1297746 九、發明說明·· 【發明所屬之技術領域】 本發明係有關於一種人造麂皮，更特別有關於一種環保 人造麂皮製造方法，其使用水性高分子彈性體樹脂及架橋 劑。 【先前技術】 習知人造麂皮的製造方法，係利用聚合物原料所製的纖 維’諸如包含島成分及海成分的海島型複合纖維，製造成 一非織物基布。再將該基布含浸於一油性高分子彈性樹 脂。再進行減量步驟，以鹼溶除該基布的複合纖維海成分。 再經中和及水洗步驟而成一人造麂皮半成品。最後進行研 磨及染色，以製成一人造麂皮。然而，習知人造麂皮製造 方法之缺點係在於含ί文製程中該油性南分子彈性樹脂須溶 有大量溶劑，因此較不環保。另外，染色製程時，由於含 有油性高分子彈性樹脂在染色中不易將未附著之殘餘染料 洗淨，因此造成染色堅牢度不佳。 舉例而言，義國專利第3,531，368號，標題為“人造纖 維及類似物（Synthetic Filament And The Like)，，，揭示一種 生產微纖維狀之仿麂皮製造方法。該製造方法是以耐隆 (Nylon)和磺酸基聚對苯二曱酸乙二酯（co-pet)雙成分製 成複合纖維（海島型）之非織物基布，再以溶有二甲基甲醯 胺（DMF)之聚胺酯（PU)含浸，然後以二甲基甲醯胺（DMF) 水溶液進行凝固。經水洗及烘乾後，再經減量步驟以去除 磺酸基聚對苯二甲酸乙二酯（Co-PET)之海成份，最後經研 5 1297746 因此，便有需要提供一種環保人造麂皮及其製造方法， 能夠解決前述的缺點。 【發明内容】 本發明之一目的在於提供一種環保人造麂皮製造方 法’其使用水性高分子彈性體樹脂及架橋劑，該架橋劑可 使凝固後之高分子彈性體樹脂更結實，用以增加人造麂皮 之強度及物性。 φ 為達上述目的，本發明提供一種人造麂皮製造方法，包 含下列步驟：提供一基布；將該基布進行減量及染色處理； 形成具有水性高分子彈性體樹脂及架橋劑之含浸層於該基 . 布中；以及固化、烘乾 '研磨、水洗、烘乾及摔軟該基布 • 及該含浸層，以形成一柔軟環保人造麂皮。 本發明之人造麂皮的物性（财汗、水洗、摩擦堅牢度及 耐光堅牢度）確實較優於先前技術。再者，本發明之含浸用 之架橋劑可使凝固後之高分子彈性體樹脂更結實，用以增 φ 加人造麂皮之強度及物性。再者，本發明之含浸層可具有 水性色料，用以微調該基布之顏色。 為了讓本發明之上述和其他目的、特徵、和優點能更明 顯’下文將配合所附圖示，作詳細說明如下。 【實施方式】 ' 以下將配合第1至2圖說明本發明提供之環保人造麂皮 製造方法。 在針軋或水軋步驟102中，將細度約1至1〇丹尼之海 7 1297746 島型超細纖維以針軋或水軋而形成一種非織物基布（圖中 未示），或者將細度約1至10丹尼之海島型超細纖維202 及補強材204針軋或水軋而形成一種非織物基布2〇6。所 • 明/母島型超細纖維」係指一種以混合紡絲法或複合紡絲 … 法紡出的纖維，其包含兩種以上溶除性不相同的成分。從 纖維斷面觀之該兩種以上之成分係排列成海島狀，因此分 別稱為海成分以及島成分。根據本發明之實施例，該海島 型超細纖維係由聚對苯二曱酸乙二酯、聚對苯二甲酸丙二 • 酯、聚對苯二曱酸丁二酯或一種以上之上述聚酯之混合物 等聚酯類以及尼龍6、尼龍66或上述尼龍之混合物等尼龍 類以及聚烯氫類（PP，PE及其共聚合物等）以及易溶解型聚 酯類（Co-PET等.)之上述聚合物材料群組中選擇出兩種以上 材料製造而成。較佳地，該海島型超細纖維的細度係在約 1至約10丹尼之間。該補強材204係可為為織布類或針織 類，其成分組成係可為T/N(聚醋/尼龍）、Nylon(尼龍）或 ERC(聚酯/嫘縈/天然棉）混紡組成。 % 在減量步驟104中，利用能溶解海成分但是不能溶解島 成分的溶媒（例如採用易溶解型聚酯作為海成分，則可用 、 濃度重量百分比為U5%的強鹼水溶除之），將前述基布 206的海成分溶除。經此減量步驟後，烘乾該基布206，能 _ 使剩下的島成分分散，使得基布206中的纖維細度減少至 . 島成分的細度（約〇.01至約1.8丹尼之間），因此能得到更 加細緻類似真皮的觸感。由於該基布206包含一補強材 204，因此在減量步驟之後，該基布206仍具有足夠的強度 而不易變形。然而，本發明所屬技術領域中具有通常知識 8 1297746 者可知該補強材係用於減量步驟後提供該基布足夠的強度 而非必要元件。 在染色步驟106中，藉由一染色機台將該基布206染 色’其中該染色機台細可為束染機（Jigger)、經軸染色機 … （Beam)或捲布染色機（wince)等機台。 在含浸步驟1 08中，含浸水性高分子彈性體樹脂及架橋 劑’或含浸水性高分子彈性體樹脂及架橋劑及水性色料， 馨 以形成一含浸層208配置於該基布206中。該架橋劑之添 加里係可為該水性高分子彈性體樹脂之H %至3 % 。該水 性高分子彈性體樹脂與水的比例係介於約2〇/8〇至60/40 • 之間。然後對該含浸層208加以固化（步驟11〇)、烘乾（步 - 驟114)及研磨（步驟Π6)等處理以形成一高染色牢度環保 人造麂皮成品200(步驟118)，如第2圖所示。此時由於該 基布206已經過減量步驟，因此含浸用之高分子樹脂溶液 月b充分填滿島成分周圍的空隙，使得整個基布2〇6‘的含浸 _ 均勻’此有均勻的密度。本發明含浸用之水性高分子彈性 體樹脂係可為聚胺酯掛脂、丙烯酸酯樹脂、丁二烯樹脂、 環氧樹脂、共聚合樹脂等。本發明之固化後該含浸層中高 、 分子彈性體樹脂與架橋劑之關係可類似於混凝土中水泥與 ， 砂石之關係，因此含浸用之架橋劑可使凝固後之高分子彈 '性體樹脂更結實，用以增加人造麂皮之強度及物性。 參考第3圖，將該高染色牢度環保人造麂皮成品2〇〇可 進行水洗（步驟122)、烘乾（步驟124)及摔軟（步驟126)，以 形成一柔軟高牢度環保人造麂皮最終成品（步驟128)。 9 Ϊ297746 下述之實施例1及實施例2係用以更詳細說明本發明， 而並非用以限定本發明。 實施例1 ·· 將細度3丹尼（尼龍/聚酯海島型超細纖維）以及厚度 0.1mm的成份尼龍網布補強材經軋針機製成重量400g/m2 厚度1.0mm的非織布基布。再將該基布送入減量機，以重 量百分比10%強鹼溶液將海烏型超細纖維的易溶解型聚酯 (Co-PET)溶除，洗淨後烘乾，此時該基布中的尼龍纖維細 度為0.07丹尼。將此減量後的基布以酸性染料（商品名·· Irgalan Blue，重量百分比4%，公司名：CIBA)於一束染機 (hgger)染色’溫度95°C且恒溫時間60分鐘，然後經水洗 及烘乾◊將已染色之基布含浸水性高分子彈性體樹脂，該 水性高分子彈性體樹脂組成份為水性樹脂（商品名·· Purepelle，公司名·· D〇w)與水比例為3〇/7〇之水性聚胺酯 .树舳（pu) ’並添加抗氧化劑（重量百分比i%)及架橋劑（重量 刀比0·7 /〇)’再進行固化、烘乾、研磨形成一高牢度環保 人造麂皮。也可再經水洗、烘乾及摔軟而形成一柔軟高牢 度環保人造麂皮。本實施例i之人造麂皮的物性係記載於 下列物性比較表中。 將細度3丹尼（尼龍/聚醋海島型超細纖維）以及〇. 的成份尼龍網布補強材經軋針機製成重量彻咖2 :二ΓΓ布基布。