TWI312016B - - Google Patents
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- Publication number
- TWI312016B TWI312016B TW094102516A TW94102516A TWI312016B TW I312016 B TWI312016 B TW I312016B TW 094102516 A TW094102516 A TW 094102516A TW 94102516 A TW94102516 A TW 94102516A TW I312016 B TWI312016 B TW I312016B
- Authority
- TW
- Taiwan
- Prior art keywords
- powder
- treatment
- coating
- cleaning
- treated
- Prior art date
Links
- 238000000034 method Methods 0.000 claims description 28
- 239000000843 powder Substances 0.000 claims description 21
- 230000008569 process Effects 0.000 claims description 19
- 239000000758 substrate Substances 0.000 claims description 12
- 239000011248 coating agent Substances 0.000 claims description 9
- 238000000576 coating method Methods 0.000 claims description 9
- 230000033001 locomotion Effects 0.000 claims description 9
- 239000002245 particle Substances 0.000 claims description 9
- 238000005245 sintering Methods 0.000 claims description 9
- 238000004519 manufacturing process Methods 0.000 claims description 8
- 238000004140 cleaning Methods 0.000 claims description 7
- 230000004048 modification Effects 0.000 claims description 7
- 238000012986 modification Methods 0.000 claims description 7
- 238000005238 degreasing Methods 0.000 claims description 5
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 claims description 5
- 239000010931 gold Substances 0.000 claims description 5
- 229910052737 gold Inorganic materials 0.000 claims description 5
- 239000000314 lubricant Substances 0.000 claims description 5
- 238000002156 mixing Methods 0.000 claims description 5
- 239000000126 substance Substances 0.000 claims description 5
- 230000004913 activation Effects 0.000 claims description 4
- 239000000463 material Substances 0.000 claims description 4
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 4
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 4
- 238000012360 testing method Methods 0.000 claims description 4
- 239000010419 fine particle Substances 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- 210000001161 mammalian embryo Anatomy 0.000 claims description 3
- 239000011882 ultra-fine particle Substances 0.000 claims description 3
- 239000002131 composite material Substances 0.000 claims description 2
- 238000009826 distribution Methods 0.000 claims description 2
- 238000011049 filling Methods 0.000 claims description 2
- 238000010438 heat treatment Methods 0.000 claims description 2
- -1 polytetrafluoroethylene Polymers 0.000 claims description 2
- 238000007747 plating Methods 0.000 claims 3
- 238000003487 electrochemical reaction Methods 0.000 claims 2
- 239000012530 fluid Substances 0.000 claims 2
- 238000005406 washing Methods 0.000 claims 2
- ATJFFYVFTNAWJD-UHFFFAOYSA-N Tin Chemical compound [Sn] ATJFFYVFTNAWJD-UHFFFAOYSA-N 0.000 claims 1
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 238000001125 extrusion Methods 0.000 claims 1
- 238000001914 filtration Methods 0.000 claims 1
- XUCNUKMRBVNAPB-UHFFFAOYSA-N fluoroethene Chemical group FC=C XUCNUKMRBVNAPB-UHFFFAOYSA-N 0.000 claims 1
- 239000007769 metal material Substances 0.000 claims 1
- 239000011859 microparticle Substances 0.000 claims 1
- 230000000704 physical effect Effects 0.000 claims 1
- 239000002904 solvent Substances 0.000 claims 1
- 229910052725 zinc Inorganic materials 0.000 claims 1
- 239000011701 zinc Substances 0.000 claims 1
- 238000005516 engineering process Methods 0.000 description 9
- 239000010687 lubricating oil Substances 0.000 description 8
- 229910052751 metal Inorganic materials 0.000 description 7
- 239000000047 product Substances 0.000 description 7
- 239000002184 metal Substances 0.000 description 6
- 229910000906 Bronze Inorganic materials 0.000 description 5
- 239000010974 bronze Substances 0.000 description 5
- KUNSUQLRTQLHQQ-UHFFFAOYSA-N copper tin Chemical compound [Cu].[Sn] KUNSUQLRTQLHQQ-UHFFFAOYSA-N 0.000 description 5
- 238000013461 design Methods 0.000 description 5
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 4
- 229910000831 Steel Inorganic materials 0.000 description 4
- 238000001816 cooling Methods 0.000 description 4
- 238000010586 diagram Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000007788 liquid Substances 0.000 description 4
- 238000005461 lubrication Methods 0.000 description 4
- 229910021645 metal ion Inorganic materials 0.000 description 4
- 239000003921 oil Substances 0.000 description 4
- 238000005096 rolling process Methods 0.000 description 4
- 239000007787 solid Substances 0.000 description 4
- 239000010959 steel Substances 0.000 description 4
- 239000012298 atmosphere Substances 0.000 description 3
- 230000008859 change Effects 0.000 description 3
- 238000006243 chemical reaction Methods 0.000 description 3
