TWI324045B - - Google Patents

Description

[Technical Field] The present invention relates to an antibacterial and deodorizing treatment agent for a water-saving toilet used in a water-saving toilet installed on a train, a bus, an airplane, and a wheel (4), and the use of the treatment agent Antibacterial and deodorant treatment methods. Further, the present invention relates to an antibacterial and deodorant treatment agent suitable for the following water-saving toilets and an antibacterial and deodorant treatment method for the treatment agent, such a water-saving discharge > 'toilet includes: The washing water in the tank for washing the dirt flows simultaneously with the dirt

The washing-type toilet in the ice storage tank is used or the washing-in toilet is used to avoid the use of the water-washing toilet in the storage tank by the decompression device. [First-class technology] So far, the squatting, setting,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,,, The use of the loop. The squat toilet allows the water and dirt stored in the dirt washing tank to flow into the washing toilet in the tank of the dirt, the shell, and the washing water. The dirt is sucked into the vacuum suction type toilet in the dirt storage tank by the decompression device. Among them, when the washing water of the washing type toilet uses only water, it cannot prevent the odor from being generated by (4) storage (4), and the money (4) material often feels unpleasant, so the antibacterial and deodorizing effect is preliminarily put into the washing water or the dirt storage tank. The treatment agent is used for preservation, deodorization and the like. In addition, in the vacuum suction toilet, although the dirt storage tank is kept at a negative C to prevent the generation of foul odors, but when the passage of the passage or the like, the pressure change 'has not been able to maintain the dirt storage (4) Negative pressure has a problem of malodor caused by 93905-990122.doc 1324045. Therefore, in many cases, a treatment agent having an anti-mite and deodorant action is preliminarily added to the dirt storage tank to perform corrosion prevention, deodorization, and the like. Such an antibacterial and deodorant treating agent for preventing spoilage in the tank for storing dirt requires an effect of stably preventing spoilage in the case of a small amount of injection for about 24 hours to 72 hours. Therefore, the main antibacterial ingredients used in the past treatment agents are 2-bromo-2-nitro-propane], 3-diol (HO-CH2-CBr(N〇2)-CH2-〇H), etc., or 5_ An antibacterial preparation which exhibits a very high antibacterial property in a small amount and stably, such as an isothiazoline such as _2_ fluorenyl-4 isothiazolin-3-one. As a treating agent using 2-bromo-2->6 schottyl-propanol-1,3-diol, 2-bromo-2-nitro-propane_丨, 3_ has been disclosed in the antibacterial agent. The diol further contains an antibacterial agent composition comprising a dissolution-regulating base formed by 12-hydroxystearic acid and cetylpyridinium rust salt chloride (for example, refer to the patent literature). However, although halogen or isothiazoline It is worth expecting that a small amount of antibacterial preparation has a very strong antibacterial effect, but on the other hand, it is highly irritating to the skin or mucous membrane, which is the highest priority for the safety of the operator, because of the fear Because of the influence of the human body, there is a tendency to keep away from the treatment agent which is difficult to use. In addition, since the chemical structure of the above-mentioned antibacterial preparation is extremely stable and it is difficult to be naturally decomposed, even if a small amount is added, there is a possibility that residue remains unresolved after the waste is recovered. Sexuality will still cause adverse effects on wastewater treatment facilities such as activated sludge tanks. Further, for halogen-based antibacterial preparations, when the treatment residue is incinerated, carcinogens such as dioxin may be produced. Environmental pollution. In addition to the safety of the human body or treatment facilities, it is also developed to use the 93905-990122.doc 1324045 for skin disinfection, etc., using the chlorination of the chlorinated section, which has less adverse effects on the human body, etc. As a treatment agent for an antibacterial component, since the structure of the fourth-order ammonium salt has a small number of functional groups having an antibacterial action, if it is in contact with an organic substance such as a dirt, the functional group immediately combines with the organic substance, so that the antibacterial force rapidly decreases. It has the problem that the effect cannot be stabilized even if it is put into a higher concentration. In addition, the reactivity of such a treatment agent is high, so if the concentration is high, it is fearful that it will rot. The problem of materials such as metals used, etc. In addition, the compatibility of the 4th (4) salt with an anionic surfactant widely used in soaps or detergents is extremely poor, even if it is mixed, for example, even if a small amount is mixed, It will immediately cause the problem of inactivation of the white turbid temple. In addition, due to the high foaming property, it may contaminate the water when it is drained after use. In the technique of each problem, a toilet washing water containing a double vein (four) microbial agent, water, an ethylene glycol compound and an active agent has been disclosed (for example, refer to Patent Document 2). By using the additive In the composition, the above-described effects can be stably maintained without reducing the sterilizing, preserving, and removing from the water, and the above-described effects can be stably maintained. [Patent Document 1] JP-A-2001-233703 (Patent Document 2) Japanese Patent Application Laid-Open No. Hei 7-150194. The bismuth-based bactericide is exemplified by a chlorhexidine such as glucidine as shown in the above Patent Document 2; Hydrochloride 93905.990122.doc 1324045 Salt 'Special line and benzyl chloride sinter ([CuHu-NGCHsX-CHa-C^HJ+Cl·) has no compatibility' with white turbidity when mixed with gasified benzalkonium The problem of precipitation and inactivation. It cannot be used in combination with the anti-corrosion treatment agent of the fourth-grade ammonium salt which has been commonly used. Therefore, it is often installed on a large number of moving bodies for cleaning and maintenance in a lot of places such as trains, buses, airplanes, and ships. Because of the difficulty in the unified management of the antibacterial and