再將該基布送入減量機，以重 肩強驗溶液將海島型超細纖維的聚酿溶除，洗 10 1297746 -* ' . - 烘乾，此時該基布中的尼龍纖維細度為0·07丹尼。將此減 量後的基布以酸性染料（商品名：Irgalan Blue，重量百分比 40/〇，公司名·· CIBA)於一束染機（jigger)染色，溫度95它恒 溫時間6〇分鐘，然後經水洗及烘乾。上述染色步驟係用以 … 粗調該基布之顏色。將已染色之基布含浸水性高分子彈性 體樹脂，該水性高分子彈性體樹脂組成份為水性樹脂（商品 名：Purepelle，公司名：DOW)與水比例為30/70之水性聚 胺酯樹脂（PU)，並添加抗氧化劑（重量·百分比1%)及架橋劑 # (重量百分比0·7%)與水性色料（對水性樹脂重量百分比 5%)。上述水性色料係用以微調該基布之顏色。最後經進行 固化、烘乾、研磨形成一高牢度環保人造麂皮。也可再經 水洗、烘乾及摔軟而形成一柔軟高牢度環保人造麂皮。本 實施例2之人造麂皮的物性係記載於下列物性比較表中。 比較例1 ·· 將細度3丹尼（尼龍/聚酯海島型超細纖維）以及〇.imm 的成份Nylon網布補強材經軋針機製成重量4〇〇g/m2厚度 _ Γ·0ιηιη的非織布基布。以該非織布基布含浸水性樹脂，水 性树鈿組成份為水性樹脂（商品名：purepelle，公司名：D〇w) • 與水比例為30/70之水性聚胺醋樹脂（PU)並添加抗氧化劑 • 再經固化及烘乾，再經重量百分比10%強鹼溶液去除海成 .份後經水洗、乾燥及研磨而形成一人造麂皮半成品。將該 人造麂皮半成品以酸性染料（商品名·· Irgalan Blue，重量百 分比4。/。，公司名：CIBA)於一束染機（Jigger)染色，溫度 95 C且恆溫時間60分鐘‘，然後經水洗、烘乾、摔軟而成一 習知人造麂皮。該比較例1之人造麂皮的物性係記載於下 1297746 列物性比較表中。 比較例2 ·· 將細度3丹尼（尼龍/聚酯海島型超細纖維）以及〇 ljnm 的成份Nylon網布補強材經軋針機製成重量400g/m2厚度 1 ·0ιηιη的非織布基布。以該非織布基布含浸油性聚胺酯樹 脂（商品名·· HS-80，公司名··日勝化學），再經固化及烘乾 步驟，然後經重量百分比丨〇%強鹼溶液去除海成份後經水 洗、中和、乾燥及研磨而形成一人造麂皮半成品。將該人 造麂皮半成品以酸性染料（商品名：IrgalanBlue，重量百分 比4%，公司名：CiBA)於一束染機⑺啊）染色，溫度％ . 它且=溫時間60分鐘，然後經水洗、烘乾、摔軟而成一習 决人L麂皮。该比較例2之人造麂皮的物性係記載於下列 物性比較表中。 測試 較表 水洗 測試 磨擦堅牢度 耐光 實施例1 ~~7~---- 4.0 測試 4.0 D:4 4.0 實施例2 —r~^·-- 4·〇 W: 4 4.0 D:4 4.0 比較例了 —-—~~__ W: 4 1 D: 3.0 W: 2.5 3.5 比較例2 2.0 ~dT3T~~ 3.0 --—^— W: 2.5BACKGROUND OF THE INVENTION 1. Field of the Invention The present invention relates to an artificial suede, and more particularly to an environmentally friendly artificial suede manufacturing method using an aqueous polymeric elastomer resin and a bridging agent. [Prior Art] A method for producing artificial husks is to produce a non-woven base fabric by using a fiber made of a polymer raw material such as an island-in-sea type composite fiber containing an island component and a sea component. The base fabric is further impregnated with an oily polymer elastic resin. Further, a reduction step is carried out to dissolve the composite fiber sea component of the base fabric with an alkali. After the neutralization and washing steps, a semi-finished artificial suede is formed. Finally, grinding and dyeing are carried out to make an artificial suede. However, the conventional method of manufacturing an artificial suede has the disadvantage that the oily southern molecular elastic resin must have a large amount of solvent dissolved in the process, and therefore is less environmentally friendly. Further, in the dyeing process, since the oily polymer elastic resin is hard to wash the unattached residual dye during dyeing, the dyeing fastness is not good. For example, U.S. Patent No. 3,531,368, entitled "Synthetic Filament And The Like," discloses a method for producing a microfibrous suede. The manufacturing method is based on Nylon. (Nylon) and sulfonic acid-polyethylene terephthalate (co-pet) are made into a non-woven base fabric of composite fiber (island type), and then dissolved in dimethylformamide (DMF). The polyurethane (PU) is impregnated and then solidified with an aqueous solution of dimethylformamide (DMF). After washing and drying, it is subjected to a reduction step to remove the sulfonic acid-based polyethylene terephthalate (Co-PET). The composition of the sea, finally research 5 1297746 Therefore, there is a need to provide an environmentally-friendly artificial suede and a manufacturing method thereof, which can solve the aforementioned disadvantages. [Invention] It is an object of the present invention to provide an environmentally-friendly artificial suede manufacturing method. 