- 230000007246 mechanism Effects 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 230000002829 reductive effect Effects 0.000 description 3
- 230000007704 transition Effects 0.000 description 3
- RYGMFSIKBFXOCR-UHFFFAOYSA-N Copper Chemical compound [Cu] RYGMFSIKBFXOCR-UHFFFAOYSA-N 0.000 description 2
- VGGSQFUCUMXWEO-UHFFFAOYSA-N Ethene Chemical compound C=C VGGSQFUCUMXWEO-UHFFFAOYSA-N 0.000 description 2
- 239000005977 Ethylene Substances 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 239000008139 complexing agent Substances 0.000 description 2
- 238000009792 diffusion process Methods 0.000 description 2
- 229910052500 inorganic mineral Inorganic materials 0.000 description 2
- 239000011707 mineral Substances 0.000 description 2
- 229910052759 nickel Inorganic materials 0.000 description 2
- 239000003381 stabilizer Substances 0.000 description 2
- 241000283690 Bos taurus Species 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 241000270722 Crocodylidae Species 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- 241001417534 Lutjanidae Species 0.000 description 1
- 241000282320 Panthera leo Species 0.000 description 1
- 239000004990 Smectic liquid crystal Substances 0.000 description 1
- 235000021355 Stearic acid Nutrition 0.000 description 1
- 239000000956 alloy Substances 0.000 description 1
- 229910045601 alloy Inorganic materials 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 230000000712 assembly Effects 0.000 description 1
- 238000000429 assembly Methods 0.000 description 1
- 239000003638 chemical reducing agent Substances 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 239000010949 copper Substances 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- LNNWVNGFPYWNQE-GMIGKAJZSA-N desomorphine Chemical compound C1C2=CC=C(O)C3=C2[C@]24CCN(C)[C@H]1[C@@H]2CCC[C@@H]4O3 LNNWVNGFPYWNQE-GMIGKAJZSA-N 0.000 description 1
- 230000002542 deteriorative effect Effects 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 210000002257 embryonic structure Anatomy 0.000 description 1
- 238000005429 filling process Methods 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007730 finishing process Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
- 229910002804 graphite Inorganic materials 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 1
- 238000005470 impregnation Methods 0.000 description 1
- 239000012535 impurity Substances 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- SHXXPRJOPFJRHA-UHFFFAOYSA-K iron(iii) fluoride Chemical compound F[Fe](F)F SHXXPRJOPFJRHA-UHFFFAOYSA-K 0.000 description 1
- 238000012423 maintenance Methods 0.000 description 1
- 238000010310 metallurgical process Methods 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 229910000480 nickel oxide Inorganic materials 0.000 description 1
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 1
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- GNRSAWUEBMWBQH-UHFFFAOYSA-N oxonickel Chemical compound [Ni]=O GNRSAWUEBMWBQH-UHFFFAOYSA-N 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000027756 respiratory electron transport chain Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 229910052708 sodium Inorganic materials 0.000 description 1
- 239000011734 sodium Substances 0.000 description 1
- 239000007779 soft material Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000008117 stearic acid Substances 0.000 description 1
- 239000004575 stone Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 238000012546 transfer Methods 0.000 description 1
- 239000000080 wetting agent Substances 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
- B22F3/02—Compacting only
- B22F3/03—Press-moulding apparatus therefor
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B22—CASTING; POWDER METALLURGY
- B22F—WORKING METALLIC POWDER; MANUFACTURE OF ARTICLES FROM METALLIC POWDER; MAKING METALLIC POWDER; APPARATUS OR DEVICES SPECIALLY ADAPTED FOR METALLIC POWDER
- B22F3/00—Manufacture of workpieces or articles from metallic powder characterised by the manner of compacting or sintering; Apparatus specially adapted therefor ; Presses and furnaces
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C26/00—Coating not provided for in groups C23C2/00 - C23C24/00
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/1601—Process or apparatus
- C23C18/1633—Process of electroless plating
- C23C18/1655—Process features
- C23C18/1662—Use of incorporated material in the solution or dispersion, e.g. particles, whiskers, wires
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
- C23C18/00—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating
- C23C18/16—Chemical coating by decomposition of either liquid compounds or solutions of the coating forming compounds, without leaving reaction products of surface material in the coating; Contact plating by reduction or substitution, e.g. electroless plating
