil absorption is from -26- (23) 1331099, which is described in the technical literature, and the carbon absorption is 60 to 158. The oil absorption of these pigments is The ultraviolet curable resin composition is a coloring pigment which is easy to absorb an ultraviolet curable resin, a diatomaceous earth having a body material such as sedimentary barium sulfate, a color pigment of an oil absorption amount 54, a blue color of an oil absorption amount 74, and a yellow pigment having an oil absorption amount 72. Considering the color of the leg color in consideration of the light resistance and the like, and the hydraulic transfer performed using the pattern of the prior art more or less will be the active agent or the ink material, and the pigment of the ink. This makes the gloss less or less. However, the decorative layer made of the active agent is made of the decorative layer as the surface protective layer on the outermost surface of the appearance, and the decorative layer obtained by the transfer of the ultraviolet curable resin group is reduced, and the suction is remarkable. Therefore, according to the prior art, when the water pressure transfer of the water-pressure transfer article of the present invention is determined, the index of the black pigment is indicated as 1〇〇~258, and the loose smoke is the difference. The high number of digits is supposed to be absorbed significantly. Other pigments that are considered to be high-oil-absorbing components of the composition, pigments, or oil-absorbing substances of 47. Red-based pigments are ultramarine blue loess made of loess. In addition, the amount of oil used in each color ink is added, and the active agent is preferably selected when the reference is selected, and the adhesion is reproduced on the decorative layer of the prior art obtained by printing, and the components are absorbed into the decorative layer together. The absorption difference caused by the concentration of the pigment or the ink is, as already mentioned, the use of the prior art surface protection function is insufficient, so that the product cannot be surfaced, and therefore, the performance is relatively similar to that of the present invention. The ease of the resin composition for reproducing the adhesion of the printed pattern is advantageous. In the press-transfer article and in the method of producing the present invention, although various advantages can be obtained by using the solvent-free type -27-(24)(24)1331099 ultraviolet curable resin composition, the so-called use of the water pressure transfer The "solvent-free type" in the solvent-free ultraviolet curable resin composition in the method is not intended to be absolutely zero in the solvent component, and as long as the inactive solvent component in the ultraviolet curable resin composition can make a typical photopolymerizable property. The re-adhesion function of the printing pattern of the monomer may be obtained as necessary and sufficient, and it is not excluded that the solvent component is added for other reasons or the solvent component used in the production of the monomer or prepolymer is excluded. Similarly, "solvent-free" means that the volatility of the photopolymerizable monomer is absolutely zero, and if the solvent content is not so high, it is of course also practically negligible. Sex. (Examples) Examples 1 to 4 and Comparative Examples 1 to 7 of the present invention in which a gloss difference was imparted to a decorative layer of an article are explained as follows. (Example 1) In the specific example 1 of the present invention, the product name of the U.S. Bridge Chemical Industry Co., Ltd., which is used for reproducing the adhesion