'It uses a water-based polymer elastomer resin and a bridging agent, and the bridging agent can make the polymer elastomer resin after solidification stronger, and is used to increase the strength and physical properties of the artificial suede. φ In order to achieve the above object, the present invention provides a A method for producing an artificial suede comprising the steps of: providing a base fabric; reducing and dyeing the base fabric; forming an impregnated layer having an aqueous polymeric elastomer resin and a bridging agent in the base fabric; and curing, Drying, grinding, washing, drying and softening the base fabric and the impregnated layer to form a soft and environmentally-friendly artificial suede. The physical properties of the artificial suede of the present invention (perspiratory sweat, water washing, friction fastness and light fastness) It is indeed superior to the prior art. Furthermore, the bridging agent for impregnation of the present invention can make the polymer elastomer resin after solidification stronger, and increase the strength and physical properties of the artificial suede. The above-described and other objects, features, and advantages of the present invention will become more apparent from the accompanying drawings. [Embodiment] The following describes the method for producing an environmentally-friendly artificial suede provided by the present invention in conjunction with Figures 1 to 2. In the needle rolling or water rolling step 102, the fineness is about 1 to 1 〇 Danny Sea 7 1297746 The island-type ultrafine fiber is formed by needle rolling or water rolling to form a non-woven base fabric (not shown), or the island-type ultrafine fiber 202 and the reinforcing material 204 having a fineness of about 1 to 10 denier are pinched or water-reduced. Rolling to form a non-woven base fabric 2〇6. “Ming/mother island type microfiber” means a fiber spun by a mixed spinning method or a composite spinning method, which contains two or more kinds of dissolving properties. The same ingredients. The two or more components are arranged in an island shape from the cross section of the fiber, and are therefore referred to as sea components and island components, respectively. According to an embodiment of the present invention, the sea-island type ultrafine fiber is composed of polyethylene terephthalate, polybutylene terephthalate, polybutylene terephthalate or more than one of the above poly Polyesters such as ester mixtures and nylons such as nylon 6, nylon 66 or a mixture of the above, and polyene hydrogens (PP, PE and its copolymers) and