TWI322135B - Bio-coagulant and method for treating high turbidity water - Google Patents

Bio-coagulant and method for treating high turbidity water Download PDF

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TWI322135B
TWI322135B TW95128612A TW95128612A TWI322135B TW I322135 B TWI322135 B TW I322135B TW 95128612 A TW95128612 A TW 95128612A TW 95128612 A TW95128612 A TW 95128612A TW I322135 B TWI322135 B TW I322135B
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water
high turbidity
coagulant
turbidity water
treating high
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TW95128612A
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TW200808661A (en
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Yu Lan Hsu
How Liang Huang
Jui Pin Chen
Chien Hsiao Chen
Hong Zhang Wu
Pearl Hsiu Ping Lin
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Dev Center Biotechnology
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1322135 九、發明說明: 【發明所屬之技術領域】 本發明係有關於處理高濁度水’且特別有關於生物性 凝聚劑及處理高濁度水之方法。 【先前技術】 傳統上淨水場處理流程多為混凝、沉降處理程序,其 中混凝沉降單元之設計標準,係以原水濁度兩千度以内, 可以出水百分之百,若濁度達五千度,則需加強藥劑,出 水量只有八成五左右;濁度達五千至一萬度,則出水量下降 至八成,而一萬度左右,只能出水五成,一萬五以上則只 有一成,且當出水量只有七成五至八成五時,便需分區供 水,即對民生或工業產生相當大的影響。 目前淨水處理常用的化學凝聚劑包括硫酸鋁 (A12(S04)3)、氯化鐵(FeCl3)、聚氣化鋁(PAC1)、聚丙烯醯 胺(polyacrylamide,PAM)、聚氯化己二晞二曱基胺 (poly(diallyldimethyl ammonium chloride) > poly (DADMAC) 及氯曱基一氧三環二曱基胺聚合物Epi-DMA polyamines(epichlorohydrin dimethylamine polymer),例 如,以PAC1處理時,先加入液驗提升pH約至8〜9之間, 再加入PAC1進行混凝動作,使混凝時控制於pH中性混凝 範圍,其成本較高且處理後水質導電度及總解解性固形物 (TDS)值較高,並因PAC1(10%)混凝劑本身電荷密度為 1,375,000 meq/g,易因高濁度水懸浮固體物多,加藥量的 0296-A21698TWF(N2):358:kai 6 1322135 增加,至使不易達到電中性,產生水質反濁現象,當濁度 大於2000NTU時,無法有效率的混凝及快速沉降,造成缺 水問題。此外,在以PAC1處理時,容易造成處理後水含 殘鋁致癌性的問題。 【發明内容】 本發明的目的為提供一種生物性凝聚劑及處理高濁度 水之方法,使處理後水濁度降至5NTU以下、殘铭量在 0.1 mg/L以下,且不會發生上清液反濁的現象。 為達成上述目的,本發明提供一種生物性凝聚劑,其 適用於處理高濁度水,其中該生物性凝聚劑的導電度介於 2.13mS/cm與16.17mS/cm之間,且電荷密度介於120meq/g 與 3055meq/g。 為達成上述目的,本發明另提供一種處理高濁度水之 方法,包括加入一生物性凝聚劑至高濁度水中,且經過一 混凝及一沉降步驟,其中該生物性凝聚劑的導電度介於 2.13mS/cm與16.17mS/cm之間,且電荷密度介於120meq/g 與3055meq/g。更包括在該沉降步驟後加入化學凝聚劑, 且再經過一混凝及一沉降步驟。 為了讓本發明之上述和其他目的、特徵、和優點能更 明顯易懂,下文特舉較佳實施例,並配合所附圖示,作詳 細說明如下: 【實施方式】 本發明主要係利用導電度介於2.13mS/cm與 0296-A21698TWF(N2):358:kai 7 1322135 16.17mS/cm之間,且電荷密度介於120meq/g與3055meq/g 之間的生物性凝聚劑來處理高濁度水。在本發明中,所用 之生物性凝聚劑可為幾丁聚醣水溶液或以其為組成之複合 配方溶液。 本發明中,處理高濁度水的方法可為單階段處理或雙 階段處理,參照第1圖,單階段處理係將導電度介於 2.13mS/cm 與 16.17mS/cm 之間,電荷密度介於 120meq/g 與3055meq/g之間’pH值介於1〜5.0及濃度介於0.1〜5% 的生物性凝聚劑加入高濁度水中,此生物性凝聚劑的添加 量在5ppm至5000ppm之間,較佳在500ppm至3000ppm 之間,依序進行混凝(快混、慢混)及沉降等步驟。參照第2 圖,其中慢混步驟可使用多槽串聯之操作模式,以多個慢 混槽201及多個攪拌器203,來增加去除濁度之效果。在 一較佳實施例中,生物性凝聚劑的導電度約為2.37 mS/cm,電荷密度約為1015.6 meq/g,pH值約為4,濃度 約為1%。其中混凝步驟包括快混及慢混,快混的轉速在 180至200rpm之間,時間在20秒至60秒之間,速度坡降 (G)在200 s_1至400 s-1之間,慢混的轉速在55至75rpm之 間,時間在3分至30分之間,速度坡降(G)在20 s·1至75 s·1 之間,Gt值在2xl04-2xl05。沉降的時間在1至120分鐘, 較佳在10分鐘。本發明生物性凝聚劑對導電度的影響很 低,處理後所獲得之膠沉水無鋁殘留、濁度去除率在90% 以上,且不會有劑量過多(overdose)產生反濁問題。 