- C23C18/31—Coating with metals
- C23C18/32—Coating with nickel, cobalt or mixtures thereof with phosphorus or boron
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C33/00—Parts of bearings; Special methods for making bearings or parts thereof
- F16C33/02—Parts of sliding-contact bearings
- F16C33/04—Brasses; Bushes; Linings
- F16C33/06—Sliding surface mainly made of metal
- F16C33/14—Special methods of manufacture; Running-in
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/067—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components
- G06K19/07—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components with integrated circuit chips
- G06K19/0701—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components with integrated circuit chips at least one of the integrated circuit chips comprising an arrangement for power management
- G06K19/0702—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components with integrated circuit chips at least one of the integrated circuit chips comprising an arrangement for power management the arrangement including a battery
-
- G—PHYSICS
- G06—COMPUTING; CALCULATING OR COUNTING
- G06K—GRAPHICAL DATA READING; PRESENTATION OF DATA; RECORD CARRIERS; HANDLING RECORD CARRIERS
- G06K19/00—Record carriers for use with machines and with at least a part designed to carry digital markings
- G06K19/06—Record carriers for use with machines and with at least a part designed to carry digital markings characterised by the kind of the digital marking, e.g. shape, nature, code
- G06K19/067—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components
- G06K19/07—Record carriers with conductive marks, printed circuits or semiconductor circuit elements, e.g. credit or identity cards also with resonating or responding marks without active components with integrated circuit chips
- G06K19/077—Constructional details, e.g. mounting of circuits in the carrier
- G06K19/07749—Constructional details, e.g. mounting of circuits in the carrier the record carrier being capable of non-contact communication, e.g. constructional details of the antenna of a non-contact smart card
- G06K19/07773—Antenna details
- G06K19/0779—Antenna details the antenna being foldable or folded
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F16—ENGINEERING ELEMENTS AND UNITS; GENERAL MEASURES FOR PRODUCING AND MAINTAINING EFFECTIVE FUNCTIONING OF MACHINES OR INSTALLATIONS; THERMAL INSULATION IN GENERAL
- F16C—SHAFTS; FLEXIBLE SHAFTS; ELEMENTS OR CRANKSHAFT MECHANISMS; ROTARY BODIES OTHER THAN GEARING ELEMENTS; BEARINGS
- F16C2220/00—Shaping
- F16C2220/20—Shaping by sintering pulverised material, e.g. powder metallurgy
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Metallurgy (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- General Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Computer Hardware Design (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Dispersion Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Theoretical Computer Science (AREA)
- General Physics & Mathematics (AREA)
- Physics & Mathematics (AREA)
- Computer Networks & Wireless Communication (AREA)
- Powder Metallurgy (AREA)
- Sliding-Contact Bearings (AREA)
- Chemically Coating (AREA)
Description
1312016 九、發明說明: 【發明所屬之技術領域】 現有產業界使用之運動對系統可區分為接觸式與非接觸 式兩大類,其中非接觸者大多以磁力懸浮或空氣壓懸浮為 =,基於製造成本、系統控制及設備維護的昂貴及複雜性影 曰所以,除了咼精密、高價值的設備允許使用外,對一 & ^運動對it件而言,滾動式及滑動式的接觸式運動對設計^ 為主要應用技術。 ⑺動式的運動對设计,一般利用兩滑動元件間添加潤滑 =、自潤性含油襯墊或軟質過渡材為主,其中以添加潤滑油 ^式較經濟,但是,對紐進行爾油添加的封閉 ^,免油潰污染的機構設計而言,就無法使用,軟質過渡 J·係精其自身易絲及可更換的特性,代替滑動對本體的^ 禎,但是,因軟質材有較明顯的磨耗問題,所以在定位尺寸 f度的變化上較大,同時軟質才大量磨耗所產生的細微顆 對系統而言仍是—項嚴重的污染,自潤型含油襯塾或軸 亩始、wt而。平均價格較低’因其具有潤滑油自動滲出潤滑 =,在旋轉軸與軸承組合之尺寸公差方面 ^界匕 士甚^但疋因潤滑油油耗及油含浸率會受工作溫度、基材 的摩差係數值等影響,對較高i動 ^度的運動對而§ ’哥命不佳,例如:自潤型軸承 的時,而遠不及滾珠轴承之5GGiKM、時為其應用上 滾動式的運崎設計,以傳統滾子轴承為大宗 ίί ϊ?命所容r由組合時有些許之傾角偏差及:承受 邓刀軸向支稱用疋件’對直線運動對的設計而言,就必須利 1312016 用數個滾^軸承裝置在固定直線導軌上,以達到直線運動的 目的i但是,因滾子與執道接觸及撞擊所造成的噪音問題、 平均價格高於自潤型含油軸承甚多及受限於數個滾珠線性組 裝的對正、調校技術需求性高,亦為其一大限制。 【先前技術】 ,今市面上有由THE GLACIER METAL CO., LTD.所開發, ,獲英國、日本、美國、加拿大、法國、義大利、德國、瑞士 等國專利之(日本之專利號碼2236〇5及438282) DU完全無 給,軸承,其係在鋼裡金上將青銅粉末燒結成為多孔質,而將 鐵氟龍-鉛的/混合物填滿含浸表面呈為鐵氟龍—鉛薄被膜,軸承 面經常有鐵氟龍-鉛因而摩擦低,所以不需用潤滑油,其鐵氟 龍一鉛含浸青銅燒結層約有〇.3mm厚,由於這個組織的功用, =期運轉磨損會約有G Glmm,其中的鋼裡金是確保轴承之固 疋性’尺寸精密度,安定性及正確之扭矩緊度所必需之強度功 用’應用此製程技術的製品有普通襯套,止推軸承,鳄付襯套, /月板如圖一即為此製程產品之剖面結構圖。此技術係在先 =工凡成之鋼裡金基材表面附上一層青銅基粉末再進行燒 二面形成—層多孔性組織,再將鐵氟龍—錯的混合物 呈為鐵氟龍-域彼膜,其中青銅基的粉末顆粒 士田乍鐵氟月I-鉛的充填材,此製程技術在多孔性表面蜱結 t須考量基材與青銅基粉末的高溫結合性,否則易產ίί ,、为離的情況,再則,青銅機粉末燒結溫度一般需達76〇它 ίί物使鋼裡金基材發生熱變形現像,鐵氟龍-鉛的 填充在夕孔性表面後,f加溫至刻。C以上,才能 與青娜充相互結合,而此高 ;h;°-3raffl ol ί ,原料中含有_成分也違反現有資訊產 規疋,因此其使用價值大受影響。 ,、土材的 6 1312016 【發明内容】 雜iiti f,本發明乃啸有顧滾伟权壽命、低 f tl! i傳統襯套的摩擦係數約為G. ‘Ο. 3。之間)、 仇Ϊί侗Ilf含油元件的低噪音、降低潤滑油脂所造成的污 Ϊ動對且二的製造成本、提升無給油軸承製程技術,使 本較減^«、財職、製造成 【實施方式】 《製程原理》 霧法程示賴’如®二所示,係直接利用喷 同粒^ί 基合金粉末顆粒,經初步篩選丨。後,將不 選)二二太,通〜尸""1’係以美國ASTM標準400號薛目_ ===(例如:石墨、硬脂酸以口 A,因th 不同粒徑之粉粒體予以均勻混 “於r⑤Γΐΐ度、混合機構等之設計,將會影響基材原 末;:二如二勻?