soluble polyesters (Co-PET, etc.). The above polymer material group is selected from two or more materials. Preferably, the sea-island type ultrafine fibers have a fineness of from about 1 to about 10 denier. The reinforcing material 204 may be woven or knitted, and its composition may be a blend of T/N (polyacetate/nylon), Nylon (nylon) or ERC (polyester/嫘萦/natural cotton). % In the reduction step 104, using a solvent capable of dissolving the sea component but not dissolving the island component (for example, using a readily soluble polyester as the sea component, it can be dissolved by a strong alkali water having a concentration percentage by weight of U 5%). The sea component of the base fabric 206 is dissolved. After the reduction step, the base fabric 206 is dried to disperse the remaining island components, so that the fineness of the fibers in the base fabric 206 is reduced to a fineness of the island composition (about 〇.01 to about 1.8 denier). Between), so you can get a more detailed leather-like touch. Since the base fabric 206 includes a reinforcing material 204, the base fabric 206 still has sufficient strength to be easily deformed after the weight reduction step. However, it is known in the art to which the present invention pertains to the general knowledge 8 1297746 that the reinforcing material is used to provide sufficient strength of the base fabric rather than the necessary components after the step of reducing. In the dyeing step 106, the base fabric 206 is dyed by a dyeing machine. The dyeing machine can be a jigger, a warp dyeing machine (Beam) or a roll dyeing machine (wince). Waiting for the machine. In the impregnation step 080, the impregnated aqueous polymer elastomer resin and the bridging agent' or the impregnated aqueous polymer elastomer resin and the bridging agent and the aqueous colorant are formed to form an impregnation layer 208 disposed in the base fabric 206. The addition agent of the bridging agent may be from H% to 3% of the aqueous polymer elastomer resin. The ratio of the aqueous polymeric elastomer resin to water is between about 2 Å / 8 Torr to 60 / 40 Å. Then, the impregnated layer 208 is cured (step 11 〇), dried (step 114), and ground (step Π 6) to form a high-dye fastness environmentally-friendly artificial suede product 200 (step 118), such as Figure 2 shows. At this time, since the base fabric 206 has been subjected to the weight reduction step, the polymer resin solution for impregnation is sufficiently filled with the voids around the island component, so that the entire base fabric 2'6's impregnation_uniform' has a uniform density. The aqueous polymer elastomer resin for impregnation according to the present invention may be a polyurethane grease, an acrylate resin, a butadiene resin, an epoxy resin, a copolymer resin or the like. After the curing of the present invention, the relationship between the high molecular elastomer resin and the bridging agent in the impregnated layer can be similar to the relationship between the cement