1320978 九、發明說明： . 【發明所屬之技術領域】' . 本發明是有關於一種奈米網狀白金系觸媒之轉印 方法，尤指一將合成於經處理過之基板上之奈米網狀 白金系觸媒轉印至一質子交換膜載體之方法。 【先前技術】 一般而言，目前使用於直接曱醇燃料電池（Direct Methanol Fuel Cell，DMFC)及質子交換膜燃料電池 (Proton Exchange Membrane Fuel Cell，PEMFC)電極之 奈米觸媒，其施加方法大約有三種：（1)直接塗佈於質 子交換膜上，（2)先塗佈於一可分離之基材上再轉印至 質子交換膜上，（3)先塗佈於電極基材上再直接熱壓至 質子交換膜上。其中以前兩種方式之觸媒用量較省。 典型乏例子，如中華民國專利公報公告第1222237號 之「燃料電池用觸媒電極及具有該觸媒電極之燃料電 池與前述各物品之製造方法」，此專利内容係為一種燃 料電池用觸媒電極，包含：基板；及觸媒層，鄰接於 該基板而形成，含有觸媒載體碳粒子與固體聚合物電 解質；其特徵為：該基板及該觸媒層中的至少任一個， 含有至少一種消泡劑。 又如中華民國專利公報公告第1250686號之「燃 料電池、燃料電池用電極及前述物品之製造方法」，此 5 1320978 專利内容係為一種燃料電池用電極， 置於。亥基質一側的表面上之集電體； 一側的表面上之觸媒層；其特徵為： 質，係接合在一起。 最近本研究小組研發出一種以白金及其它責重金 屬組成之奈米網狀白金系觸媒（方法詳述於實施方 如 Pt、Pt_Ru 搞·…·一1320978 IX. Invention Description: [Technical Field of the Invention] The present invention relates to a method for transferring a nano-network-like platinum-based catalyst, and more particularly to a nano-synthesis synthesized on a treated substrate. A method in which a reticular platinum-based catalyst is transferred to a proton exchange membrane carrier. [Prior Art] In general, nanocatalysts currently used in direct Methanol Fuel Cell (DMFC) and Proton Exchange Membrane Fuel Cell (PEMFC) electrodes are applied approximately. There are three kinds: (1) directly coated on the proton exchange membrane, (2) first coated on a separable substrate and then transferred onto the proton exchange membrane, and (3) first coated on the electrode substrate. Direct hot pressing onto the proton exchange membrane. Among them, the amount of catalyst used in the previous two methods is relatively low. A typical example of a fuel cell catalyst electrode and a fuel cell having the catalyst electrode and a method for producing the above-described articles are disclosed in the Chinese Patent Publication No. 1222237, which is a catalyst for a fuel cell. The electrode includes: a substrate; and a catalyst layer formed adjacent to the substrate, comprising catalyst carrier carbon particles and a solid polymer electrolyte; wherein at least one of the substrate and the catalyst layer contains at least one Defoamer. For example, the fuel cell battery, the electrode for a fuel cell, and the method for producing the above article are disclosed in the Japanese Patent Publication No. 1250686, which is an electrode for a fuel cell. a collector on the surface of one side of the matrix; a catalyst layer on the surface of one side; characterized by: a mass, which is joined together. Recently, the research team has developed a nano-networked platinum-based catalyst composed of platinum and other responsible metals (the method is detailed in the implementation of Pt, Pt_Ru, etc.
