TWI313690B - Conductive starburst polymer, conductive starburst block copolymer, and method for forming the same - Google Patents

Description

1313690 IX. Description of the invention: [Technical field of the invention] The present invention relates to a conductive particle and a method for forming two kinds of conductive star-shaped polymer and a conductive block type star-shaped polymer and a method [Prior Art] Polymers, also known as traditional organic recording polymers, have a variety of properties and a wide range of _ potentials, causing high levels of material I and academia, and the opportunity for the production of molecules to replace - part of the metal material Hi dipole _, _ And materials, dissident enl) electrochromic devices, anti-magnetic waves, membranes, aerospace, etc., so will play a very important role in the untransferred polymer. The f is mostly a heterocyclic or aromatic heterocyclic compound, such as polybenz??1_phene), p〇lyacetylene, pdyanmne, etc., and there are single and double chains. Special electrons, after oxidation or _, electrons can move along molecular bonds or across molecular chains, and have electrical conductivity, and the structure will have different degrees of conductivity. However, in general, the conductive polymer has a light-weight structure, so that it dissolves in the solvent, and the crunch is not easy to be chopped, which seriously degrades its processing and application. The general improvement method is that the polymer and the good polymer are blended to increase the mechanical strength, but the two components are separated to produce phase separation. Therefore, in the manner of copolymerization, the combination of the polymer with a covalent bond can improve the phase separation and improve the solubility. In addition, the improvement can also be achieved through the modification of the side chain or the principle of the impurity and the concept of the filament 1313690. SUMMARY OF THE INVENTION In the above invention, a new conductive star-shaped formation method is used for the polymer and the conductive enthalpy activity is determined by the star-shaped starting nucleus center, and the arm chain partial chain eight-star structure is utilized. Then the star-shaped structure is a quality structure. Then, using the oxidative polymerization method in the t-late, another purpose of the polymer is to provide a conductive particle having good properties. The conductive star shape provided by the visible light is provided by the present invention. The polymer and the guide i receive the 状 状 在 在 在 在 m m Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ Ϊ The segment type star-shaped polymer has high conductivity 'molecular weight shape; the invention can meet the economic benefit and the industrial applicability. According to the above purpose, the present invention discloses a conductive device comprising a - recording system Mineralized rain molecules. Secondly, the above-mentioned conductive structure is lacking in a star-shaped structure, and the sulfonic acid group on the chain is attracted to facilitate the winding of the conductive structure on the arm chain. Further, the invention discloses a conductive block type star-shaped polymer. The utility model comprises a star-shaped structure and a conductive structure having at least three arm chains. The arm chain system is a group of 1313690 tsun, and the Yi-type copolymer comprises a --segment and a second bond. Segment, second upper two segment On the outer side of the arm chain. Secondly, the second bond segment on the f-key of the i-star structure is attracted to facilitate the electrical star.