and the sand in the concrete, so that the bridging agent for impregnation can make the polymer elastic resin after solidification. More robust, to increase the strength and physical properties of artificial suede. Referring to Fig. 3, the high-dye fastness environmentally-friendly artificial suede product can be washed (step 122), dried (step 124) and softened (step 126) to form a soft high-fastness environmentally-friendly artificial The final product of the mink (step 128). 9 Ϊ 297746 The following examples 1 and 2 are intended to illustrate the invention in more detail and are not intended to limit the invention. Example 1 ·· The fineness 3 Danny (nylon/polyester island-type ultrafine fiber) and the component nylon mesh reinforcement material having a thickness of 0.1 mm were made into a non-woven fabric having a weight of 400 g/m 2 and a thickness of 1.0 mm by a needle rolling machine. Base cloth. The base fabric is sent to a reducer, and the dissolvable polyester (Co-PET) of the sea-type ultrafine fiber is dissolved by a 10% by weight alkali solution, washed and dried, and the base fabric is dried at this time. The nylon fiber has a fineness of 0.07 denier. The reduced base fabric was dyed with a dye (trade name: Irgalan Blue, 4% by weight, company name: CIBA) in a dyeing machine (hgger) at a temperature of 95 ° C and a constant temperature of 60 minutes, and then After washing and drying, the dyed base fabric is impregnated with a water-based polymer elastomer resin, and the aqueous polymer elastomer resin component is a water-based resin (trade name · Purepelle, company name · D〇w) and water ratio is 3〇/7〇 of water-based polyurethane. Tree 舳 (pu) 'and add antioxidant (% by weight i%) and bridging agent (weight knife ratio 0·7 / 〇)' then solidify, dry, grind to form a high Fast and environmentally friendly artificial suede. It can also be washed, dried and softened to form a soft, high-fastness environmentally-friendly artificial suede. The physical properties of the artificial suede of the present example i are described in the following physical property comparison table. A nylon 3 mesh reinforcing material having a fineness of 3 Danny (nylon/polyacetic island-type microfiber) and a component of 〇. is made into a weight coffee 2: a bismuth cloth. Then, the base cloth is sent to the reducer, and the island-type ultrafine fiber is melted and removed by the heavy shoulder test solution, and washed 10 1297746 -* ' . - drying, at this time, the nylon fiber fineness in the base cloth For 0. 07 Danny. The reduced base fabric was dyed with a dye (trade name: Irgalan Blue, weight percent 40/〇, company name CIBA) in a dyeing machine (jigger) at a temperature of 95 for 6 minutes, then Washed and dried. The above dyeing step is used to coarsely adjust the color of the base fabric. The dyed base fabric is impregnated with an aqueous polymer elastomer resin, and the aqueous polymer elastomer resin component is an aqueous resin (trade name: Purepelle, company name: DOW) and an aqueous polyurethane