antiseptic treatment agent, it is difficult to use it. An object of the present invention is to provide an antibacterial and deodorizing treatment agent for a water-saving toilet and an anti-deodorant method using the same, which can be used for a sewage toilet installed on a train, a bus, an airplane, a ship, or the like. The spoilage of the dirt stored in the storage tank is suppressed for a long period of time to prevent the generation of malodor. Another object of the present invention is to provide an antibacterial and deodorizing treatment agent for a water-saving toilet and an antibacterial and deodorizing treatment method using the same, wherein an antibacterial and deodorizing effect is inactivated in conjunction with a dirt load, thereby collecting and transporting the dirt Drainage facilities will not have adverse effects. Still another object of the present invention is to provide an antibacterial deodorizing treatment agent for a water-saving toilet and an antibacterial deodorizing method using the same, which can be used to input an appropriate amount of anionic interface activity in the case of residual antibacterial and deodorizing effect The agent is inactivated. SUMMARY OF THE INVENTION The invention of claim 1 is an improvement of an antibacterial deodorant for a water-saving toilet formed from an aqueous solution containing a biguanide antibacterial component and a surfactant component, and has a characteristic composition of 2% by weight to 10% by weight. % of hexamethylene sulphate hydrochloride 93905-990122.doc 1324045 salt (hereinafter referred to as PHMB) as an antibacterial component, containing i% by weight to 5 〇 by weight. /. The component of the cationic component, the nonionic surfactant, or the amphoteric surfactant is used as the surfactant component, and the weight ratio of the antimicrobial component to the surfactant component is in the range of 5·5. ·] within the scope. In the invention of claim 1, the ugly 8 which is a main component of antibacterial has the effect of being used as an antibacterial agent in a swimming pool for many years, and the toxicity is very low as compared with the fourth-grade money salt and other biguanide compounds. It has high safety, is stable to temperature or PH, and can exert antibacterial effect with respect to various microorganisms. Therefore, it achieves excellent antiseptic effect and deodorizing effect continuously in the tank for storing dirt' and the rotten money for the constituent materials of the toilet. It is less inferior. In addition, because it has compatibility with the fourth-grade salt and special system of the compatibility with other biguanide compounds, even if it is used with the fourth-level salt or other The antibacterial and antiseptic treatment agent of the biguanide compound does not inactivate the antibacterial and antiseptic effect. In addition, when the nonionic surfactant is contained, it is compatible with the anionic surfactant in the range of the twist. The degree of freedom of the method of blending is higher than that of Gutian, and because of its non-foaming nature, it also has various characteristics for low environmental load on the drainage after use. The antibacterial and deodorant treating agent of the present invention in which the k-bismuth and the surfactant component are combined in the above ratios are used as the antibacterial and deodorizing treatment agent used in the water-saving toilets for trains, bus airplanes, and the like. According to the invention of claim 1, the invention of claim 2 is a king relative to the treatment agent. The P reset 'also contains the amount of plant extract which is in proportion to the weight of the plant extract. In the invention of claim 2, the agent may further have a deodorizing effect; the invention has the invention, the invention of claim 3, the invention of claim 3 A water-saving toilet antibacterial agent having an anionic surfactant in a ratio of a weight less than PHMB when the non-ionic interface activity is less than PHMB in the interface active knives. The deodorizing treatment agent. In the invention of claim 3, the anionic surfactant activity % containing the amount of the compound can provide a cleaning effect to the treating agent. The invention of claim 4 is - 锸, 、, 令The antibacterial and deodorizing treatment method of the type of toilet is characterized in that: in the name of the ή匕 ή匕 夂 夂 夂 夂 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污 污In the tank for washing, the antibacterial deodorant described in any one of claims 1 to 3 is diluted with water to a certain concentration to form a diluent, and when the toilet is used, the diluent is washed as dirt. Water and dirt flow into the tank for storage of dirt at the same time. The invention of the month-long item 5 is an antibacterial and deodorizing treatment method for a water-saving toilet, which is characterized in that dirt is washed in a water-saving toilet. The tank is used for storing the water in the tank for storing the dirt, and is stored in the tank for storing the dirt. The antibacterial deodorant described in any one of the claims 1 to 3 is diluted with water to the water tank. - a dilution liquid formed at a constant concentration, and when the toilet is used, the washing water and the waste which are water/wrinkle are simultaneously flowed into the dirt storage tank, and the dirt is stored in the storage tank to prevent contamination. The dirt accumulated in the storage tank produces spoilage and foul odor. The invention of claim 6 is an antibacterial and deodorizing treatment method for a water-saving toilet. In the water-saving toilet, a dirt washing tank 93905-990l22.doc and a π storage tank are respectively provided. 