程度’所以在混合粉末時,必須依照粉 ίϊί:2 ?大小分佈差異、比重差異等因素,採取能 之直立合作業,依照上述特性,本發明使用 ^直”螺《型混合機,再搭配適當之轉速(6〇〜 rpm) ’即為能夠達成混粉均勻性的方法之一。 命模粉程序之基材粉末,填注於壓床機台之中 i方上、下沖頭與中模加壓合模原理,以擠 =期==;=之二成面積 1312016 密度值未達前述標準,_最終製品仍能滿足 相虽5又计要求,但會增加後續製程的處理手續及影 疋性,所以,最佳化成形密度之要求,對大量生 : 品質穩定性及製成成本的降低,有其必要性。 ασ 成形製程中所使用之潤滑劑主要用於幫助生胚從模且 脫出,減$脫膜壓力,其潤滑方式一般可採用以下兩種:其 二為將乾燥之潤滑劑先與金屬粉末充分混合,直接填充於j莫 穴中,加壓成形,另一種為採用模壁潤滑的方式進行,即是 在金屬粉末填充入模穴之前,將溶解於易揮發性有機溶 内之液巧潤滑劑塗覆或倾麵壁及㈣表面,待 揮發乾燥後m麟表面達細滑效果,依本發明^ 驗數據所得,若烟電解銅合金滅粉末粒度大小匹^ 的粉體,再搭配適當的成形壓力,其可在未添加潤滑劑的& 胳ϊί=成形後之密度達7.97 g/cm3 ’如此亦能滿足前 述生胚成形製程較佳之密度需求。 胚將其送人燒雜枝行還魏氛下燒結處 里60,1、、、σ基本上是熱力學及擴散學的延伸,促使粉末 升蚀ΐ内11氛的有效控制,產生部分固態或液態:的 擴散現像,使祕力間能結合在―起。—般而言,燒結 之製ΐ變?1包括了_、溫度曲線、爐喊氛的選擇、 氣體的流量、高溫巾停留的時間和爐體結構的設計等,所以 要確保$成功的燒結,上述各項因素的控制缺一不可。 燒結製程執行的三步驟依序為: 1、預熱區:在此區中,主要是希望藉由熱能來達到脫脂去 壞的效果,同時在脫犧過程中粉體不會因 而變形。 2、燒結區:此區主要目的為成形體經前段雜區之脫躐處 理過程後,再藉由更高溫度之熱能效果,促使 生胚本體達到密緻化的目的。 8 1312016 冷卻區:經高溫舰處理後之成職結件,#由逐漸冷 部時之冷卻速率的控制,以決定成形體之金屬 組織和性質特性。 熱==熱 作^進,二1ί之'皿度奴在考量潤滑劑特性,以45(rc為操 产二’ 行整體燒結過程中’若加熱速率太快或溫 變lit 2積石ί的現像’同時也容易造成成形件的 由若干υ速率的控制相當重要,本發明經 右干「人只馱、、.。果分析,在成形件燒結前進速率控制在45〜 55mm/min的情況下,將能獲得良好之燒結件。 _ίίί=設計,基本上是依要燒結材料性質而建立,不 ί 同的燒結溫度、燒結氣氛和氣體流 驗八程中’利用輸送帶式連續爐’經反覆實 區到正式燒結區之過渡溫度設定在710 ^^ 25 ?^^^^8〇〇±5〇(:^^ ^ ^#^,1 有报強的還原性 則結速率下,在冷卻區約停留3〇分鐘即可。 經1燒結處理之成形件,—般而言,均有少許的變来, ’右工件精度要求不高的情況下,可將此燒結件直^進 1312016 行後續之表面改質及覆層處理, 較高者,則需進行尺寸精整程庠^^對工件尺寸精度要求 校之後,再進行後續的覆層,翁件尺寸進行精度調 油脂種ί精二f二需:行表面熱脫脂處理9。,依 音波除油⑷旨)行前置清洗或超 響覆層表面品質。如圖三所示面^;否則會影 =疏密特性’當作後段製程的充填材本體進= 在常規的化學鎳錄液中力人 微米及納米級微粒所製成四氟乙稀為主的 中,此微粒平均粒徑為^ 能=丈佈在鑛液 3%〜 =匕例,以動力_均4=:== =:3『勻懸浮為標準’以獲得金屬鎳 在無需外加電壓的情形下,把溶液巾的金屬離子 動催化的化學反應方式與制存在贿財的 學反應將金屬離子還原成固態金屬,並夹 雜15%:3〇%左右之聚四氟乙稀超微粒,逐層沉積於固體表 ίΐ ’ 序是反應發生時,電子傳遞並不經由外部 V線,而疋猎由洛液中的物質在固體表面上發 時,直接進行㈣。因讀程溫度—般維持在 此製程技術能獲得-種集硬度、耐磨'低摩差係 體的複合鑛層,其平均摩差係數為Ni_p鑛層^ ㈣ 〜0. 05) ’但在覆層處理之前,基材表面的各項清潔手續,·如 表面活化處理200、400、表面改質處理3〇〇、5〇〇及夂別 洗110、210、310、410、510等清潔及活性化處^ 〇發 做好,不然會嚴重影響覆層品質。 而 Λ 10 1312016 此化學鑛液之主要組成有: 1、 金屬離子(metal ions)為鍍層金屬的來源。 2、 還原劑(reducing agent):將金屬離子還肩成今屬 3、 催化劑(catalyst):使基材表面具有催化屬 4、 錯合劑(complexing agent):防止氫氧化物沈殺、 析出速率、防止鐘浴分解,使鑛浴安定。 5、 安定劑(stabilizer):吸著微粒雜質防止鑛浴 以延長鍍浴壽命。 …、刀月年, 7 8 緩衝劑(buffer):控制PH值在操作範圍内。 潤濕劑(wetting agent):使表面作用良好。1312016 IX. Description of invention: [Technical field to which the invention belongs] The motion-to-system used in the existing industry can be divided into two types: contact and non-contact. Among them, non-contacts are mostly magnetically suspended or air-suspended as =, based on manufacturing. Cost and system control and the cost and complexity of equipment maintenance, so in addition to the use of precision, high-value equipment, for a & ^ motion to it, rolling and sliding contact movement pairs Design ^ is the main application technology. (7) Dynamic motion design, generally using lubrication between the two sliding elements =, self-lubricating oil-filled gasket or soft transition material, which is more economical by adding lubricating oil, but it is added to New Zealand oil. Closed ^, the mechanism of the mechanism of oil-free pollution can not be used, the soft transition J· is refined by its own easy wire and replaceable characteristics, instead of sliding to the body, but because of the soft material Wear problem, so the change in the size f degree of the positioning is large, and the fine particles produced by the soft mass are still serious pollution to the system, self-lubricating oil-containing lining or shaft acre, wt . The average price is lower 'because it has the lubricating oil automatically oozing out the lubrication=, in terms of the dimensional tolerance of the rotating shaft and the bearing combination, the gentleman is very good, but the lubricating oil consumption and the oil impregnation rate are affected by the working temperature and the substrate. The influence of the difference coefficient value, etc., on the movement of the higher i motion degree and the § 'poor life, such as: self-lubricating bearing, but far less than the 5GGiKM of the ball bearing, when it is applied to the rolling type Saki design, with traditional roller bearings as the bulk of the ίί ϊ 命 r r 由 由 由 由 由 由 r r r r r r r 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合 组合1312016 A number of rolling bearing devices are used on fixed linear guides to achieve linear motion. However, due to noise problems caused by contact and impact between the rollers and the road, the average price is higher than that of self-lubricating oil-impregnated bearings. Limited by the alignment and adjustment techniques of several ball linear assemblies, it is also a major limitation. [Previous technology], developed by THE GLACIER METAL CO., LTD. on the market, and obtained patents from the United Kingdom, Japan, the United States, Canada, France, Italy, Germany, Switzerland, etc. (Japanese patent number 2236〇) 5 and 438282) DU is completely unsupported, bearing, which is sintered on the steel to