參照第3圖,雙階段處理包括第一階段的預處理及第 0296-A21698TWF(N2):358:kai 8 1322135 二階段的化混處理,在第一階段,加入本發明之生物性凝 聚劑至高濁度水中,經過第一混凝及第一沉降步驟後,濁 度一般可由27072NTU降至2000NTU。生物性凝聚劑的添 加量在lOppm至200ppm,較佳30ppm至40ppm之間。第 一混凝步驟包括快混及慢混,其中快混的轉速在18〇至 200rpm之間,時間在20秒至60秒之間,速度坡降(G)在 200 s-1至400 之間,慢混的轉速在55至75rpm之間, 時間在3分至30分之間,速度坡降(G)在40 s·1至70 s·1之 間’ Gt值在1〇4-1〇5。沉降的時間可從1至12〇分鐘,較佳 10分鐘左右。其中慢混步驟包括多槽串聯之操作模式,如 第2圖所示。 接著’於第二階段中加入化學凝聚劑,再進行第二混 凝及第二沉降,以將濁度由2000NTU降至5NTU以下。化 學凝聚劑可為Al2(S〇4)3、FeCl3、聚丙烯醯胺、聚氣化己二 烯二曱基胺、氣曱基一氧三環二曱基胺聚合物或聚氯化 銘’其中又以聚氣化銘較佳。一般而言,化學凝聚劑的添 加量在lOppm至350ppm之間’較佳在ΐ〇〇ρρπι至2〇〇ppm 之間。第二混凝亦可包括快混及慢混二階段,其中快混的 參數可與第一階段相同’慢混的轉速在55至75rpm之間, 時間在3分至30分之間’速度坡降(G)在20 s-1至75 s·1之 間,Gt值在2x 104-2x 105。第二沉降的參數可與第一階段的 沉降相同。 經雙階段處理後,含銘量測試可低於mg/L,表示 雙階段處理可有效降低聚氮化紹的添加劑量,故大幅缩減 0296-A21698TWF(N2):358;kai 9 1322135 殘鋁的生成可能。 【實施例】 實施例1:單階段處理方式 將 1%,ρΗ4,導電度 2.37 ms/cm,電荷密度 1,016 meq/g 之幾丁聚醣凝聚劑溶液加至1000 ml的高濁度水中,原水 濁度為27072 NTU,原水混凝機為Jar Test式,其中各參 數如表一所示。在添加幾丁聚醣凝聚劑後經過190 rpm, 30秒的快混,65 rpm,558秒的慢混,及600秒的沉降以 去除原水中的懸浮粒子。此外,以添加聚氯化铭的高濁度 水作為對照組。由第4圖可知,幾丁聚醣凝聚劑沉降速度 較聚氯化鋁快約5-10倍,由第5a-5d圖可知,幾丁聚醣凝 聚劑不會影響原水的pH值及導電度,且濁度去除率可達 90%以上,但聚氯化鋁會導致原水導電度增加(較本發明凝 聚劑高5-10倍)、pH下降,耗鹼度較高,且會發生上清液 反濁的現象。參照表二,聚氣化铭劑量在600 ppm時,其 濁度可降至6 NTU,幾丁聚醣凝聚劑量在1500 ppm時,濁 度可降至5 NTU。 表一、處理高濁度水之參數 快混 慢混 目的 藥劑混合 膠羽形成 水樣體積 1000 ml 1000 ml 轉速 190 rpm 65 rpm 時間 30 sec 558 sec 0296-A21698TWF(N2):358:kai 13221351322135 IX. Description of the Invention: TECHNICAL FIELD OF THE INVENTION The present invention relates to a method for treating high turbidity water' and particularly to a biological coagulant and a process for treating high turbidity water. [Prior Art] Traditionally, the clean water treatment process is mostly a coagulation and sedimentation treatment program. The design standard of the coagulation sedimentation unit is within two thousand degrees of raw water turbidity, and can be 100% water. If the turbidity reaches five thousand degrees. , it is necessary to strengthen the pharmacy, the water output is only about 85 percent; the turbidity is 5,000 to 10,000 degrees, the water output drops to 80%, and about 10,000 degrees, only 50% of the water, only 10% of the 10,000 or more. And when the water output is only 75% to 85%, the district water supply is required, which has a considerable impact on people's livelihood or industry. At present, chemical coagulants commonly used in water purification include aluminum sulfate (A12(S04)3), ferric chloride (FeCl3), polyaluminized aluminum (PAC1), polyacrylamide (PAM), polychlorinated hexahydrate. Poly(diallyldimethyl ammonium chloride) > poly (DADMAC) and epi-DMA polyamines (epichlorohydrin dimethylamine polymer), for example, when treated with PAC1, Add liquid test to raise the pH to about 8~9, then add PAC1 to carry out the coagulation action, so as to control the pH neutral coagulation range