In the direction of the series, the conductive in-situ polymer and conductive = star-shaped sputum molecules and their formation methods are discussed. In order to thoroughly understand the present invention, the column-description towel presents a detailed process walk-through composition. In the face, the ff* line of the company is not limited to the Ming and Tian, which are familiar to the skilled person in the field of conductive composite particles. The other aspects of the well-known composition or process steps are not described in detail to avoid unnecessarily limiting the invention. The preferred embodiments of the present invention will be described below, and in addition to these detailed descriptions, the present invention can be broadly applied to other solid side towels and the patent scope of the present invention is based on the scope of the patent. % The first embodiment discloses a conductive star-shaped polymer comprising a star-shaped structure having at least two arm chains and a conductive structure. The above arm chain is a sulfonated polymer. Secondly, the conductive structure is attracted by a sulfonic acid group on the arm chain of the star-shaped structure, so that the conductive structure is wound on the arm chain, wherein the conductive structure is formed by polymerizing a plurality of conductive monomers or oligomers. . The above conductive monomer or oligomer. further comprises one of the following groups, derivatives thereof or any combination thereof: aniline, pyrrole, thi〇phene, bite (such as), acetylene, phenyiene suifide, σ 〇 朵 (incj〇le), phenyl vinylene (PV), phenyl ethylene (PE), phenyl, ethylenedioxythiophene (EDOT). In a preferred embodiment of the present embodiment, the conductive structure is a template (temp ate) of a star-shaped structure, and a plurality of conductive monomers or oligomers are polymerized in-situ. The material is formed to form a conductive structure 1313690 and the conductive structure is wound around the arm chain. In the present embodiment, the method for forming the above-mentioned star-shaped structure comprises: providing a star-shaped initiator; and polymerizing a plurality of monomers by a living polymerization reaction starting from a star-shaped initiator; A chiral chain precursor is formed; a sulfonation treatment is performed on the arm chain precursor to form the above-described arm chain. The above star-shaped starter structure comprises at least three terminal positions each having a terminal halide to facilitate formation of at least three arm chains. In another preferred embodiment of the present embodiment, the star-shaped initiator is replaced by 2-bromo-2-methyl propionyl bromide (2Br) with a base alcohol of a different arm bond (4, 6, 12). The reaction yielded three different arm chains (4, 6, 13⁄4 star-shaped initiators (4, Br, 6_Br, 12-Br), the structures of which are as follows:

Br 1313690 is a star-shaped starter (4-Br, 6-Br, as an example, by living polymerization polymerization), the Sternene monomer (4-PSS_Br, 6-PSS-Br) , 12-PSS-Br, VIII and arm bond precursor structure PRi show-arm bond precursor), 丨, m, only known in the structural formula

Ri〇,

RiO ο

R3q r30 \

Br

〇< ?0~〇 o r3〇 R30

p

Or3 R30

〇 r3〇 〇

When Rs is formed, the pre-heterogeneous (ie, styrene segment) is subjected to 1 treatment (the structure of the towel is recorded, and the conversion (4) is as follows

So3h so3h 1313690

In the present embodiment, referring to the first figure, when the star-shaped initiator (4-Βγ, 6-Br, 12-Br) and the styrene monomer are taken as an example, after living polymerization and sulfonation treatment In-situ polymerization of a conductive monomer (eg, aniline or EDOT) by a catalyst [eg, ammonium persulfate (APS)] to form the above-described conductive structure (the spiral segment in the first figure) And the conductive structure is wound around the arm keys. * In the present embodiment, the above monomers comprise the following two types: (1) one end of the monomer has a vinyl group or an allyl gr〇up, and the other end of the monomer has a fragrance. a group-based or aromatic heterocyclic ring or a melting ring or a molten heterocyclic ring; (2) one end of the monomer has a vinyl group or an allyl gr〇up, and the other end of the monomer has i or nitrate' base. The above two different types of monomer designs are combined with subsequent different (four) treatments such as: direct ship and indirect. The above-mentioned continuation = treatment used in the treatment agent includes one of the following groups: concentrated sulfuric acid, sulphur sulphur dioxide, sulfuric acid, UCetyl SUlfate, sulphuric acid, sultane sultone, sulphuric acid and sulphur dioxide oxygen. In addition, the above-mentioned active poly-portion reaction is a living anionic polymerization reaction ammoc P〇yme_lon in the lower group, active cationic polymerization _ po ym_ _ disk ring-opening polymerization P〇ymenZtn radical polymerization The reaction P〇lymerizatu ♦ has a molecular weight distribution (PDI) of less than 2.0 by using the above-mentioned living polymerization 1313690 conductive star polymer. A further preferred embodiment of this embodiment employs atom transfer radical polymerization (ATRP) because of its simple synthesis conditions and wide range of monomers. The principle of ATRP is to use two molecules with halogen groups as the initiators, and to select suitable transition metals and ligands as catalysts, and to achieve the activation and deactivation efficiency of transition metals. The purpose of the polymerization. A second embodiment of the present invention discloses a conductive block type star-shaped polymer comprising a star-like structure having at least two arm chains and a conductive structure. The arm chain is a block copolymer, wherein the block copolymer comprises a first segment and a second segment, the second segment is a sulfonated polymer, and the second chain The segment is located on the outside of the arm chain. Secondly, the conductive structure is attracted by the second segment on the arm chain of the star-shaped structure, so that the conductive structure is wound on the second segment, wherein the conductive structure is composed of a plurality of conductive monomers or merging elements. Aggregated. In one embodiment of the present invention, the conductive structure is characterized by a second segment of the arm chain of the star-shaped structure as a template "template" by in-situ polymerization of a plurality of electrical conductivity The monomer or the merging polymer is in a conductive structure, and the conductive structure is wound on the second key segment. The selection of the above conductive monomer or oligomer is the same as in the first embodiment. In the present embodiment, the method for forming the above-mentioned star-shaped structure comprises: providing a star-shaped initiator; starting from a star-shaped initiator, and forming a-intermediate heteropoly PLP2 by a living polymerization reaction Wherein, pi is the first bond segment, and p2# is the precursor of the second segment; and the intermediate copolymer ρι_ρ2 is subjected to a monosulfonation treatment to form a block copolymer P1?3, wherein P2 is produced. After the treatment, a sulfonated polymer p3 is formed. The above-mentioned star-shaped initiator, sulfonating agent and living polymerization reaction are selected in the same manner as in the first embodiment. Further, the first segment of the above-mentioned first segment is polymerized by a plurality of first mono-body, and one end of the first monomer has a vinyl group (vinylgr〇up) or an acryl-based group (postal group), and The other end of a monomer contains a burn group so that the core of the block type star-shaped conductive polymer has viscoelastic properties. Taking the star-shaped initiator (4_Br, 6_Br, 12 Br) and n-Butyl acrylate (BA) monomer as an example, the starting center and the first segment structure after polymerization by 'activity-combination reaction (4_ρβα·Βγ, 6_pBA_Br, 1313690 12: PBA Ο, for example, n is an integer greater than or equal to jin (only one first key segment is shown in the structural formula) ' 1, m, , ; i.