of the ink of the transfer film, is "Ubike S. Klia 33-N2". The solvent-free ultraviolet curable resin composition reproduces the adhesion of the ink of the transfer film having the wood grain pattern to the ultraviolet curable resin composition, and is formed on a flat plate made of ABS resin of l〇crnx2〇Cmx 3 mm. The wood grain pattern on the transfer film is subjected to hydraulic transfer in the order of engineering shown in Figs. 2A to 2G. The transfer film is a way of clearly expressing the late part of the black or brown-brown veins with the brown material of the brown -28- (25) (25) 1331099 color, and the wood grain pattern with thick ink. By printing, a transfer film called "ZEBRA LINE" is authorized to be sold by a technical partner of the hydraulic transfer technology of Chubic, and the above-mentioned solvent-free ultraviolet curable resin composition is The transfer film is applied to the transfer pattern of the transfer film by a bar coating method before being introduced into the transfer tank. According to this method, the transfer film having the solvent-free ultraviolet curable resin composition applied is floated on the water surface of the transfer tank, and after the ultraviolet curable resin composition is used to reproduce the adhesion of the printing pattern, As shown in Fig. 2D, the article is pressed into water via a transfer film, and after the transfer, the article is taken out of the water, irradiated with ultraviolet rays, and washed with water to obtain a (product) water-pressure-transferred article. (Embodiment 2) In the second embodiment of the present invention, a product manufactured by Nippon Kasei Chemical Co., Ltd., which is a non-depleted component, is added to the "Ubike Skeria 33-N2". The same procedure as in Example 1 was carried out, except that the solvent-free ultraviolet curable resin composition of the name "Ubike S annihilation Klia 33-N2" was used. (Example 3)
在本發明之具體的實施例3中，除了分別印刷黑及濃 褐色及濃綠色的部分及什麼也未印刷的部分4種配置成比 較大的斑狀，而具有適合十字弓槍等之戶外運動器材之迷 彩圖案的丘比克株式會社之技術合作者以稱爲「MEISAI -29- (26) (26)1331099 DARK」之商品名販賣的轉印薄膜以外，其它與實施例1 同樣地處理。 (實施例4 ) 在本發明之具體的實施例4中，除了將消豔規格之曰 本大橋化學工業株式會社製之商品名稱爲「優比克S消豔 克利亞33-N2」做爲無溶劑型之紫外線硬化樹脂組成物而 使用以外，其它與實施例3同樣地處理。 例 考 參 在本發明之具體的參考例1中，對照於實施例1中使 用的商品名爲「ZEBRA LINE」之轉印薄膜，除了使全體 爲同一基調下，使用不強調晚材部分及早材部分而全體具 有淡褐色之木紋圖案的丘比克株式會社對水壓轉印技術之 技術合作對象授權販賣稱爲「CREATION NATURAL」之 商品名的轉印薄膜以外，其它與實施例1同樣地處理。 (比較例1 ) 在該比較例1中，並非將無溶劑型之紫外線硬化樹脂 組成物使用於轉印薄膜之活性化，除了使用丘比克株式會 社對水壓轉印技術之技術合作對象授權販賣稱爲「CPA-H 」（日本國特許第3385576號之實施品）之商品名的先前 技術之活性劑以外，其它與實施例1同樣地處理。此係使 用和先前技術同樣的水壓轉印技法而獲得僅具有裝飾層、 -30- (27) (27)Ϊ331099 且尙未形成表面保護層之中間製品狀態者。 (比較例2 ) 在該比較例2中，在以比較例1所獲得的裝飾層上， 以噴射方式塗佈日本油脂BASF被覆（COATING)株式會 社製之商品名稱爲「海烏列當No.2000克利亞-G-500 21HP」之氨基甲酸乙醋系之透明塗漆，而進行乾燥形成頂 被覆層。此乃使用先前技術同樣的水壓轉印技法而迄可提 供最終製品之狀態的加工後之水壓轉印物品。 (比較例3 ) 在該比較例3中，在以比較例1所獲得的裝飾層上， 以噴射方式塗佈日本油脂BASF被覆（COATING )株式會 社製之商品名稱爲「海烏列當No.5000殊怕克利亞-G-4 81 HP」之氨基甲酸乙酯系之消豔型透明塗漆，而進行乾燥 形成頂被覆層以外，其它與比較例2同樣地處理。 (比較例4 ) 在該比較例4中，並非將無溶劑型之紫外線硬化樹脂 組成物使用於轉印薄膜之活性化，除了使用丘比克株式會 社對水壓轉印技術之技術合作對象授權販賣稱爲「CPA-H j (日本國特許第33855 76號之實施品）之商品名的先前 技術之活性劑以外，其它與實施例3同樣地處理。 -31 - (28)1331099 (比較例5 ) 在該比較例5中，在以比較例4所獲得的裝飾 以噴射方式塗佈日本油脂BASF被覆（COATING ) 社製之商品名稱爲「海烏列當No.2000克利亞 21HP」之氨基甲酸乙酯系之透明塗漆，而進行乾燥 被覆層。 (比較例6 ) 在該比較例6中，在以比較例4所獲得的裝飾 以噴射方式塗佈日本油脂BASF被覆（COATING ) 社製之商品名稱爲「海烏列當No.5 000殊怕克利 81 HP」之氨基甲酸乙酯系之消豔型透明塗漆，而進 形成頂被覆層以外，其它與比較例5同樣地處理。 (比較例7 ) 在該比較例7中，並非將無溶劑型之紫外線硬 組成物使用於轉印薄膜之活性化，除了使用丘比克 社對水壓轉印技術之技術合作對象授權販賣稱爲「 」（日本國特許第3385576號之實施品）之商品名 技術之活性劑以外，其它與實施例5同樣地處理。 各實施例中轉印時之狀況，任何一個實施例均 技術大致同樣爲可進行水壓轉印者，將各實施例之 的密著性，以圍棋盤膠帶法（1mm圍棋盤目1〇〇克 試驗之後，確認在實施例1至4及參考例1之任何 層上， 株式會 -G-500 形成頂 層上， 株式會 亞-G-4 行乾燥 化樹脂 株式會 CPA-H 的先前 與先前 裝飾層 )進行 一個， -32- (29) (29)1331099 均具有與：未施以將使用先前技術之活性劑而做活性化的 印刷圖型轉印之頂被覆層的比較例1、4、7，或在其裝飾 層上以先前技術之氨基甲酸乙酯系之透明塗漆形成有頂被 覆層的比較例2、3、5 ' 6同等的密著性。 