during coagulation, the cost is high and the water conductivity and total decomposed solidity after treatment The value of the material (TDS) is higher, and the charge density of the PAC1 (10%) coagulant is 1,375,000 meq/g, which is easy to suspend solids due to high turbidity. The dosage of 0296-A21698TWF(N2):358 :kai 6 1322135 increase, so that it is difficult to achieve electrical neutrality, resulting in anti-turbidity of water quality. When the turbidity is greater than 2000 NTU, it can not be efficient coagulation and rapid sedimentation, resulting in water shortage. In addition, when treated with PAC1, It is easy to cause the problem that the treated water contains residual aluminum carcinogenicity. The object of the present invention is to provide a biological coagulant and a method for treating high turbidity water, wherein the turbidity of the treated water is reduced to below 5 NTU, the amount of the residue is below 0.1 mg/L, and the supernatant does not occur. In order to achieve the above object, the present invention provides a biological coagulant suitable for treating high turbidity water, wherein the conductivity of the biological coagulant is between 2.13 mS/cm and 16.17 mS/cm. And the charge density is between 120 meq/g and 3055 meq/g. To achieve the above object, the present invention further provides a method for treating high turbidity water, comprising adding a biological coagulant to high turbidity water, and undergoing a coagulation and a sedimentation step, wherein the biocoagulant has a conductivity between 2.13 mS/cm and 16.17 mS/cm, and a charge density between 120 meq/g and 3055 meq/g, further comprising adding chemical condensation after the sedimentation step The above and other objects, features, and advantages of the present invention will become more apparent and understood. The description is as follows: The present invention mainly utilizes a conductivity between 2.13 mS/cm and 0296-A21698TWF(N2): 358:kai 7 1322135 16.17 mS/cm, and a charge density between 120 meq/g and 3055 meq/g. Biocoagulant to treat high turbidity water. In the present invention, the biological coagulant used may be an aqueous solution of chitosan or a composite formulation solution composed thereof. In the present invention, the method for treating high turbidity water may be a single-stage treatment or a two-stage treatment. Referring to Figure 1, the single-stage treatment system has a conductivity of between 2.13 mS/cm and 16.17 mS/cm, and the charge density is The biological coagulant having a pH between 1 and 5.0 and a concentration of 0.1 to 5% is added to the high turbidity water between 120 meq/g and 3055 meq/g, and the biological coagulant is added in an amount of 5 ppm to 5000 ppm. Preferably, between 500 ppm and 3000 ppm, the steps of