The first segment (i.e., the poly(n-butyl acrylate) segment is subjected to living polymerization reaction by a styrene monomer to form an intermediate copolymer, and the structure K is as follows (structural formula t only Show a t-copolymer): , "° eight knife

13 1313690

The styrene segment is further subjected to a monosulfonation treatment to form a star structure of three different arm chains (4, 6, 12), and the structural formulas are as follows (only one arm chain is shown in the structural formula):

1313690

12, acrylic acid T material and benzene (10) single material, after: polymerization and enhanced treatment, by the catalyst [such as ',, in this implementation, refer to the second ride, record rr electrical properties Single in situ poly to form the above-mentioned conductive structure (second segment)' and the conductive structure is wound on the second key segment of the arm chain. ",, ' 里 艚 ί ί ΓΓ ΓΓ ' i , , , The precursor of the two-strand segment is formed by a plurality of second precursors, and the n-body comprises the following two types: (1) the first end has a vinyl group or a propyl group (aUyl gr〇up), And the end of a Γ Γ 或 或 ( ( ( 芳香 芳香 芳香 芳香 芳香 芳香 芳香 ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( ( The other end of the body has a halogen or a nitro group. The monomers of the above two types are not combined with subsequent different sulfonation treatments, such as direct magnetic coupling. In addition, the conductive embedded layer provided by the present invention A segmented star ^ ^ quantity distribution (PDI) is less than 2. G. The third embodiment of the present invention discloses a conductive star-shaped high-scoring method, first providing a star The initiator, the structure comprising at least three terminal positions having a terminal hal. Then, the star-shaped initiator is used as a terminal position, and the complex is transferred by - atom radical transfer polymerization. 1313690 The second precursor. Secondly, the arm chain precursor is subjected to a characterization process to form a star-like structure with at least three arm chains. Then, by star-shaped conductivity, the in-situ polymerization (in_situ) is used to aggregate the complex number. On the arm chain, the object is formed to: a conductive structure, and the conductive structure is wound around the agent of the medicinal system, and the number of the arm chain is HI or the number of the other monomer is 2 It is greater than or equal to the star sulphate (a beer 1 suifate), because the above-mentioned preferred sulfonating agent is a sulphur egg, which has a lower strength, and is preferably formed in one of the embodiments. . Ethylene burning dlChl〇n>ethane), _ anhydride and sulfuric acid are required to react, and evenly mixed with acetic acid field, then slowly sulphuric acid ^ τ .... non-unstable, so it must be in the ice bath before use Prepared under. The degree of chemistry can rise above 90%, so the ratio of the sulphuric acid/acetic acid needle is greater than 1 ′, and the preferred value is about 1.18. The method of forming a conductive star-shaped polymer is an ancient-type contact agent whose structure contains at least three end positions each having ί i it ΐ t rinai haiide). Return, starting with Di _ starting center, you end ΐ ΐ — — - atomic radical transfer polymerization to form - arm bond precursor, the arm chain precursor system is - intermediate copolymer ρ1 · ρ2, where ρ1 = ^ one 5 The terminal ί is connected and the P2 is located outside the arm chain precursor. The ς-human, chain-driven material undergoes a sulfonation treatment to form a chain of arms, and has a star-shaped structure of '1 chain'. The arm chain system is a segmental filament ρ1_ρ3, which is formed by A = key segment, the second segment is sulfonated with a knife. Then, by using a second segment of the arm chain of the star-shaped structure, a plurality of conductive monomers or oligomers are polymerized in situ to form a conductive structure, and the conductive structure is wound around On the second segment, a conductive recording polymer is formed. The selection of the above-mentioned treatment agent or oligomer is the same as that of the first embodiment.