'Storing the item in the dirt washing tank separately】 The antibacterial deodorant described in item 3 is diluted with water to a certain concentration. The diluent is stored in the dirt storage tank. In the 3rd item, the antibacterial deodorant is diluted with water to the same or different concentration as the third release liquid, and the second dilution liquid is used as the sewage washing water and the liquid substance in the toilet. At the same time, it flows into the dirt storage tank, and the first dilution liquid and the second dilution liquid stored in the storage tank prevent contamination of the accumulated dirt in the dirt storage tank. The invention of claim 7 is an antibacterial and deodorant treatment method for a water-saving toilet: characterized in that: in a water-saving toilet, a dirt washing agent tank, a three-purpose washing water tank, and a dirt storage are separately provided. In the treatment tank: the antibacterial and deodorant treatment described in any of the items 1 to 3 in the storage tanks 1 to 3, the water is cut in the water tank, and the treatment agent and the water are treated as one = two: 'Dilute the treatment agent to a certain concentration as a diluent, which will be in the middle. At the same time, the invention is based on the invention of the invention, which is the same as the invention. Separately, the antibacterial and deodorant treatments described in the items of the items of the items i to 3, respectively, are disposed in the sewage disposal treatment tank, the dirt cleaning + tank, and the storage tank for the object. Storage in the storage tank will request item i = one: the recorded antibacterial deodorant is diluted with water to the third concentration of the constant concentration. When the toilet is used, the treatment agent and water are discharged at a certain ratio and the agent is diluted to - As the first field release solution, the fourth dilution is used as 93905-990122.doc U24U45 as the washing water and dirt of the dirt (4) in the storage tank for human dirt, by the fourth: release and storage The third dilution in the tank for storage of the material prevents spoilage and malodor from being accumulated in the dirt bedding container. The invention of claim 9 is an antibacterial and deodorizing treatment method for a water-saving toilet: characterized in that: in a water-saving toilet, a pressure reducing device, a net Jc tank, and a 'defective storage tank are separately provided, and the waste storage is performed. Use the towel to store the diluted antibacterial deodorant from the request to the third item, and dilute it to a certain concentration. When using the toilet, the dirt and the small amount of water supplied by the washing trough are simultaneously reduced. The pressure device is sucked into the dirt storage tank, and the diluent stored in the dirt storage tank prevents the dirt accumulated in the dirt storage tank from causing spoilage and malodor. In the inventions of claims 4 to 9, the rot & can be prevented until the load stored in the dirt storage tank reaches a load of -^, and the generation of malodor can be suppressed. According to the invention of any one of claims 4 to 9, the invention of claim 1 is an antibacterial deodorizing method for a water-type toilet, wherein the dirt is simultaneously stored in a diluent or a dirt tank in the dirt storage tank. The concentration of the antibacterial and deodorant treatment agent contained in either or both of the dilution liquids is determined by the storage of the storage tank for a certain period of time and the amount of the dirt load flowing into the predetermined dirt with the time. live. In the invention of claim 10, in order to inactivate the antibacterial effect according to the amount of the dirt load, the treatment agent is prepared at a certain ratio, thereby preventing the existing treatment agent from being disposed, and draining the sewage after the waste is recovered. The problem of the impact of the facility. 93905-990122.dOC 13 1324045 According to the invention of claim 4 to 10, the invention of claim (4) is an anti-deodorant treatment method for a water-saving toilet in which the waste is discharged from the storage tank. The antibacterial component remaining in the soil can be completely inactivated by the treatment. In the invention of claim 11, 'in the case of an anionic surfactant which is added in an appropriate amount (more than the amount of residual amount of PHMB (four)) when the antibacterial effect is left at the time of drainage, the deactivation treatment can be easily performed, and the drainage can be completely avoided. The impact of the facility. According to the invention of any one of claims 4 to 11, the invention of claim 12 is an antibacterial and deodorizing treatment method for a water-saving toilet, wherein the dilution liquid is diluted with water to an antibacterial and deodorant treatment agent by a weight ratio of 5 to 5 〇. Modulated by 〇. The invention of claim 13 is the antibacterial and deodorant treatment agent for a water-saving toilet used in the treatment method according to any one of claims 4 to 12. [Embodiment] Next, an embodiment of the present invention will be described. The antibacterial and deodorant treatment agent for a water-saving toilet according to the present invention is obtained by modifying an aqueous solution containing a biguanide antibacterial component and an interface active component. The structure is characterized in that PHMB is used in the anti-g component, and the ratio of 3 is 2% by weight to 1% by weight based on the total amount of the antibacterial component. /❶. If less than 2 weights. ', can not get enough antibacterial effect; if it exceeds 10% by weight, the viscosity of the treatment agent becomes high, and even if it contains more than the above amount, it can not be expected to improve the antibacterial and antiseptic effect of this purpose, resulting in Cost is wasted. PHMB is shown in the following formula (1), its toxicity is low, and it is less irritating to the skin or mucous membrane than the acicular or isothiazoline antibacterial preparation. It has the ability to swim as 93905-990I22.doc •14· 1324045 The anti-bacterial agent of the pool has been used for many years, and it is a safe component that affects the human body: [Chemical 1]

Η Η Η NH NH

HC (1) :12) In addition, PHMB has a higher number of functional groups effective for antibacterial and antiseptic effects than salt or other biguanide compounds at level 4, and it is difficult to cause deactivation by contact with organic substances such as dirt. The ancient and J μ have a long-lasting antiseptic and deodorizing effect. In addition, the corrosion resistance of the material forming the toilet is small, and the foaming property is low, so there is no need to worry about water turbidity. In addition, the antibacterial component with lower compatibility with the fourth grade money salt or the non-ionic surfactant is not compatible with the anionic surfactant below the equivalent amount: 3⁄43⁄4 'It can be considered to be used together with the antibacterial and antiseptic treatment agent at this point. Compared with the imine or heterogeneous Lin, the PHMB can be easily adjusted to a certain extent according to the amount of the investment. Therefore, in order to reduce the antibacterial effect according to the amount of the dirt load, and to prepare the treatment agent to a certain ratio, it is possible to prevent the existing treatment agent from the left-handed agent from recovering the dirt and then transporting it. Drainage facilities have an impact. Here, what is in the loss into the waste storage tank. Sewage logistics into the Fan # can only maintain the antibacterial effect in a short period of time, Qiao·Logistics 轫 Compared with J, playing, the anti-mechanical effect can last for a long time. In addition, when there is residual h @ $ x (2) in the case of drainage, the anionic surfactant 93905-990122 is used (with the residue of PHMB + dan, 曰田奴入中里) .doc thus completely avoids the effects of easy deactivation of the drainage facility. The interfacial active ingredient is one or more of cationic, M ^ 1 ^ , chlorophyll* or amphoteric surfactants, and the ratio of the total amount of the treatment agent to the total amount of the treatment agent is 1 weight. 