coagulation (fast mixing, slow mixing) and sedimentation are carried out in sequence. Referring to Fig. 2, wherein the slow mixing step can use the multi-tank series operation mode, the plurality of slow mixing tanks 201 and the plurality of agitators 203 are used to increase the effect of removing turbidity. In a preferred embodiment, the biocoagulant has a conductivity of about 2.37 mS/cm, a charge density of about 1015.6 meq/g, a pH of about 4, and a concentration of about 1%. The coagulation step includes fast mixing and slow mixing. The speed of the fast mixing is between 180 and 200 rpm, the time is between 20 seconds and 60 seconds, and the speed gradient (G) is between 200 s_1 and 400 s-1. The mixing speed is between 55 and 75 rpm, the time is between 3 and 30 minutes, the speed gradient (G) is between 20 s·1 and 75 s·1, and the Gt value is between 2xl04 and 2xl05. The settling time is from 1 to 120 minutes, preferably 10 minutes. The biocoagulant of the present invention has a low influence on conductivity, and the obtained glue has no aluminum residue and turbidity removal rate of more than 90%, and there is no overdose problem of anti-turbidity. Referring to Fig. 3, the two-stage treatment includes the first stage of pretreatment and the 0296-A21698TWF(N2):358:kai 8 1322135 two-stage chemical mixing treatment, in which the biological coagulant of the present invention is added to the first stage. In turbidity water, after the first coagulation and the first settling step, the turbidity can generally be reduced from 27072 NTU to 2000 NTU. The biological coagulant is added in an amount of from 10 ppm to 200 ppm, preferably from 30 ppm to 40 ppm. The first coagulation step includes fast mixing and slow mixing, wherein the fast mixing speed is between 18 〇 and 200 rpm, the time is between 20 seconds and 60 seconds, and the speed gradient (G) is between 200 s-1 and 400. The speed of slow mixing is between 55 and 75 rpm, the time is between 3 and 30 minutes, and the speed gradient (G) is between 40 s·1 and 70 s·1. The Gt value is 1〇4-1〇. 5. The settling time can be from 1 to 12 minutes, preferably about 10 minutes. The slow mixing step includes a multi-slot series operation mode as shown in FIG. Next, a chemical coagulant is added in the second stage, followed by a second coagulation and a second settling to reduce the turbidity from 2000 NTU to less than 5 NTU. The chemical coagulant may be Al2(S〇4)3, FeCl3, polypropylene decylamine, polygas hexadienyldidecylamine, gas sulfhydryl monooxydicyclodecylamine polymer or polychlorinated ' Among them, it is better to use gasification. In general, the amount of chemical coagulant added is between 10 ppm and 350 ppm, preferably between ΐ〇〇ρρπι and 2〇〇ppm. The second coagulation may also include two stages of fast mixing