另一方面，在耐溶劑性方面，將含有二甲苯之10片 重疊之紗網，以手抵壓在製品之表面而往復地摩擦8次之 後，確認在任何一個實施例之製品，均顯示可與：以先前 技術之氨基甲酸乙酯系之透明塗漆形成有頂被覆層的比較 例2、3、5、6匹敵程度之良好的耐溶劑性。未施以頂被 覆層的比較例1、4、7之製品，當然其耐溶劑性很差，無 法供做爲將裝飾層做爲最表面之製品。 並且，依照日本工業規格之「鏡面光澤度-測定方法 Z8741 - 1 997」的測定方法之種類「方法3-60度鏡面光澤 」，使用東京電色株式會社製之光澤度計「Gloss MeterModel GP-60」，而測定各實施例及比較例之製品的 光澤度之後，將結果顯示於表（1)及表（2)中。 -33- (30)1331099In a specific embodiment 3 of the present invention, in addition to printing portions of black and dark brown and rich green, and portions of what are not printed, the four portions are arranged in a relatively large spot shape, and have an outdoor movement suitable for a crossbow gun or the like. The technical partner of the company's camouflage pattern is treated in the same manner as in the first embodiment except for the transfer film sold under the trade name "MEISAI -29-(26) (26) 1331099 DARK". (Embodiment 4) In the specific embodiment 4 of the present invention, the product name "Obike S Cyan Klia 33-N2" manufactured by Sakamoto Bridge Chemical Co., Ltd. is used as the non-destructive specification. The solvent treatment was carried out in the same manner as in Example 3 except that the solvent-type ultraviolet curable resin composition was used. In the specific reference example 1 of the present invention, the transfer film having the trade name "ZEBRA LINE" used in the first embodiment is used, except that the whole is the same tone, and the use of the late wood portion and the early material is not emphasized. In the same manner as in the first embodiment, the Chubuk Co., Ltd., which has a light-colored wood grain pattern, is authorized to sell a transfer film called "CREATION NATURAL" under the technical cooperation object of the hydraulic transfer technology. deal with. (Comparative Example 1) In the comparative example 1, the solvent-free ultraviolet curable resin composition was not used for the activation of the transfer film, except for the use of the technical cooperation object of the hydraulic transfer technology by the Chubic Corporation. The same procedure as in Example 1 was carried out except that the active agent of the prior art, which is a trade name of "CPA-H" (Japanese Patent No. 3385576) was sold. This is achieved by the same hydraulic transfer technique as in the prior art to obtain an intermediate product state having only a decorative layer, -30-(27)(27)Ϊ331099, and no surface protective layer. (Comparative Example 2) In the comparative example 2, the product name of the Japanese oils and fats BASF coating (COATING) Co., Ltd. was applied by the spray method to the decorative layer obtained in Comparative Example 1. The 2000 gram-G-500 21HP" is varnished with a urethane acetal and dried to form a top coating. This is a processed water-pressure transfer article which can be used to provide the state of the final product using the same hydraulic transfer technique as in the prior art. (Comparative Example 3) In the comparative example 3, the product name of the Japanese oils and fats BASF coating (COATING) Co., Ltd. was applied by the spray method to the decorative layer obtained in Comparative Example 1. The same procedure as in Comparative Example 2 was carried out in the same manner as in Comparative Example 2, except that the urethane-based clear varnish of 5,000 g of Kelia-G-4 81 HP was dried to form a top coating layer. (Comparative Example 4) In the comparative example 4, the solvent-free ultraviolet curable resin composition was not used for the activation of the transfer film, except for the use of the technical cooperation object of the hydraulic transfer technology by the Chubic Corporation. The same procedure as in Example 3 was carried out except for the prior art active agent of the trade