16 1313690 In the embodiment, the first segment is formed by a plurality of first monomers, and the selection of the first monomer is the same as that of the second embodiment. When the number of the above arm chains is η (η is an integer greater than or equal to 3), the first monomer mole number is greater than 5511 times the molar number of the starting agent, <) Polymerized by a plurality of first bodies, and the second monomer is selected in the same manner as the second embodiment, and the second monomer molar number is greater than or equal to 1星11 of the star-shaped initiator molar number. Times. On the other hand, the above preferred extender is acetyl sulfate because of its strength and in a preferred embodiment of the present embodiment by dichloro-ethane, acetic anhydride and Sulfuric acid is formed by reaction. First, the mixture of dichloroethane and anhydride is uniformly mixed, and then the sulfuric acid is slowly dropped. This extender is very non-determined, so it must be formulated on ice before use. The degree of acidification can be increased to more than 90%, so the molar ratio of sulfuric acid/acetic anhydride is controlled to be greater than 丨, and the preferred value is about 1.18. In the above embodiments, the present invention forms a single star structure or a block star structure by a living polymerization method by using a star-shaped initiator as a starting center, and then an arm chain portion or an arm of the star structure. The outer side of the chain portion is modified to a sulfonic acid structure. Then, using the sulfonic acid structure as a template, a conductive polymer is formed in situ by oxidative polymerization (丨(10) addition), and is entangled on the sulfonic acid structure to form a conductive star-shaped polymer or a conductive block star shape. Polymer. In another aspect, the present invention provides conductive particles of good nature. It is found from the visible light spectrum (UV-vis) that the conductive star-shaped polymer and the conductive block type star-shaped polymer provided by the present invention have a strong absorption peak between 8 〇〇 and 1 〇〇〇 nm. , showing excellent electronic jumping ability. Further, the present invention provides a conductive star-shaped polymer and a conductive block type star-shaped polymer which are electrically conductive and have a narrow molecular weight distribution. Accordingly, the present invention is compatible with economic benefits and industrial utility. In summary, the present invention discloses a conductive star-shaped polymer comprising a star-like structure having a three-arm chain and a conductive structure. The above arms & is a monosulfonated polymer. Second, the conductive structure described above is attracted by the acid-base group on the arm chain of the star-shaped structure so that the conductive structure is wound around the arm chain. In addition, the invention discloses 17

Claims (1)