〇/0~5〇 in the heavy room/〇. The antibacterial power can be stabilized by using one or two or more kinds of cation, nonionic or interfacial sputum as an interface active component as a main component. If the team has a weight of 篁°/〇, then the anti-caries effect of the sentence cannot be obtained. If it exceeds 50, the weight of the treatment agent becomes high and the use is inconvenient. Preferably, it is 5% by weight to 3 _ m ^ ώ 川. More preferably, it is 丨0% by weight to 20% by weight of a cationic, nonionic or amphoteric surfactant, and it can be used without any problem in the antibacterial and deodorizing treatment agent of the present invention, but it is more suitable as a polyoxyalkylene ether. A low foaming substance. Specifically, as the cationic surfactant, there may be mentioned one or two selected from the group consisting of an alkylamine oxide, a gasified polyoxypropylene, a diethylhydrazine, and a vaporized dimethyldipropylpropyl group. Any of the above compounds; as the nonionic surfactant, there may be mentioned those selected from the group consisting of polyoxyalkylene oxime, polyglycerin fatty acid ester, coconut fatty acid monoethanol amide and nonyl phenyl ethoxylate or 2 As the amphoteric surfactant, a compound such as laurylamine propane-based betaine or laurylamine-acetate betaine can be exemplified. Further, when the nonionic surfactant is contained in the interface active component, an anionic surfactant may be contained in an amount equal to or less than the weight of the PHMB. When it is equal to or more than an equivalent amount, the anionic surfactant reacts with PHMB to form a sag, which is inconvenient to use. The anionic surfactant may, for example, be an alkylbenzenesulfonic acid, a 295905-990122.doc-16-1324045 alkylthiosuccinate salt, an alcohol ether sulfate salt or the like. Containing an anionic surfactant can provide a cleansing effect. The antibacterial P odor treatment of the present invention is prepared as a weight ratio of the bacterial component to the interface active component of 1:5 to 5: i. When the weight ratio is outside the above range, the viscosity of the treatment agent becomes high, and it is difficult to use it. Further, since the plant extract can be contained in a proportion of W% by weight to 4% by weight based on the total amount of the antibacterial deodorant of the present invention, the treating agent can further have a deodorizing action. A plant extract containing a ratio of 5% by weight to 2% by weight is preferred. The plant extract may be selected from the group consisting of trifolium repens extract, eucalyptus extract, cypress extract and pine needle extract, or two or more compounds. In addition, the substance extract is a part of a specific polyphenol polymer component such as a persimmon extract, which reacts with B to cause precipitation. Next, an antibacterial and deodorizing treatment method for the water-saving toilet of the present invention will be described. In the water-saving toilet which is suitable for the treatment method of the present invention, a dirt washing tank and a dirt storage tank are provided, respectively. The above-mentioned antibacterial and deodorant treating agent of the present invention is diluted with water to a certain concentration of the diluted solution in the dirt washing tank. And i, when using the toilet, the diluent is used as the dirt, the clean water and the dirt simultaneously flow into the dirt storage tank, until the dirt stored in the dirt storage tank reaches a certain load, the corruption can be prevented. Further, as a second treatment method of the present invention, water is stored in a dirt washing tank provided in a water-saving toilet suitable for the first treatment method, and is stored in a sewage 93905-990122.doc 17 1324045 The aforementioned antibacterial and deodorant treating agent of the present invention is diluted with water to a dilution of a concentration of hydrazine by storage in a tank. Further, when the toilet is used, the dirt and the water in the tank are used as the dirt washing water, and simultaneously flow into the dirt storage tank together with the dirt. The dirt accumulated in the tank for storing the dirt can prevent spoilage and malodor by the diluent stored in the tank for storing the dirt until a certain load is reached.

π μ of the goods, the third treatment method, which is stored in the dirt washing tank suitable for the first type of treatment water-saving toilet, and the antibacterial and deodorant treatment agent of the present invention is diluted with water to a certain concentration. The second dilution liquid is prepared by diluting the antibacterial and deodorant treatment agent of the present invention with water to the same or different concentration as the first dilution liquid in the dirt storage tank. In addition, when the toilet is used, the first dilution liquid stored in the dirt cleaning (4) is used as the dirt washing water, and flows into the dirt storage tank simultaneously with the dirt. The dirt accumulated in the tank for storage of dirt, and the i-th diluent that causes the dirt to flow out, dreams