name "CPA-H j (Japanese Patent No. 33855 76). -31 - (28) 1331099 (Comparative Example) 5) In the comparative example 5, the amino acid manufactured by the Japanese oils and fats BASF coating (COATING) manufactured by the method of Comparative Example 4 was coated with the amino acid of "Hei Lureang No. 2000 Kelly 21HP". The ethyl acetate-based clear paint was applied to dry the coating layer. (Comparative Example 6) In the comparative example 6, the product name of the Japanese oils and fats BASF coating (COATING) was applied by the spray method to the decoration obtained in the comparative example 4, and the name of the product was "Hui Lurang No. 5 000. It was treated in the same manner as in Comparative Example 5 except that a urethane-based clear varnish of Kelly 81 HP was used to form a top coating layer. (Comparative Example 7) In Comparative Example 7, the solvent-free ultraviolet hard composition was not used for the activation of the transfer film, except that the technical cooperation object of the hydraulic transfer technology was used by Chubicke. The treatment was carried out in the same manner as in Example 5 except for the active agent of the trade name technique of "" (Japanese Patent No. 3385576). In the case of the transfer in each of the embodiments, any one of the embodiments is substantially the same as the water-pressure transferr, and the adhesion of the respective embodiments is as follows: the board tape method (1 mm. After the gram test, it was confirmed that on any of the layers of Examples 1 to 4 and Reference Example 1, the strain -G-500 was formed on the top layer, and the previous and previous versions of the strained CPA-H The decorative layer) was carried out, and -32-(29)(29)1331099 both had and compared with the top coating layer of the printing pattern transfer which was not activated by using the prior art active agent. 7, or the same adhesion of Comparative Examples 2, 3, and 5' 6 in which the top coating layer was formed by the prior art urethane-based clear coating on the decorative layer. On the other hand, in terms of solvent resistance, 10 sheets of overlapping gauze containing xylene were rubbed back and forth on the surface of the product by hand for 8 times, and it was confirmed that the articles in any of the examples were all visible. And the solvent resistance of Comparative Examples 2, 3, 5, and 6 which were formed with the top coating layer by the urethane-based clear lacquer of the prior art. The articles of Comparative Examples 1, 4, and 7 which were not coated with the top coating were of course poor in solvent resistance and could not be used as the outermost surface of the decorative layer. In addition, the Gloss Meter Model GP-made by Tokyo Electrochrome Co., Ltd. is used according to the type of the method of measuring the "mirror gloss-measurement method Z8741 - 997" of the Japanese Industrial Standard "Method 3-60 degree specular gloss". 60. After measuring the glossiness of the products of the respective examples and comparative examples, the results are shown in Tables (1) and (2). -33- (30)1331099
-34- (31) (31)1331099-34- (31) (31) 1331099