131369 Patent Application Area 1. A conductive star-shaped polymer comprising: a star-shaped structure having at least three arm chains of a molecule, wherein the arm chain is a continuous high-conductivity structure The conductive structure is attracted to the arm chain of the star structure so that the conductive structure is wound on the arm chain, wherein ς is mechanically supported by a plurality of conductive cells or wires (4). + electricity ',,. Structure 2. The conductive star polymer as described in claim 1 of the patent application, wherein the polymer comprises polystyrene. 3 3. The conductive star polymer described in claim 1 of the patent application, the method for forming the above structure comprises: providing a star-shaped initiator; single Zhao: star into _ arm: for the second middle A plurality of the arm chain precursors are subjected to a monosulfonation treatment by a living-polymerization reaction to form the arm chain. 4. The conductive star-shaped polymer according to claim 3, wherein the above-mentioned structure of the towel comprises at least three terminal positions each having an end-half) ° 5. As described in the third item of the patent Conductive star-shaped polymer, the above-mentioned monomer at the two ends has a vinyl group or a propylene group, and the monomer has a vinyl group or an aromatic ring at the other end. Secret ring or dissolved heterocyclic ring. 6. The conductive star-shaped polymer according to item 3 of the patent application scope of Shenyi, wherein the above-mentioned monomer ends have a county (postal P) or an allyl group, and the monomer is another One end has its own or stone base. 7. The conductive star-shaped polymer according to item 3 of the patent application (4), wherein the above activity is * * - Lu: active aion polymerization (living a^onie polymerization), living cationic polymerization (living cati 〇nic P〇lymerizati〇n), living ring-opening 19 1313690 polymerization and living radical polymerization (ΐίν_ γ& (Μ) ° 8. Conductive star-shaped polymer, wherein the above is confirmed. = The mineralizer used contains the following groups: concentrated sulfuric acid, fuming sulfuric acid, sulfur dioxide, acetyi sulfate, chloride acid, qingjiajia The sulphuric acid, the sulphur dioxide, the sulphur dioxide and the sulphur dioxide are added to the oxidized sulfuric acid. The conductive star polymer as described in claim 1, wherein the above conductive, singular monomer or oligomer further comprises the following groups One, its derivatives or a combination of Α: aniline (sister mne), η pyro (pyrrole), porphin (thi_ene疋 /,, = (fine 311), ace (ylene), stupid Sulfur Nylene sulfide), Indole > phenyl vinylene (PV) > phenyl ethylene (PE ) > phenyl ^ ethylenedioxythiophene (EDOT) 〇 10. The conductive star shape as described in claim 1 a polymer, wherein the conductive, 纟β-structure is templated by the arm chain of the star-shaped structure, and a plurality of the conductive monomers or oligomers are formed by in-situ polymerization to form The conductive structure, " and the conductive structure is wound around the arm chain. 11. t The conductive star-shaped polymer described in claim 1 of the patent scope, the molecular weight distribution (PDI) of the conductive star-shaped polymer Less than 2.0 12. A conductive block type star-shaped polymer, the conductive sinusoidal star polymer comprises: • a star-shaped structure having at least three arm chains, the arm chain is a block copolymer Wherein, the block copolymer comprises a first segment and a second segment, the second segment is a sulfonated polymer, and the second segment is located on the outer side of the arm chain; a conductive structure, the conductive structure being subjected to the star structure The second segment on the chain suction arm so wound around the electrically conductive structure on the second segment, wherein the electrically conductive structure by a plurality of conductive lines monomer or oligomer polymerized. The conductive block type star-shaped polymer according to claim 12, wherein the sulfonated polymer comprises polystyrenesulfonic acid. 14. The conductive block type star-shaped polymer according to claim 12, wherein the method for forming the star-shaped structure described in the above 20 1313690 comprises: providing a star-shaped starter; The starting center is formed by an active polymerization reaction to form an intermediate copolymer pLp2, wherein P1 is the first segment and P2 is the precursor of the second segment; ]_P2 riding - the ship's axis is the neon copolymer 'p ^, wherein P2 is sulfonated to form a sulfonated polymer P3. 