The second dilution stored in the tank for the storage of dirt can prevent spoilage and malodor until it reaches a certain negative line. In the water-saving toilet of the fourth method of the present invention, a treatment tank, a sewage washing tank, and a dirt storage tank are separately provided. In order to store the sewage cleaning agent, the antibacterial and deodorant cleaning agent tank of the present invention is stored in the water in the water tank, and the dirt is washed. When the toilet is used, the dirt is not used. First use the water tank, the treatment agent and water will flow out in a certain ratio, and dilute the treatment agent to the constant concentration to prepare the dilution, and wash the »hai dilution solution as dirt _ zhong, ji _ π At the same time, the dirt storage tank is infiltrated until the dirt stored in the storage tank reaches a certain load of 93905-990122.doc 1324045 洳, which can prevent corruption and suppress the generation of malodor. As a fifth treatment method of the present invention, the antibacterial and deodorant treatment agent of the present invention is stored in a treatment tank provided in a water-saving toilet suitable for the fourth treatment method, and water is stored in a water tank; In the storage tank, the antibacterial and deodorant treatment agent of the present invention is diluted with water to a third concentration of a predetermined concentration. Moreover, when the toilet is used, the treatment agent and the water are discharged at a certain ratio by the treatment tank and the water tank, and the treatment agent is diluted to a predetermined concentration to prepare the fourth dilution liquid. The fourth dilution liquid is used as the dirt washing water. Simultaneously with the dirt, it flows into the dirt storage tank. The dirt accumulated in the dirt storage tank can prevent spoilage and malodor by the third dilution liquid flowing into the dirt and the third dilution liquid stored in the dirt storage tank until the load is reached. In the water-saving toilet which is suitable for the sixth treatment method of the present invention, a pressure reducing device, a washing water tank, and a dirt storage tank are provided, respectively. In the dirt storage tank, the antibacterial and deodorant treating agent of the present invention is diluted with water to a dilution of a certain concentration. Moreover, when the toilet is used, the water and the dirt in the J provided by the washing tank K are simultaneously sucked into the dirt storage tank by means of the reducing device. The dirt accumulated in the tank for storing the dirt 'is prevented from spoilage and stench by the dilution liquid stored in the tank for storage of the dirt until it reaches a certain position." 1~ The dilution solution used in the sixth treatment method, the anti-caries and deodorant treatment agent is diluted by water 5 times to 5 times, and the dilution ratio is just doubled to the foot. The dilution is prepared by the method of dilution. If the ratio is less than 5 times, it may be asked to resist the anti-mite and deodorizing effect. When the recovered dirt is sent to the drainage, the possibility of deactivation treatment is increased, which makes it troublesome. 93905-990122. Doc •19· 1324045

If the dilution ratio exceeds 5 GG times, the ratio of the treating agent is too small to have an adequate antibacterial and deodorizing effect. From the other day, when the sputum is discharged from the dirt storage tank, the dirt is completely deactivated, and the residual antibacterial component can be completely lost by a certain treatment. For example, an anionic surfactant having an I or more equal to the amount of the needle is added to the soil, and the remaining antibacterial component is inactivated. 0 "The antibacterial and deodorant treating agent of the present invention used in the above treatment method, You can hunt the anti-components and the interfacial active ingredients Xi Xi, ☆ ☆ one of the battles of each of the 77, and the amount of the anti-bacterial effect of the dirt load is 任 ^ 忍 忍 忍 忍 。 。 。 。 。 。 。 。 。 。 。 。 。 。 After a certain amount of the dirt is poured into the tank for storing the dirt, the antibacterial and deodorizing effect can be inactivated. The concentration of the antibacterial and deodorizing treatment agent contained in the diluent can be determined according to the respective concentrations of the anti-® component and the interfacial active component. The embodiment of the present invention and the comparative example will be described in detail. <Example 1> It is assumed that a method of placing urination or stool into a dirt storage tank in a water-saving toilet provided in a train is Sewage storage In the storage tank, the spoilage condition of the π substance and the diluted solution of the antibacterial and deodorant treatment agent diluted with water is separately verified in the following test. First, 10 parts by weight of 20% by weight 1 &gt; 11 River 3 aqueous solution (trade name Proxel®, manufactured by 匕シ7 Co., Ltd.) was prepared as an antibacterial component at 2% by weight, and the polyoxyalkylene ether as a nonionic surfactant was 丨〇% by weight and pure water was 88% by weight. Mixing ratio of % of antibacterial and deodorizing treatment 93905-990122.doc •20· 1324045. Then, in a 500 ml Erlenmeyer flask, add 50 such as pure water, add 2 ml of spoiled dirt, add 〇25 Mi The above-mentioned treatment agent. Corrosive dirt is collected from the dirt storage tank of the water-saving toilet used in the actual train. Due to the fresh urine or stool seen in the toilet of the series car, in a short time. In the case of the operation of the train, the culture is carried out in the constant temperature water tank at 35 〇c, and the vibration is carried out at 8 rpm. Assume that the toilet of the train is used to continuously add 1 () mi urine every 1 minute in 12 hours, and add 0.1 ml of spoiled dirt per b. It is assumed that the train enters the garage after the end of the day of operation] Stand in a constant temperature water tank of 3 5 C for 12 hours. Repeat this operation and test until the longest time is 72 hours. In order to confirm the pH rise in the Erlenmeyer flask as the corruption progresses, the pH is measured every hour, at pH. In the state of 8 or more, the addition of urine and dirt is stopped, and the amount of ammonia produced by the gas detection tube (Beichuan gas detection tube) is measured to confirm the malodor caused by the corruption. When the pH is close to 9, the test is terminated. &lt;Example 2&gt; In addition to the use of an antibacterial and deodorant treatment agent prepared by mixing a mixture of a PHMB of 4% by weight, a polyoxyalkylene ether of 2% by weight, and a pure water of 76% by weight, according to Examples and Examples 1 The same method, conducted corruption test. <Example 3 &gt; Antibacterial and deodorizing treatment prepared by mixing in a mixing ratio of PHMB of 1% by weight, polyoxyalkylene ether of 3% by weight, and pure water of 60% by weight/° 93905-990122.doc • 21 - 1324045 In addition, according to the same method as in Example 1, the test was carried out by spoilage. &lt;Example 4&gt; The same procedure as in Example 1 except that the antibacterial and deodorant treatment agent prepared by mixing in a mixing ratio of 10% by weight of PHMB, 2% by weight of polyoxyalkylene ether, and 88% by weight of pure water was used. Method, conduct corruption tests. &lt;Example 