里直接甲醇燃料電池及質子交換膜燃料電池使用之觸 媒。但此奈米網狀白金系觸媒係直接成長於基板或基 材上，無法脫離，亦無法轉印至質子交換膜上•故二 一般習用方法無法符合於實際使用時之所需。 【發明内容】Catalysts used in direct methanol fuel cells and proton exchange membrane fuel cells. However, the nano-networked platinum-based catalyst is directly grown on the substrate or the substrate, and cannot be detached, and cannot be transferred to the proton exchange membrane. Therefore, the conventional method cannot be adapted to the actual use. [Summary of the Invention]
包含：基質，·配 配置於該基質另 該集電體與該基 本發明之主要目的係在於，將成長於基板之 網狀白金系觸媒轉印至一質子交換臈載體。 T 、 t達上述之目W，本發明係為—種奈米 系觸媒之轉印方法，係至少包括下列步驟： 免 a. 於一基板噴塗一高分子材料膜； b. 成長-奈米網狀白金系觸媒於具高分子材料臈 c, 進行加熱處理使該高分子材料膜分解，並使該 奈米網狀白金系觸媒與基板分離；以及 " 6 劑之一面愈-面喷塗一接著劑，並將喷塗接著 、該奈米網狀白金系觸媒接合，經熱 使該奈米網狀白金系觸媒轉印至載體。' 【實施方式】 請參閱『第1、ΪΔ ^ 係本發明之阶立1C及第1D圖』所示， 發明之2 意圖、本發明之步驟a示意圖、本 二之步：：2意圖、本發明之步驟C示意圖及本發 網狀白圖。如圖所示··本發明係為一種奈米 米網狀白金==法’係將成長於基板1之奈 驟·· 、 P至載體，係至少包含下列步 該αΠΓ於—基板1嘴塗—高分子材料膜2,其中， ^可為聚Hi膜㈣或玻璃’而高分子材料膜 板時，其厚度係非常薄，並須保持平坦。 子材2米網狀白金系觸媒3於具高分 構中二^加熱處理4使由上述步驟構成之結 媒並使該奈来網狀白金系觸 於攝氏500度。 …、處理4之,皿度係小 步驟d:於一載體$少 . α 戰髖5之一面喷塗一接著劑6,並將 噴塗接著劑6之一面盘兮太， ^ _ ^面與該奈米網狀白金系觸媒3接 Ά熱壓處理7 ’使該奈米網狀白金系觸媒3轉印 ，載體5’其t’該載體5係可為質子㈣膜，例如 、=杜邦么司之Nafl〇n離子交換膜等，而該接著劑係 可為Nafion成份組成之溶液。 由上述之方法可達到轉印該奈米網狀白金系 3至載體5。 μ參閱第2圖』所示’係為本發明成長奈米網 狀白金系觸媒之流程示意圖。如圖所示：於上述之步 驟b中’奈㈣狀白金系觸媒成長於基板之過程，係 至少包括下列步驟： 利用自身組合方法’將奈求球堆積排列 分子材料膜之基板上；其中，該奈米球係可為 a本乙烯或聚曱基丙稀酸甲醋之有機高分子聚合物 f ’或如二氧化石夕之無機化合物球，該奈米球係具有 粒检5〇nm至5〇〇nm之奈米粒’並附著於基板上呈至 :構層以上之立方堆積’可形成至少-層以上之網狀 步驟b2:於各奈米球間C真人金屬或其離子 >谷液’其中，該金屬係可為白㈣金屬及其與釘、錢、 鈀、銥或餓混合之金屬中至少擇其一；以及該金屬離 子溶液係可為 Pth、Pt4+、Ir3+、Rh3+、Ru3+、pd2+、Including: a substrate, a distribution, and a current collector, and a primary object of the present invention, is to transfer a reticulated platinum-based catalyst grown on a substrate to a proton-exchanged ruthenium carrier. T, t up to the above object W, the present invention is a nano-catalyst transfer method, comprising at least the following steps: Free a. spraying a polymer material film on a substrate; b. growing - nano The reticular platinum-based catalyst is provided with a polymer material 臈c, which is subjected to heat treatment to decompose the polymer material film, and separates the nano-network-like platinum-based catalyst from the substrate; and " 6-component one-face-face An adhesive is sprayed, and the nano-reticular platinum-based catalyst is subsequently sprayed, and the nano-network-like platinum-based catalyst is transferred to the carrier by heat. [Embodiment] Please refer to "1st, Ϊ Δ ^ is the steps 1C and 1D of the present invention", the intention of the invention 2, the schematic diagram of the step a of the present invention, the second step: 2 intention, this The schematic diagram C of the invention and the white pattern of the present invention. As shown in the figure, the present invention is a kind of nano-mesh white gold == method, which will grow on the substrate 1 and the P-carrier, at least including the following steps: - The polymer material film 2, wherein ^ can be a poly-Hi film (4) or a glass material, and the polymer material film plate is very thin in thickness and must be kept flat. The sub-material 2 m reticulated platinum-based catalyst 3 is in a high-profile structure. The heat treatment 4 causes the composition consisting of the above steps to cause the nematic reticulated platinum to contact 500 degrees Celsius. ..., process 4, the degree of the small step d: on a carrier $ less. α one of the hips 5 spray an adhesive 6, and spray one of the adhesive 6 面 too, ^ _ ^ face and Nano-networked platinum-based catalyst 3 is subjected to hot pressing treatment 7 'transfers the nano-networked platinum-based catalyst 3, and the carrier 5' is t'. The carrier 5 can be a proton (tetra) film, for example, = DuPont Nafl〇n ion exchange membrane, etc., and the binder may be a solution composed of Nafion components. The transfer of the nano-reticulated platinum system 3 to the carrier 5 can be achieved by the above method. μ is shown in Fig. 2, which is a schematic flow chart of the growth nano-network-like platinum catalyst of the present invention. As shown in the figure: in the above step b, the process of growing the nano-type platinum-based catalyst on the substrate comprises at least the following steps: using the self-combining method to