and slow mixing, wherein the parameters of the fast mixing may be the same as the first stage. The speed of the slow mixing is between 55 and 75 rpm, and the time is between 3 and 30 minutes. The drop (G) is between 20 s-1 and 75 s·1, and the Gt value is between 2 x 104 and 2 x 105. The parameters of the second settling can be the same as the settling of the first stage. After two-stage treatment, the containing quantity test can be lower than mg/L, which means that the two-stage treatment can effectively reduce the amount of additive of polynitrile, so the reduction of 0296-A21698TWF(N2):358; kai 9 1322135 residual aluminum is greatly reduced. The build is possible. EXAMPLES Example 1: Single-stage treatment method A solution of 1%, ρΗ4, a conductivity of 2.37 ms/cm, and a charge density of 1,016 meq/g of chitosan coagulant was added to 1000 ml of high turbidity water, raw water. The turbidity is 27072 NTU, and the raw water mixer is Jar Test type, and the parameters are shown in Table 1. After the addition of the chitosan coagulant, 190 rpm, 30 seconds of rapid mixing, 65 rpm, 558 seconds of slow mixing, and 600 seconds of sedimentation were used to remove suspended particles in the raw water. In addition, high turbidity water of polychlorinated rice was added as a control group. It can be seen from Fig. 4 that the sedimentation rate of chitosan coagulant is about 5-10 times faster than that of polyaluminium chloride. It can be seen from Fig. 5a-5d that the chitosan coagulant does not affect the pH and conductivity of the raw water. And the turbidity removal rate can reach more than 90%, but the polyaluminum chloride will lead to an increase in the conductivity of the raw water (5-10 times higher than the coagulant of the present invention), a decrease in pH, a high alkalinity, and a supernatant will occur. The phenomenon of liquid turbidity. Referring to Table 2, the turbidity can be reduced to 6 NTU at a concentration of 600 ppm, and the turbidity can be reduced to 5 NTU at a dose of 1500 ppm. Table 1. Parameters for handling high turbidity water Quick mixing Slow mixing Purpose Agent mixing Glue formation Water sample volume 1000 ml 1000 ml Speed 190 rpm 65 rpm Time 30 sec 558 sec 0296-A21698TWF(N2):358:kai 1322135

表二、比較聚氣化鋁與幾丁聚醣處理後之水質 原水 聚氣化紹(600 幾丁聚醣(1500 ppm) ppm) pH值 7.23 6.77 7.14 混凝劑量 0 600 1500 (PPm) 殘留濁度 27072 6 5 (NTU) 界達電位 -19.3 0.4 -0.191 (mV) 導電度 0.188 0.293 0.191 (mS/cm) 殘留鹼度 84.5 73.9 80.6 (mg/L) 殘铭(mg/L) ND 0.12 ND 角速度 19.89 rad/s 6.28 rad/s 速度 0.44745 m/s 0.1413 m/s 輸入功率 0.0919 kg/m2/s2 0.0029 kg/m2/s2 速度坡降 303 s—1 60 s'1 Gt 9000 33850 實施例2 :雙階段處理方式 首先,第一階段將1%,pH4,導電度2.37 ms/cm,電 0296-A21698TWF(N2):358;kai 1322135 荷密度1,016 meq/g之幾丁聚醣凝聚劑溶液加至1000 ml的 高濁度水中,原水濁度為27072 NTU ’幾丁聚的添加量 為 35 ppm,經過 190 rpm,30 秒的快混,65 ipm,558 秒 的慢混,及600秒的沉降後,加入50 ppm至200 ppm之聚 氯化銘,再經過190 rpm,30秒的快混’ 65 rpm,558秒的 慢混,及600秒的沉降以去除懸浮粒子。