5&gt; The same procedure as in Example 1 except that the antibacterial and deodorant treatment agent prepared by mixing in a mixing ratio of 25% by weight of PHMB, 5% by weight of polyoxyalkylene ether, and 93% by weight of φ pure water was used. The method of conducting corruption tests. &lt;Example 6&gt; An antibacterial and deodorant treatment agent prepared by mixing and mixing a ratio of a burnt amine oxide having a PHMB of 2% by weight to a cationic surfactant of 1% by weight and a purity of 88% by weight. Except for the same method as in Example 1, the test was conducted for spoilage. &lt;Example 7&gt; The use of PHMB was 5 weights. /. In the same manner as in Example 1, except that the alkylamine oxide was 5% by weight, the pure water was 85 % by weight, and the eucalyptus extract of the plant extract was mixed at a mixing ratio of $% by weight. The method of performing the test for spoilage β &lt;Example 8&gt; In addition to using 1 wt% of PHMB, 9 wt% of polyoxyalkylene ether, and 1 wt% of alkylbenzenesulfonic acid as an anionic surfactant, Pure water is 6% by weight and the eucalyptus extract as a plant extract is 2 ounces by weight. /. The test was conducted in the same manner as in Example i 93905.990122.doc -22- except that the antibacterial and deodorant treatment agent prepared by mixing in proportion was mixed. &lt;Comparative Example 1&gt; In addition to using 2-bromo-2-nitropropane-1,3-diol (hereinafter, referred to as bronopol) instead of PHMB as an antibacterial agent, bronopol was used as 5 In the same manner as in Example ,, except for the antibacterial and deodorant treatment agent prepared by mixing and mixing the alkylamine oxide as an anionic surfactant in an amount of 1% by weight and 85% by weight of pure water. Corruption is being tested. &lt;Comparative Example 2&gt; In addition to using 50 parts by weight of 40% by weight of benzalkonium chloride in place of pHMB, 20% by weight of benzalkonium chloride, 3% by weight of polyoxyalkylene ether and 50% by weight of pure water were used. The antibacterial deodorant treatment agent which was mixed and mixed in a mixture of % was tested for spoilage according to the same method as in Example 1. &lt;Comparative Example 3&gt; The test was carried out according to the same method as in Example 除了 except that the antibacterial and deodorant treatment agent was not used. &lt;Comparative Example 4&gt; The same procedure as in Example 1 was carried out, except that the antibacterial deodorant treatment agent prepared by mixing a mixture of a polyoxyalkylene ether of 5 wt% and a pure water content of 94 wt% was used. Conduct corruption tests. &lt;Comparative Example 5&gt; A weight of 15 mg was used in addition to PHMB. /. The test for spoilage was carried out in the same manner as in Example 1 except that the polyoxyalkylene ether was mixed with an antibacterial deodorant treatment agent prepared by mixing a mixture ratio of 15% by weight to 70% by weight of pure water. 93905-990122.doc • 23· 1324045 &lt;Comparative Example 6&gt; Antibacterial deodorization treatment prepared by mixing with a mixing ratio of 12% by weight of PHMB and a mixture ratio of 12% by weight of polyoxyalkylene ether to 86% by weight of pure water In addition to the agent, the test was carried out in the same manner as in Example 1. &lt;Comparative Example 7&gt; In addition to the antibacterial deodorizing treatment agent prepared by mixing the polyoxyalkylene ether in an amount of 1% by weight and the mixed ratio of pure water to 88.3 wt%, the amount of the PHMB was 1% by weight. 1 In the same way, conduct corruption tests. &lt;Comparative Example 8&gt; In addition to the use of a mixing ratio of 2% by weight of polyoxyalkylene oxide, 2% by weight of oxyalkylene sulfonic acid, and 86% by weight of pure water in terms of PHMB of 2% by weight, In addition to the odor treatment agent, the test was carried out in the same manner as in Example 腐败. &lt;Comparative Example 9&gt; Except that chlorohexyl gluconate was used instead of phmb, and hexose gluconate was used as a weight ❶/❶, polyoxyalkylene ether was 1 〇 weight/〇 and pure water was 80. The test for spoilage was carried out in the same manner as in Example 1 except that the antibacterial deodorant treatment agent prepared by mixing and mixing the weight % was mixed. &lt;Comparative Test and Evaluation&gt; ° Table 1 shows the mixed compositions of the antibacterial anti-six treatment agents in each of Examples 1 to 8 and Comparative Examples 1 to 9. In addition, in Table 1, A represents PHMB, B represents no bromide, c represents benzalkonium chloride, 〇 represents hexyl hexahydrogluconate, E represents polyoxyalkylene ether, and F represents alkylamine oxide, 〇 Alkyl

Benzene oxime I 〇 in ^ Φ ^ I , double Z represents the elapsed time when the pH exceeds 8 and the amount of NH 3 93905-990122.doc -24· 1324045 produced at this time. Further, Fig. 1 shows the results of the change in the pH per unit interval in the test using the spoilage of the antibacterial and deodorant treating agents of Comparative Examples 1 to 4, respectively. Call [Table 1] Corruption in the trial to make parsley

93905-990122.doc 25· 1324045 [Table 2] Elapsed time when pH exceeds 8 NH NH3 production amount in pH 8 [ppm] Elapsed time when pH exceeds 8 n nh3 production amount in pH 8 [ppm] Example 1 36 30 Comparative Example 1 &gt; 72 0 Example 2 48 40 Comparative Example 2 18 110 Example 3 72 60 Comparative Example 3 10 180 Example 4 72 65 Comparative Example 4 12 150 Example 5 30 40 Comparative Example 5 &gt; 72 0 Example 6 36 32 Comparative Example 6 32 50 Example 7 50 45 Comparative Example 7 60 85 Example 8 72 20 Comparative Example 8 10 180 Comparative Example 9 30 30

As shown in Table 2 and Figure 1, the treatment agent of the comparative example using bromide in the antibacterial component can obtain a very strong and stable anti-staining effect when a small amount is added, and even after 72 hours, the corruption is confirmed. Not carried out, no ammonia was detected. Therefore, the antibacterial component remaining after the use of the discharge is not easily deactivated, which may affect the drainage treatment facility. The treatment agent of Comparative Example 2 using benzalkonium chloride was confirmed to have spoilage after 12 hours even after a relatively high concentration was applied, and after 18 hours, the pH exceeded 8 and 110 ppm of ammonia was detected, which was completely corrupt. situation. Thus, it can be determined that a stable antiseptic effect cannot be obtained. In Comparative Example 3, in which no treating agent was added, the pH rose sharply after 5 hours, and after 10 hours, the pH exceeded 8, which was completely spoiled, and 180 ppm of ammonia was detected. The treatment agent of Comparative Example 4 in which the amount of PHMB was less than 1% by weight increased the pH sharply after 6 hours, and after 12 hours, the pH exceeded 8 and became completely spoiled, and the ammonia of 150 ppm was measured. It was found to have the same tendency as Comparative Example 3 in which no treatment agent was added. PHMB input exceeds 15 weights 93905-990122.doc -26-