15. The conductive block type star polymer according to claim 14, wherein the star-shaped initiator structure comprises at least three terminal positions each having a terminal halide. The conductive neon star-shaped polymer according to claim 14, wherein the first segment is polymerized by a plurality of first monomers, and one end of the first monomer has a vinyl group ( Vinyl group) or allylgr〇up, and the other end of the monomer contains an alkyl group. 17. The conductive block type star polymer according to claim 1, wherein the precursor of the two-stage segment is polymerized by a plurality of second monomers, and the second monomer is One end has a vinyl group or an allylgrup, and the other end of the first monomer has an aromatic group or an aromatic heterocyclic ring or a melting ring or a molten heterocyclic ring. 18. The conductive block type star-shaped polymer according to claim 14, wherein the precursor of the two-stage segment is polymerized by a plurality of second monomers, and the second single One end of the body has a vinyl group or a propylene group, and the other end of the first monomer has a _ or a nitro group. 19. The conductive block type star polymer according to claim 14, wherein the living polymerization reaction is one of the following groups: living anionic polymerization, living cationic polymerization ( Addition _ eati〇nic polymerization), living ring-opening polymerization and living radical polymerization ° 1313690 20. The conductive block type star polymer as described in claim 14 of the patent application, The sulfonating agent used in the above sulfonation treatment comprises one of the following groups: concentrated sulfuric acid, fuming sulfuric acid, sulfur trioxide, acetyl sulfate, chloric acid, propane sultone, sodium sulfite, sulfur dioxide. Add chlorine and sulfur dioxide to add oxygen. 21. The conductive block type star-shaped polymer according to claim 12, wherein the conductive monomer or oligomer further comprises one of the following groups, a derivative thereof or any combination thereof: aniline (aniline), π pyrrole, thiophene, fbran, acetylene, phenylene sulfide, indole, phenyl vinylene (PV), phenyl ethylene (PE), pheny 丨ethylenedioxythiophene (EDOT) 〇 22. The conductive block type star polymer according to claim 12, wherein the conductive structure is the same as the arm chain of the star structure The two-segment is a template' by in-situ polymerization of a plurality of the conductive monomers or oligomers to form the conductive structure' and the conductive structure is wound on the second segment. 23. The conductive block type star-shaped polymer according to claim 12, wherein the conductive star-shaped polymer has a molecular weight distribution (pDI) of less than 2. 24. A method for forming a conductive star-shaped polymer, the method for forming the conductive star polymer comprising: providing a star-shaped initiator, wherein the star-shaped initiator structure comprises at least three Having a terminal halide; starting from the star-shaped initiator, at the terminal position, polymerizing a plurality of monomers by one atom radical transfer polymerization to form a one-arm chain precursor; The arm chain drive is subjected to a process to form an arm chain and form a star-like structure having at least three arm chains; and the arm chain of the star structure is used as a template A plurality of conductive monomers or merging polymers are polymerized in-situ to form a conductive structure, and the conductive structure is wound around the arm chain, thereby forming the conductive star-shaped polymer. 5. The method for forming a conductive star-shaped polymer according to claim 24, wherein one end of the above monomer has a vinyl group or a propylene group (aUyl 22 1313690 group), and the An additional ring or a molten heterocycle of the first monomer. The method for forming a conductive star-shaped polymer according to claim 24, wherein the sulfonating agent used in the sulfonation treatment comprises one of the following groups: concentrated sulfuric acid, fuming sulfuric acid, sulfur dioxide, sulfuric acid Acetyl sulfate, chloride acid, sultone, sodium sulfite, sulfur dioxide plus gas and sulfur dioxide plus oxygen. 