此外,以二階段 皆添加聚氯化鋁作為對照組,對照組之第一階段加入5 ppm之聚氣化銘,第二階段加入加入50 ppm至200 ppm之 聚氯化鋁。由第6、7圖可知,對照組會產生上清液反濁的 現象,而添加本發明之幾丁聚醣凝聚劑則無反濁現象,且 由表三、四可知,對照組最後的原水殘留濁度在10〜20 NTU,而本發明的殘留濁度則可降至5 NTU以下。 表三、以幾丁聚醣+聚氯化鋁處理後之水質 第一階段 幾丁聚 醣的添 加 量 (PPm) 濁 度 (NTU) 界達電位 (mV) pH值 導電度 (jiiS/cm) 殘留鹼度 (mg/L) 紹含量 35 1,914 -9.2 7.8 807 87.5 ND 第二階段 聚氣4匕 濁 度 界達電位 pH值 導電度 殘留鹼度 铭含量 紹的添 (NTU) (mV) (pS/cm) (mg/L) 加 量 0296-A21698TWF(N2);358:kai 1322135Table 2: Comparison of polyaluminum and chitosan treated water raw water gasification (600 chitosan (1500 ppm) ppm) pH 7.23 6.77 7.14 Coagulation dose 0 600 1500 (PPm) Residual turbidity Degree 27072 6 5 (NTU) Boundary potential -19.3 0.4 -0.191 (mV) Conductivity 0.188 0.293 0.191 (mS/cm) Residual alkalinity 84.5 73.9 80.6 (mg/L) Residue (mg/L) ND 0.12 ND angular velocity 19.89 rad/s 6.28 rad/s speed 0.44745 m/s 0.1413 m/s input power 0.0919 kg/m2/s2 0.0029 kg/m2/s2 speed ramp 303 s-1 1 s'1 Gt 9000 33850 Example 2: double Stage treatment method First, the first stage will add 1%, pH4, conductivity 2.37 ms/cm, electricity 0296-A21698TWF(N2):358; kai 1322135 density 1,016 meq/g chitosan coagulant solution to 1000 In high turbidity water of ml, the raw water has a turbidity of 27,072 NTU. The addition amount of 35 ppm is 35 ppm, after 190 rpm, 30 seconds of fast mixing, 65 ipm, 558 seconds of slow mixing, and 600 seconds of sedimentation. Add 50 ppm to 200 ppm polychlorination, then 190 rpm, 30 seconds of fast mixing '65 rpm, 558 seconds of slow mixing, and 600 Sedimentation in seconds to remove suspended particles. In addition, polyaluminum chloride was added as a control group in two stages, and a 5 ppm polygasification was added in the first stage of the control group, and a polychlorinated aluminum (50 ppm to 200 ppm) was added in the second stage. It can be seen from Figures 6 and 7 that the control group will produce the phenomenon of anti-turbidity of the supernatant, while the addition of the chitosan aggregating agent of the present invention has no anti-turbidity phenomenon, and the final raw water of the control group is known from Tables 3 and 4. The residual turbidity is between 10 and 20 NTU, while the residual turbidity of the present invention can be reduced to below 5 NTU. Table 3. Addition of chitosan in the first stage of water quality after treatment with chitosan + polyaluminum chloride (PPm) Turbidity (NTU) Boundary potential (mV) pH conductivity (jiiS/cm) Residual alkalinity (mg/L) Content 35 1,914 -9.2 7.8 807 87.5 ND Second stage gas collection 4 turbidity boundary potential pH conductivity residual alkalinity content content of addition (NTU) (mV) (pS /cm) (mg/L) Addition 0296-A21698TWF(N2);358:kai 1322135