resin having a water ratio of 30/70 (PU). ), and added antioxidant (weight·% 1%) and bridging agent # (weight percent 0.7%) and aqueous colorant (5% by weight of aqueous resin). The above aqueous coloring is used to fine tune the color of the base fabric. Finally, it is cured, dried and ground to form a high-fastness environmentally-friendly artificial suede. It can also be washed, dried and softened to form a soft high-fastness environmentally-friendly artificial suede. The physical properties of the artificial suede of the second embodiment are described in the following physical property comparison table. Comparative Example 1 ·· The fineness 3 Danny (nylon/polyester island-type microfiber) and the component of 〇.imm Nylon mesh reinforcement material were made into a weight of 4〇〇g/m2 by a needle rolling machine _ Γ· 0ιηιη non-woven fabric. The non-woven base fabric is impregnated with a water-based resin, and the water-based dendritic component is an aqueous resin (trade name: purepelle, company name: D〇w) • an aqueous polyurethane resin (PU) having a water ratio of 30/70 and added Antioxidant • After curing and drying, remove the Haicheng. After 10% by weight of strong alkali solution, it is washed, dried and ground to form a semi-finished artificial suede. The artificial suede semi-finished product was dyed with a dye (trade name: Irgalan Blue, weight percentage 4%, company name: CIBA) in a dyeing machine (Jigger) at a temperature of 95 C and a constant temperature of 60 minutes', then It is a well-known artificial suede that has been washed, dried, and softened. The physical properties of the artificial suede of Comparative Example 1 are described in the physical property comparison table of the following 1297746. Comparative Example 2 ·· The fineness 3 Danny (nylon/polyester island-type ultrafine fiber) and the 〇ljnm component Nylon mesh reinforcement material were made into a non-woven fabric with a weight of 400 g/m2 and a thickness of 1·0ιηιη by a needle rolling machine. Base cloth. The non-woven base fabric is impregnated with an oil-soluble polyurethane resin (trade name · · HS-80, company name · Risheng Chemical), and then subjected to a curing and drying step, and then the sea component is removed by a weight percentage 丨〇% strong alkali solution. It is washed, neutralized, dried and ground to form a semi-finished artificial suede. The artificial suede semi-finished product was dyed with an acid dye (trade name: Irgalan Blue, weight percentage 4%, company name: CiBA) in a dyeing machine (7), temperature %. It was = warm time 60 minutes, then washed with water, Drying and softening becomes a smashing L-skin. The physical properties of the artificial suede of Comparative Example 2 are described in the following physical property comparison table. Test comparison table wash test friction fastness lightfast Example 1 ~~7~---- 4.0 Test 4.0 D:4 4.0 Example 2 -r~^·-- 4·〇W: 4 4.0 D:4 4.0 Comparative Example ---~~~__ W: 4 1 D: 3.0 W: 2.5 3.5 Comparative Example 2 2.0 ~dT3T~~ 3.0 ---^—W: 2.5