如表1所示，實施例1係晚材部分與早材部分之光澤 度差異很明顯#，相對於此，_ 2所示比較例i係完 全沒有it些部分的光澤度差異者’並且，由此開始迄可提 - 35 - (32) (32)1331099 供做爲製品之狀態的被加工者之比較例2及比較例3，雖 然兩比較例之間在光澤加工由於消豔加工之不同而造成測 定數値很大的差，但是各比較例完全沒有晚材部分與早材 部分之光澤度差異。在實施例1中，利用該光澤度差異， 而更進一步地強烈感受到木紋圖案之實物感》 並且，將比較例1與實施例2之測定結果比較時，實 施例2與實施例1比較，係晚材部分與早材部分均爲測定 數値降低很大者，依然在晚材部分與早材部分有光澤度差 異，看去的感覺係如長期在風雨日光下曝曬一般，被賦予 侘、寂之枯萎之感。 另一方面，如由比較例2及比較例3之測定結果般， 不論光澤型或消豔型，透明塗漆做爲頂被覆層而被塗佈之 時，其影響係晚材部分與早材部分均爲共通作用之光澤加 工而使全體之光澤度提高，或者消豔加工而使全體之光澤 度降低，因而無法產生晚材部分與早材部分之光澤度的差 異。 其次，觀察實施例3的測定結果時，可理解，與色調 之不同部位並列地，底色部（相當於非印刷部之轉印部位 )上很明顯地產生光澤度的差。在黑部分-濃褐部分-濃綠 部分之間，光澤度的測定數値依序地成倍數提高，底色部 分更提高而成爲最高的光澤度。實施例3，係介由該光澤 度的差，在黑部分-濃褐部分-濃綠部分-底色部分上，被立 體地賦予似有深度感之感受的迷彩圖案。 觀察實施例4的測定結果時，可理解，與色調之不同 -36- (33) (33)1331099 部位並列地，底色部（相當於非印刷部之轉印部位）上或 多或少產生光澤度的差，該差之程度係極微小，幾乎不產 生光澤度的差。因此，在該狀態中，無法提供做爲將其做 成商品之最表面的製品，因而雖然形成頂被覆層係爲必要 ，但是依此方式進行時，如比較例5及比較例6之測定結 果所顯示，可了解全體爲均勻的光澤度，無法達成本發明 之目的。 參考例1，係在一個裝飾層上並未巧妙地形成低光澤 圖案部與高光澤圖案部，但是係顯示做爲測定高光澤圖案 部之光澤度的例子而參考之用》參考例1之光澤度，係 測定相同褐色系之部分的結果數値，可了解，其比實施例 1之早材部分的光澤度更高，與實施例3的濃綠部分之光 澤度大致相同。此乃實施例1之早材部分的褐色係比參考 例1者更濃，僅此部分使添加更容易吸收紫外線硬化樹脂 組成物之黑顏料等之顏料的墨水，以高充塡量而被轉印， 其結果，推測應爲實施例1之早材部分的測定數値低所造 成的結果。並且，實施例3的濃綠部分之的色調係做成濃 暗感者，而光澤度之測定數値卻大致相同，推測係即使其 濃綠部分中墨水充塡多之時，添加本來不太吸收紫外線硬 化樹脂組成物之顏料的墨水所轉印之結果。 另一方面，比較例7之光澤度的測定數値，係與比較 例4之黑部分、濃褐色部分、濃綠部分、底色部（相當於 非印刷部分之轉印部位）爲大致相同的程度。將這些測定 結果綜合之時，在任何比較例之情況，均爲墨水成分中之 -37- (34) (34)1331099 顏料的吸油量對光澤度之影響，與墨水之色調（顏料種類 )或充塡量不太有關，任何實施例與其比較，則確認並不 顯著。 從而，例如，若欲獲得低光澤圖案部與高光澤圖案部 之間的光澤度之差爲最大的木紋圖案的話，使實施例3的 黑部分成爲晚材部分、使實施例5的淡褐色成爲早材部分 的方式，而使用墨水之印刷圖型的轉印薄膜進行水壓轉印 即可。並且，由比較例之測定結果可判明，形成先前技術 的頂被覆層之時，當然僅全體獲得大致均勻的光澤度，以 先前技術之活性劑將印刷圖型活性化而獲得的裝飾層，亦 已確認難以將光澤度的差做成顯著。 在表1之實施例2中，低光澤圖案部與高光澤圖案部 之光澤度，均在光澤度之數値範圍30至60之外，如已經 敘述者，即使其差爲5之時，亦感受到光澤度的差很大。 在實施例1中，雖然高光澤圖案部之光澤度在30至60之 範圍內，但是低光澤圖案部與高光澤圖案部之光澤度的差 約爲18而太大，因此即使一·方在該範圍內時，亦可充分 地辨識該光澤度的差。 (產業上利用之可行性） 必須轉印的印刷圖型之附著再現性賦予用之無溶劑型 的紫外線硬化樹脂組成物，係與印刷圖型渾然一體化而被 硬化，因此將機械及化學的表面保護功能賦予物品之裝飾 層上，並且該紫外線硬化樹脂組成物，在依照印刷圖型之 -38- (35)1331099 墨水中之顏料的種類而容易吸收或難以吸收地在 成之裝飾層的墨水印刷部分上，形成有低光澤圖 光澤圖案部，利用這些光澤度之差的存在而可提 感賦予裝飾層上的製品（水壓轉印物品），因此 上之利用性提高。 【圖式簡單說明】 第1圖係顯示使用於本發明之水壓轉印方法 槪圖。 第2圖係以工程順序顯示本發明之水壓轉印 個形態，第2A圖係轉印薄膜之剖面圖，第2B圖 線硬化樹脂組成物塗佈於轉印薄膜上之狀態的剖 2C圖係將第2B圖之轉印薄膜飄浮於水面的狀態 ，第2D圖係正要將須水壓轉印的物品壓入水中 態之剖面圖，第2E圖係在轉印後照射紫外線的 面圖，第2F圖係從物品將水溶性薄膜進行水洗 剖面圖，第2G圖係將物品的表面乾燥的狀態之g 第3圖係經由本發明之方法所獲得的製品之 圖。 第4圖係本發明之一個實施形態之製品的立 第5圖係顯示將第4圖之製品的一部分之圖 放大圖。 【主要元件符號說明】 轉印地形 案部與高 供將立體 可使產業 之槪略的 方法之一 係將紫外 面圖，第 之剖面圖 之前的狀 狀態之剖 的狀態之 j面圖。 放大剖面 m γβί 擐圖。 案放大之 -39- (36)1331099 10 1 OS 1 Ο5 12 14 16 物品 表面 製品 印刷圖型 水溶性薄膜 轉印薄膜 18 水 20 無溶劑型之紫外線硬化樹脂組成物 22 紫外線 2 4 沖水 26 熱風 30 裝飾層 2 0 0 製品 202 基材 230R 微細凹凸 130A,230A,130C,130B,23 0B 圖案部分 100,200 製品 1 02,202 基材 1 3 0,23 0 裝飾層 40-As shown in Table 1, in Example 1, the difference in gloss between the late wood portion and the early material portion was significant. In contrast, the comparative example i shown in _ 2 had no difference in glossiness of some portions. From this, it is possible to draw up - 35 - (32) (32) 1331099 for Comparative Example 2 and Comparative Example 3 of the processed product in the state of the product, although the gloss processing differs between the two comparative examples due to the brightness reduction processing. However, the measurement number is greatly different, but each comparative example has no difference in gloss between the late wood portion and the early material portion. In Example 1, the physical feeling of the wood grain pattern was further strongly felt by the difference in glossiness. Further, when comparing the measurement results of Comparative Example 1 and Example 2, Example 2 was compared with Example 1. , the late wood part and the early wood part are both measured greatly, and the gloss is still different in the late wood part and the early wood part. The feeling of seeing is like long-term exposure in the wind and rain, and is given 侘The feeling of wilting of silence. On the other hand, as in the measurement results of Comparative Example 2 and Comparative Example 3, regardless of the gloss type or the radiance type, when the clear lacquer is applied as a top coating layer, the influence is on the late wood portion and the early wood material. In some cases, the gloss processing is common, and the gloss of the whole is improved, or the gloss is reduced, and the gloss of the whole is lowered, so that the difference in gloss between the late wood portion and the early material