make the bronze powder porous, and the Teflon-lead/mixture is filled with the impregnated surface as a Teflon-lead film, bearing The surface often has Teflon-lead and therefore low friction, so no lubricating oil is needed. The Teflon-lead-impregnated bronze sintered layer is about 3 mm thick. Due to the function of this structure, the wear and tear of the = phase will be about G Glmm. Among them, the steel gold is the strength function to ensure the bearing's solidity 'size precision, stability and correct torque tightness'. The products using this process technology have ordinary bushings, thrust bearings, crocodile linings. The set, the moon plate, is the cross-sectional structure of the process product. This technology is based on the surface of the gold substrate of the steel, and the surface of the gold substrate is coated with a layer of bronze-based powder and then formed into a layer of porous structure, and then the mixture of Teflon-wrong is Teflon-domain film. Among them, the bronze-based powder particles of Shi Tianxi iron-fluoride I-lead filling material, the process technology on the porous surface 蜱 knot t must consider the high temperature combination of the substrate and the bronze-based powder, otherwise easy to produce ίί, In the case of separation, the sintering temperature of the bronze machine powder generally needs to reach 76 〇. It is used to thermally deform the gold substrate in the steel. After the Teflon-lead is filled on the surface of the smectic surface, f is heated to the moment. Above C, it can be combined with Qingna, and this high; h; °-3raffl ol ί, the raw material contains _ ingredients also violates the existing information regulations, so its use value is greatly affected. 6 1312016 [Inventive content] Miscellaneous iiti f, the invention is a whistling and rolling life, low f tl! i traditional bushing friction coefficient is about G. ‘Ο. Between), Qiu Ϊ 侗 侗 Ilf oil-containing components of low noise, reduce the pollution caused by grease and the second manufacturing cost, improve the technology of the oil-free bearing process, so that the reduction of ^ «, wealth, manufacturing into [ The implementation method] "Process Principle" The fog method is shown as "Like", which is directly used to spray the same grain of the alloy powder, and is initially screened. After that, will not choose) Twenty-two too, pass ~ corpse ""1' is US ASTM standard No. 400 Xuemu _ === (for example: graphite, stearic acid to mouth A, due to different particle size of th The powder and granules are evenly mixed. The design of the r5 twist, mixing mechanism, etc. will affect the original end of the substrate; the second is equal to the degree of the mixture. Therefore, when mixing the powder, it must be in accordance with the size distribution of the powder ίϊί:2? According to the above characteristics, the invention uses the "straight" screw type mixer, and the appropriate rotation speed (6 〇 ~ rpm) is a method capable of achieving uniformity of mixing powder. One. The base powder of the life molding powder program is filled in the presser machine, the upper punch, the lower punch and the middle die press and clamp the principle, so that the squeeze = period ==; = two of the area 1312016 The density value does not meet the above criteria, _ the final product can still meet the requirements of the phase 5, but will increase the processing procedures and impact of subsequent processes, so the requirements for optimizing the forming density, for a large number of students: quality stability And the cost of production is reduced, it is necessary. Used in ασ forming process Lubricant is mainly used to help the raw embryos to escape from the mold and reduce the pressure of the film. The lubrication method can generally be as follows: The second is to mix the dry lubricant with the metal powder and fill it directly. In the hole, pressure forming, and the other method is to use the mold wall lubrication method, that is, before the metal powder is filled into the cavity, the liquid lubricant dissolved in the volatile organic solvent is coated or tilted and (4) The surface is to be volatilized and dried, and the surface of m Lin has a smooth sliding effect. According to the data of the present invention, if the powder of nickel oxide is used to extinguish the powder of powder size and size, and then with appropriate forming pressure, it may not be added. Lubricant & ϊ ϊ = the density after forming is 7.97 g / cm3 'This can also meet the better density requirements of the aforementioned green forming process. The embryo will be sent to the burning branch and 60 in the sintering place under the Wei atmosphere. 