X X1324045 The amount of the treatment agent of Comparative Example 5 was not confirmed even after 72 hours. • Corruption No ammonia was detected. At this time, at the time of discharge after use, it is necessary to carry out deactivation treatment by an appropriate amount (above or equal to the amount of PHMB) of an anionic surfactant. The treatment agent of Comparative Example 6 in which the amount of the PHMB was 2% by weight and the polyoxyalkylene domain was 12% by weight and the ratio of the interface active ingredient was higher, and 50 ppm of ammonia was detected at 32 hours, and PHMB was detected. Investing ϊ: Compared with the same example, the duration of the antibacterial effect is not prolonged, but instead, there is a tendency to become shorter. On the other hand, the treatment agent of Comparative Example 7 in which the amount of the PHMB was 1 〇 by weight of the polyoxyalkylene ether was a ratio of 1.7 畺 畺 / 〇 to the interface active ingredient, and 85 ppm was detected at 60 hours. As compared with Example 3 in which the amount of ammonia was the same as that of ρΗΜβ, it was found that the duration of the antibacterial effect tends to be relatively short. Compared with the input amount of PHMB of 2% by weight, the input polyoxyalkylene ether was 1% by weight, and the alkylbenzene sulfonic acid was 3% by weight of Comparative Example 8, the liberation of the ruthenium during the preparation process resulted in white turbidity. Precipitation, which can be seen as 1, is 1 80 PPm at 1 hr and Comparative Example 3 without adding a treating agent has a tendency to be the same. Using the treatment of Comparative Example 9 of 5% by weight of chlorhexidine gluconate, 3 〇ppm of ammonia was detected at 30 hours, although it was found to be more stable and durable than the treatment of Comparative Example 2 using ammonium chloride. The antibacterial effect is, however, that the duration of the antibacterial effect is less than half of the pH MB2 Examples 3 and 4 as in /. For this, the antibacterial and deodorant treating agents of Examples 1 to 8 were changed in accordance with PHMBi +, and the duration of the amount of the dirt load with respect to the anticorrosive effect was changed in the yoke example 1 to detect 3 在 in 36 hours. Ppm, in Example 2, 939〇5-99〇i22.doc •27· was detected at 40 hours in 48 hours, / , PPm was detected in Example 3 at 6 hours of PP〇 at 72 hours. In Example 4, 65 Å was detected at 72 hours, 4 〇 ppm was detected at 30 hours in Example 5, and 32 Ppm was detected after % hour in Example 6 in Example 7. It was found to be "PPm at 5 () hours, and 2 氨 ammonia was detected at 72 hours in Example 8. From the above results, it was confirmed that the antibacterial and deodorant treatment agent of Example 8 of the present invention was stable. The antiseptic effect changes the composition ratio of the treatment agent by collecting the situation, and when the toilet is used, it suppresses the spoilage of the dirt to prevent the generation of foul odor, and when the discharge after use occurs, the spoil is generated without leaving the antibacterial component. It is judged that it does not affect the drainage treatment facility such as the activated sludge tank. The invention relates to an improvement of an environmentally-friendly toilet & bacteria deodorant treatment agent comprising an aqueous solution of a biguanide antibacterial component and an interface active component, which is characterized in that it contains 2% by weight to 1% by weight of I&gt; HMB as an antibacterial component, and contains 1% by weight to 50% by weight mainly as a surfactant component of any one or two or more of cationic, nonionic or amphoteric surfactants, and the weight ratio of the antimicrobial component to the interface active component is 1: In the range of 5 to 5: ι. The antibacterial and deodorant treatment agent having such a mixing ratio can be stored in the dirt storage tank of the water-saving toilet installed on trains, buses, airplanes, ships, and the like. Corruption is stably suppressed over a long period of time to prevent malodor. Further, the antibacterial and deodorant treatment agent of the present invention has an effect of deactivating the antibacterial and deodorizing effect according to the amount of dirt load proportional to the use time. In the case of residual antibacterial and deodorizing effect, it can be used as an amount of 93905-990122.doc -28 - 1324045 by inputting an appropriate amount (amount equal to or greater than the amount of PHMB) The sub-type surfactant is deactivated and does not adversely affect the feeding to the wastewater treatment facility after the waste is recovered. It can provide products with less environmental load. [Simplified Schematic] Figure 1 shows A schematic diagram of the change in pH per a certain period of time in the test using the spoilage of the antibacterial and deodorant treating agents of Examples 1 to 8 and Comparative Examples 1 to 9. 93905-990122.doc 29-

Claims (1)

丨II卞i Μ X. Apply for a patent Fanyuan factory' - one...·-- 】. A water-saving toilet antibacterial and deodorant (4), which contains an aqueous solution containing double-pulse antibacterial ingredients and interface active ingredients, The antibacterial and deodorant treatment agent is characterized in that it contains 2% by weight to 1% by weight of polyhexyldiamine hydrochloride as the antibacterial component, and contains 5% by weight to 5% by weight of cations, nonionics or Any one or two or more components of the amphoteric surfactant are used as the surfactant component, and the weight ratio of the antimicrobial component to the interface active component is in the range of 1:5 to 5:1. 2. The antibacterial and deodorant treating agent for a water-saving toilet according to claim 1, wherein the plant extract containing i% by weight to 4% by weight is further added to the total weight of the treating agent. 3. In the case of the antibacterial and deodorant treatment agent for a water-saving toilet of claim 1, wherein the non-ionic surfactant is contained in the interface active component, the amount of the weight of the hexamethylene dihydrazine hydrochloride is not equal to _, An anionic surfactant is further contained in the interface core component. 