portion cannot be produced. Next, when the measurement results of the third embodiment were observed, it is understood that the difference in gloss is apparently observed in the under color portion (corresponding to the transfer portion of the non-printing portion) in parallel with the difference in color tone. Between the black portion - the thick brown portion - the dark green portion, the measured number of gloss is sequentially increased in multiples, and the background portion is further increased to have the highest gloss. In the third embodiment, the camouflage pattern which is perceived as having a sense of depth is stereoscopically imparted to the black portion - the thick brown portion - the dark portion - the background portion by the difference in gloss. When observing the measurement results of Example 4, it can be understood that the difference between the -36-(33) and (33) 1331099 portions is juxtaposed, and the undercolor portion (corresponding to the transfer portion of the non-printing portion) is more or less produced. The difference in gloss is extremely small, and the difference in gloss is hardly produced. Therefore, in this state, it is not possible to provide a product which is the outermost surface of the product. Therefore, it is necessary to form the top coating layer, but when it is carried out in this manner, the measurement results of Comparative Example 5 and Comparative Example 6 are obtained. As shown, it can be understood that the whole is a uniform gloss and the object of the present invention cannot be achieved. In Reference Example 1, the low-gloss pattern portion and the high-gloss pattern portion were not subtly formed on one decorative layer, but the gloss was measured as an example of measuring the gloss of the high-gloss pattern portion. The degree of the result of measuring the portion of the same brown color was found to be higher than that of the early material portion of Example 1, and substantially the same as the gloss of the green portion of Example 3. The brown color of the early material portion of the first embodiment is more concentrated than that of the reference example 1, and only the ink which is added with the pigment of the black pigment or the like which absorbs the ultraviolet curable resin composition more easily is transferred at a high charge. As a result, it is presumed that the result of the measurement of the early material part of Example 1 is low. Further, the color tone of the green portion of the third embodiment is thick and dark, and the measurement of the gloss is substantially the same, and it is presumed that even if the ink is rich in the dark portion, the addition is not so much. The result of transfer of the ink absorbing the pigment of the ultraviolet curable resin composition. On the other hand, the measured number of gloss of Comparative Example 7 was substantially the same as that of the black portion, the dark brown portion, the dark green portion, and the ground portion (corresponding to the transfer portion of the non-printed portion) of Comparative Example 4. degree. When these measurement results are combined, in any of the comparative examples, the influence of the oil absorption amount of the -37-(34) (34) 1331099 pigment on the gloss in the ink composition, and the color tone (pigment type) of the ink or The amount of charge is not very relevant, and any embodiment is not significant. Therefore, for example, if the wood grain pattern having the largest difference in gloss between the low gloss pattern portion and the high gloss pattern portion is to be obtained, the black portion of the third embodiment is made into the late wood portion, and the light brown of