1, σ, π is basically an extension of thermodynamics and diffusion, which promotes the effective control of the 11 atmosphere in the powder eclipse, and produces a part of the solid or liquid: the diffusion of the image, so that the secret force can be combined. Words, the system of sintering has changed? 1 includes _, temperature curve, choice of furnace atmosphere, flow of gas, time of stay of high temperature towel and design of furnace structure, so to ensure the successful sintering, the control of the above factors is indispensable. The three steps of the process are as follows: 1. Preheating zone: In this zone, it is mainly hoped that the effect of degreasing and deteriorating can be achieved by thermal energy, and the powder will not be deformed during the sacrifice process. Zone: The main purpose of this zone is to achieve the purpose of densification of the green body by the higher temperature thermal energy effect after the dislocation process of the shaped body through the front section. 8 1312016 Cooling zone: treated by high temperature ship After the completion of the work, # is controlled by the cooling rate of the gradual cold part to determine the metal structure and properties of the shaped body. Heat == hot work, two 1 ί's 'study of the lubricant characteristics, to 45 (rc for the production of two 'line during the overall sintering process' if the heating rate is too fast or temperature change lit 2 stone ί At present, it is also very easy to cause the control of the formed part by a certain rate of enthalpy. The present invention is right-handed by the "right, only.", fruit analysis, in the case where the sintering progress rate of the formed part is controlled at 45 to 55 mm/min. , will get a good sintered part. _ ί ί ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ ̄ The transition temperature from the real zone to the formal sintering zone is set at 710 ^^ 25 ?^^^^8〇〇±5〇(:^^ ^ ^#^,1 with a reductive reductive rate at the junction rate, in the cooling zone It takes about 3 minutes to stay. After the sintering process, the molded parts, in general, have a little change. When the accuracy of the right workpiece is not high, the sintered part can be straightened into 1312016. Surface modification and coating treatment, the higher the size, the size finishing process 庠 ^ ^ on the workpiece size After the accuracy is required to be corrected, the subsequent coating is carried out, and the size of the ingot is adjusted to the precision of the grease. ί 精 二 f 2 needs: line surface thermal degreasing treatment 9. According to the sound wave degreasing (4)) pre-cleaning or super-sounding The surface quality of the layer. As shown in Figure 3, the surface is ^; otherwise, the shadow = density characteristic 'as the filling process of the back-end process. In the conventional chemical nickel recording liquid, the human-made micron and nano-scale particles are made of PTFE. In the case of ethylene-based, the average particle size of the particles is ^ can be = zhang in the ore solution 3% ~ = 匕 example, with power _ average 4 =: == =: 3 "even suspension as the standard" to obtain metal nickel In the absence of an applied voltage, the chemical reaction of the metal ion catalyzed by the solution towel and the chemical reaction of the bribes are used to reduce the metal ions into a solid metal, and the polytetrafluoroethylene is contained in an amount of 15%: 3〇%. Ethylene ultrafine particles are deposited layer by layer on the solid surface. The order is that when the reaction occurs, the electron transfer does not pass through the external V line, but when the material in the Lok liquid is emitted on the solid surface, it is directly carried out (4). The process temperature is generally maintained in this process technology can be obtained - a collection of hardness, wear resistance 'low friction The composite ore layer of the system has an average friction coefficient of Ni_p ore layer ^ (4) ~ 0. 05) 'But before the coating treatment, various cleaning procedures of the surface of the substrate, such as surface activation treatment 200, 400, surface Modification of 3〇〇, 5〇〇 and 洗Do not wash 110, 210, 310, 410, 510 and other cleaning and activation sites ^ 〇 发 done well, otherwise it will seriously affect the quality of the coating. Λ 10 1312016 This chemical mine The main components of the liquid are: 1. Metal ions are the source of the coated metal. 2. Reducing agent: the metal ions are returned to the current genus. 3. Catalyst: Catalyst on the surface of the substrate. Genus 4, complexing agent (complexing agent): prevent hydroxide sinking, precipitation rate, prevent the decomposition of the clock bath, so that the mineral bath is stable. 5, stabilizer (stabilizer): absorbing particulate impurities to prevent mineral bath to extend the life of the bath. ..., knife year, 7 8 buffer: control PH value within the operating range. Wetting agent: Makes the surface work well.