(ppm) 50 8.63 0.6 7.37 822 74 ND 75 5.57 0.8 7.19 833 71.8 ND 100 3.36 0.8 7.1 846 69.6 ND 125 3.05 0.9 6.96 852 64.8 ND 150 2.83 1.0 6.89 866 56.6 ND 200 4.25 1.2 6.78 888 55.9 ND 表四、皆以聚氯化鋁處理後之水質(ppm) 50 8.63 0.6 7.37 822 74 ND 75 5.57 0.8 7.19 833 71.8 ND 100 3.36 0.8 7.1 846 69.6 ND 125 3.05 0.9 6.96 852 64.8 ND 150 2.83 1.0 6.89 866 56.6 ND 200 4.25 1.2 6.78 888 55.9 ND Table 4 Water quality after treatment with polyaluminum chloride

第一階段 聚氯化 在呂的添 加 量 (PPm) 濁 度 (NTU) 界達電位 (mV) pH值 導電度 (μS/cm) 殘留鹼度 (mg/L) 1呂含量 5 2,508 -10.6 7.68 816 88.0 ND 第二階段 聚氣4匕 在呂的添 加 量 (PPm) 濁 度 (NTU) 界達電位 (mV) pH值 導電度 (/xS/cm) 殘留鹼度 (mg/L) 鋁含量 50 8.63 0.6 7.40 832 76.4 ND 75 10.52 0.7 7.23 842 74.5 ND 100 12.72 0.8 7.09 855 68.8 ND 125 14.06 0.8 7.00 863 64.2 ND 0296-A21698TWF(N2);358:kai 1322135Addition amount of first stage polychlorination in Lu (PPm) Turbidity (NTU) Limit potential (mV) pH conductivity (μS/cm) Residual alkalinity (mg/L) 1 Lu content 5 2,508 -10.6 7.68 816 88.0 ND second stage gas accumulation 4 匕 addition amount in Lu (PPm) turbidity (NTU) boundary potential (mV) pH conductivity (/xS / cm) residual alkalinity (mg / L) aluminum content 50 8.63 0.6 7.40 832 76.4 ND 75 10.52 0.7 7.23 842 74.5 ND 100 12.72 0.8 7.09 855 68.8 ND 125 14.06 0.8 7.00 863 64.2 ND 0296-A21698TWF(N2);358:kai 1322135

150 19 0.8 6.88 876 60.9 ND 200 22.6 0.9 6.75 888 53.0 ND 雖然本發明已以較佳實施例揭露如上,然其並非用以 限定本發明,任何熟習此技藝者,在不脫離本發明之精神 和範圍内,當可作些許之更動與潤飾,因此本發明之保護 範圍當視後附之申請專利範圍所界定者為準。150 19 0.8 6.88 876 60.9 ND 200 22.6 0.9 6.75 888 53.0 ND Although the invention has been described above by way of a preferred embodiment, it is not intended to limit the invention, and those skilled in the art without departing from the spirit and scope of the invention In the meantime, the scope of protection of the present invention is defined by the scope of the appended claims.

0296-A21698TWF(N2);358;kai 14 1322135 【圖式簡單說明】 第1圖顯示本發明之單階段處理方式。 第2圖顯示本發明之多槽慢混處理單元。 第3圖顯示本發明之雙階段處理方式。 第4圖顯示比較本發明凝聚劑與聚氣化鋁的沉降速 度。 第5a-5d圖顯示比較本發明凝聚劑與聚氯化鋁的濁 度、去除率、pH值及導電度。 第6圖顯示雙藥劑雙階段處理方式的殘留濁度。 第7圖顯示單藥劑雙階段處理方式的殘留濁度。 【主要元件符號說明】 201〜慢混槽; 203〜攪拌器。0296-A21698TWF(N2);358;kai 14 1322135 [Simplified Schematic] FIG. 1 shows a single-stage processing method of the present invention. Figure 2 shows the multi-slot slow mixing processing unit of the present invention. Figure 3 shows the two-stage processing of the present invention. Fig. 4 shows a comparison of the sedimentation speed of the coagulant of the present invention and the polyaluminized aluminum. Figures 5a-5d show comparisons of the turbidity, removal rate, pH and conductivity of the coagulant and polyaluminum chloride of the present invention. Figure 6 shows the residual turbidity of the two-agent two-stage treatment. Figure 7 shows the residual turbidity of the single-agent two-stage treatment. [Main component symbol description] 201~ slow mixing tank; 203~ stirrer.