the embodiment 5 is obtained. The method of forming the early material portion can be carried out by hydraulic transfer using a transfer film of a printing pattern of ink. Further, from the measurement results of the comparative examples, it has been found that, when forming the top coating layer of the prior art, it is a matter of course that only a substantially uniform gloss is obtained, and the decorative layer obtained by activating the printing pattern by the active agent of the prior art is also It has been confirmed that it is difficult to make the difference in gloss remarkable. In the second embodiment of Table 1, the gloss of the low-gloss pattern portion and the high-gloss pattern portion are outside the range of the glossiness range of 30 to 60, as already described, even if the difference is 5, I feel a lot of difference in gloss. In the first embodiment, although the gloss of the high gloss pattern portion is in the range of 30 to 60, the difference in gloss between the low gloss pattern portion and the high gloss pattern portion is about 18 and too large, so even if In the range, the difference in gloss can be sufficiently recognized. (Feasibility of industrial use) The solvent-free ultraviolet curable resin composition for imparting adhesion reproducibility to the transfer pattern to be transferred is integrated with the printing pattern and hardened, so mechanical and chemical The surface protection function is imparted to the decorative layer of the article, and the ultraviolet curable resin composition is easily absorbed or difficult to absorb in the decorative layer according to the type of the pigment in the printing pattern of -38-(35)1331099 ink. In the ink-printed portion, a low-gloss pattern gloss pattern portion is formed, and the presence of the difference in glossiness is provided to impart a feeling to the product (hydraulic transfer article) on the decorative layer, so that the usability is improved. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a view showing a water pressure transfer method used in the present invention. Fig. 2 is a view showing a hydraulic transfer form of the present invention in an engineering order, a cross-sectional view of the transfer film of Fig. 2A, and a sectional view 2C of a state in which the cured resin composition of the 2B line is applied to the transfer film. The transfer film of FIG. 2B is floated on the surface of the water. The 2D image is a cross-sectional view in which the article to be subjected to water pressure transfer is pressed into the water state, and the second image is a plan view of the ultraviolet light after transfer. 2F is a water-washed cross-sectional view of the water-soluble film from the article, and FIG. 2G is a state in which the surface of the article is dried. FIG. 3 is a view of the product obtained by the method of the present invention. Fig. 4 is a perspective view showing a part of the article of Fig. 4, showing a plan view of a product according to an embodiment of the present invention. [Explanation of main component symbols] Transfer topography and high supply One of the methods for making the industry a three-dimensional method is to view the state of the state before the cross-sectional view of the ultraviolet profile. Zoom in on the section m γβί 擐. Case magnification -39- (36)1331099 10 1 OS 1 Ο5 12 14 16 Article surface product printing pattern Water-soluble film transfer film 18 Water 20 Solvent-free UV-curing resin composition 22 UV 2 4 Flush 26 Hot air 30 Decorative layer 2 0 0 Product 202 Substrate 230R Fine irregularities 130A, 230A, 130C, 130B, 23 0B Pattern part 100, 200 Article 1 02, 202 Substrate 1 3 0, 23 0 Decorative layer 40-