4. = Anti-bacterial and deodorizing treatment method for water-saving toilets, characterized in that: sewage is provided in the water-saving toilet, and it is not suitable, and the tank and the storage tank for the dirt are used in the sewage. The diluent is stored in a tank for diluting the antibacterial deodorant according to any one of claims 1 to 3 to a weight ratio of 50 to 500 times; in the case of using a toilet, The above-mentioned diluent is used as a stain for washing. 5. In the case of the clean water and the above-mentioned stain (4), it is in the tank for storing the dirt. An antibacterial and deodorizing treatment method for a water-saving toilet, characterized in that: in the t-water type: a sewage washing tank and a dirt storage tank are separately provided, respectively, in the above-mentioned &gt; Storage water, in the aforementioned dirt storage 93905-990122.doc 1324045 The diluent is stored in the tank, and the dilution is diluted with water to 50% to 5 times the weight ratio of the antibacterial deodorant according to any one of the items (1); when the use is obvious, the water is used as a stain The washing water of the object flows into the dirt storage container simultaneously with the dirt, and the dirt stored in the dirt storage tank (4) is prevented from causing spoilage and malodor by the diluent stored in the dirt storage tank. 6. The antibacterial and deodorizing treatment method for a water-saving toilet is characterized in that a dirt washing tank and a dirt storing tank are respectively provided in the water-saving toilet of the φ, respectively, in the dirt washing tank. The first dilution is stored, and the i-th dilution is diluted with water to an antibacterial deodorant such as jg 1 g 2 / of the item 1 to 3 to 5 (H. 5 call. The second dilution liquid is stored in the dirt storage tank. The second dilution liquid is diluted with water to remove the antibacterial deodorant according to any one of the items (1) to the same or different concentration as the first dilution liquid. When the toilet is used, the washing liquid which is the first dilution liquid and the dirt are simultaneously flowed into the dirt storage tank, and the ith xiao solution is stored in the dirt storage. Using the second dilution stored in the tank to prevent the accumulation of dirt in the above-mentioned dirt storage (4), causing spoilage and malodor. 7: An antibacterial and deodorizing treatment method for a water-saving toilet, characterized in that: in a water-saving toilet In the middle, separate the treatment tank for dirt washing, the sink for dirt washing, and the storage of dirt (4) Storing the antibacterial and deodorant treatment agent of any one of claims 1 to 3 in the aforementioned treatment agent tank to store water in the water tank; when using the toilet, the treatment agent and the water are discharged in a proportional manner. The treatment agent is diluted to a ratio of 50 to 500 times by weight. 93905-990122.doc 8. As the diluent, the diluent is used as a cleaning solution for the dirt and flows into the dirt storage tank simultaneously with the above-mentioned 'depletion matter. An antibacterial and deodorizing treatment method for a water-saving toilet, characterized in that: in a water-type toilet, a sewage cleaning treatment tank, a dirt washing water tank, and a dirt storage tank are respectively provided, The antibacterial and deodorant treatment agent according to any one of Items 1 to 3 is stored in the treatment agent tank, and the third dilution liquid is stored in the sewage storage tank in the water storage tank, and the second dilution liquid is stored in the sewage storage tank. The water of the antibacterial deodorant according to any one of the items (1) is released to a weight ratio of 50 times to 500 times; when the toilet is used, the treatment agent is discharged in a certain ratio with the water, and the treatment agent is used. Dilute heart times ~ _ times the weight ratio In the fourth dilution liquid, the fourth dilution liquid and the dirt are simultaneously introduced into the dirt storage tank, and the fourth dilution liquid is stored in the dirt storage tank. The third dilution liquid prevents the contamination accumulated in the dirt storage tank from causing spoilage and malodor. 9. The antibacterial and deodorizing treatment method of the y-type water-saving toilet is characterized in that, in the water-saving type, respectively Providing a pressure reducing device, a washing water tank, and a dirt storage tank, wherein the diluent is stored in the dirt storage tank, and the diluent is diluted with water as an antibacterial deodorant according to any one of claims 3 to 3. To a weight ratio of 5 to 500 times; when using the toilet, the dirt and the small amount of water supplied from the washing tank are simultaneously sucked into the tank by the aforementioned decompression device, The dilution liquid stored in the dirt storage tank prevents spoilage and malodor from being generated in the dirt storage tank. 93905-990122.doc 1324045 10. An antibacterial and deodorizing treatment method for a water-saving toilet according to any one of items 4 to 9 wherein the dirt and the dirt are simultaneously stored in the diluent or the dirt tank in the dirt storage tank. The concentration of the antibacterial and deodorant treatment agent contained in either or both of the dilution liquids is determined according to the storage time in the storage tank and the amount of dirt load in the inflow of the sewage. Inactivation of antibacterial and deodorant effects. 11. The antibacterial and deodorizing treatment method for a water-saving toilet according to any one of claims 4 to 9, wherein when the dirt is discharged from the storage tank, the hexyl hydrazine hydrochloride is added and concentrated with respect to the dirt. An anionic surfactant having an amount equal to or greater than the amount of the salt can completely deactivate the remaining antibacterial component in the soil by a certain treatment. 12. For the antibacterial and deodorizing treatment method of the water-saving toilet of the item 1 of the present invention, wherein the amount of the hexyl hydrazine hydrochloride is added and concentrated with respect to the dirt when the dirt is discharged from the storage tank. The anionic surfactants of equal amounts or more can completely inactivate the remaining antibacterial components in the above-mentioned soil by a certain treatment. The antibacterial and deodorant treatment agent for a water-saving toilet used in the treatment method according to any one of claims 4 to 2. 93905-990l22.doc