八 °亥比較表之物性判定標準伤妒據TCA 標等級區分為i ”根據ISO 105-03灰 (1·差，5:優），包含下列： ※耐汗測試標準·· AATCC 1A法 12 I297746 ※水洗測試標準：AATCC 15法 ※摩擦堅牢度測試標準（D:乾燥，W:潮濕）：AATCC 8 法 ※而t光堅牢度測試標準：ASTM D1148法 根據該物性比較表，本發明實施例1及2之人造麂皮的 物性（耐汗、水洗、摩擦堅牢度及耐光·堅牢度）確實較優於 先前技術之比較例1、2。 | 本發明之人造麂皮製造方法使用水性高分子彈性體樹 月曰及架橋劑而不需要溶劑，諸如二甲基甲醯胺（DMF)，因 此k ί哀保。再者’本發明之含浸用之架橋劑可使凝固後之 巧分子彈性體樹脂更結實，用以增加人造麂皮之強度及物 性。再者’本發明之含浸層可具有水性色料，用以微調該 基布之顏色。 雖然本發明已以前述實施例揭示，然其並非用以限定本 發明，任何本發明所屬技術領域中具有通常知識者，在不 Φ 脫離本發明之精神和範圍内，當可作各種之更動與修改。 因此本發明之保護範圍當視後附之申請專利範圍所界定者 為準。 【圖式簡單說明】 • 第1圖為根據本發明之人造麂皮成品製造方法之流程 • 圖。 第2圖為根據本發明之人造麂皮之剖面示意圖。 第3圖為根據本發明之人造麂皮最終成品製造方法之 13 1297746 ' 流程圖。 【主要元件符號說明】 102 針軋 104 減量 106 染色 108 含浸 110 固化 114 烘乾 116 研磨 118 成品 122 水洗 124 烘乾 126 摔軟 128 最終成品 200 人造麂皮成品 202 超細纖維 204 補強材 206 基布 208 含浸層 14According to the TCA standard grade, the scar according to the TCA standard is classified as i" according to ISO 105-03 gray (1. poor, 5: excellent), including the following: ※Khan test standard ·· AATCC 1A method 12 I297746 ※ Washing test standard: AATCC 15 method ※ Friction fastness test standard (D: dry, W: wet): AATCC 8 method ※ and t light fastness test standard: ASTM D1148 method according to the physical property comparison table, the first embodiment of the present invention The physical properties of the artificial suede of 2 and 2 (perspiration, washing, rubbing fastness, light fastness and fastness) are indeed superior to those of Comparative Examples 1 and 2 of the prior art. | The artificial suede manufacturing method of the present invention uses aqueous polymer elastic The body tree and the bridging agent do not require a solvent, such as dimethylformamide (DMF), so k ί 保. Further, the bridging agent for impregnation of the present invention can make the gelled molecular elastomer resin after solidification. More robust to increase the strength and physical properties of the artificial suede. Further, the impregnated layer of the present invention may have an aqueous coloring material for finely adjusting the color of the base fabric. Although the present invention has been disclosed in the foregoing embodiments, it is not Used to define the invention, Those skilled in the art to which the invention pertains will be able to make various changes and modifications without departing from the spirit and scope of the invention. The scope of the present invention is defined by the scope of the appended claims. BRIEF DESCRIPTION OF THE DRAWINGS Fig. 1 is a flow chart of a method for producing a synthetic suede product according to the present invention. Fig. 2 is a schematic cross-sectional view of a synthetic suede according to the present invention. Inventive artificial suede final product manufacturing method 13 1297746 'Flowchart. [Main component symbol description] 102 pin rolling 104 reduction 106 dyeing 108 impregnation 110 curing 114 drying 116 grinding 118 finished product 122 washing 124 drying 126 breaking soft 128 Finished product 200 Artificial suede finished product 202 Microfiber 204 Reinforced material 206 Base cloth 208 Impregnated layer 14