Dispersion:使超微粒耐磨材,均勻披覆。 n劑通常可用次概鈉,PH是控制鍛層p的含量,一 P含量較少,鑛層性質因而有所改變,低P含量 ίϋϋ的鑛層耐雌較差,p含量大於8%則錢層不含ί 置放f 3°叱〜默之高溫烘烤 ίΪίίίίί 此覆層表面達到更進—步的密著性處理_, 影ί 丄(P〇St_baking)對鑛層的結晶結構將有顯著 可再2理獅後之零件,依製程精度需求, 應600後^未^人芦^童’以再一:欠清除電化學反 件運轉初期於基材表面的微細顆粒,以維持零 1千運轉初_不牛社微 性尺寸精度柳。如圖岭㈣表面經密著 《實驗結果》 盆不作之高效能滑動對經實驗職結果得到 八不僅此献低摩擦係數、耐磨耗、硬度高、尺寸精密1 π 1312016 造成本較低及提高系統動力能量的效能,同時,覆只面、宜 之磨耗量僅約為0. 1〜0· 2/zm。 初^ 下 本發明所製造之產品其理論上之基本物理、化學性質如 、工作溫度約為-30°C〜200°C。 2 、具惰性層保護,可抗一般之化學及氧化腐蝕作用。 、低摩擦係數,在冷卻風扇測試實驗負載下運轉3〇天後於 測,幾乎無磨耗發生,在極少量的潤滑油環境下’ w 運轉250天後之磨耗量,< 1 。 貝 4 、表面機械抗張強度可達2〇〇Kgf/cm2。 5、 熱傳導係數值約〇. 5左右,熱膨漲係數可經由 使其分佈在5〜10/。。左右。 刀拴制 6、 表面改質層厚薄較均勻且不易剝離,較能 下之產品精密度。 亏W連轉 7、 因费緻化結果表面無微孔。 做如^ 明亦糊此技術應用於DC風扇之轉動軸承製 5(4 Γί,、甘經線上實際測試結果,諸BF值超過 =00小時’其職結果如附件—之報 =足以媲美現有應用叙驗子録,同理用t 直線運動_絲錢如此。 i⑯其應用於 《結論與討論》 之将技娜狀產品可雜—:欠將銅'祕零件表面 末顆粒當作四氟乙烯高分子 面 擦係數、耐磨耗、硬度高、尺寸精密穿; 迴轉效能’因此能有效應用於直線運“ 她精崎升上,又遠 方式時右之粉末冶金製程的基材,改以金屬切削 、由本W只要能適當控师絲材表面之粗縫 12 ,值(Ra值約在〇 6〜〇8 # 局低輪靡變化,作 由基材表面適度的斷面 程戶梅產品之物理之填,’仍能具備上述之製 ,冶金製程,因此,在其製造成本將高於前述 求下,本發酬提f 、域本賴程技術要 案之-。 衣姑姻f是能滿足缝需求的解決方 ^圖式簡單說明】 第 弟三圖 第四圖 第五圖 ί - Ξ 案DU完全無給油承之剖面結構圖。 弟一圖·係本發明之製造流程圖。 係本發明粉末燒結表面組織結構放大圖。 ,士發明覆層表面經密著性處理後之表面狀況圖。 笛丄5係本發明迴轉運動對之實體製品圖。 f^;、圖·係本發明實驗用風扇轉動部組裝後之實體圖。 L主要元件符號說明】 13Dispersion: Makes ultra-fine particles wear-resistant and evenly coated. The n agent can usually be used as a sub-sodium, the pH is the content of the forged p layer, the P content is less, the properties of the ore layer are changed, the low P content is poorer than the female, and the p content is more than 8%. ί 置 f 3 3 3 3 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 默 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此 此After the second part of the lion, according to the precision requirements of the process, it should be 600 after the ^ ^ ^ ^ ^ ^ ^ to one more: under the removal of the electrochemical particles in the initial stage of the fine particles on the surface of the substrate to maintain zero thousand operation Initial _ not cattle company micro-size accuracy Liu. As shown in Figure XI (4), the surface is closely covered with the "Experimental Results". The high-performance sliding of the pot is not achieved. The results of the experimental results are not only the low friction coefficient, the wear resistance, the high hardness, and the precision of the size 1 π 1312016. 1〜0· 2/zm。 The efficiency of the system of the power, at the same time, the surface is only about 0. 1~0· 2/zm. Initially, the product of the present invention has theoretical basic physical and chemical properties such as an operating temperature of about -30 ° C to 200 ° C. 2, with inert layer protection, can resist general chemical and oxidative corrosion effects. , low friction coefficient, after running for 3 days in the cooling fan test test load, almost no wear occurred, and the wear amount after 250 days of operation in a very small amount of lubricating oil environment, < 1 . Shell 4, the surface mechanical tensile strength can reach 2〇〇Kgf/cm2. 5, the heat transfer coefficient value is about 〇. 5 or so, the thermal expansion coefficient can be distributed through 5~10/. . about. Knife system 6. The surface modification layer is relatively thin and not easy to peel off, which is better than the product precision. Loss W continuous turn 7. Due to the cost of the results, there is no micropores on the surface. Do as well as ^ Ming also paste this technology applied to the DC fan's rotating bearing system 5 (4 Γ ί,, the actual test results on the Ganjing line, the BF value exceeds 00 hours'' job results as attached - report = enough to match existing applications The narration of the sub-records, the same use of t-linear motion _ silk money so. i16 its application in the "conclusions and discussion" will be the product of Na-like products can be mixed -: owe the copper 'secret parts surface particles as high PTFE Molecular surface friction coefficient, wear resistance, high hardness, precision wear; rotation efficiency 'so can be effectively applied to the linear transport" As long as the W can properly control