0296-A21698TWF(N2):358:kai 150296-A21698TWF(N2):358:kai 15

Claims (1)

1322135 第 95128612 號 修正日期:99.1.15 修正本 十、申請專利範圍: 1.一種生物性凝聚劑,其適用於處理高濁度水,其中 該生物性凝聚劑包括幾丁聚醣水溶液、或以其為組成之複 合配方溶液,其濃度介於0.1%至5.0%之間、pH值約4、 導電度介於2.13mS/cm與16.17mS/cm之間,且電荷密度介 於 120meq/g 與 3055meq/g 之間。 2. —種處理高濁度水之方法,包括加入一生物性凝聚 劑至高濁度水中,且依序進行第一混凝及第一沉降步驟, 以移除原水中的懸浮粒子,其中該生物性凝聚劑包括幾丁 聚醣水溶液、或以其為組成之複合配方溶液,其濃度介於 0.1%至5.0%之間、pH值約4、導電度介於2,13mS/cm與 16.17mS/cm之間,且電荷密度介於120meq/g與3055meq/g 之間。 3. 如申請專利範圍第2項所述之處理高濁度水之方 法,更包括在該沉降步驟後加入一化學凝聚劑,且再依序 進行第二混凝及第二沉降步驟。 4. 如申請專利範圍第3項所述之處理高濁度水之方 法,其中該第一及第二混凝步驟各包括一快混及一慢混或 採單一混合單元。 5. 如申請專利範圍第4項所述之處理高濁度水之方 法,其中該快混的速度坡降(G)介於200s_1至40(^4之間, 時間介於20至60秒。 6. 如申請專利範圍第4項所述之處理高濁度水之方 法,其中該慢混的速度坡降(G)介於20s_1至75s_1之間,時 16 間介於3至30分鐘之間。 7·如申請專利範圍第6項所述之處理高濁度水之方 法’其中該慢混包括多槽串聯之操作或以水道混凝模式操 8.如申請專利範圍第3項所述之處理高濁度水之方 去,其中該第一及第二沉降的時間介於丨至12〇分鐘之間。 、、9.如申請專利範圍第3項所述之處理高濁度水之方 $,其中該化學凝聚劑為A12(s〇4)3、FeC13、聚丙烯醯胺、 ::化己二烯二甲基胺、氣甲基一氧三環二甲基胺聚合物 或聚氯化鋁。 法, 法 复0.如申响專利範圍第3項所述之處理高濁度水之方 、中該處理後之水導電度較以聚氣化紹處理低倍。 女申味專利範圍第3項所述之處理高濁度水之方 "中該處理後之水’濁度去除率在9〇%以上。1322135 Amendment No. 9512812: 99.1.15 Amendment to this application, patent scope: 1. A biological coagulant suitable for treating high turbidity water, wherein the biological coagulant comprises an aqueous solution of chitosan, or It is a composite solution of the composition, the concentration is between 0.1% and 5.0%, the pH is about 4, the conductivity is between 2.13mS/cm and 16.17mS/cm, and the charge density is between 120meq/g and Between 3055meq/g. 2. A method of treating high turbidity water comprising adding a biological coagulant to high turbidity water, and sequentially performing a first coagulation and a first settling step to remove suspended particles in the raw water, wherein the organism The coagulant comprises an aqueous solution of chitosan or a composite formulation solution thereof, the concentration of which is between 0.1% and 5.0%, the pH value is about 4, and the conductivity is between 2,13 mS/cm and 16.17 mS/. Between cm, and the charge density is between 120meq/g and 3055meq/g. 3. The method of treating high turbidity water as described in claim 2, further comprising adding a chemical coagulant after the settling step, and sequentially performing the second coagulation and the second settling step. 4. The method of treating high turbidity water according to claim 3, wherein the first and second coagulation steps each comprise a fast mixing and a slow mixing or a single mixing unit. 5. The method of treating high turbidity water according to claim 4, wherein the fast mixing speed gradient (G) is between 200 s_1 and 40 (^4, and the time is between 20 and 60 seconds. 6. The method for treating high turbidity water according to claim 4, wherein the slow mixing speed gradient (G) is between 20 s_1 and 75 s_1, and between 16 and 3 to 30 minutes. 7. The method for treating high turbidity water as described in claim 6 wherein the slow mixing comprises a multi-tank series operation or a water channel coagulation mode. 8. As described in claim 3 The treatment of the high turbidity water is carried out, wherein the first and second sedimentation time is between 丨 and 12〇 minutes. 9. The method for treating the high turbidity water as described in claim 3 of the patent application scope. $, wherein the chemical coagulant is A12(s〇4)3, FeC13, polyacrylamide, ::hexadienedimethylamine, gas methyl-oxytricyclodimethylamine polymer or polychlorinated Aluminium. Method, method recovery 0. If the high turbidity water is treated as described in the third paragraph of the patent scope, the conductivity of the water after treatment is lower than that of the gasification treatment. The high turbidity of the treated water in item 3 female flavor Patent application range side " of the treated water in the 'above 9〇% turbidity removal.
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