29. The method for forming a conductive star-shaped polymer according to claim 28, wherein the above-mentioned agent is acetyl sulfate, and acesulfate is made of dichloro-ethane or acetic acid. The anhydride and sulfuric acid react to form. a method for forming a conductive star-shaped polymer having an aromatic group or an aromatic heterocyclic ring or a melting term at one end, which has a vinyl group (vinyl group) or an acryl group i group ) 'and the first-single_other end has a dentate or a determinant. The method for forming a conductive star-shaped polymer according to the item 24, wherein the number of the above # chain is η ' η is an integer greater than or equal to 3, and the number of monomer moles is greater than or equal to The method for forming a conductive star-shaped polymer according to claim 29, wherein the above-mentioned sulfuric acid/acetic acid needle has a molar ratio of more than 1 The method for forming a conductive star polymer according to claim 24, wherein the conductive monomer or oligomer further comprises one of the following groups, a derivative thereof, or any of the following Combination: aniline, pyrr〇le, thiophene, fUran, acetylene, phenylene sulfide, indole, phenyl vinylene (PV) , phenyl ethylene (PE) ' phenyl > ethylenedioxythiophene (EDOT) 〇 32. A method for forming a conductive block type star-shaped polymer, the method for forming the conductive star-shaped polymer comprises: providing a star-shaped initiator , wherein the star-shaped starter structure comprises Each of the three terminal positions has a terminal halide; the star-shaped initiator is used as a starting center, and at the end position, an arm-chain radical precursor is formed by one atom radical transfer polymerization, which The arm chain precursor system is a medium 23 1313690 copolymer P>P2 'where 'P1 is a first segment, and the pi system is connected to the end position, and the P system is located outside the arm chain precursor; The arm chain is subjected to a 4-arming treatment to form an -arm chain, and a member having at least an arm bond, and the star-shaped structure is a -I-stage copolymer pl_p3 ' wherein P is P through the sulfonate Forming a second segment formed by the treatment, the second segment is a continuous polymer; and the second segment of the arm chain having the star structure is used as a template The m-situ polymerizes a plurality of conductive monomers or merging polymers to form a conductive structure 'and the conductive structure is wound around the second segment, thereby forming the conductive star-shaped polymer. The formation of the conductive block type star polymer as described in claim 32 The first-bond segment is formed by polymerizing a plurality of first monomers, and the terminal end of the first monomer has a vinyl group (vinyl or acryl group), and the first single The other end of the body comprises an alkyl group. The number of the above-mentioned arm chain is η, and η is an integer greater than or equal to 3 in the formation of the conductive * segmental star-shaped polymer described in Item 33 of the claim. The number of monomer moles is greater than or equal to the number of moles of the star-shaped initiator. The formation of the conductivity-type star-shaped polymer described in Item 232 of the Hi-Li range is the result of the above-mentioned p-storage being polymerized by a plurality of second monomers, and the second end of the second ^ has a B A thin group (vinyl_P) or a propylene group (Ullylgroup), and = the other end of the monomer has an aromatic group or an aromatic heterocyclic ring or a condensed ring or a dissolved heterocyclic ring. The formation of the conductive block type star-shaped polymer described in Item 35 of the scope is η, the η is an integer greater than or equal to 3, and the second gas is equal to or equal to the star shape. 1000 n times the molar number of the agent. The formation of the conductive money type star-shaped polymer described in Item 32 of the claim 32 is that the p is polymerized by a plurality of second monomers, and the second flute, ^ has a vinylgrouP or allylgrcmp' and the other end of the first precursor has a halogen or a nitro group. 24 1313690 38. The method of claim 3, wherein the number of the above-mentioned arm chains is n, and the formation of n-type two=two molecules is equal to the number of the star-shaped initiator Mo's The continuating agent used in the above-mentioned continuation zone S includes one of the following groups: concentrated sulfuric acid, fuming sulfuric acid, three Sulfur oxide, acesulfate (1 acetal), chloric acid, propane sultone, sodium sulfite, sulfur dioxide plus chlorine and sulfur dioxide. 40. The method for forming a conductive block type star-shaped polymer according to claim 32, wherein the above-mentioned extender is acetyl sulfate, and acesulfate is made of dichloro-ethane or acetic acid. The anhydride and sulfuric acid react to form. The method of forming a conductive block type star-shaped polymer according to the fourth aspect of the invention, wherein the sulfuric acid/acetic anhydride has a molar ratio of more than 1. 25