the rough seam 12 on the surface of the wire, the value (Ra value is about 〇6~〇8#), the low rim changes, and the physical surface of the substrate is moderately sectioned. Filled in, 'still can have the above-mentioned system, metallurgical process, therefore, in terms of its manufacturing cost will be higher than the above-mentioned requirements, this offer is f, the domain of the technology is necessary. - Yigu marriage f can meet the seam demand The solution of the solution ^ simple description] the third brother of the fourth figure Figure 5 - The DU is completely free of oil-bearing cross-sectional structure diagram. The first diagram is the manufacturing flow chart of the present invention. It is an enlarged view of the surface structure of the powder sintered surface of the present invention. The surface condition map of the following. The snapper 5 is a physical product diagram of the rotary motion pair of the present invention. f^;, Fig. is a physical diagram of the assembled fan rotating part of the present invention. L main component symbol description] 13
Claims (1)
Priority Applications (7)
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TW094102516A TW200626756A (en) | 2005-01-27 | 2005-01-27 | Surface cladding manufacturing method of high-efficiency motion pairs system |
AU2006200273A AU2006200273A1 (en) | 2005-01-27 | 2006-01-23 | High-Effect Surface Cladding Manufacturing Method of Motion Pairs System |
KR1020060007973A KR20060086873A (en) | 2005-01-27 | 2006-01-25 | Manufacturing method of overlap surface for high efficiency movement |
DE102006003823A DE102006003823A1 (en) | 2005-01-27 | 2006-01-26 | A method for highly effective coating of a surface of a system of pairs of motion |
JP2006018384A JP2006225762A (en) | 2005-01-27 | 2006-01-27 | Method for producing covered layer of component |
GB0601645A GB2423306A (en) | 2005-01-27 | 2006-01-27 | Surface cladding manufacturing method of motion pairs system |
US11/340,536 US20080138231A1 (en) | 2005-01-27 | 2006-01-27 | High-effect surface cladding manufacturing method of motion pairs system |
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TW094102516A TW200626756A (en) | 2005-01-27 | 2005-01-27 | Surface cladding manufacturing method of high-efficiency motion pairs system |
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TWI312016B true TWI312016B (en) | 2009-07-11 |
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DE (1) | DE102006003823A1 (en) |
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CN102537361B (en) * | 2010-12-07 | 2015-05-27 | 济源市中科新型陶瓷有限公司 | Sealing ring for water circulation sealing box of car and preparation method of sealing ring |
CN106217912B (en) * | 2016-09-26 | 2018-03-23 | 佛山慧氟高分子材料有限公司 | A kind of production technology of LCD liquid crystal displays module binding Teflon film |
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GB2050429B (en) * | 1979-06-05 | 1984-04-04 | Hitachi Powdered Metals | Method of producing bronze-based sintered bearing material |
JP2512477B2 (en) * | 1987-06-17 | 1996-07-03 | 大豊工業株式会社 | Copper-based sliding material |
US4830889A (en) * | 1987-09-21 | 1989-05-16 | Wear-Cote International, Inc. | Co-deposition of fluorinated carbon with electroless nickel |
DE3838461A1 (en) * | 1988-11-12 | 1990-05-23 | Krebsoege Gmbh Sintermetall | POWDER METALLURGICAL MATERIAL BASED ON COPPER AND ITS USE |
GB9114291D0 (en) * | 1991-07-02 | 1991-08-21 | Johnson Electric Sa | A sheet metal bearing for an electric motor |
ES2189917T3 (en) * | 1996-12-14 | 2003-07-16 | Federal Mogul Deva Gmbh | BEARING MATERIAL AND PROCEDURE FOR MANUFACTURING. |
US6132486A (en) * | 1998-11-09 | 2000-10-17 | Symmco, Inc. | Powdered metal admixture and process |
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JP2006225762A (en) | 2006-08-31 |
DE102006003823A1 (en) | 2006-08-10 |
AU2006200273A1 (en) | 2006-08-10 |
US20080138231A1 (en) | 2008-06-12 |
GB0601645D0 (en) | 2006-03-08 |
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