deposit the ball on the substrate of the molecular material film; The nanosphere system may be an organic polymer of the present ethylene or polymethyl methacrylate methyl acrylate or an inorganic compound sphere such as a dioxide dioxide having a particle size of 5 〇 nm. Nanoparticles up to 5 〇〇 nm and attached to the substrate to: a cubic buildup above the formation layer can form at least a layer or more of the mesh step b2: between the nanospheres C true human metal or its ions > In the liquid solution, the metal system may be white (four) metal and at least one of metals mixed with nails, money, palladium, rhodium or hungry; and the metal ion solution may be Pth, Pt4+, Ir3+, Rh3+, Ru3+, pd2+,
Os及上述混合中擇其一或其多種離子溶液混合物， 而於各奈米ί求間之空隙填入金屬4其離子溶液係可採 用還原法或真空濺鍍方式達成。 步驟b3 ··將上述步驟構成之結構進行加氫氣還原 反應生成金屬觸媒及加熱處理，使於該結構中之奈米 求刀解即得到成長於基板之奈米網狀白金系觸媒， '、中右該奈米球為有機高分子聚合物球，須將該結 構送入高溫爐或通氣式氧化爐進行加熱，其加熱溫度 係小於攝& 500纟；若該奈米球為無機化合物球，須 添加氫㈣水溶液並進行加熱，其加熱溫度係小於攝 氏100度，經上述方式即可將奈米球分解。 呈上述步驟可得到成長於基板之奈米網狀白金系 觸媒’該奈米網狀白金系觸媒係可應用於直接甲醇燃 料電，及質子交換臈燃料電池。 、、综上所it ’本發明奈米網狀白金系觸媒之轉印方 法可有效改善習用之種種缺點，利用簡單製程，即可 將成長於基板之奈米網狀白金系觸媒轉印至質子交換 膜載體’進而使本發明之産生能更進步、更實用、更 符合使用者之所須’確已符合發明專利申請之要件， 爰依法提出專利申請。 I惟以上所述者，僅為本發明之較佳實施例而已， :不能以此限定本發明實施之範圍；&，凡依本發明 Μ專利範圍及發明說明書内容所作之簡單的等效變 1320978 化與修飾，皆應仍屬本發明專利涵蓋之範圍内。 1320978 【圖式簡單說明】 第1圖，係本發明之流程示意圖。 第1A圖，係本發明之步驟a示意圖。 第1B圖，係本發明之步驟b示意圖。 第1C圖，係本發明之步驟c示意圖。 第1D圖，係本發明之步驟d示意圖。 第2圖，係本發明成長奈米網狀白金系觸媒之流程示 意圖。 【主要元件符號說明】 步驟：a〜d 基板1 高分子材料膜2 奈米網狀白金系觸媒3 加熱處理4 載體5 接著劑6 熱壓處理7 步驟：bl〜b3Os and the above mixture may be selected from one or a plurality of ionic solution mixtures, and the space between the respective nanometers may be filled with metal 4, and the ionic solution may be obtained by reduction or vacuum sputtering. Step b3 ·· The structure formed by the above steps is subjected to hydrogen reduction reaction to form a metal catalyst and heat treatment, so that the nano-network-like platinum catalyst grown on the substrate is obtained by solving the solution in the structure. The middle and right nanospheres are organic polymer polymer spheres, and the structure is sent to a high temperature furnace or a ventilated oxidation furnace for heating, and the heating temperature is less than 500 amps; if the nanosphere is an inorganic compound The ball is added with a hydrogen (tetra) aqueous solution and heated, and the heating temperature is less than 100 degrees Celsius, and the nanosphere can be decomposed by the above method. In the above steps, a nano-network-like platinum catalyst developed on the substrate can be obtained. The nano-network-like platinum-based catalyst can be applied to direct methanol fuel, and proton-exchanged fuel cells. In general, the transfer method of the nano-network-like platinum-based catalyst of the present invention can effectively improve various disadvantages of the conventional use, and the nano-network-like platinum-based catalyst transfer which grows on the substrate can be realized by a simple process. To the proton exchange membrane carrier', the production of the invention can be made more progressive, more practical, and more in line with the requirements of the user, and indeed meets the requirements of the invention patent application, and the patent application is filed according to law. The above is only the preferred embodiment of the present invention, and the scope of the present invention is not limited thereto; & the simple equivalent of the invention and the scope of the invention 1320978 and modifications should still fall within the scope of the invention patent. 1320978 [Simplified description of the drawings] Fig. 1 is a schematic flow chart of the present invention. Figure 1A is a schematic view of step a of the present invention. Figure 1B is a schematic view of step b of the present invention. Figure 1C is a schematic view of step c of the present invention. Figure 1D is a schematic diagram of step d of the present invention. Fig. 2 is a flow chart showing the process of growing a nano-networked platinum-based catalyst of the present invention. [Description of main component symbols] Steps: a~d Substrate 1 Polymer material film 2 Nano-networked platinum-based catalyst 3 Heat treatment 4 Carrier 5 Next agent 6 Hot-pressing treatment 7 Step: bl~b3